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USGS2024

Biogeochemical and community ecology responses to the wetting of non-perennial streams

Transitions between dry and wet hydrologic states are the defining characteristic of non-perennial rivers and streams, which constitute the majority of the global river network. Although past work has focused on stream drying characteristics, there has been less focus on how hydrology, ecology and biogeochemistry respond and interact during stream wetting. Wetting mechanisms are highly variable and can range from dramatic floods and debris flows to gradual saturation by upwelling groundwater. This variation in wetting affects ecological and biogeochemical functions, including nutrient processing, sediment transport and the assembly of biotic communities. Here we synthesize evidence describing the hydrological mechanisms underpinning different types of wetting regimes, the associated biogeochemical and organismal responses, and the potential scientific and management implications for downstream ecosystems. This combined multidisciplinary understanding of wetting dynamics in non-perennial streams will be key to predicting and managing for the effects of climate change on non-perennial ecosystems.

Nature Water↗

USGS2024

Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment

Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.

ACS ES&T Water↗

USGS2025

Hydrogeologic characterization of the Cahuilla Valley and Terwilliger Valley Groundwater Basins, Riverside County, California

The relation between the groundwater and the amount of natural recharge to the Cahuilla Valley and Terwilliger Valley groundwater basins is not well understood. During the 20th century, the reliance on groundwater near Anza, California, used for agricultural, domestic, and municipal reasons has increased, and there is the potential for changes in groundwater availability related to climate change. Several types of existing data were evaluated, and new data were collected for this study, with the goal of characterizing the region’s hydrogeology. The study’s scope included constructing a geologic framework model to show where the groundwater-bearing units are present and their relation to each other, estimating the major components of the groundwater budget, and understanding local short-term and regional long-term groundwater flow and how that has changed since the early 1900s. Two electrical resistivity tomography surveys were done in the Durasno Valley about 2,150 feet apart to identify the thickness of the alluvium, its horizontal extent, and the depth-to-basement along two profiles perpendicular to Cahuilla Creek. The subsurface sediments were mostly horizontally layered and the transitional boundary between the alluvium and basement was thinner and shallower along the upgradient profile where the depth-to-basement was about 70 feet below land surface; the depth-to-basement at the downgradient profile was more than about 140 feet below land surface. The results from the surveys were used to place four monitoring wells at two sites along the survey profiles. Artesian flow from the deepest well at the downgradient site indicated that the decomposed and competent basement likely contributed some groundwater to the overlying alluvium, laterally, from below, or both. A digital three-dimensional geologic framework model was constructed using EarthVision software to represent the subsurface geometry of the alluvium, decomposed basement, and competent basement. Maps and cross sections of the modeled thicknesses of the alluvium and decomposed basement, and the modeled elevation of the top of the competent basement, were made to show the subsurface geometry of vertical faults, selected wells, and the groundwater-bearing units. Because natural recharge is related to the variable cycles of precipitation, estimates are difficult to quantify. Recharge and runoff have extreme interannual variability in the study area; recharge and runoff can be sporadic, and a substantive amount may not occur in some years. Estimates of recharge from a previous study and the regional-scale Basin Characterization Model for California for four different periods ranged from 3,800 acre-feet/year for 1897–1947 to 5,900 acre-feet/year for 1971–2000. Potential recharge from the disposal of domestic septic systems may have been as much as 500 acre-feet in 2020. It was estimated that between about 400 and 2,400 acre-feet/year of groundwater is lost through evapotranspiration by vegetation and evaporation from open water bodies, but the main source of discharge is through pumpage, mainly used for agriculture from the alluvium in the Cahuilla Valley and Terwilliger Valley groundwater basins. The estimated total pumpage for 1991–2021 ranged from about 1,140 acre-feet in 2019 to about 3,450 acre-feet in 1994. When summed, the cumulative amount of estimated pumpage between 1991 and 2021 was about 81,400 acre-feet. The general direction of groundwater flow is from the northeast along the San Jacinto fault zone at the headwaters of Cahuilla and Hamilton Creeks, to the surface-water outlets at the west and southeast parts of the study area. Groundwater-level data from the 1950s and earlier indicate that there was a natural groundwater divide between the Cahuilla Valley and Terwilliger Valley groundwater basins, but the changing magnitude and extent of the groundwater depressions caused by pumping since about 1950 indicate that the location of the natural groundwater boundary between the Cahuilla Valley and Terwilliger Valley groundwater basins has migrated over time. Flow from the upper to the lower parts of the Cahuilla Valley groundwater basin roughly follows the course of Cahuilla Creek through the narrow Durasno Valley where an estimated volume of flow in April 2019 was about 10–150 acre-feet/year. Short-term trends in groundwater levels, particularly in wells where groundwater is shallow and in the basement unit, show how some areas respond quickly to recharge and discharge. Wells located further to the east within the Cahuilla Valley groundwater basin in the alluvium show much less of a response to recharge events; areas of sustained pumpage from the alluvium, primarily for agriculture, show long-term declines in groundwater levels and generally do not show the effects of storm events or recent runoff. Groundwater levels in wells that are farthest from where most of the recharge occurs and where pumping has been the greatest, had some of the largest long-term groundwater-level declines at a rate of about 0.8 foot/year between 1971 and 2021.

