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Integrated geoscience studies in the Greater Yellowstone Area - Volcanic, tectonic, and hydrothermal processes in the Yellowstone geoecosystem

Yellowstone National Park, rimmed by a crescent of older mountainous terrain, has at its core the Quaternary Yellowstone Plateau, an undulating landscape shaped by forces of volcanism, tectonism, and later glaciation. Its spectacular hydrothermal systems cap this landscape. From 1997 through 2003, the United States Geological Survey Mineral Resources Program conducted a multidisciplinary project of Yellowstone National Park entitled Integrated Geoscience Studies of the Greater Yellowstone Area, building on a 130-year foundation of extensive field studies (including the Hayden survey of 1871, the Hague surveys of the 1880s through 1896, the studies of Iddings, Allen, and Day during the 1920s, and NASA-supported studies starting in the 1970s—now summarized in USGS Professional Paper 729 A through G) in this geologically dynamic terrain. The project applied a broad range of scientific disciplines and state-of-the-art technologies targeted to improve stewardship of the unique natural resources of Yellowstone and enable the National Park Service to effectively manage resources, protect park visitors from geologic hazards, and better educate the public on geologic processes and resources. This project combined a variety of data sets in characterizing the surficial and subsurface chemistry, mineralogy, geology, geophysics, and hydrothermal systems in various parts of the park. The sixteen chapters presented herein in USGS Professional Paper 1717, Integrated Geoscience Studies in the Greater Yellowstone Area—Volcanic, Tectonic, and Hydrothermal Processes in the Yellowstone Geoecosystem , can be divided into four major topical areas: (1) geologic studies, (2) Yellowstone Lake studies, (3) geochemical studies, and (4) geophysical studies. The geologic studies include a paper by Ken Pierce and others on the influence of the Yellowstone hotspot on landscape formation, the ecological effects of the hotspot, and the human experience and human geography of the greater Yellowstone ecosystem as influenced by the Yellowstone hotspot. Another paper by Paul Carrara describes the recent movement of a large landslide block dated by tree-ring analyses in the Tower Falls area. The section under Yellowstone Lake studies begins with a classic paper by J. David Love and others on ancestral Lake Yellowstone. Other papers in this section include results and interpretation of the high-resolution bathymetric, seismic reflection, and submersible studies by Lisa Morgan and others. Ken Pierce and others describe results from their studies of shorelines along Yellowstone Lake and their interpretation of inflation-deflation cycles, tilting, and faulting in the Yellowstone caldera. The influence of sublacustrine hydrothermal vent fluids on the geochemistry of Yellowstone Lake is described by Laurie Balistrieri and others. In Pat Shanks and others’ chapter, hydrothermal reactions, stable-isotope systematics, sinter deposition, and spire formation are related to the geochemistry of sublacustrine hydrothermal deposits in Yellowstone Lake. The geochemical studies section considers park-wide geochemical systems in Yellowstone National Park. In Bob Rye and Alfred Truesdell’s paper, the question of recharge to the deep thermal reservoir underlying the geysers and hot springs of Yellowstone National Park is discussed. Irving Friedman and Dan Norton report on the chloride flux emissions from Yellowstone in their paper questioning whether Yellowstone is losing its steam. Wildlife issues as addressed by examining trace-element and stable-isotope geochemistry are discussed in a chapter by Maurice Chaffee and others. In another chapter by Chaffee and others, natural and anthropogenic anomalies and their potential impact on the environment using geochemistry is reported. Pam Gemery-Hill and others present geochemical data for selected rivers, lake waters, hydrothermal vents, and subaerial geysers for the time interval of 1996–2004. The life cycle of gold deposits near the northeast corner of the park is discussed by Brad Van Gosen. Under the geophysical studies segment, Ray Kokaly and others use AVIRIS (Airborne Visible and Infrared Spectroscopy) data to map vegetation cover and microbial communities in Yellowstone National Park. Eric Livo and others report their results using AVIRIS data on hydrothermally altered rock and hot-spring deposits. In his final paper following a half century of scientific research, Irving Friedman presents data on monitoring changes in geothermal activity at Norris Geyser Basin using satellite telemetry. These papers summarize a near-decade-long effort by the USGS from the late 1990s to mid-2000s. In 2001, the USGS in cooperation with the National Park Service (Yellowstone National Park) and the University of Utah established the Yellowstone Volcano Observatory, the 5th volcano observatory in the United States.

Professional Paper↗

Frictional properties of the Mount St. Helens gouge

Frictional properties of gouge bounding the solid dacite plug that extruded at Mount St. Helens during 2004 and 2005 may have caused stick-slip upward motion of the plug and associated seismicity. Laboratory experiments were performed with a ring-shear device to test the dependence of the peak and steady-state frictional strength of the gouge on shearing rate and hold time. A remolded gouge specimen (~0.012 m 3 ) was sheared under constant normal stresses ranging from 5 to 200 kPa and at rates ranging from 10 -6 to 10 -3 m/s. The gouge exhibited rate-weakening behavior at rates lower than 1×10 -4 m/s and rate-strengthening at rates above 5×10 -4 m/s. Peak strengths occurred during the onset of shearing, when displacements were generally less than 0.5 mm. In slide-holdslide tests, the peak strength of the gouge increased logarithmically as hold times increased from 3 s to almost 10 5 s. Rate-weakening friction is a requirement for stick-slip behavior that is satisfied by the Mount St. Helens gouge. Indeed, regular stick-slip oscillations were observed in two experiments performed at the highest normal stress and lowest rates of shear. The conditions under which this stick-slip motion occurred indicate that the gouge also satisfies a second criterion for stick-slip behavior of materials exhibiting rateand-state dependent friction-gouge stiffness exceeds that of the ascending magma that drives upward motion of the plug. The presence of highly compliant magma as a driving element may be crucial for generating stick-slip instabilities at the shallow earthquake focal depths observed during the eruption.

