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A framework for integrating spatiotemporal deep learning methods with landsat for annual land cover and impervious surface mapping

Land cover information is essential for understanding Earth’s surface dynamics and how vegetation, water, soil, climate, and terrain interact. The National Land Cover Database (NLCD) has been the authoritative source for consistent U.S. land cover mapping. To extend NLCD’s temporal resolution and reduce production latency, we developed the Land Cover Artificial Mapping System (LCAMS)—a prototype spatiotemporal deep learning framework piloted as the foundation for the new Annual NLCD. LCAMS builds on concepts from legacy NLCD and the U.S. Geological Survey Land Change Monitoring, Assessment, and Projection (LCMAP) initiatives. It employs a loosely coupled two-stage architecture consisting of independent but functionally interdependent spatial and temporal models. Spatial models extract per-year information from Landsat data, while the temporal models refine the spatial outputs to enforce inter-annual consistency—critical for reliable land change monitoring. LCAMS produces annual 30 m resolution land cover and impervious surface outputs, with region-specific fine-tuning to generalize across diverse landscapes and temporal dynamics. Validation was conducted using an independent dataset of 1925 randomly sampled plots from five U.S. Landsat Analysis Ready Data (ARD) tiles spanning 1985-2021, selected for spatial and temporal variability. This dataset was used consistently to evaluate LCAMS, Legacy NLCD, and LCMAP. Using the NLCD legend, LCAMS achieved 72.1 ± 1.60% overall agreement, compared to 71.1 ± 1.7% agreement for Legacy NLCD. Using the LCMAP legend, LCAMS achieved 83.4 ± 1.22% agreement, compared to 84.6 ± 1.11% agreement for LCMAP. Overall, LCAMS delivers comparable accuracy while offering higher thematic resolution, longer temporal coverage, and automated production of annual 30 m CONUS land cover.

Remote Sensing of Environment

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio

Fish beta diversity associated with hydrologic and anthropogenic disturbance gradients in contrasting stream flow regimes

Understanding the role of hydrologic variation in structuring aquatic communities is crucial for successful conservation and sustainable management of native freshwater biodiversity. Partitioning beta diversity into the additive components of spatial turnover and nestedness can provide insight into the forces driving variability in fish assemblages across stream flow regimes. We examined stream fish beta diversity across hydrologic and anthropogenic disturbance gradients using long-term (1916–2016) site occurrence records ( n = 17,375) encompassing 252 species. We assessed total beta diversity (Sørensen dissimilarity), spatial turnover, and nestedness of fish assemblages in contrasting stream flow regimes across a gradient of decreasing flow stability: groundwater stable ( n = 77), groundwater ( n = 67), groundwater flashy ( n = 175), perennial runoff ( n = 141), runoff flashy ( n = 255), and intermittent ( n = 63) streams. Differences in total beta diversity among the stream flow regimes were driven predominantly (>86 %) by spatial turnover (i.e. species replacement) as opposed to nestedness (i.e. species loss or gain). Total fish beta diversity and spatial turnover were highest in streams with intermediate flow stability (groundwater flashy), while more flow-stable streams (groundwater stable and groundwater) had lower turnover and higher nestedness. Species turnover was also strongly associated with seasonal variation in hydrology across all flow regimes, but these relationships were most evident for assemblages in intermittent streams. Distance-based statistical comparisons showed significant correlations between beta diversity and anthropogenic disturbance variables, including dam density, dam storage volume and water withdrawals in catchments of groundwater stable streams, while hydrologic variables were more strongly correlated with beta diversity in streams with runoff-dominated and flashy flow regimes. The high spatial turnover of species implies that fish conservation actions would benefit from watershed-focused approaches targeting multiple streams with wide spatial distribution, as opposed to simply focusing on preserving sites with the greatest number of species.