California↗

USGS2025

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, situated in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the impact of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study we constructed the Strawberry Creek integrated hydrological model (SCIHM) to increase this understanding. The SCIHM is an integrated surface runoff and groundwater model that uses the coupled groundwater and surface-water flow model (GSFLOW), which is based on the integration of the precipitation-runoff modeling system (PRMS) and the modular groundwater flow model commonly called MODFLOW, version MODFLOW-2005 software to simulate surface runoff and infiltration and groundwater flow. The model has three layers, 263 rows, and 176 columns. The model area includes the Strawberry Creek and four adjacent watersheds. The PRMS model was calibrated using two streamflow gaging stations and the GSFLOW model was calibrated to reported spring diversion discharge and a sparse number of groundwater-level measurements. The SCIHM was run with and without diversions active and simulated streamflow was compared, finding that in the headwaters of Strawberry Creek about 35 percent of the diversion flow was captured from base flow.

EarthArXiv↗

USGS2024

Simulated effects of projected 2014–40 withdrawals on groundwater flow and water levels in the New Jersey Coastal Plain

Abstract Groundwater flow between 2014 through 2040 was simulated in the New Jersey Coastal Plain based on three withdrawal scenarios. Two of the scenarios were based on projected population trends and the assumption of water conservation; the nominal water-loss scenario projected a status quo in the efficiency of water loss in the delivery systems whereas the optimal water-loss scenario projected a better water-loss efficiency resulting in less withdrawals. The third scenario assumes that all wells will withdraw water at their full allocation level which is generally much more than reported withdrawals in 2013 or projected under the other two scenarios. Maps and summaries of heads and drawdowns are presented for nine confined aquifers. All the aquifers have areas with heads below sea level by 2040. Of the three scenarios, the drawdowns are most extreme in the full allocation scenarios; there are large areas of head decline greater than 20 feet in 5 of the 9 confined aquifers. The exceptions are the Vincentown aquifer, despite some areas of large drawdown in the vicinity of wells, and the three Potomac-Raritan-Magothy (PRM) aquifers where withdrawals are regulated by Critical Area restrictions. The nominal and optimal water-loss scenarios have some areas of head declines; most are less than 15 feet. The simulation of these scenarios shows some extensive areas of head recovery as well—especially in the aquifers that are regulated by the Critical Area restrictions. Budgets of inflow and outflow components were calculated for 44 hydrologic budget areas (HBAs). The budget analysis shows that the water movement is complex and varies based on the aquifer geometry and location of pumping wells. Flow components between the unconfined and confined parts of the system were summarized by HUC11 (hydrologic unit code 11) basins.

