USGS ScienceSearch

SEARCH · USGS Science

Results for “General Information Product”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

831 records · Page 41Linked to original sources

Syn-magmatic subsidence during the early stages of continental rifting in the Mesoproterozoic—A reanalysis of legacy data for the Midcontinent Rift, western Lake Superior

The Midcontinent Rift system (ca. 1.1 Ga) is a 2000-km-long series of elongated volcanic and sedimentary troughs and associated intrusive centers exposed chiefly in the Lake Superior region of North America. The rift system represents a long history of intense magmatism and subsequent sedimentation that was arrested by far-field tectonic events before sea-floor spreading was established. The premature cessation preserved a record of processes related to the beginning of continental rifting. The rift system under Lake Superior has been long studied using seismic-reflection data collected as part of the Great Lakes International Multidisciplinary Program on Crustal Evolution (GLIMPCE). We reexamine GLIMPCE Line C by developing a detailed velocity model for time to depth conversion constrained by other legacy data. We corroborate the model and develop a geologic interpretation using gravity and magnetic modeling and ties to geology mapped onshore. We recognize superposed subsiding sedimentary and volcanic basins for the southern half of the Line C depth section. This interpretation differs from previous paradigms that show major crustal faults that bound half-grabens or full grabens. We conclude that high-velocity (6.9 km/s) intrusive zones rather than major crustal faults border the sides of the basins. We speculate that the volcanic basin represents the initiation of seaward dipping reflectors. The syn-magmatic subsidence can be explained by dike injection and volcanic loading. Discrete lava basins throughout the region likely subsided at different times in a disorganized manner along the rift trend, raising questions about the long-term role of lithospheric thinning and melt generation.

Michigan, Minnesota, Ontario, Wisconsin

Developing international standards and guidelines for disseminating and validating simulated ground motions

We are leading an effort to develop international standards and guidelines for curating, disseminating, and validating simulated ground-motion data. This effort is organized as a working group within the Consortium of Organizations for Strong Motion Observation Systems (COSMOS). In 2022 we held online workshops on 7 and 8 June and 20 October. The first workshop focused on curating and disseminating simulated ground-motion data. The second workshop focused on validating simulated ground-motions for engineering applications. About 100 people participated in each of the workshops with strong representation from North America, Europe, and western Asia. In the coming year, we intend to form a technical committee to draft the international guidelines and standards while continuing to engage stakeholders from across the globe through online and in-person meetings. The key points from the workshops include: (1) Numerous groups are generating simulated earthquake ground motions and making them openly available; however there is very little coordination among groups to provide consistent interfaces for searching and retrieving data; (2) Standardizing interfaces for metadata and data access should consider agile approaches that can adapt to changing capabilities and user needs while building upon existing efforts; (3) A distributed architecture is preferred by most participants to allow institutions to host and manage their own data while broadcasting their holdings to a combined catalog; (4) Validation of ground-motion simulations applies to the entire workflow for simulating earthquake ground-motions, including the rupture model, seismic velocity model, and seismic wave propagation software; (5) Metrics to evaluate the validation are application dependent; more research is needed to tie structural response characteristics to ground-motion characteristics; and (6) Validation results should provide a clear, transparent, and quantitative assessment of the simulated ground motions.

Conference Paper

Suspended-sediment characteristics in the Housatonic River Basin, western Massachusetts and parts of eastern New York and northwestern Connecticut, 1994-96

