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USGS2026

Insights into Mountain Pass carbonatite formation from in-situ sulfur isotopes and geochemistry of sulfate and sulfide minerals

The Mountain Pass carbonatite stock hosts a world-class rare earth element deposit and may be classified as a carbonate-sulfate igneous rock, as it contains on average > 50 volume percent carbonate minerals and 20 to 30 volume percent sulfate minerals. The sulfates range in composition from barite to celestine and locally occur with sparse sulfide minerals. We investigate the origin of sulfur enrichment and the occurrence of sulfur-bearing minerals in the Mountain Pass carbonatite with in-situ sulfur isotope and mineral chemistry. Barite cores with δ 34 S of 1 to 3‰ do not coexist with sulfides, whereas celestine rims with δ 34 S of > 3‰ are associated with sulfides with δ 34 S < -10‰. We propose a model in which sulfur-bearing sediments were subducted during episodes of plate convergence in the Mojave Province that preceded Mountain Pass magmatism. Metasomatism of the overlying mantle by melts derived from the subducted sediments generated an unusually carbon- and sulfur-rich source to yield carbonatite magmas. Sulfur from primary carbonatite magmas and ~ 1 to 7% sulfur from subducted sediment melts yielded a slightly enriched δ 34 S composition (relative to depleted mantle δ 34 S of -1‰) for early crystallizing barite. Celestine rims on magmatic barite cores formed at low, hydrothermal temperatures (< 350 °C) based on S isotope thermometry for equilibrium celestine-galena and celestine-pyrite pairs. The sparse sulfides in the carbonatite stock are not in equilibrium with the primary barite cores and therefore do not permit S isotope thermometry estimates of magmatic temperatures. The S/Se ratios of sulfide minerals (> 3,400) typically exceed primitive mantle values (S/Se of 3,340), also consistent with their derivation from hydrothermal fluids. Trace occurrences of sulfide and sulfate minerals in alkaline silicate stocks related to the carbonatite stock have similar δ 34 S compositions and yield similarly low formation temperatures, suggesting regionally extensive and chemically similar sulfur-bearing hydrothermal fluids that imparted lithologically diverse rocks with a consistent sulfur isotope fingerprint.

California, Nevada↗
USGS2025

Mine waste as a potential source of critical minerals and other commodities: Examples from the Four Corners states, USA

The growing demand for critical minerals and other mineral resources has raised concerns about possible supplies of these essential commodities. Mine waste is a potential source of these essential commodities. We compiled a geospatial database of publicly available data of the largest non-fuel mine waste features (>200,000 m 2 in areal extent) in the Four Corners states of the United States, where most of those features are from porphyry Cu deposits. The combined volume of those large porphyry Cu mine waste features is approximately 17 cubic kilometers, 60% of which is ore-related material such as tailings. Using publicly available data on density, grade, and previous recovery values, we estimate the contained endowments of Ag, As, Au, Bi, Cu, Mo, Re, S, Sb, Se, Te, and W. These estimates indicate endowments within ore-related mine wastes are collectively comparable to endowments of giant to supergiant deposits. If fully recovered, these commodities could meet current global demand from less than 1 year (Sb) to more than 200 years (Re), underscoring the enormous untapped resource potential of mine waste.

Arizona, Colorado, New Mexico, Utah↗
USGS2025

Geochemistry and radiogenic isotopes constrain the mantle source region of the Mountain Pass Intrusive Suite, California