New Jersey↗

USGS2025

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska↗

USGS2026

Spatial variation in effectiveness and costs of sagebrush restoration treatments across the western United States

Natural resource managers strive to improve restoration efficiency across the vast network of public lands of the United States, seeking the best return on investment through innovation, geographic prioritization, and adaptive management. This challenge is exemplified by ecosystems dominated by sagebrush ( Artemisia spp.), which occur across the western United States and have been degraded by increasing wildfire frequency driven by invasive plant spread, among other factors. However, both costs and effectiveness of sagebrush restoration can vary spatially due to management practices in addition to biotic and abiotic factors, and characterizing this variation could inform broad-scale planning. We leveraged published models of sagebrush recovery and treatment costs to predict and evaluate cost-effectiveness of aerial and drill seeding Artemisia spp. across 429 718 km 2 that overlapped 12 US states. Compared to natural recovery, effectiveness for both methods was generally low, yet effectiveness was often greater, and costs were always greater, for drill than aerial seeding, resulting in slightly higher cost-effectiveness on average for drill seeding. Cost-effectiveness for both treatments increased near major roads and in areas with more repeated burns. Cost-effectiveness also increased with predisturbance cover of sagebrush but decreased with herbaceous cover. However, we also identified areas where aerial seeding was more cost-effective than drill seeding, particularly with greater slope. Our results provide spatially explicit estimates and potential mechanisms of cost-effectiveness for two common seeding methods for sagebrush, which can help prioritize limited resources, guide land use, and improve restoration efficiency and effectiveness across public rangelands of the western United States.

western United States↗

USGS2025

Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia↗

USGS2024

Shallow faulting and folding beneath south‐central Seattle, Washington State, from land‐based high‐resolution seismic‐reflection imaging

The geologic framework of the Seattle fault zone (SFZ) has been extensively studied, but the structure and fault strand locations in the central portion of the fault zone through the city of Seattle have remained controversial. Much of what is known about the SFZ has come from light detection and ranging (lidar)‐topographic surveys and paleoseismic investigations of fault scarps primarily west of Puget Sound, regional gravity and aeromagnetic modeling, and multiscale marine seismic imaging in waters both west and east of Seattle. We analyze ∼24 km of land‐based P ‐wave seismic‐reflection data that fill in a critical gap in our understanding of the SFZ beneath the urban areas of West Seattle, south‐central Seattle, and Mercer Island. These data image deformed strata in the upper 1 km, including upwarped Tertiary rock and younger sediments. Collectively, these data provide evidence for multiple Quaternary‐active thrust faults, back thrusts, and sub‐basins within the SFZ beneath the city of Seattle. The results indicate that multiple and potentially active back thrusts in the upper ∼500 m extend across the length of the SFZ and the entire urban corridor that may be analogous to those on Bainbridge Island west of Puget Sound.

Washington↗

USGS2024

Status of water-level altitudes and long-term and short-term water-level changes in the Chicot and Evangeline (undifferentiated) and Jasper aquifers, greater Houston area, Texas, 2023

