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Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas

Biogeochemical and community ecology responses to the wetting of non-perennial streams

Transitions between dry and wet hydrologic states are the defining characteristic of non-perennial rivers and streams, which constitute the majority of the global river network. Although past work has focused on stream drying characteristics, there has been less focus on how hydrology, ecology and biogeochemistry respond and interact during stream wetting. Wetting mechanisms are highly variable and can range from dramatic floods and debris flows to gradual saturation by upwelling groundwater. This variation in wetting affects ecological and biogeochemical functions, including nutrient processing, sediment transport and the assembly of biotic communities. Here we synthesize evidence describing the hydrological mechanisms underpinning different types of wetting regimes, the associated biogeochemical and organismal responses, and the potential scientific and management implications for downstream ecosystems. This combined multidisciplinary understanding of wetting dynamics in non-perennial streams will be key to predicting and managing for the effects of climate change on non-perennial ecosystems.

Nature Water

Fairweather transform boundary Oligocene to present orogenesis: Fairweather Range vertical extrusion and rotation of the Yakutat microplate at ca. 3 Ma

Oblique-slip along transform fault boundaries is often partitioned between a strike-slip system and thrust faults that accommodate contraction. However, topography along the Yakutat-North American transform (Fairweather fault), is asymmetric with low-terrain above active thrusts on the western, Yakutat side of the transform and high topography on the continental side with peaks >4500 m (Mount Fairweather: 4671 m) to the west of the Border Ranges fault, limited recorded earthquakes >M4, and no apparent reverse faults to generate the highest terrain. In this study we compile, for the first time, published U-Pb zircon, 40 Ar/ 39 Ar and K-Ar (hornblende, muscovite, and biotite) and U-Th/He and fission-track (zircon and apatite) bedrock ages (109) from 75 samples to investigate the exhumation history of the Fairweather Range region, complemented by a published detrital sample (ZFT and AFT) and 13 new 40 Ar/ 39 Ar (hornblende, biotite, and K-feldspar) ages on 9 bedrock samples from both sides of the Fairweather fault. Additionally, we examined published seismicity and geodetic data of the Fairweather region and assessed if plate paleo-vectors correlate with the cooling history of the Fairweather Range. Cooling age, seismic, and block-motion patterns indicate the Fairweather Range has been vertically extruded between the Fairweather and the Border Ranges faults as a coherent block since ca. 25 Ma. The pre-6 Ma Pacific plate motion (N30°W) aligns with the N33°W strike of the Fairweather Fault whereas a hypothetical pre-6 Ma Yakutat microplate paleo-vector of (N39°W) does not: indicating a post-6 Ma timing for Yakutat microplate counter-clockwise rotation (9°). We infer that rotation and impingement of the Yakutat microplate along the Fairweather fault at ca. 3 Ma led to the development of the Fairweather restraining bend and increased cooling rates. The resultant thickened Fairweather welt and the ∼30 km thick southeast end of the Yakutat microplate compounded double-indenter tectonics into Alaska's southeast convergent corner

Tectonophysics

Assessing future hydrologic extremes using an integrated hydrology and river operations model in the Russian River watershed

Study region The Russian River watershed, situated in coastal, northern California, experiences hydrologic extremes, including periodic droughts and flooding. Water managers are working to maintain sustainable water supplies and environmental flows, while mitigating flood risks. Study focus This paper introduces an integrated hydrology and river operations model for the Russian River watershed. This model is distinct from models in previous studies because it represents surface-groundwater interactions and uses climate forcings to estimate dynamic water use demands that are superimposed onto both reservoir operations and water supply constraints. The model was used to examine three historical (1990–2015) and eight future (2016–2099) water use and climate change scenarios. New hydrological insights for the region The direct connection between streams and aquifers facilitated both annual aquifer replenishment by high winter streamflows and streamflow depletion by groundwater wells (19 % of pumped groundwater in alluvial aquifers from stream leakage) during critical low flow periods. Simulated streamflow changes included 59 % longer and 54 % more severe streamflow droughts, 26 % lower seasonal low streamflows, and up to 125 % higher peak streamflows, averaged over future climate and water use scenarios, suggesting increased future flood and water availability risks. Results showed the importance of reservoir operations for mitigating the impacts of increased hydroclimatic volatility, despite a decrease in reservoir reliability at Lake Mendocino, suggesting that reservoir management may be used to decrease future risks.

