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Selected data from field studies of pesticide runoff to surface waters

Citations from the scientific literature for studies that quantified selected pesticides in field runoff or streams were obtained from two computerized bibliographic databases: Chemical Abstracts and AGRICOLA. Selected data were extracted from studies in field environments that lasted longer than a day and are summarized here. The data extracted from each article, if available, include pesticide information, environmental setting, year of study, and the mass of the pesticide in runoff as a percent of the mass applied. Data from two national studies of pesticides in surface waters done by the U.S. Geological Survey (National Water-Quality Assessment Program, 1992?1995, and National Stream-Quality Accounting Network, 1996-1998) also are summarized.

Water-Resources Investigations Report↗

Investigation of Ground-Water Availability and Quality in Orange County, North Carolina

A countywide inventory was conducted of 649 wells in nine hydrogeologic units in Orange County, North Carolina. As a result of this inventory, estimates of ground-water availability and use were calculated, and water-quality results were obtained from 51 wells sampled throughout the County from December 1998 through January 1999. The typical well in Orange County has an average depth of 208 feet, an average casing length of 53.6 feet, a static water level of 26.6 feet, a yield of 17.6 gallons per minute, and a well casing diameter of 6.25 inches. The saturated thickness of the regolith averages 27.0 feet and the yield per foot of total well depth averages 0.119 gallon per minute per foot. Two areas of the County are more favorable for high-yield wells—a west-southwest to east-northeast trending area in the northwestern part of the County, and a southwest to northeast trending area in the southwestern part of the County. Well yields in Orange County show little correlation with topographic or hydrogeologic setting. Fifty-one sampling locations were selected based on (a) countywide areal distribution, (b) weighted distribution among hydrogeologic units, and (c) permission from homeowners. The list of analytes for the sampling program consisted of common anions and cations, metals and trace elements, nutrients, organic compounds, and radon. Samples were screened for the presence of fuel compounds and pesticides by using immuno-assay techniques. Dissolved oxygen, pH, temperature, specific conductance, and alkalinity were measured in the field. The median pH was 6.9, which is nearly neutral, and the median hardness was 75 milligrams per liter calcium carbonate. The median dissolved solids concentration was 125 milligrams per liter, and the median specific conductance was 175 microsiemens per centimeter at 25 degrees Celsius. Orange County ground water is classified as a calcium-bicarbonate type. High nutrient concentrations were not found in samples collected for this study. Nitrate was detected in 82 percent of the samples at concentrations ranging up to 7.2 milligrams per liter, although the median concentration was 0.49 milligram per liter; all other samples had a concentration of 2.9 milligrams per liter or less. In general, trace elements were detected infrequently or at concentrations less than State drinking-water standards. However, exceedances of North Carolina drinking-water standards were observed for iron (3 exceedances of 51 analyses, detection up to 1,100 micrograms per liter), manganese (12 exceedances of 51 analyses, detection up to 890 micrograms per liter), and zinc (4 exceedances of 31 analyses, detection up to 4,900 micrograms per liter). Lead was detected in 8 of 31 samples with a concentration up to 3.5 micrograms per liter. Zinc, manganese, iron, and copper were the most frequently detected trace metals at 100, 94, 80, and 61 percent, respectively. Lead, arsenic, bromide, alum inum, and selenium were detected in 13 to 26 percent of the analyses. No benzene, toluene, ethylbenzene, and xylene (BTEX) or atrazine compounds were detected in any of the samples. Radon activities in ground water can be high because of the rock units present in Orange County. Radon activity ranged from 38 to 4,462 picocuries per liter countywide, with a median activity of 405 picocuries per liter. Median radon activities in Orange County were highest in felsic rocks (487 picocuries per liter) and lowest in mafic rocks (357 picocuries per liter). When evaluated by individual hydrogeologic units, the median radon activity was highest in the phyllite unit (1,080 picocuries per liter in 2 samples) and the felsic metaigneous unit (571 picocuries per liter in 13 samples). Overall, water-quality data in Orange County indicate few drinking-water concerns. No organic contaminants analyzed (total BTEX and atrazine) or excessive nutrient concentrations were detected, and few exceedances of North Carolina drinking- water standards were detected.