Since the early 1900s, groundwater withdrawn from the primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers—has been an important source of water in the greater Houston area, Texas. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of water-level altitudes and water-level changes in these aquifers in the greater Houston area. In this report, the Chicot and Evangeline aquifers are treated as a single aquifer for the purposes of providing annual assessments of regional-scale water-level altitudes and water-level changes over time. In 2023, shaded depictions of water-level altitudes for the Chicot and Evangeline aquifers (undifferentiated) ranged from about 286 feet (ft) below the North American Vertical Datum of 1988 (NAVD 88) to about 169 ft above NAVD 88. The largest decline in water-level altitudes indicated by the 1977–2023 long-term water-level-change map was in south-central Montgomery County southeast of The Woodlands. In comparison, the 1990–2023 long-term water-level-change map depicts the largest declines in water-level altitudes in localized areas at or near certain wells in parts of northwestern Harris County and south-central Montgomery County. The largest rise in water-level altitudes for 1977–2023 is depicted in a relatively large area in southeastern Harris County, whereas the largest rise in water-level altitudes for 1990–2023 is depicted in a relatively large area in central Harris County. The 5-year short-term water-level-change map depicts the largest declines at three wells in northern Fort Bend County, one well in western Harris County, and three wells in south-central Montgomery County and the largest rise at one well in central Harris County. The 1-year short-term water-level-change map depicts the largest declines at one well in northern Fort Bend County and two wells in southwestern Harris County and the largest rises at one well in northern Brazoria County and one well in south-central Montgomery County. In 2023, shaded depictions of water-level altitudes for the Jasper aquifer ranged from about 242 ft below NAVD 88 to about 218 ft above NAVD 88. The 2000–23 long-term water-level-change map depicts water-level declines throughout the study area where water-level-measurement data from the aquifer were collected, with the largest declines in north-central Harris County and south-central Montgomery County south of The Woodlands. The 5-year short-term water-level-change map depicts the largest declines at two wells in central Montgomery County near Conroe and two wells in south-central Montgomery County southeast of The Woodlands and the largest rise at one well in western Montgomery County. The 1-year short-term water-level-change map depicts the largest declines at four wells in south-central Montgomery County southeast of The Woodlands and one well in central Montgomery County near Conroe and the largest rises at two wells in western Montgomery County.

Texas↗

USGS2025

Conceptual and numerical groundwater flow model of the Iowa River alluvial aquifer near Tama County, Iowa, 1980 through 2022

The Iowa River alluvial aquifer is an important source of water on the Meskwaki Settlement in Tama County, Iowa, which is land owned by the Sac & Fox Tribe of the Mississippi in Iowa (commonly known as the Meskwaki Nation). The U.S. Geological Survey constructed a groundwater flow model, including a conceptual and numerical model, of the Iowa River alluvial aquifer and underlying hydrogeologic units near the Meskwaki Settlement in Tama County, Iowa, for the period of January 1980–August 2022 to estimate the fraction of water pumped from the Iowa River alluvial aquifer by Meskwaki Settlement wells that is derived from streamflow depletion in the Iowa River and its tributaries. Streamflow depletion is a reduction in streamflow caused by groundwater pumping and includes the interception by groundwater production wells of water that otherwise would have been discharged to streams (called “captured groundwater discharge”) and induced infiltration of streamflow to the production wells. Calibrated model runs were performed with no simulated pumping and simulated pumping only at Meskwaki Settlement wells, and the change in simulated flow rates between the groundwater system and streams for the two model runs represents the amount of streamflow depletion in the Iowa River and tributary streams resulting from pumping at the Meskwaki Settlement wells. Streamflow depletion in the Iowa River and its tributaries as a percentage of simulated pumping at the Meskwaki Settlement wells was calculated by dividing this difference by the total simulated pumping rate for the Meskwaki Settlement wells. The model results demonstrate that the mean monthly streamflow depletion, including induced infiltration and captured discharge, in the Iowa River and its tributary streams as a percentage of mean monthly pumping at the Meskwaki Settlement wells was 97.4 percent and ranged from 65.4 to 112 percent. Of the total streamflow depletion, mean monthly induced recharge was 20.9 percent and ranged from 4.9 to 37.2 percent. Mean monthly captured discharge was 76.5 percent and ranged from 57.1 to 97.1 percent. These results indicate that most of the water pumped from the Meskwaki Settlement wells is the result of streamflow depletion, in the form of both induced infiltration and captured discharge.

