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Profiles of gamma-ray and magnetic data for aerial surveys over parts of the Western United States from longitude 108 to 126 degrees W. and from latitude 34 to 49 degrees N.

This CD-ROM contains images generated from geophysical data, software for displaying and analyzing the images and software for displaying and examining profile data from aerial surveys flown as part of the National Uranium Resource Evaluation (NURE) Program of the U.S. Department of Energy. The images included are of gamma-ray data (uranium, thorium, and potassium channels), Bouguer gravity data, isostatic residual gravity data, aeromagnetic anomalies, topography, and topography with bathymetry. This publication contains image data for the conterminous United States and profile data for the conterminous United States within the area longitude 108 to 126 degrees W. and latitude 34 to 49 degrees N. The profile data include apparent surface concentrations of potassium, uranium, and thorium, the residual magnetic field, and the height above the ground. The images on this CD-ROM include graytone and color images of each data set, color shaded-relief images of the potential-field and topographic data, and color composite images of the gamma-ray data. The image display and analysis software can register images with geographic and geologic overlays. The profile display software permits the user to view the profiles as well as obtain data listings and export ASCII versions of data for selected flight lines.

Data Series

Statistical approaches for modeling correlated grade and tonnage distributions and applications for mineral resource assessments

Correlations between grade and tonnage exist in mineral resource data compiled from published reports, but they are not always addressed during quantitative assessment of undiscovered mineral resources. Failure to account for correlated grade and tonnage distributions can result in geologically unrealistic assessment results. Current software tools simulate univariate ore tonnage and multivariate resource grades of undiscovered deposits independently. As a result, analysts are forced to rely on ad-hoc solutions to minimize the correlation issues by: 1) creating subsets of data with restricted criteria; 2) truncating grade and tonnage distributions; and 3) testing model robustness using exploratory data analysis. While these methods represent pragmatic solutions, the statistical solutions presented here provide additional options to address real correlations in grade and tonnage data used for mineral resource assessments. We present a modified version of the MapMark4 package in R that introduces two alternatives for modeling grade and tonnage distributions, consisting of a multivariate solution that accounts for correlations between ore tonnage and metal grades and an empirical solution that utilizes simple random sampling with replacement to reproduce coupled grades and tonnages from the input data. We present simulations for contained ore and metal for three case studies representing tungsten skarn, komatiite-hosted nickel, and sediment-hosted carbonate amagmatic zinc-lead (Mississippi Valley-type) deposits. Employing the methods presented here yields quantitative mineral resource assessment results that more closely reflect the empirical distributions of grades and tonnages observed in nature and expands the applicability of these tools for ongoing critical mineral resource assessments.

Applied Computing and Geosciences

Methods and guidelines for effective model calibration; with application to UCODE, a computer code for universal inverse modeling, and MODFLOWP, a computer code for inverse modeling with MODFLOW

This report documents methods and guidelines for model calibration using inverse modeling. The inverse modeling and statistical methods discussed are broadly applicable, but are presented as implemented in the computer programs UCODE, a universal inverse code that can be used with any application model, and MODFLOWP, an inverse code limited to one application model. UCODE and MODFLOWP perform inverse modeling, posed as a parameter-estimation problem, by calculating parameter values that minimize a weighted least-squares objective function using nonlinear regression. Minimization is accomplished using a modified Gauss-Newton method, and prior, or direct, information on estimated parameters can be included in the regression. Inverse modeling in many fields is plagued by problems of instability and nonuniqueness, and obtaining useful results depends on (1) defining a tractable inverse problem using simplifications appropriate to the system under investigation and (2) wise use of statistics generated using calculated sensitivities and the match between observed and simulated values, and associated graphical analyses. Fourteen guidelines presented in this work suggest ways of constructing and calibrating models of complex systems such that the resulting model is as accurate and useful as possible.

