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Quality of groundwater and surface water, Wood River Valley, south-central Idaho, July and August 2012

Residents and resource managers of the Wood River Valley of south-central Idaho are concerned about the effects that population growth might have on the quality of groundwater and surface water. As part of a multi-phase assessment of the groundwater resources in the study area, the U.S. Geological Survey evaluated the quality of water at 45 groundwater and 5 surface-water sites throughout the Wood River Valley during July and August 2012. Water samples were analyzed for field parameters (temperature, pH, specific conductance, dissolved oxygen, and alkalinity), major ions, boron, iron, manganese, nutrients, and Escherichia coli (E.coli) and total coliform bacteria. This study was conducted to determine baseline water quality throughout the Wood River Valley, with special emphasis on nutrient concentrations. Water quality in most samples collected did not exceed U.S. Environmental Protection Agency standards for drinking water. E. coli bacteria, used as indicators of water quality, were detected in all five surface-water samples and in two groundwater samples collected. Some analytes have aesthetic-based recommended drinking water standards; one groundwater sample exceeded recommended iron concentrations. Nitrate plus nitrite concentrations varied, but tended to be higher near population centers and in agricultural areas than in tributaries and less populated areas. These higher nitrate plus nitrite concentrations were not correlated with boron concentrations or the presence of bacteria, common indicators of sources of nutrients to water. None of the samples collected exceeded drinking-water standards for nitrate or nitrite. The concentration of total dissolved solids varied considerably in the waters sampled; however a calcium-magnesium-bicarbonate water type was dominant (43 out of 50 samples) in both the groundwater and surface water. Three constituents that may be influenced by anthropogenic activity (chloride, boron, and nitrate plus nitrite) deviate from this pattern and show a wide distribution of concentrations in the unconfined aquifer, indicating possible anthropogenic influence. Time-series plots of historical water-quality data indicated that nitrate does not seem to be increasing or decreasing in groundwater over time; however, time-series plots of chloride concentrations indicate that chloride may be increasing in some wells. The small amount of temporal variability in nitrate concentrations indicates a lack of major temporal changes to groundwater inputs.

Idaho↗

The effects of withdrawals and drought on groundwater availability in the Northern Guam Lens Aquifer, Guam

Owing to population growth, freshwater demand on Guam has increased in the past and will likely increase in the future. During the early 1970s to 2010, groundwater withdrawals from the limestone Northern Guam Lens Aquifer, the main source of freshwater on the island, tripled from about 15 to 45 million gallons per day. Because of proposed military relocation to Guam and expected population growth, freshwater demand on Guam is projected to increase further. The expected increased demand for groundwater has led to concern over the long-term sustainability of withdrawals from existing and proposed wells. A three-dimensional numerical groundwater flow and transport model was developed to simulate the effects of hypothetical withdrawal and recharge scenarios on water levels and on the transition zone between freshwater and saltwater. The model was constructed by using average recharge during 1961–2005 and withdrawals from 2010. Hydraulic properties used to construct the model were initially based on published estimates but ultimately were adjusted to obtain better agreement between simulated and measured water levels and salinity profiles in the modeled area. Two hypothetical groundwater withdrawal scenarios were simulated: no withdrawal to simulate predevelopment conditions and withdrawal at 2010 rates under a 5-year drought. Simulation results indicate that prior to pumping; the fresh-water lens was 10 to 50 feet thicker in the Yigo-Tumon basin and more than 50 feet thicker in the Hagåtña basin. Results also indicate that continuing the 2010 withdrawal distribution during a 5-year drought would result in decreased water levels, a thinner freshwater lens, and increased salinity of water pumped from wells. The available water with an acceptable salinity (chloride concentration less than 200 milligrams per liter) would decrease from about 34 million gallons per day to 11.5 million gallons per day after 5 years but recover to pre-drought levels 5 years after the return of average recharge conditions. Five additional scenarios were simulated to assess groundwater demand projections and proposed new well sites for the Department of Defense and Guam Water Authority wells under average and drought conditions. Simulation results from these projected withdrawal scenarios indicate decreased water levels, a thinner freshwater lens, increased water salinity, and unacceptable salinity at several current withdrawal sites. However, for the scenario including projected U.S. Marine Corps demands (46.62 million gallons per day, including 10 proposed wells) more than 40 million gallons per day of the withdrawn groundwater remains in the acceptable category. During a 5-year drought, this same pumping distribution results in only about 15 million gallons per day of withdrawn groundwater having acceptable salinity. A scenario in which groundwater withdrawal was redistributed in an attempt to maximize withdrawal while maintaining acceptable salinities in the withdrawn water was simulated. The redistributed withdrawal simulates about 47 million gallons per day of withdrawal with more than 41 million gallons per day of withdrawal with acceptable salinity.

Guam;Northern Guam Lens Aquifer↗

Simulation of groundwater flow in the aquifer system of the Anacostia River and surrounding watersheds, Washington, D.C., Maryland, and Virginia

The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, Water Quality Division, is investigating the hydrogeology of the tidal Anacostia River watershed within Washington, D.C., with the goal of improving understanding of the groundwater-flow system and the interaction of groundwater and surface water in the watershed. To help meet this goal, a three-dimensional steady-state groundwater-flow model for the Anacostia River and surrounding watersheds in Washington, D.C., Maryland, and Virginia was constructed. The goal of the modeling study was to quantify the rate and pattern of groundwater flow to the tidal Anacostia River. The model domain includes weathered and unweathered rocks of the Piedmont Physiographic Province and the southeast-dipping sediments of the Atlantic Coastal Plain Physiographic Province. The model includes processes of recharge, evapotranspiration, withdrawals from wells, and base flow to streams, rivers, and tidal waters. Final model calibration was achieved by using the objective parameter estimation and sensitivity analysis capabilities of UCODE_2005. Simulated gradients in the surficial aquifer in the vicinity of the tidal Anacostia River indicate that flow is predominantly toward the river, with changes in the magnitude and direction of the gradients from the northeast, where the Anacostia River enters Washington, D.C., to the southwest, toward the confluence with the tidal Potomac River. Flow paths to the tidal Anacostia River from the north are largely horizontal through the surficial aquifer and Patuxent aquifer. From the south, the flow paths toward the river originate in the elevated topographic areas southeast of the river and pass through the surficial aquifer and Patapsco confining unit, lower Patapsco aquifer/Arundel Clay, and to some extent, the Patuxent aquifer. Groundwater-flow rates to and from the tidal rivers (Potomac and Anacostia) are generally greatest near the land-water boundary, where the gradient in the water table is greatest, and diminish toward the middle of the tidal river channels. The tidal rivers are predominantly areas of groundwater discharge, although there are areas where tidal waters are recharging the subsurface, typically where small variations or depressions in the topography produce small locally reversed gradients in the water table. Substantial recharge of tidal waters to the groundwater system is observed for the tidal Potomac where the upper Patapsco aquifer subcrops south of Washington, D.C. Water budget calculations indicate that inflows to the groundwater system beneath the tidal Anacostia River are predominantly from the land area of Washington, D.C., followed by tidal surface water and flows from lower layers. Outflows are largely to the tidal Anacostia River, with a smaller part going to the land area underlying Washington, D.C.

