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At least 721 records · Page 40Linked to original sources

Concentration comparison of selected constituents between groundwater samples collected within the Missouri River alluvial aquifer using purge and pump and grab-sampling methods, near the city of Independence, Missouri, 2013

The U.S. Geological Survey, in cooperation with the City of Independence, Missouri, Water Department, has historically collected water-quality samples using the purge and pump method (hereafter referred to as pump method) to identify potential contamination in groundwater supply wells within the Independence well field. If grab sample results are comparable to the pump method, grab samplers may reduce time, labor, and overall cost. This study was designed to compare constituent concentrations between samples collected within the Independence well field using the pump method and the grab method. Relative percent differences between environmental grab and duplicate grab samples were greater than 10 percent for 80 percent of the constituents. Duplicate grab samples were collected by tethering two grab samplers together, because the amount of water collected by each grab sampler is close to the amount necessary for analysis. The screened interval lengths of monitoring wells within the Independence well field is not conducive to collecting multiple grab samples by tethering samplers. The inability to collect required duplicate quality assurance samples may limit the use of grab samplers. Concentrations between pump and grab samples were similar for analyzed nutrient species, the variability between methods was less than the variability between historical duplicate samples, and there were no significant differences determined. Major ion relative percent differences were less than 10 percent and root mean square error differences between methods and between historical duplicate samples were less than 1 milligram per liter with the exception of sulfate. Statistically significant differences were determined between pump and grab samples for sodium and fluoride. There is a strong association between major ion pump and grab samples based on bivariate plots and simple linear regressions. Variability between pump and grab samples of analyzed nutrients and major ions may have minimal effect on the ability to monitor temporal changes and potential groundwater contamination threats. Relative percent differences between methods were greater than 10 percent for most analyzed trace elements. Barium, cobalt, manganese, and boron had concentrations that were significantly different between sampling methods. Barium, molybdenum, boron, and uranium method concentrations indicate a close association between pump and grab samples based on bivariate plots and simple linear regressions. Grab sample concentrations were generally larger than pump concentrations for these elements and may be because of using a larger pore sized filter for grab samples. Analysis of zinc blank samples suggests zinc contamination in filtered grab samples. Variations of analyzed trace elements between pump and grab samples could reduce the ability to monitor temporal changes and potential groundwater contamination threats. The degree of precision necessary for monitoring potential groundwater threats and application objectives need to be considered when determining acceptable variation amounts.

Missouri↗

Simulation of groundwater flow in the "1,500-foot" sand and "2,000-foot" sand and movement of saltwater in the "2,000-foot" sand of the Baton Rouge area, Louisiana

Groundwater withdrawals have caused saltwater to encroach into freshwater-bearing aquifers beneath Baton Rouge, Louisiana. Groundwater investigations in the 1960s identified a freshwater-saltwater interface located at the Baton Rouge Fault, across which abrupt changes in water levels occur. Aquifers south of the fault generally contain saltwater, and aquifers north of the fault contain freshwater, though limited saltwater encroachment has been detected within 7 of the 10 aquifers north of the fault. The 10 aquifers beneath the Baton Rouge area, which includes East and West Baton Rouge Parishes, Pointe Coupee Parish, and East and West Feliciana Parishes, provided about 167 million gallons per day (Mgal/day) for public supply and industrial use in 2010. Groundwater withdrawals from an aquifer that is 2,000-feet (ft) deep in East Baton Rouge Parish (the “2,000-foot” sand of the Baton Rouge area) have caused water-level drawdown up to 356 ft and induced saltwater movement northward across the fault. Groundwater withdrawals from the “2,000-foot” sand averaged 23.9 Mgal/d during 2010. Saltwater encroachment threatens wells that are located about 3 miles north of the fault, where industrial withdrawals account for about 66 percent of the water withdrawn from the “2,000-foot” sand in East Baton Rouge Parish. Constant and variable-density groundwater models were developed with the MODFLOW and SEAWAT groundwater modeling codes to evaluate strategies to control saltwater migration, including changes in the distribution of groundwater withdrawals and installation of “scavenger” wells to intercept saltwater before it reaches existing production wells. Five hypothetical scenarios simulated the effects of different groundwater withdrawal options on groundwater levels within the “1,500-foot” sand and the “2,000-foot” sand and the transport of saltwater within the “2,000-foot” sand. Scenario 1 is considered a base case for comparison to the other four scenarios and simulates continuation of 2007 reported groundwater withdrawals. Scenario 2 simulates discontinuation of withdrawals from seven selected industrial wells located in the northwest corner of East Baton Rouge Parish, and water levels within the “1,500-foot” sand were predicted to be about 15 to 20 ft higher under this withdrawal scenario than under scenario 1. Scenario 3 simulates the effects of a scavenger well, which withdraws water from the base of the “2,000-foot” sand at a rate of 2 Mgal/d, at two possible locations on water levels and concentrations within the “2,000-foot” sand. In comparison to the concentrations simulated in scenario 1, operation of the scavenger well in the locations specified in scenario 3 reduces the chloride concentrations at all existing chloride-observation well locations. Scenario 4 simulates a 3.6 Mgal/d reduction in total groundwater withdrawals from selected wells screened in the “2,000-foot” sand that are located in the Baton Rouge industrial district. For scenario 4, the median and mean plume concentrations are slightly lower than scenario 1. Scenario 5 simulates the effect of total cessation of groundwater withdrawals from the “2,000-foot” sand in the industrial district. The simulated chloride-concentration distribution in scenario 5 reflects the change in groundwater flow direction. Although some saltwater would continue to cross the Baton Rouge Fault and encroach toward municipal supply wells, further encroachment toward the industrial district would be abated.

