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Extending the Boore and Abrahamson (2023) modified square-root-impedance method for the development of site amplifications consistent with the full-resonance approach to a range of VS30 values

The square-root-impedance (SRI) method is commonly used to approximate the seismic site amplifications computed using the full-resonance (FR) method for gradient shear-wave velocity ( V S ) profiles that are smoothly varying with depth. The SRI site amplifications have been observed to systematically underpredict the FR site amplifications by a ratio of FR/SRI amplifications around 1.05 to 1.3 across a wide frequency range (Boore, 2013). Recently, Boore and Abrahamson (2023; hereafter, BA23) related this difference in the SRI and FR methods to differences in the exponent η of the ratio of seismic impedances between the two methods. They proposed the implementation of a modified frequency-dependent η in the SRI method to improve its match to the FR site amplifications. This modified η was derived using only five V S profiles. We investigate the performance of the BA23 η for a wide range of realistic gradient V S profiles with V S30 ranging from 180 to 1500 m/s. These gradient V S profiles are constructed using two power-law functions of depth and are constrained by the assigned VS30 value, the depth and velocity of the half-space, and depths to shear-wave velocity horizons of 1.0 and 2.5 km/s ( Z 1.0 and Z 2.5 ) based on western United States sites. Despite observing a V S30 dependence of η, we find that the BA23 η generally works reasonably well for the range of V S profiles analyzed. Using the VS30 -dependent η derived in this study results in improvements in matching the FR site amplification compared to using the BA23 η. These improvements are more pronounced for the soft-site conditions and become modest to negligible for the stiff site conditions

Bulletin of the Seismological Society of America

New York and Landsat

From the iconic skyline of New York City to the forested landscapes of the Adirondack Mountains and the countryside of the Allegheny Plateau, the State of New York is overflowing with diversity and life. Bordered by the Atlantic Ocean on the east and two of the Great Lakes to the north and west, New York has more than 7,600 lakes, ponds, and reservoirs and more than 70,000 miles of rivers and streams. New York’s stewardship of its freshwater resources is fundamental to the health and well-being of all who work at, reside in, and visit the State’s landmarks and places. Harmful algal blooms in the State’s waterbodies are a growing concern and threaten the health of the region and its inhabitants. Images and data from Landsat satellites continue to provide critical information to scientists, public health officials, and resource managers who are studying the effects and risks of the problem.

New York

Map of topographic lineaments interpreted as recent surface ruptures along the Bennett Valley and Southern Maacama Fault Zones, Sonoma County, California

This study documents lidar-illuminated topographic lineaments interpreted as evidence of recent surface fault ruptures and surface ruptures related to distributed deformation along the Bennett Valley Fault Zone and the southernmost Maacama Fault Zone in the northern San Francisco Bay area (fig. 1, on map sheet). Together, these fault zones form a structural connection across a right stepover between the main Maacama Fault Zone and the Rodgers Creek Fault, overlapping principal strands of the San Andreas plate boundary system north of San Francisco Bay (figs. 1, 2, on map sheet) that accommodate about a quarter of the ~40 millimeters per year of regional dextral tectonic slip (Parsons and others, 2013). Although much of the Bennett Valley Fault Zone is seismically active (McLaughlin and others, 2012; Sowers and others, 2010), only the north end of the fault zone (the “Spring Valley strand,” indicated on southern map panel of map sheet and labeled “D” in figure 2, on map sheet) was previously known to have youthful geomorphic expression and to displace Holocene deposits (McLaughlin and others, 2008; Sowers and others, 2010; Sowers and others, 2016). Holocene activity along the length of the Bennett Valley Fault Zone and southernmost Maacama Fault Zone, with possible implications for rupture propagation, continuity, and slip transfer, had not been identified. However, fault splays that project eastward from the Rodgers Creek Fault have been mapped and hypothesized to accommodate slip transfer to the Bennett Valley Fault Zone (Hecker and Randolph Loar, 2018). The generally subtle and distributed nature of surface-rupture evidence along the Bennett Valley and southernmost Maacama Fault Zones, and extensive vegetation cover, had left recent faulting previously unmapped along most of the zone. The map presented here represents a new compilation of inferred surface-rupture features detected using high-resolution topographic lidar data from an airborne lidar survey of Sonoma County, California (OpenTopography, 2014). These data, which enable subtle topographic features to be discerned, indicate that recent (likely Holocene) surface ruptures extend throughout the Bennett Valley and southernmost Maacama Fault Zones. The rupture-lineament map was created using a GIS (geographic information system) framework and is included herein as an image map at a scale of 1:36,000 and as digital datasets (included as supplemental information to this report). The mapping is intended to lay the groundwork for future studies designed to better characterize how plate-boundary slip is accommodated on this important and complex system of faults.