Science of the Total Envionrment

Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

The 3D Elevation Program—Supporting the economy of Massachusetts

Introduction Massachusetts extends from the mountains of the Appalachian system in the west of the State to the sandy beaches and rocky shorelines of the Atlantic coast in the east. Inland topographic data support a wide range of important activities, including geologic mapping, transportation planning, forest and wildlife management, quantifying ecological services, water supply protection, commonwealth-wide infrastructure planning, local site planning, and flood-plain management. Nearshore bathymetry can be used to support coastal portions of the Commonwealth by addressing the combined threats of ocean warming, strong storm surge, and rising sea levels. The maintenance and (or) expansion of Massachusetts ports (for instance, Boston, New Bedford) and Cape Cod sediment management depends upon the accurate mapping of bathymetry and the frequent influx of sediment and redeposition. Critical applications that address the broad range of requirements depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Massachusetts. The status of available and in-progress 3DEP baseline lidar data in Massachusetts is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.23 million in new benefits annually to Massachusetts. The top 10 Massachusetts business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Massachusetts

Spatio-temporal modeling for assessing geoenergy resources: A workflow applied to gas in place variation in coal beds

The ability to estimate spatio-temporal changes in hydrocarbon reservoir properties and energy resources within pore volumes is essential for optimizing production, reservoir management, geologic energy storage, and safety in underground mining operations. In coal seams, predicting remaining methane gas-in-place (GIP) is critical for quantifying producible gas and improving mine safety and productivity through effective ventilation planning. Although such changes are commonly evaluated using physics-based numerical simulation models, these approaches often require extensive data, calibration effort, and time. This study presents a spatio-temporal geostatistical modeling approach that bridges the gap between purely spatial models and full numerical simulations. The method is applied to a case study of coal seam degasification in the Mary Lee coal group, Black Warrior Basin, Alabama, USA, to estimate GIP evolution over time within a selected mining district. The analysis uses published data from prior natural gas production history-matching of degasification using vertical wells. Empirical spatial and temporal statistics were calculated for reservoir pressure and water saturation, and spatio-temporal variogram models were fitted to experimental variograms. These models provided the structural basis for spatio-temporal kriging, integrated with spatial estimates of time-invariant parameters (porosity, density, and thickness) to estimate GIP. This approach enabled estimation of GIP changes over time, including periods without data. Boxplots of GIP estimates indicated systematic depletion and decreasing spatial variability, reflecting the impacts of degasification. Comparison with cumulative gas production from empirical well records showed approximately 85% agreement based on a relative similarity metric. Spatio-temporal GIP estimates were also used to estimate methane emissions to longwall ventilation systems and compared with reported emissions from the U.S. EPA Greenhouse Gas Reporting Program, showing similar distributions (≈80%) given data limitations. Overall, this integrated modeling approach provides time-dependent GIP estimates with broader implications for resource assessment applications.

Alabama

Geochemical and hydrological investigations of historical data collected at the Lee Acres Landfill and Giant Bloomfield Refinery, New Mexico, 1985–2020

The Lee Acres Landfill and Giant Bloomfield Refinery are adjacent properties near the City of Farmington, New Mexico, each having undergone monitoring and remediation related to historical site activities. At the landfill, site cleanup has included the installation of a capillary barrier over former liquid waste lagoons and periodic monitoring of groundwater elevations and groundwater quality. At the refinery, remediation has focused on several petrochemical and crude oil release areas and included soil excavation, groundwater treatment, and regular monitoring of groundwater elevations and quality. Groundwater at both sites has higher concentrations of volatile organic compounds and trace metals than background aquifer concentrations. In 2022, the U.S. Geological Survey compiled the Lee Acres-Giant Bloomfield Refinery Database (LAGBRD), which contains publicly available groundwater-elevation data and organic and inorganic groundwater-quality data from both sites, spanning from 1985 to 2020. Data from the LAGBRD and precipitation data from other sources were used to better understand the cause of relatively high manganese concentrations observed in some groundwater wells at the site through comparison of groundwater chemistry to chemical end members, interpretation of spatial and temporal patterns in the groundwater chemistry, and interpretation of groundwater flow properties. In this study, elevated chloride concentrations in groundwater downgradient from the landfill have been attributed to landfill leachate based on the temporal and spatial variability of chloride concentrations and chloride-to-bromide ratios. Installation of a capillary barrier and surface-water runoff controls at the landfill in 2005 appears to have altered infiltration patterns at that site, resulting in a decrease in chloride at some wells but an increase in chloride and dissolved manganese at others. The timing and relation among groundwater elevation, chloride concentration, and manganese concentration suggest that leachate stored in the vadose zone provides a continued source of contamination to groundwater.

