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At least 721 records · Page 40Linked to original sources

Use of a ground-water flow model with particle tracking to evaluate ground-water vulnerability, Clark County, Washington

A ground-water flow model was used in conjunction with particle tracking to evaluate ground-water vulnerability in Clark County, Washington. Using the particle-tracking program, particles were placed in every cell of the flow model (about 60,000 particles) and tracked backwards in time and space upgradient along flow paths to their recharge points. A new computer program was developed that interfaces the results from a particle-tracking program with a geographic information system (GIS). The GIS was used to display and analyze the particle-tracking results. Ground-water vulnerability was evaluated by selecting parts of the ground-water flow system and combining the results with ancillary information stored in the GIS to determine recharge areas, characteristics of recharge areas, downgradient impact of land use at recharge areas, and age of ground water. Maps of the recharge areas for each hydrogeologic unit illustrate the presence of local, intermediate, or regional ground-water flow systems and emphasize the three-dimensional nature of the ground-water flow system in Clark County. Maps of the recharge points for each hydrogeologic unit were overlaid with maps depicting aquifer sensitivity as determined by DRASTIC (a measure of the pollution potential of ground water, based on the intrinsic characteristics of the near-surface unsaturated and saturated zones) and recharge from on-site waste-disposal systems. A large number of recharge areas were identified, particularly in southern Clark County, that have a high aquifer sensitivity, coincide with areas of recharge from on-site waste-disposal systems, or both. Using the GIS, the characteristics of the recharge areas were related to the downgradient parts of the ground-water system that will eventually receive flow that has recharged through these areas. The aquifer sensitivity, as indicated by DRASTIC, of the recharge areas for downgradient parts of the flow system was mapped for each hydrogeologic unit. A number of public-supply wells in Clark County may be receiving a component of water that recharged in areas that are more conducive to contaminant entry. The aquifer sensitivity maps illustrate a critical deficiency in the DRASTIC methodology: the failure to account for the dynamics of the ground-water flow system. DRASTIC indices calculated for a particular location thus do not necessarily reflect the conditions of the ground-water resources at the recharge areas to that particular location. Each hydrogeologic unit was also mapped to highlight those areas that will eventually receive flow from recharge areas with on-site waste-disposal systems. Most public-supply wells in southern Clark County may eventually receive a component of water that was recharged from on-site waste-disposal systems.Traveltimes from particle tracking were used to estimate the minimum and maximum age of ground water within each model-grid cell. Chlorofluorocarbon (CFC)-age dating of ground water from 51 wells was used to calibrate effective porosity values used for the particle- tracking program by comparison of ground-water ages determined through the use of the CFC-age dating with those calculated by the particle- tracking program. There was a 76 percent agreement in predicting the presence of modern water in the 51 wells as determined using CFCs and calculated by the particle-tracking program. Maps showing the age of ground water were prepared for all the hydrogeologic units. Areas with the youngest ground-water ages are expected to be at greatest risk for contamination from anthropogenic sources. Comparison of these maps with maps of public- supply wells in Clark County indicates that most of these wells may withdraw ground water that is, in part, less than 100 years old, and in many instances less than 10 years old. Results of the analysis showed that a single particle-tracking analysis simulating advective transport can be used to evaluate ground-water vulnerability for any part of a ground-wate

Open-File Report↗

Determining sources of water and contaminants to wells in a carbonate aquifer near Martinsburg, Blair County, Pennsylvania, by use of geochemical indicators, analysis of anthropogenic contaminants, and simulation of ground-water flow

Water supply for the Borough of Martinsburg, Pa., is from two well fields (Wineland and Hershberger) completed in carbonate-bedrock aquifers in the Morrison Cove Valley. Water supply is plentiful; however, waters with high concentrations of nitrate are a concern. This report describes the sources of water and contaminants to the supply wells. A review of previous investigations was used to establish the aquifer framework and estimate aquifer hydraulic properties. Aquifer framework and simulation of ground-water flow in a 25-square-mile area using the MODFLOW model helped to further constrain aquifer hydraulic properties and identify water-source areas in the zone of contribution of ground water to the well fields. Flow simulation identified potential contaminant-source areas. Data on contaminants and geochemical characteristics of ground water at the well fields were compared to the results of flow simulation. The Woodbury Anticline controls the aquifer framework near the well fields and four carbonate-bedrock formations contain the primary aquifers. Three carbonate-bedrock aquifers of Ordovician age overlie the Gatesburg aquifer of Cambrian age on the flanks of the anticline. Fracture, not conduit, permeability was determined to be the dominant water-bearing characteristic of the bedrock. The horizontal hydraulic conductivity of the Gatesburg aquifer is about 36 feet per day. The other carbonate aquifers (Nittany/Stonehenge, Bellefonte/Axemann, and Coburn through Loysburg aquifers) overlying and flanking the Gatesburg aquifer have horizontal hydraulic conductivities of about 1 foot per day. Regional directions of ground-water flow are toward the major streams with Clover Creek as the major discharge point for ground water in the east. Ground-water flow to the well fields is anisotropic with a 5:1 preferential horizontal direction along strike of the axial fold of the anticline. Thus, the zone of contribution of ground water to the well fields is elongate in a north-south direction along the anticline axis, with the majority of the flow to the well fields originating from the south. Human activity in the areal extent of the zone of contribution to the well fields was the source of contaminants. The areal extent of the zone of contribution included both urban areas in the Borough and a large amount of agricultural land. By relating results of flow simulation, natural geochemistry, and analyses of anthropogenic (human-made) contaminants, the source areas for water and contaminants were determined with more confidence than by using only flow simulation. Analysis of natural geochemistry identified water sources from both limestone and dolomite aquifers. Geochemistry results also indicated fractures, not conduits, were the dominant source of water from aquifers; however, quantitative source identification was not possible. Chemical ratios of chloride and bromide were useful to show that all samples of ground water had sources with chemical contributions from land surface. Nitrogen isotope ratio analysis indicated animal manure as the possible primary source of nitrate in most ground water. Some of the nitrate in ground water had chemical fertilizer as a source. At the Wineland well field, chemical fertilizer was likely the source of nitrate. The nitrate in water from the Hershberger well field was from a mixture of fertilizer and animal-manure sources. Human sewage was ruled out as a major source of nitrate in water from the municipal wells by results showing 1) wastewater compounds in sewage were rarely detected and 2) a mass-balance calculation indicating the small contribution of nitrogen that could be attributed to septic systems.