North Carolina↗

Analytical results of a long-term aquifer test conducted near the Rio Grande, Albuquerque, New Mexico, with a section on piezometric-extensometric test results

The City of Albuquerque, New Mexico, is interested in gaining a better understanding, both quantitative and qualitative, of the aquifer system in and around Albuquerque. Currently (2000), the City of Albuquerque and surrounding municipalities are completely dependent on ground-water reserves for their municipal water supply. This report presents the results of a long-term aquifer test conducted near the Rio Grande in Albuquerque. The long-term aquifer test was conducted during the winter of 1994-95. The City of Albuquerque Griegos 1 water production well was pumped continuously for 54 days at an average pumping rate of 2,331 gallons per minute. During the 54-day pumping and a 30-day recovery period, water levels were recorded in a monitoring network that consisted of 3 production wells and 19 piezometers located at nine sites. These wells and piezometers were screened in river alluvium and (or) the upper and middle parts of the Santa Fe Group aquifer system. In addition to the measurement of water levels, aquifer-system compaction was monitored during the aquifer test by an extensometer. Well-bore video and flowmeter surveys were conducted in the Griegos 1 water production well at the end of the recovery period to identify the location of primary water- producing zones along the screened interval. Analytical results from the aquifer test presented in this report are based on the methods used to analyze a leaky confined aquifer system and were performed using the computer software package AQTESOLV. Estimated transmissivities for the Griegos 1 and 4 water production wells ranged from 10,570 to 24,810 feet squared per day; the storage coefficient for the Griegos 4 well was 0.0025. A transmissivity of 13,540 feet squared per day and a storage coefficient of 0.0011 were estimated from the data collected from a piezometer completed in the production interval of the Griegos 1 well.

New Mexico↗

Shallow ground-water quality beneath rice areas in the Sacramento Valley, California, 1997

In 1997, the U.S. Geological Survey installed and sampled 28 wells in rice areas in the Sacramento Valley as part of the National Water-Quality Assessment Program. The purpose of the study was to assess the shallow ground-water quality and to determine whether any effects on water quality could be related to human activities and particularly rice agriculture. The wells installed and sampled were between 8.8 and 15.2 meters deep, and water levels were between 0.4 and 8.0 meters below land surface. Ground-water samples were analyzed for 6 field measurements, 29 inorganic constituents, 6 nutrient constituents, dissolved organic carbon, 86 pesticides, tritium (hydrogen- 3), deuterium (hydrogen-2), and oxygen-18. At least one health-related state or federal drinking-water standard (maximum contaminant or long-term health advisory level) was exceeded in 25 percent of the wells for barium, boron, cadmium, molybdenum, or sulfate. At least one state or federal secondary maximum contaminant level was exceeded in 79 percent of the wells for chloride, iron, manganese, specific conductance, or dissolved solids. Nitrate and nitrite were detected at concentrations below state and federal 2000 drinking-water standards; three wells had nitrate concentrations greater than 3 milligrams per liter, a level that may indicate impact from human activities. Ground-water redox conditions were anoxic in 26 out of 28 wells sampled (93 percent). Eleven pesticides and one pesticide degradation product were detected in ground-water samples. Four of the detected pesticides are or have been used on rice crops in the Sacramento Valley (bentazon, carbofuran, molinate, and thiobencarb). Pesticides were detected in 89 percent of the wells sampled, and rice pesticides were detected in 82 percent of the wells sampled. The most frequently detected pesticide was the rice herbicide bentazon, detected in 20 out of 28 wells (71 percent); the other pesticides detected have been used for rice, agricultural, and non-agricultural purposes. All pesticide concentrations were below state and federal 2000 drinking-water standards. The relation of the ground-water quality to natural processes and human activities was tested using statistical methods (Spearman rank correlation, Kruskal?Wallis, or rank-sum tests) to determine whether an influence from rice land-use or other human activities on ground-water chemistry could be identified. The detection of pesticides in 89 percent of the wells sampled indicates that human activities have affected shallow ground-water quality. Concentrations of dissolved solids and inorganic constituents that exceeded state or federal 2000 drinking-water standards showed a statistical relation to geomorphic unit. This is interpreted as a relation to natural processes and variations in geology in the Sacramento River Basin; the high concentrations of dissolved solids and most inorganic constituents did not appear to be related to rice land use. No correlation was found between nitrate concentration and pesticide occurrence, indicating that an absence of high nitrate concentrations is not a predictor of an absence of pesticide contamination in areas with reducing ground-water conditions in the Sacramento Valley. Tritium concentrations, pesticide detections, stable isotope data, and dissolved-solids concentrations suggest that shallow ground water in the ricegrowing areas of the Sacramento Valley is a mix of recently recharged ground water containing pesticides, nitrate, and tritium, and unknown sources of water that contains high concentrations of dissolved solids and some inorganic constituents and is enriched in oxygen-18. Evaporation of applied irrigation water, which leaves behind salt, accounts for some of the elevated concentrations of dissolved solids. More work needs to be done to understand the connections between the land surface, shallow ground water, deep ground water, and the drinking-water supplies in the Sacramento Valley.

