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Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California

Fiber-optic distributed temperature sensing of hydrologic processes—Diverse deployments and new applications by the U.S. Geological Survey

Fiber-optic distributed temperature sensing instruments harness the temperature-dependent properties of glass to measure temperature continuously along optical fibers by using precise pulses of laser light. In the mid-2000s, this technology was refined for environmental monitoring purposes such as snowpack-air exchange, groundwater/surface-water exchange, and lake-water stratification. Fiber-optic distributed temperature sensing has revealed unprecedented details about preferential flow processes; however, the method is labor intensive and requires specific training, resulting in limited use by the broader water community. With the ongoing national implementation of the U.S. Geological Survey Next Generation Water Observing System, there has been renewed interest in harnessing the unique spatiotemporal monitoring capabilities of fiber-optic distributed temperature sensing. This fact sheet briefly describes this technology, highlights uses by the U.S. Geological Survey, and discusses current applications and future opportunities.

Fact Sheet

Uranium and trace elements in stream sediments as an exploration tool

More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.

Open-File Report

Quantitative evaluations of earthquake early warning performance using “Did You Feel It?” and post-alert surveys

We examine responses to the U.S. Geological Survey’s “Did You Feel It?” (DYFI) survey and its companion earthquake early warning (EEW) questionnaire to assess the performance of the U.S. ShakeAlert EEW system directly from the alert recipients’ perspectives. ShakeAlert rapidly detects earthquakes and develops alert information, but as official alert delivery partners issue these alerts, it is thus difficult to determine how many people were alerted and when. We investigate DYFI reports for six California earthquakes that had EEW alerts and substantial responses to the DYFI EEW questionnaire. Comparisons of ShakeAlert predictions to reported intensities demonstrate that magnitude estimation accuracy is not necessarily indicative of ground-motion prediction accuracy. Perceived warning time distributions indicate that estimating maximum-expected warning times using the S-wave arrival is a reasonable assumption when discussing public EEW performance. However, we also find many reports of shorter warning times, late alerts, and missed alerts than expected based on ShakeAlert publication times, suggesting alert delivery latencies are substantial and highly variable. The novelty of our analysis is that we demonstrate that the DYFI EEW survey provides useful EEW efficacy information—independent of the specific alerting pathway—that can be used to inform our choices for conveying EEW performance.

California

Testing rate‐and‐state predictions of aftershock decay with distance

We analyze aftershocks of the 2019 M 7.1 Ridgecrest mainshock and isolated M 5–6 mainshocks in southern California to test predictions made by the rate‐and‐state friction model of Dieterich (1994) . Rate‐and‐state friction predicts that the seismicity rate after a stress step follows Omori decay, where the Omori c ‐value, which is the saturation in aftershock rate observed at small times, is larger for smaller stress steps. Put in the context of an aftershock sequence, this predicts that the Omori c ‐value will be systematically larger at greater distances from the mainshock. To our knowledge, this predicted effect has not been observed. In part this may be because the Omori c ‐value is difficult to measure because it often reflects short‐term catalog incompleteness rather than a true saturation in aftershock rate. We explore the dependence of the Omori c ‐value on the distance to the mainshock by applying the “ a ‐positive” method ( van der Elst and Page, 2023 ). This method is insensitive to short‐term aftershock incompleteness and allows resolution of the true aftershock rate deep into the mainshock coda. For aftershocks of the Ridgecrest mainshock and stacked M 5–6 mainshocks, we observe systematic differences in early aftershock rates, relative to mainshock distance, consistent with the predictions of rate‐and‐state friction. Furthermore, for the larger Ridgecrest dataset, we observe that aftershocks nearer to the mainshock start earlier, and we resolve a flattening of the Omori curve consistent with a larger Omori c ‐value for the farthest aftershocks, as predicted by Dieterich (1994) .

Seismological Research Letters

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Tracing fluid evolution during batholith and deposit formation: In-situ and bulk rock Mo isotopes from the Questa porphyry Mo deposit, New Mexico, USA

The Oligocene Questa porphyry Mo deposit, located in New Mexico, USA, is a well-characterized system that formed over 400 kyr, punctuating the 8 Myr formation of the Questa-Latir batholith. Detailed sampling of the intrusions and minerals associated with magmatichydrothermal mineralization, as well as bookending barren intrusions, allows for examination of the Mo isotope record of the deposit and its host batholith. Through this established chronologic framework, such data can yield insights into the metallogenesis of deposit formation and long-term magma genesis evolution for upper crustal magmatism. The Mo isotopic compositions of barren intrusions yield a younging trend towards lighter δ 98 Mo. However, intrusions associated with Mo deposit formation yield heavier δ 98 Mo relative to barren magmatism, by up to 2.0‰. This indicates that they were affected by an isotopically heavy and Mo-rich fluid. The in-situ data from molybdenite covers the range observed in mineralized bulk rocks. However, individual samples consistently yield Mo isotopic variations of 0.4‰ to 0.5‰. The consistency of the δ 98 Mo variation in in-situ analyses of molybdenite within hand samples and individual mineral grains is likely the result of MoS 2 crystallization in a closed system and reflects an almost complete precipitation of Mo.

New Mexico

Seismic moment and local magnitude scales in Ridgecrest, CA from the SCEC/USGS Community Stress Drop Validation Study

We illustrate the systematic difference between moment magnitude and local magnitude caused by underlying earthquake source physics, using seismic moments submitted to the Statewide California Earthquake Center/United States Geological Survey Community Stress Drop Validation Study 2019 Ridgecrest data set. While the relationship between seismic moment and moment magnitude ( M or M w ) of log 10 ( M 0 ) ~ 1.5* M is uniformly valid for all earthquake sizes by definition (Hanks and Kanamori, 1979), the relationship between local magnitude M L and moment is itself magnitude dependent. For moderate events, ~3< M < ~6, M and M L are coincident; for earthquakes smaller than ~3, M L ~ 1.0 log 10 M 0 (Hanks and Boore, 1984). This is a physical consequence of the corner frequency fc becoming larger than the upper frequency of observation and implies that M L and M differ systematically by a factor of 1.5 for these small events. While this idea is not new, we propose a new, continuous relationship between local magnitude and moment, for magnitudes 2 to 6 which extrapolates to smaller and larger magnitudes, applicable to southern California specific to the Ridgecrest region. We make use of the plethora of seismic moments as submitted by many participants of the Community Stress Drop study, compared to the Southern California Seismic Network (SCSN) catalog magnitudes. Overall, the seismic moments in the Community Study recover moment magnitude well, so we use our new M L - M 0 to convert M L to M , refining the SCSN operational M Lr scale. This systematic difference of 50% in slope between local and moment magnitude at small magnitudes has implications for spectral stress drop estimates, earthquake ground motion modeling, as well as other magnitude scales and earthquake occurrence statistics.

California

Estimation of dynamic geologic CO2 storage resources in the Illinois Basin, including effects of brine extraction, anisotropy, and hydrogeologic heterogeneity

Since the vast majority of carbon dioxide (CO 2 ) storage resources in the United States are in deep saline aquifers, optimizing the use of these saline storage resources could be crucial for efficient development of geologic CO 2 storage (GCS) resources and basin- or larger-scale deployment of GCS in the country. Maximum CO 2 injection rates can be enhanced by extracting brine from the CO 2 storage unit. However, disposal of the extracted brine is both a technological and economic challenge. The lowest-cost option would likely be reinjection of the extracted brine into another formation above or below the CO 2 storage unit. Therefore, it is important to estimate brine injectivity as it will constrain the potential to increase CO 2 injectivity at an injection site that has access to multiple geologic storage units where either CO 2 or brine can be injected. Using a simulation-optimization framework, coupled with a non-isothermal, multiphase CO 2 -water-salt equation-of-state module, we developed a computationally efficient method for evaluating optimization of simultaneous CO 2 injection, brine extraction, and brine (re)injection at hypothetical injection sites deployed across a geologic basin. The Illinois basin is ideal for testing our methodology because it contains multiple geologic storage units with seals in between them to isolate injection of CO 2 in one unit from interfering with the injection of either brine or CO 2 in another unit above or below it. In addition, we investigated the relative effects of variation in key geologic parameters as well as two reservoir structures (hydrogeologic heterogeneity/anisotropy and homogeneity/isotropy) on CO 2 injectivities and enhancement of CO 2 injectivity through extracting brine. Results suggest that permeability, depth, and especially thickness of the storage unit could be the most influential parameters determining CO 2 injectivity. They also suggest that only injecting CO 2 into the storage unit with the greatest injectivity, enhancing that unit’s injectivity by extracting brine, and disposing of the produced brine in other suitable units could maximize total CO 2 injectivity in limited regions of the basin. At the majority of simulated injection sites, however, we found that injecting CO 2 into all of the accessible and suitable storage units was more likely to maximize the CO 2 storage resource.

Illinois, Kentucky, Indiana

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Post-glacial stratigraphy and late Holocene record of great Cascadia earthquakes in Ozette Lake, Washington, USA

Ozette Lake is an ~100-m-deep coastal lake located along the outer coast of the Olympic Peninsula (Washington, USA); it is situated above the locked portion of the northern Cascadia megathrust but also relatively isolated from active crustal faults and intraslab earthquakes. Here we present a suite of geophysical and geological evidence for earthquake-triggered mass transport deposits (MTDs) and related turbidite deposition in Ozette Lake since ca. 14 ka. Comprehensive high-resolution bathymetry data, seismic reflection profiles, and sediment cores are used to characterize the post-glacial stratigraphic framework and examine paleoseismic evidence in the lacustrine sediments. Stacked sequences of MTDs along the steep eastern flanks of the lake appear to grade basin-ward from thick, chaotic, blocky masses to thin, parallel-bedded turbidite beds. The discrete turbidite event layers are separated by fine-grained (silt and clay) lake sedimentation. The event layers are observed throughout the lake, but the physical characteristics of the deposits vary considerably depending on proximity to primary depocenters, steep slopes, and subaqueous deltas. A total of 30–34 event deposits are observed in the post-glacial record. Radiometric dating was used to reconstruct a detailed sedimentation history over the last ~5.5 k.y., develop an age model, and estimate the recurrence (365–405 yr) for the most recent 12 event layers. Based on sedimentological characteristics, temporal overlap with other regional paleoseismic chronologies, and recurrence estimates, at least 10 of the dated event layers appear to be sourced from slope failures triggered by intense shaking during megathrust ruptures; the recurrence interval for these 10 events is 440–560 yr. Thus, Ozette Lake contains one of the longest and most robust geological records of repeated shaking along the northern Cascadia subduction zone.

Washington

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri and Mississippi Rivers on the periphery of Missouri, June 13–22, 2022

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near seven bridges at six highway crossings of the Missouri and Mississippi Rivers on the periphery of Missouri from June 13–22, 2022. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 feet longitudinally and generally extending laterally across the active channel from bank to bank during minor flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a minor flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All bridge sites in this study were surveyed and documented in previous studies. Although partial exposure of substructural support elements was observed at several piers, at most sites the exposure most likely is minimal compared to the overall substructure that remains buried in bed material at these piers. The notable exceptions are piers 12 and 13 at structure L0135 on State Highway 51 at Chester, Illinois, where the bedrock material was fully exposed around the piers. The average difference between the bathymetric surfaces between 2022 and 2018 varied from 0.41 foot higher to 1.86 feet lower. Between 2022 and 2014, the average difference between the bathymetric surfaces varied from 1.02 feet higher to 4.69 feet lower. Only the two sites on the Missouri River and the Caruthersville site were surveyed in 2011; for those sites, the average difference between the bathymetric surfaces varied from 5.83 feet higher to 1.34 feet lower. The most substantial overall net gain of sediment in a reach was between 2011 and 2022 at structure A1700 near Caruthersville, Mo. (site 38). This result was expected because structure A1700 is downstream from the confluences of the Missouri and Ohio Rivers, and therefore subject to the largest streamflows, the largest streamflow fluctuations, and the most substantial sediment flux, as has historically been observed at this site. The presence of riprap blankets, pier size and nose shape, and alignment to flow had a substantial effect on the size of the scour hole observed for a given pier. Piers that were surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers at which no rock or riprap were present. New riprap blankets were surveyed at pier 3 of structure L0098 at Brownville, Nebraska, and at piers 15–18 of structure A1700 near Caruthersville, Mo., that effectively mitigated the scour holes historically observed at these piers. Narrow piers having round or sharp noses that were aligned with flow often had scour holes that were difficult to discern from nearby bed features, whereas piers having wide or blunt noses resulted in larger, deeper scour holes. Several of the structures had piers that were skewed to primary approach flow. Scour holes near these piers consistently displayed greater depth on the side of the pier with impinging flow and deposition on the leeward side of the pier.

Missouri

Analysis of aquifer framework and properties, Alvahs Lane well field, Cutchogue, New York

The U.S. Geological Survey, in cooperation with the Suffolk County Water Authority, evaluated the aquifer transmissivity and storage properties at the Alvahs Lane well field north of the village of Cutchogue, New York. This analysis of aquifer properties provides the Suffolk County Water Authority with hydrogeologic information needed to develop water supplies to meet the increasing water demands of the residents of Suffolk County, New York. An aquifer test was conducted at the Alvahs Lane well field from October 18 through October 21, 2022, when a production well was pumped at 550 gallons per minute for about 24 hours, and groundwater-level drawdown and recovery were measured in two monitoring wells. The three wells are screened in a glaciofluvial aquifer under unconfined (water table) conditions. Drawdown and recovery data were analyzed with an analytical solution for partial penetration and delayed yield in an unconfined aquifer to provide estimates of the glaciofluvial aquifer properties. Inclusion of lateral aquifer boundaries was not necessary for the analysis to result in satisfactory matches with the observed water-level responses. Aquifer transmissivity was estimated at 32,000 feet squared per day. Assuming a saturated aquifer thickness of 120 feet, this result is equivalent to a horizontal hydraulic conductivity value of 270 feet per day. Specific yield was estimated at 0.15 (dimensionless). The estimated properties are consistent with those of a highly transmissive unconfined aquifer.

New York

Generalized potentiometric maps of the Fort Union, Hell Creek, and Fox Hills aquifers within the Standing Rock Reservation

Generalized potentiometric surfaces of the Fort Union, Hell Creek, and Fox Hills aquifers were constructed to assess the groundwater resources of the Standing Rock Reservation. Additionally, this information can provide water managers with tools and data to effectively manage water resources in the future. Previous studies that mapped the geology and hydrogeology of the area at differing scales were used to confirm in which aquifer the study wells were completed. Water-level data from wells are provided by the U.S. Geological Survey Groundwater System Inventory database, the South Dakota Department of Agriculture and Natural Resources, and the North Dakota Department of Water Resources. Hydrographs were constructed for five selected observation wells to evaluate historical water-level fluctuations and trends. Hydrographs for the Hell Creek aquifer showed a flat trend with a rise in 2020. Hydrographs for the deeper Fox Hills aquifer showed that water levels fluctuated in response to climatic conditions and demonstrated an increasing trend in water-level elevations starting in 2010. Hydrographs were not constructed for any wells completed in the Fort Union Formation because none of the wells had continuous long-term measurements. Generalized potentiometric surfaces, constructed from interpolating water-level elevations, gave insight into groundwater flow directions. Groundwater in the Fort Union aquifer likely flows radially outward from the northwest part of the study area to the northeast and south-southeast parts. Groundwater in the Hell Creek aquifer generally flows from higher elevations in the northwest towards lower areas, where surface-water tributaries have incised into the aquifer. Groundwater in the Fox Hills aquifer likely flows from higher elevations in the west, southwest, and central parts of the study area towards the valleys of the Grand River and Missouri River. Most wells used for constructing potentiometric maps had only one recorded water-level measurement from drillers at the time of well construction. These measurements are often subject to error because the well is still recovering and because of spatial limitations of data availability. Also, because single water-level measurements were recorded at different points in time, additional uncertainty is introduced by fluctuating climatic conditions effect on water levels. Potentiometric map interpretation limitations are a result of areas with sparse data. Limitations also arise from potentiometric surfaces generalizing a complex and dynamic hydrogeologic system; however, the generalized potentiometric surface maps can be used to assist water managers and can help prioritize locations for future monitoring in areas with high uncertainty from sparse existing data.

North Dakota, South Dakota

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois

Macroseismology

In this chapter I discuss the use of so-called macroseismic data, i.e., reports of damage and other effects of shaking on humans and the built environment, to improve the characterization of earthquakes and the ground motions they produce. Macroseismic data are critical not only to investigate earthquakes that occurred before the start of the instrumental era in seismology, but are also, by virtue of the spatially rich nature of the data, of tremendous potential importance to investigate early instrumental and even recent earthquakes. Fueled by both the advent of on-line systems that now produce unprecedented volumes of macroseismic intensity data and by recognition of the importance of understanding key historical earthquakes, there has been a growing appreciation for the value of macroseismic data. It is, however, critical to understand both the unique challenges and the unique opportunities associated with these data. I review the evolution of thought and practices regarding analysis of macroseismic data, and the use of such data to improve the characterization of historic and early instrumental earthquakes.

Book chapter