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Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas

Cross section N–N' through the Valley and Ridge province of the southern Appalachian basin, from Greene County, west-central Alabama, to Bibb County, central Alabama

Introduction Geologic cross section N–N′ is the sixth in a series of geologic cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section N–N′ provides a regional view of the structural and stratigraphic framework of the Appalachian basin in the Valley and Ridge province in western and central Alabama; it spans approximately 69 miles (mi) (111 kilometers [km]). This geologic cross section is a companion to geologic cross sections E–E′ , D–D′ , C–C′ , I–I′ , and A–A′ that are located approximately 350 to 550 mi (563 to 885 km) to the northeast. Cross section N–N' complements earlier geologic cross sections through the Alabama part of the Appalachian basin. Although some of the other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section N–N′ contains information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and petroleum migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. In addition, cross section N–N′ may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Alabama

Distributed volcanic fields—Patterns, products, processes, and plumbing

Distributed volcanic fields—also referred to as “monogenetic fields” or simply “volcanic fields”—are found on every continent, on the seafloors, and in every tectonic setting on Earth. Yet, our understanding of what constitutes a distributed volcanic field, and our knowledge of the common products, spatiotemporal patterns in activity, and plumbing systems of these fields, are commonly poor and (or) debated. Here we provide an overview of the current understanding of distributed volcanic fields (DVFs) through review and compilation of published data, with an emphasis on understanding the characteristics of fields that are essential to prepare for future hazardous volcanic activity. Distributed fields can erupt restricted to variable magma compositions. Activity in these fields produces nearly all types of volcanoes, including scoria and spatter cones, maars, low shields, lava fields, stratovolcanoes, and calderas, but monogenetic volcanoes are the defining characteristic of DVFs. The number of vents and lifespans of DVFs vary greatly; vent numbers range from 2 to greater than 1,000, and fields can remain active for 150,000 to 10 million years. Some characteristics of DVFs appear field dependent. Although the volumes of single monogenetic eruptions within DVFs globally are variable (from less than 0.1 to a few cubic kilometers), each field may have a characteristic range in eruption volumes. Eruptions within distributed volcanic fields can have a random distribution and timing, but spatial and (or) temporal vent clustering and alignment are common, and eruptions may be time or volume predictable. Average eruption recurrence intervals in DVFs span over an order of magnitude, from less than 3 to greater than 100 thousand years. Exposures of the shallow portions of older systems reveal that many magma batches end their ascent before reaching the surface, with some dikes stopping within only meters of the surface. Petrologic insights into the deeper plumbing systems of DVF volcanoes indicate variable depths of magma crystallization and (or) stalling, and that magma transport and storage systems may be unique to a particular DVF and its underlying crustal structure. Both seismic and petrologic data for mafic DVF eruptions corroborate intrusions of magma into storage systems in the months to years before eruption, as well as variable ascent rates through the crust (days to weeks). Few distributed fields are closely monitored, as they erupt infrequently, but these observations imply that the amount of time available to install monitoring instrumentation after the first felt seismicity may be short, as precursory activity is frequently on the order of days to months for modern DVF eruptions. Satellite-based geodesy may provide useful warning in such cases. This chapter concludes with outstanding questions and areas for future research that will aid in our understanding and preparedness for future DVF eruptions.

Professional Paper

The geometry of fault reactivation and uplift along the central part of the Maacama fault zone, northern California Coast Ranges (USA)