California

Geophysical characterization of mine influenced groundwater and surface water in the Mayflower section of the Animas River, Bonita Peak Mining District, Silverton Colorado

This report details findings from geophysical investigations to identify possible groundwater - surface water interactions near the Mayflower Section of the Animas River in Silverton, Colorado. The Mayflower Section is a mine influenced Superfund Site in Colorado. This investigation utilized electromagnetic induction (EM or EMI), magnetic, and fiber optic distributed temperature system (FODTS) geophysical methods to measure the bulk earth electrical conductivity, magnetic susceptibility, and temperature of specific surveyed volumes of the earth near the Mayflower Section of the Animas River. These physical parameters are used to understand the groundwater – surface water interactions, which can guide decision makers in their assessment of mine-impacted surface water. This report details the results from characterization and monitoring technologies to provide high data density and continuous monitoring of bulk earth electrical conductivity and temperature in the Mayflower section of the Animas River to identify zones of groundwater – surface water interactions and potential metal loading from mine influenced water. The investigation separated right and left bank characterization for each method and indicates more groundwater is entering from the right bank than the left bank and these predominantly right bank discharges potentially contain metal-rich water compared to the left bank. Results also indicate mineral veins facilitate preferential groundwater discharge to the river due to possible jointing, fractures, and permeability differences sometimes occurring along veins relative to host rock. For example, Boulder Gulch is likely groundwater dominated and may be receive water impacted by Mayflower Impoundments #1 and #2. Additionally, the beaver ponds near Blair Gulch may influence groundwater discharge and Mayflower Impoundment #4 is possibly impacting groundwater and surface water and may be connected to the wetlands to the west of the impoundment. These data could be further analyzed for smaller spatial scale analysis within areas of interest. The identification of these locations along sections of the river likely impacted by mine influenced groundwater potentially entering the Animas River and can be used by site investigators, decision makers, and stakeholders in mitigation decisions and strategies.

Colorado

Surface rupture and slip distribution of the 2025 Mw7.7 Mandalay earthquake and updated length scaling of supershear earthquakes

The 2025 M w 7.7 Mandalay, Burma (Myanmar), earthquake ruptured 475 km of the central Sagaing fault and is the longest continental strike-slip rupture on record. The observed rupture length is 1.6–4.7 times the value expected (100–300 km) from existing length-magnitude scaling relations for strike-slip earthquakes. The earthquake resulted from shallow dextral faulting and ruptured bilaterally with supershear speeds south of the epicenter, rupturing close to three major cities in Myanmar and exposing over six million people to violent or extreme shaking. We report on the surface rupture character, length, and slip distribution based on sub-pixel correlation of Sentinel-2 (10 m) and Planet Dove (3 m) optical images and visual analysis of SkySat and WorldView (0.3–0.5 m) optical images. The earthquake had moderate surface slip (average = 3.3 m, maximum = 5.6 m, 25–75% range = 3.0–4.0 m), narrow deformation zone width (1–10 pixels in sub-pixel correlation and up to 190 meters for the detailed surface rupture mapping), and simple fault geometry (no stepovers or large changes in strike, 87% of the rupture that was mapped in detail is single-stranded). We attribute the extreme length of the Mandalay earthquake to supershear rupture speed, simple fault geometry, narrow down-dip width, and moderate surface slip. Based on a compilation of 25 supershear strike-slip earthquakes ( M w 6.5–8.6; 1979–2025), we find that the rupture length of supershear earthquakes does not fit empirical scaling relationships for strike-slip earthquakes that predict length from magnitude. A length-magnitude scaling relationship based on supershear earthquakes has a best fit of log 10 (surface rupture length) = 0.89 M w – 4.44, indicating that supershear earthquakes tend to be longer than their subshear counterparts for any given magnitude and thus may expose a greater population to shaking.