Delaware, Maryland, Washington D.C.↗

Subsidence (2004-2009) in and near lakebeds of the Mojave River and Morongo groundwater basins, southwest Mojave Desert, California

Subsidence, in the vicinity of dry lakebeds, within the Mojave River and Morongo groundwater basins of the southwest Mojave Desert has been measured by Interferometric Synthetic Aperture Radar (InSAR). The investigation has focused on determining the location, extent, and magnitude of changes in land-surface elevation. In addition, the relation of changes in land-surface elevation to changes in groundwater levels and lithology was explored. This report is the third in a series of reports investigating land-surface elevation changes in the Mojave and Morongo Groundwater Basins, California. The first report, U.S. Geological Survey (USGS) Water-Resources Investigations Report 03-4015 by Sneed and others (2003), describes historical subsidence and groundwater-level changes in the southwest Mojave Desert from 1969 to 1999. The second report, U.S. Geological Survey Water-Resources Investigations Report 07-5097, an online interactive report and map, by Sneed and Brandt (2007), describes subsidence and groundwater-level changes in the southwest Mojave Desert from 1999 to 2004. The purpose of this report is to document an updated assessment of subsidence in these lakebeds and selected neighboring areas from 2004 to 2009 as measured by InSAR methods. In addition, continuous Global Positioning System (GPS)(2005-10), groundwater level (1951-2010), and lithologic data, if available, were used to characterize compaction mechanisms in these areas. The USGS California Water Science Center’s interactive website for the Mojave River and Morongo groundwater basins was created to centralize information pertaining to land subsidence and water levels and to allow readers to access available data and related reports online. An interactive map of land subsidence and water levels in the Mojave River and Morongo groundwater basins displays InSAR interferograms, subsidence areas, subsidence contours, hydrographs, well information, and water-level contours. Background information, including a basic description of the mechanics of land subsidence and InSAR, as well as a description of the study area, is presented within the Mojave Water Resources Interactive Map and report.

California↗

Effect of land-applied biosolids on surface-water nutrient yields and groundwater quality in Orange County, North Carolina

Land application of municipal wastewater biosolids is the most common method of biosolids management used in North Carolina and the United States. Biosolids have characteristics that may be beneficial to soil and plants. Land application can take advantage of these beneficial qualities, whereas disposal in landfills or incineration poses no beneficial use of the waste. Some independent studies and laboratory analysis, however, have shown that land-applied biosolids can pose a threat to human health and surface-water and groundwater quality. The effect of municipal biosolids applied to agriculture fields is largely unknown in relation to the delivery of nutrients, bacteria, metals, and contaminants of emerging concern to surface-water and groundwater resources. Therefore, the North Carolina Department of Environment and Natural Resources (NCDENR) collaborated with the U.S. Geological Survey (USGS) through the 319 Nonpoint Source Program to better understand the transport of nutrients and bacteria from biosolids application fields to groundwater and surface water and to provide a scientific basis for evaluating the effectiveness of the current regulations. The USGS conducted a paired agricultural watershed study in the Collins Creek and Cane Creek Reservoir watersheds in Orange County, North Carolina. Field activities were conducted from March 2011 through May 2013 at two field study sites, including biosolids field application sites owned by Orange County Water and Sewer Authority (OWASA) in the Collins Creek watershed and a background study site in the Cane Creek watershed that has no fields receiving biosolids applications. Samples of biosolids source material and soil were collected from the land-application fields for laboratory analyses. Soil samples were also collected from a background agricultural field in the Cane Creek watershed that has never received land-applied municipal biosolids. Shallow groundwater samples were collected quarterly from new monitoring wells installed by NCDENR along the edge of the biosolids land-application fields and a background agricultural field for laboratory analyses. Two surface-water monitoring sites were established on Collins Creek to compute continuous streamflow and collect discrete baseflow and stormwater runoff water-quality data upstream and downstream from the biosolids land-application fields. Surface water-quality samples were also collected for baseflow and stormwater runoff conditions at an existing USGS streamgage on Cane Creek to monitor water-quality conditions in the background study watershed. The study primarily focused on nutrients and bacteria; however, data for field properties and water-quality constituents, including metals, major ions, and contaminants of emerging concern (household-, industrial-, and agricultural-use compounds, pharmaceutical compounds, hormones, and antibiotics) also were collected and used in the analyses. There were no exceedances of the 10 elements with designated U.S. Environmental Protection Agency (EPA) ceiling concentrations for land-applied biosolids in any of the biosolids samples. Treatment processes and storage techniques used by OWASA are effective in eliminating Escherichia coli and fecal coliform bacteria from biosolids. Copper, molybdenum, total Kjeldahl nitrogen, and total phosphorus were elevated in the soil from biosolids land-application fields relative to the background field. The relative richness of these constituents in the biosolids land-application fields is consistent with biosolids being the source of the elevated concentrations given the relatively high concentrations of these constituents in the biosolids samples that were collected. Shallow groundwater in the transitional zone wells, which were located adjacent to and topographically downgradient from all the biosolids land-application fields, were found to be statistically different and had higher nitrate concentrations (medians greater than 12 milligrams per liter) than all the other wells sampled as part of the study. Surface-water nutrient concentrations and yields, primarily nitrate, were higher at the monitoring site on Collins Creek downstream from the biosolids land-application fields than the other study sites that drained watersheds without biosolids land application. The largest differences in concentrations between sites were measured at baseflow conditions, which indicate that the main cause of these differences, particularly between Cane Creek and the Collins Creek site downstream from the OWASA application fields, is related to nitrate contribution from the shallow groundwater. Contaminants of emerging concern were detected in approximately 40 percent of the laboratory analyses of the biosolids samples and more frequently in soil samples from the biosolids land-application fields (approximately 40 percent of laboratory analyses) relative to the soil samples from the background field (approximately 12 percent of laboratory analyses). However, contaminants of emerging concern detected in the laboratory analysis for this study do not appear to be good indicators of human-waste contaminants derived from land-applied biosolids in groundwater or surface-water because the number of detections and concentrations at the background wells and surface-water monitoring sites are similar to or higher than those at wells and monitoring sites adjacent to or downstream from the biosolids land-application fields. The data, analysis, and conclusions associated with this study can be used by regulatory agencies, resource managers, and wastewater-treatment operators to (1) better understand the quantity and characteristics of nutrients, bacteria, metals, and contaminants of emerging concern that are transported away from biosolids land-application fields to surface water and groundwater under current regulations for the purposes of establishing effective total maximum daily loads (TMDLs) and restoring impaired water resources, (2) assess how well existing regulations protect waters of the State and potentially recommend effective changes to regulations or land-application procedures, and (3) establish a framework for developing guidance on effective techniques for monitoring and regulatory enforcement of permitted biosolids land-application fields.