Fault reactivation of bedrock structures in active fault zones influences stress state and earthquake rupture phenomena through the introduction of weak slip surfaces that impact fault zone geometry and width. Yet, geometric relationships between modern faults and older reactivated faults are difficult to quantify in rocks that have experienced multiple deformation episodes. We used new geologic mapping, geomorphic tools, and structural modeling to quantify rock uplift and subsurface fault geometry of the central part of the Maacama Fault Zone near Ukiah, California, USA, and the surrounding area. Results suggest that the northern Mayacamas Mountains are in a tectonically driven disequilibrium, with differential rock uplift focused on the western side of the range. Steeply east-dipping fault surfaces and splays characterize the geometry of the Maacama Fault Zone. We mapped two newly identified faults to the east of the main Maacama Fault, the Cow Mountain–Mill Creek Fault, and Willow Creek Fault, which align with a moderately east-dipping cluster of microseismicity between 4–10 km depth beneath the Mayacamas Mountains. Static stress modeling on the Maacama Fault Zone and newly identified faults to the east quantify slip tendency values of 0.5–0.4, which suggests that the faults are moderately to poorly suited for slip in the modern stress field and may be weak. We infer that modern uplift is driven by oblique reverse, up-to-the-east, dip-slip motion on the reactivated Cenozoic Cow Mountain–Mill Creek and Willow Creek Faults as material is advected through a restraining bend on the Maacama Fault. This study shows that reactivated bedrock faults increase the fault zone width and introduce fault surfaces that contribute a component of vertical deformation and uplift in major strike-slip fault zones. Deformation is accommodated on an interconnected network of new and reactivated faults that delineate a complex seismic hazard.

California

Estimation of magnitude and frequency of floods for streams in Puerto Rico: New empirical models

Flood-peak discharges and frequencies are presented for 57 gaged sites in Puerto Rico for recurrence intervals ranging from 2 to 500 years. The log-Pearson Type III distribution, the methodology recommended by the United States Interagency Committee on Water Data, was used to determine the magnitude and frequency of floods at the gaged sites having 10 to 43 years of record. A technique is presented for estimating flood-peak discharges at recurrence intervals ranging from 2 to 500 years for unregulated streams in Puerto Rico with contributing drainage areas ranging from 0.83 to 208 square miles. Loglinear multiple regression analyses, using climatic and basin characteristics and peak-discharge data from the 57 gaged sites, were used to construct regression equations to transfer the magnitude and frequency information from gaged to ungaged sites. The equations have contributing drainage area, depth-to-rock, and mean annual rainfall as the basin and climatic characteristics in estimating flood peak discharges. Examples are given to show a step-by-step procedure in calculating a 100-year flood at a gaged site, an ungaged site, a site near a gaged location, and a site between two gaged sites.

Puerto Rico

3D Dynamic rupture modeling of the 6 February 2023, Kahramanmaraş, Turkey Mw 7.8 and 7.7 earthquake doublet using early observations

The 2023 Turkey earthquake sequence involved unexpected ruptures across numerous fault segments. We present 3D dynamic rupture simulations to illuminate the complex dynamics of the earthquake doublet. Our models are constrained by observations available within days of the sequence and deliver timely, mechanically consistent explanations of the unforeseen rupture paths, diverse rupture speeds, multiple slip episodes, heterogeneous fault offsets, locally strong shaking, and fault system interactions. Our simulations link both earthquakes, matching geodetic and seismic observations and reconciling regional seismotectonics, rupture dynamics, and ground motions of a fault system represented by 10 curved dipping segments and embedded in a heterogeneous stress field. The M w 7.8 earthquake features delayed backward branching from a steeply branching splay fault, not requiring supershear speeds. The asymmetrical dynamics of the distinct, bilateral M w 7.7 earthquake are explained by heterogeneous fault strength, prestress orientation, fracture energy, and static stress changes from the previous earthquake. Our models explain the northward deviation of its eastern rupture and the minimal slip observed on the Sürgü fault. 3D dynamic rupture scenarios can elucidate unexpected observations shortly after major earthquakes, providing timely insights for data‐driven analysis and hazard assessment toward a comprehensive, physically consistent understanding of the mechanics of multifault systems.