California

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Assimilation of reduced carbon triggers platinum alloy saturation in mafic and ultramafic magmas

It is generally observed that magmatic sulfide ores have higher ratios of Pd/Pt than the mantle-like values of their parental magmas. This discrepancy has defied simple explanation because the partitioning behavior of both elements between sulfide and silicate liquids is very similar. Assimilation of sulfur- and carbon-rich country rocks by mafic and ultramafic magmas is considered a critical, if not essential, step in the formation of magmatic base metal sulfide deposits. Although there is general consensus that the assimilation of external sulfur and carbon promotes sulfide saturation, the effect of carbon assimilation on the solubilities of platinum-group elements in natural S-bearing silicate melt has been overlooked. In this study, we investigate the variations of platinum and palladium solubilities during assimilation of graphite and methane through thermodynamic modeling, in comparison with data from an array of highly distinctive magmatic sulfide ore systems representing ages from Archean to Paleozoic, melt compositions from komatiite to basalt, and magmatic settings including lavas, hypabyssal intrusions, plutonic continental arc roots, and plutonic layered intrusions, namely: Raglan, Norilsk-Talnakh, Lac des Iles, and the J-M Reef of the Stillwater Complex. We model assimilation-fractional crystallization processes to estimate the reduction of oxygen fugacity ( ⁠fO2⁠ ) of the melt due to incorporation of graphite and methane. The simulations show that although Pd remains highly soluble during the progressive assimilation of reduced carbon, Pt solubility decreases significantly as the silicate melt becomes increasingly reduced. With less than 8 % of sediment assimilation, Pt alloy may saturate and then deviate from sulfide-undersaturated silicate melts, concomitantly increasing the Pd/Pt value of the remaining melts of the Raglan and Norilsk-Talnakh systems. For the Lac des Iles and Stillwater systems, a higher extent of assimilation is needed to reach Pt saturation because of the relatively carbon-poor nature of the lower crustal rocks. The assimilation of methane volatiles is shown to be more effective than graphite assimilation, and it provides a pathway to Pt alloy fractionation in the absence of detectable amounts of bulk host-rock assimilation. High Pd/Pt values have been documented in many world-class magmatic sulfide deposits whose parental magmas have demonstrably experienced crustal contamination. Our model suggests that although anomalous Pd/Pt values may be explained by other mechanisms such as incongruent melting of preexisting sulfide or differences in the diffusivities of the metals within achieving equilibration, the assimilation of graphite or methane may play an important role in the global occurrence of magmatic sulfide ores with elevated Pd/Pt values.

Economic Geology

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research

A comparison of electronic particle counting and pipette techniques in routine mud analysis

Electronic particle counting and pipette size-analysis techniques are compared for their relative effectiveness in large-scale routine mud analysis. Optimum laboratory procedures for conducting electronic analyses with a Model TA Coulter Counter are presented. Comparative electronic and pipette analyses conducted on the same samples resulted in equivalent precision for both techniques. Results of electronic analyses consistently showed size distributions significantly coarser than those obtained by pipette analyses. The laboratory efficiency of the relatively rapid electronic technique is far superior to that of the pipette technique, although more extensive precautionary measures are required to maintain a high level of analytical accuracy and precision. The quality of electronic analyses largely depends upon the effectiveness of standardized operational procedures established within the laboratory.