The Mountain Pass carbonatite stock is the largest rare earth element (REE) deposit and only active REE mine in the United States. The carbonatite intrusion and spatially associated alkaline silicate intrusions constitute the Mountain Pass Intrusive Suite, which is located within the Mojave Province in California. Both the carbonatite and the alkaline silicate rocks are enriched in large ion lithophile elements and light REEs, and less enriched to depleted in high field strength elements, indicating the mantle source region was metasomatically enriched in incompatible trace elements. The cause of this metasomatic mantle enrichment and the genetic relationship between the carbonatite and the alkaline silicate stocks are poorly understood. In this study, major and trace element geochemical data and isotopic (Rb-Sr, Sm-Nd, and Lu-Hf) data are presented to constrain genesis of the Mountain Pass Intrusive Suite, from mantle source region to the intrusion of the stocks. Our geochemical data are consistent with derivation of the alkaline silicate and carbonatite melts through partial melting from a shared mantle source region rather than through liquid immiscibility or fractional crystallization and separation of a carbothermal fluid. Although the Rb-Sr isotopic system in the Mountain Pass Intrusive Suite is disturbed at the whole-rock scale, the isotopic systems for whole-rock Sm-Nd (εNd i = ‐2.2 ± 0.8) and zircon Lu-Hf (εHf i = 0.1 ± 1.1) are robust and support mantle derivation of the magmas. Geochemical modeling using experimentally derived partition coefficients was used to identify possible causes of enrichment in incompatible elements through metasomatism in the mantle source region. Modeling of metasomatism by melts derived by partial melting of deeply subducted carbonated sediments approximates observed Mountain Pass Intrusive Suite trace element chemistry. Scattered εHf i in inherited zircon (2.8 ± 2.6) is consistent with derivation from an arc-related environment with substantial crustal contamination. Paleotectonic studies in the Mojave Province indicate that regional subduction preceded emplacement of the Mountain Pass Intrusive Suite by ∼300 Ma. Melting of the Mountain Pass source region may have been caused by post-collisional thermal relaxation and extension.

California↗
USGS2024

Estimated groundwater recharge for mid-century and end-of-century climate projections, Kaua‘i, O‘ahu, Moloka‘i, Lāna‘i, Maui, and the Island of Hawai‘i

Demand for freshwater in the State of Hawaiʻi is expected to increase by roughly 13 percent from 2020 to 2035. Groundwater availability in Hawaiʻi is affected by a number of factors, including land cover, rainfall, runoff, evapotranspiration, and climate change. To evaluate the availability of fresh groundwater under projected future-climate conditions, estimates of groundwater recharge are needed. A water-budget model with a daily computation interval was used to estimate the spatial distribution of groundwater recharge for Kauaʻi, Oʻahu, Molokaʻi, Lānaʻi, Maui, and the Island of Hawaiʻi for recent climate conditions and three future-climate scenarios. Climate conditions from 1978 to 2007 were used as the reference period for recent climate conditions on each island. The three future-climate scenarios were developed using available high-resolution downscaled climate projections that include (1) a mid-century scenario using projected rainfall conditions for the Representative Concentration Pathway (RCP) scenario during 2041–71 with a total radiative forcing of 8.5 watts per square meter by the year 2100 (RCP8.5 2041–71 scenario), (2) a dry-climate scenario using projected rainfall conditions for the RCP8.5 scenario during 2071–99, and (3) a wet-climate scenario using projected rainfall conditions for the “Special Report on Emissions Scenarios” A1B scenario during 2080–99 for Maui, the RCP4.5 scenario during 2080–99 for Kauaʻi, Lānaʻi, and the Island of Hawaiʻi, and the RCP8.5 scenario during 2080–99 for Oʻahu and Molokaʻi. An additional drought scenario was added for Lānaʻi to assess the effect of extreme drought conditions during 2008–12 on groundwater recharge. All scenarios used 2020 land cover. Mean annual groundwater recharge is estimated to decrease between 5 and 55 percent on all six islands in this study for the mid-century and dry-climate scenarios relative to the reference-period recharge. Recharge is estimated to increase for Kauaʻi, Oʻahu, Molokaʻi, Lānaʻi, and Maui between 2 and 43 percent and decrease for the Island of Hawaiʻi by about 4 percent for the wet-climate scenario. Comparing the mid-century and dry-climate scenarios, all 110 aquifer systems (management areas defined by the State of Hawaiʻi Commission on Water Resource Management) from all six islands show similar direction in drying (104 aquifer systems) or wetting (6 aquifer systems) changes for recharge. However, among the three future scenarios, only 35 of 110 aquifer systems show similar direction in drying (30 aquifer systems) or wetting (5 aquifer systems) changes for recharge.