Suspended-sediment concentrations, discharges, loads, and yields were determined for eight subbasins in the Housatonic River Basin in western Massachusetts, eastern New York, and northwestern Connecticut from April 1994 through March 1996. Suspended-sediment samples were collected at three continuous-record sediment stations and at four partial-record sediment stations. Suspended-sediment concentrations in samples collected during the period of study ranged from less than 0.5 to 3,400 milligrams per liter, and concurrent streamflows ranged from 0.03 to 126 cubic feet per second per square mile at the seven stations. Median suspended-sediment concentrations in samples collected at each station ranged from 7 to 61 milligrams per liter. Median streamflows during suspended-sediment sampling ranged from 1.86 to 5.88 cubic feet per second per square mile. Instantaneous suspended-sediment yields ranged from less than 0.005 to 185 tons per day per square mile, and medians ranged from 0.03 to 1.12 tons per day per square mile at the seven stations. Total suspended-sediment loads (mass) from April 1994 through March 1996 at the continuous-record sediment stations were 11,603 tons at Housatonic River near Great Barrington, 7,929 tons at Green River, and 54,347 tons at Housatonic River near Ashley Falls. Suspended-sediment load during January 1996 at the Green River station accounted for about 54 percent of the total suspended-sediment load for the Green River during the 2-year study. Suspended-sediment load on January 19 and 20, 1996, at the Green River station accounted for about 50 percent of the January 1996 suspended-sediment load, or about 27 percent of the total suspended-sediment load during the 2-year study. This large suspended-sediment transport was the result of rainfall and snowmelt on January 19 and 20, 1996--the equivalent of a 5- to 6-inch rain storm in the Green River subbasin. Total suspended-sediment loads during the 2-year study at the partial-record sediment stations were 3,052 tons at Williams River, 1,758 tons at Ironworks Brook, and 17,927 tons at Konkapot River. Suspended-sediment yields from April 1994 through March 1996 at the continuous-record sediment stations were 21 (tons/yr)/mi 2 at Housatonic River near Great Barrington, 78 (tons/yr)/mi 2 at Green River, and 58 (tons/yr)/mi 2 at Housatonic River near Ashley Falls. Suspended-sediment yields during the 2- year study at the partial-record sediment stations were 35 (tons/yr)/mi 2 at Williams River, 78 (tons/yr)/mi 2 at Ironworks Brook, and 147 (tons/yr)/mi 2 at Konkapot River. Suspended-sediment yields were estimated for two subbasins in the Housatonic River Basin--Schenob Brook at Sheffield, a partial-record sediment station, and the area adjacent to the Housatonic River between Great Barrington and Ashley Falls. The estimate of suspended-sediment yield at Schenob Brook at Sheffield of 82 (tons/yr)/mi 2 is comparable to the yield determined for the Green River and Ironworks Brook. The estimate of suspended-sediment yield for the area adjacent to the Housatonic River between Great Barrington and Ashley Falls was 395 (tons/yr)/mi 2 . This estimated suspended-sediment yield was 2.7 to 18.8 times greater than that estimated for any of the other subbasins. Several basin and land-use characteristics thought to affect suspended-sediment transport in the subbasins were compared to the suspended-sediment yields. The characteristics that seemed to affect suspended-sediment discharge were dams, which contributes to decreased yields; Hadley, Limerick, Linlithgo, Saco, and Winooski silt loam soils (high erodibility soils), which contributes to increased yields; stratified-drift deposits, which contributes to increased yields; and agricultural and open land, which contributes to increased yields. The effect of stratified-drift deposits on suspended-sediment discharge is thought to be greater when those deposits are of glaciolacustrine (generally clay, silt, and fine sand), rather than glaciofluvial (clay, silt, sand, gravel, and cobbles) origin. The silt loam soils, glaciolacustrine deposits, and agricultural and open land are interrelated, inasmuch as the silt loam soils generally are associated with glaciolacustrine deposits and agricultural activities.

Connecticut, Massachusetts, New York

Reflections on a trio of North American earthquakes in 1925

In 1925, three moderately large damaging earthquakes occurred in North America over four months: the 28 February (local time; LT) M 6.2 Charlevoix, 27 June (LT) M 6.6 Montana, and 29 June M 6.5 Santa Barbara earthquakes. The centennial anniversaries of these events motivated this retrospective consideration focused on the ground motions generated by the three events, including a reconsideration of early intensity assignments for the Montana earthquake. At the time, these three earthquakes appeared to support the arguments of some geologists who downplayed the severity of seismic hazard in southern California relative to other parts of the country. Some of the arguments advanced at that time, for example that Los Angeles “has the least to fear from ‘Acts of God’ of any city under the American flag,” ( Hill, 1928 ) sound naïve if not laughable now, but a comparison of well‐constrained shaking distributions for the three earthquakes reveals the dramatic difference in wave propagation efficiency in western versus eastern North America (ENAM), which leads to moderate ENAM events being felt to much larger distances. At M 6.2, the 1925 Charlevoix earthquake was a notably large event in ENAM. This earthquake was the largest event in eastern Canada since 1870 and caused damage in the epicentral region in addition to towns as far away as 200 km, with felt shaking extending over 1000 km. In contrast, felt shaking from the Santa Barbara earthquake barely extended beyond ∼200 km. Compiling published intensity distributions for larger ENAM earthquakes, we show that perceptible earthquake shaking is not uncommon in ENAM over century time scales, but experience with weakly felt shaking may incline people to downplay potential earthquake risk.