Water-Resources Investigations Report↗

Simulation of ground-water flow in the Mojave River basin, California

The proximity of the Mojave River ground-water basin to the highly urbanized Los Angeles region has led to rapid growth in population and, consequently, to an increase in the demand for water. The Mojave River, the primary source of surface water for the region, normally is dry-except for a small stretch of perennial flow and periods of flow after intense storms. Thus, the region relies almost entirely on ground water to meet its agricultural and municipal needs. Ground-water withdrawal since the late 1800's has resulted in discharge, primarily from pumping wells, that exceeds natural recharge. To better understand the relation between the regional and the floodplain aquifer systems and to develop a management tool that could be used to estimate the effects that future stresses may have on the ground-water system, a numerical ground-water flow model of the Mojave River ground-water basin was developed, in part, on the basis of a previously developed analog model. The ground-water flow model has two horizontal layers; the top layer (layer 1) corresponds to the floodplain aquifer and the bottom layer (layer 2) corresponds to the regional aquifer. There are 161 rows and 200 columns with a horizontal grid spacing of 2,000 by 2,000 feet. Two stress periods (wet and dry) per year are used where the duration of each stress period is a function of the occurrence, quantity of discharge, and length of stormflow from the headwaters each year. A steady-state model provided initial conditions for the transient-state simulation. The model was calibrated to transient-state conditions (1931-94) using a trial-and-error approach. The transient-state simulation results are in good agreement with measured data. Under transient-state conditions, the simulated floodplain aquifer and regional aquifer hydrographs matched the general trends observed for the measured water levels. The simulated streamflow hydrographs matched wet stress period average flow rates and times of no flow at the Barstow and Afton Canyon gages. Steady-state particle-tracking was used to estimate travel times for mountain-front and streamflow recharge. The simulated travel times for mountain-front recharge to reach the area west of Victorville were about 5,000 to 6,000 years; this result is in reasonable agreement with published results. Steady-state particle-tracking results for streamflow recharge indicate that in most subareas along the river, the particles quickly leave and reenter the river. The complaint that resulted in the adjudication of the Mojave River ground-water basin alleged that the cumulative water production upstream of the city of Barstow had overdrafted the ground-water basin. In order to ascertain the effect of pumping on ground-water and surface-water relations along the Mojave River, two pumping simulations were compared with the 1931-90 transient-state simulation (base case). The first simulation assumed 1931-90 pumping in the upper region (Este, Oeste, Alto, and Transition zone model subareas) but with no pumping in the remainder of the basin, and the second assumed 1931-90 pumping in the lower region (Centro, Harper Lake, Baja, Coyote Lake, and Afton Canyon model subareas) but with no pumping in remainder of the basin. In the upper region, assuming pumping only in the upper region, there was no change in storage, recharge from the Mojave River, ground-water discharge to the Mojave River, or evapotranspiration when compared with the base case. In the lower region, assuming pumping only in the upper region, there was storage accretion, decreased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. In the upper region, assuming pumping only in the lower region, there was storage accretion, decreased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. In the lower region, assuming pumping only in the lower region, there was less storage depletion, increased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. Overall, pumping in the lower region does not negatively affect the upper region; however, pumping in the upper region negatively affects the lower region by decreasing recharge from the Mojave River. Streamflow, pumpage, and water-level data from calendar years 1995-99 were used to validate the calibrated ground-water flow model, that is, to test that the ground-water flow model will duplicate measured data for a noncalibration period without modification of the model parameters. In general, the simulated results are in good agreement with the measured data, and the simulated hydrographs for wells in the floodplain and regional aquifers follow the measured water-level trends. Simulated streamflow data for the 1995-99 wet and dry stress periods at the Lower Narrows, Barstow, and Afton Canyon were compared with the measured data for average streamflow for the same periods; in general, the model reflects 1995-99 streamflow conditions. The simulation results also indicate that the streambed conductance values calibrated to the 1931-94 conditions reasonably simulate the 1995-99 conditions and therefore can be used for predictive purposes. To visualize the magnitude, spatial distribution, and timing of water-level changes in the basin through time, simulated hydraulic heads for 1932-99 were compared with simulated hydraulic heads for 1931. Greater than average annual inflows to the Mojave River from the headwaters during the late 1930's and throughout much of the 1940's resulted in simulated hydraulic heads that were higher than the 1931 hydraulic heads along the Mojave River in most model subareas. Parts of the Baja and Harper Lake model subareas had declines in the simulated hydraulic head because of the increase in agricultural pumpage. By 1960, the simulated hydraulic heads were lower than the simulated hydraulic heads for 1931 in all model subareas of the floodplain and the regional aquifers because of pumpage. After 1960, the size and the magnitude of the areas of the regional aquifer for which simulated hydraulic heads were lower than those for 1931 continued to increase until the end of the simulation (1999). Along the Mojave River, hydraulic heads fluctuated in the floodplain aquifer in response to recharge during years with large inflows with little apparent effect on the simulated hydraulic heads in the regional aquifer. Three water-management alternatives were evaluated to determine their effect on ground-water resources using the calibrated ground-water flow model. The water-management alternatives consider the artificial recharge of imported water allocated to the Mojave Water Agency (MWA): the first assumes that zero percent of the MWA allocation is available (alternative 1), the second assumes that 50 percent of the MWA allocation is available (alternative 2), and the third assumes that 100 percent of the MWA allocation is available (alternative 3). Each of the three water-management alternatives were evaluated for a 20-year drought. Streamflow conditions were simulated using the 20-year drought of 1945-64 with associated calibrated stream parameters. Management alternative 1 results in a reduction in ground-water recharge from the Mojave River compared with average recharge for 1995-99; this reduction is reflected in simulated hydraulic-head declines between 1999 and 2019 of as much as 45 feet. Management alternatives 2 and 3 result in no change in recharge from the Mojave River for management alternative 2 and a small increase for management alternative 3 when compared with recharge for management alternative 1. The artificial recharge of imported water causes increases in simulated hydraulic head for both management alternatives at each of the artificial-recharge sites. Some of the increases are related to water that recharges into areas of low transmissivity which implies that the recharge operations may benefit from being distributed over a larger area.