Open-File Report

Technique for estimating magnitude and frequency of floods in Kentucky

This report presents flood magnitude and frequency relations applicable to unregulated streams in Kentucky. The relations are based on flood data at 117 gaging stations in Kentucky and 14 in adjacent states having 10 or more years of record not significantly affected by man-made changes. Equations that relate flood magnitude and frequency to contributing drainage area in 16 geographic areas may be used to estimate magnitude of future floods with recurrence intervals of as much as 100 years on gaged and ungaged streams having drainage areas of 10 to 4,300 square miles (25 .9 to 11,100 square kilometers) . Estimating equations are also presented in graphical form for the convenience of the user. Additional graphs are presented to estimate flood magnitude for selected recurrence intervals along the Cumberland, Kentucky, and Ohio Rivers.

Kentucky

Status of water-level altitudes and long-term and short-term water-level changes in the Chicot and Evangeline (undifferentiated) and Jasper aquifers, greater Houston area, Texas, 2024

Since the early 1900s, groundwater withdrawn from the primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers—has been an important source of water in the greater Houston area, Texas. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of water-level altitudes and water-level changes in these aquifers in the greater Houston area. In this report, the Chicot and Evangeline aquifers are treated as a single aquifer for the purposes of providing annual assessments of regional-scale water-level altitudes and water-level changes over time. In 2024, shaded depictions of estimated water-level altitudes for the Chicot and Evangeline aquifers (undifferentiated) ranged from about 301 feet (ft) below the North American Vertical Datum of 1988 (NAVD 88) to about 184 ft above NAVD 88. The largest decline in water-level altitudes depicted by the 1977–2024 long-term water-level-change map was in south-central Montgomery County. In comparison, the 1990–2024 long-term water-level-change map depicts the largest declines in water-level altitudes in an area northwest of The Woodlands and in an area of northern Waller County. The largest rise in water-level altitudes for 1977–2024 is depicted in an area of east-central Harris County, whereas the largest rise in water-level altitudes for 1990–2024 is depicted in an area of central Harris County. The 5-year short-term water-level-change map depicts the largest declines in several parts of the study area, but these declines are concentrated primarily in northern Fort Bend County, southwestern Harris County, and south-central Montgomery County. The largest rise for 2019–24 is depicted at a well in northern Fort Bend County. The 1-year short-term water-level-change map depicts the largest declines at a well in northern Fort Bend County and a well in west-central Harris County. The largest rise for 2023–24 is depicted at a well in east-central Fort Bend County. In 2024, shaded depictions of estimated water-level altitudes for the Jasper aquifer ranged from about 255 ft below NAVD 88 to about 321 ft above NAVD 88. The 2000–24 long-term water-level-change map depicts the largest water-level decline in an area of central San Jacinto County; the largest rise is depicted in an area of central Grimes County. The 5-year short-term water-level-change map depicts the largest declines across parts of central and southern Montgomery County and at one well in north-central Harris County. The largest rise for 2019–24 is depicted at a well centered on the Montgomery-Grimes County line. The 1-year short-term water-level-change map depicts the largest declines at two wells in south-central Montgomery County and one well in northwestern Montgomery County on the west side of Lake Conroe. The largest rises during 2023–24 are depicted at one well in northwestern Montgomery County and one well in south-central Montgomery County.

Texas

Ubiquity and causes of soil water preferential flow across 17 ecoregions

Preferential flow (PF) in soil causes the rapid transport of water, nutrients, and contaminants into the subsurface, influencing groundwater recharge and streamflow. Data scarcity has hindered the quantification of PF occurrence and the identification of its drivers across diverse ecoregions. We address this gap by analyzing high-frequency, multi-depth soil moisture data across 17 ecoregions in the USA, using ∼1,500 sensors at 40 sites. We discovered that PF is widespread, with sites experiencing PF in up to 60% of rainfall events ≥2 mm. Multiple approaches consistently show that PF is more likely to occur with increased peak rainfall intensity, finer textured material, low soil moisture variability, humid climate, and higher net primary productivity. This suggests that PF patterns could shift with projected climate changes, increasing uncertainty in predictions of groundwater recharge, water quality, and streamflow generation.

conterminous United States and Puerto Rico

Eruptive history within the vicinity of Al Madīnah in northern Harrat Rahat, Kingdom of Saudi Arabia