Washington↗

Deglaciation and postglacial treeline fluctuation in the northern San Juan Mountains, Colorado

The San Juan Mountains of southwestern Colorado contain numerous lakes and bogs at and above treeline. In June 1978, Lake Emma, a tarn above present-day treeline, was suddenly drained by the collapse of underground mine workings. This study was initiated because the draining exposed a well-preserved archive of subfossil coniferous wood fragments that provided a unique opportunity to further our understanding of the paleoclimatic history of this region. These paleoclimatic studies-coniferous macrofossil identification in conjunction with radiocarbon dating, deuterium analysis of the dated conifer fragments, as well as pollen and fossil insect analyses-yielded new information regarding Holocene climate and accompanying treeline changes in the northern San Juan Mountains. This report synthesizes previously published reports by the author and other investigators, and unpublished information of the author bearing on late Pleistocene and Holocene treeline and climate in this region. Retreat of the glacier that occupied the upper Animas River valley from its Pinedale terminal position began about 19.4 + or - 1.5 10 Be thousands of years ago and was essentially complete by about 12.3 + or - 1.0 10 Be thousands of years ago. Two sets of late Pleistocene cirque moraines were identified in the northern San Juan Mountains. The older set is widespread and probably correlates with the Younger Dryas (11,000-10,000 radiocarbon years before present; 12,800-11,500 calendar years). The younger set is found only in the Grenadier Range and represents remnant glacier ice lying in well-shaded niches in a mountain range undergoing rapid deglaciation. A snowbank at the northern base of this range appears to be fronted by a Little Ice Age moraine. Soon after deglaciation the average July temperature is estimated to have been about 5°C cooler and timberline about 650 meters lower than at present. However, timberline (and treeline) responded rapidly to the postglacial warming and reached higher-than-present elevations by the early Holocene. A comparison of recently obtained accelerator mass spectrometry radiocarbon ages of coniferous wood fragments from Lake Emma, previously dated by conventional radiocarbon methods during the 1980s, led to a slight modification of previously published ages of Holocene treeline fluctuations. As early as 9,200 radiocarbon years before present (about 10,400 calendar years) and probably to about 5,400 radiocarbon years before present (about 6,200 calendar years), treeline was at least 80 meters higher than at present (about 3,660 meters). Furthermore, a large conifer fragment with a complacent annual ring record suggests that timberline may have been at least 140 meters higher than present (about 3,600 meters) about 8,000 radiocarbon years before present (about 8,900 calendar years). These past elevations of treeline and timberline suggest that growing-season temperatures were at least 0.5°-0.9°C warmer than at present. Deuterium data from the Lake Emma wood samples suggests that the maximum average temperature change from about 9,000 to 5,400 radiocarbon years before present (about 10,150 to 6,200 calendar years) was about 4°C. Owing to these warmer temperatures the summer monsoon circulation, which currently brings a large part of the annual precipitation to the San Juan Mountains, probably was more intense during the early and middle Holocene than it is today. Between about 5,400 and 3,500 radiocarbon years before present (about 6,200 and 3,770 calendar years) it appears that treeline was near its present-day limit. After 3,500 radiocarbon years before present (about 3,770 calendar years), evidence of treeline position is very sparse, suggesting that treeline lay at, or below, its present-day elevation. However, a spruce krummholz fragment from the Lake Emma site provided two radiocarbon ages of about 3,100 radiocarbon years before present (about 3,300 cal

Colorado↗

Land use, population dynamics, and land-cover change in eastern Puerto Rico: Chapter B in Water quality and landscape processes of four watersheds in eastern Puerto Rico

We assessed current and historic land use and land cover in the Luquillo Mountains and surrounding area in eastern Puerto Rico, including four small subwatersheds that are study watersheds of the U.S. Geological Survey's Water, Energy, and Biogeochemical Budgets (WEBB) program. This region occupies an area of 1,616 square kilometers, about 18 percent of the total land in Puerto Rico. Closed forests occupy about 37 percent of the area, woodlands and shrublands 7 percent, nonforest vegetation 43 percent, urban development 10 percent, and water and natural barrens total less than 2 percent. The area has been classified into three main land-use categories by integrating recent census information (population density per barrio in the year 2000) with satellite image analyses (degree of developed area versus natural land cover). Urban land use (in this analysis, land with more than 20 percent developed cover within a 1-square-kilometer area and population density greater than 500 people per square kilometer) covered 16 percent of eastern Puerto Rico. Suburban land use (more than 80 percent natural land cover, more than 500 people per square kilometer, and primarily residential) covers 50 percent of the area. Rural land use (more than 80 percent natural land cover, less than 500 people per square kilometer, and primarily active or abandoned agricultural, wetland, steep slope, or protected conservation areas) covered 34 percent of the area. Our analysis of land-cover change indicates that in the 1990s, forest cover increased at the expense of woodlands and grasslands. Urban development increased by 16 percent during that time. The most pronounced change in the last seven decades has been the shift from a nonforested to a forested landscape and the intensification of the ring of urbanization that surrounds the long-protected Luquillo Experimental Forest.