Hawaii↗
USGS2026

Computation of regional groundwater budgets for the Virginia Coastal Plain aquifer system

Computation of detailed groundwater flow budgets for subdivisions of the Virginia Coastal Plain aquifer system has enabled quantification and more thorough understanding of groundwater flow within this important water resource. A zone budget analysis based on previously published groundwater models of the Virginia Coastal Plain and Virginia Eastern Shore indicates that groundwater conditions vary substantially throughout the Coastal Plain aquifer system because of local variations in hydrogeology and historical and ongoing variations in groundwater use and management. Decades of substantial groundwater withdrawal from the Coastal Plain aquifer system have altered groundwater flow from predevelopment conditions. Rates of sustainable withdrawal are limited because the downward groundwater flow rate into confined aquifers is a relatively small part of the total groundwater budget for the aquifer system compared to the rate of recharge at the land surface. Analyses of groundwater budgets from the Virginia Coastal Plain model indicate that groundwater flow is generally outward from the surficial aquifer to rivers and coastal waterbodies and downward through a series of underlying aquifers and confining units to the Potomac aquifer, which is the deepest aquifer and the source of most groundwater withdrawals. Downward flow into the Potomac aquifer is estimated to be only 7 percent of total net precipitation-derived net recharge at the land surface but makes up about 66 percent of inflow to the aquifer in Virginia, with much of the remaining inflow occurring laterally from outside of defined groundwater budget regions in Virginia. For several decades prior to 2010, high rates of withdrawal from the Potomac aquifer resulted in substantial decline in groundwater storage in the aquifer and in most overlying aquifers and confining units. From 2010 to 2023, rates of withdrawal substantially lower than the historical maximum resulted in small net increases in groundwater storage in the confined aquifer system for most regions of the Virginia Coastal Plain. Nevertheless, for the same period, groundwater storage for the entire model domain continues to incrementally decline, indicating that storage recovery in Virginia is offset by a continued decrease in storage in areas beneath the Chesapeake Bay or adjacent areas of Maryland and North Carolina. Withdrawals from the Potomac aquifer have induced substantial downward flow which is a large part of groundwater budgets for confined aquifers such as the Potomac. For the most recent simulated conditions (2023) downward groundwater flow continues, but because vertical flow rates are a function of the difference between water pressure in the upper surficial systems and lower confined units, rates of downward flow are lower than those in earlier decades as the confined water levels partially recover from larger groundwater withdrawals in the past. Geographically, groundwater flow is generally inward from perimeter regions of the Virginia Coastal Plain toward central regions with the largest withdrawal rates. Groundwater inflow from coastal regions could be contributing to saltwater intrusion, even though that was not measured in this study. Analyses of groundwater budgets from the Virginia Eastern Shore peninsula, a geographic region of the Virginia Coastal Plain, indicate that groundwater flow for that isolated aquifer system is generally outward from the surficial aquifer to coastal water bodies and downward into the confined Yorktown-Eastover aquifer system, which is the source of most withdrawals. Downward groundwater flow into the confined Yorktown-Eastover aquifer system is estimated to be less than 2 percent of total recharge and less than 9 percent of net recharge at the water table but makes up more than 93 percent of all inflow to the confined aquifer system. Decades of substantial but relatively consistent groundwater withdrawals have induced greater downward flow rates into the confined aquifer system but also have resulted in loss of groundwater from storage. For the most recent simulated period (2023), estimated storage loss accounts for slightly under 7 percent of withdrawals from the confined aquifer system. The reported withdrawal rate for this period from the confined Yorktown-Eastover system is near the highest reported rate for the Virginia Eastern Shore, which means that the storage depletion is expected to continue, even though groundwater levels appear to be relatively stable. Estimated groundwater flow rates upward from the confining unit underlying the Yorktown-Eastover system and low rates of inflow from coastal water bodies underscore ongoing concerns about up-coning and lateral intrusion of salty groundwater.

Virginia↗
USGS2024

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research↗
USGS2025

System characterization report on the Environmental Mapping and Analysis Program (EnMAP)

This report addresses system characterization of the Environmental Mapping and Analysis Program hyperspectral sensor by the DLR (German Aerospace Center, ground segment project management), GFZ (Deutsches Geoforschungszentrum, science lead) and is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the EnMAP hyperspectral sensor; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior), and radiometric performances of the EnMAP hyperspectral sensor. Results of these analyses indicate that the Environmental Mapping and Analysis Program has a band-to-band geometric performance in the range of −0.135 to 0.15 pixel, geometric performance relative to the Operational Land Imager in the range of −27.716 meters (−0.92 pixel) to 32.892 meters (1.09 pixels) offset in comparison to Landsat 8 Operational Land Imager, offset of a radiometric comparison in the range of −0.012 to 0.020, slope of a radiometric comparison in the range of 0.947 to 1.031.