The Seismic Record

A scientific vision and roadmap for earthquake rupture forecast developments, a USGS perspective

We articulate a scientific vision and roadmap for the development of improved Earthquake Rupture Forecast models, which are one of the two main modeling components used in modern seismic hazard and risk analysis. One primary future objective is to provide fully time-dependent models that include both elastic rebound and spatiotemporal clustering nationwide, which is particularly important for shorter-term hazard and risk considerations (e.g., earthquake insurance products). We also discuss the importance and perennial challenges associated with quantifying epistemic uncertainties, including those associated with deformation-model slip rates, un-quantified sampling errors with respect to off-fault seismicity, and any spatial covariances. The need for more physics-based approaches is also emphasized, as is the benefit of adding model valuation (quantifying usefulness) to our verification and validation protocols. Given the multidisciplinary and system-level nature of this activity, modular design is critical. Future updates will also draw from best-available science by both the United States Geological Survey and the external community. The primary goal of this paper is to highlight plans that guide research and facilitate community engagement with model development, especially with respect to lowering the entry barrier for early career scientists and engineers. The paper is written so readers can focus on the sections that interest them most (see table of contents), with the Introduction and Discussion providing a stand-alone overview and summary.

Bulletin of the Seismological Society of America

High-resolution magnetic survey using an unoccupied aerial vehicle to constrain buried lava flow geometry, volume, and eruptive history of Little Cones, Crater Flat, Nevada

Magnetic surveys are an important tool used to augment geologic mapping in distributed volcanic fields. Using magnetic anomalies, it is possible to model the geometry of shallowly buried volcanic features, such as conduits, sills, and lava flows. This subsurface mapping is important for understanding eruption dynamics and emplacement of lava flows, and it sometimes reveals buried volcanoes no longer visible at the surface. These data are critical to better interpret the numbers, styles, and magnitudes of eruptions in distributed volcanic fields and their associated volcanic hazards. New advances in unoccupied aerial vehicles (UAVs) offer an attractive middle range of resolution and aerial coverage between ground-based magnetic surveys and aeromagnetic surveys. Here, we present the results of a UAV fluxgate magnetic survey of the Little Cones, Nevada, scoria cones, which have been the target of previous ground and aeromagnetic surveys. The magnetic anomalies at Little Cones are of interest because the surrounding alluvium conceals lava flows that erupted from Little Cones, making it very difficult to understand the volume and morphology of lava flows from geologic mapping alone. Nonlinear inversion of UAV-collected magnetic data were used to model the thickness and morphology of buried Little Cones’ lava flows with higher precision than achieved previously. The sequence of events and calculated flow characteristics are then interpreted. The total volume of Little Cones, including concealed lava flows, is approximately 0.016 cubic kilometer, and the initial sheet flow erupted in less than 24 hours. The findings presented herein demonstrate that UAV-based magnetic surveys are a reliable method of data collection and an efficient alternative to other survey methods, facilitating development of a three-dimensional perspective of distributed volcanic fields.

Nevada

Petrogenesis and mineralization potential of spinifex komatiitic basalts in the Bradley Peak greenstone terrane, Wyoming Province

Komatiitic volcanic rocks are important hosts of Ni sulfide mineralization and record early Earth evolution; however, those in the well-studied Archean Wyoming Province have received little attention. Here, we elucidate the timing and petrogenesis of the Bradley Peak komatiitic volcanic rocks using field and textural observations, geochronology, and geochemistry. Detrital and igneous zircon U-Pb ages for two samples from previously undated units support published age determinations, placing the eruption age at 2.72 Ga. Stratigraphy of the volcanic flows was mapped and 36 samples including cumulates, greenschists, and spinifex-textured rocks were collected. Whole-rock geochemistry was used to classify the spinifex-textured samples as Al-undepleted komatiitic basalts (11–17 wt% MgO). Platinum-group element concentrations (n = 25) are like those in global Al-undepleted komatiitic basalts, and PGE/Ti ratios do not indicate the volcanic flows likely host sulfide mineralization. Initial ε Nd values of −0.5 to +4.7 (n = 16), indicate that these lavas were derived from a depleted mantle source and have negligible evolved crust contamination. The primary magma to the komatiitic basalt flows is estimated to have had 19 wt% MgO and be derived from ∼15 to 25 % mantle partial melting at 3–4 GPa. Trace element chemistry and thermodynamic modeling suggest the primary melt assimilated local banded iron formation. Although the Bradley Peak komatiitic basalts do not contain positive evidence of magmatic sulfide deposits, depleted Au in the flows suggests they could be source rocks for nearby orogenic gold deposits.