Professional Paper↗

Postglacial eruptive history, geochemistry, and recent seismicity of Aniakchak volcano, Alaska Peninsula

Aniakchak is a Pleistocene to Holocene composite volcano of the Alaska&ndash;Aleutian arc that suffered at least one caldera-forming eruption in postglacial time and last erupted in 1931. The oldest recognized postglacial eruption, Aniakchak I, produced andesite ignimbrite ca. 9,500&ndash;7,500 14 C yr B.P. Subsequently, a vent northeast of the summit issued dacite&ndash;rhyodacite magma ca. 7,000 14 C yr B.P. mainly as the Black Nose Pumice falls. The ca. 3,430 14 C yr B.P. Aniakchak II eruption produced rhyodacite plinian fall followed by rhyodacite and andesite ignimbrite extending &ge;50 km to the Bering Sea and Pacific coasts and resulted in collapse of the 10-km-diameter caldera. Postcaldera vents are mainly on the caldera ring-fracture system. The earliest extruded small dacite domes into a deep caldera lake and a lava flow on the northwest flank. Three basaltic andesite&ndash;andesite tuff cones were constructed on the eastern caldera floor after catastrophic draining of the lake by ~200 m. Dacite&ndash;andesite magmas issued from Vent Mountain and Half Cone starting as early as ~1,000 years ago. Plinian eruption at Half Cone ~400 14 C yr B.P. yielded widespread dacite Pink and overlying andesite Brown Pumice fall deposits. Strombolian eruption of basaltic andesite built Blocky Cone after Half Cone and most Vent Mountain activity. The most recent eruption, in 1931, yielded dacite&ndash;rhyodacite tephra followed by relatively voluminous andesite tephra and ended with minor basaltic andesite. Current indications of an active magmatic system include high 3 He/ 4 He of CO 2 -rich gas at intracaldera Surprise Lake, InSAR pattern of caldera floor subsidence, and episodic seismicity. The majority of earthquakes are long-period (LP) events. Epicenters for 135 (2009&ndash;2012; M L &le;2.1) define a bow-tie pattern elongated parallel to plate convergence. Hypocenters identify events14&ndash;28 km below sea level (bsl), few events 7&ndash;14 km bsl beneath the caldera, and events <10 km bsl concentrated under Vent Mountain. Recent seismicity is consistent with long-lived mush in the quiet zone, from which magma escapes to be stored ephemerally to within ~2.5 km bsl. Future volcanic activity of Aniakchak could include hydromagmatic explosions, possibly followed by effusion or strombolian eruption of basaltic andesite to Plinian eruption of dacite. Another voluminous eruption, such as Aniakchak II, is considered unlikely in the near future.

