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Integrity of production wells and confining unit at the Naval Weapons Industrial Reserve Plant, Dallas, Texas, 1995

Ground water in the shallow alluvial aquifer is contaminated at the Naval Weapons Industrial Reserve Plant, Dallas, Texas. Five production wells at the site are cased through the alluvial aquifer and underlying units and are screened in either the Paluxy or Twin Mountains aquifers. Three abandoned wells, originally completed in the Twin Mountains aquifer but filled with drilling mud in 1958, also penetrate the alluvial aquifer. The Paluxy and Twin Mountains aquifers are used for drinking-water supplies in and around the Dallas-Fort Worth metroplex. Trichloroethylene and its degradation products, dichloroethylene and vinyl chloride, and the metal chromium previously have been detected in the shallow alluvial aquifer. Current (1995) analyses of water-quality samples taken from the static water column of the five production wells and one of the abandoned wells indicate no trichloroethylene, dichloroethylene, or vinyl chloride in the water column of these wells. Chromium was detected in all samples, but concentrations were less than the practical quantitation limit, which is the regulatory action level for this site. The results of borehole geophysical log analysis indicate that two of the production wells could have vertically connected intervals where cement bonding in the well annulus is poor. The other production wells have overall good bonding. Temperature logs do not indicate flow behind casing except in the screened interval of one well. Geophysical logs show the Eagle Ford Shale ranges from 147 to 185 feet thick at the site. The Eagle Ford Shale has low permeability and a high plasticity index. These physical characteristics make the Eagle Ford Shale an excellent confining unit.

Texas

Investigating the influence of climate and volcanic surface aging on fluvial erosion: A case study of Réunion Island, Indian Ocean

Precipitation is one of the dominant drivers of landscape erosion and evolution; however, the effects of typical rainfall compared with less frequent, high-magnitude precipitation events on erosion remain unclear. Volcanic islands are ideal locations to study such phenomena due to their simple geometries, nontectonic construction, and strong spatiotemporal rainfall gradients. However, spatial variation in surface age, created during their construction, often complicates their degradation histories by introducing temporal changes in erosion rates as drainage networks develop. Réunion Island (western Indian Ocean) presents a clear example of this, with an east–west gradient in both surface age and mean annual precipitation, as well as infrequent cyclones that alter the background rainfall pattern. In this study, we analyze the effects of surface age, average rainfall, and rainfall variability on basin development and fluvial erosion across the island. We calculate basin-averaged values of basin morphology, age, precipitation, river discharge, eroded volumes, and erosion rates, and use these to analyze the dominant drivers of landscape evolution through a series of correlation analyses. Our results indicate a temporal dependence on the influence of precipitation, with young surfaces being dominantly eroded by high-rainfall events and older surfaces eroded by mean annual rainfall patterns. Furthermore, we show that drainage development of shield volcanoes follows similar trends to other volcano types, and suggest that surface permeability and groundwater structure are important controls on runoff-driven erosion on shield volcanoes. These results add new components to the question of how precipitation impacts erosion.

Réunion Island

(Re)discovering the seismicity of Antarctica: A new seismic catalog for the southernmost continent

We apply a machine learning (ML) earthquake detection technique on over 21 yr of seismic data from on‐continent temporary and long‐term networks to obtain the most complete catalog of seismicity in Antarctica to date. The new catalog contains 60,006 seismic events within the Antarctic continent for 1 January 2000–1 January 2021, with estimated moment magnitudes (⁠Mw ⁠) between −1.0 and 4.5. Most detected seismicity occurs near Ross Island, large ice shelves, ice streams, ice‐covered volcanoes, or in distinct and isolated areas within the continental interior. The event locations and waveform characteristics indicate volcanic, tectonic, and cryospheric sources. The catalog shows that Antarctica is more seismically active than prior catalogs would indicate, examples include new tectonic events in East Antarctica, seismic events near and around the vicinity of David Glacier, and many thousands of events in the Mount Erebus region. This catalog provides a resource for more specific studies using other detection and analysis methods such as template matching or transfer learning to further discriminate source types and investigate diverse seismogenic processes across the continent.