Louisiana;Mississippi↗

Hydrogeology and groundwater flow in alluvial deposits, north Summerset, South Dakota

The city of Summerset is a growing community in west South Dakota. The Sun Valley Estates subdivision in the north part of the city was developed on unconsolidated deposits surrounded by steep terrain. During years with greater than normal precipitation, particularly in 2019, groundwater levels increased in the unconsolidated deposits and caused damage to stormwater systems, sewer infrastructure, and houses with basements. The U.S. Geological Survey, in cooperation with the City of Summerset, completed a study of the hydrogeology and groundwater flow in the alluvial aquifer part of the unconsolidated deposits in north Summerset to understand the groundwater system in the area and to provide hydrogeologic information in support of future development planning. The study area included most of the Sun Valley Estates subdivision in the north part of the city of Summerset in the east Black Hills of west South Dakota. About 0.7 square mile of water-bearing alluvial deposits is included in the study area. Precipitation in the study area from 2017 to 2019 was compared to the monthly normal values at a nearby climate site. The largest departure from normal was in May 2019 with precipitation exceeding the monthly normal by about 5 inches (in.). All months in 2019, except March, exceeded the monthly normal precipitation. Cumulative departure from normal precipitation in 2019 increased from about 4 in. greater than normal in January to about 18 in. greater than normal in December. The geologic setting of the study area is characterized by the surrounding Black Hills. Unconsolidated Quaternary-age deposits overlie consolidated to partially consolidated Mesozoic-age and Paleozoic-age shales, sandstones, and limestones. Surficial deposits of alluvium and other unconsolidated deposits are the primary surficial geologic units in the study area and form the components of the alluvium hydrogeologic unit of the study area. Results from previous studies of alluvium along nearby Rapid Creek estimated hydraulic conductivity to range from 89 to 2,292 feet per day (ft/d), transmissivity to range from 1,001 to 32,083 feet squared per day, and storage coefficients to range from 0.0002 to 0.16. Hydraulic conductivity and transmissivity generally decreased downstream along Rapid Creek (west to east). Slug tests were completed August 16, 2019, at two observation wells completed in the alluvial aquifer in the Sun Valley Estates subdivision to determine hydraulic conductivity. Hydraulic conductivity estimated from AQTESOLV curve-fitting analysis using the Bouwer-Rice method for all slug-in and slug-out trials from two observation wells in the study ranged from 0.20 to 0.26 ft/d for well 441318103220001 (SunValley1 well) and from 0.54 to 14 ft/d for well 441319103215701 (SunValley2 well). The mean, median, and standard deviation of all trials at both wells were 4.3 ft/d, 0.8 ft/d, and 5.6 ft/d, respectively. The extent of the alluvial aquifer was determined by geologic maps and lithologic logs. Alluvial deposits in the study area extend to about 1 mile in the north–south direction and about 1.5 miles in the southeast–northwest direction. The direction of groundwater flow was estimated using water-level records and topographic maps. The resulting potentiometric map indicated that groundwater in the alluvial aquifer under the Sun Valley Estates subdivision originates from higher elevations of the west part of the area of interest and from streams in the southeast part. Recharge and evapotranspiration estimates were results from a Soil-Water Balance model that calculated a matrix of recharge for 2019 with values ranging from 0 to 11.4 in. and an annual mean value of 5.1 in. across the study area. Soil-Water Balance-estimated potential evapotranspiration for 2019 ranged from 28.90 to 28.75 in. and the estimated annual mean was 28.86 in. across the study area. Estimated groundwater budget components for the alluvial aquifer in the area of interest included inflows and outflows. Total estimated groundwater budget components for inflows for 2019 were about 66 percent from recharge, 33 percent from streamflow, and 1 percent from inflow from adjacent aquifers. Total estimated outflows were about 99-percent evapotranspiration and less than 1-percent outflow to adjacent aquifers.