Scientific Investigations Report↗

Death Valley regional ground-water flow system, Nevada and California -- hydrogeologic framework and transient ground-water flow model

A numerical three-dimensional (3D) transient ground-water flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the ground-water flow system and previous less extensive ground-water flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect ground-water flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley Regional Ground-Water Flow System (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the ground-water flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural ground-water discharge occurring through evapotranspiration and spring flow; the history of ground-water pumping from 1913 through 1998; ground-water recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were provided by acquiring additional data, by reevaluating existing data using current technology and concepts, and by refining earlier interpretations to reflect the current understanding of the regional ground-water flow system. Ground-water flow in the Death Valley region is composed of several interconnected, complex ground-water flow systems. Ground-water flow occurs in three subregions in relatively shallow and localized flow paths that are superimposed on deeper, regional flow paths. Regional ground-water flow is predominantly through a thick Paleozoic carbonate rock sequence affected by complex geologic structures from regional faulting and fracturing that can enhance or impede flow. Spring flow and evapotranspiration (ET) are the dominant natural ground-water discharge processes. Ground water also is withdrawn for agricultural, commercial, and domestic uses. Ground-water flow in the DVRFS was simulated using MODFLOW-2000, a 3D finite-difference modular ground-water flow modeling code that incorporates a nonlinear least-squares regression technique to estimate aquifer parameters. The DVRFS model has 16 layers of defined thickness, a finite-difference grid consisting of 194 rows and 160 columns, and uniform cells 1,500 m on each side. Prepumping conditions (before 1913) were used as the initial conditions for the transient-state calibration. The model uses annual stress periods with discrete recharge and discharge components. Recharge occurs mostly from infiltration of precipitation and runoff on high mountain ranges and from a small amount of underflow from adjacent basins. Discharge occurs primarily through ET and spring discharge (both simulated as drains) and water withdrawal by pumping and, to a lesser amount, by underflow to adjacent basins, also simulated by drains. All parameter values estimated by the regression are reasonable and within the range of expected values. The simulated hydraulic heads of the final calibrated transient model gener

Scientific Investigations Report↗

Ground-water flow and water quality in the Upper Floridan aquifer, southwestern Albany area, Georgia, 1998-2001

During 1997, the Dougherty County Health Department sampled more than 700 wells completed in the Upper Floridan aquifer in Dougherty County, Georgia, and determined that nitrate as nitrogen (hereinafter called nitrate) concentrations were above 10 milligrams per liter (mg/L) in 12 percent of the wells. Ten mg/L is the Georgia primary drinking-water standard. The ground-water flow system is complex and poorly understood in this predominantly agricultural area. Therefore, the U.S. Geological Survey (USGS) - in cooperation with Albany Water, Gas and Light Commission - conducted a study to better define ground-water flow and water quality in the Upper Florida aquifer in the southwestern Albany area, Georgia. Ground-water levels were measured in the southwestern Albany area, Georgia, during May 1998 and March 1999 (spring), and October 1998 and September 1999 (fall). Groundwater levels measured in 75 wells open only to the Upper Floridan aquifer were used to construct potentiometric-surface maps for those four time periods. These maps show that ground water generally flows from northwest to southeast at gradients ranging from about 2 to greater than 10 feet per mile. During spring and fall 1998, ground-water levels were high and mounding of the potentiometric surface occurred in the central part of the study area, indicating a local recharge area. Water levels declined from December through February, and by March 1999 the mound in the potentiometric surface had dissipated. Of the 75 wells in the potentiometric network, 24 were selected for a water-quality network. These 24 wells and 1 spring were sampled during fall 1998 and spring 1999. Samples were analyzed for major chemical constituents, selected minor constituents, selected nutrients, and chlorofluorocarbons (CFC). Water-quality field measurements - such as water temperature, pH, specific conductance (SC), and dissolved oxygen (DO) - were taken at each well. During August 2000, a ground-water sample was collected and analyzed for selected sewage tracers. During March 2001, water samples from selected wells were analyzed for nitrogen and oxygen isotopes. Age-dating analysis using CFCs yield apparent groundwater ages that range from modern to greater than 50 years. The chemistry of ground water in the Upper Floridan aquifer varies widely throughout the southwestern Albany area, Georgia, and in general represents the chemistry commonly found in recharge areas. From fall 1998 through spring 1999, median values of pH, SC, and DO concentration were 7.6 standard units, 266 microsiemens per centimeter at 25 degrees Celsius (uS/cm), and 5.6 mg/L, respectively. The SC is highest (350 - 400 uS/cm) where mounding of the potentiometric surface exists. Specific DO concentrations indicate an area of anoxic ground water in the north-central part of the study area. Water samples indicate that ground water in the study area is dominated by calcium and bicarbonate ions, which is consistent with the limestone lithology of the aquifer. About 25 percent of the samples contained sodium and chloride at ratios similar to those in rainfall, indicating a close proximity to recharge areas. The remaining water samples, however, had sodiumchloride ratios less than 0.90, the ratio in Tift County, Georgia, rainfall samples. These low sodium-chloride ratios are consistent with chloride enrichment. Minor constituent and nutrient concentrations typically are below laboratory reporting limits; however, the maximum nitrate concentration measured during the study period was 12.2 mg/L, and the median concentration for the study period was 3.0 mg/L. Samples collected during 1999 had a higher median nitrate concentration than the 1998 samples. Regression analysis indicated that nitrate concentrations are related exponentially to chloride concentrations. Four distinct groups of ground-water-quality samples, plus four unique samples, were identified using cluster analysis. Water-quality groups I and