North Carolina↗

Delineation of areas having elevated electrical conductivity, orientation and characterization of bedrock fractures, and occurrence of groundwater discharge to surface water at the U.S. Environmental Protection Agency Barite Hill/Nevada Goldfields Superfund site near McCormick, South Carolina

During October 2012 through March 2013, the U.S. Geological Survey (USGS), in cooperation with the U.S. Environmental Protection Agency (EPA) Region 4, Superfund Section, conducted borehole geophysical logging, surface geophysical surveys, and water-quality profiling in selected wells and areas to characterize or delineate the extent of elevated subsurface electrical conductivity at the EPA Barite Hill/Nevada Goldfields Superfund site near McCormick, South Carolina. Elevated electrical conductivity measured at the site may be related to native rock materials, waste rock disposal areas used in past operations, and (or) groundwater having elevated dissolved solids (primarily metals and major ions) related to waste migration. Five shallow screened wells and four open-borehole bedrock wells were logged by using a suite of borehole tools, and downhole water-quality profiles were recorded in two additional wells. Well depths ranged from about 26 to 300 feet below land surface. Surface geophysical surveys based on frequency-domain electromagnetic and distributed temperature sensing (DTS) techniques were used to identify areas of elevated electrical conductivity (Earth materials and groundwater) and potential high dissolved solids in groundwater and surface water on land and in areas along the northern unnamed tributary at the site. Results from the electromagnetic-induction logging of four selected wells near the Main Pit and one well located about 800 feet southeast of the Main Pit lake indicate that elevated electrical conductivity extends to a depth of about 110 feet below land surface. Groundwater-quality properties recorded in eight selected wells were highly variable, suggesting a broad spectrum of geochemical conditions and contaminant concentrations within the groundwater system. Ranges of field water-quality properties recorded from water-profiling of groundwater in all wells logged were as follows: pH, 3.1 to 9.2; specific conductance, 48 to 5,300 microsiemens per centimeter; dissolved oxygen, 0.2 to 4.4 milligrams per liter; and water temperature, 17.0 to 18.0 degrees Celsius. The highest specific conductance and lowest pH measurements were made in boreholes located between the Main Pit lake and the northern unnamed tributary. Conceptually, these wells may intercept elevated dissolved solids in groundwater leaking from the Main Pit lake along a flow path that discharges into the unnamed tributary to the north. Results from surface geophysical electromagnetic and fiber-optics surveys confirm areas of focused discharge of groundwater near the Main Pit lake along the northern unnamed tributary. The frequency-domain surface electromagnetic surveys also identified an area with higher levels of elevated electrical conductivity located northwest of the former Rainsford Pit area. Bedrock properties were characterized from borehole geophysical logs collected from three open-borehole bedrock wells. The mean strike azimuth of the borehole foliation data measured in bedrock well IR-1 was 221° (N. 41° E.), and the mean dip angle was 78° to the northwest. Dominant strike azimuth orientations of primary fractures measured in three boreholes were from 210° to 250° (N. 30° E. to N. 70° E.) with a mean dip of 68° northwest. Transmissivity estimates interpreted from the heat-pulse flowmeter data from bedrock well IR-1 were about 69 feet squared per day, and the radius of influence was estimated at about 640 feet.

South Carolina↗

Groundwater chemistry in the vicinity of the Puna Geothermal Venture Power Plant, Hawai‘i, after two decades of production

We report chemical data for selected shallow wells and coastal springs that were sampled in 2014 to determine whether geothermal power production in the Puna area over the past two decades has affected the characteristics of regional groundwater. The samples were analyzed for major and minor chemical species, trace metals of environmental concern, stable isotopes of water, and two organic compounds (pentane and isopropanol) that are injected into the deep geothermal reservoir at the power plant. Isopropanol was not detected in any of the groundwaters; confirmed detection of pentane was restricted to one monitoring well near the power plant at a low concentration not indicative of source. Thus, neither organic compound linked geothermal operations to groundwater contamination, though chemical stability and transport velocity questions exist for both tracers. Based on our chemical analysis of geothermal fluid at the power plant and on many similar results from commercially analyzed samples, we could not show that geothermal constituents in the groundwaters we sampled came from the commercially developed reservoir. Our data are consistent with a long-held view that heat moves by conduction from the geothermal reservoir into shallow groundwaters through a zone of low permeability rock that blocks passage of geothermal water. The data do not rule out all impacts of geothermal production on groundwater. Removal of heat during production, for example, may be responsible for minor changes that have occurred in some groundwater over time, such as the decline in temperature of one monitoring well near the power plant. Such indirect impacts are much harder to assess, but point out the need for an ongoing groundwater monitoring program that should include the coastal springs down-gradient from the power plant.