Alaska↗

Geology of the Arabian Peninsula; shield area of western Saudi Arabia

Western Arabia lies within the low-latitude desert of north Africa and the Middle East, the core being the Arabian segment of the African Shield. The core of complex basement rocks accounts for about 670,000 km 2 , or one-third of the Arabian Peninsula. Reconnaissance mapping of these crystalline rocks, together with bordering sedimentary rocks and volcanic flows, begun in 1950, resulted during the next 13 years in a series of geologic and geographic maps without extensive texts. The maps served as general guides for development of natural resources, including water supplies, ore deposits, and building materials. An intensive exploration program that began in 1963 and involved numerous geologists has vastly increased geologic information. Rainfall in Arabia is meager and episodic, and vegetation is sparse except in isolated copses on the crest of the Hejaz Range. Comparison of flora with similar species in the Sudan, where records of rainfall have long been kept, allows evaluation of mean annual precipitation. Wandering bedouin following fodder created a delicate balance between population and water supply-now disturbed by wells drilled in alluvium and lava fields. A trapezoidal region of Precambrian crystalline rocks lies along the northeast flank of the Red Sea, with two long prongs extending northwest and southeast for a total of 1,800 km. These basement rocks of the Arabian Shield are well exposed on the uplands, scarp mountains, and coastal pediments where the Phanerozoic cover rocks have been stripped as a result of Paleozoic epeirogeny and Tertiary ramping. The shield outcrops are divided into three tectonic provinces by N. 45&deg;W.- trending shear zones of the Najd fault system of latest Proterozoic and possibly earliest Paleozoic time. The southwestern province, the 'Asir1 upland, was sharply uplifted and tilted to the northeast during the Neogene. The northwestern province, consisting of the Ash Shifa'- Hisma upland as well as Jabal Shammar farther east, similarly was uplifted and tilted. These two provinces are separated by the flat-lying median N ajd province, which is chiefly bounded by the principal Najd faults. The outcrops of the shield rocks are of the Late Proterozoic Eonupper Riphean to Vendian or Infracambrian epochs, including the Ediacarian System. The most reliable isotopic ages range from about 900 to 560 m.y., but some Middle Proterozoic rocks may be present in the easternmost shield. The rocks are divided into six lithostratigraphic sequences, two plutonic suites, and an ophiolitic suite. The mafic and ultramafic volcanic and plutonic rocks of the ophiolitic suite everywhere were emplaced tectonically and are probably of different ages in different places. Some ophiolite occurs as obducted blocks, but most is highly deformed and altered to serpentinite in fault zones that mostly define sutures between different tectonic blocks or terranes within the shield. Three of the lithostratigraphic sequences consist of mafic to silicic volcanic rocks and volcanic-derived clastic rocks which, with their subvolcanic plutonic rocks of a dioritic suite, probably formed in oceanic island arcs during convergent plate tectonism. These rocks make up the primary, or first-formed, crust of the shield. Chemical analyses show that the primary shield rocks, regardless of age, are principally calc-alkalic with some associated tholeiitic varieties. Most of the layered rocks are andesitic, but they range from basalt to dacite and in places contain intercalated pillow basalt, marble, chert, and carbonaceous or graphitic schist. Most of the plutonic rocks of the dioritic suite are dioritic, but they range from gabbro to trondhjemite and rarely contain potassium feldspar. The sequences and an associated dioritic suite become younger toward the eastern shield, that is, the primary crust of the shield youngs toward the east. Two western sequences consist of the Jiddah (Samran) and BaishBahah Groups and range in radiometric age from about 900 to 800 m.y.; the eastern sequence consists of the Halaban (Hulayfah) Group and ranges from 800 to about 700 m.y. During subsequent orogeny, most of the rocks were intensely deformed and mostly metamorphosed to upper greenschist facies, but rising in places to the almandine-amphibolite facies. Two other lithostratigraphic sequences with an associated plutonic granitic suite are the products of two mountain-building episodes during which the primary crust was greatly thickened and converted into craton. The two sequences, including largely the Ablah (Al Ays) and Murdama (Shammar) Groups, consist of abundant sedimentary rocks, commonly arkosic, that are the erosional products of the orogenic mountains. They are several thousand meters thick. Less abundant calc-alkalic to alkalic volcanic rocks, commonly dacitic and rhyolitic, are intercalated with the sedimentary rocks. The plutonic rocks of the granitic suite in association with both sequences have syntectonic and posttectonic phases, are products of the orogenies, and are the principal new ingredients making up the craton. Gneiss domes were a significant part of these cratonization orogenies. In association with orogenic crustal heating, some of the low-density, more silicic tonalitic and trondhjemitic rocks of the primary crust rose as gneiss domes. Partial melting in the middle or lower crust below the gneiss domes produced large volumes of granitic magma that intruded the gneiss domes as granodioritic batholiths. The Ablah Group and the older part of the granitic suite are about 775 to 740 Ma old and are associated with the Ablah orogeny and early cratonization in the western and earlier formed half of the shield. The Murdama (Shammar) Group and the younger part of the granitic suite are about 660 to 580 Ma old and are associated with the culminant orogeny and late cratonization that was shieldwide. The granitic suite during both orogenies consists of early, syntectonic granodiorite batholiths associated with the gneiss domes and late, posttectonic monzogranite plutons. Only during the culminant orogeny, late magmatic evolution produced syenogranite and alkali-feldspar granite commonly in circular and ring-structured plutons and with associated explosive volcanic deposits (Shammar Group); final products, some of which have economic potential, were peralkalic and peraluminous. The late plutonism of the culminant orogeny was distinctly bimodal in that subordinate gabbroic rocks are associated with the granites. Various building blocks or terranes of the andesitic and dioritic primary crust were collisionally agglomerated during the Ablah orogeny, early cratonization, whereas the entire shield as currently exposed was further collisionally accreted and compressionally consolidated during the culminant orogeny, final cratonization. Thousands of kilometers of oceanic crust had to be subducted in about 300 m.y. to form the large primary crust of the Arabian Shield. The inevitable collisional events during consumption of such a large volume of oceanic crust invariably led to numerous collisional orogenies that collectively encompass the widely known Pan African tectonic episode. The youngest lithostratigraphic sequence, the Jubaylah Group, is essentially postcratonic, although it is the end product of the collisional culminant orogeny. Final east-west compression of the entire shield from about 580 to 560 m.y. caused the craton to fracture along the large northwest-trending, left-lateral faults and elsewhere along lesser, northeast-trending, right-lateral, conjugate faults of the N ajd fault system. Erosional products of this more localized deformation were the sedimentary rocks of the Jubaylah Group, which also includes intercalated andesitic to basaltic volcanic rocks of a mafic alkalic compositional trend. The collisional edge of an old continental plate (or tectonic fragments thereof), suspected on the eastern edge of the Arabian Shield, has not been shown with certainty to be exposed. Presumably, widespread contamination from such an old continental crust affects U/Pb, Sm/Nd, Rb/Sr, and common lead ratios in the young plutonic rocks of the easternmost shield. One mass of anorthosite near Jabal Khida' on the central eastern edge of the shield may be a fragment of this old continental plate in that associated granodiorite may be as old as 1,600 to 1,800 Ma. Epeirogenic uplift, erosion, and cooling of the uppermost shield during Early and Middle Cambrian time is indicated by an average fission track age of 510&plusmn;52 m.y., on sphene from diorite (hornblende K-Ar age of 615&plusmn;12 m.y.) in the southwestern part of the shield. The hiatus was followed by extensive deposition of the Cambro-Ordovician Saq Sandstone in the north and northeast and the Wajid Sandstone in the southeast and south of the shield. The Cambrian Siq Sandstone had already been deposited in the northern part. During the middle and late Paleozoic, broad epeirogeny caused further erosion of the shield until marine transgression deposited the Upper Permian Khuff Formation at least in the eastern part of the shield. In the southwestern shield, the nonmarine Upper Triassic Khums Sandstone was deposited variably on Wajid or Precambrian rocks and is overlain by limestone of the middle Upper Jurassic Amran Formation. Except for shallow marine sandstone of problematic Cretaceous age deposited on the Amran Formation in the south.western shield and on Precambrian rocks in the northwestern shield, the younger beds on the shield are Paleocene and younger, with the possibility that the lowermost are upper Maestrichtian. The early Tertiary beds contain vertebrate fossils of coastal marine or estuarine environment 250 km east of the Red Sea in the central shield. Marginal marine sediments were deposited in a western tongue of the latest Tethys Sea as late as Eocene on the western shield and at least as far south as Jiddah. The great harrats of flood basalt erupted on th~ western shield during late Oligocene and early Miocene at the same time a 2,000-kmlong continental rift valley developed along the future Red Sea axis. Within this rift valley, Baid freshwater tuffaceous lakebeds were deposited between mafic and silicic volcanoes. During late early Miocene time, the Red Sea opened at a rate of 4.4 cm/yr in a firststage movement while continental dikes and swarms of oceanic tholeiitic dikes, gabbro, and granophyre plutonic rocks were intruded into the rift sedimentary and volcanic rocks at the newly formed continental margin. The continental margin was deformed and greatly extended at this time. About 14 or 15 m.y., as the first-stage spreading stopped, the Red Sea Escarpment rose; its erosion caused deposition of coarse conglomerate of the Bathan Formation. About 3,000 m of evaporite was deposited on the young Red Sea oceanic crust during the late Miocene desiccation crisis. A second stage of sea-floor spreading about 4-5 m.y. produced the Red Sea axial trough, consisting of oceanic crust, as well as renewed uplift and tilting of the three tectonic provinces in response to compression from counterclockwise rotation against the Dead Sea Rift. This late movement caused widespread major stream capture, especially along the wadis that formerly drained southwesterly or northwesterly, the channels turning westward through narrow gorges to the coastal plain and the Red Sea.