California, Montana, Quebec

Seismic characteristics of the April 2024 eruption of Ruang Volcano, North Sulawesi, Indonesia

The two most recent eruptions of Ruang volcano, in 2002 and 2024, have been large (VEI 4) with very short precursory periods, 3 and 6 days, respectively. Background seismicity at Ruang volcano is generally low with 0–2 volcano-tectonic (VT) earthquakes per day. The 2024 eruptions were preceded by a notable increase in VT earthquakes from 11 to 15 April with a rapid escalation from 16 to 17 April in the form of increased VT swarms, and the appearance of low frequency earthquakes and short bursts of VT drumbeats shortly before the eruption. Similar VT seismic unrest was recorded in March 2015, May 2016, and April 2022, although none of these episodes culminated in an eruption. A comparison of seismic energy release between April 2022 and April 2024 shows distinct differences. In 2024, cumulative seismic energy reached its peak within 5 days, just before the onset of eruption on 17 April. In contrast, during the 2022-episode, energy release followed a more gradual increase over 8 days peaking on 16 April, then declining gradually without leading to eruption. Notably, low frequency (LF) and drumbeat earthquakes were absent in non-eruptive unrest episodes. The transition to proximal LFs in 2024 likely signals pressure fluctuations, intensified magma degassing, and conduit formation, acting as an important precursor to eruption. Additionally, the occurrence of short bursts of drumbeat seismicity likely reflects the onset of the shallow magma ascent and was an important short-term precursor to the eruption. Finally, we examine the potential influence of regional tectonic earthquakes on the escalation of precursory unrest in 2024.

North Sulawesi, Ruang volcano

Numerical modeling of Late Pleistocene to Holocene earthquake-induced progressive rock slope damage in the paraglacial Serpentine valley, Prince William Sound, Alaska

Landslides in deglaciating fjords pose a potential tsunami threat to nearby communities; however, processes contributing to long-term progressive rock damage and landslide conditioning remain poorly constrained in paraglacial settings. Here, we analyse the role of earthquake-induced rock mass damage over late Pleistocene to Holocene time scales, as a conditioning factor for modern landslides, using distinct element numerical modelling to assess spatial and temporal patterns of fracture propagation influenced by varying glacier thickness. Conceptualised numerical models were parameterised by in situ rock mass, glacial and topographic conditions in Serpentine valley, located in Prince William Sound, Alaska, where several large landslides are actively developing along the western valley wall. Results show that although rigid glacier buttressing reduces co-seismic rock mass damage, it does not suppress it completely, and damage occurs both above and below the glacier surface elevation. We demonstrate that topography, and especially steep slopes with topographic convexity, as well as preexisting damage of joint networks and faults inherited from tectonic and exhumation induced stresses, exert primary control on the location of new co-seismic damage. Simulations representing a simplified deglaciation sequence over the past 25 ka, with a series of 10 evenly spaced earthquakes, generated rock mass damage patterns that qualitatively match in situ landslide structural and kinematic observations at one instability in Serpentine valley. Our conceptual study helps clarify the role of repeated seismicity over glacial timescales as a long-term conditioning process for paraglacial rock slope failure, highlighting spatial and temporal patterns of progressive damage accumulation, with outcomes relevant for modern landslide hazard assessment.