California↗

Evaluation of borehole geophysical logs and hydraulic tests, phase III, at AIW Frank/Mid-County Mustang Superfund Site, Chester County, Pennsylvania

Borehole geophysical logs, heatpulse-flowmeter measurements, and aquifer-isolation tests were used to characterize the ground-water-flow system at the AIW Frank/Mid-County Mustang Superfund Site. The site is underlain by fractured carbonate rocks. Caliper, natural-gamma, single-point-resistance, fluid-resistivity, and fluid-temperature logs were run in six wells, and an acoustic borehole televiewer and borehole deviation log was run in one well. The direction and rate of borehole-fluid movement was measured with a high-resolution heatpulse flowmeter for both nonpumping and pumping conditions in four wells. The heatpulse-flowmeter measurements showed flow within the borehole during nonpumping conditions in three of the four wells tested. Flow rates up to 1.4 gallons per minute were measured. Flow was upward in one well and both upward and downward in two wells. Aquifer-isolation (packer) tests were conducted in four wells to determine depth-discrete specific capacity values, to obtain depth-discrete water samples, and to determine the effect of pumping an individual fracture or fracture zone in one well on water levels in nearby wells. Water-level data collected during aquifer-isolation tests were consistent with and confirmed interpretations of borehole geophysical logs and heatpulse-flowmeter measurements. Seven of the 13 fractures identified as water-producing or water-receiving zones by borehole geophysical methods produced water at a rate equal to or greater than 7.5 gallons per minute when isolated and pumped. The specific capacities of isolated fractures range over three orders of magnitude, from 0.005 to 7.1 gallons per minute per foot. Vertical distribution of specific capacity between land surface and 298 feet below land surface is not related to depth. The four highest specific capacities, in descending order, are at depths of 174-198, 90-92, 118-119, and 34-37 feet below land surface.