Professional Paper↗

Geologic Map of the MTM -30262 and -30267 Quadrangles, Hadriaca Patera Region of Mars

Introduction Mars Transverse Mercator (MTM) -30262 and -30267 quadrangles cover the summit region and east margin of Hadriaca Patera, one of the Martian volcanoes designated highland paterae. MTM -30262 quadrangle includes volcanic deposits from Hadriaca Patera and Tyrrhena Patera (summit northeast of map area) and floor deposits associated with the Dao and Niger Valles canyon systems (south of map area). MTM -30267 quadrangle is centered on the caldera of Hadriaca Patera. The highland paterae are among the oldest, central-vent volcanoes on Mars and exhibit evidence for explosive eruptions, which make a detailed study of their geology an important component in understanding the evolution of Martian volcanism. Photogeologic mapping at 1:500,000-scale from analysis of Viking Orbiter images complements volcanological studies of Hadriaca Patera, geologic investigations of the other highland paterae, and an analysis of the styles and evolution of volcanic activity east of Hellas Planitia in the ancient, cratered highlands of Mars. This photogeologic study is an extension of regional geologic mapping east of Hellas Planitia. The Martian highland paterae are low-relief, areally extensive volcanoes exhibiting central calderas and radial channels and ridges. Four of these volcanoes, Hadriaca, Tyrrhena, Amphitrites, and Peneus Paterae, are located in the ancient cratered terrains surrounding Hellas Planitia and are thought to be located on inferred impact basin rings or related fractures. Based on analyses of Mariner 9 images, Potter (1976), Peterson (1977), and King (1978) suggested that the highland paterae were shield volcanoes formed by eruptions of fluid lavas. Later studies noted morphologic similarities between the paterae and terrestrial ash shields and the lack of primary lava flow features on the flanks of the volcanoes. The degraded appearances of Hadriaca and Tyrrhena Paterae and the apparently easily eroded materials composing their low, broad shields further suggest that the highland paterae are composed predominantly of pyroclastic deposits. Analyses of eruption and flow processes indicate that the distribution of units at Hadriaca and Tyrrhena Paterae is consistent with emplacement by gravity-driven pyroclastic flows. Detailed geologic study of the summit caldera and flanks of Hadriaca Patera is essential to determine the types of volcanic materials exposed, the nature of the processes forming these deposits, and the role of volcanism in the evolution of the cratered highlands that are characteristic of the southern hemisphere of Mars.

Scientific Investigations Map↗

Geologic map of the Artemis Chasma quadrangle (V-48), Venus

Artemis, named for the Greek goddess of the hunt, represents an approximately 2,600 km diameter circular feature on Venus, and it may represent the largest circular structure in our solar system. Artemis, which lies between the rugged highlands of Aphrodite Terra to the north and relatively smooth lowlands to the south, includes an interior topographic high surrounded by the 2,100-km-diameter, 25- to 200-km-wide, 1- to 2-km-deep circular trough, called Artemis Chasma, and an outer rise that grades outward into the surrounding lowland. Although several other chasmata exist in the area and globally, other chasmata have generally linear trends that lack the distinctive circular pattern of Artemis Chasma. The enigmatic nature of Artemis has perplexed researchers since Artemis Chasma was first identified in Pioneer Venus data. Although Venus' surface abounds with circular to quasi-circular features at a variety of scales, including from smallest to largest diameter features: small shield edifices (>1 km), large volcanic edifices (100-1,000 km), impact craters (1-270 km), coronae (60-1,010 km), volcanic rises and crustal plateaus (~1,500-2,500 km), Artemis defies classification into any of these groups. Artemis dwarfs Venus' largest impact crater, Mead (~280 km diameter); Artemis also lacks the basin topography, multiple ring structures, and central peak expected for large impact basins. Topographically, Artemis resembles some Venusian coronae; however Artemis is an order of magnitude larger than the average corona (200 km) and about twice the size of Heng-O Corona (which is 1,010 km in diameter), the largest of Venusian coronae. In map view Artemis' size and shape resemble volcanic rises and crustal plateaus; however, both of these classes of features differ topographically from Artemis. Volcanic rises and crustal plateaus form broad domical regions, and steep-sided regions with flat tops, respectively; furthermore, neither rises nor plateaus include circular troughs. So although it seems clear what Artemis is not, there is little consensus about what Artemis is, much less how Artemis formed. Debate during the past decade has resulted in the proposal of at least four hypotheses for Artemis' formation. The first (herein referred to as H1) is that Artemis Chasma represents a zone of northwest-directed convergence and subduction. The second hypothesis (herein referred to as H2) is that Artemis consists of a composite structure with a part of its interior region marking the exposure of deformed ductile deep-crustal rocks analogous to a terrestrial metamorphic core complex. The third (herein referred to as H3) is that Artemis reflects the surface expression of an ancient (>3.5 Ga) huge bolide impact event on cold strong lithosphere. The fourth hypothesis (herein referred to as H4) is that Artemis marks the surface expression of a deep mantle plume. Each of these hypotheses holds different implications for Venus geodynamics and evolution processes, and for terrestrial planet processes in general. Viability of H1 would provide support that terrestrial-like plate-tectonic processes once occurred on Earth's sister planet. The feasibility of H2 would require high values of crustal extension and therefore imply that significant horizontal displacements occurred on Venus-displacement that may or may not be related to terrestrial-like plate-tectonic processes. The possibility of H3 would suggest that Venus' surface is extremely old, and that Venus has experienced very little dynamic activity for the last 3.5 billion years or more; this would further imply that Venus is essentially tectonically dead, and has been for most of its history. This view contrasts strongly with studies that highlight a rich history of Venus including activity at least as young as 750 million years ago, and quite likely up to the present. If H4 has credibility, then Artemis could provide clues to cooling mechanisms of Earth's sister planet. Each of these hypotheses