Iowa↗

USGS2025

Dynamic baseflow storage estimates and the role of topography, geology and evapotranspiration on streamflow recession characteristics in the Neversink Reservoir Watershed, New York

Estimates of dynamic groundwater volumes supplying baseflow to streams are important for water availability projections during extended periods of drought. The primary goals of this study were to provide dynamic storage volume estimates, inferred from streamflow recession analysis, for baseflow regimes within seven gaged catchments within the Neversink Reservoir Watershed (NRW), a critical municipal water source for New York City. Additionally, geomorphological properties, surficial geology and hydro-meteorological processes were quantified and described in relation to time and spatially variable recession behaviour and storage estimates across the NRW. To explore these relationships, we (1) evaluated seasonal trends in streamflow recession behaviour in relation to modelled potential evapotranspiration (PET) and catchment runoff rates, (2) derived empirical streamflow models for cool-season runoff using both linear and nonlinear reservoir assumptions for baseflow and (3) calculated metrics related to the geology and geomorphology of each catchment and compared these metrics to area normalised baseflow dynamic storage estimates. Results show that baseflow recession behaves as a nonlinear reservoir, and applying linear groundwater reservoir assumptions may underestimate the total dynamic storage volumes compared to what would be predicted for a nonlinear reservoir. Increases in PET caused decreases in storage conditions that resulted in increased recession rates and nonlinearity in streamflow recession during the growing season. Additionally, we found that while no single physical catchment characteristic solely predicted catchment storage dynamics, sediment volume and stream gradients were stronger predictors of normalised storage volumes than catchment surface area or surface topography alone. Within the NRW, catchments with the highest sediment volume exhibited the lowest recession rates and higher dynamic storage volumes, while the smallest catchment, mostly devoid of sediment, had the fastest recession rate and lowest dynamic storage volume.

New York↗

USGS2000

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas↗

USGS2000

Quality assurance and analysis of water levels in wells on Pahute Mesa and vicinity, Nevada Test Site, Nye County, Nevada

Periodic and continual water-level data from 1963 to 1998 were compiled and quality assured for 65 observation wells on Pahute Mesa and vicinity, Nye County, Nevada. As part of the quality assurance of all water levels, ancillary data pertinent to computing hydraulic heads in wells were compiled and analyzed. Quality-assured water levels that were not necessarily in error but which did not represent static heads in the regional aquifer system, or required some other qualification, were flagged. Water levels flagged include those recovering from recent pumping or well construction, water levels affected by nuclear tests, and measurements affected by borehole deviations. A cursory examination of about 30 wells with available water-level and down-hole temperature data indicate that water levels in most wells on Pahute Mesa would not be significantly affected by temperature if corrected to 95 degrees Fahrenheit. Wells with large corrections (greater than 10 feet) are those with long water columns (greater than 1,500 feet of water above the assumed point of inflow) in combination with mean water-column temperatures exceeding 105 degrees Fahrenheit. Water-level fluctuations in wells on Pahute Mesa are caused by several factors including infiltration of precipitation, barometric pressure, Earth tides, ground-water pumpage, and seismic events caused by tectonic activity and underground nuclear testing. No observed water-level fluctuations were attributed to a naturally occurring earthquake. The magnitude and duration of changes in water levels caused by nuclear tests are affected by the test size and the distance from a well to the test. Identifying water levels that might be affected by past nuclear tests is difficult because pre-testing water-level data are sparse. Hydrologically significant trends were found in 13 of 25 wells with multiple years of water-level record. The largest change in water levels (1,029 feet in 25 years) occurred in well U-19v PS 1D as a result of the Almendro nuclear test. Likely explanations for trends in most of the wells are either changes in precipitation patterns that affect recharge rates to the ground-water system, pumping effects from water-supply well U-20 WW, or a combination of these two factors.

Nevada↗

USGS2024

Hypothetical CO2 leakage into, and hydrological plume management within, an underground source of drinking water at a proposed CO2 storage facility, Kemper County, Mississippi, USA

A large Geologic Carbon Sequestration (GCS) hub has been proposed in Kemper County, Mississippi. The target injection interval consists of numerous Cretaceous-aged deep saline aquifers overlain by a competent and extensive regional sealing layer. Above the seal, the deepest Underground Source of Drinking Water (USDW) at the site is the Eutaw aquifer of the Eutaw Group and McShan Formation, undifferentiated. To assess potential risks of leakage from the deep sequestration reservoir, a model of a portion of the Cretaceous Eutaw Group was constructed in this study. Simulations tested various permeabilities, hypothetical leakage rates, and plume mitigation strategies utilizing existing wells. Results suggest that, under the influence of regional groundwater flow fields, leaking CO 2 would effectively bypass the existing wells, and to influence this migration would require very large water extraction rates. Therefore, to ensure plume detection, monitoring for leakage at the injection wells themselves is very important.