Mandalay

New U-Pb geochronology and geochemistry of Paleozoic metaigneous rocks from western Yukon and eastern Alaska, cross-border synthesis, and implications for tectonic models

The tectonic evolution of and relation between the Yukon-Tanana terrane and the Lake George assemblage, as well as other associated tectonic assemblages in western Yukon and eastern Alaska, have been debated for decades. The Yukon-Tanana terrane is widely considered to be an allochthonous rifted fragment derived from the Laurentian continental margin, whereas the Lake George assemblage and associated assemblages are currently interpreted to be part of the parautochthonous continental margin of western North America (Laurentia). To address these topics, we present 40 new U-Pb zircon ages and 20 new whole-rock geochemical analyses. We incorporate these data into a new compilation of available geological mapping for a large area that straddles the Alaska-Yukon border, together with 34 previously published U-Pb age determinations and an extensive geochemical database of metaigneous rocks from Late Devonian to Early Mississippian and middle to late Permian assemblages in this area. Magmatism in the Lake George assemblage and related assemblages occurred in two pulses from about 371 to 360 and from about 358 to 347 million years ago (Ma); geochemical discrimination diagrams indicate a large crustal component, possibly indicative of arc magmatism, for felsic metaigneous rocks and a range of tectonic environments for mafic rocks. Magmatism in the Fortymile River and related assemblages, and parts of the Nasina assemblage—all parts of the Yukon-Tanana terrane—are mainly Early Mississippian and span a crystallization age range from about 361 to 343 Ma; geochemical discrimination diagrams for these rocks indicate primarily arc geochemical signatures for both mafic and felsic rocks. Middle to late Permian crystallization ages (about 261–253 Ma) are indicated for felsic metaigneous rocks in the Klondike assemblage and some of the felsic metaigneous rocks in the Nasina assemblage. Based on our mapping, we propose the existence of a possible unconformity between the Mississippian and Permian felsic metavolcanic rocks within the Nasina assemblage that is marked by sporadic occurrences of stretched-pebble conglomerate. Our combined database supports the well-established model of a magmatic arc comprising the Fortymile River and Finlayson assemblages of the rifted Yukon-Tanana terrane continental fragment on which a middle to late Permian arc (Klondike assemblage) was later built. The assemblages of the Yukon-Tanana terrane were subsequently intruded by Late Triassic to Early Jurassic granitoids, presumably during reaccretion of the Yukon-Tanana terrane to the continental margin. Permian and Late Triassic to Early Jurassic intrusions have not been mapped in the now structurally lower plate Lake George assemblage; their absence is one of the lines of evidence that have been used to support the parautochthonous, rather than allochthonous, origin of the Lake George assemblage and related assemblages. Our new data, together with previously published ranges of igneous crystallization ages and geochemical tectonic signatures of the Late Devonian to Early Mississippian magmatic rocks in the Lake George assemblage and associated assemblages and in the Fortymile River, Nasina, and correlated assemblages of the Yukon-Tanana terrane, indicate that the currently accepted interpretation of the Lake George assemblage and associated rocks being part of parauthochthonous North America is not the only possible interpretation of this tectonic entity. Approximately half of the dated intrusive rocks in the Lake George assemblage are contemporaneous with the metaigneous rocks of the Yukon-Tanana terrane arc (<361 Ma). We speculate that our approximately 361 Ma U-Pb age for quartz syenite in part of the North American continental margin in south-central Yukon defines the beginning of rifting of the Laurentian margin. Although the currently favored model of prolonged middle Paleozoic subduction and extension in both the Yukon-Tanana terrane and parautochthonous North America allows for simultaneous middle Paleozoic magmatism on both sides of the Slide Mountain Ocean, we now propose an alternative hypothesis in which the Lake George assemblage represents a deeper part of the rifted Yukon-Tanana terrane arc. If this is the case, the absence of Permian and Late Triassic to Early Jurassic arc rocks in the Lake George assemblage could be explained either by the arcs of these ages not being wide enough to have affected the Lake George assemblage or by tectonic displacement of these arc rocks away from the Lake George assemblage. Our approximately 259 Ma U-Pb zircon age and geochemical analyses of metarhyolite in the Seventymile terrane in Alaska, which comprises remnants of the back-arc basin that separated the Yukon-Tanana terrane from the Laurentian continental margin, confirm the presence of a late middle Permian volcanic arc component to the terrane. Our approximately 319 Ma U-Pb zircon age from the Chicken assemblage (as redefined in this study) in eastern Alaska, combined with previously reported fossil ages and a U-Pb zircon age from this assemblage, indicate that it is a Late Mississippian to Early Pennsylvanian arc assemblage. We propose several other relatively young, locally developed arc assemblages outboard of the ancient continental margin of Laurentia that may correlate with the Chicken assemblage, but we consider its origin to remain an enigma.