Georgia↗

Reconnaissance of surface-water and ground-water quality at the Lincoln Boyhood National Memorial near Lincoln City, Indiana, 2001-02

In cooperation with the National Park Service, the U.S. Geological Survey investigated water quality of key water bodies at the Lincoln Boyhood National Memorial near Lincoln City in southwestern Indiana. The key water bodies were a stock pond, representing possible nonpoint agricultural effects on water quality; an ephemeral stream, representing the water quality of drainage from forested areas of the park; parking-lot runoff, representing water quality related to roads and parking lots; an unnamed ditch below the parking lot, representing the water quality of drainage from the parking lot and from an adjacent railroad track; and Lincoln Spring, a historical ground-water source representing ground-water conditions near a former diesel-fuel-spill site along a rail line. Water samples were analyzed for pH, temperature, specific conductance, and dissolved oxygen and for concentrations of selected major ions and trace metals, nutrients, organic constituents, and Escherichia coli bacteria. Surface-water-quality data of water samples from the park represent baseline conditions for the area in relation to the data available from previous studies of area streams. Specific-conductance values and concentrations of most major ions and various nutrients in surface-water samples from the park were smaller than those reported for samples collected in other USGS studies in areas adjacent to the park. Water-quality-management issues identified by this investigation include potentially impaired water quality from parking-lot runoff, unknown effects on surface-water quality from adjacent railroads, and the potential impairment of water quality in Lincoln Spring from human influences. Parking-lot runoff is a source of calcium, alkalinity, iron, lead, and organic carbon in the water samples from the unnamed ditch. Detection of small concentrations of petroleum hydrocarbons in water from Lincoln Spring could indicate residual contamination from a 1995 diesel-fuel spill and cleanup. The concentration of nitrite plus nitrate in water from Lincoln Spring was 16.5 milligrams per liter as nitrogen, greater than the State of Indiana standard for nitrate in drinking water (10 milligrams per liter as nitrogen). Lead concentrations in samples from the stock pond, parking-lot runoff, and the unnamed ditch exceeded the Indiana chronic aquatic criteria.

Indiana↗

Simulated effects of water-level changes in the Mississippi River and Pokegama Reservoir on ground-water levels, Grand Rapids area, Minnesota

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, used an existing, three-dimensional, numerical ground-water flow model (referred to as the calibrated model) to assess the effects of water-level changes in the Mississippi River and Pokegama Reservoir on ground-water levels in adjacent glaciofluvial aquifers in the Grand Rapids area of north-central Minnesota. Pokegama Reservoir consists of Pokegama Lake, Little Jay Gould Lake, Jay Gould Lake, Cut-off Lake, and Blackwater Lake. Water levels in the Pokegama Reservoir are regulated at Pokegama Dam on the Mississippi River west of Grand Rapids. A steady-state model was used, and simulations represent “worse-case” scenarios for the effects of lowering or raising the river and lake water levels. The simulated ground-water levels represent levels that would result if the river and lake stages permanently declined or rose by the specified amounts. Eight hypothetical scenarios were simulated by varying water levels in the Mississippi River and Pokegama Reservoir from values used in the calibrated model. In the simulations, water levels for the Mississippi River, riverine wetlands of the Mississippi River, and lakes of the Pokegama Reservoir were raised and lowered uniformly by 0.50, 1.00, 2.00, and 3.00 feet from calibrated water levels. The extent of aquifer water-level changes resulting from these river, wetland, and lake water-level changes varied because of the complex hydrogeology of the study area. A 1.00-foot decline in reservoir/river water levels caused a maximum simulated ground-water-level decline in the middle aquifer near Jay Gould and Little Jay Gould Lakes of 1.09 feet and a maximum simulated ground-water-level decline of 1.00 foot in the lower aquifer near Cut-off and Blackwater Lakes. The amount and extent of ground-water-level changes in the middle and lower aquifers can be explained by the thickness, extent, and connectivity of the aquifers. Surface-water/ground-water interactions near wetlands and lakes with water levels unchanged from the calibrated model resulted in small water-table altitude differences among the simulations. Results of the ground-water modeling indicate that lowering of the reservoir and river water levels by 1.00 foot likely will not substantially affect water levels in the middle and lower aquifers.

Minnesota↗

Hydrogeologic setting, ground-water flow, and ground-water quality at the Lake Wheeler Road research station, 2001-03 : North Carolina Piedmont and Mountains Resource Evaluation Program

Results of a 2-year field study of the regolith-fractured bedrock ground-water system at the Lake Wheeler Road research station in Wake County, North Carolina, indicate both disconnection and interaction among components of the ground-water system. The three components of the ground-water system include (1) shallow, porous regolith; (2) a transition zone, including partially weathered rock, having both secondary (fractures) and primary porosity; and (3) deeper, fractured bedrock that has little, if any, primary porosity and is dominated by secondary fractures. The research station includes 15 wells (including a well transect from topographic high to low settings) completed in the three major components of the ground-water-flow system and a surface-water gaging station on an unnamed tributary. The Lake Wheeler Road research station is considered representative of a felsic gneiss hydrogeologic unit having steeply dipping foliation and a relatively thick overlying regolith. Bedrock foliation generally strikes N. 10? E. to N. 30? E. and N. 20? W. to N. 40? W. to a depth of about 400 feet and dips between 70? and 80? SE. and NE., respectively. From 400 to 600 feet, the foliation generally strikes N. 70? E. to N. 80? E., dipping 70? to 80? SE. Depth to bedrock locally ranges from about 67 to 77 feet below land surface. Fractures in the bedrock generally occur in two primary sets: low dip angle, stress relief fractures that cross cut foliation, and steeply dipping fractures parallel to foliation. Findings of this study generally support the conceptual models of ground-water flow from high to low topographic settings developed for the Piedmont and Blue Ridge Provinces in previous investigations, but are considered a refinement of the generalized conceptual model based on a detailed local-scale investigation. Ground water flows toward a surface-water boundary, and hydraulic gradients generally are downward in recharge areas and upward in discharge areas; however, local variations in vertical gradients are apparent. Water-quality sampling and monitoring efforts were conducted to characterize the interaction of components of the ground-water system. Elevated nitrate concentrations as high as 22 milligrams per liter were detected in shallow ground water from the regolith at the study site. These elevated nitrate concentrations likely are related to land use, which includes agricultural practices that involve animal feeding operations and crop fertilization. Continuous ground-water-quality data indicate seasonal fluctuations in field water-quality properties, differences with respect to depth, and fluctuations during recharge events. Water-quality properties recorded in the regolith well following rainfall indicate the upwelling of deeper ground water in the discharge area, likely from ground water in the transition-zone fractures. Additionally, interaction with a surface-water boundary appears likely in the ground-water discharge area, as water levels in all three ground-water zones, including the deep bedrock, mimic the surface-water rise during rainfall.