Water-Resources Investigations Report

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts

Stable isotope composition and geochemistry of calcite and dolomite in the Mountain Pass carbonatite: A lens into petrogenesis

Carbonatites host most of the global rare earth element (REE) deposits. The petrogenesis of these rocks, including magmatic and post-magmatic processes, are poorly understood but critical in forming and upgrading these deposits. The Mountain Pass carbonatite, which hosts the only active REE mine in North America, is lithologically variable but consistently contains >50% calcite and/or dolomite. Multiple generations of carbonates are evident, suggesting bulk analysis of carbonate minerals would generate a mixed isotopic and geochemical signature. In-situ stable carbon and oxygen isotopes, combined with geochemical analysis and petrography, distinguish carbonate generations, trace the source region of the carbonatite magma, and link carbonate genesis to REE mineralization throughout the intrusion. Primary carbon and oxygen isotope values outside the accepted mantle range may suggest a subduction-related carbon and oxygen source in the mantle. Deformation textures in primary calcite indicate syn- or post-crystallization ductile flow. Carbonates with secondary textures and heavy δ 13 C and δ 18 O values are associated with ore mineralization, suggesting fluid mobilization was important in concentrating REE and upgrading of the Mountain Pass deposit.

California

Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming

Tungsten skarn quantitative mineral resource assessment and gold, rare earth elements, graphite, and uranium qualitative assessments of the Kuldjuktau and Auminzatau Ranges, in the central Kyzylkum region, Uzbekistan

A new quantitative mineral resource assessment for tungsten skarn was conducted for the Auminzatau and Kuldjuktau mountain ranges in Central Uzbekistan, along with qualitative assessments of orogenic gold, rare earth elements (REEs), amorphous graphite, and uranium. By integrating a variety of geological, geochemical, geophysical, and remote sensing data sets, estimates of undiscovered tungsten skarn deposits in permissive tracts are combined with grade and tonnage distributions of known deposits to generate probabilistic estimates of undiscovered resources. Undiscovered deposits in Auminzatau are estimated to contain median resources of 98 thousand metric tons (kt) of WO 3 with a 70 percent (%) probability of at least 28 kt and a 10% probability of at least 468 kt, of which 16 kt to 293 kt may be economic to extract. In Kuldjuktau, the undiscovered deposits are estimated to contain median resources of 27 kt of WO 3 with a 60% probability of at least 12 kt and a 10% probability of at least 208 kt, of which 5 kt to 132 kt may be economic to extract. Our results suggest that the Auminzatau–Kuldjuktau Mountains area is highly prospective for additional discovery of significant Au and U resources and has low prospectivity for discovery of significant REE and graphite resources.

Minerals

Integrating habitat suitability and climate constraints to predict nonnative fish invasion risk for U.S. streams and inland lakes

Introduction: Nonnative fishes in streams and inland lakes can substantially alter aquatic ecosystems by degrading habitat conditions, competing with native species, and restructuring food webs. Identifying invasion hotspots can inform proactive management and prevention of nonnative species establishment. Methods: In this study, we identified streams and lakes across the conterminous United States that are vulnerable to invasion by 18 nonnative stream and 28 nonnative lake fish species. Habitat suitability models were developed separately for stream and lake species across nine ecoregions using natural and anthropogenic predictors, and species occurrences were predicted by integrating model results with climate match scores based on comparisons between environmental conditions in species’ native and potential nonnative ranges. We classified areas with both high habitat suitability and strong climate similarity as having high invasion potential and generated hotspot maps by stacking species-level predictions. Results: Florida exhibits the highest invasion risk for both habitat types. Stream hotspots were concentrated near major metropolitan areas, whereas lake hotspots were more widely distributed across the Great Lakes basin and the northeastern U.S. Twelve species were predicted to invade both habitat types, with goldfish ( Carassius auratus ) and pirapitinga ( Piaractus brachypomus ) showing particularly high invasion potential. Discussion: These findings provide a comprehensive assessment of nonnative freshwater fish invasion risk and support targeted monitoring and management strategies.

conterminous United States

Monazite and xenotime U-Pb geochronology and thermometry of the Blue Ridge and Inner Piedmont of North Carolina: Implications for the thermal-metamorphic evolution of the southern Appalachian metamorphic “core”