Seismological Research Letters

Airborne radiometric data map alteration of porphyry copper systems in the Elkhorn district, MT

The Elkhorn district in southwestern Montana is known for past production of high-grade base and precious metals from skarn and carbonate replacement deposits. The district also hosts a porphyry Cu-Mo deposit. A radiometric survey flown over the district and surrounds provides maps of surficial concentrations of potassium, thorium, and uranium. Handheld gamma ray spectrometer measurements on altered and unaltered rocks in the district and surrounding region provide a means to ground truth the airborne data. We demonstrate that the airborne and ground-based measurements show similar map patterns. We calculate ratios of the radioelement concentrations and present a potassium enhancement map that combines potassium and ratios of potassium to thorium and uranium. The results highlight the rocks previously mapped as having K-feldspar-biotite and quartz-sericite alteration assemblages in the Elkhorn district and map additional hydrothermal systems in the region, including known alteration in the Radersburg district. The data enhancement techniques can be used as a screening tool for mapping additional porphyry copper systems.

Montana

ShakeAlert Earthquake Early Warning System performance during the Mw 7.0 offshore Cape Mendocino earthquake

The 5 December 2024 M w 7.0 Offshore Cape Mendocino earthquake was a challenging test of the U.S. West Coast ShakeAlert earthquake early warning system due to its offshore epicenter and limited near‐source station coverage. We analyzed real‐time performance of all components of the ShakeAlert system, including the seismic algorithms (earthquake point‐source integrated code [EPIC] and Finite‐fault rupture Detector [FinDer]), the geodetic algorithm (Geodetic First Approximation of Size and Time–peak ground displacement [GFAST‐PGD]), and network telemetry during the event. EPIC created the first solution for this earthquake 15 s after origin time with an initial magnitude estimate of M 5.6 and location error of 10 km from the Advanced National Seismic System epicenter. An early spurious trigger from station CE.89101 fortuitously maintained location accuracy and, correspondingly, magnitude accuracy. FinDer contributed its first solution at 18 s with a location estimate closer to the seismic network and produced two distinct rupture geometries, leading to minor fluctuations in estimated intensity contours. GFAST‐PGD did not meet alerting thresholds but otherwise performed as expected. Network latencies were <2 s for most stations, supporting the rapid detection of this earthquake by the system. Roughly five million alerts were delivered to cell phone devices in California and Oregon during this event. This was also the first instance of a school district‐wide ShakeAlert‐powered system being activated. Comparisons to recorded seismograms demonstrate that the maximum warning times before potentially damaging shaking (intensity 6+) were in the range of 5–55 s. Although the ShakeAlert system provided accurate solutions and useful alert delivery, this earthquake raised awareness of potential issues within the system, including the need for improved offshore location estimates, a combination of solutions from ShakeAlert servers, and handling of spurious triggers.

California

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Water quality of selected springs and public-supply wells, Pine Ridge Indian Reservation, South Dakota, 1992-97