South Dakota↗

Geohydrologic framework of the coastal plain aquifers of South Carolina

The U.S. Geological Survey is conducting a series of investigations of aquifers throughout the United States as a part of the RASA (Regional Aquifer System Analysis) program. These investigations provide a comprehensive regional understanding of groundwater resources throughout the Nation. The Coastal Plain aquifers in South Carolina are being studied as a part of this program. An important part of a description of the groundwater resources is the development of a geohydrologic framework. Such a framework delineates the aquifers through which groundwater flows and the confining units which retard the flow of groundwater between aquifers. The Coastal Plain of South Carolina is underlain by a wedge of sediments that thickens from its inner margin, the Fall Line, to the coast and consists of sand, silt, clay, and limestone of Late Cretaceous to Holocene age. These sediments are underlain by pre-Cretaceous rocks consisting of consolidated sedimentary rocks of Triassic age and a complex of metamorphic and igneous rocks similar to those found near the surface in the Piedmont province of the State. The geohydrologic framework that divides the sediments of the South Carolina Coastal Plain into the Coastal Plain aquifer system is delineated by eleven geohydrologic sections and four maps showing the configuration of the top or base of individual aquifers. Although flow within the Coastal Plain aquifer system is three dimensional, simplifying the system by dividing it into a framework of discrete hydrologic units can aid significantly in understanding the hydrology of the system. This framework is the basis for the aquifers used in potentiometric mapping, transmissivity mapping, geochemical analysis, and groundwater flow modeling for the South Carolina RASA program. (Lantz-PTT)

South Carolina↗

Quality of groundwater used for domestic supply in the western Central Valley, California—2023

More than 2 million Californians rely on groundwater from domestic wells for their drinking-water supply. This report summarizes a 2023 California Groundwater Ambient Monitoring and Assessment Priority Basin Project water-quality survey of 44 domestic and small-system drinking-water supply wells in the western Sacramento Valley (basin number 5-021) and San Joaquin Valley (basin number 5-022) groundwater basins in the Central Valley, California, where more than 88,000 residents are estimated to utilize privately owned, domestic wells. The study area includes the Corning, Colusa, Yolo, and Solano subbasins (subbasin numbers 5-021.51, 5-021.52, 5-021.67, and 5-021.66, respectively) of the Sacramento Valley groundwater basin, and the East Contra Costa, Tracy, Delta-Mendota, and Westside subbasins (subbasin numbers 5-022.19, 5-022.15, 5-022.07, and 5-022.09, respectively) of the San Joaquin Valley groundwater basin. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of the aquifer system rather than groundwater resources used for public drinking-water supply, which are typically drawn from deeper parts. This assessment characterized the quality of ambient groundwater used for domestic supply, rather than the quality of drinking water at a tap or faucet, which may be filtered or treated after extraction. To provide context, concentrations of constituents in groundwater were compared to Federal and State of California regulatory and non-regulatory benchmarks for drinking-water quality. Regulatory benchmarks were U.S. Environmental Protection Agency and State of California maximum contaminant levels (MCLs) for drinking water. Non-regulatory benchmarks were State of California secondary maximum contaminant levels (SMCLs) for managing aesthetic conditions, such as taste, odor, or color. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking supply that have water-quality constituents present at high concentrations (greater than the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth of the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other California Groundwater Ambient Monitoring and Assessment Priority Basin Project study areas. In this study, inorganic constituents in groundwater were greater than regulatory benchmarks for public drinking-water quality in 30 percent of domestic groundwater resources. Inorganic constituents present at concentrations greater than MCLs for drinking water were hexavalent chromium, total chromium, and nitrate. Total dissolved solids, manganese, and iron were present at concentrations greater than their SMCL in 27 percent of domestic groundwater resources. 1,2,3-trichloropropane was present at concentrations greater than State of California MCLs for drinking water in 2.3 percent of domestic groundwater resources and was the only volatile organic compound detected at concentrations greater than a benchmark. Per-and polyfluoroalkyl substances were detected in 16 percent of domestic groundwater resources, and 2.3 percent had concentrations greater than U.S. Environmental Protection Agency MCLs. Total coliform bacteria and enterococci were detected in 9.1 and 2.3 percent of domestic groundwater resources, respectively. To understand groundwater quality in the study area, factors that affect groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential physical and chemical variables. Relevant factors include the oxidation-reduction conditions of groundwater, agricultural land use, and geologic sources of aquifer sediments. Manganese and iron concentrations were affected by oxidation-reduction state. Nitrate concentrations were affected by the interplay of agricultural practices and denitrification, where denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Ultramafic aquifer sediments in the western Central Valley provide a geogenic source for chromium and hexavalent chromium. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials, but agricultural practices may also contribute to these concentrations.