Scientific Investigations Map↗

Geologic map of MTM −15032 and −20032 quadrangles, western Ladon basin, Mars

Our mapping efforts focused on the geomorphic terrains and geologic units contained within Mars Transverse Mercator (MTM) −15032 and −20032 quadrangles. These two quadrangles are located along the west side of Ladon basin and span lat −12.5° N. to −22.5° N. and long 325° E. to 330° E. The western part of Ladon basin and its bounding basin ring structures to the west preserved features that help to understand the long history of drainage across the Margaritifer Terra region of Mars. Our geologic map provides new insight into the extent of aqueous activity across western Ladon basin and the adjoining highlands, which includes the northern part of Ladon Valles, Arda Valles, numerous small valleys in the western highlands, and light-toned layered deposits associated with these fluvial features. The Mars Odyssey Thermal Emission Imaging System (THEMIS) infrared (IR) daytime mosaic (100 meters per pixel) was used as the primary base map. We constructed the geologic map of western Ladon basin at 1:1,000,000 scale. We identified 20 geologic units in the map area, which we divided into the following groups: crater units; volcanic units; chaotic units; basin fill units; crater, valley, and channel units; and plateau and highlands units. We observed the following sequence of events: (1) formation of Ladon and Holden impact basins in the middle Noachian, producing a mountainous unit; (2) landscape degradation and infilling during the Late Noachian to Late Hesperian forming terra units; (3) formation of Ladon Valles in the Late Noachian to Early Hesperian by catastrophic flooding, producing channel units; (4) accumulation of sediments in the Late Noachian to Early Amazonian, forming basin fill units; (5) formation of a smooth crater fill unit during the Early to Late Hesperian; (6) deposition during the Late Hesperian to Early Amazonian, creating light-toned layered units within Ladon Valles, Ladon basin, and other smaller valley networks along the western uplands, as well as formation of a light-toned unit along some crater floors; (7) formation a of chaotic unit in the Early to Middle Amazonian, formation of alluvial fans in the Early Amazonian, and eruption of a volcanic unit in the Middle Amazonian; and (8) formation of craters throughout the geologic history of the map region.

Scientific Investigations Map↗

Changes in composition and porosity occurring during the thermal degradation of wood and wood components

Samples of pine and poplar wood, pine bark, and purified cellulose and lignin were charred at temperatures ranging from 250?C to 500?C for times ranging from 1 hour to 168 hours. Changes in composition were examined by Fourier Transform Infrared (FTIR) and 13C Nuclear Magnetic Resonance (NMR) spectrometry, mass loss, and elemental composition (carbon, hydrogen, and oxygen) of the char. Structural changes were examined by changes in porosity as measured by nitrogen gas adsorption. 13C NMR spectrometry, mass loss, and elemental composition were combined to estimate the mass of aromatic and aliphatic carbon remaining in the char. Mass loss and elemental composition were combined to estimate the chemical composition of material lost for various time intervals of heating. These analyses showed that aliphatic components in the test materials were either lost or converted to aromatic carbon early in the charring process. Nitrogen adsorption showed that no porosity develops for any of the test materials with heating at 250?C, even though substantial loss of material and changes in composition occurred. Porosity development coincided with the loss of aromatic carbon, indicating that micropores were developing within a fused-ring matrix.

Scientific Investigations Report↗

Use of chemical analysis and assays of semipermeable membrane devices extracts to assess the response of bioavailable organic pollutants in streams to urbanization in six metropolitan areas of the United States