Alaska

A global assessment of SAOCOM-1 L-band stripmap data for InSAR characterization of volcanic, tectonic, cryospheric, and anthropogenic deformation

SAOCOM-1 is an L-band (23.5 cm) synthetic aperture radar (SAR) constellation made up of two satellites launched in 2018 and 2020 by Comisión Nacional de Actividades Espaciales (CONAE, Argentina). In this contribution, we present a global summary of interferometric SAR (InSAR) observations of ground deformation with SAOCOM-1 stripmap data for tracking volcanic, tectonic, glacier, and anthropogenic deformation. These examples include: 1) episodes of unrest at volcanoes in the Aleutian Islands, Southern Andes, and Italy, with line-of-sight (LOS) deformation from 4 cm/yr in InSAR time series to ~70 cm in interferograms; 2) dike intrusions in Hawai’i; 3) earthquakes in the Andean fold and thrust belt and the East Anatolian fault; 4) ice flow of the Southern Patagonia icefield; and 5) subsidence due to lithium brine extraction in the Salar de Atacama basin (northern Chile). Comparisons between SAOCOM-1, ALOS-2 SM3, Sentinel-1, and TerraSAR-X/ TanDEM-X/PAZ (TSX/TDX/PAZ) mean velocities from InSAR time series show a 1:1 ± 3% correlation in the LOS velocity, which highlights the high accuracy of SAOCOM-1 data. The minimum deformation that we measured in individual interferograms is 4 ± 0.6 cm. One limitation of SAOCOM-1 is the lack of a global acquisition program, which reduces its global and broader applications. Considering the repeat periods, background observation program, and lack of a controlled orbital tube, the best suited targets for SAOCOM-1 InSAR are two. First, volcanoes that deform with secular rates located in vegetated regions in mid- and high-latitudes, and/or that undergo transient episodes of fast deformation in which C-band coherence is lost quickly. Second, glaciers where coherence can be sustained during the repeat period of eight days.

IEEE Transactions on Geoscience and Remote Sensing

Multiple machine-learning estimation of groundwater levels and trends for the regional Mississippi River Valley alluvial aquifer

The Mississippi River Valley alluvial aquifer provides irrigation, public, and domestic water supplies across the south-central United States. Declining groundwater levels require improved characterization of changing conditions. Traditional potentiometric-surface mapping does not use all available water-level data or quantify uncertainty. To address these limitations, we developed a data-driven multiple machine-learning (MML) framework delivered through two open-source R packages. The covMRVAgen1 software assembles covariates to 155,960 monthly groundwater levels from 57,695 wells; the mmlMRVAgen1 software trains Cubist and Random Forest models, blends them, and makes 1-kilometer gridded predictions of monthly potentiometric surfaces for the period January 1980–December 2022. The MML approach provides a methodological foundation for region-scale spatiotemporal groundwater prediction and uncertainty quantification, generating 90-percent prediction limits with appropriate empirical coverage. Model performance is acceptable, with a root-mean-square error of about 4.2 feet, standard deviation of 24.82 feet, and a normalized Nash–Sutcliffe efficiency of 0.973.

Arkansas, Illinois, Louisiana, Mississippi, Missou

Three-dimensional geologic framework model of the Rio San Jose groundwater basin and adjacent areas, New Mexico

As part of a U.S. Geological Survey study in cooperation with the Bureau of Reclamation and the Pueblo of Acoma, New Mexico, and the Pueblo of Laguna, New Mexico, a digital three-dimensional geologic framework model was constructed for the Rio San Jose and its surface-water drainage basin in west-central New Mexico. This three-dimensional model defines the altitude, thickness, and extent of 18 geologic units for use in a regional numerical hydrologic model. The model included an undifferentiated Proterozoic basement layer, 13 consolidated Paleozoic and Mesozoic rock units, and 4 Cenozoic units. Model input data were compiled from published cross sections, well data, structure contour maps, selected geophysical data, and data derived from geologic maps and structural features in the study area. These data were used to construct faulted surfaces that represent the upper and lower subsurface geologic unit boundaries. The digital three-dimensional geologic framework model combines faults, the altitude of the tops of each geologic unit, and boundary lines depicting the subsurface extent of each geologic unit. The digital three-dimensional geologic model described in this report and the corresponding data release represents the generalized geometry of the subsurface geologic units; it reproduces with reasonable accuracy the input geologic data and is consistent with previously published subsurface conceptualizations of the region. The geologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