California↗

Simulated flow of groundwater and brine from a flooded salt mine in Livingston County, New York, and effects of remedial pumping on an overlying aquifer

Two ceiling collapses in the Retsof salt mine near Geneseo in upstate New York in spring 1994 resulted in the upward propagation of two columns of rubble through 600 feet of overlying shale and carbonate bedrock. This upward propagation formed a hydraulic connection between the lower confined aquifer (LCA) and the mine and allowed water from the aquifer and bedrock fracture zones that intersected the rubble columns to flow into the mine at a rate of 18,000 gallons per minute (gal/min) . All salt mining ceased in September 1995, and the mine was completely flooded by January 1996. The flow of water from the lower confined aquifer into the mine caused widespread drawdowns, and water levels in the aquifer declined by as much as 400 feet near the collapse area and by more than 50 feet at wells 7 miles to the north and south. Within 3 to 4 weeks of the collapses, water levels in about a dozen domestic and industrial wells had declined severely, and some wells went dry. Water levels in at least 58 wells in the lower and middle confined aquifers were affected by mine flooding. Groundwater in the upper unconfined aquifer and surface water in streams were unaffected by water-level drawdown, but channels of the Genesee River and Beards Creek were altered by land subsidence related to the mine collapse. Water levels recovered from 1996 through 2006, but the mine is now filled with about 15 billion gallons of saturated halite brine. The weight of the overlying rock and sediment is expected to cause the salt beds to deform and fill the mine cavity during the next several hundred years; this in turn could displace as much as 80 percent of the brine and cause it to move upward through the rubble chimneys, rendering the LCA unusable as a source of water supply. Saline water was detected in the LCA in 2002 but was found to be derived primarily from fractures in the limestone and shale units between the mine and the LCA, rather than from the mine. In September 2006, the mine company began a brine-mitigation project that entailed pumping five wells finished in limestone and shale units within the collapse areas to alter the flow gradient and thereby prevent further movement of brine and saline water into the LCA. The pumped brine was routed to an onsite desalination plant. At the same time, the U.S. Geological Survey (USGS) began a study in cooperation with the New York State Office of the Attorney General to construct numerical models to analyze the groundwater chemistry and delineate the directions of flow. Specific objectives of the study were to: * Assess the sources of salinity within the collapse area and identify the factors that control the movement and mixing of freshwater, saline waters from fracture zones, and brine; * Evaluate the likelihood that the pumping will induce anhydrite dissolution and lead to continued land subsidence; * Construct variable-density groundwater flow models to predict the effect of remedial pumping on salinity within the LCA; * Evaluate the effectiveness of remedial pumping in preventing the movement of saline water into the LCA; and * Predict the extent of brine migration 8 years after a hypothetical shutdown of all pumping in 2008. This report (1) summarizes the hydrogeologic setting and effects of mine flooding, (2) describes the geochemical and variable-density model simulations and their principal results, (3) discusses the implications of (a) continued pumping and desalination to protect the LCA and (b) a full shutdown of pumping after 2008, and (4) suggests further research that could lead to refinement of model predictions. Additional information may be found in Yager and others (2001 and 2009). These reports can be accessed at http://pubs.usgs.gov/pp/pp1611/ and http://pubs.usgs.gov/pp/pp1767/, respectively. A summary of simulation results can be accessed at http://ny.water.usgs.gov/projects/Coram/seawat/seawat.html.

