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USGS2025

Emerging investigator series: Post-wildfire sediment geochemical characterization reveals manganese reactivity and a potential link to water quality impairment in the Gallinas Creek watershed, New Mexico

Water quality post-wildfire is often impaired by increased turbidity and elevated concentrations of elements such as manganese (Mn) and iron (Fe). Precipitation events exacerbate these issues, due in part to increased erosion and transport of sediment from hillslopes to surface water. Both Mn and Fe are major redox-active elements in sediments that drive a variety of biogeochemical cycles, precipitate adsorptive phases, and can themselves be drinking water contaminants. By investigating Mn and Fe sediment geochemistry in post-wildfire sediment deposits, related water quality hazards can be assessed. To establish and strengthen this connection, we analyzed the geochemistry of sediment deposits and surface water in the Gallinas Creek watershed, New Mexico over 1.5 years post-wildfire. Analyses included particle size analysis, water extractions, sequential extractions and aqua regia extractions to determine metal partitioning in sediment deposits. Data demonstrate Mn concentrations were distributed across labile and reactive fractions, such as the exchangeable and oxyhydroxide fractions, while Fe concentrations were mainly associated with the residual fraction. Manganese concentrations in aqua regia extractions and several fractions of sequential extractions were also strongly and significantly correlated with fine-grained sediment while the same pools of Fe concentrations were not. Dissolved Mn concentrations in surface water were elevated (>50 μg L −1 ) multiple times over the 1.5 years post-wildfire, highlighting a relationship between sediment geochemistry and water quality. This work shows Mn in sediments mobilized post-wildfire has an influence on water quality and highlights how further investigation into Mn sediment redox processes and mineralogy post-wildfire can inform risk assessments and resource management.

New Mexico↗
USGS2026

Season and antecedent conditions impact concentration-discharge relationships for dissolved organic carbon and alkalinity in southeast Alaskan watershed

Fluvial export of dissolved carbon plays an important role in watershed-scale biogeochemistry. Predicted changes in climate are expected to impact watershed hydrologic regimes, and in turn, the sources and export of dissolved carbon from watersheds. Here, we utilize high resolution measurements of discharge and dissolved carbon concentration to examine how concentration-discharge (CQ) relationships vary seasonally and during high flow events over the main runoff season (May–October) in a temperate forested watershed in Southeast Alaska. Concentration-discharge relationships for dissolved organic carbon (DOC) and alkalinity demonstrated strong seasonal patterns, with more linear relationships in May and June versus other months. Changing power law model slopes ( b values; the exponent in a power law regression between runoff and carbon yields) indicated potentially shifting watershed sources (biogenic vs. geologic) and contrasting dominant flowpaths (shallow vs. deeper groundwater) for DOC and alkalinity over the sampling period. During the largest storm event of the study, DOC and alkalinity b values shifted from an overall pattern of transport (mean b = 1.58 values >1.0 indicate transport limitation) and source limitation (mean b = 0.48, values <1.0 indicate source limitation) to chemostatic (DOC, b = 0.99; alkalinity, b = 1.019). In June through August, patterns in hysteresis index suggest that CQ relationships were altered when storms followed in close succession to each other. Together, these findings indicate that seasonal and antecedent flow conditions play a role in dissolved carbon export from forested watersheds. Understanding these dynamics, particularly during winter months, will become increasingly important as changes to hydroclimate impact riverine carbon export.

Alaska↗
USGS2026

Post-fire soil hydrologic response and recovery in northern California (USA)

Background Wildfires abruptly change landscapes by altering soil properties and vegetation cover. These changes are thought to reduce soil infiltration capacity, making landscapes susceptible to runoff and erosion. However, post-fire soil response is complex and likely varies across locations and time. Aims Here, we aim to understand regional post-fire soil response and recovery by tracking changes across different northern California (USA) lithology and vegetation types. Methods We conducted repeat in situ soil infiltration tests for 3 years post-fire at 31 burned and 10 unburned sites spanning the 2021 Dixie, 2020 LNU Lightning Complex, 2020 Walbridge and 2020 Glass fires. Key results Our two main findings are: (1) burned chaparral soils have increased hydraulic conductivity compared with unburned sites, and (2) infiltration rates return to pre-fire conditions within 3 years across most lithologies and vegetations. Conclusions Recovery might be generalizable by vegetation and lithology but differ regionally, making it important to identify meaningful hydrologic response units (HRUs). Multi-year studies with paired burned and unburned measurements can constrain the recovery timeline and provide information missed by observations solely of burned soils. Implications Understanding where, and for how long, soil remains susceptible to runoff and erosion can help prioritize areas and time periods most in need of mitigation.

California↗
USGS2024

Methods for quantifying interactions between groundwater and surface water

Driven by the need for integrated management of groundwater (GW) and surface water (SW), quantification of GW–SW interactions and associated contaminant transport has become increasingly important. This is due to their substantial impact on water quantity and quality. In this review, we provide an overview of the methods developed over the past several decades to investigate GW–SW interactions. These methods include geophysical, hydrometric, and tracer techniques, as well as various modeling approaches. Different methods reveal valuable information on GW–SW interactions at different scales with their respective advantages and limitations. Interpreting data from these techniques can be challenging due to factors like scale effects, heterogeneous hydrogeological conditions, sediment variability, and complex spatiotemporal connections between GW and SW. To facilitate the selection of appropriate methods for specific sites, we discuss the strengths, weaknesses, and challenges of each technique, and we offer perspectives on knowledge gaps in the current science.

Annual Review of Environment and Resources↗
USGS2024

Spatial distribution of API gravity and gas/oil ratios for petroleum accumulations in Upper Cretaceous strata of the San Miguel, Olmos, and Escondido Formations of the south Texas Maverick Basin—Implications for petroleum migration and charge history

The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.