Hawaii↗

Particle tracking for selected groundwater wells in the lower Yakima River Basin, Washington

The Yakima River Basin in south-central Washington has a long history of irrigated agriculture and a more recent history of large-scale livestock operations, both of which may contribute nutrients to the groundwater system. Nitrate concentrations in water samples from shallow groundwater wells in the lower Yakima River Basin exceeded the U.S. Environmental Protection Agency drinking-water standard, generating concerns that current applications of fertilizer and animal waste may be exceeding the rate at which plants can uptake nutrients, and thus contributing to groundwater contamination. The U.S. Geological Survey (USGS) recently completed a regional scale transient three-dimensional groundwater-flow model of the Yakima River Basin using MODFLOW-2000. The model was used with the USGS particle-tracking code MODPATH to generate advective flowpaths and associated travel times. Analyses used particle backtracking in time from September 2001 through 504 monthly stress periods to October 1959 or until pathlines terminated at a model boundary. The particle starting locations were assigned to 1,000 foot square computational model cells containing one or more of the 121 sampling locations with measured nitrate concentrations greater than the U.S. Environmental Protection Agency drinking-water standard for nitrate (10 milligrams per liter [mg/L]). Of the 2,403 particles, the simulated pathlines for 2,080 reached the water table within the 42-year simulation period, thus identifying the predicted recharge areas for those particles. The median horizontal straight-line distance was 13,194 feet between starting and ending locations for these particles and the median time-of-travel for particles that intersected the water table was 984 days. Well to water-table travel times for 75.4 percent of the particles were less than the average travel time of 3,749 days. Predicted recharge locations for all particles, including those that did not reach the water table in 42 years, were between 50 feet and 34 miles horizontal distance from their starting locations, with a median distance of less than 3 miles away. Generalized groundwater-flow directions in unconsolidated basin-fill deposits were towards the Yakima River, which acts as a local sink for shallow groundwater, and roughly parallel to topographic gradients. Particles backtracked from more shallow aquifer locations traveled shorter distances before reaching the water table than particles from deeper locations. Flowpaths for particles starting at wells completed in the basalt units underlying the basin-fill deposits sometimes were different than for wells with similar lateral locations but more shallow depths. In cases where backtracking particles reached geologic structures simulated as flow barriers, abrupt changes in direction in some particle pathlines suggest significant changes in simulated hydraulic gradients that may not accurately reflect actual conditions. Most groundwater wells sampled had associated zones of contribution within the Toppenish/Benton subbasin between the well and the nearest subbasin margin, but interpretation of these results for any specific well is likely to be complicated by the assumptions and simplifications inherent in the model construction process. Delineated zones of contribution for individual wells are sensitive to the depths assigned to the screened interval of the well, resulting in simulated areal extents of the zones of contribution to a discharging well that are elongated in the direction of groundwater flow.

Washington↗

Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

Overview This study assessed lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes applying three approaches: statistical analysis, field study, and groundwater-flow modeling. Statistical analyses of lake levels were completed to assess the effect of physical setting and climate on lake-level fluctuations of selected lakes. A field study of groundwater and surface-water interactions in selected lakes was completed to (1) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (2) estimate general ages for waters extracted from the wells, and (3) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Groundwater flow was simulated using a steady-state, groundwater-flow model to assess regional groundwater and surface-water exchanges and the effects of groundwater withdrawals, climate, and other factors on water levels of northeast Twin Cities Metropolitan Area lakes.

Minnesota↗

Groundwater-flow budget for the lower Apalachicola-Chattahoochee-Flint River Basin in southwestern Georgia and parts of Florida and Alabama, 2008–12

As part of the National Water Census program in the Apalachicola-Chattahoochee-Flint (ACF) River Basin, the U.S. Geological Survey evaluated the groundwater budget of the lower ACF, with particular emphasis on recharge, characterizing the spatial and temporal relation between surface water and groundwater, and groundwater pumping. To evaluate the hydrologic budget of the lower ACF River Basin, a groundwater-flow model, constructed using MODFLOW-2005, was developed for the Upper Floridan aquifer and overlying semiconfining unit for 2008–12. Model input included temporally and spatially variable specified recharge, estimated using a Precipitation-Runoff Modeling System (PRMS) model for the ACF River Basin, and pumping, partly estimated on the basis of measured agricultural pumping rates in Georgia. The model was calibrated to measured groundwater levels and base flows, which were estimated using hydrograph separation. The simulated groundwater-flow budget resulted in a small net cumulative loss of groundwater in storage during the study period. The model simulated a net loss in groundwater storage for all the subbasins as conditions became substantially drier from the beginning to the end of the study period. The model is limited by its conceptualization, the data used to represent and calibrate the model, and the mathematical representation of the system; therefore, any interpretations should be considered in light of these limitations. In spite of these limitations, the model provides insight regarding water availability in the lower ACF River Basin.

Alabama, Florida, Georgia↗

Hydrologic assessment and numerical simulation of groundwater flow, San Juan Mine, San Juan County, New Mexico, 2010–13

Coal combustion byproducts (CCBs), which are composed of fly ash, bottom ash, and flue gas desulfurization material, produced at the coal-fired San Juan Generating Station (SJGS), located in San Juan County, New Mexico, have been buried in former surface-mine pits at the San Juan Mine, also referred to as the San Juan Coal Mine, since operations began in the early 1970s. This report, prepared by the U.S. Geological Survey in cooperation with the Mining and Minerals Division of the New Mexico Energy, Minerals and Natural Resources Department, describes results of a hydrogeologic assessment, including numerical groundwater modeling, to identify the timing of groundwater recovery and potential pathways for groundwater transport of metals that may be leached from stored CCBs and reach hydrologic receptors after operations cease. Data collected for the hydrologic assessment indicate that groundwater in at least one centrally located reclaimed surface-mining pit has already begun to recover. The U.S. Geological Survey numerical modeling package MODFLOW–NWT was used with MODPATH particle-tracking software to identify advective flow paths from CCB storage areas toward potential hydrologic receptors. Results indicate that groundwater at CCB storage areas will recover to the former steady state, or in some locations, groundwater may recover to a new steady state in 6,600 to 10,600 years at variable rates depending on the proximity to a residual cone-of-groundwater depression caused by mine dewatering and regional oil and gas pumping as well as on actual, rather than estimated, groundwater recharge and evapotranspirational losses. Advective particle-track modeling indicates that the number of particles and rates of advective transport will vary depending on hydraulic properties of the mine spoil, particularly hydraulic conductivity and porosity. Modeling results from the most conservative scenario indicate that particles can migrate from CCB repositories to either the Shumway Arroyo alluvium after 1,320 years and from there to the San Juan River alluvium after 1,520 years or from southernmost CCB repositories directly to the San Juan River alluvium after 2,400 years after the cessation of mining.