New York↗

Groundwater-quality data associated with abandoned underground coal mine aquifers in West Virginia, 1973-2016: Compilation of existing data from multiple sources

This report describes a compilation of existing water-quality data associated with groundwater resources originating from abandoned underground coal mines in West Virginia. Data were compiled from multiple sources for the purpose of understanding the suitability of groundwater from abandoned underground coal mines for public supply, industrial, agricultural, and other uses. This compilation includes data collected for multiple individual studies conducted from July 13, 1973 through September 7, 2016. Analytical methods varied by the time period of data collection and requirements of the independent studies.This project identified 770 water-quality samples from 294 sites that could be attributed to abandoned underground coal mine aquifers originating from multiple coal seams in West Virginia.

West Virginia↗

Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 1

This report delineates and describes the geohydrology and susceptibility of the major aquifers to contamination in Area 1 - Colbert, Franklin, Lauderdale, Lawrence, Limeston, Madison, and Morgan Counties. Most of the area is underlain by a Mississippian carbonate sequence that includes two major aquifers, the Tuscumbia-Fort Payne aquifer and the Bangor aquifer. A third major aquifer, the Tuscaloosa aquifer of Cretaceous age, occurs in the southwest part of the area. The Mississippi carbonate aquifers are the Tuscumbia-Fort Payne aquifer which includes most Tuscumbia Limestone and the Fort Payne Chert, and a small area of the Monteagle Limestone, and the Bangor aquifer which includes the Bangor Limestone and Hartselle Sandstone. Both of these aquifers possess highly-variable secondary porosity and permeability related to fractures that have been enlarged, sometimes to cavernous proportions, due to solution processes. The Tuscaloosa aquifer consists of the Tuscaloosa Group, an unconsolidated clastic deposit that has relatively uniform primary porosity and permeability. Significant quantities of groundwater are available from each of the aquifers. Water levels at nearly 2 ,000 wells indicate that, for each aquifer, general groundwater movement is from topographically high to low areas. Each of the aquifers is recharged throughout its outcrop in the study area and is susceptible to contamination within the outcrop. Generalized topographic settings such as closed-contour depressions are identified as areas that are highly susceptible to contamination. Specific features such as sinkholes also are identified as extremely susceptible to contamination.

Alabama↗

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California↗

Generalized potentiometric surface, estimated depth to water, and estimated saturated thickness of the High Plains aquifer system, March–June 2009, Laramie County, Wyoming

The High Plains aquifer system, commonly called the High Plains aquifer in many publications, is a nationally important water resource that underlies a 111-million-acre area (173,000 square miles) in parts of eight States including Wyoming. Through irrigation of crops with groundwater from the High Plains aquifer system, the area that overlies the aquifer system has become one of the major agricultural regions in the world. In addition, the aquifer system also serves as the primary source of drinking water for most residents of the region. The High Plains aquifer system is one of the largest aquifers or aquifer systems in the world. The High Plains aquifer system underlies an area of 8,190 square miles in southeastern Wyoming. Including Laramie County, the High Plains aquifer system is present in parts of five counties in southeastern Wyoming. The High Plains aquifer system underlies 8 percent of Wyoming, and 5 percent of the aquifer system is located within the State. Based on withdrawals for irrigation, public supply, and industrial use in 2000, the High Plains aquifer system is the most utilized source of groundwater in Wyoming. With the exception of the Laramie Mountains in western Laramie County, the High Plains aquifer system is present throughout Laramie County. In Laramie County, the High Plains aquifer system is the predominant groundwater resource for agricultural (irrigation), municipal, industrial, and domestic uses. Withdrawal of groundwater for irrigation (primarily in the eastern part of the county) is the largest use of water from the High Plains aquifer system in Laramie County and southeastern Wyoming. Continued interest in groundwater levels in the High Plains aquifer system in Laramie County prompted a study by the U.S. Geological Survey in cooperation with the Wyoming State Engineer's Office to update the potentiometric-surface map of the aquifer system in Laramie County. Groundwater levels were measured in wells completed in the High Plains aquifer system from March to June 2009. The groundwater levels were used to construct a map of the potentiometric surface of the High Plains aquifer system. In addition, depth to water and estimated saturated-thickness maps of the aquifer system were constructed using the potentiometric-surface map.