North Carolina↗

Occurrence of trihalomethanes in the nation's ground water and drinking-water supply wells, 1985-2002

This report describes the occurrence of trihalomethanes (THMs) in the Nation's ground water and drinking-water supply wells based on analysis of 5,642 samples of untreated ground water and source water collected or compiled during 1985-2002 by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. THMs are a group of volatile organic compounds (VOCs) with natural and anthropogenic sources that are of interest because they are associated with acute and chronic health problems in humans. THMs occur in water primarily from chlorination and are classified as disinfection by-products. In this report, the four THMs are discussed in the order of chloroform, bromodichloromethane, dibromochloromethane, and then bromoform; this sequence corresponds to largest to smallest chlorine content and smallest to largest bromine content. Four trihalomethanes were detected in less than 20 percent of samples from studies of (1) aquifers, (2) shallow ground water in agricultural areas, (3) shallow ground water in urban areas, (4) domestic wells, and (5) public wells. Detection frequencies for individual THMs in the five studies ranged from zero for shallow ground water in agricultural areas to 19.5 percent for shallow ground water in urban areas. None of the samples from aquifer studies, domestic wells, or public wells had total THM concentrations (the sum of the concentrations of chloroform, bromodichloromethane, dibromochloromethane, and bromoform) greater than or equal to the U.S. Environmental Protection Agency Maximum Contaminant Level of 80 micrograms per liter (?g/L). Comparisons of results among studies of aquifers, shallow ground water in agricultural areas, and shallow ground water in urban areas were used to describe the occurrence of the four THMs in ground water for three different land-use settings-mixed, agricultural, and urban, respectively. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 7.9 percent of the samples from aquifer studies, 2.2 percent of the samples from shallow ground water in agricultural areas, and 19.5 percent of the samples from shallow ground water in urban areas. In general, detection frequencies and concentrations of the four THMs were greater in shallow ground water in urban areas compared to aquifer studies and to shallow ground water in agricultural areas. For all three of these studies, the most common two-THM mixture at the 0.2-?g/L assessment level was chloroform-bromodichloromethane, and this was the only two-THM mixture found in samples of shallow ground water in agricultural areas. Comparisons of results between studies of domestic wells and public wells were used to describe the occurrence of the four THMs in two different supplies of ground water used for drinking water. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 5.2 percent of the domestic well samples and in 14.7 percent of the public well samples. In general, detection frequencies and THM concentrations were greater in samples from public wells than from domestic wells. At the 0.2-?g/L assessment level, the six possible two-THM mixtures occurred about six times more frequently in samples from public wells than from domestic wells. One of the most common two-THM mixtures in samples from domestic and public wells was bromodichloromethane-dibromochloromethane. Detection frequency is associated with the chlorine content of the THM compound. In general, for each of the five studies, as the chlorine content of the THM compound decreased, the detection frequency at the 0.2-?g/L assessment level also decreased. The exception was the study of public wells in which the detection frequency of the THMs decreased in the following order: chloroform, bromoform, dibromochloromethane, and bromodichloromethane. At the 0.2-?g/L assessment level, the median concentration for one or more of the four THMs ranged from 0.3 ?g/L (shallow ground water in agricultural a

Scientific Investigations Report↗

Questa baseline and pre-mining ground-water quality investigation 22 — Groundwater budget for the Straight Creek drainage basin, Red River Valley, New Mexico, with a section on Sulphur Gulch water budget