Mississippi↗

USGS2025

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts↗

USGS2026

Archean to Mesozoic–Cenozoic seismic crustal structure: Implications for geological and biological evolution

We use >4500 measurements of crustal structure to investigate the seismic structure of continental crust, Archean to Mesozoic–Cenozoic. The mean crustal thickness of continents, including their margins, is 36.5 km. We find that Archean, Paleoproterozoic, and Mesoproterozoic crust have similar mean crustal thickness (41 km), seismic velocities, Vp/Vs ratio, and density. Crusts of these ages span 3 Ga, from 4.0 to 1.0 Ga, and their similarity of physical properties (thickness, density, and seismic velocities) suggests that the process of crustal formation may have been similar during this time period, which covers 66% of Earth's history. Neoproterozoic crustal properties differ significantly from Mesoproterozoic and older crusts. The mean thickness of Neoproterozoic crust is 32 km, some 9 km thinner than the mean thickness of Archean, Paleoproterozoic, and Mesoproterozoic crust. A lithospheric root with a thickness of 150–200 km underlies Archean, Paleoproterozoic, and Mesoproterozoic crusts, and this root resists lithospheric rifting and crustal extension and thinning. Based on these observations, particularly the lithospheric thickness, we conclude that Archean, Paleoproterozoic, and Mesoproterozoic lithosphere are unique and together form the stable cratonic nuclei, defined as the thick (150–250 km), long-lived cores of continents. Higher mantle temperatures during the Archean, Paleoproterozoic, and Mesoproterozoic may have played a key role in the formation of the thick lithospheric roots. The second key finding is that the similarities of mean seismic properties indicate that the process of crustal formation operating in the Archean continued during the Paleoproterozoic and Mesoproterozoic. The thin (mean value < 135 km) lithospheric root beneath Neoproterozoic and younger crust may be related to the steady decrease in mantle temperature through time. Neoproterozoic and Paleozoic crust have similar physical properties, and these eras are characterized by pronounced biodiversification, including the renowned Garden of Ediacara, the Cambrian Explosion, and the Great Ordovician Biodiversification. Mesozoic–Cenozoic crust is the most diverse and reflects the current tectonic and magmatic processes of crustal formation.

Book chapter↗

USGS2024

Seismic response comparison of a historical masonry church subject to real and simulated ground motions

In recent years, advanced numerical models and high-performance computing have facilitated the utilization of ground motion time series in the assessment of the non-linear dynamic behavior of historic masonry structures. Since recorded accelerograms can be sparse for specific analysis conditions, stochastic ground motion simulations have become a viable alternative to overcome this limitation. This study simulates the recorded acceleration time series of the Central Italy 2016 earthquake event at the closest station to the town of Macerata using a site-based stochastic approach. The simulated motions are seismologically evaluated using a goodness-of-fit method in terms of various intensity measures. The simulated records, in conjunction with real records, are used to study the non-linear dynamic behavior of San Filippo Neri church located in Macerata. The church of San Filippo represents an important example of Baroque religious architecture in central Italy, which was damaged and closed off to the public after the 2016 earthquake events. The construction was investigated with a vast diagnostic campaign which included on-site testing and dynamic identification tests. The collected data is used to calibrate the dynamic response of a three-dimensional finite element model of the church. The model is finally used to compare the non-linear seismic responses under real and simulated ground motions with the site recorded damage. The results of structural responses demonstrate a strong agreement between the real and simulated records, providing evidence to support the validation of the site-based stochastic simulation.

Macerata↗