Wyoming↗

Groundwater and surface-water data from the C-aquifer monitoring program, Northeastern Arizona, 2012–2019

The Coconino aquifer (C aquifer) is a regionally extensive multiple-aquifer system supplying water for municipal, agricultural, and industrial use in northeastern Arizona, northwestern New Mexico, and southeastern Utah. This report focuses on the C aquifer in the arid to semi-arid area between St. Johns, Ariz., and Flagstaff, Ariz., along the Interstate-40 corridor where an increase in groundwater withdrawals coupled with ongoing drought conditions increase the potential for substantial water-level decline within the aquifer. The U.S. Geological Survey (USGS) C-aquifer Monitoring Program began in 2005 to establish baseline groundwater and surface-water conditions and to quantify physical and water-chemistry responses to pumping stresses and climate. This report presents data previously reported in Brown and Macy (2012) that extend back as far as the 1950s, along with new data collected from the USGS C-aquifer Monitoring Program since that publication, from water years 2012 to 2019. Water levels in 17 wells are measured quarterly as part of the C-aquifer Monitoring Program, and five of those are continuously monitored at 15-minute intervals. Water levels in an additional 18 wells in the study area are measured periodically by the USGS or other agencies. The largest historical change in water level in the study area was a decrease of 81.20 feet in Lake Mary 1 Well near Flagstaff between 1962 and 2018. Changes in water levels were greatest around major pumping centers and in the eastern extent of the study area. Surface-water water-quality parameters (pH, water temperature, specific conductance, and dissolved oxygen) and streamflow discharge measurements were collected and analyzed along perennial, groundwater-fed reaches of Clear Creek, Chevelon Creek, and the Little Colorado River during nine baseflow investigations of varying extent between 2005 and 2019. Both Clear Creek and Chevelon Creek gain in flow from the beginning of their perennial reaches to their outflow into the Little Colorado River. The Little Colorado River has relatively steady streamflow in the reach between where the two tributaries enter the river. Chevelon Creek showed an increase in median specific conductance during all baseflow investigations of nearly 4,000 microsiemens per centimeter (μS/cm) from near the headwaters to the confluence with the Little Colorado River; Clear Creek also showed an increase in median specific conductance of almost 5,000 μS/cm from headwaters to confluence. Water temperature, dissolved oxygen, and pH do not show substantial trends along the reaches of Clear Creek, Chevelon Creek, or the Little Colorado River.

Arizona↗

Probing the deep critical zone beneath the Luquillo Experimental Forest, Puerto Rico

Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world's oceans, thereby exerting a primary control on global temperature via the well-known positive feedback between silicate weathering and CO 2 . In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g. soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared with the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream

Earth Surface Processes and Landforms↗

Sustainable Land Use Requires Attention to Ecological Signals

This case study details the difficulties of landscape management, highlighting the challenges inherent in managing natural resources when multiple agencies are involved, when the land users have no incentive for conservation, and when government agencies have too few resources for effective management. Pumping of groundwater from the aquifer of La Costa de Hermosillo in the state of Sonora, Mexico, began in 1945 and developed so quickly that by the late 1950s salinity intrusion from the Gulf of California was occurring in the wells. In the 1970s, the irrigatable land in La Costa peaked at 132,516 ha and the extracted volume of water from the aquifer peaked at around 1.14 billion cubic meters annually. By the 1980s, 105 wells of the total of 498 were contaminated with seawater and, therefore, identified for closure. At present La Costa de Hermosillo still represents 15% of the total harvested land, 16% of the total annual production, and 23% of the gross agricultural production of the state of Sonora. However, there are approximately 80,000 ha of abandoned fields due to salt water intension, lack of water and/or lack of credit available to individual farmers. This unstable situation resulted from the interplay of water management policies and practices, and farm-land policies and practices. While government agencies have been able to enforce better water use for agricultural production, there remains a significant area that requires restoration from its degraded state. For this piece of the ecosystem management puzzle, government agencies have thus far been unable to affect a solution.

