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1,669 records · Page 42Linked to original sources

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin

The influence of nodule versus crust morphology on the composition of seamount-hosted ferromanganese minerals

Ferromanganese mineral precipitation in the global oceans is ubiquitous, occurring in the form of both crusts and nodules at a broad range of depths and seafloor terrains. Although ferromanganese crusts and nodules are both composed of ferromanganese minerals, mineralogy and mean element concentrations compiled for regional crust versus nodule occurrences differ. Notably, most published compilations compare nodules from abyssal plain sediments to crusts forming on seamounts, and do not address the question as to whether mineral morphology may affect the composition of crusts and nodules in addition to environmental factors. To address this, we have compiled a dataset of co-located hydrogenetic (seawater sourced) open-ocean ferromanganese crusts and seamount-hosted nodules. The preliminary data presented here support our hypothesis that co-located crusts and nodules exhibit similar compositions, both in terms of their mineralogy and mean element concentrations, as well as overall variance in concentrations for any given element. These data indicate that local processes influence sample-to-sample variation in both crusts and nodules, in contrast to broader ferromanganese variation reported between open-ocean seamounts- hosted crusts and abyssal plain-hosted nodules.

Conference Paper

Numerical model of the groundwater-flow system near the southeastern part of Puget Sound, Washington

Groundwater flow in the active model area (AMA) was simulated using a groundwater-flow model. A steady-state model version of the model simulates equilibrium conditions, and a transient model version simulates monthly variability. The model corresponds to the physical and temporal dimensions of the conceptual model and groundwater budget. The steady-state model version represents average conditions for an 11-year period (January 1, 2005–December 31, 2015), and the transient model represents monthly hydrologic variability within that period. The 13-layer model was constructed using MODFLOW-NWT with a uniformly spaced grid consisting of 416 rows, 433 columns, and cells with a horizontal dimension of 500 feet (ft) on a side. The model was calibrated to measured values of water levels in wells and lakes and estimated base flow for selected streamflow measurement stations, commonly referred to as streamgages. Model calibration was accomplished using a combination of manual and automatic methods, including the Model-Independent Parameter Estimation (PEST) program that adjusted model input parameters with the aim of minimizing the difference between estimated and model-simulated values of hydraulic head and base flow. Model boundary conditions consist of all simulated groundwater inflow to and outflow from the AMA. For example, a stream reach that simulates a gain from or loss to groundwater is a boundary condition that allows water to exit or enter, respectively, the groundwater system. Other boundary conditions include springs, seeps, precipitation recharge, groundwater exchange with lakes and Puget Sound, and groundwater pumping. A comparison of the estimated groundwater budget to that simulated by the steady-state model version indicates that the relative percentages of total inflow or total outflow for six major categories of boundary conditions are similar for the two budgets. The model was used to simulate three suites of scenarios of potential drought and water-use changes. Scenario 1 suite consisted of the steady-state model version that was run with 0, 15, 20, and 25 percent reduction of precipitation recharge to assess the corresponding reductions in base flow with decreasing recharge. The last simulation for the scenario 1 suite consisted of the transient model version simulating 3 years of consecutive seasonal drought, defined by the months of May through September, to assess the corresponding base-flow reductions. Scenario 2 suite consisted of the steady-state model version with all simulated groundwater use removed, compared with a simulation that includes current groundwater use to evaluate changes to potentiometric surfaces and base flows. Scenario 3 suite consisted of a transient model version of the model that simulated pumping increases for four different categories of water-supply wells (compared to no pumping increases) to evaluate resulting reductions in base flow. Although, these scenarios provide examples of model applications and useful insights, many other scenarios could be simulated. A description of how to download the model is described in the body of this report. Uncertainty is associated with most model inputs. Groundwater levels, lake levels, and land-surface altitudes are relatively certain; other model inputs are far less certain, including precipitation recharge, base flow, hydraulic properties, water use, and the three-dimensional structure of subsurface hydrogeologic units. Models are useful not because of high levels of accuracy of all model inputs, but because they combine the best information and estimates available, thereby providing the best predictions available related to physical processes. The model described in this report simulates groundwater flow on a regional scale, which has inherent limitations for simulating hydrologic scenarios at local scales. Model structures and inputs were generalized to be consistent with this regional scale. For example, the actual groundwater system has much greater heterogeneity of hydraulic conductivity than is possible within the model’s degrees of freedom. Variations in hydraulic gradients over distances less than 500 ft cannot be simulated. The distances between model features, such as a pumping well and a stream, must be placed at 500-ft intervals and are co-located if both features are within the same model cell.

Washington

Coastal Science Navigator companion guide—Discover the U.S. Geological Survey coastal science products you need

The Coastal Science Navigator is an online gateway to a wide variety of U.S. Geological Survey (USGS) coastal change hazards-related information, data, and tools relevant to stakeholders’ scientific and decision-making needs. The products within the Coastal Science Navigator provide data related to past, present, and future threats to our coastlines. The filter search allows users to see all available products and identify relevant options by time scale, geographic scope, coastal hazard theme, and other filters. The guided search suggests products based on users’ answers to a short series of questions. A comprehensive summary is available for each product. The idea for the Coastal Science Navigator arose in 2020 in response to stakeholder feedback identifying the need for a central source for USGS coastal science information. It was published in July 2023 and initially included 55 products. Regular updates are planned to integrate other existing and new products. This guide introduces some of the many coastal change hazards-related products available through the USGS. In it, we showcase the products included in the Coastal Science Navigator’s initial publication in July 2023. While it is not representative of all the information, tools, and data available, we hope it serves as a compelling snapshot of what the USGS has to offer and encourages you to explore the Coastal Science Navigator to discover more of the products you need. To navigate this guide, the products have been organized by the time scale they are best suited for—past, present, or future—although many products cover multiple time scales. An additional section features software, one of the many product types available as filters within the Coastal Science Navigator. Other products include downloadable data, websites, and geonarratives (web pages that combine text, images, and interactive maps into narratives you can scroll through). Featured geographic scopes are also highlighted within this guide, detailing some of the many regions in which the USGS conducts research and illustrating another way to filter products within the Coastal Science Navigator.

Circular

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico

Diamond drilling at the Ma'milah Mine, Kingdom of Saudi Arabia

The Ma'millah gold mine is about 90 km southeast of At Ta'if at lat 21°03'N., long 41°18'E., in southwestern Saudi Arabia. The deposit, which was worked extensively by ancient miners, consists of several veins and massive lenses of quartz along a regional fault. The extensive ancient mine workings, large size of some quartz outcrops, and significant gold content of several samples indicated that subsurface exploration was warranted. Accordingly, two holes were drilled into the deposit during the interval December 1972 to February 1973. The drill findings were disappointing; the grade of vein material was found to be too low to be of economic interest and the quartz bodies were found to pinch out both along strike and downdip. The drilling program therefore was terminated. The deposit is not worth further exploration

Ma'milah Mine

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

Isotopic evaluation of the National Water Model reveals missing agricultural irrigation contributions to streamflow across the western United States

The National Water Model (NWM) provides critical analyses and projections of streamflow that support water management decisions. However, the NWM performs poorly in lower-elevation rivers of the western United States (US). The accuracy of the NWM depends on the fidelity of the model inputs and the representation and calibration of model processes and water sources. To evaluate the NWM performance in the western US, we compared observations of river water isotope ratios ( 18 O / "> 16 O and 2 H / "> 1 H expressed in δ notation) to NWM-flux-estimated (model) river reach isotope ratios. The modeled estimates were calculated from long-term (2000–2019) mean summer (June, July, and August) NWM hydrologic fluxes and gridded isotope ratios using a mass balance approach. The observational dataset comprised 4503 in-stream water isotope observations in 877 reaches across 5 basins. A simple regression between observed and modeled isotope ratios explained 57.9 % ( δ 18 O) and 67.1 % ( δ 2 H) of variance, although observations were 0.5 ‰ ( δ 18 O) and 4.8 ‰ ( δ 2 H) higher, on average, than mass balance estimates. The unexplained variance suggest that the NWM does not include all relevant water fluxes to rivers. To infer possible missing water fluxes, we evaluated patterns in observation–model differences using δ 18 O diff ( δ 18 O obs − δ 18 O mod ) and d diff ( δ 2 H diff - 8 ⋅ δ 18 O diff "> ). We detected evidence of evaporation in observations but not model estimates (negative d diff and positive δ 18 O diff ) at lower-elevation, higher-stream-order, arid sites. The catchment actual-evaporation-to-precipitation ratio, the fraction of streamflow estimated to be derived from agricultural irrigation, and whether a site was reservoir-affected were all significant predictors of d diff in a linear mixed-effects model, with up to 15.2 % of variance explained by fixed effects. This finding is supported by seasonal patterns, groundwater levels, and isotope ratios, and it suggests the importance of including irrigation return flows to rivers, especially in lower-elevation, higher-stream-order, arid rivers of the western US.

Hydrology and Earth Systems Science

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Hydrogeology, groundwater salinity distributions, and assessment of the effect of oil-production activities on groundwater in the Midway Valley area, western Kern County, San Joaquin Valley, California

This study seeks to determine the effects of oil field produced water disposal operations and well mechanical integrity issues on groundwater quality in oil fields in the southwest San Joaquin Valley, California. Whereas previous studies used groundwater wells to study shallow aquifers outside the oil fields, this study demonstrates that future approaches may use oil well geophysical logs to map groundwater head gradients, create salinity profiles and document changes in salinity over time in oil field areas with sparse groundwater well data and at depths greater than 330 m. We also incorporate an analysis of well histories to determine potential effects of compromised wellbore seals on changes in aquifer quality that cannot be explained by water disposal practices. Water quality in the aquifers is naturally brackish across most of the area, with better quality groundwater occurring in the eastern part. Geophysical logs are used to determine salinity variations within aquifers including the depth at which TDS exceeds 10,000 mg/L. This depth ranges from 366 m in the northwest to approximately 1,500 m in the southeast. Oil well porosity logs are used to determine water table elevations. These logs indicate the water table slopes south-southeast, showing the predominant groundwater flow direction is from oil field disposal areas toward better quality groundwater east of the oil fields. Geophysical logs show formation resistivity near some disposal facilities has decreased over time, indicating the salinity of the aquifer has increased due to disposal of saline produced water in injection wells and ponds. Oil well history analysis suggests that increased salinity over time in water-saturated sand intervals >1.5 km from disposal facilities may be caused by mechanical failures and/or incomplete borehole seals in poorly constructed or abandoned wellbores prevalent throughout the study area—particularly wells drilled prior to 1930.

California

Spectral characteristics and mapping of lithium-rich playas in the Basin and Range Province, western United States

This report presents a comprehensive set of prospectivity maps for lithium in brines located within the playas of the Basin and Range Province of western United States. The prospectivity assessment is based on criteria established in the descriptive deposit model outlined in a previous U.S. Geological Survey report, with a focus on regional remote sensing methodologies. The playas within the study area have been systematically ranked according to several key factors, including size, the presence and abundance of source rocks, vegetation as an indicator of water availability, documented prospects, and data products derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor. Notably, the deposits in the playa of Clayton Valley make it stand out as the sole lithium brine-producing playa in the United States. The ASTER sensor provides optimal regional coverage, characterized by a 60-kilometer swath width and unique multispectral capabilities that are not available with other remote sensing instruments. This report and the accompanying maps are intended to serve as resources for further multidisciplinary assessments of lithium or other elements or commodities where prospectivity can be inferred from the presence of proxies such as alteration minerals.

Arizona, Baja California, California, Chihuahua, I

Airborne radiometric data map alteration of porphyry copper systems in the Elkhorn district, MT

The Elkhorn district in southwestern Montana is known for past production of high-grade base and precious metals from skarn and carbonate replacement deposits. The district also hosts a porphyry Cu-Mo deposit. A radiometric survey flown over the district and surrounds provides maps of surficial concentrations of potassium, thorium, and uranium. Handheld gamma ray spectrometer measurements on altered and unaltered rocks in the district and surrounding region provide a means to ground truth the airborne data. We demonstrate that the airborne and ground-based measurements show similar map patterns. We calculate ratios of the radioelement concentrations and present a potassium enhancement map that combines potassium and ratios of potassium to thorium and uranium. The results highlight the rocks previously mapped as having K-feldspar-biotite and quartz-sericite alteration assemblages in the Elkhorn district and map additional hydrothermal systems in the region, including known alteration in the Radersburg district. The data enhancement techniques can be used as a screening tool for mapping additional porphyry copper systems.

Montana

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming

Water supply in the conterminous United States, Alaska, Hawaii, and Puerto Rico, water years 2010–20

We present an assessment of water supply across the conterminous United States (CONUS), Alaska, Hawaii, and Puerto Rico covering water years 2010–20. Our analysis drew on two national hydrologic models, the National Hydrologic Model Precipitation-Runoff Modeling System and the Weather Research and Forecasting model hydrologic modeling system. Both models produced estimates of streamflow, evapotranspiration, soil moisture, snow water equivalent, and other hydrologic states and fluxes. The models were driven by the bias-adjusted 4-kilometer-resolution, long-term regional hydroclimate simulation over the conterminous United States dataset (CONUS404). We assessed spatial and temporal error distributions by comparing monthly simulations at the 12-digit hydrologic unit code and regional scale from both models against external benchmarking datasets. Results showed that average annual rainfall across the CONUS was 857 millimeters per year for the period of analysis, with water year 2012 the driest year (729 millimeters) and water year 2019 the wettest year (995 millimeters). Key interannual variability results included the following: (1) the California–Nevada hydrologic region had the highest variability in precipitation and snow accumulation, and (2) the Texas hydrologic region was among hydrologic regions with the highest variability in precipitation. We related interannual variability in precipitation to storage volumes in soil moisture, snow water equivalent, and lakes and reservoirs to highlight areas with little storage and large year-to-year variability in precipitation. These areas included the Southern High Plains, Central High Plains, Texas, Souris–Red–Rainy, Mississippi Embayment, and Midwest regions. Our analysis of groundwater-level data showed that several of these areas overlap aquifers where groundwater levels were considerably lower than historical averages, including the Colorado Plateaus aquifers, the Rio Grande aquifer system, and the Central and Southern regions of the High Plains aquifer. Many of these lowered groundwater levels are continuations of decades-long declines from overpumping that started well before the assessment period. The resulting water budgets and their analyses provide a high-resolution foundational assessment of the mean state and variability of the terrestrial hydrologic cycle across the CONUS and Alaska, Hawaii, and Puerto Rico to support a wide range of water resource management applications.

Professional Paper

Predicting hydrothermal reservoir depth from chemical geothermometers using a three-dimensional temperature model in the Great Basin, USA

Recent work in the Great Basin region of the western United States has made it possible to predict the depth of hydrothermal reservoirs (i.e., the depth at which heat is accumulated prior to ascent via hydrothermal upflow) identified through geochemistry and to contextualize the spatial patterns of these reservoir depths. Chemical geothermometers use the chemical and mineral constituents of hydrothermal fluids to predict the temperature at which fluids equilibrated with the host rocks at depth. Assuming that most of the Great Basin is dominated by conductive conditions until a vertically connected hydrothermal flow path is created (e.g., by faulting), geothermometers reflect the chemical and thermal conditions at the depth interval that the fluid has conductively equilibrated over a long period before a vertical conduit allows convective upflow. By pairing geothermometer temperature estimates with our recent three-dimensional temperature model of conductive heat flow in the Great Basin, we estimate the corresponding reservoir depths and construct a map of circulation depths. The predicted depths from geothermometers have spatial patterns across the Great Basin that relate to patterns seen in other geologic and geophysical data. Deeper springs generally occur disproportionately in areas with higher strain rates and in basins. We posit that current elevated strain rates reflect patterns of historic deformation where ongoing tectonic activity maintains permeable pathways to deeper reservoirs, some of which are estimated to exceed 6 km depth. Basins, as expected, contain a disproportionate number of these deep systems, because the underlying aquifers are closer to the surface in basins, thus requiring less water pressure to reach the surface than in mountain ranges. Most springs estimated to have their source in a deep reservoir occur at places known to host a hydrothermal system; these refined depth estimates of the source reservoir can help to better constrain the source depth for many known hydrothermal systems across the Great Basin.