This report presents results of a water-quality study for the Pine Ridge Indian Reservation, South Dakota. The study was a cooperative effort between the U.S. Geological Survey and the Water Resources Department of the Oglala Sioux Tribe. Discharge and water-quality data were collected during 1992-97 for 14 contact springs located in the northwestern part of the Reservation. Data were collected to evaluate potential alternative sources of water supply for the village of Red Shirt, which currently obtains water of marginal quality from a well completed in the Inyan Kara aquifer. During 1995-97, water-quality data also were collected for 44 public-supply wells that serve about one-half of the Reservation's population. Quality-assurance sampling was used to evaluate the precision and accuracy of environmental samples. Ten of the springs sampled contact the White River Group, and four contact the Pierre Shale. Springs contacting the White River Group range from calcium bicarbonate to sodium bicarbonate water types. Two springs contacting the Pierre Shale have water types similar to this; however, sulfate is the dominant anion for the other two springs. In general, springs contacting the White River Group are shown to have better potential as alternative sources of water supply for the village of Red Shirt than springs contacting the Pierre Shale. Nine of the springs with better water quality were sampled repeatedly; however, only minor variability in water quality was identified. Six of these nine springs, of which five contact the White River Group, probably have the best potential for use as water supplies. Discharge from any of these six springs probably would provide adequate water supply for Red Shirt during most periods, based on a limited number of discharge measurements collected. Concentrations of lead exceeded the U.S. Environmental Protection Agency (USEPA) action level of 15 µg/L for three of these six springs. Five of these six springs also had arsenic concentrations that exceeded 10 µg/L, which could be problematic if the current maximum contaminant level (MCL) is lowered. Blending of water from one or more springs with water from the existing Inyan Kara well may be an option to address concerns regarding both quantity and quality of existing and potential sources. All nine springs that were sampled for indicator bacteria had positive detections on one or more occasions during presumptive tests. Although USEPA standards for bacteria apply only to public-water supplies, local residents using spring water for domestic purposes need to be aware of the potential health risks associated with consuming untreated water. One spring contacting the White River Group and two springs contacting the Pierre Shale exceeded 15 pCi/L for gross alpha; these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Nine springs were sampled for selected pesticides and tritium. The pesticides atrazine, carbaryl, and 2,4-D were not detected in any of the samples. The nine springs were analyzed for tritium in order to generally assess the age of the water and to determine if concentrations exceeded the MCL established for gross beta-particle activity. Tritium results indicated two springs are composed primarily of water recharged prior to atmospheric testing of nuclear bombs and two other springs have a relatively large percentage of test-era water. The remaining five springs had tritium values that indicated some percentage of test-era water; however, additional sampling would be needed to determine whether water is predominantly pre- or post-bomb age. Of the 44 public-supply wells sampled, 42 are completed in the Arikaree aquifer, one is completed in an alluvial aquifer, and one is completed in the Inyan Kara aquifer. Water from the alluvial well is a sodium bicarbonate water type, water from Arikaree aquifer ranges from calcium bicarbonate to sodium bicarbonate types, and water from the Inyan Kara well is a calcium sulfate bicarbonate type. Of the 44 wells sampled, 28 (64 percent) tested positive for indicator bacteria in presumptive tests. Because these were single samples that generally were collected upstream from chemical treatment feeders, positive detections do not necessarily constitute exceedances of drinking-water standards. A single sample from an Arikaree well exceeded the MCL for arsenic of 50 µg/L. Arsenic exceeded 10 µg/L for six additional Arikaree wells and for the alluvial well and the Inyan Kara well, which could be problematic if the current MCL is lowered. The alluvial well also exceeded the secondary maximum contaminant level (SMCL) for dissolved solids, which is non-enforceable, and the action level for lead. The Inyan Kara well exceeded the SMCL's for iron and for manganese and the MCL of 5 pCi/L for radium-226 and 228 combined. Several Arikaree wells exceeded SMCL's for either pH, sulfate, dissolved solids, iron, or manganese. One Arikaree well exceeded the MCL of 4.0 mg/L for fluoride and another exceeded the MCL of 10 mg/L for nitrite plus nitrate. Ten Arikaree wells equalled or exceeded 15 pCi/L for gross alpha; however, these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Eight wells, all from the Arikaree aquifer, equalled or exceeded the proposed MCL of 20 µg/L for uranium and 33 wells (75 percent) equalled or exceeded one-half of the proposed MCL. Although this standard has only been proposed, additional information regarding the extent of elevated uranium concentrations in the Arikaree aquifer, and the geochemical processes involved, may be beneficial. It was determined from analyses of uranium isotope data for five wells that the source of elevated uranium concentrations is naturally occurring, rather than anthropogenic.