New Mexico

Predicting hydrothermal reservoir depth from chemical geothermometers using a three-dimensional temperature model in the Great Basin, USA

Recent work in the Great Basin region of the western United States has made it possible to predict the depth of hydrothermal reservoirs (i.e., the depth at which heat is accumulated prior to ascent via hydrothermal upflow) identified through geochemistry and to contextualize the spatial patterns of these reservoir depths. Chemical geothermometers use the chemical and mineral constituents of hydrothermal fluids to predict the temperature at which fluids equilibrated with the host rocks at depth. Assuming that most of the Great Basin is dominated by conductive conditions until a vertically connected hydrothermal flow path is created (e.g., by faulting), geothermometers reflect the chemical and thermal conditions at the depth interval that the fluid has conductively equilibrated over a long period before a vertical conduit allows convective upflow. By pairing geothermometer temperature estimates with our recent three-dimensional temperature model of conductive heat flow in the Great Basin, we estimate the corresponding reservoir depths and construct a map of circulation depths. The predicted depths from geothermometers have spatial patterns across the Great Basin that relate to patterns seen in other geologic and geophysical data. Deeper springs generally occur disproportionately in areas with higher strain rates and in basins. We posit that current elevated strain rates reflect patterns of historic deformation where ongoing tectonic activity maintains permeable pathways to deeper reservoirs, some of which are estimated to exceed 6 km depth. Basins, as expected, contain a disproportionate number of these deep systems, because the underlying aquifers are closer to the surface in basins, thus requiring less water pressure to reach the surface than in mountain ranges. Most springs estimated to have their source in a deep reservoir occur at places known to host a hydrothermal system; these refined depth estimates of the source reservoir can help to better constrain the source depth for many known hydrothermal systems across the Great Basin.

Arizona, California, Idaho, Nevada, Oregon, Utah

Seismic techniques and suggested instrumentation to monitor volcanoes

Introduction Changes in the pressure or location of magma can stress or break surrounding rocks and trigger flow of nearby waters and gases, causing seismic signals, such as discrete earthquakes and tremor. These phenomena are types of seismic unrest that commonly precede eruption and can be used to forecast volcanic activity. Mass movements at the surface, including avalanches, debris flows, and lahars, may also generate seismic signals that are specifically addressed in chapter H , this volume (Thelen and others, 2024). Our focus in this chapter is to determine the levels of instrumentation recommended to produce high-quality, well-constrained seismic observations important for early warning of impending eruptions, detecting changes in ongoing eruptions, and characterizing other hazardous volcanic events. There are emerging techniques and new types of instrumentation, such as distributed acoustic sensing or rotational seismometers, that we do not consider here. These types of instrumentation show promise for monitoring but still require maturation before being considered more generally in volcano monitoring. Most of the capabilities mentioned below are universal for all types of volcanic systems, although some are best applied to stratovolcanoes with an apical single vent. In some settings, such as calderas or shield volcanoes, we must broaden coverage to include multiple possible storage regions or vent locations. As an example, Thelen (2014) discretized the long rift zones of shield volcanoes in Hawaiʻi as a set of evenly spaced “vents.” In this construct, each vent comes with recommendations, and several thousand network configurations were simulated to assess the effect on network quality levels and to determine the most efficient network design. The same process could be applied in a caldera setting or a volcanic field, where an evenly spaced grid of potential vents is considered. Localized recommendations for each unique system are beyond the scope of this report and left up to local experts to assess based on the conditions, restrictions, and requirements of each volcano.