New Mexico↗

Geochemistry and microbiology of groundwater and solids from extraction and monitoring wells and their relation to well efficiency at a Federally operated confined disposal facility, East Chicago, Indiana

In cooperation with the U.S. Army Corps of Engineers, Chicago District, the U.S. Geological Survey investigated the processes affecting water quality, geochemistry, and microbiology in representative extraction and monitoring wells at a confined disposal facility (CDF) in East Chicago, Indiana. The CDF is a 140-acre Federally-managed facility that was the former location of an oil refinery and is now used for the long-term disposal and storage of dredge material from the Indiana Harbor and Indiana Harbor Canal. Residual petroleum hydrocarbons and leachate from the CDF are contained within the facility by use of a groundwater cutoff wall. The wall consists of a soil-bentonite slurry and a gradient control system made up of an automated network of 96 extraction wells, 42 monitoring wells, and 2 ultrasonic sensors that maintain an inward hydraulic gradient at the site. The pumps in the extraction wells require vigilant maintenance and must be replaced when unable to withdraw water at a rate sufficient to maintain the required inward gradient. The wells are screened in the Calumet aquifer, a coarse-grained sand and gravel unit that extends approximately 35 feet below the land surface and is not utilized for drinking-water supply at the CDF or in the surrounding area. This study was initiated to identify the cause of decreased pump discharges and to identify potential mitigation strategies. For this study, the U.S. Geological Survey collected groundwater and solids from monitoring and extraction wells. Groundwater samples were collected during June 2014 for precautionary health screening and on four occasions during September 2014 through November 2014. Groundwater samples collected from two extraction wells during June 2014 were analyzed for concentrations of anthropogenic organic constituents. During September through November 2014, groundwater samples were collected from one additional extraction well, and samples from three monitoring wells were analyzed for concentrations of inorganic and organic constituents, dissolved gases, and bacterial abundance and diversity. Solid samples were collected during April 2014, during September 2014 through November 2014, and during November 2016. Solid samples were collected from the exterior of extraction-well pumps and as flocculent from water samples. Solid samples were collected from 10 wells, including 1 extraction well and 3 monitoring wells sampled for water quality. Solid samples were analyzed for mineralogy, solid-phase habit, geochemistry, and organic composition. The following is a list of observations that were made during this study: (1) the water quality is substantially variable among the six well locations sampled as part of this study—lower (more negative) redox values and higher concentrations of many constituents (including calcium, magnesium, sodium, and sulfate) and properties (including dissolved solids, hardness, and turbidity) were detected in sampled wells located near the extraction wells with the highest frequency of failure; (2) water-level drawdown is variable between extraction wells—wells with the greatest drawdown may pull deeper groundwater into the borehole; (3) dissolved gas results indicate reducing oxidation-reduction processes in the aquifer material that can feasibly contribute iron, carbon dioxide, and other byproducts from hydrocarbon degradation to precipitates and solids that accumulate on and impair pump operation; (4) crystalline and amorphous solid-phase minerals are precipitating in the borehole; (5) several types of bacteria are present in water pumped from extraction wells and are likely responsible for bonding mineral and microbiologic matter to the pump (and other well components); and (6) bacteria may create microenvironments that facilitate precipitation of solids or inhibit dissolution of unstable minerals once the bacteria adhere to biofilm attached to the pump. Results of the study indicate that bacteria may be accumulating and entrapping solid material on the exterior of pumps. This accumulation reduces heat transfer and water discharge from the pump and may lead to decreased efficiency or mechanical failure. Observations could not be made on the well screen, gravel pack, or surrounding geologic formation; therefore, mitigating measures in the borehole may not solve well-productivity issues. Remedies for the pump fouling problems were derived from the review and interpretation of data collected during this study and from information documented in other sources about groundwater well fouling. Potential remedies to problems associated with pump fouling at the CDF may include the following: (1) reducing attractiveness of the extraction wells for microbiological growth by modifying the chemical or physical environment of the well, (2) modifying the pump exterior to decrease microbiological adherence, (3) changing the pumping regime to control the chemistry of water entering the well from the surrounding aquifer material, (4) modifying the pumps to be less physically and thermally attractive, and (5) removing hydrocarbons from groundwater and the aquifer material surrounding the wells or adding surfactants to make them more mobile. Pilot scale testing may be necessary to identify the most effective treatment or combination of treatments.

Indiana↗

Hydrogeology of Lower Amargosa Valley and groundwater discharge to the Amargosa Wild and Scenic River, Inyo and San Bernardino Counties, California, and adjacent areas in Nye and Clark Counties, Nevada

In 2009, Congress designated certain reaches of the Amargosa River in Inyo County, California between the town of Shoshone and Dumont Dunes as a Wild and Scenic River. As part of the management of the Amargosa Wild and Scenic River, the Bureau of Land Management cooperated with the U.S. Geological Survey to assess the surface and groundwater resources of the Tecopa basin. Groundwater is the primary source of water to the perennial reaches of the Amargosa River. The U.S. Geological Survey studied the surface and groundwater systems in the basin, and assessed the sources and volume of groundwater discharging into the perennial reaches of the Amargosa Wild and Scenic River. The springs within the Tecopa basin (and the greater Lower Amargosa Valley Hydrographic Area) can be generally grouped by spring type and geographic location. There are four types of groundwater discharge points in the Tecopa basin—regional carbonate-rock springs and seeps, Tecopa Hills springs and seeps, thermal springs and seeps, and Amargosa Canyon hillslope springs and seeps. Results of chemical analysis indicate that water from all of these springs in the Lower Amargosa Valley and particularly in the Tecopa basin, is sourced in the carbonate-rock aquifer, with a local component of recharge. Groundwater is recharged in the Spring Mountains and moves through and around the Nopah and Resting Spring Ranges and into the Tecopa basin. A small (less than 1 cubic foot per second [ft 3 /s] or 500 acre‑feet per year) component of flow from the Amargosa Desert moves through the river channel alluvium and basin fill from the north. The location and type of spring appear to be controlled by the geology and geologic structure of the Lower Amargosa Valley. The regional springs (such as Shoshone and Borax Springs) and associated seeps tend to occur along the west side of the basin whereas other carbonate-rock aquifer springs discharge from adjacent mountain ranges, such as the Resting Spring Range, and as a result of low-permeability barriers, such as the Tecopa Hills. The thermal springs and seeps discharge from an area near the town of Tecopa, California. The Amargosa Canyon hillslope springs and seeps discharge directly into the river. Salt-crusted soils adjacent to the river indicate additional areas of diffuse discharge where groundwater is being evaporated. Perennial flow in the main channel of the Amargosa River appears to originate in an area of thermal springs near Tecopa. Persistent groundwater-fed pools begin to appear along the river channel just to the south of the Tecopa Hills. Flow between these pools is evident, but difficult to measure. During the synoptic seepage measurement survey in February 2014, flow in the Amargosa River at the Tecopa streamgage (U.S. Geological Survey site 10251300, Amargosa River at Tecopa, California) was approximately 1 ft 3 /s. Just to the south of the Tecopa streamgage, a line of cooler water springs (the Amargosa Canyon hillslope springs) emerges east of the river channel and continues for approximately 1 mile along the Amargosa Canyon wall. At the end of the spring reach, the flow in the river increased to just over 4 ft 3 /s. Flow then decreased to approximately 3 ft 3 /s at the confluence of Willow Creek, approximately 3.5 miles downstream. Downstream from the confluence of Willow Creek, the river consistently loses water and was dry just north of Dumont Dunes during the February 2014 synoptic seepage measurement survey.