South Dakota

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho

PEST++IES how many iterations & realizations, finding the point of diminishing returns

PEST++IES (White 2018; White et al. 2020) is widely used in the groundwater modeling community for its ability to perform computationally efficient history matching and uncertainty analysis in a highly parameterized context. One primary advantage of using an iterative ensemble smoother is that the number of model runs required per iteration depends on the number of realizations in an ensemble, not the number of parameters in each realization. However, this raises the question: what is the optimal number of realizations and iterations to use for any one model before the point of diminishing returns? Using a modified version of the Freyberg model (Freyberg 1988; Hunt et al. 2020), different parameter and observation scenarios were evaluated for four iterations and ensembles of 10, 25, 50, 100, 250, 500, 1000, and 2000 realizations. To match observations, PEST++IES altered hydraulic conductivity ( k ), both globally across the model and locally at three different pilot point densities, as well as global recharge (via a single multiplier), global river conductance, and individual well flow rates. Risk-based well capture zone results (Fienen et al. 2022a) and estimated hydraulic conductivity fields from each scenario were quantitatively and qualitatively compared against the “truth” model and its outputs. Across the cases examined, ensemble sizes of 100 to 250 realizations and two PEST++IES iterations were generally sufficient to achieve good results.

Groundwater

A geographic dataset of rocky reefs habitat areas of particular concern for the United States West Coast

The United States National Marine Fisheries Service determines “essential fish habitat (EFH)” for federally managed species in coordination with regional fishery management councils, considers adverse effects to those habitats, and provides information to further habitat conservation and enhancement. Identifying discrete subsets of EFH as “habitat areas of particular concern (HAPC)” can help focus conservation, management, and research efforts. In 2006, the Pacific Fishery Management Council designated rocky reefs along the United States (U.S.) West Coast as HAPCs for groundfishes because of their ecological significance, sensitivity to human impacts, and relative rarity. To better understand where rocky reefs occur, we (1) located rocky reef areas that were not included in the 2006 rocky reef dataset, and (2) incorporated best available data into a refined geographic dataset that enables visualization. Our update shows that rocky reefs are distributed throughout the U.S. West Coast continental margin, are patchier than previously known, and comprise 8% of the extent of all data inputs. This updated dataset will inform resource management decisions in coastal and marine environments.

California, Oregon, Washington

Vulnerability assessment of groundwater influenced ecosystems in the Northeastern United States

Groundwater-influenced ecosystems (GIEs) are increasingly vulnerable due to groundwater extraction, land-use practices, and climate change. These ecosystems receive groundwater inflow as a portion of their baseflow or water budget, which can maintain water levels, water temperature, and chemistry necessary to sustain the biodiversity that they support. In some systems (e.g., springs, seeps, fens), this connection with groundwater is central to the system’s integrity and persistence. Groundwater management decisions for human use often do not consider the ecological effects of those actions on GIEs. This disparity can be attributed, in part, to a lack of information regarding the physical relationships these systems have with the surrounding landscape and climate, which may influence the environmental conditions and associated biodiversity. We estimate the vulnerability of areas predicted to be highly suitable for the presence of GIEs based on watershed (U.S. Geological Survey Hydrologic Unit Code 12 watersheds: 24–100 km 2 ) and pixel (30 m × 30 m pixels) resolution in the Atlantic Highlands and Mixed Wood Plains EPA Level II Ecoregions in the northeastern United States. We represent vulnerability with variables describing adaptive capacity (topographic wetness index, hydric soil, physiographic diversity), exposure (climatic niche), and sensitivity (aquatic barriers, proportion urbanized or agriculture). Vulnerability scores indicate that ~26% of GIEs were within 30 m of areas with moderate vulnerability. Within these GIEs, climate exposure is an important contributor to vulnerability of 40% of the areas, followed by land use (19%, agriculture or urbanized). There are few areas predicted to be suitable for GIEs that are also predicted to be highly vulnerable, and of those, climate exposure is the most important contributor to their vulnerability. Persistence of GIEs in the northeastern United States may be challenged as changes in the amount and timing of precipitation and increasing air temperatures attributed to climate change affect the groundwater that sustains these systems.