Pennsylvania↗

Simulations of flooding on Tchoutacabouffa River at State Highways 15 and 67 at D'Iberville, Mississippi

A two-dimensional finite-element surface-water model was used to simulate the effects of the proposed State Highways 15 and 67 relocation on water-surface elevations and flow distributions for the 100-year flood on the Tchoutacabouffa River at D'Iberville, Mississippi. The Mississippi Department of Transportation plans to relocate State Highways 15 and 67 by removing a portion of the existing four-lane highway and constructing a four-lane facility upstream of the existing alignment. The proposed alignment is located on the northern floodplain and will tie into the existing highway about 1,000 feet north of the dual State Highways 15 and 67 bridges. The proposed alignment will intercept flows that cross the existing highway during large floods. Seven scenarios were simulated for the 100-year flood, including four proposed alternative configurations for drainage structures. The model grid was developed by using surveyed floodplain cross sections and channel bathymetry data obtained by using an Acoustic Doppler Current Profiler, in combination with a global positioning system. The model was calibrated and verified by using surveyed flood profiles through the study reach and flood discharge measurements obtained at the State Highways 15 and 67 crossing. Model parameters were adjusted so that the computed water-surface profiles agreed closely with the surveyed flood profiles. Computed water-surface differentials across the proposed alignment near the northern edge of the floodplain for the four alternatives proposed by the Mississippi Department of Transportation ranged from 1.4 to 2.6 feet. Much lower differentials were computed in the vicinity of the main-channel bridge. The computed water-surface elevation at McCully Drive, upstream of the proposed alignment, was 17.3 feet for existing conditions. Computed water-surface elevations at McCully Drive for the proposed alternatives ranged from 17.3 to 17.8 feet.

Mississippi↗

Ground-water quality of the surficial aquifer system and the upper Floridan Aquifer, Ocala National Forest and Lake County, Florida, 1990-99

Data from 217 ground-water samples were statistically analyzed to assess the water quality of the surficial aquifer system and Upper Floridan aquifer in the Ocala National Forest and Lake County, Florida. Samples were collected from 49 wells tapping the surficial aquifer system, 141 wells tapping the Upper Floridan aquifer, and from 27 springs that discharge water from the Upper Floridan aquifer. A total of 136 samples was collected by the U.S. Geological Survey from 1995 through 1999. These data were supplemented with 81 samples collected by the St. Johns River Water Management District and Lake County Water Resources Management from 1990 through 1998. In general, the surficial aquifer system has low concentrations of total dissolved solids (median was 41 milligrams per liter) and major ions. Water quality of the surficial aquifer system, however, is not homogeneous throughout the study area. Concentrations of total dissolved solids, many major ions, and nutrients are greater in samples from Lake County outside the Ocala National Forest than in samples from within the Forest. These results indicate that the surficial aquifer system in Lake County outside the Ocala National Forest probably is being affected by agricultural and (or) urban land-use practices. High concentrations of dissolved oxygen (less than 0.1 to 8.2 milligrams per liter) in the surficial aquifer system underlying the Ocala National Forest indicate that the aquifer is readily recharged by precipitation and is susceptible to surface contamination. Concentrations of total dissolved solids were significantly greater in the Upper Floridan aquifer (median was 182 milligrams per liter) than in the surficial aquifer system. In general, water quality of the Upper Floridan aquifer was homogeneous, primarily being a calcium or calcium-magnesium- bicarbonate water type. Near the St. Johns River, the water type of the Upper Floridan aquifer is sodium-chloride, corresponding to an increase in total dissolved solids. Dissolved-oxygen concentrations in the Upper Floridan aquifer ranged from less than 0.1 to 7.3 milligrams per liter, indicating that, in parts of the aquifer, ground water is rapidly recharged by rainfall and is susceptible to surface contamination. Median concentrations of nutrients in the Upper Floridan aquifer were not significantly different between the Ocala National Forest and the area of Lake County outside the Forest. The maximum nitrate concentration in the Upper Floridan aquifer in Ocala National Forest was only 0.20 milligram per liter, whereas, 9 of 39 samples from the Upper Floridan aquifer in Lake County had elevated nitrate concentrations (greater than 1.0 milligram per liter). Hence, nitrate concentrations of the Upper Floridan aquifer appear to be affected by land use in Lake County.

