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Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico

A targeted approach for mapping groundwater discharge to surface water and fish thermal refuge in four Lake Ontario tributaries

The duration, magnitude, and frequency of heatwaves are predicted to increase in the coming decades, a combination that can reduce the survival of many fish species. Across the world, there is broad interest in identifying thermal refuge for heat-intolerant fish species and exploring opportunities to enhance or protect these areas. Because deeper groundwater maintains a relatively constant temperature, groundwater-influenced areas along streams can provide cool-water refuge for fish during periods of extreme heat. A targeted approach was developed for identifying existing cold-water zones and areas of substantial groundwater discharge in four high priority Lake Ontario tributaries. Our approach included: (1) predicting where groundwater discharge is most likely with a simple geospatial model and (2) using model predictions to select field sites for intensive high-resolution study, including ground-based mapping of groundwater features (springs, seeps, tributaries) as well as drone-based optical and thermal infrared surveys. Results from field sites were used to both verify model performance and map different types and aerial extents of thermal anomalies. Geospatial modelling successfully predicted regions of widespread groundwater upwelling, later verified and mapped by field and drone surveys. Comparison of model and field survey results further highlighted specific geospatial layers, such as soil/bedrock types and topographic wetness index, as being particularly useful for predicting groundwater influence on streams in the study area. In addition, a comparison of geospatial model results with a model of fish abundances along the studied streams showed significant positive correlations for many heat-intolerant fish species over a wide geographic area. The approach developed in this study can be applied to other watersheds to highlight areas of probable groundwater discharge and could be used by fishery and water resource managers to support cold-water fish habitat management decision-making and resource conservation.

New York

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Geologic map of pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Much of the southeastern United States, including all of Florida, is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains which have accumulated since Middle Jurassic time. The pre-Middle Jurassic rocks that underlie these coastal plains in Florida, here collectively referred to as “basement,” are known only from a relatively small number of boreholes. This scientific investigations map presents an interpretation of the basement geology in a 1:1,000,000-scale subsurface geologic map with supporting text, data, and figures. The subsurface mapping methodology integrates petrographic, geochronological, thermochronological, geochemical, and mineralogical analyses of drill cores and cuttings in the context of regional geophysical data. The pre-Middle Jurassic rocks of Florida consist of the Gondwanan (West African) Suwannee terrane which was accreted to Laurentia during the Alleghanian orogeny and subsequently intruded by Permian granites, superposed by early Mesozoic rift basins, and partially overlain by bimodal Jurassic volcanic rocks. The younger basement components, specifically the Southwest Florida volcanic province, North Florida tholeiites, early Mesozoic rift basins, and Alleghanian granitoids, have correlative and contemporaneous units throughout the Appalachian orogen. In contrast, Florida’s older basement rocks, including Paleozoic siliciclastic strata of the Suwannee basin, North Florida volcanic series, Osceola and Gaskin intrusive complexes, and the St. Lucie Metamorphic Complex, have neither surface exposures nor unequivocal correlates. Major structures include early Mesozoic normal faults and northwest-striking transfer zones such as the Jay fault. Many of these faults define the boundaries of subbasins within the South Georgia rift system. Top-of-basement structure contours show gentle arches and embayments that are also recognized in overlying coastal plain strata.

Florida

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 2 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 2, the subject of this scientific investigations map, has a mapped area of 209 km 2 and has water depths that range from about 19 meters (m) on the Stellwagen Bank crest to about 68 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates across the southwestern part of Stellwagen Bank, in Stellwagen Basin to the west and southwest of the bank, and in Little Stellwagen Basin and the western part of Race Point Channel to the south of the bank. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 733 stations were analyzed, including 656 sediment samples. The geologic substrate maps of quadrangle 2 show the distribution of 19 geologic substrates that represent a wide range of textures, such as rippled and immobile sand, immobile muddy sand and sandy mud, sand that partially veneers gravel, and a boulder ridge. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 2. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and support seabed management in the region.