The northernmost part of the Harrat Rahat volcanic field contains early Pleistocene to Holocene mafic eruptive products within the vicinity of the city of Al Madīnah, Kingdom of Saudi Arabia. A detailed geologic investigation into the eruptive history of a 570 square kilometer (km 2 ) area covering Al Madīnah and the surrounding area has yielded 33 mapped Quaternary volcanic units consisting of lava flows, scoria cones, and shield volcanoes. These eruptive products consist of continental, intraplate alkalic and minor transitional basalts, hawaiites, and a single mugearite that were emplaced from at least 1,014±14 thousand years ago (ka) to a single Holocene eruption in 1256 C.E. Lava flows are generally 10 to 15 kilometers (km) long (but can reach 23 km long), 1 to 3 km wide, and at least 10 meters thick. Most of the mapped units erupted episodically between 400 and 340 ka and 180 and 100 ka. Despite small individual volumes (less than 1 cubic kilometers dense rock equivalent), each unit represents eruption of a distinct magma batch that was strongly influenced by clinopyroxene, olivine, and plagioclase fractionation. Some of these units are interpreted to have undergone magma mixing pre- and (or) syneruptively. Integrating eruption ages, geochemistry, and paleomagnetic data yields evidence that some eruptions were temporally and (or) spatially clustered. Aligned scoria cones and elongate vent edifices were constructed atop fissure vent systems that reflect the local stress field, which controls dike ascent through the middle and upper crust.

Professional Paper

Low-sulfidation epithermal deposits of the central Basin and Range Province, USA

The Basin and Range Province is host to many important low-sulfidation epithermal deposits. Within this broad zone of extension, epithermal deposits are hosted by specific areas of Miocene and younger bimodal volcanism. In northern Nevada, rifting and related volcanic activity occurred in response to thermal bulging during the development of the Yellowstone hotspot. The Colorado River Extensional Corridor in southern Nevada, adjoining eastern California and northwestern Arizona, is a major zone of Miocene crustal extension formed during the transformation of the western margin of North America from a convergent to a transform plate boundary. The style of mineralization in the low-sulfidation epithermal deposits in these areas is strongly controlled by the nature of the volcanic successions. Highgrade, low-tonnage deposits are commonly found in flow-dominated volcanic successions where ore deposition occurred through short-lived periods of fluid flashing. In contrast, low-grade, large-tonnage deposits are more commonly located in clastic-dominated successions where fluid infiltration of the permeable hosts and cooling predominated.

Arizona, California, Nevada, Oregon

Mechanics and statistics of postseismic shaking

Analysis of two weeks of continuous post-seismic shaking after the 2019 M7.1 Ridgecrest, CA earthquake sequence using 4 nearby borehole seismometers reveals that continuous ground motions decay as Omori’s law in time and follow the Gutenberg-Richter distribution in logarithmic amplitude. The measured temporal decay in amplitudes agrees with predictions of the rate-and-state framework and indicates shaking amplitudes are proportional to the velocity of afterslip. Our ground motion-based statistical framework provides a basis to forecast shaking intensity in the minutes to hours after a large earthquake.

California

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida

Introduction and methods of analysis for peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods Report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. Flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done by the U.S. Geological Survey, in cooperation with the Departments of Transportation of Illinois, Iowa, Michigan, Minnesota, Missouri, South Dakota, and Wisconsin; the Montana Department of Natural Resources and Conservation; and the North Dakota Department of Water Resources, to assess potential nonstationarity in peak flows in the north-central United States. This chapter summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. A wide range of analyses and statistical approaches are applied to document the primary mechanisms controlling floods and characterize temporal changes in hydroclimatic variables and peak flow. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The climate data consist of monthly time series estimates of temperature, precipitation, potential evapotranspiration, actual evapotranspiration, snowfall, soil moisture storage, snow water equivalent, and runoff on a 3.1-mile by 3.1-mile grid for the conterminous United States. Statistical and graphical analyses were used to investigate potential changes in hydrology and climate. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. To examine potential causal drivers of changes, the climate data were analyzed graphically and statistically. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Iowa, Illinois, Michigan, Missouri, Minnesota, Mon

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou