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A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream

Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.

Iowa

Groundwater-level elevations in the Denver Basin bedrock aquifers and Upper Black Squirrel Creek alluvial aquifer, El Paso County, Colorado, 2021–24

El Paso County is the second-most populous county in Colorado and is projected to grow another 15 percent by 2030. Within El Paso County is the Upper Black Squirrel Creek Designated Groundwater Basin (Black Squirrel Basin), an area where surface water is scarce and water users rely primarily on groundwater from five different aquifers (the Upper Black Squirrel Creek alluvial aquifer and four bedrock aquifers within the Denver Basin aquifer system: the lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) to meet their needs. Currently (2024), land within the Upper Black Squirrel Creek Basin is primarily used for rural grazing and agriculture; however, municipal development is ongoing. In 2021, the U.S. Geological Survey, in cooperation with the Upper Black Squirrel Creek Ground Water Management District, began a study to establish a baseline dataset and assess the groundwater resources of the aquifers within the Black Squirrel Basin. A network of 39 wells was established in 2021; discrete groundwater-level measurements were made bimonthly. Nine of the 39 wells were equipped with pressure transducers to record hourly groundwater-level data. Seven wells had statistically significant seasonal trends, and trends at 3 wells were negative. For the discrete data, 16 wells had a significant trend for the study period, and 4 wells had negative trends. For the time-series data, 8 wells had significant trends, and 3 wells had negative trends. Potentiometric surface maps were created for this study using discrete, static groundwater levels measured in April 2023. These maps showed the estimated groundwater flow direction from the north-northwest to the south-southeast in the alluvial aquifer and from the northwest to the east-southeast for the lower Dawson and Denver aquifer wells. This study indicates the potential benefit of monitoring wells in the areas near municipal pumping. Additional monitoring could lead to a better understanding of connectivity between aquifers and be an important tool for assessing long-term sustainability of groundwater use.

Colorado

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida

Data gap analysis for estimation of agricultural return flows in the Upper Gunnison River Basin, Colorado

The Gunnison River and many tributaries in the Upper Gunnison River Basin provide water to irrigate agricultural crops. The application of irrigation water can recharge some aquifers locally by water percolating below the root zone and eventually flowing back to the stream or river through the subsurface. Diverting surface water for irrigation reduces streamflow during the irrigation season but can provide temporary storage of water and supplement streamflow after the snowmelt runoff season. Understanding the timing and quantity of agricultural return flows could help resource managers make informed decisions and adapt to potential changes in water management and availability that could affect irrigation practices. In 2024, the U.S. Geological Survey, in cooperation with the Upper Gunnison River Water Conservancy District, began a study to characterize agricultural return flows in the Upper Gunnison River Basin by using endmember mixing analysis and developing a groundwater model. Both approaches require data from multiple sources, but data gaps exist in the East River study reach and other reaches of interest (Ohio Creek, Tomichi Creek, and Cochetopa Creek). The East River Basin, which is the initial focus of the study, has fewer data gaps than the other basins. Data gaps could be addressed by installing additional surface water and groundwater monitoring sites, making regular streamflow measurements on tributaries, and completing tests to characterize local aquifer properties.

Colorado

Impact of land subsidence on housing sale values: Evidence from the San Joaquin Valley, California

This study assesses the impact of land subsidence on housing sale values in the San Joaquin Valley, California. The study utilizes home sale transactions and vertical land-surface displacement data from Interferometric Synthetic Aperture Radar techniques. Using fine-scale fixed effects, matching, as well as a repeat-sales approach, our results indicate that land subsidence resulted in a 2.4% to 5.8% reduction in housing sale values, with the largest reductions occurring in areas where substantial subsidence occurred. Such findings may have implications for groundwater management and can potentially help inform policy design to help mitigate the causes and impacts of land subsidence.

California

Simulated ground-motion records for the seismic assessment of monumental masonry structures

Earthquakes are natural disasters that can cause widespread devastation and loss of life. Simulated ground-motion records can be useful in regions with limited seismic stations or a history of damaging but infrequent earthquakes. This is especially true in areas with a high concentration of heritage masonry structures, which are especially susceptible to damage, as simulated records can be crucial in predicting their seismic response and protecting these buildings from seismic damage. Despite the importance of simulated earthquakes, few studies have investigated how effective they are compared to real earthquakes when assessing the structural response of heritage buildings. To address this knowledge gap, we employ two different simulation methods of the Mw 6.2 Faial earthquake, which occurred on July 9th, 1998, in the Azores, to replicate the recorded time-series at four available stations within an epicentral distance of 150 km. The study has two objectives: first, to validate the simulated records of the 1998 Faial earthquake using alternative stochastic ground-motion simulation approaches, and second, to determine how these approaches impact the seismic assessment of historic masonry structures. To accomplish these objectives, this study uses real and simulated ground-motion datasets to conduct non-linear response history analyses of the São Francisco Church, a monumental structure in Horta that sustained damage during the Faial earthquake. The results show that both simulation approaches yield structural responses similar to the observed records.

Conference Paper

Utilization of stochastic ground motion simulations for scenario-based performance assessment of geo-structures

Probabilistic seismic performance assessments of engineered structures can be highly sensitive to the seismic input excitation and its variability. In the present study, the scenario-based performance assessment recommended by Federal Emergency Management Agency (FEMA) P-58 guidelines is adopted to estimate seismic fragility of concrete dams for various seismic hazard scenarios. Due to the scarcity of recorded ground motions and thereby their poor representation of uncertainties, stochastic ground motion simulation methods are utilized to obtain the required input excitations. Moreover, to understand the uncertainty in ground motion simulation models, two broadband stochastic simulation models are used to generate input excitations representing six seismic hazard scenarios defined by earthquake magnitude, source-to-site distance, and soil conditions. Optimal intensity measure parameters for each scenario are identified using a systematic procedure that considers criteria such as efficiency, practicality, proficiency, sufficiency, and hazard compatibility. Fragility curves and surfaces are derived using the cloud analysis technique, taking into account various damage measures and limit state functions. The study finds that the derived fragility curves are particularly sensitive to the selection of earthquake scenarios, the choice of records, and the methods used to calculate fragility curves, with less sensitivity observed to different engineering demand parameters. Given this sensitivity, particularly to ground motion selection, the study highlights the necessity of incorporating both model-to-model variability (epistemic uncertainty) and record-to-record variability (aleatory uncertainty), alongside the established material and modeling uncertainties, in the probabilistic seismic assessment.

Reliability Engineering and System Safety (RESS)

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within Hays County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018 within Hays County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in Hays County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic framework and hydrostratigraphic units (HSUs) in the study area. The study includes updates to the interpretation of the Kainer Formation of the Edwards Group with the addition of a burrowed unit between the basal nodular and dolomitic members. Hydrostratigraphy was also updated with the addition of the Seco Pass HSU for the burrowed member of the Kainer Formation. The study also includes updates to the interpretation of the hydrostratigraphy of the Trinity aquifer with the addition of the cavernous HSU at the top of the upper zone of the Trinity aquifer and the Herff Falls HSU between the Bulverde and Rust HSUs of the middle zone of the Trinity aquifer. This updated report provides additional information about a complex aquifer system. The complexity in the aquifer system results from a combination of the original depositional history, bioturbation, development of primary and secondary porosity, postdepositional diagenesis, fracturing, and faulting.

Texas

Characteristics of the fault damage zone From high-resolution seismic imaging along the Palos Verdes Fault, California

The distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in-situ distribution of fault damage remain limited and along-strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub-bottom profiles. The combination of high-resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi-trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

California

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas

Induced earthquakes are generally not tidally triggered in Oklahoma and Kansas

Human-induced earthquakes occur along critically stressed faults as injected wastewater simultaneously heightens fluid pressure and pushes faults to failure. We investigate the possibility that small stresses imposed by Earth tides could trigger earthquakes in the induced seismicity region of Oklahoma and Kansas from 2011 to 2018. We decluster a catalog consisting of ∼110,000 earthquakes using three methods (Reasenberg, nearest-neighbor distance, and phase-bin). We find no significant tidal earthquake triggering using Schuster's p -value test for the declustered catalogs as a whole. We search for localized triggering using discretized space-time cells and find ∼0–6% of cells have significant tidal triggering which is close to what is randomly expected (5%) and indicates there is an insignificant amount of tidal triggering for the full study region. One area that has significant p -values across multiple time windows, ∼2014–2016 is ∼15 km from a region of large wastewater injection volume. It is possible that localized tidal triggering occurs for this time and area because faults remain critically stressed and are particularly susceptible to slip under the small stress load from the semidiurnal tide. Possible explanations for the lack of tidal triggering in our broader study are that the pre-seismic stressing rate in the earthquake nucleation area is faster than the tidal stressing rate (∼3 kPa/day), faults are not close enough to critically stressed to be affected by tidal forcing, and that nucleation occurs over longer periods than the tides considered in this study (∼1, ∼14 days). Fluid injection could be the source of a higher pre-seismic stress rate.

Kansas, Oklahoma

A history of cryohydrogeology modeling and recent advancements through the integration of solute transport

Groundwater flow systems and permafrost are interrelated because permafrost thaw enhances permeability, while groundwater flow can advect heat and accelerate permafrost thaw (McKenzie et al. 2021). Given amplified climate change in cold regions, there is renewed interest in ‘cryohydrogeology’, the study of groundwater in cold regions. Many data-driven studies have shown that permafrost thaw is leading to activated aquifers and increased baseflow across the pan-Arctic region (e.g. Walvoord and Striegl 2007, Evans et al. 2020). Empirical evidence of a subsurface ‘replumbing’ (Walvoord and Kurylyk 2016) in permafrost regions raises questions about the fate of sequestered contaminants in the North (Langer et al. 2023). We will discuss the history of and emerging opportunities in cryohydrogeological modeling, with a focus on recent contaminant transport modeling.

Conference Paper

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida

Channel morphology and large wood control postfire debris-flow erosion and deposition

Runoff-generated debris flows are a known response to wildfire, and accurately predicting the volume of these debris flows is important for estimating the magnitude of downstream hazards. Prior data collection efforts have focused on debris-flow volume measurements at catchment outlets, but few studies have considered how erosion and deposition modulate the volume of sediment arriving at catchment outlets. This study takes advantage of a high-resolution dataset to document the factors that control the total debris-flow volume reaching the catchment outlet during a fatal postfire debris flow. Using pre- and post-event airborne lidar, satellite imagery and field mapping, we found that a postfire debris flow in the Black Hollow catchment in northern Colorado eroded 136,000 ± 30,000 m 3 and redeposited 27,000 ± 7,500 m 3 in the main channel. Most of the in-channel deposition (52% by volume) occurred where a confined channel reach transitioned to an unconfined channel reach downstream, allowing the flow to widen and deposit material. Wood jams played multiple roles in the debris-flow dynamics, both nucleating deposition (25% of the deposit volume was stored behind wood jams) and exacerbating erosion (50% of the total erosion occurred downstream from a wood dam break). The remaining deposition occurred due to spatial changes in channel slope as well as deposition observed at newly formed channel bars. Using these data in this study, we identified topographic and vegetation metrics that can be used (pre-event) to anticipate where deposition may occur in channels prior to a debris flow.

Colorado

Land application of drill waste: A scope analysis

Drilling fluid waste land application, a process where drilling wastes are spread and tilled into the land surface, has become common in some petroleum-producing states, however, the potential benefits and risks of this practice are not well studied. Drilling fluids can be water- or oil-based and can have high concentrations of total soluble salts and total petroleum hydrocarbons. Comprehensive chemical characterization of these fluids is not well documented in the literature, and the extent of land application is largely unknown. We hypothesized that the land application of drill waste would fluctuate over time due to economic factors. To begin to understand the extent of historical and potential future land application, we analyzed data from over 5,800 drilling fluid land application permits collected by the Oklahoma Corporation Commission for years 2000, 2005, 2010, and 2015–2020. During the years studied, drilling fluid wastes were applied to more than 250,000 acres in Oklahoma, with over 54,000 thousand barrels (Mbbl) of liquids and nearly 21,000 Mbbl of solids applied. Land application is widespread (occurring in 59/77 counties), however recent drilling activity, land availability, and the economics of transportation have created conditions favorable for land application specifically in the Anadarko Basin. Land application can co-occur with sensitive areas, such as important groundwater and surface-water drinking sources and agricultural fields used for subsistence or feed crop production. Our approach for quantifying the extent of land application, along with further chemical characterization studies, can aid operators and land managers who are considering this practice in assessing the associated benefits and risks.