Wyoming

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California

Assessment and characterization of ephemeral stream channel stability and mechanisms affecting erosion in Grand Valley, western Colorado, 2018–21

The Grand Valley in western Colorado is in the semiarid Southwest United States. The north side of the Grand Valley has many ungaged ephemeral streams, which are of particular interest because (1) the underlying bedrock geology, Late Cretaceous Mancos Shale, is a sedimentary rock deposit identified as a major salinity contributor to the Colorado River and (2) despite infrequent streamflows of short duration, monsoon-derived floods in these ephemeral streams can carry substantial amounts of sediment downstream, affecting upstream and downstream banks and channel cross sections. The study area is of interest, because salinity, or the total dissolved solids concentration, in the Colorado River causes an estimated $300 million to $400 million per year in economic damages in the United States, and it is estimated 62 percent of the Upper Colorado River Basin’s total dissolved solid loads originate from geologic sources. In an effort to minimize salt contributions to the Colorado River from public lands administered by the Bureau of Land Management, a comprehensive salinity control approach is typically used to reduce nonpoint sources of salinity through land management techniques and practices. In 2018, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, began an assessment of ephemeral streams located on the north side of the Grand Valley, western Colorado, to characterize stream channel stability and identify mechanisms affecting erosion. The U.S. Geological Survey developed a method for automatically extracting channel cross-section geometry from existing remotely sensed terrain models. Based on estimated flood stage and surrogate streamflows, hydraulic characteristics were calculated. Furthermore, the channel geometries and hydraulic characteristics were used to estimate channel stability using a statistical model. Cross-section stabilities were determined from a stream channel stability assessment for a subset of 1,406 visited (field observed) locations out of 13,415 cross sections, which were delineated from remotely sensed terrain models. The application of Manning’s resistance equation in combination with multiple logistic regression models demonstrated channel stability can be estimated with a 0.845 goodness of fit for a validation dataset when using a combination of drainage area, width-to-depth ratio, sinuosity, and shear stress as the explanatory variables. Stream channel stability was extrapolated for 13,415 unvisited (not field observed) cross sections using the multiple logistic regression model and defined explanatory variables. Mapping of the ephemeral streams and their associated stabilities may be used by the Bureau of Land Management to prioritize areas for remediation or changes in management strategies to reduce sediment and salinity loading to the Colorado River. The study found channel stability within the ephemeral streams to be spatially variable, longitudinally discontinuous, and dictated by changes in channel bed slope. The stable ephemeral streams were relatively wide and shallow and often had smaller drainage areas with less potential for producing shear stresses capable of overcoming channel adhesion. A change in channel bed slope can provide the means necessary to generate shear stresses appropriate to initiate erosion and a subsequent stability transition to incising channels. Channel widening happens when either or both banks of an incising channel reach a critical height for mass wasting, or when channel curvature causes higher sidewall stress. Regardless, widening channels can promote increases in sinuosity and subsequently reduce steep channel bed slopes. Consequently, stable and widening channels can have comparable bed slopes, making channel bed slope a poor explanatory variable to predict channel stability overall, despite its function to initiate channel instability. The results were based on a surrogate 0.10 annual exceedance probability (AEP; return period equal to the 10-year flood) interval streamflow, although it was recognized fluctuations in streamflow would also affect channel stability. Past and current changes within the study area affect streamflow; therefore, mechanisms affecting erosion include land use disturbances, soil compaction, loss of vegetation cover, drought, less frequent and more extreme precipitation, and fires—which all intensify the potential runoff and erosion within the study area.

Colorado

Telecommunications fiber for sensing earthquake aftershocks: Progress and hurdles

Aftershocks offer valuable clues to earthquake behavior. The challenge: quickly deploying sensors to capture the early details of earthquake ruptures within the zone of aftershocks. Telecommunication fibers might be an answer, providing denser networks in otherwise difficult areas, potentially faster than traditional methods.