The southern Appalachian orogen preserves a complex distribution of metamorphism and deformation varying in timing, magnitude, and spatial extent. These complexities give rise to disparate interpretations for southern Appalachian tectonic evolution, which complicates the testing and interpretation of tectonic models in this system. New monazite (Mnz) and xenotime (Xtm) laser ablation split stream (LASS) analyses alongside Mnz-Xtm thermometry in the orogenic core in the eastern Blue Ridge (EBR), western Inner Piedmont (WIP), and Cat Square terranes (CST) of North Carolina yield new constraints that define distinct pro- and retrograde metamorphic events. The EBR preserves two prograde thermal events: the Taconic (∼470-440 Ma, >660°C) and Neoacadian (∼380-340 Ma, 600–700°C), separated by a period of cooling (exhumation?) and followed by garnet breakdown from 339 to 329 Ma. Evidence of pervasive Neoacadian ductile deformation in the EBR is largely limited to the Brevard fault zone (BFZ), indicating that a major rheological gradient existed across the BFZ during the Neoacadian and early Alleghanian. Southeast of the BFZ, in the WIP and CST, monazite data define a protracted Neoacadian evolution from early mineral growth at ∼405 Ma at ∼450–600°C to >700°C at ∼360 Ma, followed by early Alleghanian retrograde metamorphism and deformation (<345 Ma, 350–500°C). These constraints, together with previously reported thermobarometric data, define a P-T-t evolution for the WIP and CST consistent with Neoacadian crustal flow, while the coeval presence of a thermal-rheological boundary along the BFZ further supports a model of Neoacadian crustal “escape” flow within the orogen.

North Carolina

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia

The Long Island Sound and Watershed Metadata map application

The Long Island Sound and its watershed encompass an area of about 17,000 square miles and include the Connecticut, Housatonic, and Thames Rivers, which all drain to the sound. Dozens of organizations from government agencies, nonprofits, and Tribal Nations have developed projects and monitoring programs to analyze and protect the water resources of the watershed and sound. The abundance of data and lack of an existing searchable index require a centralized metadata repository to allow users to find water resources data more efficiently. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Long Island Sound Study, has created an interactive map application to visualize and search for metadata information across organizations working to monitor and protect the Long Island Sound.

Connecticut, Massachusetts, New Hampshire, New Yor

New York and Landsat

From the iconic skyline of New York City to the forested landscapes of the Adirondack Mountains and the countryside of the Allegheny Plateau, the State of New York is overflowing with diversity and life. Bordered by the Atlantic Ocean on the east and two of the Great Lakes to the north and west, New York has more than 7,600 lakes, ponds, and reservoirs and more than 70,000 miles of rivers and streams. New York’s stewardship of its freshwater resources is fundamental to the health and well-being of all who work at, reside in, and visit the State’s landmarks and places. Harmful algal blooms in the State’s waterbodies are a growing concern and threaten the health of the region and its inhabitants. Images and data from Landsat satellites continue to provide critical information to scientists, public health officials, and resource managers who are studying the effects and risks of the problem.

New York

Cambrian and Ordovician stratigraphy, conodont biostratigraphy, and microfacies analysis to support 1:24,000-scale geologic mapping of the southern Lake Champlain valley, New York and Vermont

Introduction Geologic mapping in the southern Lake Champlain valley of New York and Vermont (fig. 1) has required evaluation of stratigraphic nomenclature used since the early 1900s. The paleogeography of the Cambrian and Ordovician adjacent to the Adirondack Highlands, the high-relief mountains of Proterozoic igneous and metamorphic rocks of northern New York, has impacted the lithostratigraphic succession, facies changes, and several hiatuses that occur within the package of clastic and carbonate rocks that demonstrates overall deepening consistent from the southern to northern Appalachians. The stratigraphic nomenclature used for the geologic mapping of the Cambrian and Ordovician strata of the study area is derived from evaluation of names put forth by previous workers from areas of northern New York and western Vermont. Descriptions of type localities or type sections and other criteria set forth by the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature [NACSN], 2021) were consulted. The North American Stratigraphic Code states that lithostratigraphic units, such as the fundamental unit, the formation, be defined by lithic character and be mappable (NACSN, 2021, Article 24). However, some early workers (Walcott, 1912; Kay, 1937; Fisher and Hanson, 1951; Oxley and Kay, 1959) have defined stratigraphic units based on fossil content, which may or may not be facies dependent, and hence may not be mappable as lithostratigraphic units. Although preservation of older names takes priority in stratigraphic nomenclature (NACSN, 2021, Article 7), some do not have adequately defined stratotypes or are located a distance away with different lithologies than that in the study area. Biostratigraphy can be a helpful tool for understanding correlations and facies changes. Herein, conodont biostratigraphy is utilized to date and correlate separate lithologic units. Further, microfacies analyses of units through inspection of petrographic thin sections provide paleogeographic information that helps in understanding the genesis of geologic units.