Studies to assess the effects of urbanization on stream ecosystems are being conducted as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. The overall objectives of these studies are to (1) determine how hydrologic, geomorphic, water quality, habitat, and biological characteristics respond to land-use changes associated with urbanization in specific environmental settings, and (2) compare these responses across environmental settings. As part of an integrated assessment, semipermeable membrane devices (SPMDs) were deployed in streams along a gradient of urban land-use intensity in and around Atlanta, Georgia; Raleigh-Durham, North Carolina; and Denver-Fort Collins, Colorado, in 2003; and Dallas-Fort Worth, Texas; Milwaukee-Green Bay, Wisconsin; and Portland, Oregon, in 2004. Sites were selected to avoid point-source discharge and to minimize natural variability within each of the six metropolitan areas. In addition to standard chemical analysis for hydrophobic organic contaminants, three assays were used to address mixtures and potential toxicity: (1) Fluoroscan provides an estimate of the total concentration of polycyclic aromatic hydrocarbons (PAHs); (2) the P450RGS assay indicates the presence and levels of aryl hydrocarbon receptor agonists; and (3) Microtox® measures toxicological effects on photo-luminescent bacteria. Of the 140 compounds targeted or identified by gas chromatography/mass spectrometry analysis in this study, 67 were not detected. In terms of numbers and types of compounds, the following were detected: 2 wood preservatives, 6 insecticides (parent compounds), 5 herbicides, 22 polycyclic aromatic hydrocarbons, 2 dibenzofurans, 4 polychlorinated biphenyls, 7 compounds associated with fragrances or personal care products, 4 steroids associated with wastewater, 5 polydibromated diphenyl ethers (flame retardants), 3 plasticizers, 3 antimicrobials/disinfectants, and 3 detergent metabolites. Of the 73 compounds detected and three assays utilized, 29 were detected in 25 percent or more of the streams and were strongly related to increases in urban intensity (defined as having a Spearman’s rho > 0.5 with percent urban land cover) in at least one of the six metropolitan areas investigated. These 29 endpoints included 16 PAHs, a wood preservative (pentachloroanisole), 2 insecticides (chlorpyrifos and chlordane), 3 herbicides (benfluralin, trifluralin, and dacthal), a synthetic musk (hexahydrohexamethylcyclopentabenzopyran, HHCB), 2 furans (methyldibenzofuran and benzo[b]naphtho[2,3-d]furan), and a flame retardant (BDE 47). In addition, the number of compounds detected and results of the Fluoroscan and P450RGS assays were strongly related to urban intensity. Average water concentrations estimated from SPMDs were compared to screening benchmarks for the protection of human health and aquatic life; of the 14 compounds with available benchmarks, 3 compounds (anthracene, dieldrin, and diazinon) exceeded those levels in one or more streams. Both dieldrin and anthracene exceeded their respective benchmarks in seven streams, and diazinon in only one stream. There were more exceedances in Milwaukee-Green Bay and Raleigh-Durham than in the other metropolitan areas, and there were no exceedances in Dallas-Fort Worth. The six metropolitan areas studied differed in the number and types of endpoints related to urban intensity, probably from a combination of factors governing source strength, transport, and fate of hydrophobic compounds. The number of endpoints strongly related to urban intensity ranged from 3 in Dallas-Fort Worth and Portland to 21 in Raleigh-Durham. High frequencies of detection and strong correlations with urban land cover for pyrogenic PAHs (such as unsubstituted 4-ringed PAHs) in all six metropolitan areas indicate that these compounds are an important component of urbanization, regardless of location. Pentachloroanisole, dibenzofurans, and petrogenic PAHs (alkylated PAHs and heterocyclic dibenzothiophenes) were frequently detected and strongly related to urban intensity in Atlanta, Raleigh-Durham, Milwaukee-Green Bay, and Denver-Fort Collins. Two insecticides were related to urban intensity: chlorpyrifos in Atlanta, Raleigh-Durham, and Dallas-Fort Worth; and chlordane in Raleigh-Durham. Three herbicides were strongly related to urban intensity: trifluralin in Atlanta and Raleigh-Durham; benfluralin in Atlanta, and dacthal in Denver-Fort Collins. The detection frequencies for most wastewater indicator compounds were too low to establish relations with urban intensity. Of the wastewater compounds analyzed, HHCB in Raleigh-Durham and Denver-Fort Collins, and BDE 47 in Denver-Fort Collins and Dallas-Forth Worth, had the strongest relations with urban intensity. In addition to pyrogenic PAHs, levels of aryl hydrocarbon receptor agonists (as measured by the P450RGS assay) were strongly related to increasing urban intensity in all six metropolitan areas. PAHs were the only group of aryl hydrocarbon agonists consistently detected and related with urban intensity in all six metropolitan areas. It is unknown which compounds in the SPMDs caused the increased response in the P450RGS assay because the SPMDs likely contained many aryl hydrocarbon receptor agonists not quantified by chemical analysis. It is clear that bioavailable, aryl hydrocarbon receptor agonists increase in streams with increasing urban intensity in the basin. Potential toxicity mediated by this metabolic pathway should be considered in integrated assessments of the response of aquatic biota to urbanization.

Scientific Investigations Report↗

Numerical groundwater-flow model of the Minnelusa and Madison hydrogeologic units in the Rapid City area, South Dakota