Massachusetts

Evaluating Laramide orogenesis via flexural basin response in the San Juan basin, New Mexico and Colorado

A challenge in interpreting the location, timing, and magnitude of ancient orogenic events is that ongoing uplift and erosion in the hinterlands often destroys much of the primary record of these events. However, basin-thickness patterns in the sedimentary record can provide complimentary evidence of uplift via flexural effects. Here, we deploy well-log correlation, isochores, basin modeling, flexural modeling, and subcrop mapping to evaluate the Late Cretaceous to Paleogene basin response to Laramide tectonism in the San Juan basin. A wedge of upper Campanian to Maastrichtian sedimentary rock thickens from 200 to 800 meters from southeast to northwest in the basin. This pattern can be successfully simulated via flexural modeling if we infer early Laramide uplift along the northwest basin flank that produced a 0.8 km high topographic load. The Laramide unconformity bounds the top of this Upper Cretaceous sedimentary wedge and truncates progressively older strata to the east, further supporting a westward tilt of the basin. The onset of Campanian Laramide flexure may have also contributed to the profound transgression from the upper Menefee Formation to the Lewis Shale. The Paleocene isochore map displays an approximately symmetrical pattern, with thickening towards the center of the basin. This suggests the possibility of competing flexural loads. The base Eocene structure indicates an asymmetric deep on the northeast flank of the basin, providing flexural evidence of contemporaneous uplift/loading of the Nacimiento uplift and Archuleta arch; this has been modeled as ~2.1 km load height. Both Cretaceous and Paleocene sedimentary wedges are narrow, suggesting low flexural rigidity; modeled effective elastic thicknesses (EET) are 20-30 km, comparable to estimates of modern EET for the region.

Colorado, New Mexico

Constraining the earthquake recording threshold of intraslab earthquakes with turbidites in southcentral Alaska’s lakes and fjords

Strong ground motion from intraslab earthquakes, which do not produce primary paleoseismic evidence, may initiate gravity-driven turbidity flows in subaqueous basins. The resulting deposits (turbidites) can provide a paleoseismic proxy if the conditions that initiate these flows are known. To better constrain the initiating conditions, we use two recent intraslab earthquakes in southcentral Alaska, the M w 7.1 30 November 2018 Anchorage earthquake and the M w 7.1 24 January 2016 Iniskin earthquake, as calibration events. Through a multilake investigation, we document the occurrence, or the absence, of earthquake-generated turbidity flows from these two events. Both earthquakes are recorded by centimeter-scale turbidites that can be differentiated from climatically generated deposits, as well as other seismic sources based on deposit thickness, sedimentological properties, and deposit age. We show that a Modified Mercalli Intensity (MMI) of ∼V–V1/2 is the minimum shaking intensity required to generate localized sediment remobilization from deltaic slopes, and an MMI of ∼V1/2 is required to produce a deposit of sufficient thickness that a seismic origin can be confidently assigned. The documentation of seismically generated deposits in quick succession (∼2 years) with diagnostic features highlights the utility of using recent earthquakes as calibration events to investigate the subaqueous response to strong ground motion.

Alaska

Groundwater response to managed aquifer recharge at the Southeast Houghton Artificial Recharge Project in Tucson, Arizona

Managed aquifer recharge is a widespread practice for storing water in the subsurface as groundwater. At a managed aquifer recharge facility in southern Arizona, groundwater-level and repeat microgravity data were collected to monitor aquifer response. These data were used to inform parameter identification for an unsaturated-zone flow model used to simulate the recharge process. The facility, the Southeast Houghton Artificial Recharge Project (SHARP), consists of 3 surface basins (about 27,600 square meters [6.8 acres] total surface area) where recycled water is distributed in recharge cycles lasting several months, with dry periods in between. During the study period, December 2020–December 2022, Tucson Water (the City of Tucson’s water utility) reported 6.56×10 6 cubic meters of water (5,320 acre-feet) recharged. Monitoring included groundwater-level observations at 3 monitoring wells and repeat microgravity measurements at as many as 22 locations (some stations were destroyed between surveys). Six gravity surveys were carried out using absolute- and relative-gravity meters. Large gravity increases, more than 250 microgals, were observed during the first repeat survey, 3.5 months after the start of recharge, but only in the immediate vicinity of the recharge basins. Data show that water moved downward to the water table, and storage changes in the unsaturated zone away from the facility were likely minimal. Gravity decreased at stations more than 1 kilometer from the facility, consistent with regional groundwater-level changes. Groundwater-level increases in wells adjacent to the recharge basins began 2 months after the second repeat gravity survey, and 5.5 months after recharge began. Unsaturated-zone flow modeling was carried out using software that simulates water movement and parameter estimation. Model calibration was carried out by minimizing an objective function calculated from the differences between simulated and observed groundwater levels, and between simulated and observed repeat microgravity data. Including repeat microgravity data in the objective function reduced the uncertainty in estimated parameter values for saturated hydraulic conductivity and saturated water content. Modeling indicated that the unsaturated zone between the recharge basins and the water table does not become saturated even after 685 days of simulated infiltration. This gradual wetting may account for increasing infiltration rates over time, as hydraulic conductivity increases with increasing water content. Unsaturated-zone water content decreased rapidly between recharge cycles. Model-simulated groundwater mounding extended about 1 kilometer from the center of SHARP after the 685-day period following the onset of recharge.

Arizona

Measuring stress In high pressure deformation experiments with high speed fiber-optics

High‐pressure, high‐temperature rock deformation experiments are essential for understanding deep Earth processes, but accurately measuring stress is challenging due to the inaccuracy introduced by seal friction within the apparatus and large inertia, which affects earthquake process measurements made far from the experimental fault. To overcome these limitations, we developed and implemented a simple, compact fiber‐optic sensor based on an External Cavity Fabry–Perot Interferometer for in situ load measurement on a piston inside the pressure vessel of a Griggs‐type high‐pressure apparatus. The sensor can be used at sample temperatures up to 800°C for both slow creep and fast rupture testing with bandwidth capability from DC to 6 MHz. Two important experimental results are described: (1) the first direct measurements of seal friction in this apparatus type; these measurements record seal friction approximately one‐tenth of the confining pressure under both low (150 MPa) and high (1 GPa) pressure conditions; and (2) high‐temporal resolution capture of dynamic stress drops during stick‐slip faulting events at high‐confining pressure, revealing near‐fault wave propagation details, high‐frequency oscillations, and implying high‐transient slip rates (6–12 m/s) previously inaccessible with external sensors.

The Seismic Record

False positives in the identification of dynamic earthquake triggering

Dynamic earthquake triggering is commonly identified through the temporal correlation between increased seismicity rates and global earthquakes that are possible triggering events. However, correlation does not imply causation. False positives may occur when unrelated seismicity rate changes coincidently occur at around the time of candidate triggers. We investigate the expected false positive rate in Southern California with global M ≥ 6 earthquakes as candidate triggers. We compute the false positive rate by applying the statistical tests used by DeSalvio and Fan (2023), https://doi.org/10.1029/2023jb026487 to synthetic earthquake catalogs with no real dynamic triggering. We find a false positive rate of ∼3.5%–8.5% when realistic earthquake clustering is present, consistent with the 95% confidence typically used in seismology. However, when this false positive rate is applied to the tens of thousands of spatial-temporal windows in Southern California tested in DeSalvio and Fan (2023), https://doi.org/10.1029/2023jb026487 , thousands of false positives are expected. The expected false positive occurrence is large enough to explain the observed apparent triggering following 70% of large global earthquakes (DeSalvio & Fan, 2023, https://doi.org/10.1029/2023jb026487 ), without requiring any true dynamic triggering. Aside from the known triggering from the nearby El Mayor-Cucapah, Mexico, earthquake, the spatial and temporal characteristics of the reported triggering are indistinguishable from random false positives. This implies that best practice for dynamic triggering studies that depend on temporal correlation is to estimate the false positive rate and investigate whether the observed apparent triggering is distinguishable from the correlations that may occur by chance.

JGR Solid Earth

Evaluating the potential of co-located non-petroleum energy resources in the Gulf Coast using play fairwayaAnalysis

Geological resources critical to the energy transition, such as sedimentary geothermal, carbon storage potential, and lithium in brines, commonly struggle for economic feasibility as stand-alone developments but can have greater viability when the potential for more than one of these resources exist within the same reservoir or stacked in different stratigraphic intervals. There may also be instances where development of one resource inhibits development of others and decisions need to be made on how to best prioritize the use of those resources in the subsurface. Subsurface data sets were analyzed and integrated to evaluate the distribution of non-petroleum energy and related resources in the onshore and nearshore U.S. Gulf Coast. Temperature, pressure, brine composition (lithium content), and reservoir quality data for thirty-four depositional units have been compiled and visualized to high-grade areas where multiple resource opportunities likely coexist. For sedimentary geothermal, possible resource areas are defined as low potential (<90°C), moderate potential (90–150°C), and high potential (>150°C). For CO 2 storage, high potential areas exhibit supercritical CO 2 conditions less than 80% of the fracture gradient. Areas with pore pressure between 80% and 100% of the fracture gradient are considered to exhibit moderate potential and areas where the fracture gradient is equal to or greater than 100% are assigned low potential. Lithium resources in brines were defined by lithium concentrations as low potential (<100ppm), moderate potential (100-200ppm), or high potential (>200ppm). Reservoir quality affects the viability of all three of these resources and is evaluated using depositional environment maps of each unit. The resulting play fairway maps can be used for regional scale screening evaluations of these resources and to identify areas of interest where more detailed, prospect-scale studies can be undertaken.

Gulf Coast

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Scoping decision-maker needs and science availability to support regional natural capital accounting in the U.S. Colorado River Basin

Natural capital accounting has the potential to yield important policy insights at multiple scales, but there remains a disconnect between regional-scale natural capital accounts and their use for informing policy. In this paper, we propose a roadmap that could lead to the creation of policy-relevant regional accounts, with steps split across an initial scoping phase and a subsequent development phase. We demonstrate the scoping steps in action with an application to the Colorado River Basin (“Basin”), a large watershed in the southwestern United States (U.S.) that has faced aridification and substantial high-profile tradeoffs around the use of its water and other natural resources. Drawing on prior U.S. Geological Survey science co-production efforts, we conducted a series of eight discussion sessions with 41 scientists and science representatives whose work is relevant to Basin water, riparian and riverine ecosystems, upland ecosystems and energy and minerals. We summarise participants' thoughts on key topics and economic linkages, their insights and questions of interest and their recommendations on existing scientific data sources and gaps. We evaluate the suitability of the available data for construction of System of Environmental-Economic Accounting (SEEA) Central Framework and SEEA Ecosystem Accounting accounts, including those for land, water, forests, energy and minerals and ecosystems (covering extent, condition and ecosystem services). We present a series of lessons learned during the scoping phase, as well as lessons that could be relevant for future practitioners engaging in the development phase. The information can help guide the development of timely and relevant regional-scale environmental-economic accounts in the U.S. and beyond.

Arizona, California, Colorado, Nevada, New Mexico,

Non-destructive sampling of larval amphibians shows tail tissues reflect whole-body methylmercury concentrations and trophic-related differences in bioaccumulation

Mercury (Hg), and specifically methylmercury (MeHg), is a contaminant of global concern to humans and wildlife, but there is still limited understanding of its effects on many taxa. Amphibians are closely associated with water, where Hg is converted to MeHg, and high concentrations of MeHg can reduce survival of amphibians in the wild. However, limited non-lethal proxies exist for estimating MeHg bioaccumulation in amphibian larvae, which could be used to reduce destructive sampling and allow sampling of imperiled species. We evaluated whether tail clips were indicative of whole-body MeHg concentrations of larval amphibians, whether dragonflies were an effective bioindicator of Hg concentrations of larval amphibians, and compared MeHg bioaccumulation in predatory caudate (salamanders, newts) and non-predatory anuran (frogs, toads) larvae. Tail-clip and whole-body MeHg concentrations were strongly correlated, especially for caudates. There was high variability among sites and species, but caudates had higher MeHg than anurans, and MeHg concentrations of caudates and anurans were strongly correlated. Dragonflies were a weak indicator of MeHg for anurans but strong indicators for larval caudates, likely because caudates and dragonflies are carnivorous and occupy similar trophic positions. Our study revealed that sampling tails can be an effective non-destructive index of whole-body MeHg for larval amphibians and demonstrates differences in MeHg bioaccumulation related to trophic position in larval amphibians and dragonflies. All post-embryo life stages for a broad suite of amphibian species can now be sampled non-lethally for MeHg, allowing for a broader examination of population-level effects and focus on imperiled species that cannot be sampled destructively.

conterminous United States

Use of a numerical groundwater-flow model and projected climate scenarios to simulate the effects of future climate conditions on base flow for reach 1 of the Washita River alluvial aquifer and Foss Reservoir storage, western Oklahoma