Conference Paper

Modeled groundwater and surface-water interactions surrounding Mobile Bay, Alabama, 2008–15

The U.S. Geological Survey, in cooperation with the Gulf Coast Ecosystem Restoration Council, has used MODFLOW 6 to develop a groundwater-flow model to simulate groundwater and surface-water interactions in the Mobile Bay, Alabama, area. The model results indicated that, on average, groundwater discharge near the coastline is equal to 2.5 percent of the surface water that flows into the bay. The model was also used to determine how changes in recharge, sea level, and groundwater pumping affect groundwater levels and discharge rates. The results indicate that more groundwater discharge occurred in the winter and spring when recharge was higher, sea level was lower, and groundwater pumping was lower than during the summer and fall. Additionally, the amount of emergent groundwater was closely related to sea level; when sea level was higher, there was more area with emergent groundwater. Furthermore, the depth of nonemergent groundwater was related to trends in recharge and pumping. During periods of increased recharge and reduced pumping, a significant portion of the model area exhibited a depth to the water table of less than 1 meter below the land surface. Conversely, during periods of decreased recharge and heightened pumping, much of the model area showed a depth to the water table ranging from 1 to 5 meters.

Alabama, Mississippi

Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York

Medicine Lodge thrust system, east-central Idaho and southwest Montana

The Medicine Lodge thrust system, exposed in east-central Idaho and southwest Montana, is a major segment of the North America Cordilleran fold and thrust belt on which Precambrian and Paleozoic rocks have been telescoped and transported far east of their depositional area. The fault has overlapped rocks that initially were deposited in differing sedimentary environments on opposite sides of the northwest-trending geanticlinal Lemhi arch. The nature of the arch itself has been obscured by later thrusting, but it can be roughly reconstructed as a major landmass recurrently uplifted from Precambrian Y time at least through the Mesozoic. Although sections of the large landmass have been identified in the past as small islands, it was instead a southern extension of Belt island, and exerted a major influence on sedimentation patterns. The thrust has obscured recognition of correlative sedimentary rock units. It also appears to have controlled the distribution of volcanic rocks in satellite centers of the main field of Challis Volcanics. The thrust system has exerted a major influence on the emplacement of granodiorite-quartz monzonite stocks and related mineral deposits in east-central Idaho. Recognition of the fault as a major influence in intrusive activity and deposition of metallic mineral deposits suggests new possibilities for mineral resource exploration in this region. And consideration of the stratigraphic, paleogeographic, and structural framework of sedimentary rocks beneath the thrust suggests the possibility of petroleum and natural gas resources in the region north of the Snake River Plain.

Idaho, Montana

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico

Effects of septic-tank effluent on ground-water quality in northern Williamson County and southern Davidson County, Tennessee

An investigation of the potential contamination of ground water from septic tank systems blasted in bedrock in Williamson and Davidson Counties, Tennessee, was conducted during 1988-89. Water samples were collected from domestic and observation wells, springs, and surface-water sites in a residential subdivision in the northern part of Williamson County near Nashville. The subdivision has a high density of septic-tank field lines installed into blasted bedrock Water samples also were collected from a well located in an area of Davidson County where field lines were installed in 5 feet of soil. Samples were analyzed for major inorganic constituents, nutrients, total organic carbon, optical brighteners, and bacteria. Although results of analyses of water samples from wells indicate no effect of septic-tank effluent on ground-water quality at these sites, water from two springs located downgradient from the subdivision had slightly larger concentrations of nitrite plus nitrate (2.2 and 2.7 milligrams per liter N), and much larger concentrations of fecal coliform and fecal streptococci bacteria (2,000 to 3,200 and 700 to 900 colonies per 100 milliliters of sample, respectively), than other wells and springs sampled during 1988. Water from one of these springs contained optical brighteners, which indicates that septic-tank effluent is affecting ground-water quality.

Tennessee