Open-File Report↗
USGS2026

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii↗
USGS2026

Geologic map of the Emmons Lake volcanic center, Alaska

Introduction The Emmons Lake volcanic center is a spatially clustered group of stratovolcanoes and calderas in the southwestern part of the Alaska Peninsula, Alaska. The volcanic center is characterized by several ice- and snow-clad stratovolcanoes located within and along the margins of a nested-caldera complex that includes Emmons Lake. A shieldlike ancestral edifice (ancestral Mount Emmons) is truncated by the caldera complex and forms a broad volcanic platform around the center. The main stratovolcanoes of the Emmons Lake volcanic center are Pavlof Sister, Pavlof Volcano, Little Pavlof, Double Crater, Mount Hague, and Mount Emmons. Several small unnamed cinder cones and vents also are located within Emmons Lake volcanic center and on the east flank of Pavlof Volcano. Many of these cones and vents have been the source of the young lava flows that mantle the floor of the caldera. Pavlof Volcano, in the northeastern part of the Emmons Lake volcanic center, is one of the most historically (that is, the past about 300 years) active volcanoes in Alaska, and eruptions from Pavlof Volcano pose the greatest hazards to the region. Volcanic rocks of the Emmons Lake volcanic center overlie continental and marine sedimentary rocks of chiefly Late Jurassic to early Tertiary age. The oldest rocks in the area are those of the Naknek Formation, consisting of volcaniclastic sandstone, siltstone, and conglomerate of Late Jurassic age. The southern part of the area includes rocks of the Belkofski Formation, a thick sequence of volcaniclastic sandstone, siltstone, and conglomerate of middle Tertiary age. Lava flows, volcanic breccia, and fluvial volcaniclastic rocks of late Miocene age, which unconformably overlie the Belkofski Formation south of the Emmons Lake volcanic center, are primarily exposed on the islands just south of the Alaska Peninsula. The Emmons Lake volcanic center was affected multiple times by glaciation associated with the glacier expansion that characterized the Quaternary. Glaciation has played a key role in shaping the present-day landscape, and much of the eruptive history of the Emmons Lake volcanic center has involved interactions with glacier ice. Thus, a brief review of the Quaternary glacial history of the area is provided to establish the physical context for Emmons Lake volcanic center eruptive activity.

Alaska↗
USGS2025

Geologic map of MTM −15032 and −20032 quadrangles, western Ladon basin, Mars

Our mapping efforts focused on the geomorphic terrains and geologic units contained within Mars Transverse Mercator (MTM) −15032 and −20032 quadrangles. These two quadrangles are located along the west side of Ladon basin and span lat −12.5° N. to −22.5° N. and long 325° E. to 330° E. The western part of Ladon basin and its bounding basin ring structures to the west preserved features that help to understand the long history of drainage across the Margaritifer Terra region of Mars. Our geologic map provides new insight into the extent of aqueous activity across western Ladon basin and the adjoining highlands, which includes the northern part of Ladon Valles, Arda Valles, numerous small valleys in the western highlands, and light-toned layered deposits associated with these fluvial features. The Mars Odyssey Thermal Emission Imaging System (THEMIS) infrared (IR) daytime mosaic (100 meters per pixel) was used as the primary base map. We constructed the geologic map of western Ladon basin at 1:1,000,000 scale. We identified 20 geologic units in the map area, which we divided into the following groups: crater units; volcanic units; chaotic units; basin fill units; crater, valley, and channel units; and plateau and highlands units. We observed the following sequence of events: (1) formation of Ladon and Holden impact basins in the middle Noachian, producing a mountainous unit; (2) landscape degradation and infilling during the Late Noachian to Late Hesperian forming terra units; (3) formation of Ladon Valles in the Late Noachian to Early Hesperian by catastrophic flooding, producing channel units; (4) accumulation of sediments in the Late Noachian to Early Amazonian, forming basin fill units; (5) formation of a smooth crater fill unit during the Early to Late Hesperian; (6) deposition during the Late Hesperian to Early Amazonian, creating light-toned layered units within Ladon Valles, Ladon basin, and other smaller valley networks along the western uplands, as well as formation of a light-toned unit along some crater floors; (7) formation a of chaotic unit in the Early to Middle Amazonian, formation of alluvial fans in the Early Amazonian, and eruption of a volcanic unit in the Middle Amazonian; and (8) formation of craters throughout the geologic history of the map region.