California, Nevada↗

Estimation of groundwater flow through Yucca Flat based on a multiple-well aquifer test at well ER-6–1–2 main , Nevada National Security Site, southern Nevada

The rate of groundwater flow past underground nuclear testing areas in Yucca Flat at the Nevada National Security Site, southern Nevada, was estimated using results from the ER-6-1-2 main multiple-well aquifer test (MWAT), done during February 5–July 23, 2004. Drawdowns in 13 observation wells were evaluated from pumping in well ER-6-1-2 main and used as observations in a regional groundwater-flow model to estimate the groundwater-flow rate. Flow from southern Yucca Flat regionally was constrained by detecting drawdown in Tracer Well 3 , which is 33 miles south-southwest of pumping well ER-6-1-2 main . Predevelopment flow, the ER-6-1-2 main MWAT, and regional groundwater pumping were simulated in separate models that jointly informed estimates of transmissivity and specific-yield distributions. Predevelopment flow constrained groundwater-flow estimates from southern Yucca Flat because the steady-state model correctly simulated regional groundwater discharges in the Ash Meadows groundwater basin and the surrounding basins. Less than 600 acre-feet per year of groundwater moves from underground nuclear testing areas and flows south of well ER-6-1-2 main in southern Yucca Flat.

Nevada↗

Determination of study reporting limits for pesticide constituent data for the California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project, 2004–2018—Part 1: National Water Quality Schedules 2003, 2032, or 2033, and 2060

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality of groundwater resources used for public and domestic drinking water supplies in the State of California, to monitor and evaluate changes to that quality, to investigate the human and natural factors controlling water quality, and to improve the availability of comprehensive groundwater quality data and information. Between May 18, 2004, and May 3, 2018, the GAMA-PBP collected 3001 groundwater samples for analysis of pesticide constituents by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL)(note that ‘pesticide constituents’ includes parent compounds and degradates). Of these samples, 2994 were analyzed for pesticide constituents on schedules 2003, 2032, or 2033 (65 to 84 constituents), and 840 were analyzed for pesticide constituents on schedule 2060 (58 constituents). The original dataset reported by the NWQL to the USGS National Water Information System (NWIS) database contained a total of 2,688 detections of 78 pesticide constituents and 253,825 non-detections. In this original dataset, 33 percent of the 3,001 samples analyzed had reported detections of one or more pesticide constituents. This report describes the GAMA-PBP data-quality objectives for pesticide data, the procedures used to establish study reporting limits, and use of those reporting limits to censor the data from the NWQL so that the final data published by the GAMA-PBP meet these data-quality objectives. The final GAMA-PBP dataset for samples collected from May 2004 to May 2018, after censoring, had a total of 1,632 detections of 37 pesticide constituents. In the final GAMA-PBP dataset, 25 percent of the 3,001 samples analyzed had detections of one or more pesticide constituents. The presence of pesticides in groundwater is commonly evaluated by calculating detection frequencies. Detection frequencies for pesticides are sensitive to detection limits and method performance for concentrations near those limits; therefore, the two primary data quality issues addressed in the GAMA-PBP data-quality objectives for pesticides are (1) establishing criteria for classifying data from the laboratory as detections or non-detections for the purpose of data reporting by the project and (2) accounting for changes in analytical methods or method performance over time. The GAMA-PBP addresses these issues by developing study reporting limits that are used as the boundary between detections and non-detections for the reporting of GAMA-PBP results. These reporting limits are defined from method detection limits (MDLs) provided by the NWQL, unless examination of results from laboratory set blanks (LSBs) and GAMA-PBP field blanks indicates that a higher concentration censoring limit is warranted. The GAMA-PBP selected the MDL as the primary choice for defining study reporting limits for consistency with U.S. Environmental Protection Agency (EPA) guidelines for reporting detections of pesticides and other organic constituents. A five-step procedure is used to develop study reporting limits and censor the GAMA-PBP dataset accordingly. The effect of the censoring at each step is described to provide information about the relative effect of each step on the overall censoring of the dataset. Steps 1 and 2 can be implemented at the time the data are received, whereas steps 3−5 require information accumulated over an extended period. Step 1: Reject results that were most likely the result of specific contamination instances attributable to unusual field or laboratory conditions during sample collection or processing. Two such instances were identified, leading to rejection of 25 detections, which were assigned a data-quality indicator code of “Q” for “reviewed and rejected” in the NWIS database. Step 2: Use the NWQL MDLs in effect at the time each sample was analyzed as the reporting limit. A total of 506 detections were censored on this basis. Step 3: Use the maximum MDL established by the NWQL during July 2004–August 2018 (MDLmax) as the reporting limit. The rationale for using the MDLmax as the reporting limit is based primarily on the observation that the concentrations of MDLs generally increased over time. A total of 438 detections were censored on this basis. Step 4: Use the LSBs to identify periods of greater potential laboratory contamination bias and define raised reporting limits to be used during those periods. These periods were defined by using a moving average detection frequency approach. For consistency with the NWQL procedures for defining raised reporting limits on the basis of detections in LSBs, the raised reporting limits were defined as equal to three times the highest concentration measured in an LSB during the period. A total of 25 detections in groundwater samples analyzed during periods of increased laboratory contamination bias were censored. Step 5: Use the LSBs and field blanks to identify potential contamination bias from field or laboratory processes outside of the time periods identified in step 4. The NWQL protocols were used to define the MDLs from blanks analyzed outside of the periods identified in step 4. If an MDL defined from blanks was greater than the MDLmax, the MDL defined from blanks was used to censor the data. One constituent had a study reporting limit defined on this basis, and a total of 62 detections in groundwater samples were censored. As of 2019, the USGS NWIS database does not have the capability to store both the original value reported by the NWQL and the final value published by the GAMA-PBP that reflects application of the quality-control censoring described in this report. In the interim, while this capability is developed, the 1,031 results censored in steps 2−5 are blocked from public release in NWIS, and the GAMA-PBP has published the original and final values in a USGS data release accompanying this report. The entire GAMA-PBP final dataset for pesticide constituents on schedules 2003, 2032, or 2033, or on schedule 2060 is publicly available in that USGS data release, through the USGS GAMA-PBP public web portal, and through the California State Water Resources Control Board GAMA public groundwater information system.