Oklahoma

Selected water-quality data from the Cedar River and Cedar Rapids well fields, Cedar Rapids, Iowa, 2017–22

The Cedar River alluvial aquifer is the source of drinking water in Cedar Rapids, Iowa. Production wells are completed in the alluvial aquifer approximately 40 to 80 feet below land surface. The City of Cedar Rapids and the U.S. Geological Survey have studied the groundwater-flow system and water quality of the aquifer in the vicinity of Cedar Rapids since 1992. Results of these studies documented hydrologic conditions, water quality, and geochemistry of the alluvial aquifer and interactions with the Cedar River. Water-quality samples were collected for studies involving well field monitoring, trends, source-water protection, groundwater geochemistry, surface-water–groundwater interaction, and pesticides in groundwater and surface water. Water quality was analyzed for dissolved major ions (boron, bromide, calcium, chloride, fluoride, iron, magnesium, manganese, potassium, silica, sodium, sulfate, and total dissolved solids), dissolved nutrients (ammonia as nitrogen, ammonia plus organic nitrogen as nitrogen, nitrite plus nitrate as nitrogen, nitrite as nitrogen, orthophosphate as phosphorus, and phosphorus), dissolved organic carbon, and selected pesticides. Physical characteristics (alkalinity, dissolved oxygen, pH, specific conductance, and water temperature) were measured on site and recorded for each water sample collected. This report presents the results of routine water-quality data-collection activities from October 2017 through September 2022. Methods of data collection, quality assurance, water-quality analyses, and statistical procedures are presented. Data include the results of water-quality analyses from quarterly sampling from monitoring wells, production wells, two water treatment plants, and the Cedar River at Blairs Ferry Road at Palo, Iowa, streamgage (U.S. Geological Survey station number 05464420), as well as monthly nutrient sampling from the Cedar River and Morgan Creek near Covington, Iowa, streamgage (U.S. Geological Survey station number 05464475).

Iowa

Geospatial PDF map of the compilation of GIS data for the mineral industries of select countries in the Indo-Pacific region

Introduction In 2024, the U.S. Geological Survey's (USGS) National Minerals Information Center (NMIC) completed the project titled "Compilation of geospatial data for the mineral industries of select countries in the Indo-Pacific." This project aimed to leverage the expertise and capabilities of the NMIC to collect, synthesize, and interpret geospatial data to inform on the extractive resources of select countries in the Indo-Pacific region (area of study) and expand the NMIC's understanding on the impact of mineral industry of these countries in the global economy. The 19 countries of interest in the Indo-Pacific study area include Bangladesh, Bhutan, Brunei, Burma, Fiji, Malaysia, Mongolia, Nauru, New Caledonia, New Zealand, Papua New Guinea, Philippines, Singapore, Solomon Islands, South Korea (Republic of Korea), Sri Lanka, Taiwan, Timor-Leste, and Vietnam. The primary objective of this effort was to create a fully attributed Geographic Information System (GIS) portraying existing mining infrastructure, resources, and production capacities across the Indo-Pacific study area as well as highlight mineral production and processing sites under development and potential areas of future extractive industry operations and development in the region. The compiled GIS geodatabase with supporting documentation including comprehensive metadata was published as a USGS data release titled "Compilation of Geospatial Data (GIS) for the Mineral Industries of Select Countries in the Indo-Pacific." This georeferenced portable document format (GeoPDF) map sheet presents a new geographic information product containing a partial representation of the GIS data. This GeoPDF map provides a visual comparison of the distribution of mineral industry GIS data, which contributes to a deeper understanding of the intersections and complexities of the extractive industries within the select countries in the Indo-Pacific region.

Open-File Report

Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24

The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.

Scientific Investigations Report