Scientific Investigations Map↗
USGS2024

System characterization report on the Earth Surface Mineral Dust Source Investigation (EMIT) sensor

Executive Summary This report addresses system characterization of the Earth Surface Mineral Dust Source Investigation (EMIT) sensor, an imaging spectrometer developed by the National Aeronautics and Space Administration. This report is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the specific sensing system being evaluated; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior) and radiometric performances. Results of these analyses indicate that the EMIT sensor has a band-to-band geometric performance in the range of −0.355 to 0.210 pixel with a few exceptions of shortwave infrared channels. Geometric offset relative to the Landsat 8 Operational Land Imager ranged from −15.966 meters (−0.266 pixel) to 43.844 meters (0.731 pixel). Offset of a radiometric comparison ranged from −0.016 to 0.025, and slope of a radiometric comparison ranged from 0.837 to 0.985. EMIT agreed with Radiometric Calibration Network measurements within 5 percent across most of the spectral channels.

Open-File Report↗
USGS2025

Surficial geology and Quaternary tectonics of the Madison Valley and fault zone, Madison, Gallatin, and Beaverhead Counties, southwest Montana

The north-northwest-striking Madison fault is approximately 95 kilometers in length, lying at the confluence of the northeastern Basin and Range province and the Yellowstone tectonic parabola. The fault zone consists primarily of west-dipping normal faults that have east-dipping antithetic faults, which create the Madison Valley graben and several northeast-trending intrabasin faults. The Madison fault and associated sections discussed herein refer to the main west-dipping, range-bounding fault along the eastern side of the valley. Detailed geologic mapping (1:12,000 scale) of the entire fault zone and fault scarp profiling (total of 102 profiles) of the Madison fault reveal greater late Quaternary paleoseismic activity towards the south, including at least three paleoevents along the southern part of the fault that postdate Pinedale glaciation. Early to middle Holocene alluvial fans have vertical surface offsets that average between 2.0 and 3.0 meters and define the characteristic single-event surface offset. Pinedale lateral moraines have vertical surface offsets as great as 12.0 meters. Late Pleistocene to Holocene multiple-event fault scarps show little evidence of beveling, suggesting short seismic recurrence intervals and potential late Pleistocene and Holocene temporal clustering. Long-term average tectonic activity rates indicate slip rates ranging from 0.18–0.6 millimeters per year. Based on a comparison of fault-scarp height versus maximum slope angle of known regression lines developed from other paleoseismic investigations, the most recent event ranges from 5–1 ka. The northern section of the fault zone is defined by multiple normal faults, which detached the hanging walls of Laramide thrust faults within the Paleozoic and Mesozoic strata. This resulted in the partitioning of extension along multiple preexisting structures and less displacement along individual normal fault strands. Structural controls on lateral propagation of individual paleoevents involve the position of lateral ramps along preexisting Laramide contractional faults. This resulted in greater displacement within the larger basement-cored structures along the southern section of the fault zone, where extension is accommodated by one inferred principal basement-involved normal fault. Inferred east-northeast trending, intrabasin, normal faults within the southern half of the fault zone have no late Pleistocene displacement.

Idaho, Montana, Wyoming↗
USGS2025

Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper↗
USGS2024

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report↗
USGS2021

Geology, mineralogy, and cassiterite geochronology of the Ayawilca Zn-Pb-Ag-In-Sn-Cu deposit, Pasco, Peru