Environmental Management↗

Measurement of fluid velocity using temperature profiles: Experimental verification

Temperature profiling has been used to predict the rate and direction of groundwater movement. A controlled field experiment was conducted to ascertain the validity of the rate calculations made using this method. The vertical velocity, or leakage, of groundwater between two aquifers was calculated utilizing both hydrologic and temperature measurements in a well drilled into the Paw Paw buried bedrock valley in northern Illinois. The experiment showed that accurate estimates of leakage can be made in stable boreholes where there are no geologic complications. Estimates utilizing temperature and hydrologic methods produced similar results for one of two aquicludes. However, the methods produced dissimilar results for the second aquiclude. It is speculated that the presence of a thin organic silt caused most of the problem; other complicating factors were lithologic variation and a very low hydraulic gradient. Nevertheless, the method appears to have great promise in many geologic environments.

Illinois↗

Natural attenuation strategy for groundwater cleanup focuses on demonstrating cause and effect

In the 20 years since cleanup of contaminated groundwater has been a high priority in the United States, recognition of both the scope of the problem and the technical difficulties involved has grown steadily. Estimates of the number of hazardous waste sites where groundwater may be contaminated vary between 300,000 and 400,000 nationwide [NRC, 1994]. Legislation passed in the 1980s by Congress and the states generally required that groundwater in contaminated aquifers be restored to background or drinking water standards. Unfortunately, attempts to meet these goals using conventional methods, such as pump and treat systems, frequently have been unsuccessful [NRC, 1994].

Eos, Transactions, American Geophysical Union↗

Time-fractional flow equations (t-FFEs) to upscale transient groundwater flow characterized by temporally non-darcian flow due to medium heterogeneity

Upscaling groundwater flow is a fundamental challenge in hydrogeology. This study proposed time-fractional flow equations (t-FFEs) for upscaling long-term, transient groundwater flow and propagation of pressure heads in heterogeneous media. Monte Carlo simulations showed that, with increasing variance and correlation of the hydraulic conductivity ( K ), flow dynamics gradually deviated from Darcian flow and exhibit sub-diffusive, time-dependent evolution which can be separated into three major stages. At the early stage, the interconnected high- K zones dominated flow, while at intermediate times, the transverse flow due to mixed high- and low- K zones caused delayed rise of the piezometric head. At late times when flow in the relatively high- K domains reached stability, cells with very low- K continued to block the entry of water and generate “islands” with low piezometric head, significantly extending the temporal evolution of the piezometric head. The elongated water breakthrough curve cannot be quantified by the flow equation with an effective K , the space-fractional flow equation, or the multi-rate mass transfer (MRMT) flow model with a few rates, motivating the development of t-FFEs assuming temporally non-Darcian flow. Model applications showed that both the early and intermediate stages of flow dynamics can be captured by a single-index t-FFE (whose index is the exponent of the power-law probability density function of the random operational time for water parcels), but the overall evolution of flow dynamics, especially the enhanced retention of flow at later times, required a distributed-order t-FFE with variable indexes for different flow phases that can dominate flow dynamics at different stages. Therefore, transient groundwater flow in aquifers with spatially stationary heterogeneity can be temporally non-Darcian and non-stationary, due to the time-sensitive, combined effects of interconnected high- K channels and isolated low- K deposits on flow dynamics (which is the hydrogeological mechanism for the temporally non-Darcian flow and sub-diffusive pressure propagation), whose long-term behavior can be quantified by multi-index stochastic models.

Water Resources Research↗

Copepod communities from surface and ground waters in the everglades, south Florida

We studied species composition and individual abundance of copepods in the surficial aquifer northeast of Everglades National Park. We identified the spatial distribution of subsurface habitats by assessing the depth of the high porosity layers in the limestone along a canal system, and we used copepods to assess the exchange between surface water and ground water along canal banks, at levels in the wells where high porosity connections to the canals exist. Surface- and ground-water taxa were defined, and species composition was related to areal position, sampling depth, and time. Subsurface copepod communities were dominated by surface copepods that disperse into the aquifer following the groundwater seepage along canal L-31N. The similarities in species composition between wells along canal reaches, suggest that copepods mainly enter ground water horizontally along canals via active and passive dispersal. Thus, the copepod populations indicate continuous connections between surface- and ground waters. The most abundant species were Orthocyclops modestus, Arctodiaptomus floridanus, Mesocyclops edax, and Thermocyclops parvus, all known in literature from surface habitats; however, these species have been collected in ground water in ENP. Only two stygophiles were collected: Diacylcops nearcticus and Diacyclops crassicaudis brachycercus. Restoration of the Everglades ecosystem requires a mosaic of data to reveal a complete picture of this complex system. The use of copepods as indicators of seepage could be a tool in helping to assess the direction and the duration of surface and ground water exchange.

Florida↗

Arsenic, iron, lead, manganese, and uranium concentrations in private bedrock wells in southeastern New Hampshire, 2012-2013

Trace metals, such as arsenic, iron, lead, manganese, and uranium, in groundwater used for drinking have long been a concern because of the potential adverse effects on human health and the aesthetic or nuisance problems that some present. Moderate to high concentrations of the trace metal arsenic have been identified in drinking water from groundwater sources in southeastern New Hampshire, a rapidly growing region of the State (Montgomery and others, 2003). During the past decade (2000–10), southeastern New Hampshire, which is composed of Hillsborough, Rockingham, and Strafford Counties, has grown in population by nearly 48,700 (or 6.4 percent) to 819,100. These three counties contain 62 percent of the State’s population but encompass only about 22 percent of the land area (New Hampshire Office of Energy and Planning, 2011). According to a 2005 water-use study (Hayes and Horn, 2009), about 39 percent of the population in these three counties in southeastern New Hampshire uses private wells as sources of drinking water, and these wells are not required by the State to be routinely tested for trace metals or other contaminants. Some trace metals have associated human-health benchmarks or nonhealth guidelines that have been established by the U.S. Environmental Protection Agency (EPA) to regulate public water supplies. The EPA has established a maximum contaminant level (MCL) of 10 micrograms per liter (μg/L) for arsenic (As) and a MCL of 30 μg/L for uranium (U) because of associated health risks (U.S. Environmental Protection Agency, 2012). Iron (Fe) and manganese (Mn) are essential for human health, but Mn at high doses may have adverse cognitive effects in children (Bouchard and others, 2011; Agency for Toxic Substances and Disease Registry, 2012); therefore, the EPA has issued a lifetime health advisory (LHA) of 300 μg/L for Mn. Recommended secondary maximum contaminant levels (SMCLs) for Fe (300 μg/L) and Mn (50 μg/L) were established primarily as nonhealth guidelines—based on aesthetic considerations, such as taste or the staining of laundry and plumbing fixtures—because these contaminants, at the SMCLs, are not considered to present risks to human health. Because lead (Pb) contamination of drinking water typically results from corrosion of plumbing materials belonging to water-system customers but still poses a risk to human health, the EPA established an action level (AL) of 15 μg/L for Pb instead of an MCL or SMCL (U.S. Environmental Protection Agency, 2012). The 15-μg/L AL for Pb has been adopted by the New Hampshire Department of Environmental Services for public water systems, and if exceeded, the public water system must inform their customers and undertake additional actions to control corrosion in the pipes of the distribution system (New Hampshire Department of Environmental Services, 2013). Unlike the quality of drinking water provided by public water suppliers, the quality of drinking water obtained from private wells in New Hampshire is not regulated; consequently, private wells are sampled only when individual well owners voluntarily choose to sample them. The U.S. Geological Survey (USGS), in cooperation with the EPA New England, conducted an assessment in 2012–13 to provide private well owners and State and Federal health officials with information on the distribution of trace-metal (As, Fe, Pb, Mn, and U) concentrations in groundwater from bedrock aquifers in the three counties of southeastern New Hampshire. This fact sheet analyzes data from water samples collected by a randomly selected group of private well owners from the three-county study area and describes the major findings for trace-metal concentrations.

New Hampshire↗