Scientific Investigations Report

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters

Groundwater drought in the United States: Spatial and temporal variability

Many communities and ecosystems in the United States that are dependent on groundwater are potentially adversely affected by groundwater drought. We computed yearly groundwater-drought metrics and mean groundwater levels at well locations across the conterminous United States (CONUS), using data from wells and remotely sensed and modeled Gravity Recovery and Climate Experiment Drought Monitor Data Assimilation (GRACE-DADM). We also modeled the probability of low or high human impact at each well location. The spatial distribution of groundwater-drought duration and severity from 2001 to 2020 for 1,510 wells shows longer maximum duration and higher maximum severity events in drier regions like the Southwest than in wetter regions like the Northeast. Based on 613 wells in CONUS from 1981 to 2020, there are many significant decreases in drought duration and severity in the Northeast and many significant increases in annual-mean groundwater levels. In contrast, there are many significant increases in drought metrics and decreases in mean water levels in parts of the Southeast. There are major differences in trends from 2001 to 2020 between well-based and GRACE-DADM-based groundwater metrics in some CONUS regions and a very low correlation between trends at individual locations across CONUS. A potential reason for this disparity is the low GRACE-DADM resolution (∼12 km) and the potential for a large amount of groundwater variation at the local scale. Also, GRACE-DADM represents shallow, unconfined aquifers which may not match the screened interval of the monitoring wells we evaluated. Large spatial gaps in long-term, high frequency, and quality-assured groundwater-well monitoring data present a challenge for understanding groundwater-drought variability across CONUS. Remote sensing tools such as GRACE can help but cannot fully replace well monitoring, as highlighted by our study results. Substantially more long-term monitoring wells would more accurately represent groundwater-drought trends and spatial variability across CONUS, particularly in western regions.

conterminous United States

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

Time-varying rates of organic and inorganic mass accumulation in southeast Louisiana marshes: Relationships to sea-level anomalies and tropical storms

Louisiana's coastal wetlands are complex systems that require a continuous input of organic and inorganic material to keep pace with relative sea-level rise. Coastal restoration projects such as sediment diversions are being implemented to mitigate land loss and increase availability of inorganic sediment to coastal wetlands, and marshes specifically rely on organic material to build soil volume and maintain surface elevation. Interannual-to-decadal sea-level anomalies such as hurricanes can affect marsh accretion, mineral deposition, and plant productivity. In this light, complex ecogeomorphic feedback controls whether a marsh surface is sustainable or eroded/drowns. This study performs some of the first differential vertical accretion rates (VARs) and organic and inorganic mass accumulation rates (MARs) over time in SE Louisiana marshes determined from the 210 Pb Constant Rate of Supply model, coupled with standard 137 Cs VARs. These accumulation rates over the past ∼100 years were measured from a total of six brackish and salt marsh locations in Barataria Basin near the proposed Mid-Barataria Sediment Diversion. They were then related to interannual sea-surface elevations at Grand Isle, Louisiana, over the last ∼60 years and recorded hurricane activity in the delta. Results show VARs range from 0.63 cm/y to 1.69 cm/y and total MARs range from 0.11 to 0.43 g/cm 2 /y. Temporally, VARs and MARs (total, inorganic, and organic) are characterized by gradual increases in rates with decreasing age along with episodic peaks in VARs and MARs. The findings of this study indicate that no relationship occurs between sea-level anomalies and VARs or organic and inorganic MARs; however, a strong relationship appears to occur between major hurricanes to VAR and MAR contributions. Furthermore, high water content (81 ± 8%) and organic-rich soils in the sediment cores highlight the significance of belowground biomass and associated pore volume in maintaining marsh elevation in the study area.