California↗

Potential groundwater recharge rates for two subsurface-drained agricultural fields, southeastern Minnesota, 2016–18

Subsurface drainage is used to efficiently drain saturated soils to support productive agriculture in poorly drained terrains. Although subsurface drainage alters the water balance for agricultural fields, its effect on groundwater resources and groundwater recharge is poorly understood. In Minnesota, subsurface drainage has begun to increase in southeastern Minnesota, even though this part of the State is underlain by permeable karstic bedrock aquifers with only a thin layer of glacial sediments separating these aquifers from land surface. To gain a better understanding of groundwater recharge effects from subsurface drainage, the U.S. Geological Survey (USGS), in cooperation with the Legislative-Citizen Commission on Minnesota Resources, led a 2-year hydrologic study to investigate this connection for two agricultural fields in southeastern Minnesota with subsurface drainage. A total of three monitoring plots were used between the two agricultural fields: two monitoring plots that included an actively drained area with peripheral, undrained areas, and a third monitoring plot without any subsurface drainage. Multiple piezometer transects were set up across the three monitoring plots to characterize the unsaturated zone and shallow water-table flow using pressure transducers and soil moisture probes. From these piezometers, groundwater recharge rates were derived using two different methods: the RISE Water-Table Fluctuation (WTF) method and the DRAINMOD model. In addition to these two methods, the USGS Soil-Water-Balance (SWB) model was used to estimate potential recharge rates for three different monitoring plots. In addition to deriving groundwater recharge rates, the hydrologic budget was analyzed to interpret the water-table surface elevation and soil volumetric water content time series. At one of the two drained plots, the transects exhibited varying water-table surface elevation patterns. Frequent backflow from the adjacent ditch caused subsurface drainage flow to slow down or stop drainage through the main collector drain and cause pipe pressurization, so the closest transect appeared to be mostly controlled by the drain pressurization, whereas the farthest transect was more efficiently drained. Both of the drained monitoring plots had an elevation gradient parallel to the pattern tiles, sloping downward towards the collector drain that aggregated the parallel lines into a single drain. Because the transects were set at different gradients in the field, some of the water-table surface elevation differences were also attributed to lateral flow towards the lowest parts of the field. Three methods were used to derive potential groundwater recharge rates: the RISE WTF method, the USGS SWB model, and DRAINMOD-derived deep seepage rates. Potential groundwater recharge rates, using the RISE WTF method, across all piezometers were 1.55 and 1.94 inches per year, respectively, for water years 2017 and 2018. More differentiation of potential recharge rates between different piezometer types occurred for water year 2018. Although the difference was slightly more than 1 inch between the drained and nondrained piezometers for water year 2018, this difference was statistically significant based on a t-test with a p -value of 0.036 ( α =0.05). When looking at recharge based on distance from the drain, the subsurface drain did not affect potential recharge, although other factors such as variability in screen depths, well construction, and specific yield variability cannot be eliminated. The SWB model was also used to estimate potential recharge rates for water years 2017–18, with rates between 2.44 and 5.92 inches per year for the two drained sites, generally higher than the RISE WTF estimates. DRAINMOD-derived potential recharge rates were generally the highest of the three methods, with potential recharge rates varying from 2.07 to 9.49 inches per year. Overall, there was a lack of agreement between the three methods. These results were not remarkable, considering the fundamental differences in the methodology for each method. However, all methods did show a fundamental difference between piezometers within the drained area and piezometers outside the drained area, including the third undrained monitoring plot. The drained areas show a lower overall potential groundwater recharge compared to the nondrained areas for all three estimates. The difference for the 2018 recharge estimates was slightly higher than 1 inch for the RISE WTF method, the difference was almost double for the nine sites for the DRAINMOD model, and the difference between the drain and undrained plots was even more significant for the SWB model.

Minnesota↗

Quality of pesticide data for groundwater analyzed for the National Water-Quality Assessment Project, 2013–18

The National Water-Quality Assessment (NAWQA) Project of the U.S. Geological Survey (USGS) submitted nearly 1,900 samples collected from groundwater sites across the United States in 2013–18 for analysis of 225 pesticide compounds (pesticides and pesticide degradates, hereafter referred to as “pesticides”) by USGS National Water Quality Laboratory schedule 2437 (S2437). For the associated NAWQA study of pesticide occurrence and concentration in groundwater, and for other studies using pesticide results determined by S2437, it is necessary to assess the ability of reported results to meet data-quality requirements that will allow study objectives to be achieved. This assessment of the quality of S2437 results reported in 2013–18 examined data from field and laboratory quality-control samples, along with third-party performance assessment samples, to estimate bias and variability and to identify their potential sources, with an emphasis on implications for the interpretation of pesticide data for groundwater. Results indicate that measurements produced by the S2437 method for most pesticides have bias and variability that would be considered acceptable for many interpretative studies, which could therefore use the results without qualification or censoring. However, the reported data for a subset of pesticides have the potential for unacceptable contamination bias, high or low recovery bias, or high variability as a consequence of method performance and (or) nonlaboratory factors that could preclude their use for certain common objectives or could necessitate adjustment or qualification to meet those objectives. Based on data for laboratory blanks, censoring of some detections for a subset of pesticides reported by the laboratory in environmental samples might be necessary or desirable to avoid an unacceptably high likelihood of a false-positive result caused by laboratory contamination. The 90-percent upper confidence limit for the 95th percentile of laboratory blank concentration equals or exceeds the minimum reported groundwater concentration in at least 1 water year for 28 pesticides. During at least 1 water year, this upper confidence limit exceeds the maximum laboratory detection limit for 17 pesticides and exceeds the maximum laboratory reporting limit for 3 pesticides (ametryn, atrazine, and diazinon). The level of contamination indicated by this upper confidence limit should not substantially affect the suitability of reported environmental concentrations for any compound for comparison with corresponding human-health benchmarks. Despite being subjected to the same laboratory processes as laboratory blanks, field blanks indicated little evidence of contamination bias. This observation could largely be the consequence of data-reporting practices, which utilize detections in laboratory blanks to censor results in associated field samples (including blanks and environmental samples) when relative concentrations indicate that a result could have a substantial contribution from laboratory contamination. Laboratory censoring appears likely to reduce the risk of false-positive results in environmental samples below the level that laboratory blank results alone would imply. Whereas data available for third-party blind blank samples analyzed in 2018 indicate that only propoxur had any false-positive results, data for pesticides that were not spiked into blind spike samples analyzed in 2013–18 indicate that the false-positive rates for 31 pesticides exceeded 1 percent when considering only detections reported at concentrations greater than the maximum detection limit. Although about half of these pesticides lack substantial supporting evidence of contamination bias based on laboratory blank or field blank detections, indicating that spiking issues or degradation of parent compounds within the spiked samples might be a contributing factor to some false-positive results, these results indicate the need to closely examine detections reported for some pesticides in environmental samples analyzed during a similar period for possible contributions from contamination bias. Data for blind spike samples that were spiked at concentrations above the maximum reporting limit indicate that false-negative rates for eight pesticides exceed 10 percent; substantial low bias could affect results reported for these pesticides in environmental samples analyzed during a similar period. Data for laboratory reagent spikes, which measure recovery of pesticides in blank water, show little evidence for unacceptable recovery bias for S2437 pesticides. However, field matrix spikes, which measure recovery of pesticides in environmental matrices, indicate that degradation and (or) matrix effects could result in moderate to substantial low bias for groundwater results for several pesticides. Low bias could cause some reported concentrations to be categorized as being below a benchmark when the actual concentration in groundwater is greater than the benchmark. Occurrence and concentrations in groundwater could be substantially underrepresented for six pesticides with benchmarks (1H-1,2,4-triazole, asulam, bifenthrin, cis-permethrin, fenbutatin oxide, and naled) that have median recoveries between zero and 50 percent in field matrix spikes. Two compounds (didealkylatrazine and 2-hydroxy-6-ethylamino-4-amino-s-triazine) have median recoveries near or greater than 150 percent in field matrix spikes, indicating a substantial high bias. Plots of data for all spike types show clear changes in the typical recovery with time for some pesticides, which would require further examination for evaluation of temporal trends in environmental concentrations. Data for laboratory reagent spikes indicate that nearly all S2437 pesticides have acceptable variability resulting from random measurement error. Only two compounds (fenbutatin oxide and naled) have F-pseudosigma values greater than 30 percent for recovery, which implies the potential for relatively high variability in reported concentrations and could affect comparison of concentrations to benchmarks and determination of whether concentrations for samples collected at separate locations or times are truly different with a specified level of confidence. Data for third-party blind spike samples show relatively high variability for a greater number of pesticides, although these results likely reflect the influence of degradation and (or) differences in the magnitude and variability of concentrations used for blind spikes relative to laboratory reagent spikes. Detailed analysis of variability using field replicate data is possible for only 12 pesticides on S2437; low variability in analyte detection and concentration is indicated for most of these pesticides in groundwater.

Scientific Investigations Report↗

Numerical modeling of groundwater flow in the crystalline-rock aquifer in the vicinity of the Savage Municipal Water-Supply Well Superfund site, Milford, New Hampshire

In 2010, tetrachloroethylene (PCE), a chlorinated volatile organic compound, was detected in groundwater from deep (more than 300 feet below land surface) fractures in monitoring wells tapping a crystalline-rock aquifer. The aquifer underlies the Milford-Souhegan glacial-drift aquifer, a high water-producing aquifer, and the Savage Municipal Water-Supply Well Superfund site in Milford, New Hampshire. Between 30 and 40 residential water-supply wells are near (0.25 mile north of) the PCE-contaminated monitoring wells. Some of the residential water-supply wells are likely installed in similar rock types and formations as those of the monitoring wells installed as part of the Superfund site. As of 2020, periodic sampling by the U.S. Environmental Protection Agency and New Hampshire Department of Environmental Services (cooperative partners for this study) since 1996 had not detected PCE in groundwater from the residential water-supply wells. Nevertheless, understanding the vulnerability of the residential water wells to capture PCE contaminated groundwater was of concern. A numerical groundwater flow model was developed by the U.S. Geological Survey to assess groundwater flow and advective transport of PCE-contaminated groundwater in the crystalline-rock aquifer of the Milford area. The model (called the area-wide model) encompasses a 26.5-square mile area to allow for more accurate computation of water fluxes near the PCE-contaminated monitoring wells and the residential water wells. Simulations with the area-wide model show that, with the 2016 configuration of residential wells, capture of PCE by the residential water wells appears unlikely for hydrologic conditions typical of 2010 based on steady-state, advective transport modeling. However, simulations also show that adding residential water wells to the north of the PCE-contaminated monitoring wells could affect the transport of PCE. Groundwater withdrawals at other adjacent wells in the overlying Milford-Souhegan glacial-drift aquifer affect advective transport in the crystalline-rock aquifer. Therefore, the potential for future changes in withdrawals in the area, as well as changes in hydrologic conditions, including groundwater recharge and streamflow amounts, should be considered in the remedial assessment process. The development of the area-wide model and linkages established by this study with previously developed Milford-Souhegan glacial-drift aquifer transport models will help facilitate the development of remedial strategies for this Superfund site.

New Hampshire↗