Arizona, California, Idaho, Nevada, Oregon, Utah

Stress states on the eve of past earthquakes inform earthquake rupture through fault complexity along the San Andreas and San Jacinto faults

Estimating the evolving state of stress along active fault systems can provide insight into the conditions that generated past ground‐rupturing earthquakes and influenced their ability to propagate through areas of geometric complexity, such as fault branches and stepovers. We use quasi‐static forward numerical models that incorporate the 3D complex configuration of active faults in southern California to estimate shear tractions on the geometrically complex southern San Andreas and San Jacinto faults from 1000 to 1900 C.E. These tractions include interseismic accumulation of traction due to tectonic loading, viscoelastic relaxation of shear stress within the upper crust between earthquakes, and effects of other earthquakes on the fault network. We simulate ground‐rupturing earthquakes based on the along‐strike earthquake extents modeled by Scharer and Yule (2020) , assuming that stress drop is complete in each earthquake. We use Monte Carlo simulations to estimate uncertainty in evolving shear tractions due to uncertainties in earthquake timing and in upper‐crustal viscosity. Pre‐earthquake shear tractions typically do not exceed ∼2 MPa. Although ruptures with length <200 km have pre‐earthquake shear tractions that range from near zero to ∼1.75 MPa, these tractions are not less than ∼0.4 MPa for earthquakes with rupture length >200 km. Earthquakes with long (>200 km) ruptures occur only in the single‐stranded part of the system, whereas those with short (<125 km) rupture length and high pre‐earthquake shear traction occur near fault stepovers and branches. This suggests that high accumulated shear traction encourages longer rupture propagation, but may not be sufficient to overcome geometric complexities. This modeling approach informs our understanding of rupture propagation and provides estimates of fault shear tractions that are unavailable from direct measurements.

Callifornia

Deep groundwater total dissolved solids mapping in the Dakota Group, Williston Basin, USA

Growing concern about the quantity of available freshwater around the world has led to interest in surveying groundwater total dissolved solids (TDS) below water well depths. Deep TDS has not been systematically mapped, and there is much to learn about the distribution and controls on deeper groundwater. In sedimentary basins across the United States, groundwater resources often overlie hydrocarbon resources, providing an opportunity to use borehole geophysical data collected for hydrocarbons to characterize groundwater and pore space resources. This study adapts a recently developed subsurface geostatistical and geophysical modeling approach to continuously map groundwater TDS, porosity, and temperature in the Dakota Group of the Williston Basin—an undercharacterized regional aquifer system overlying deeper hydrocarbon reservoirs. Groundwater TDS in the Dakota Group ranges from approximately 4800 to 26,900 mg/L. TDS patterns are stratified with higher TDS in the lower and upper Dakota Group, and relatively lower TDS in the middle Dakota Group. The lower TDS in the middle zone may represent a preferential regional flow path for lower-TDS meteoric recharge from the west. The alternating pattern of TDS may also be evidence of higher-TDS inflows into the Dakota Group from underlying and potentially from overlying aquifers. Porosity is lower near the center of the Williston Basin and tends to be higher to the east, which may be related to grain size distributions. The new regional TDS and porosity modeling serves as a quantitative reference for water users and provides supporting evidence for hypotheses on Dakota Group recharge.

Montana, North Dakota, South Dakota