Alaska

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana

Timescales of cumulate mobilization and mixing for the 1868 A.D. eruption of Mauna Loa, Island of Hawai‘i

The deadly 1868 A.D. eruption of Mauna Loa’s lower Southwest Rift Zone (Island of Hawai‘i) included a M7.9 earthquake and associated tsunami and landslides, demonstrating the severe hazards posed by Earth’s largest active subaerial volcano. To better understand the relationship between intense seismic activity, dike emplacement, magma storage, transport histories, and mobilization of olivine cumulates at Mauna Loa, we examine compositional zoning of olivine in the 1868 lava flows. Samples range from basalt (< 10% olivine) to picrite (30–40% olivine). The olivine cargo is heterogeneous (Fo 78.2–89.2 ; forsterite = [Mg/(Mg + Fe) × 100]) but dominated by ~ Fo 89 cores that lie above the Fe-Mg equilibrium field of host glasses. Crystal rims < Fo 80 are due to post-eruptive modification in slow cooling lava flows. Minor element compositions fall within the range of other Mauna Loa olivine erupted in the past 200 years. Olivine crystals exhibit both normal and complex Fo zoning patterns that yield timescales of diffusive re-equilibration that range from 3 to 258 days, with 72% of crystals recording 71 days or less. These timescales correspond to magmatic priming of the summit reservoir system ~ 2 months prior to the eruption and the M7.9 earthquake likely facilitated the transport of the crystal-rich summit-derived magmas downrift shortly prior to eruption. If the recently proposed faster Fe-Mg diffusion coefficient is used, timescales instead range from < 1 day to 25 days, with most recording 1 week or less. In this scenario, most of the olivine zoning would have to have been generated after the M7.9 earthquake perturbed the system.

Hawaii

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island

Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits. Generally, the upper Peace River is characterized by a shallow, buried irregular top of rock, numerous observed sinkholes, and subsidence depressions. The downward head gradient provides potential for the Peace River to lose water to the ground-water system. Along the middle Peace River area, head gradients alternate between downward and upward, creating both recharging and discharging ground-water conditions. Seismic records show that buried, laterally continuous reflectors in the lower Peace River pinch out in the middle Peace River streambed. Small springs have been observed along the streambed where these units pinch out. This area corresponds to the region where highest ground-water seepage volumes were measured during this study. Further south, along the lower Peace River, upward head gradients provide conditions for ground-water discharge into the Peace River. Generally, confinement between the surficial aquifer and the confined ground-water systems in this area is better than to the north. However, localized avenues for surface-water and ground-water interactions may exist along discontinuities observed in seismic reflectors associated with large-scale flexures or subsidence features. Ground-water seepage gains or losses along the Peace River were quantified by making three seepage runs during periods of: (1) low base flow, (2) high base flow, and (3) high flow. Low and high base-flow seepage runs were performed along a 74-mile length of the Peace River, between Bartow and Nocatee. Maximum losses of 17.3 cubic feet per second (11.2 million gallons per day) were measured along a 3.2-mile reach of the upper Peace River. The high-flow seepage run was conducted to quantify losses in the Peace River channel and floodplain between Bartow and Fort Meade. Seepage losses calculated during high-flow along a 7.2-mile reach of the Peace River, from the Clear Springs Mine bridge to the Mobil Mine bridge, were approximately 10 percent of the river flow, or 118 cubic feet per second. Calculated seepages along the Peace River in Hardee and De Soto Counties were inconclusive, because most seepages were within the range of discharge measurement error. Two continuous aerial thermal infrared imagery surveys were conducted to locate sites of ground-water discharge along the Peace River. Although temperature and hydrologic conditions were ideal to observe spring flow using thermal infrared imaging techniques, no sources of ground-water discharge were identified using this method. Diffuse ground-water seepage may, however, provide significant ground-water discharge.

Florida

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2024

Potentiometric-surface and depth-to-water maps for spring 2024 were created for the Mississippi River Valley alluvial aquifer using groundwater-altitude data from 1,151 wells completed in the Mississippi River Valley alluvial aquifer and from the altitude of the top of the water surface in area rivers from 160 U.S. Geological Survey and U.S. Army Corps of Engineers streamgages. The potentiometric-surface and depth-to-water maps for 2024 were created to support investigations to characterize the Mississippi River Valley alluvial aquifer as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the Mississippi River Valley alluvial aquifer for spring 2024 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 330 feet (ft) above the North American Vertical Datum of 1988. The regional direction of the groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient direction was into the depression, and near rivers, where the groundwater gradient direction was either from the aquifer to the river or from the river into the aquifer. Groundwater depressions in the potentiometric-surface map are in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions. Depth to water by well in the Mississippi River Valley alluvial aquifer in spring 2024 ranged from 0.27 ft above land surface to 145.65 ft below land surface.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Bioconcentration of per- and polyfluoroalkyl substances and precursors in fathead minnow tissues environmentally exposed to aqueous film-forming foam-contaminated waters