New Mexico

Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse

Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concerns, and their commodity (e.g., lithium) potential. However, produced water geochemistry from many active petroleum plays remain poorly constrained leading to knowledge gaps associated with the origin of brine salinity and parameters (e.g., radium levels) that can impact treatment, disposal, and possible reuse. Here we evaluate the major ion geochemistry, radium concentrations, and stable water isotope composition of ~120 produced water samples collected from 17 producing unconventional petroleum wells in Weld County, Colorado from the Late Cretaceous Niobrara Formation. This sample set encompasses eight produced water time series from four new wells across production days 0 to ~365 and from four established wells across production days ~1000 to ~1700. Additionally, produced water from nine other established Niobrara Formation wells were sampled at discrete time points ranging from day 458 to day 2256, as well as hydraulic fracturing input fluids. These results expand the available Niobrara Formation produced water geochemical data, previously limited to few wells sampled within the first year of production, allowing for the heterogeneity of major ions and radium to be evaluated. Furthermore, we explore the geochemical relationships between major ion ratios and stable water isotope composition to understand the origin of salinity in Niobrara Formation brines from the Denver-Julesburg Basin. These findings are discussed with perspective toward potential treatment and reuse of Niobrara produced water prior to disposal.

Colorado, Nebraska, Wyoming

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Perspectives and insights gained from applying landscape ecological approaches to the Upper Mississippi riverscape

Advances in remote sensing, spatial data collection, hydraulic and geospatial models, and the maturation of landscape ecology during the early 2000s spurred the concept of rivers as landscapes or ‘riverscapes’. Since that time, the Upper Mississippi River Restoration (UMRR) Program - one of the world’s longest running large-river ecosystem restoration and monitoring programs - has applied landscape ecological principles to the Upper Mississippi River System (UMRS). I examine spatial patterns of aquatic nutrient concentrations, submersed aquatic vegetation, and fish and mussel communities, finding that within-river patterns are often patchy in nature, likely resulting from how nutrient processes and community traits interact with spatial variability in hydraulic exchange patterns. Local-scale patchy spatial patterns in the UMRS are embedded in system-scale longitudinal gradients and a hierarchical view of the river has provided a foundation for strategic river restoration planning. Key Words: Aquatic Habitat, hydraulic connectivity, patch, restoration, riverscape

BioScience

Non-destructive sampling of larval amphibians shows tail tissues reflect whole-body methylmercury concentrations and trophic-related differences in bioaccumulation

Mercury (Hg), and specifically methylmercury (MeHg), is a contaminant of global concern to humans and wildlife, but there is still limited understanding of its effects on many taxa. Amphibians are closely associated with water, where Hg is converted to MeHg, and high concentrations of MeHg can reduce survival of amphibians in the wild. However, limited non-lethal proxies exist for estimating MeHg bioaccumulation in amphibian larvae, which could be used to reduce destructive sampling and allow sampling of imperiled species. We evaluated whether tail clips were indicative of whole-body MeHg concentrations of larval amphibians, whether dragonflies were an effective bioindicator of Hg concentrations of larval amphibians, and compared MeHg bioaccumulation in predatory caudate (salamanders, newts) and non-predatory anuran (frogs, toads) larvae. Tail-clip and whole-body MeHg concentrations were strongly correlated, especially for caudates. There was high variability among sites and species, but caudates had higher MeHg than anurans, and MeHg concentrations of caudates and anurans were strongly correlated. Dragonflies were a weak indicator of MeHg for anurans but strong indicators for larval caudates, likely because caudates and dragonflies are carnivorous and occupy similar trophic positions. Our study revealed that sampling tails can be an effective non-destructive index of whole-body MeHg for larval amphibians and demonstrates differences in MeHg bioaccumulation related to trophic position in larval amphibians and dragonflies. All post-embryo life stages for a broad suite of amphibian species can now be sampled non-lethally for MeHg, allowing for a broader examination of population-level effects and focus on imperiled species that cannot be sampled destructively.

conterminous United States