Florida↗

Shallow ground-water quality adjacent to burley tobacco fields in northeastern Tennessee and southwestern Virginia, spring 1997

In 1994, the U.S. Geological Survey began an assessment of the upper Tennessee River Basin as part of the National Water-Quality Assessment (NAWQA) Program. A ground-water land-use study conducted in 1996 focused on areas with burley tobacco production in northeastern Tennessee and southwestern Virginia. Land-use studies are designed to focus on specific land uses and to examine natural and human factors that affect the quality of shallow ground water underlying specific types of land use. Thirty wells were drilled in shallow regolith adjacent to and downgradient of tobacco fields in the Valley and Ridge Physiographic Province of the upper Tennessee River Basin. Ground-water samples were collected between June 4 and July 9, 1997, to coincide with the application of the majority of pesticides and fertilizers used in tobacco production. Ground-water samples were analyzed for nutrients, major ions, 79 pesticides, 7 pesticide degradation products, 86 volatile organic compounds, and dissolved organic carbon. Nutrient concentrations were lower than the levels found in similar NAWQA studies across the United States during 1993-95. Five of 30 upper Tennessee River Basin wells (16.7 percent) had nitrate levels exceeding 10 mg/L while 19 percent of agricultural land-use wells nationally and 7.9 percent in the Southeast had nitrate concentrations exceeding 10 mg/L. Median nutrient concentrations were equal to or less than national median concentrations. All pesticide concentrations in the basin were less than established drinking water standards, and pesticides were detected less frequently than average for other NAWQA study units. Atrazine was detected at 8 of 30 (27 percent) of the wells, and deethylatrazine (an atrazine degradation product) was found in 9 (30 percent) of the wells. Metalaxyl was found in 17 percent of the wells, and prometon, flumetralin, dimethomorph, 2,4,5-T, 2,4-D, dichlorprop, and silvex were detected once each (3 percent). Volatile organic compounds were detected in 27 of 30 wells. Although none of the volatile organic compound concentrations exceeded drinking water standards, the detection frequency was higher than the average for the other NAWQA study units.

Water-Resources Investigations Report↗

Influence of stream habitat and land use on benthic macroinvertebrate indicators of stream quality of selected above-tidal streams in the Houston-Galveston Area Council service area, Texas, 1997–98

During 1997–98, the U.S. Geological Survey, in cooperation with the Houston-Galveston Area Council, collected stream-habitat and benthic macroinvertebrate data for 31 reaches on abovetidal streams in the Council service area near Houston, Texas. Stream-habitat, land-use and population, and benthic aquatic insect metrics were determined for the 31 reaches. Statistical analyses were used to determine the stream-habitat, land-use and population, and aquatic insect variables that are strongly intercorrelated and that explain the greatest amount of variation between the reaches. Comparison of stream-habitat and biological integrity scores computed for each of the 31 reaches indicated (1) reaches generally had larger stream-habitat integrity scores in drainage areas that were heavily forested and had fewer people per square mile, (2) larger biological integrity scores were significantly correlated with larger stream-habitat integrity scores, and (3) urban reaches generally had more simplified streamhabitat conditions and smaller biological integrity scores. Seven reaches in the study area were selected as reference reaches on the basis of high streamhabitat integrity and high biological integrity. The reference-reaches median biological integrity score was equaled or exceeded by three reaches (one on Spring Creek and two on Cypress Creek) that are on the State of Texas 303(d) list of threatened or impaired waters with respect to aquatic life. This indicates that direct measures of biological integrity could be used to supplement surrogatebased designations of biological integrity such as the State list. A statistically significant multipleregression model was developed that uses independent variables that can be obtained without fieldintensive studies to predict the biological integrity score for a reach. The deviation from the model’s predicted score with the score based on biological sampling can be used to interpret the degree of biological impairment in a reach. Data from reaches outside the group of reaches used in this study are needed to test the validity of the multipleregression model.