Connecticut, Delaware, District of Columbia, Maine

Formation of the Mount Weld rare earth deposit, Western Australia: Geochronology constraints

Constraining the age of protracted chemical weathering in stable cratonic areas that may form thick regoliths and the potential enrichment of various elements is challenging. Economic deposits of aluminium, iron, copper, nickel, cobalt, niobium, and rare earth elements (REEs) form in this manner. Determining the age of formation can provide key information for exploration of similar deposits as well as to better constrain paleoclimatic conditions. This study describes our effort to constrain the age of formation of the Mount Weld deposit, a world-class carbonatite-derived REE laterite deposit. We utilize multiple geochronological techniques on different minerals. The oldest dates, ranging from ca. 100 to 50 Ma, were from laser ablation ICPMS, Lu-Hf dating of churchite, a heavy REE phosphate mineral formed by mineral saturation in groundwater. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane, a potassium-bearing manganese oxide mineral, yielded ages ranging from ca. 40 to 26 Ma. Similarly, (U–Th)/He geochronology of goethite yielded ages from ca. 45 to 19 Ma.

Mount Weld deposit

Latitudinal gradients of snow contamination in the Rocky Mountains associated with anthropogenic sources

Seasonal snow is an important source of drinking water and recreation, and for agriculture in the Rocky Mountain region. Monitoring snow-water quality can inform on the effects to the albedo and energy balance of the snowpack, and the sources of natural and anthropogenic aerosol and gases. This study analyzed metals in the seasonal snowpack from water year (WY) 2018 for 49 sites. Calcium, lanthanum, and cerium concentrations support the importance of mineral dust to the southern Rocky Mountains. Mercury (Hg), zinc (Zn), and cadmium (Cd) concentrations showed a similar spatial pattern to mineral dust, whereas antimony (Sb) concentrations were highest in the northern Rocky Mountains. To assess the relative contributions from dust versus anthropogenic contaminant sources, enrichment factors (EF) were calculated, with values above 10 indicating anthropogenic contamination. For Cd, Hg, Sb, and Zn, EF values exceeded 10 at northern sites. These observations were compared to spatial trends of EF values of Hg from WY2009 to WY2018, regional monitoring networks, and back trajectory analyses. The agreement between these datasets revealed temporally consistent contaminant sources and/or transport processes to the northern Rocky Mountains snowpack. Sources include current and historical mining and smelting in the region. Strategies to limit the emissions of these metals to the Northern Rockies could benefit from focusing on remediation of contaminated sites, and continued monitoring and mitigation of active mining and smelting.

Colorado , Idaho, Montana, New Mexico, Utah, Wyomi

Using hydrogeologic context and water budgets to evaluate the potential for groundwater contributions to contaminants in Lake Superior

This study presents a synthesis of the hydrogeology in the U.S. Lake Superior watershed and the contribution of groundwater to the water budget of the U.S. Lake Superior basin. Much of the shoreline of Lake Superior in Minnesota and Michigan is composed of hydrogeologic units contributing very little direct groundwater discharge to the lake. Groundwater in watersheds adjacent to the lake typically flows in short, local flow systems characterized by thin glacial sediments with active groundwater flow in fractured bedrock within the top 60–90 m below land surface. The complex groundwater system in Wisconsin’s Bayfield Peninsula has the largest groundwater reservoir near the lake, characterized by thick sand and gravel glacial deposits and underlying sandstone aquifer. Although these thick sandy glacial deposits are not in direct contact with the lake at the shoreline, groundwater discharge may still be significant via subsurface exposures beyond the shoreline or flow through the underlying sandstone aquifer. Overall, most groundwater in the watershed is contributed as indirect base flow in streams around the lakeshore and comprises about 60 percent of the upland water budget. Direct groundwater flow to the shoreline contributes 2 to 9 percent of the inflow. Identifying possible contamination sources through direct sampling of groundwater would be an inefficient way to detect problems if sources are unknown, particularly for some chemicals of concern such as PFAS, pesticides, PCBs, chloride, and nutrients. Evaluating the chemical characteristics of contamination is also important to consider in evaluating how groundwater may contribute to pollution in Lake Superior.

Lake Superior

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia