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At least 775 records · Page 43Linked to original sources
USGS2001

A metallogenic survey of alkalic rocks of Mt. Somma-Vesuvius volcano

Somma-Vesuvius is an alkaline volcano whose products (pumice, scoria and lava) have alkaline (Na2O+K2O) contents between 6 and 16 wt%, Mg number <50, SiO2 59-47 wt% and MgO 0-7.8 wt% (more than 50% of the samples have a content <2 wt%). Immobile-element ratios (Th/Yb, Ta/Yb, Ce/Yb) indicate a shoshonitic character, while the K2O content (4-10 wt%) is characteristic of ultrapotassic rocks. The behavior of selected metals is discussed by grouping them on the basis of the stratigraphic sequence and differentiating the volcanic activity between plinian and interplinian (Rolandi et al., 1998; Ayuso et al., 1998). This allows observation of the variation within each formation from 25.000y. BP to the last historic eruptive cycle (1631-1944 AD). The main processes to explain the wide distribution of the data presented are fractional crystallization of a mantle-derived magma, magma mixing, and contamination with heterogeneous lower and/or upper crust. Variation diagrams distinguish different behavior for groups of metals: Ag (0.01-0.2 ppm), Mo (1-8.8 ppm), W (1.3-13 ppm), Pb (16-250 ppm), Sb (0.2-2.6 ppm), Sc (0.2-61 ppm), Li (15-140 ppm) and Be (1-31 ppm) increase with increasing differentiation and tend to correlate with the incompatible trace elements (Th, Hf, etc). Cu (10-380 ppm), Au (2-143 ppb), Co (0.7-35.1 ppm) and Fe (1.3-6.2 wt%) decrease towards advanced stage of differentiation. Iron also identifies three magmatic groups. The ratio Fe3+/Fe2+ ranges between 0.2 and 1.8, and Fe2O3/ (Fe2O3+FeO) ranges between 0.2 and 0.8, giving rise to an oxidized environment; exceptions are in the samples belonging to the interplinian formations: I, II, medieval and 1631-1994 AD. Fluorine ranges between 0.1 and 0.4 wt% for the complete Mt. Somma-Vesuvius activity, except for the Ottaviano and Avellino plinian (0.8 wt%) events. Chlorine has a wider range, from 0.1 wt% to 1.6 wt%. Mt Somma-Vesuvius has some features similar to those of mineralized alkaline magmatic systems which coincide with the transition between subduction-related compression and extension-related to continental rifting. We infer that a prospective time for the formation of mineralization at Mt Somma-Vesuvius was during the 1631-1944 eruptive period.

Mineralogy and Petrology↗
USGS1995

Sources of the Early Cretaceous plutons in the Turtle and West Riverside Mountains, California

Ages and initial isotopic ratios of Early Cretaceous (˜100 Ma) plutons of the Cordilleran Interior in the southern Turtle and West Riverside mountains distinguish them from Late Cretaceous plutons in surrounding ranges in the eastern Mojave Desert. Furthermore, the studied plutons have isotopic and geochemical characteristics more similar to plutons of Cretaceous age in the coastal batholiths (Peninsular Ranges and Sierra Nevada) than to most Mesozoic plutons in the Cordilleran Interior. The studied plutons are calcic, in contrast to the mostly cak-alkaline Mesozoic plutons of the eastern Mojave Desert. Distinctive isotopic signatures of the granitoids include lower initial 87 Sr/ 86 Sr of 0⋅705–0⋅710, δ 18 O of +6⋅3 to +7⋅7‰, 208 Pb/ 204 Pb of 38⋅3–39⋅5, and higher ε Nd of −3⋅86 to −9⋅60 than the Late Cretaceous plutons in the region. The distinctive characteristics of these Early Cretaceous plutons are probably both location and time specific and result from: (1) emplacement in a cold, untapped ‘Mojave-type’ Proterozoic upper crust, (2) a significant component of basaltic magmas partially melted from the asthenosphere or subcontinental lithosphere and (3) a magmatic component derived from Proterozoic, mafic, lower crust. They interacted less with their crustal hosts than did the later, more voluminous Late Cretaceous plutons.

California↗
USGS1997

Comagmatic A-type granophyre and rhyolite from the Alid volcanic center, eritrea, northeast Africa

Granophyric blocks within late-Pleistocene pyroclastic flow ejecta from the Alid volcanic center, northeast Africa, are the rapidly crystallized, intrusive equivalent of pumice from the pyroclastic flow. Phenocryst compositions and geochemical characteristics of the pumice and granophyre are virtually identical. Silicate melt inclusions and other geochemical and geological constraints reveal those processes leading to development of the granophyric texture. Rhyolitic (A-type) magma with ∼2.6 wt % dissolved H 2 O and a temperature near 870°C was intruded to within 2–4 km of the surface, causing deformation and structural doming of shallow marine and subaerial strata. Eruptions of crystal-poor rhyolite from this shallow magma chamber caused degassing, which forced undercooling and consequent granophyric crystallization of some of the magma remaining in the intrusion. The most recent eruption from Alid excavated the crystallized granitic wall of the magma chamber, bringing the granophyric clasts to the surface.

Journal of Petrology↗
USGS1998

Petrochemistry of late miocene peraluminous silicic volcanic rocks from the Morococala field, Bolivia

Late Miocene peraluminous volcanic rocks of the Morococala field, Bolivia, define a layered stratigraphy of basal andalusite-, biotite- (± muscovite)-bearing rhyolite tuffs (AR), overlain by cordierite-, biotite-bearing rhyolite tuffs (CR), and capped by biotite-bearing quartz latite tuffs, lavas, and late domal flows (QL). Mineral and whole-rock compositions become more evolved from top to bottom, with differentiation reflected by decreasing Ca, Ba, Mg, Fe, and rare earth elements (REE) versus increasing F, Na/K, and aluminosity from QL to AR. Mineral, whole-rock, and glass inclusion compositions are consistent with derivation of all three rock types from a single stratified magma reservoir, but age and spatial relations between the three units make this unlikely. Genesis of the QL involved biotite-dehydration melting of an aluminous source at T > 750°C and P ≥ = 4–6 kbar. If not co-magmatic with QL, the other units were generated primarily by muscovite-dehydration melting at T = 730–750°C and P ≥ = 3.5–4.5 kbar for CR, and T ≤ = 750°C for AR with pre-eruptive residence at low pressure (1.5–3.0 kbar). Low hematite contents (X Hem ≤ = 0.06) of ilmenite grains in AR, CR, and early grains (as inclusions in plagioclase and sanidine cores) in QL indicate reduced conditions imposed by a graphite-bearing source. Compositional variability among texturally later oxides (ilmenite with X Hem = 0.06–0.50, primary magnetite), however, apparently records progressive increases in pre-eruptive f(O 2 ) in QL. Plagioclase-melt equilibria and electron microprobe analysis difference for quartz-hosted glass inclusions suggest pre-eruptive melt H 2 O contents ≥ = 5–7 wt % for the AR, ∼4–6 wt % for the CR, and ∼3–5 wt % for the QL.

Journal of Petrology↗
USGS1998

The petrogenesis of felsic calc-alkaline magmas from the southernmost Cascades, California: Origin by partial melting of basaltic lower crust

The majority of felsic rocks from composite centers in the southernmost Cascades have geochemical and Sr, Nd and Pb isotopic ratios that suggest derivation by partial melting of lower crust that is compositionally similar to calc-alkaline basalts observed in the region. Only a few felsic rocks have δ 18 O and Pb isotopic compositions that indicate interaction with the upper crust. Mineralogical and geochemical differences among the felsic magmas result primarily from melting under variable f (H 2 O) and temperature conditions. Partial melting under low f (H 2 O) and high temperature conditions leaves an amphibole-poor residuum, and produces magmas that have orthopyroxene as the most abundant ferromagnesian phenocryst, relatively low silica contents, and straight rare earth element patterns. Partial melting under higher f (H 2 O) and lower temperature conditions leaves an amphibole-rich residuum, and produces magmas that have amphibole ± biotite phenocrysts, relatively high silica contents, and pronounced middle rare earth element depletions. These conclusions are consistent with published thermal models that suggest that reasonable volumes of basaltic magma emplaced beneath large composite centers in the southernmost Cascades can serve as the heat source for melting of the lower crust. Melting of the lower crust under variable f (H 2 O) conditions is likely to result from differences in the H 2 O contents of these basaltic magmas.

Journal of Petrology↗
USGS1999

A complex magma mixing origin for rocks erupted in 1915, Lassen Peak, California

The eruption of Lassen Peak in May 1915 produced four volcanic rock types within 3 days, and in the following order: (1) hybrid black dacite lava containing (2) undercooled andesitic inclusions, (3) compositionally banded pumice with dark andesite and light dacite bands, and (4) unbanded light dacite. All types represent stages of a complex mixing process between basaltic andesite and dacite that was interrupted by the eruption. They contain disequilibrium phenocryst assemblages characterized by the coexistence of magnesian olivine and quartz and by reacted and unreacted phenocrysts derived from the dacite. The petrography and crystal chemistry of the phenocrysts and the variation in rock compositions indicate that basaltic andesite intruded dacite magma and partially hybridized with it. Phenocrysts from the dacite magma were reacted. Cooling, crystallization, and vesiculation of the hybrid andesite magma converted it to a layer of mafic foam. The decreased density of the andesite magma destabilized and disrupted the foam. Blobs of foam rose into and were further cooled by the overlying dacite magma, forming the andesitic inclusions. Disaggregation of andesitic inclusions in the host dacite produced the black dacite and light dacite magmas. Formation of foam was a dynamic process. Removal of foam propagated the foam layer downward into the hybrid andesite magma. Eventually the thermal and compositional contrasts between the hybrid andesite and black dacite magmas were reduced. Then, they mixed directly, forming the dark andesite magma. About 40–50% andesitic inclusions were disaggregated into the host dacite to produce the hybrid black dacite. Thus, disaggregation of inclusions into small fragments and individual crystals can be an efficient magma-mixing process. Disaggregation of undercooled inclusions carrying reacted host-magma phenocrysts produces coexisting reacted and unreacted phenocryst populations.

Journal of Petrology↗
USGS1999

Magmatic interactions as recorded in plagioclase phenocrysts of Chaos Crags, Lassen Volcanic Center, California

The silicic lava domes of Chaos Crags in Lassen Volcanic National Park contain a suite of variably quenched, hybrid basaltic andesite magmatic inclusions. The inclusions represent thorough mixing between rhyodacite and basalt recharge liquids accompanied by some mechanical disaggregation of the inclusions resulting in crystals mixing into the rhyodacite host preserved by quenching on dome emplacement. 87Sr/86Sr ratios (~0.7037-0.7038) of the inclusions are distinctly lower than those of the host rhyodacite (~0.704-0.7041), which are used to fingerprint the origin of mineral components and to monitor the mixing and mingling process. Chemical, isotopic, and textural characteristics indicate that the inclusions are hybrid magmas formed from the mixing and undercooling of recharge basaltic magma with rhyodacitic magma. All the host magma phenocrysts (biotite, plagioclase, hornblende and quartz crystals) also occur in the inclusions, where they are rimmed by reaction products. Compositional and strontium isotopic data from cores of unresorbed plagioclase crystals in the host rhyodacite, partially resorbed plagioclase crystals enclosed within basaltic andesite inclusions, and partially resorbed plagioclase crystals in the rhyodacitic host are all similar. Rim 87Sr/86Sr ratios of the partially resorbed plagioclase crystals in both inclusions and host are lower and close to those of the whole-rock hybrid basaltic andesite values. This observation indicates that some crystals originally crystallized in the silicic host, were partially resorbed and subsequently overgrown in the hybrid basaltic andesite magma, and then some of these partially resorbed plagioclase crystals were recycled back into the host rhyodacite. Textural evidence, in the form of sieve zones and major dissolution boundaries of the resorbed plagioclase crystals, indicates immersion of crystals into a hotter, more calcic magma. The occurrence of partially resorbed plagioclase together with plagioclase microlites and olivine crystals reflects disaggregation of inclusions and mingling of this material into the silicic host. These processes are commonplace in some orogenic magma systems and may be elucidated by isotopic microsampling and analysis of the plagioclases crystallizing from them.

Journal of Petrology↗
USGS1969

Coexisting amphiboles from blueschist facies metamorphic rocks

Four pairs of associated calcic and sodic amphiboles from blueschist facies metamorphic rocks were analyzed with the electron microprobe and studied by single-crystal X-ray diffraction techniques. Except for ranges in the ratios Mg/(Mg+Fe) and Fe 3+ /(Fe 3+ +Al+Ti), the sodic amphiboles are similar in chemical composition. The amount of calcium in the M(4)-site ranges only from 0·18 to 0·21 ion per formula unit. The calcic amphiboles, in addition to a range in Mg/(Mg+Fe), vary in Na/(Na+Ca) ratio (0·29–0·48). Three of the calcic amphiboles contain less than 1·5 calcium ions per formula unit, indicating a significant solid solution of sodic amphibole components in the calcic amphibole phase. The a and b unit-cell parameters of the calcic amphiboles decrease with increased content of the sodic component.

Journal of Petrology↗
USGS1969

Biotites from granitic rocks of the central Sierra Nevada batholith, California

Biotites from plutonic rocks of the central Sierra Nevada and Inyo Mountains, California, have been examined and characterized by powder X-ray diffraction and optical and chemical methods. Compositions of the biotites define a trend in the compositional triangle Fe+3 Fe+2Mg. When related to the experimentally studied ternary system KFe 3 +3AlSisO 12 H- 1 -KFe 3 +2 AlSi 3 O 10 (OH) 2 -KMg 3 AlSi 3 O 10 (OH) 2 and coupled with the estimated positions of biotite solid solutions for different oxygen buffers, the trend suggests that oxygen fugacities in magmas during biotite crystallization were slightly higher than those defined by the Ni-NiO buffer. The compositional data also suggest that magmas were ‘buffered’ with respect to oxygen by oxides existing within the magmas themselves. Correlation between the Fe/(Fe+Mg) ratio, an inferred temperature indicator, and other elements is generally poor, which suggests that factors other than temperature at the time of crystallization exerted an important influence on compositions.

California↗
USGS1969

Minor-element and revised major-element contents of some Mediterranean pantellerites and comendites

Optical emission spectrographic analysis of three pantellerites from Pantelleria and two comendites from Sardinia show high concentrations of B, Be, Ga, La, Mo, Nb, Sn, Y, Yb, and Zt and low contents of Ba, Co, Cr, Ni, Sr, and V. Minor-element trends of these specimens are very similar to those of pantellerites from southern Nevada and New Zealand and other peralkaline silicic rocks from various localities. Fluorine contents of the Pantellerian specimens range from 0.19 to 0.32 per cent by weight resulting in abnormally high Cl to F ratios. New analyses for MgO, Na 2 O, and K 2 O are almost identical with the values obtained by Zies. Revised major-element compositions and calculated glass-phase compositions for the three Pantellerian specimens are given.

Pantelleria, Sardinia↗
USGS1969

Rheology of basalt in the melting range

Experimental data have been obtained for viscosities of tholeiite melts at temperatures from 1300 to 1120 °Cat 1 atm, using a concentric cylinder viscometer. The apparent viscosity increases more than two orders of magnitude between 1200 and 1120 °C (0–25 per cent crystallization) for shear rates of about 10 sec -1 and even more for lower shear rates. Non-Newtonian behaviour of ‘pseudo-plastic type’ becomes extremely pronounced at temperatures below about 1130 °C. At these temperatures, differences of less than 5 °C can produce changes in apparent viscosity amounting to orders of magnitude. These observations have led to the conclusion that the heat of deformation must itself influence rheological behaviour in the melting range. An equation for thermal energy balances and their rates of change is constructed and placed in a non-dimensional form that has been given published solutions by I. J. Gruntfest (1963) relating the shear stress, rate of strain, and temperature through the temperature dependence of viscosity. The results show that in an adiabatic system the heating rate increases with time so that the temperature eventually runs out of bounds, a process termed ‘thermal feedback’ by Gruntfest. A hypothesis of shear melting is derived on the basis of a simplified viscosity function extrapolated to the solidus temperature. The hypothesis is applied to magma generation in the earth on the basis of dimensional arguments. It is also suggested that thermal instabilities give rise to a sort of viscous failure responsible for deep-focus earthquakes, and that the two phenomena have the same cause relating ultimately to a gravitational energy source.

Journal of Petrology↗
USGSDate not supplied

Xenoliths in the honolulu volcanic series, Hawaii

The Pleistocene to Holocene Honolulu Volcanic Series was erupted from about 37 vents scattered over the older Koolau tholeiite shield. The rocks of this series are compositionally zoned with respect to the shield; near the Koolau caldera the predominant rocks are melilitenepheline basalts, but these give way outward to nepheline basalts, and ultimately, at the apron of the shield, to alkalic olivine basalts. The xenoliths in these are likewise zoned: most of those in the caldera area consist of dunite, most of those at intermediate distances of lherzolite, and some of those in the apron of the shield consist of garnet pyroxenite and peridotite. The zoning of the xenoliths, however, does not coincide with that of the enclosing rocks. We believe that copious eruption of Koolau tholeiite produced a lateral and vertical heterogeneity in the mantle beneath Oahu, and that the zoning in both Honolulu lavas and their xenoliths is caused by that heterogeneity. The textures of the xenoliths indicate that the basalts were mainly produced by fractional melting rather than fractional crystallization. There is some evidence that the dunite xenoliths are mantle residua produced during the generation of the tholeiite, and that the Honolulu magmas were generated at greater depths than the Koolau magmas, probably as a result of elastic unloading. © 1970 Oxford University Press.

Hawaii↗
USGS1971

Origin of the differentiated and hybrid lavas of Kilauea Volcano, Hawaii

Kilauea Volcano has erupted lava from its summit caldera and from two rift zones that extend from the summit towards the east and south-west. Lavas erupted from the summit of the volcano differ from each other principally in their content of olivine and define lines of ‘olivine control’ on magnesia variation diagrams. Lavas erupted on the rift zones may be similar in composition to the summit lavas or may be differentiated by processes that involve minerals other than olivine. All of the differentiated lavas have less than 6·8 per cent MgO and plot off the extension of olivine control lines for the summit lavas. Prehistoric vents (before A.D. 1750) from which differentiated lavas have been erupted are found on the east rift zone and in the western Koae fault zone adjacent to the south-west rift zone; historic vents for differentiated lavas are confined to the east rift zone. Twenty-one new analyses are presented for several of the east rift differentiates and for the newly discovered differentiates adjacent to the south-west rift zone. The differentiates have MgO as low as 3·9 per cent and SiO 2 as high as 56 per cent; both extremes are found in the prehistoric lavas adjacent to the south-west rift. Detailed petrochemical studies suggest the following conclusions: The chemical composition of magma erupted at Kilauea summit varies with the date of eruption. Lavas erupted before 1750, during the eighteenth and nineteenth centuries, and in the twentieth century form groups that can be distinguished chemically. On a lesser scale, each Kilauea summit eruption in the twentieth century has a chemistry that is distinctive with respect to the chemistry of every other summit eruption. During late prehistoric time pockets of differentiated magma were formed within the rift zones by separation of the liquid remaining after partial crystallization of bodies of summit magma. This process presumably is still going on within the east rift zone, but the more recently separated liquids have not yet been erupted to the surface. The relative time at which these differentiated magmas were produced can be estimated from calculations based on their chemical compositions, which show that the differentiates could lie on the liquid line of descent for Kilauea summit magma of prehistoric composition but not on any liquid line of descent for younger summit magmas. Lava from some eruptions, notably the early part of the 1955 eruption on the lower east rift, has the composition of the liquid fraction as it is generated within the rift. Lava compositions of other eruptions, including those of the later lavas of 1955, are best explained by mixing of magma supplied from a central reservoir beneath Kilauea summit with the differentiated liquid in the rift. Lava from each summit eruption is unique chemically, so it is possible to recognize its presence or absence as components of mixing in such mixed lavas. It appears that summit magma of composition characteristic of the 1952 and 1961 Halemaumau eruptions contributed to the composition of the mixed lavas produced in the latter part of the 1955 eruption. Summit magma of 1961 composition is alone sufficient to explain the composition of mixed lavas erupted in 1960 and 1961. In rift lavas erupted from 1962 to 1965, the composition of lava erupted in Halemaumau in 1967, in addition to the 1961 composition, is a component of mixing, and it is the dominant summit component in the composition of the two 1965 eruptions. The proportion of summit magma to differentiated magma needed to explain the composition of lavas erupted on the upper east rift increases from 1961 to 1965; this increase indicates that the differentiated magma was being diluted and used up by repeated flooding of this part of the rift zone by magma supplied from the central reservoir. The fact that components of ‘summit composition’ appear in rift eruptions before they appear undiluted in Halemaumau suggests that the central reservoir is vertically zoned. Rift eruptions are fed from lower levels where younger magma is available, and summit eruptions are fed from the relatively older magma above. The chemical distinction between lava of successive summit eruptions implies that significant convective mixing of magma does not take place throughout the central reservoir. The unique and uniform composition of lava of each successive summit eruption also suggests that summit eruptions end when all of the magma of one composition has been erupted. The magma erupted from the upper levels of the reservoir during one cycle is continually replaced from below by younger magma of different composition. In order for eruption to be renewed in Halemaumau, new magma from the mantle must be held in storage at intermediate levels before it attains an ‘eruptive state’. The hypothesis presented in 2–4 above permits qualitative predictions concerning future lava compositions. The composition of the next lava to be erupted in Halemaumau is expected to be distinct from that of the 1967 eruption, and this composition will presumably be identified in rift eruptions occurring between 1967 and the time of its appearance in Halemaumau. Differentiates of prehistoric age also were apparently formed in the same way as those of historic age, but the mixing cannot be described quantitatively because of poor control on the stratigraphy and the compositions of erupted lavas. One lava in the Koae group, that from Yellow Cone, appears to be a mixture of a picritic magma (12 per cent MgO) with a differentiated liquid with less than 2·5 per cent MgO and nearly 60 per cent SiO 2 .

Hawaii↗
USGS1971

A chemical study of serpentinization — Burro Mountain, California

Serpentinized dunites and harzburgites from the Burro Mountain peridotite show no change in the ratio of iron and magnesia to silica when compared with the same ratio for the unserpentinized equivalents. The mineral assemblage resulting from serpentinization consists of lizardite-chrysotile, brucite, and magnetite and is determined by the original bulk composition of the peridotite. The chemical and mineralogical data indicate that serpentinization proceeded under isochemical conditions except for the introduction of water into the peridotite. Expansion accompanies serpentinization because the serpentine products occupy a greater volume than the peridotite protolith. Tectonic emplacement of the Burro Mountain peridotite was facilitated by serpentinization and the attendant expansion.

California↗
USGS1971

Origin and emplacement of the ultramafic rocks of the Emigrant Gap area, California

The ultramafic bodies of the Emigrant Gap area are part of a mafic complex within a large composite pluton of the northern Sierra Nevada. The pluton was magmatically emplaced and is surrounded by an aureole of hornblende-hornfels facies rocks. Inclusions of country rock in ultramafic rock are of pyroxene-hornfels facies and appear to have been partly melted. Gravity studies indicate that the ultramafic bodies have near-vertical contacts extending to depths of at least 1½ to 2½ km. The mafic complex shows rough concentric zoning of rock types: ultramafic bodies occur at the core; gabbro forms a discontinuous intermediate unit; and diorite, tonalite, and granodiorite occur at the margins. Within the ultramafic bodies, unserpentinized wehrlitic peridotite is dominant; dunite and olivine clinopyroxenite are present but greatly subordinate. The ultramafic rocks consist almost entirely of olivine (FO 80 ) and diopside (Ca 46 Mg 46 Fe 8 ); orthopyroxene, hornbolende, and plagioclase occur locally. The gabbro, diorite, tonalite, and granodiorite contain both ortho- and clinopyroxene. Both ultramafic and two-pyroxene-bearing rocks were emplaced nearly simultaneously, as partly crystallized magmas and magmatic crystal mushes that had similar temperature. In all the rocks the structures are dominantly magmatic and were produced by sorting and orientation of crystals by magmatic flow. Structures produced by post-consolidation deformation and replacement are minor and local. The structural and chemical relations within the mafic complex suggest that all the rocks are derived from a single gabbroic magma by crystal fractionation, with the ultramafic rocks formed by mechanical accumulation of early crystallized mafic minerals, and the two pyroxene-bearing granodiorite crystallized from a felsic differentiate. It is likely that flowage differentiation was the dominant process of crystal segregation. The Emigrant Gap mafic complex is similar in structure, rock texture, and mineralogy to zoned ultramafic complexes, such as those of south-eastern Alaska, and is very different from either stratiform or alpine-type bodies. Though unlike the Alaskan bodies in detail, it appears that this complex should be classed with the zoned complexes in any broad grouping of ultramafic occurrences.

California↗
USGS1973

Phase relations of basalts in their melting range at PH2O = 5 kb as a function of oxygen fugacity: Part I. Mafic phases

The phase relations of three basalts, the Picture Gorge tholeiite, the 1921 Kilauea olivine tholeiite, and the 1801 Hualalai alkali basalt, were studied at 5 kb water pressure, 680–1000°C, at the oxygen fugacities of the quartz-fayalite-magnetite (QFM) and hematite-magnetite (HM) buffers. In the range 680–850 °C, the crystalline assemblage on the QFM buffer is dominantly hornblende+ plagioclase, ± ilmenite, magnetite, sphene, fayalitic olivine, and phlogopitic mica. From 875 to 1000 °C the crystalline assemblage is hornblende+ olivine± augite+ ilmenite± magnetite. A melt phase is present from 700 to 1000 °C; a vapor phase was present in all charges. The hornblendes formed on the QFM buffer range in composition from common green hornblendes at low temperatures to kaersutitic hornblendes at 1000 °C. A1(IV) and Ti increase temperature. AI(VI) passes through a maximum near 825 °C, decreasing both above and below this temperature. AI(IV) is proportional to the sum A1(VI)+2Ti. There is a positive linear correlation of approximately 3 : 1 between AI(IV) and the number of cations in the A-site. The most likely explanation for this correlation at present is that the substitution of AI(VI) or Ti +4 for a divalent cation creates local charge imbalances in the amphibole structure which can be compensated only by further A-site substitution. There also appears to be a correlation between the a-cell dimension of hornblende and the A-site occupancy. Above a thresh hold value of approxmately 0.5 cations in A, a increases as A-site occupancy increases. Phase relations on the hematite-magnetite buffer are considerably simpler. The hornblendes show relatively little change in composition as temperature increases, and in the tholelitic compositions break down at or below 970 °C 35–60 °C above the first appearance of augite±olivine. The melting of hornblende is incongruent in all cases. The Fe-Ti oxides are pseudo-brookite and titanohematite; at 1000 °C these oxides make up 10 per cent by weight of the assemblage and contain most of the Tio 2 and FeO in the charge. The patterns of hornblende variation observed in this study compare closely with those reported in a wide range of experimental and field data. The appearance of high-TiO 2 kaersutitic hornblendes in the tholeities at 1000° C, P H2O = 5 kb on the QFM buffer implies that the restricted occurence of kaersutite in nature (where it is associated only with mafic to intermediate alkalic rocks) is controlled by volatile content (H 2 O , F 2 )rather than by differences in condensed bulk composition.

Journal of Petrology↗
USGS1973

Oxidation during magmatic differentiation, Finnmarka Complex, Oslo area, Norway: Part 2, the mafic silicates

Electron-microprobe analyses are presented for pyroxene, amphibole, and biotite from monzonite, granodiorite, and granite at Finnmarka, Norway. Compositional trends measured in biotite, present in all three rock types, and in amphibole, present in the monzonite and granodiorite, are markedly atypical and are interpreted as reflecting crystallization under progressively more oxidizing conditions. The average Fe/Fe + Mg for biotites from successively more silicic rock types changes from 0.64 → 0.35 → 0.28, and for amphiboles changes from 0.58 in the monzonite to 0.29 in the granodiorite. Analyses of selected areas within amphibole grains in the granodiorite show marked chemical variations, although single-crystal X-ray photographs are sharp and do not reveal multiple phases. On the basis of 33 such analyses, four coupled substitutions are identified as operative; the most unusual finding is the relation of 1 Ti cation to 4 Al IV cations in the unit cell. Variations within individual amphibole grains of the granodiorite resemble changes noted in evolution of amphibole composition from monzonite to granodiorite and are interpreted as reflecting progressive oxidation. Consideration of these data for the mafic silicates, data for the opaque oxides, and the extensive formation of sphene in the granodiorite, has allowed development of schematic reactions and an overall picture of magmatic environment and evolution at Finnmarka. Crystallization apparently took place at PH 2 o of 1000 bars or less and a temperature of about 700 °C. The trend of oxidation during differentiation is more extreme than any heretofore reported. Amphiboles, as well as biotites, may participate in oxidation reactions and may reflect the oxidation-reduction processes that occurred during magmatic evolution.

Oslo↗
USGS1974

Prehnite- and pumpellyite-bearing mineral assemblages, west side of the Appalachian metamorphic belt, Pennsylvania to Newfoundland

Prehnite- and/or pumpellyite-bearing meta-igneous rocks are found on the west side of the Appalachian metamorphic belt (1) near Jonestown, south-eastern Pennsylvania; (2) on Rensselaer Plateau, eastern New York; (3) near Quebec City, Quebec; and (4) at Little Port, Humber Arm, western Newfoundland. The assemblages critical to determining the conditions of metamorphism are (1) chlorite-epidote-hematite-pumpellyite-prehnite; actinolite-chlorite-hematite-pumpellyite-stilpnomelane; (2) actinolite-chlorite-epidote-stilpnomelane; chlorite-epidote-pumpellyite-stilpnomelane; chlorite-epidote-hematite-pumpellyite; (3) chlorite-epidote-hematite-pumpellyite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite; and (4) chlorite-epidote-prehnite; chlorite-prehnite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite. One pumpellyite-bearing rock from western Newfoundland shows a later vein of analcime-calcite. All the assemblages also include quartz, sphene, calcite, K-mica, and albite. Analysis of the mineral assemblages by the Schreinemakers method for the phases actinolite-chlorite-epidote-hematite-prehnite-pumpellyite-stilpnomelane shows that the different localities can be assigned different metamorphic grades. Though the detailed results of the Schreinemakers analysis depend on the assumed source of ferric iron in epidote, the major conclusions are not affected. The thermodynamic role of calcite is more problematic, but it appears that CO 2 did not behave as a boundary-value component during metamorphism. If calcite is treated as an excess phase, the Schreinemakers bundle decomposes to a net in a multisystem. Plotted on such a net, the various localities again occupy different parts signifying different metamorphic grades. The occurrence of pumpellyite-bearing assemblages on the west flank of the northern Appalachian metamorphic belt might suggest that these assemblages, contrary to the ideas of Miyashiro and of others, do not indicate high-pressure and low-temperature type of metamorphism. These assemblages, however, are compatible with an alternative interpretation as remnants of a high-pressure, low-temperature Taconic metamorphic regime, whose imprint within most of the Appalachian metamorphic belt has been obliterated by later events. Such a reconstruction is compatible with the suggestion that this zone, lying near the margin of the early Paleozoic craton, was an active subduction zone during the Taconic orogeny.

Appalachian metamorphic belt↗