In April 2001, the U.S. Geological Survey (USGS) and the New Mexico Environment Department (NMED) began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley. The Molycorp mine has been in operation since the 1920s. Because ground-water conditions prior to mining are not available, sites analogous to the pre-mining conditions at the mine site must be studied to infer those pre-mining conditions. The Straight Creek drainage basin (watershed) was selected as the primary analog site for this study because of its similar terrain and geology to the mine site, accessibility, potential for well construction, and minimal anthropogenic activity. The purpose of this report is to present results of a water-budget analysis of the debris-flow aquifer in the Straight Creek watershed. The water budget is based on mean annual conditions and is assumed to be steady state. For this study, the Straight Creek watershed was divided into sub-watersheds on the basis of locations of seismic lines, which were used to calculate cross-section area through the Straight Creek debris-flow deposits and underlying fractured and weathered bedrock (regolith). Water-budget components were calculated for areas upstream from and between the seismic lines. Components of the water budget were precipitation, evapotranspiration, surface-water flow, and ground-water flow under a steady-state mean annual condition. Watershed yield, defined as precipitation minus evapotranspiration, was separated into surface-water flow, ground-water flow through the debris-flow deposits and regolith, and ground-water flow through fractured bedrock. The approach to this calculation was to use Darcy's Law to calculate the flow through the cross-section area of the saturated debris-flow deposits and underlying regolith as defined by the interpreted seismic data. The amount of watershed yield unaccounted for through this section then was attributed to either surface-water flow or the component of ground-water flow through fractured bedrock. The inflow to the watershed, calculated to be 701 gallons per minute, is from precipitation. The calculated outflow from the watershed at or upstream from seismic-line 5 (the downstream-most line in Straight Creek prior to entering the Red River Valley) is 540 gallons per minute of evapotranspiration in the watershed upstream from line 5 (77.0 percent of precipitation), 5 gallons per minute of surface-water flow (0.7 percent of precipitation), 122 gallons per minute of ground-water flow through the debris-flow deposits and underlying regolith defined by the seismic data (17.4 percent of precipitation), and 34 gallons per minute of ground-water flow through fractured bedrock below the defined seismic line (4.9 percent of precipitation). The ground-water flow through the alluvium and inter-tonguing debris-flow deposits of the Red River Valley was calculated to be 5,227 gallons per minute at seismic-line 7, the first seismic line in the Red River Valley downstream from Straight Creek. The water budget indicates the amount of ground-water flow that enters the Red River alluvium from the debris-flow deposits and regolith in Straight Creek is small (about 2.3 percent; 122 gallons per minute) compared to the volume of flow that moves through the Red River alluvium. The total amount of ground-water flow from Straight Creek (156 gallons per minute; 122 gallons per minute from debris-flow deposits and regolith plus 34 gallons per minute through fractured bedrock) is about 3.0 percent of the ground-water flow calculated at line 7 for the Red River alluvium.

New Mexico↗

Water resources data, Washington, water year 1996

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, local, and other Federal agencies, obtains a large amount of data pertaining to the water resources of Washington each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, the data are published annually in this report series entitled "Water Resources Data Washington." This report includes records on both surface and ground water in the State. Specifically, it contains: (1) Discharge records for 225 stream-gaging stations, 29 partial-record or miscellaneous streamflow stations, and 3 crest-stage partial-record streamflow station; (2) stage only records for 2 gaging stations; (3) stage and (or) content records for 34 lakes and reservoirs; (4) water-quality records for 68 stream, canal and drain sites; (5) water-level records for 4 observation wells; and (6) water quality record for 1 observation well. Records included for stream stages and for ground-water levels are only a small fraction of those obtained during the water year. This series of annual reports for Washington began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report format was changed to present, in one volume, data on quantities of surface water, quality of surface and ground water, and ground-water levels.

Washington↗

Historical water-quality data for the High Plains Regional Ground-Water Study Area in Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming, 1930-98

The High Plains aquifer underlies 174,000 square miles in parts of eight States and includes eight primary hydrogeologic units, including the well-known Ogallala Formation. The High Plains aquifer is an important resource, providing water for 27 percent of the Nation’s irrigated agricultural lands in an otherwise dry landscape. Since the 1980’s there has been concern over the sustainability of the aquifer due to water-level declines caused by substantial pumping. Water quality of the aquifer is a more recent concern. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, historical water-quality data have been gathered for the High Plains Regional Ground-Water Study Area into a retrospective data base, which can be used to evaluate the occurrence and distribution of water-quality constituents of concern. Data from the retrospective data base verify that nitrate, pesticides, and dissolved solids (salinity) are important water-quality concerns in the High Plains study area. Sixteen percent of all measured nitrate concentrations were larger than the U.S. Environmental Protection Agency drinking-water standard of 10 milligrams per liter. In about 70 percent of the counties within the High Plains study area, nitrate concentrations for 1980-98 were significantly larger than for 1930-69. While nitrate concentrations are largest where depth to water is shallow, concentrations also have increased in the Ogallala Formation where depth to water is large. Pesticide data primarily are available only in the northern half of the study area. About 50 pesticides were detected in the High Plains study area, but only four pesticides (atrazine, alachlor, cyanazine, and simazine) had concentrations exceeding a drinking-water standard. The occasional detection of pesticides in deeper parts of the Ogallala Formation indicates that contamination pathways exist. Dissolved solids, which are a direct measure of salinity, had 29 percent of measured concentrations in excess of the secondary drinking-water standard of 500 milligrams per liter. Comparison of dissolved-solids concentrations prior to 1980 to concentrations after 1980 indicates dissolved-solids concentrations have increased in the alluvial valleys of the Platte, the Republican, and the Arkansas Rivers, as well as in the Ogallala Formation–South hydrogeologic unit. Water-quality results indicate that human activities are affecting the water of the High Plains aquifer. Because there is a potential for water quality to become impaired relative to the historical uses of the aquifer, water quality needs to be considered when evaluating the sustainability of the High Plains aquifer. Data collected as part of the High Plains Regional Ground-Water Study will help to fill in gaps in water-quality information and provide additional information for understanding the factors that govern ambient water quality.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma, ↗

Simulation of projected water demand and ground-water levels in the Coffee Sand and Eutaw-McShan aquifers in Union County, Mississippi, 2010 through 2050