To better understand the relation between climate variability and future groundwater resources in reach 1 of the Washita River alluvial aquifer and Foss Reservoir in western Oklahoma, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used a previously published numerical groundwater-flow model and climate-model data to investigate changes in base flow and reservoir storage by evaluating three scenarios. The three projected climate scenarios were (1) a central-tendency scenario, (2) a warmer/drier scenario, and (3) a less-warm/wetter scenario. To estimate future base flow and groundwater availability in western Oklahoma, specifically in reach 1 of the Washita River alluvial aquifer, downscaled climate-model data from 231 Coupled Model Intercomparison Project phase 5 (CMIP5) projections coupled with a previously published numerical groundwater-flow model were used to compare the effects of different climate scenarios on the aquifer. Changes in base flow and groundwater-level elevations during a 30-year baseline scenario (1985–2014) and the three 30-year projected climate scenarios (2050–79) under central-tendency, warmer/drier, and less-warm/wetter climatic conditions were assessed by using the calibrated model. In the simulations, the amount of base flow and reservoir storage declined in the central-tendency and warmer/drier scenarios compared to the amount of base flow and reservoir storage under historical climatic conditions (baseline scenario). Mean annual change in reservoir storage decreased from the baseline scenario the most in the warmer/drier scenario, followed by the central-tendency scenario, but increased in the less-warm/wetter scenario compared to the baseline scenario. At the end of the simulation period (2079), the largest magnitude differences in groundwater-level elevations in all three projected climate scenarios relative to the baseline scenario occurred upstream from Foss Reservoir. Results from incorporating downscaled climate projections into localized numerical groundwater-flow models can highlight potential future changes in and implications for groundwater resources and availability.

Oklahoma

Mapping the resistivity structure of Walker Ridge 313 in the Gulf of Mexico using the marine CSEM method

A marine controlled source electromagnetic (CSEM) campaign was carried out in the Gulf of Mexico to further develop marine electromagnetic techniques in order to aid the detection and mapping of gas hydrate deposits. Marine CSEM methods are used to obtain an electrical resistivity structure of the subsurface which can indicate the type of substance filling the pore space, such as gas hydrates which are more resistive. Results from the Walker Ridge 313 study (WR 313) are presented in this paper and compared with the Gulf of Mexico Gas Hydrate Joint Industry Project II (JIP2) logging while drilling (LWD) results and available seismic data. The hydrate, known to exist within sheeted sand deposits, is mapped as a resistive region in the two dimensional (2D) CSEM inversion models. This is consistent with the JIP2 LWD resistivity results. CSEM inversions that use seismic horizons provide more realistic results compared to the unconstrained inversions by providing sharp boundaries and architectural control on the location of the resistive and conductive regions in the CSEM model. The seismic horizons include: 1) the base of the gas hydrate stability zone (BGHSZ), 2) the top of salt, and 3) the top and bottom of a fine grained marine mud interval with near vertical hydrate filled fractures, to constrain the CSEM inversion model. The top of salt provides improved location for brines, water saturated salt, and resistive salt. Inversions of the CSEM data map the occurrence of a ‘halo’ of conductive brines above salt. The use of the BGHSZ as a constraint on the inversion helps distinguish between free gas and gas hydrate as well as gas hydrate and water saturated sediments.

Louisiana

Earthquake magnitude and source parameter estimation with a distributed acoustic sensing dataset in the Gorda subduction zone

Distributed acoustic sensing (DAS) systems offer a cost‐effective way to create large‐scale strainmeter arrays for seismological applications using fiber‐optic cables. DAS‐based strain measurements are known to be influenced by various factors, bringing into question their general reliability for accurate earthquake characterization. A 15‐km‐long DAS deployment in northern California was operational within 3 days of the 2022 M w 6.4 Ferndale earthquake and ran continuously throughout the aftershock sequence. We utilize these aftershock data to validate DAS‐based strain measurements in two ways. We first test the accuracy of DAS‐based magnitude estimates from peak dynamic strains by comparing them with magnitude and attenuation scaling relations derived independently from traditional borehole strainmeter (BSM) data. We demonstrate that DAS‐based magnitudes are comparable to BSM‐based magnitudes when corrections for variations in site response along the fiber‐optic cable are properly made. Magnitude errors are spatially correlated, potentially because of factors such as finite‐fault effects (e.g., stress drop) or more complex, unmodeled path attenuation or because of wave propagation effects in heterogeneous media. We then apply more advanced source characterization methodology to the DAS data using a time‐domain empirical Green’s function (EGF) deconvolution approach to measure details of the moment rate history. The EGF approach using DAS data depends on careful treatment of distorting factors such as anthropogenic sources of noise and optical phase wrapping but successfully isolates source spectra for moderate‐magnitude earthquakes: source spectral ratios obtained from DAS data, broadband seismometer data, and BSM data in the same region show consistent results, revealing differences in directivity and spectral shape among earthquakes. Although further research is needed to refine source‐time‐function estimation techniques for DAS data, particularly for larger magnitude events, these case studies demonstrate the clear potential of DAS for earthquake source characterization.

California