New York, Vermont

Uppermost Oligocene and Miocene diatom biostratigraphy of Ocean Drilling Program Sites 682 and 688 from the Peru Margin

The diatom biochronology of ODP (Ocean Drilling Program) Holes 682A and 688E provides a detailed framework for refiningMiocene diatom zonation in the East Pisco Basin of southern Peru, establishing both a nearly complete offshore reference section and a correlation tool for the fragmentary onshore vertebrate-bearing deposits. This new biostratigraphic record documents a complete succession of low latitude and/or northeastern Pacific Miocene diatom zones, with two notable exceptions: a dissolution and/or hiatus interval (*16.5–14 Ma) during the Middle Miocene Climatic Optimum and a likely earliest Miocene hiatus (*23.4–21.8 Ma). Although eastern equatorial Pacific diatom zones characterize the Upper Oligocene and Lower Miocene strata, an increased abundance of cool-water diatoms that lived during the Middle and Late Miocene allows better application of northeast Pacific diatom zones, except during the Messinian (7–6 Ma) when warm-water diatoms predominate. The effects of eustatic sea level and tectonics on depositional sequences in the EPB and in offshore cores off central Peru are discussed.

Stratigraphy

Detection of viral, bacterial, and protozoan pathogens and microbial source tracking markers in paired large- and small-volume water samples

When sampling for waterborne microbes, researchers may need to diverge from recommended sample volumes due to logistical constraints, novel targets, or challenging matrices, with little guidance about the potential impact on results. In field studies, we measured bacteria, viruses, and protozoa (15 quantitative polymerase chain reaction assays) in paired large- and small-volume samples to evaluate method performance and relevant factors. Concordance between methods was low. Large-volume ultrafiltration yielded more detections than small-volume sampling, especially for pathogens in groundwater. Greater microbial concentrations were associated with more frequent detections in small-volume samples and greater concordance between paired samples. Large-volume samples appeared to be more susceptible to diminished sensitivity from complex sample matrices. In laboratory studies, recovery of microbes was poorer for large- than small-volume methods, although large-volume methods more reliably detected low-concentration targets. Large-volume samples were less stable than small-volume samples during storage. Overall, large-volume sampling was superior for detecting pathogens but may underestimate concentrations; small-volume sampling was more prone to false negatives but was adequate when concentrations were relatively high, like we observed for microbial source tracking in surface waters.

Wisconsin

Apatite geo-thermochronology and geochemistry constrain Oligocene-Miocene growth and geodynamics of the northeastern Tibetan Plateau

Understanding the geodynamics of plateau evolution requires examining the spatial and temporal aspects of mountain building in the northeastern Tibetan Plateau, which are still under debate. Here we integrate apatite geo-thermochronological and geochemical data from the Oligocene-Miocene succession of the Xunhua Basin to elucidate the evolution of the regional topography. The results suggest sediment provenance changes, at ca. 28, 20 and 12 Ma, indicating topographic growth of the West Qinling, Laji Shan, and Jishi Shan source areas, respectively. Our findings reveal Oligocene-Miocene stepwise deformation and middle Miocene stress reorganization within the northeastern Tibetan Plateau. We attribute this to Oligocene lithospheric foundering beneath the south-central Tibetan Plateau and the middle Miocene initiation of sinistral strike-slip faults due to the underthrusting of India and North China. This study highlights the roles of lithospheric removal and continental underthrusting in plateau growth, and the value of multi-proxy apatite analyses in provenance studies.

Northeastern Tibetan Plateau

Petrography and mineralogy of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Florida is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains. These strata have accumulated since Middle Jurassic time. The pre-Middle Jurassic, or basement, rocks that underlie the Coastal Plain in Florida are known only from drill cores and cuttings recovered from a relatively small number of boreholes. This data report presents petrographic observations and the results of X-ray diffraction analyses of basement rocks from 18 boreholes across Florida in support of the identification, discrimination, and correlation of units for a subcrop geologic map of pre-Middle Jurassic rocks composing Florida’s sub-Coastal Plain geology.

Florida