The Ayawilca deposit in Pasco, Peru, represents the most significant recent base-metal discovery in the central Andes and one of the largest undeveloped In resources globally. As of 2018, it hosts an 11.7 Mt indicated resource grading 6.9% Zn, 0.16% Pb, 15 g/t Ag, and 84 g/t In, an additional 45.0 Mt inferred resource grading 5.6% Zn, 0.23% Pb, 17 g/t Ag, and 67 g/t In, and a separate Sn-Cu-Ag inferred resource of 14.5 Mt grading 0.63% Sn, 0.21% Cu, and 18 g/t Ag. Newly obtained U–Pb dates for cassiterite by LA-ICP-MS (22.77 ± 0.41 and 23.05 ± 2.06 Ma) assign the Ayawilca deposit to the Miocene polymetallic belt of central Peru. The polymetallic mineralization occurs as up to 70-m-thick mantos hosted by carbonate rocks of the Late Triassic to Early Jurassic Pucará Group, and subordinately, as steeply dipping veins hosted by rocks of the Pucará Group and overlying Cretaceous sandstones-siltstones of the Goyllarisquizga Group. Relicts of a distal retrograde magnesian skarn and cassiterite (stage pre-A) were identified in the deepest mantos. The volumetrically most important mineralization at Ayawilca comprises a low-sulfidation assemblage (stage A) with quartz, pyrrhotite, arsenopyrite, chalcopyrite, Fe-rich sphalerite, and traces of stannite and herzenbergite. Stage A sphalerite records progressive Fe depletion, from 33 to 10 mol% FeS, which is compatible with the observed transition from low- to a subsequent intermediate-sulfidation stage (B) marked by the crystallization of abundant pyrite and marcasite. Finally, during a later intermediate-sulfidation stage (C) sphalerite (up to 11 mol% FeS), galena, native bismuth, Cu-Pb-Ag sulfosalts, siderite, Mn-Fe carbonates, kaolinite, dickite, and sericite were deposited. This paragenetic evolution shows striking similarities with that at the Cerro de Pasco Cordilleran-type polymetallic deposit, even if at Ayawilca stage C did not reach high-sulfidation conditions. The occurrence of an early retrograde skarn assemblage suggests that the manto bodies at Ayawilca formed at the transition between distal skarn and skarn-free (Cordilleran-type) carbonate-replacement mineralization. Mineral assemblages define a T- f S 2 evolutionary path close to the pyrrhotite-pyrite boundary. Buffering of hydrothermal fluids by underlying Devonian carbonaceous phyllites of the Excelsior Group imposed highly reduced conditions during stage A mineralization (log f O 2 < − 30 atm). The low f O 2 favored efficient Sn mobility during stages pre-A and A, in contrast to other known ore deposits in the polymetallic belt of central Peru, in which the occurrence of Sn minerals is minor. Subsequent cooling, progressive sealing of vein walls, and decreasing buffering potential of the host rocks promoted the shift from low- (stage A) to intermediate-sulfidation (stages B and C) states. LA-ICP-MS analyses reveal significant In contents in Fe-rich sphalerite (up to 1.7 wt%), stannite (up to 1908 ppm), and chalcopyrite (up to 1185 ppm). The highest In content was found in stage A sphalerite that precipitated along with chalcopyrite and stannite, thus pointing to the early, low-sulfidation assemblage as prospective for this high-tech metal in similar mineral systems. Indium was likely incorporated into the sphalerite crystal lattice via Cu + + In 3+ ↔ 2 Zn 2+ and (Sn, Ge) 4+ + (Ga, In) 3+ + (Cu + Ag) + ↔ 4 Zn 2+ coupled substitutions. Indium incorporation mechanisms into the stannite and chalcopyrite crystal lattices remain unclear.

Pasco↗
USGS2024

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment↗
USGS1976

Medicine Lodge thrust system, east-central Idaho and southwest Montana

The Medicine Lodge thrust system, exposed in east-central Idaho and southwest Montana, is a major segment of the North America Cordilleran fold and thrust belt on which Precambrian and Paleozoic rocks have been telescoped and transported far east of their depositional area. The fault has overlapped rocks that initially were deposited in differing sedimentary environments on opposite sides of the northwest-trending geanticlinal Lemhi arch. The nature of the arch itself has been obscured by later thrusting, but it can be roughly reconstructed as a major landmass recurrently uplifted from Precambrian Y time at least through the Mesozoic. Although sections of the large landmass have been identified in the past as small islands, it was instead a southern extension of Belt island, and exerted a major influence on sedimentation patterns. The thrust has obscured recognition of correlative sedimentary rock units. It also appears to have controlled the distribution of volcanic rocks in satellite centers of the main field of Challis Volcanics. The thrust system has exerted a major influence on the emplacement of granodiorite-quartz monzonite stocks and related mineral deposits in east-central Idaho. Recognition of the fault as a major influence in intrusive activity and deposition of metallic mineral deposits suggests new possibilities for mineral resource exploration in this region. And consideration of the stratigraphic, paleogeographic, and structural framework of sedimentary rocks beneath the thrust suggests the possibility of petroleum and natural gas resources in the region north of the Snake River Plain.

Idaho, Montana↗
USGS2025

Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S↗