Texas↗
USGS2025

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho↗
USGS2026

Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis

Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.

Michigan, Wisconsin↗
USGS2026

Early Miocene volcanic rocks and associated tectonics, Lava Hills and southern Bristol Mountains, California

Volcanic rocks of latest Oligocene to early Miocene age form an east-west belt across part of the central eastern Mojave Desert from the Whipple Mountains on the east to the Rosamond Hills on the west. We term this the central belt because it is separated from northern and southern belts by swaths with no volcanic rocks. Limited geochronologic data indicate that much of the belt is latest Oligocene and early Miocene in age, about 24 to 19 Ma, a finding that is consistent with these rocks being overlain by the 18.8 Ma Peach Spring Tuff in many places. We describe Miocene geology in a central area of the belt, in the Lava Hills, southern Bristol Mountains, and southern Old Dad Mountains. Sedimentary basins formed coeval with early andesite to rhyolite volcanism, progressing from fluvial and lacustrine tuffaceous sandstone to volcanic lavas, tuffs, and breccias, indicating that early basins formed proximal to volcanic edifices. Higher strata are fluvial and lacustrine with lavas punctuating the sequence. Although basins may partly have been formed within topographic lows bounded by volcanic domes, plateaus, and stratovolcanoes, consistent stratigraphic sections over wide areas indicate that tectonic basin evolution affected broad areas. The volcanic section is capped by local basalt flows and the regional Peach Spring Tuff. Limited data on normal faults support interpretations of early extensional basin development caused by northeast-southwest oriented stretching. Later extension caused stratal rotations, tilting early deposits down to the southwest. This tilted and subsequently beveled basin architecture was overlain by the youngest volcanic deposits, primarily rhyolite and basalt. The Peach Spring Tuff, 18.8 Ma, lies within this upper unit. Similar stratigraphic and structural relations are exposed in the nearby Marble Mountains and Van Winkle Mountain sections, reinforcing that a broad area underwent similar volcanism and tectonism. In our study area the upper unit is only very gently tilted except near dextral strike-slip faults of the eastern California shear zone. These late Miocene to Recent faults are represented as four main fault zones spaced about 5 km apart, representing distributed shear north of the Bristol Lake basin.

California↗
USGS2025

A generalized deep learning model to detect and classify volcano seismicity

Volcano seismicity is often detected and classified based on its spectral properties. However, the wide variety of volcano seismic signals and increasing amounts of data make accurate, consistent, and efficient detection and classification challenging. Machine learning (ML) has proven very effective at detecting and classifying tectonic seismicity, particularly using Convolutional Neural Networks (CNNs) and leveraging labeled datasets from regional seismic networks. Progress has been made applying ML to volcano seismicity, but efforts have typically been focused on a single volcano and are often hampered by the limited availability of training data. We build on the method of Tan et al. [2024] ( 10.1029/2024JB029194 ) to generalize a spectrogram-based CNN termed the VOlcano Infrasound and Seismic Spectrogram Neural Network ( VOISS-Net ) to detect and classify volcano seismicity at any volcano. We use a diverse training dataset of over 270,000 spectrograms from multiple volcanoes: Pavlof, Semisopochnoi, Tanaga, Takawangha, and Redoubt volcanoes\replaced (Alaska, USA); Mt. Etna (Italy); and Kīlauea, Hawai`i (USA). These volcanoes present a wide range of volcano seismic signals, source-receiver distances, and eruption styles. Our generalized VOISS-Net model achieves an accuracy of 87 % on the test set. We apply this model to continuous data from several volcanoes and eruptions included within and outside our training set, and find that multiple types of tremor, explosions, earthquakes, long-period events, and noise are successfully detected and classified. The model occasionally confuses transient signals such as earthquakes and explosions and misclassifies seismicity not included in the training dataset (e.g. teleseismic earthquakes). We envision the generalized VOISS-Net model to be applicable in both research and operational volcano monitoring settings.

Volcanica↗
USGS2026

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv↗
USGS2026

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming↗
USGS2025

Estimated average annualized losses from potential building damage and fatalities due to earthquake-generated tsunamis in the United States

Earthquake-generated tsunamis represent substantial economic threats to states and territories in the United States (U.S.), but we are unaware of any effort to quantify potential impacts at the national level. This gap is partially due to the lack of nationally consistent data on tsunamigenic sources and associated return periods. This study addresses this issue and provides estimates of average annualized losses (AAL) for potential residential fatalities and capital stock losses associated with building damage (i.e., structural, non-structural, contents, and inventory damage) in the U.S. by curating tsunami-hazard information based on deterministic scenarios and probabilistic approaches, calculating potential losses, and estimating return periods where necessary. This assessment was done for the U.S. West Coast, Alaska, Hawaii, U.S. Pacific Territories, and U.S. Atlantic Territories. We estimate that earthquake-generated tsunamis that could affect these states and territories collectively represent $1 billion in potential AAL with 79 % of losses due to residential fatalities and 21 % of losses due to capital stock losses from building damage. We identify AAL variations based on county and county equivalents, states and territories, geographic regions, return periods, and departure-delay assumptions for evacuating residents. Results include high AAL values for potential fatalities in Puerto Rico and the U.S. Pacific Northwest region, high AAL values for potential building-related damage in Hawaii and California, and high building- and population-loss ratios for county equivalents in Alaska and U.S. territories.

International Journal of Disaster Risk Reduction↗
USGS2025

Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods↗
USGS1997

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS2025

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana↗
USGS2024

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research↗
USGS2026

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont↗
USGS2025

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado↗