Louisiana

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment

Evaluating mass flow meter measurements from chambers for greenhouse gas emissions from orphan wells and other point sources

This study evaluates the performance of a rigid gas flux chamber equipped with a mass flow meter (MFM) for measuring gas emissions from leaking orphan wells and similar pressure-driven gas point sources. We conducted a series of laboratory and field experiments to evaluate the sensitivity, stability, and dynamic range of an MFM chamber system and found an optimal method for sealing the chamber to the ground to isolate the emission source. From these results, we estimate the effects of different soil gas permeabilities on measurements and identify the uncertainty of environmental processes that can impact measurements. Simulations of an MFM chamber are compared to those of a dynamic flux chamber to contrast the data derived with both methodologies and illustrate the potential for measuring high variability leaks with the MFM chamber. Using a low flow resistance MFM and a chamber well-sealed to the ground, it is possible to measure leaks down to 1.08 x 10 -3 cubic meters per hour (m 3 h −1 ) (refenced to 25°/1 atm), corresponding to 0.77 grams per hour (g h −1 ) methane or 2.11 g h −1 carbon dioxide, with a mean uncertainty of 0.89 % relative standard deviation. Environmental processes such as heated gas inside the chamber from solar gain, wind blowing across the chamber vent, and changing humidity in the chamber, can cause variation in MFM measurements. Over 11 d of continuous monitoring under varying weather conditions, the standard deviation of the environmentally sourced signals was found to be 7.40 x 10 -3 m 3 h −1 (equivalent to or 5.27 g h −1 methane or 14.45 g h −1 carbon dioxide). Strategies to obtain the highest quality data from MFM chambers include burying the edges of the chamber below the surface sufficiently deep to seal the chamber edges against gas flow and soaking the dirt with water to lower the chances of escaping gases, while monitoring the gas flow and adjusting the chamber seal to achieve a maximum flow rate.

Atmospheric Measurement Techniques

3-D geological modeling for numerical flow simulation studies of gas hydrate reservoirs at the Kuparuk State 7-11-12 Pad in the Prudhoe Bay Unit on the Alaska North Slope

Accurate reservoir evaluation requires reliable three-dimensional (3-D) geological models. This study conducted 3-D geological modeling for numerical flow simulation of the B1 sand gas hydrate reservoir at the Kuparuk State 7-11-12 pad, Prudhoe Bay Unit, Alaska North Slope. The model integrates well logs, core, and seismic data to address spatial heterogeneity in geological structures and reservoir properties. Two modeling types were performed: structural framework modeling and petrophysical property modeling. For structural framework modeling, seismic data and well log markers were used to reproduce subsurface structures characterized by a normal fault system. A volume-based modeling algorithm and stair-step gridding were applied. The resulting 3-D model comprised 2,640,000 grid cells across 264 layers, including seven fault grids. For petrophysical property modeling, total porosity was initially modeled using sequential Gaussian simulation with collocated cokriging. To reproduce the upward coarsening of the B1 sand, upscaled log-derived total porosity and a 3-D trend depicting total porosity variation were used as primary and secondary data, respectively. Gas hydrate saturation distribution was modeled similarly, with secondary data from estimated porosity distribution and seismic-derived acoustic impedance map enhancing accuracy. Results indicate higher gas hydrate saturation in the upper part of the B1 sand and areas with higher acoustic impedance. Intrinsic permeability was modeled from the total porosity and clay-bound water volume, and effective permeability was derived from the gas hydrate saturation and intrinsic permeability distributions based on the “Tokyo model”. Effective permeability distributions were influenced by the total porosity, gas hydrate saturation, and intrinsic permeability. Within the same layer, higher gas hydrate saturation leads to decreased effective permeability. In total, 100 sets of multiple scenarios were prepared, providing input data for dynamic flow simulations to evaluate the effects of lateral heterogeneity in reservoir properties and the hydraulic characteristics of faults on production behavior for preassessment before the long-term production test.

Alaska