Exposure to per- and polyfluoroalkyl substances (PFAS) has been associated with toxicity in wildlife and negative health effects in humans. Decades of fire training activity at Joint Base Cape Cod (MA, USA) incorporated the use of aqueous film-forming foam (AFFF), which resulted in long-term PFAS contamination of sediments, groundwater, and hydrologically connected surface waters. To explore the bioconcentration potential of PFAS in complex environmental mixtures, a mobile laboratory was established to evaluate the bioconcentration of PFAS from AFFF-impacted groundwater by flow-through design. Fathead minnows ( n = 24) were exposed to PFAS in groundwater over a 21-day period and tissue-specific PFAS burdens in liver, kidney, and gonad were derived at three different time points. The ∑PFAS concentrations in groundwater increased from approximately 10,000 ng/L at day 1 to 36,000 ng/L at day 21. The relative abundance of PFAS in liver, kidney, and gonad shifted temporally from majority perfluoroalkyl sulfonamides (FASAs) to perfluoroalkyl sulfonates (PFSAs). By day 21, mean ∑PFAS concentrations in tissues displayed a predominance in the order of liver > kidney > gonad. Generally, bioconcentration factors (BCFs) for FASAs, perfluoroalkyl carboxylates (PFCAs), and fluorotelomer sulfonates (FTS) increased with degree of fluorinated carbon chain length, but this was not evident for PFSAs. Perfluorooctane sulfonamide (FOSA) displayed the highest mean BCF (8700 L/kg) in day 21 kidney. Suspect screening results revealed the presence of several perfluoroalkyl sulfinate and FASA compounds present in groundwater and in liver for which pseudo-bioconcentration factors are also reported. The bioconcentration observed for precursor compounds and PFSA derivatives detected suggests alternative pathways for terminal PFAS exposure in aquatic wildlife and humans.

Environmental Toxicology and Chemistry

Nodal seismic deployment on Mauna Loa volcano, Hawaii: Dataset and preliminary insights

Mauna Loa is the largest active volcano on Earth, comprising ∼51% of the Island of Hawai‘i’s landmass and posing significant risks to the island’s communities, infrastructure, and natural environment. Historical eruptions have produced lava flows that have reached the ocean in as little as 3 hr. The timing and location of such lava flows in the past 200 yr underscore how critical determination of the location and geometry of magma storage and structure is for volcanic hazard assessment and eruption forecasting. Now, after nearly 38 yr of volcanic quiescence, Mauna Loa has erupted again. On 27 November 2022, fissures initiated within the summit caldera and then migrated to the northeast rift zone, where they generated a large lava flow that threatened a major highway. To improve our understanding of the geometry of this magma system, we deployed a temporary nodal array on Mauna Loa in the summer of 2024. This increased our seismic coverage sufficiently to image this magmatic system. This nodal array consists of 33 seismometers distributed on and around the volcano and was deployed for over three months to record seismic signals. The primary objective of this project is to resolve the high‐resolution seismic velocity structure and characterize seismic features associated with magma storage and ascent pathways. In this article, we present an overview of the deployment, evaluate the quality of the data, and show example recordings to evaluate the suitability of the data set for future seismic investigations, including earthquake relocation, seismic tomography, and receiver function analysis. Comparisons with nearby permanent broadband and short‐period seismic stations demonstrate that the nodal array recorded high‐quality waveforms, making it a valuable resource for constraining the magmatic system beneath Mauna Loa at multiple scales.

Hawaii

Groundwater response to managed aquifer recharge at the Southeast Houghton Artificial Recharge Project in Tucson, Arizona

Managed aquifer recharge is a widespread practice for storing water in the subsurface as groundwater. At a managed aquifer recharge facility in southern Arizona, groundwater-level and repeat microgravity data were collected to monitor aquifer response. These data were used to inform parameter identification for an unsaturated-zone flow model used to simulate the recharge process. The facility, the Southeast Houghton Artificial Recharge Project (SHARP), consists of 3 surface basins (about 27,600 square meters [6.8 acres] total surface area) where recycled water is distributed in recharge cycles lasting several months, with dry periods in between. During the study period, December 2020–December 2022, Tucson Water (the City of Tucson’s water utility) reported 6.56×10 6 cubic meters of water (5,320 acre-feet) recharged. Monitoring included groundwater-level observations at 3 monitoring wells and repeat microgravity measurements at as many as 22 locations (some stations were destroyed between surveys). Six gravity surveys were carried out using absolute- and relative-gravity meters. Large gravity increases, more than 250 microgals, were observed during the first repeat survey, 3.5 months after the start of recharge, but only in the immediate vicinity of the recharge basins. Data show that water moved downward to the water table, and storage changes in the unsaturated zone away from the facility were likely minimal. Gravity decreased at stations more than 1 kilometer from the facility, consistent with regional groundwater-level changes. Groundwater-level increases in wells adjacent to the recharge basins began 2 months after the second repeat gravity survey, and 5.5 months after recharge began. Unsaturated-zone flow modeling was carried out using software that simulates water movement and parameter estimation. Model calibration was carried out by minimizing an objective function calculated from the differences between simulated and observed groundwater levels, and between simulated and observed repeat microgravity data. Including repeat microgravity data in the objective function reduced the uncertainty in estimated parameter values for saturated hydraulic conductivity and saturated water content. Modeling indicated that the unsaturated zone between the recharge basins and the water table does not become saturated even after 685 days of simulated infiltration. This gradual wetting may account for increasing infiltration rates over time, as hydraulic conductivity increases with increasing water content. Unsaturated-zone water content decreased rapidly between recharge cycles. Model-simulated groundwater mounding extended about 1 kilometer from the center of SHARP after the 685-day period following the onset of recharge.

Arizona

Factors contributing to pesticide contamination in riverine systems: The role of wastewater and landscape sources

Wastewater treatment plant (WWTP) discharges can be a source of organic contaminants, including pesticides, to rivers. An integrated model was developed for the Potomac River watershed (PRW) to determine the amount of accumulated wastewater percentage of streamflow (ACCWW) and calculate predicted environmental concentrations (PECs) for 14 pesticides in non-tidal National Hydrography Dataset Plus Version 2.1 stream segments. Predicted environmental concentrations were compared to measured environmental concentrations (MECs) from 32 stream sites that represented a range of ACCWW and land use to evaluate model performance and to assess possible non-WWTP loading sources. Statistical agreement between PECs and MECs was strongest for insecticides, followed by fungicides and herbicides. Principal component analysis utilizing optical fluorescence and ancillary water quality data identified wastewater and urban runoff sources. Pesticides that indicated relatively larger sources from WWTPs included dinotefuran, fipronil, carbendazim, thiabendazole, and prometon whereas imidacloprid, azoxystrobin, propiconazole, tebuconazole, and diuron were more related to urban runoff. In addition, PECs generally comprised a low proportion of MECs, which indicates possible dominant loading sources beyond WWTP discharges. Cumulative potential toxicity was higher for sites with greater ACCWW and/or located in developed areas. Imidacloprid, fipronil, and carbendazim accounted for the largest portion of predicted potential toxicity across sites. The chronic aquatic life toxicity benchmarks for freshwater invertebrates were exceeded for 82 % of the imidacloprid detections ( n = 28) and 47 % of the fipronil detections ( n = 19). These results highlight the ecological implications of pesticide contamination from WWTP discharges and also the potential legacy effects from accumulated soil and groundwater sources. Pesticide management strategies that mitigate both current and historical impacts may improve the health of aquatic ecosystems.

Potomac River watershed

Geologic framework, hydrostratigraphy, and ichnology of the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles, Blanco, Comal, Hays, and Kendall Counties, Texas

During 2023, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised an initial characterization completed during 2015–16 of the geologic framework, hydrostratigraphy, and ichnology of the Edwards and Trinity aquifers in the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles in Blanco, Comal, Hays, and Kendall Counties, Texas. The purpose of this report is to present the updated geologic framework, hydrostratigraphy, and ichnology of the Trinity and Edwards Groups in those quadrangles. Rocks exposed in the study area are of the Lower Cretaceous Trinity Group and lower part of the Fort Terrett Formation of the Lower Cretaceous Edwards Group. The faulting and fracturing in the study area are part of the Balcones Fault Zone, an extensional system of faults active during the Paleocene to middle Eocene that generally trends southwest to northeast in south-central Texas. Hydrostratigraphically, the rocks exposed in the study area contain a section of the Edwards (Balcones Fault Zone) aquifer, upper zone of the Trinity aquifer, and middle zone of the Trinity aquifer. In the study area, the only hydrostratigraphic units of the Edwards (Balcones Fault Zone) aquifer remaining are (from top to bottom) VII and VIII, which cap several hills. The mapped hydrostratigraphic units of the upper zone of the Trinity aquifer are (from top to bottom) the cavernous, Camp Bullis, upper evaporite, fossiliferous, and lower evaporite. The mapped hydrostratigraphic units of the middle zone of the Trinity aquifer are (from top to bottom) the Bulverde, Little Blanco, Twin Sisters, Doeppenschmidt, Herff Falls (where present), Rust, Honey Creek, Hensell, and Cow Creek hydrostratigraphic units.

Texas

Simulated effects of projected 2014–40 withdrawals on groundwater flow and water levels in the New Jersey Coastal Plain

Abstract Groundwater flow between 2014 through 2040 was simulated in the New Jersey Coastal Plain based on three withdrawal scenarios. Two of the scenarios were based on projected population trends and the assumption of water conservation; the nominal water-loss scenario projected a status quo in the efficiency of water loss in the delivery systems whereas the optimal water-loss scenario projected a better water-loss efficiency resulting in less withdrawals. The third scenario assumes that all wells will withdraw water at their full allocation level which is generally much more than reported withdrawals in 2013 or projected under the other two scenarios. Maps and summaries of heads and drawdowns are presented for nine confined aquifers. All the aquifers have areas with heads below sea level by 2040. Of the three scenarios, the drawdowns are most extreme in the full allocation scenarios; there are large areas of head decline greater than 20 feet in 5 of the 9 confined aquifers. The exceptions are the Vincentown aquifer, despite some areas of large drawdown in the vicinity of wells, and the three Potomac-Raritan-Magothy (PRM) aquifers where withdrawals are regulated by Critical Area restrictions. The nominal and optimal water-loss scenarios have some areas of head declines; most are less than 15 feet. The simulation of these scenarios shows some extensive areas of head recovery as well—especially in the aquifers that are regulated by the Critical Area restrictions. Budgets of inflow and outflow components were calculated for 44 hydrologic budget areas (HBAs). The budget analysis shows that the water movement is complex and varies based on the aquifer geometry and location of pumping wells. Flow components between the unconfined and confined parts of the system were summarized by HUC11 (hydrologic unit code 11) basins.

New Jersey

lasertram: A Python library for time resolved analysis of laser ablation inductively coupled plasma mass spectrometry data

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data has a wide variety of uses in the geosciences for in-situ chemical analysis of complex natural materials. Improvements to instrument capabilities and operating software have drastically reduced the time required to generate large volumes of data relative to previous methodologies. Raw data from LA-ICP-MS, however, is in counts per unit time (typically counts per second), not elemental concentrations and converting these count ratesto concentrations requires additional processing. For complex materials where the ablated volume may contain a range of material compositions, a moderate amount of user input is also required if appropriate concentrations are to be accurately calculated. In geologic materials such as glasses and minerals that potentially have numerous heterogeneities (e.g., microlites or other inclusions) within them, this is typically determiningwhether the total ablation signal should be filtered to remove these heterogeneities. This necessitates that the LA-ICP-MS data processing pipeline is one that is not automated, but is also designed to enable rapid and efficient processing of large volumes of data. Here we introduce , a Python library for the time resolved analysis of LA-ICP-MS data. We outline its mathematical theory, code structure, and provide an example of how it can be used to provide the time resolved analysis necessitated by LA-ICP-MS data of complex geologic materials. Throughout the pipeline we show how metadata and data are incrementally added to the objects created such that virtually any aspect of an experiment may be interrogated and its quality assessed. We also show, that when combined with other Python libraries for building graphical user interfaces, it can be utilized outside of a pure scripting environment. can be found at https://doi.org/10.5066/P1DZUR3Z

Applied Computing and Geosciences