Ground water from the Eutaw-McShan and the Coffee Sand aquifers is the major source of supply for residential, commercial, and industrial purposes in Union County, Mississippi. Unbiased, scientifically sound data and assessments are needed to assist agencies in better understanding and managing available water resources as continuing development and growth places more stress on available resources. The U.S. Geological Survey, in cooperation with the Tennessee Valley Authority, conducted an investigation using water-demand and ground-water models to evaluate the effect of future water demand on groundwater levels. Data collected for the 12 public-supply facilities and the self-supplied commercial and industrial facilities in Union County were used to construct water-demand models. The estimates of water demand to year 2050 were then input to a ground-water model based on the U.S. Geological Survey finite-difference computer code, MODFLOW. Total ground-water withdrawals for Union County in 1998 were estimated as 2.85 million gallons per day (Mgal/d). Of that amount, municipal withdrawals were 2.55 Mgal/d with about 1.50 Mgal/d (59 percent) delivered to residential users. Nonmunicipal withdrawals were 0.296 Mgal/d. About 80 percent (2.27 Mgal/d) of the total ground-water withdrawal is produced from the Eutaw-McShan aquifer and about 13 percent (0.371 Mgal/d) from the Coffee Sand aquifer. Between normal- and high-growth conditions, total water demand could increase from 72 to 131 percent (2.9 Mgal/d in 1998 to 6.7 Mgal/d in year 2050) with municipal demand increasing from 77 to 146 percent (2.6 to 6.4 Mgal/d). Increased pumping to meet the demand for water was simulated to determine the effect on water levels in the Coffee Sand and Eutaw- McShan aquifers. Under baseline-growth conditions, increased water use by year 2050 could result in an additional 65 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 120 feet of maximum drawdown in the Eutaw-McShan aquifer. Under normal-growth conditions, increased water use could result in an additional 65 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 135 feet of maximum drawdown in the Eutaw-McShan aquifer. Under high-growth conditions, increased water use could result in 75 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 190 feet of maximum drawdown in the Eutaw-McShan aquifer. The resulting highgrowth projected water level for the year 2050 at the center of the drawdown cone in the New Albany area is between 450 and 500 feet above the top of the Eutaw-McShan aquifer.

Mississippi↗

Simulation of ground-water/surface-water flow in the Santa Clara-Calleguas ground-water basin, Ventura County, California

Ground water is the main source of water in the Santa Clara-Calleguas ground-water basin that covers about 310 square miles in Ventura County, California. A steady increase in the demand for surface- and ground-water resources since the late 1800s has resulted in streamflow depletion and ground-water overdraft. This steady increase in water use has resulted in seawater intrusion, inter-aquifer flow, land subsidence, and ground-water contamination. The Santa Clara-Calleguas Basin consists of multiple aquifers that are grouped into upper- and lower-aquifer systems. The upper-aquifer system includes the Shallow, Oxnard, and Mugu aquifers. The lower-aquifer system includes the upper and lower Hueneme, Fox Canyon, and Grimes Canyon aquifers. The layered aquifer systems are each bounded below by regional unconformities that are overlain by extensive basal coarse-grained layers that are the major pathways for ground-water production from wells and related seawater intrusion. The aquifer systems are bounded below and along mountain fronts by consolidated bedrock that forms a relatively impermeable boundary to ground-water flow. Numerous faults act as additional exterior and interior boundaries to ground-water flow. The aquifer systems extend offshore where they crop out along the edge of the submarine shelf and within the coastal submarine canyons. Submarine canyons have dissected these regional aquifers, providing a hydraulic connection to the ocean through the submarine outcrops of the aquifer systems. Coastal landward flow (seawater intrusion) occurs within both the upper- and lower-aquifer systems. A numerical ground-water flow model of the Santa Clara-Calleguas Basin was developed by the U.S. Geological Survey to better define the geohydrologic framework of the regional ground-water flow system and to help analyze the major problems affecting water-resources management of a typical coastal aquifer system. Construction of the Santa Clara-Calleguas Basin model required the compilation of geographic, geologic, and hydrologic data and estimation of hydraulic properties and flows. The model was calibrated to historical surface-water and ground-water flow for the period 1891-1993. Sources of water to the regional ground-water flow system are natural and artificial recharge, coastal landward flow from the ocean (seawater intrusion), storage in the coarse-grained beds, and water from compaction of fine-grained beds (aquitards). Inflows used in the regional flow model simulation include streamflows routed through the major rivers and tributaries; infiltration of mountain-front runoff and infiltration of precipitation on bedrock outcrops and on valley floors; and artificial ground-water recharge of diverted streamflow, irrigation return flow, and treated sewage effluent. Most natural recharge occurs through infiltration (losses) of streamflow within the major rivers and tributaries and the numerous arroyos that drain the mountain fronts of the basin. Total simulated natural recharge was about 114,100 acre-feet per year (acre-ft/yr) for 1984-93: 27,800 acre-ft/yr of mountain-front and bedrock recharge, 24,100 acre-ft/yr of valley-floor recharge, and 62,200 acre-ft/yr of net streamflow recharge. Artificial recharge (spreading of diverted streamflow, irrigation return, and sewage effluent) is a major source of ground-water replenishment. During the 1984-93 simulation period, the average rate of artificial recharge at the spreading grounds was about 54,400 acre-ft/yr, 13 percent less than the simulated natural recharge rate for streamflow infiltration within the major rivers and tributaries. Estimated recharge from infiltration of irrigation return flow on the valley floors averaged about 51,000 acre-ft/yr, and treated sewage effluent averaged about 9,000 acre-ft/yr. Artificial recharge as streamflow diversion to the spreading grounds has occurred since 1929, and treated-sewage effluent has been discharged to stream channels since 1930. Under

Water-Resources Investigations Report↗

Hydrology, water quality, and potential alternatives for water-resources development in the Río Majada and Río Lapa basins near the Albergue Olimpico, southern Puerto Rico

A water-resources investigation was conducted during 1989 in the Rio Lapa mountain basins in southern Puerto Rico, to define the hydrology, water quality, and to describe alternatives for additional water- resources supply. The total water budget for both surface- and ground-water resources in the study area was estimated to be 7,530 acre-feet per year for 1989. The water budget for the ground-water system, from which water needs are supplied in the study area, was estimated to be 2,760 acre-feet per year for 1989. Concentration of dissolved solids and fecal bacteria increased during the dry season as both streamflow and ground-water levels decreased. Water samples collected at two stream sites exceeded the recommended U.S. Environmental Protection Agency fecal bacteria concentration for natural water of 2,000 colonies per 100 milliliters during June to November 1989. Water samples obtained from a well in the Rio Lapa Valley exceeded the secondary drinking-water standard for dissolved solids of 500 milligrams per liter during four dry months. In addition, fecal bacteria concentrations at this water-supply well exceeded the primary fecal- bacteria drinking-water standard of 1 colony per 100 milliliter during June to October 1989. Existing water resources can probably be developed to meet additional demands of 110 acre-feet per year pro- jected for 1995. Storage of the surface-water runoff during the wet season and its gradual release to the study area could offset ground-water declines during the dry season. Ground-water withdrawals can be increased by the construction and use of low- capacity wells to reduce the amount of water lowing out of the study area.

Puerto Rico↗

Quality of ground water around Vadnais Lake and in Lambert Creek watershed, and interaction of ground water with Vadnais Lake, Ramsey County, Minnesota

Vadnais Lake is located in northern Ramsey County, Minnesota. The lake is managed by the St. Paul Water Utility for storage of municipal water supplies that are provided to residents of St. Paul and surrounding communities. In recent years, algal blooms in Vadnais Lake have caused taste and odor problems in St. Paul's municipal water supply. This problem has potentially been exacerbated by phosphorus enrichment of the lake from surface-water transport and from nutrient recycling between the lake and bottom sediments. Phosphorus loading in Vadnais Lake has been linked to increased algal growth. Surface-water drainage from supply lakes and, during wet years, from wetlands in Lambert Creek watershed, which extends over about 20 square miles east of the lake, is known to be a significant source of phosphorus. The role of ground water in the phosphorus budget of the lake was unknown. The results of this study indicate that ground-water transport of phosphorus into Vadnais Lake is a small part of the phosphorus budget of the lake. Seepage into and out of Vadnais Lake was estimated by the following methods: (1) interpretation of the hydraulic conductivities of glacial deposits around the lake and of the hydraulic gradients between ground water in these deposits and the lake; and (2) interpretation of the hydraulic conductivities of lakebed materials and of the hydraulic gradients between ground water in the lakebed and the lake. The estimated net annual seepage out of the lake determined by the second method of 9.56 x 10 7 feet 3 per year was greater by an order of magnitude than the value determined by the first method, which was 7.63 x 10 6 feet 3 per year. The net seepage out of Vadnais Lake was a small part of the lake water budget. Inflow to the lake is mostly streamflow from Sucker Creek, which is water from the Mississippi River routed through a series of lakes. Outflow from the lake is mostly withdrawals by the St Paul Water Utility. The net seepage out of the lake between spring and winter was from less than 1 to about 4 percent of the total loss attributed to withdrawals and evaporation. The quality of the ground water in the study area was similar to the quality measured in shallow glacial-drift aquifers throughout Minnesota. Calcium magnesium bicarbonate water was the dominant type. Concentrations of volatile organic compounds in ground-water samples were below detection limits. The concentration of total phosphorus in ground-water samples generally was below 0.15 milligrams per liter. The results of the seepage analysis and ground-water quality evaluation indicate that the effect of the quality of the surrounding ground water on the quality of Vadnais Lake probably was small. Ground water that discharged to the lake generally had lower concentrations of calcium, magnesium, bicarbonate, and total dissolved solids than the lake. The mixing of ground water with the lake slightly diluted the lake with respect to these constituents.

Minnesota↗

Simulated ground-water flow and sources of water in the Killbuck Creek Valley near Wooster, Wayne County, Ohio

The stratified-drift aquifer in the 3,000-ft (feet)-wide and 100-ft-deep buried valley of Killbuck Creek near Wooster in northeastern Ohio was studied. The stratified drift with adjacent sandstone and shale bedrock produce a system of ground-water flow representative of the western part of the glaciated north-eastern United States. The stratified-drift aquifer is an excellent source of water for municipal and industrial wells. The aquifer is recharged locally by water from precipitation on the valley floor and uplands, by infiltration from streams, and by lateral flow to the valley from the uplands. As a result, the aquifer is vulnerable to surface or subsurface spills of contaminants in the valley or the adjacent uplands. Quality of water in the stratified drift is affected by influx of water from bedrock lateral to or beneath the valley. This influx is controlled, in part, by the pumping stress placed on the stratified-drift aquifer. Hydrogeologic and aqueous-geochemical data were analyzed to establish the framework necessary for stead-state and transient simulations of ground-water flow in stratified drift and bedrock with a three-layer ground-water-flow model. A new model routine, the Variable-Recharge procedure, was developed to simulate areal recharge and the contribution of the uplands to the drift system. This procedure allows for water applied to land surface to infiltrate or to be rejected. Rejected recharge and ground water discharged when the water table is at land surface form surface runoff-this excess upland water can be redirected as runoff to other parts of the model. Infiltration of streamwater, areal recharge to uplands and valley, and lateral subsurface flow from the uplands to the valley are sources of water to the stratufued0druft aquifer. Water is removed from the stratified-drift aquifer at Wooster primarily by production wells pumping at a rate of approximately 8.5 ft3/s (cubic feet per second). The ground-water budget resulting from two types of simulations of ground-water flow in this study indicates the primary sources of water to the wells are recharge at or near land surface and lateral subsurface flow from the shale and sandstone bedrock. Components of recharge at land surface include induced infiltration from streams, precipitation on the valley floor, and infiltration of unchanneled upland runoff that reaches the valley floor. The steady-state simulation was designed to represent conditions during the fall of 1984. The transient simulation was designed to represent an 11-day snowmelt event, 23 February to 5 March 1985, that caused water levels to rise significantly throughout the valley. Areal recharge to the valley and flow from the uplands to the valley were determined through the Variable-Recharge procedure. The total steady-state recharge to the valley was 12.5 ft3/s. Upland sources, areal valley recharge, and induced infiltration from Killnuck Creek accounted for 63, 23, and 8 percent, respectively, of the valley recharge. An analysis of the simulated vertical flow to the buried stratified drift through surficial slit, clay, and fine sand indicates that about 75 percent of the total recharge to the buried deposits is the sum of areally extensive, relatively small flows less than about 0.01 ft? /s per model node), whereas about 25 percent of the recharge results from a really restricted, relatively large flows (greater than about 0.01 ft? /s per model node). The large-magnitude flows are located primarily beneath Clear and Little Killbuck Creeks where seepage provides abundant recharge and the surficial sediments grade into coarser alluvial-fan deposits. Chemical and isotopic studies of ground water and streamwater combined with measurements of stream infiltration provide independent support for the conclusions derived from computer simulation of ground-water flow. In addition, the chemical and isotopic studies helped quantity the rate and pathways of infiltrating water from

Water-Resources Investigations Report↗

Nitrate in ground water and spring water near four dairy farms in North Florida, 1990-93

Concentrations of nitrate and other selected water- quality characteristics were analyzed periodically for two years in water from 51 monitoring wells installed at four farms and in water discharging from three nearby springs along the Suwannee River in Lafayette and Suwannee Counties to examine the quality of ground water at these farms and the transport of nutrients in ground water to the nearby spring-fed Suwannee River: Ground water from shallow wells, which were completed in the top ten feet of the saturated zone in a surficial sandy aquifer and in the karstic Upper Floridan aquifer generally had the highest concentrations of nitrate, ranging from <.02 to 130 mg/L as nitrogen. Nitrate concentrations commonly exceeded the primary drinking water standard of 10 mg/L for nitrate as nitrogen in water from shallow wells, which tapped the top ten feet of the uppermost aquifers near waste-disposal areas such as wastewater lagoons and defoliated, intensive-use areas near milking barns. Upgradient from waste-disposal areas, concentrations of nitrate in ground water were commonly less than 1 mg/L as nitrogen. Water samples from deep wells (screened 20 feet deeper than shallow wells in these aquifers) generally had lower concentrations of nitrate (ranging from <0.02 to 84 mg/L) than water from shallow wells. Water samples from the three monitored springs (Blue, Telford, and Convict Springs) had nitrate concentrations ranging from 1.5 to 6.5 mg/L as nitrogen, which were higher than those typically occurring in water from upgradient wells at the monitored dairy farms or from back- ground wells sampled in the region. Analyses of nitrogen isotope ratios in nitrate indicated that leachate from animal wastes was the principal source of nitrate in ground water adjacent to waste-disposal areas at the monitored and unmonitored dairy farms. Leachate from a combi- nation of fertilizers, soils, and animal wastes appeared to be the source of nitrate in ground- water downgradient from pastures and wastewater spray fields at dairy farms and in water discharging from three nearby springs. Although denitrifying bacteria were present in counts sometimes exceeding 240,000 colonies/100mL in water from dairy-farm monitoring wells, ground water in the uppermost aquifers in Lafayette and Suwannee Counties generally contained too much oxygen for denitrification to remove nitrate from shallow ground water. Denitrification was more likely to occur in deeper ground water, which typically has lower dissolved oxygen concentrations.

Florida↗

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas -- Shallow ground-water quality and land use in the Albuquerque area, central New Mexico, 1993

This report describes the quality of shallow ground water and the relations between land use and the quality of that shallow ground water in an urban area in and adjacent to Albuquerque, New Mexico. Water samples were collected from 24 shallow wells. Samples were analyzed for selected common constituents, nutrients, trace elements, radionuclides, volatile organic compounds, and pesticides. The study area, which is in the Albuquerque Basin in central New Mexico, was limited to the Rio Grande flood plain; depth to water in this area generally is less than 25 feet. The amount and composition of recharge to the shallow ground-water system are important factors that affect shallow ground-water composition in this area. Important sources of recharge that affect shallow ground-water quality in the area include infiltration of surface water, which is used in agricultural land-use areas to irrigate crops, and infiltration of septic-system effluent in residential areas. Agricultural land use represents about 28 percent of the area, and residential land use represents about 35 percent of the total study area. In most of the study area, agricultural land use is interspersed with residential land use and neither is the dominant land use in the area. Land use in the study area historically has been changing from agricultural to urban. The composition of shallow ground water in the study area varies considerably. The dissolved solids concentration in shallow ground water in the study area ranges from 272 to 1,650 milligrams per liter, although the relative percentages of selected cations and anions do not vary substantially. Calcium generally is the dominant cation and bicarbonate generally is the dominant anion. Concentrations of nutrients generally were less than 1 milligram per liter. The concentration of many trace elements in shallow ground water was below or slightly above 1 microgram per liter and there was little variation in the concentrations. Barium, iron, manganese, molybdenum, and uranium were the only trace elements analyzed for that had median concentrations greater than 5 micrograms per liter. Volatile organic compounds were detected in 5 of 24 samples. Cis-1,2-dichloroethene and 1,1-dichloroethane were the most commonly detected volatile organic compounds (detected in two samples each). Pesticides were detected in 8 of 24 samples. Prometon was the most commonly detected pesticide (detected in 5 of 24 samples). Concentrations of volatile organic compounds and pesticides detected were much smaller than any U.S. Environmental Protection Agency standards that have been established. Infiltration of surface water and the evaporation or transpiration of this water, which partially is the result of past and present agricultural land use, seem to affect the concentrations of common constituents in shallow ground water in the study area. The small excess chloride in shallow ground water relative to surface water that has been affected by evaporation or transpiration could be due to mixing of shallow ground water with small amounts of precipitation/bulk deposition or septic-system effluent. Infiltration of septic-system effluent (residential land use) has affected the shallow ground-water composition in parts of the study area on the basis of the small dissolved oxygen concentrations, large dissolved organic carbon concentrations, and excess chloride. Despite the loading of nitrogen to the shallow ground-water system as the result of infiltration of septic-system effluent, the small nitrogen concentrations in shallow ground water probably are due to the small dissolved oxygen concentrations and relatively large dissolved organic carbon concentrations. The small concentrations and lack of variation of most trace elements indicate that land use has not substantially affected the concentration

New Mexico↗