Texas↗

U.S. Geological Survey Karst Interest Group: proceedings, St Petersburg, Florida February 13-16, 2001

Karst and similar landscapes are found in a wide range of biogeographic classes. In the U.S. for example, Everglades, Mammoth Cave, and Hawaii Volcanoes National Parks have little in common - except karst or pseudokarst, and a cultural past (even though these are very different). This diversity of geologic settings makes karst difficult to categorize and work with when designing a national program such as the recent NPS-USGS Geo-Indicators effort. A GIS-based approach with multiple datalayers is the only sane way to understand and convey the many relationships, in X, Y, and Z axes, between component ecosystems and cultural resources within karst and pseudokarst landscapes. Obviously, karst and cultural landscapes cross modern political as well as biogeographic boundaries. Here again, three-dimensional data are the foundation for understanding similar to that in anatomy and physiology: structure and function. In understanding where the most vulnerable 'pressure points' exist within karst landscapes, we can target landscape-scale ecosystem management to greatest effect. USGS and the National Cave and Karst research Institute could play an extremely significant role in cave and karst management on a national scale beyond NPS or other agency boundaries via cooperative management of three-dimensional karst datasets analogous to programs in several states.

Florida↗

Summary of and factors affecting pesticide concentrations in streams and shallow wells of the lower Susquehanna River basin, Pennsylvania and Maryland, 1993-95

This report presents the detection frequency of 83 analyzed pesticides, describes the concentrations of those pesticides measured in water from streams and shallow wells, and presents conceptual models of the major factors affecting seasonal and areal patterns of pesticide concentrations in water from streams and shallow wells in the Lower Susquehanna River Basin. Seasonal and areal patterns of pesticide concentrations were observed in 577 samples and nearly 40,000 pesticide analyses collected from 155 stream sites and 169 shallow wells from 1993 to 1995. For this study, shallow wells were defined as those generally less than 200 feet deep. The most commonly detected pesticides were agricultural herbicides?atrazine, metolachlor, simazine, prometon, alachlor, and cyanazine. Atrazine and metolachlor are the two most-used agricultural pesticides in the Lower Susquehanna River Basin. Atrazine was detected in 92 percent of all the samples and in 98 percent of the stream samples. Metolachlor was detected in 83 percent of all the samples and in 95 percent of the stream samples. Nearly half of all the analyzed pesticides were not detected in any sample. Of the 45 pesticides that were detected at least once, the median concentrations of 39 of the pesticides were less than the detection limit for the individual compounds, indicating that for at least 50 percent of the samples collected, those pesticides were not detected. Only 10 (less than 0.025 percent) of the measured concentrations exceeded any established drinking-water standards; 25 concentrations exceeded 2 mg/L (micrograms per liter) and 55 concentrations exceeded 1 mg/L. None of the elevated concentrations were measured in samples collected from streams that are used for public drinking-water supplies, and 8 of the 10 were measured in storm-affected samples. The timing and rate of agricultural pesticide applications affect the seasonal and areal concentration patterns of atrazine, simazine, chlorpyrifos, and diazinon observed in water from wells and streams in the Lower Susquehanna River Basin. Average annual pesticide use for agricultural purposes and nonagricultural pesticide use indicators were used to explain seasonal and areal patterns. Elevated concentrations of some pesticides in streams during base-flow and storm-affected conditions were related to the seasonality of agricultural-use applications and local climate conditions. Agricultural-use patterns affected areal concentration patterns for the high-use pesticides, but indicators of nonagricultural use were needed to explain concentration patterns of pesticides with smaller amounts used for agricultural purposes. Bedrock type influences the movement and discharge of ground water, which in turn affects concentration patterns of pesticides. The ratio of atrazine concentrations in stream base flow to concentrations in shallow wells varied among the different general rock types found in the Lower Susquehanna River Basin. Median concentrations of atrazine in well water and stream base flow tended to be similar in individual areas underlain by carbonate bedrock, indicating the connectivity of water in streams and shallow wells in these areas. In areas underlain by noncarbonate bedrock, median concentrations of atrazine tended to be significantly higher in stream base flow than in well water. This suggests a deep ground-water system that delivers water to shallow wells and a near-surficial system that supplies base-flow water to streams. In addition to the presence or absence of carbonate bedrock, pesticide leaching potential and persistence, soil infiltration capacity, and agricultural land use affected areal patterns in detection frequency and concentration differences between samples collected from streams during base-flow conditions and shallow wells.

Water-Resources Investigations Report↗

Estimates of mountain-front streamflow available for potential recharge to the Tularosa Basin, New Mexico

Streamflow in the Tularosa Basin, New Mexico, infiltrates into alluvial-basin aquifers at or near mountain fronts. Streamflow at or near mountain fronts is a substantial component of potential recharge to these aquifers. Streamflow response from precipitation differs substantially between the streams draining the Sacramento Mountains on the eastern side of the basin and those draining the San Andres Mountains on the western side. Mean annual streamflow at mountain fronts that is available for potential recharge to the Tularosa Basin was estimated using two regional regression methods. The method for estimating mean annual streamflow using basin-climatic characteristics was applied to 46 subbasins in the Tularosa Basin. Drainage areas for the subbasins ranged from 0.87 to 157 square miles, and mean annual precipitation ranged from 11.80 to 24.89 inches. Mean annual streamflow to the basin is estimated to be about 95 cubic feet per second or 68,800 acre-feet using the basin-climatic characteristics method. The method for estimating mean annual streamflow using channel-geometry characteristics was applied to 12 subbasins in the Tularosa Basin. Of the 46 basins, 31 had drainage areas less than 20.7 square miles and 3 had active-channel widths less than 15 feet, which were outside the ranges used to develop the regression equations.

Water-Resources Investigations Report↗

Analysis of borehole-radar reflection logs from selected HC boreholes at the Project Shoal area, Churchill County, Nevada

Single-hole borehole-radar reflection logs were collected and interpreted in support of a study to characterize ground-water flow and transport at the Project Shoal Area (PSA) in Churchill County, Nevada. Radar logging was conducted in six boreholes using 60-MHz omni-directional electric-dipole antennas and a 60-MHz magnetic-dipole directional receiving antenna.Radar data from five boreholes were interpreted to identify the location, orientation, estimated length, and spatial continuity of planar reflectors present in the logs. The overall quality of the radar data is marginal and ranges from very poor to good. Twenty-seven reflectors were interpreted from the directional radar reflection logs. Although the range of orientation interpreted for the reflectors is large, a significant number of reflectors strike northeast-southwest and east-west to slightly northwest-southeast. Reflectors are moderate to steeply dipping and reflector length ranged from less than 7 m to more than 133 m.Qualitative scores were assigned to each reflector to provide a sense of the spatial continuity of the reflector and the characteristics of the field data relative to an ideal planar reflector (orientation score). The overall orientation scores are low, which reflects the general data quality, but also indicates that the properties of most reflectors depart from the ideal planar case. The low scores are consistent with reflections from fracture zones that contain numerous, closely spaced, sub-parallel fractures.Interpretation of borehole-radar direct-wave velocity and amplitude logs identified several characteristics of the logged boreholes: (1) low-velocity zones correlate with decreased direct-wave amplitude, indicating the presence of fracture zones; (2) direct-wave amplitude increases with depth in three of the boreholes, suggesting an increase in electrical resistivity with depth resulting from changes in mineral assemblage or from a decrease in the specific conductance of ground water; and (3) an increase in primary or secondary porosity and an associated change in mineral assemblage, or decrease in ground water specific conductance, was characterized in two of the boreholes below 300 m.The results of the radar reflection logging indicate that even where data quality is marginal, borehole-radar reflection logging can provide useful information for ground-water characterization studies in fractured rock and insights into the nature and extent of fractures and fracture zones in and near boreholes.

Nevada↗