The city of Rapid City and other water users in the Rapid City area obtain water supplies from the Minnelusa and Madison aquifers, which are contained in the Minnelusa and Madison hydrogeologic units. A numerical groundwater-flow model of the Minnelusa and Madison hydrogeologic units in the Rapid City area was developed to synthesize estimates of water-budget components and hydraulic properties, and to provide a tool to analyze the effect of additional stress on water-level altitudes within the aquifers and on discharge to springs. This report, prepared in cooperation with the city of Rapid City, documents a numerical groundwater-flow model of the Minnelusa and Madison hydrogeologic units for the 1,000-square-mile study area that includes Rapid City and the surrounding area. Water-table conditions generally exist in outcrop areas of the Minnelusa and Madison hydrogeologic units, which form generally concentric rings that surround the Precambrian core of the uplifted Black Hills. Confined conditions exist east of the water-table areas in the study area. The Minnelusa hydrogeologic unit is 375 to 800 feet (ft) thick in the study area with the more permeable upper part containing predominantly sandstone and the less permeable lower part containing more shale and limestone than the upper part. Shale units in the lower part generally impede flow between the Minnelusa hydrogeologic unit and the underlying Madison hydrogeologic unit; however, fracturing and weathering may result in hydraulic connections in some areas. The Madison hydrogeologic unit is composed of limestone and dolomite that is about 250 to 610 ft thick in the study area, and the upper part contains substantial secondary permeability from solution openings and fractures. Recharge to the Minnelusa and Madison hydrogeologic units is from streamflow loss where streams cross the outcrop and from infiltration of precipitation on the outcrops (areal recharge). MODFLOW-2000, a finite-difference groundwater-flow model, was used to simulate flow in the Minnelusa and Madison hydrogeologic units with five layers. Layer 1 represented the fractured sandstone layers in the upper 250 ft of the Minnelusa hydrogeologic unit, and layer 2 represented the lower part of the Minnelusa hydrogeologic unit. Layer 3 represented the upper 150 ft of the Madison hydrogeologic unit, and layer 4 represented the less permeable lower part. Layer 5 represented an approximation of the underlying Deadwood aquifer to simulate upward flow to the Madison hydrogeologic unit. The finite-difference grid, oriented 23 degrees counterclockwise, included 221 rows and 169 columns with a square cell size of 492.1 ft in the detailed study area that surrounded Rapid City. The northern and southern boundaries for layers 1-4 were represented as no-flow boundaries, and the boundary on the east was represented with head-dependent flow cells. Streamflow recharge was represented with specified-flow cells, and areal recharge to layers 1-4 was represented with a specified-flux boundary. Calibration of the model was accomplished by two simulations: (1) steady-state simulation of average conditions for water years 1988-97 and (2) transient simulations of water years 1988-97 divided into twenty 6-month stress periods. Flow-system components represented in the model include recharge, discharge, and hydraulic properties. The steady-state streamflow recharge rate was 42.2 cubic feet per second (ft3/s), and transient streamflow recharge rates ranged from 14.1 to 102.2 ft3/s. The steady-state areal recharge rate was 20.9 ft3/s, and transient areal recharge rates ranged from 1.1 to 98.4 ft3/s. The upward flow rate from the Deadwood aquifer to the Madison hydrogeologic unit was 6.3 ft3/s. Discharge included springflow, water use, flow to overlying units, and regional outflow. The estimated steady-state springflow of 32.8 ft3/s from seven springs was similar to the simulated springflow of 31.6 ft3/s, which included 20.5 ft3

South Dakota↗

Sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower intermediate confining unit and most of the Floridan aquifer system, Broward County, Florida

Deep well injection and disposal of treated wastewater into the highly transmissive saline Boulder Zone in the lower part of the Floridan aquifer system began in 1971. The zone of injection is a highly transmissive hydrogeologic unit, the Boulder Zone, in the lower part of the Floridan aquifer system. Since the 1990s, however, treated wastewater injection into the Boulder Zone in southeastern Florida has been detected at three treated wastewater injection utilities in the brackish upper part of the Floridan aquifer system designated for potential use as drinking water. At a time when usage of the Boulder Zone for treated wastewater disposal is increasing and the utilization of the upper part of the Floridan aquifer system for drinking water is intensifying, there is an urgency to understand the nature of cross-formational fluid flow and identify possible fluid pathways from the lower to upper zones of the Floridan aquifer system. To better understand the hydrogeologic controls on groundwater movement through the Floridan aquifer system in southeastern Florida, the U.S. Geological Survey and the Broward County Environmental Planning and Community Resilience Division conducted a 3.5-year cooperative study from July 2012 to December 2015. The study characterizes the sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower part of the intermediate confining unit aquifer and most of the Floridan aquifer system. Data obtained to meet the study objective include 80 miles of high-resolution, two-dimensional (2D), seismic-reflection profiles acquired from canals in eastern Broward County. These profiles have been used to characterize the sequence stratigraphy, seismic stratigraphy, and seismic structures in a 425-square-mile study area. Horizon mapping of the seismic-reflection profiles and additional data collection from well logs and cores or cuttings from 44 wells were focused on construction of three-dimensional (3D) visualizations of eight sequence stratigraphic cycles that compose the Eocene to Miocene Oldsmar, Avon Park, and Arcadia Formations. The mapping of these seismic-reflection and well data has produced a refined Cenozoic sequence stratigraphic, seismic stratigraphic, and hydrogeologic framework of southeastern Florida. The upward transition from the Oldsmar Formation to the Avon Park Formation and the Arcadia Formation embodies the evolution from (1) a tropical to subtropical, shallow-marine, carbonate platform, represented by the Oldsmar and Avon Park Formations, to (2) a broad, temperate, mixed carbonate-siliciclastic shallow marine shelf, represented by the lower part of the Arcadia Formation, and to (3) a temperate, distally steepened carbonate ramp represented by the upper part of the Arcadia Formation. In the study area, the depositional sequences and seismic sequences have a direct correlation with hydrogeologic units. The approximate upper boundary of four principal permeable units of the Floridan aquifer system (Upper Floridan aquifer, Avon Park permeable zone, uppermost major permeable zone of the Lower Floridan aquifer, and Boulder Zone) have sequence stratigraphic and seismic-reflection signatures that were identified on cross sections, mapped, or both, and therefore the sequence stratigraphy and seismic stratigraphy were used to guide the development of a refined spatial representation of these hydrogeologic units. In all cases, the permeability of the four permeable units is related to stratiform megaporosity generated by ancient dissolution of carbonate rock associated with subaerial exposure and unconformities at the upper surfaces of carbonate depositional cycles of several hierarchical scales ranging from high-frequency cycles to depositional sequences. Additionally, interparticle porosity also contributes substantially to the stratiform permeability in much of the Upper Floridan aquifer. Information from seismic stratigraphy allowed 3D geomodeling of hydrogeologic units—an approach never before applied to this area. Notably, the 3D geomodeling provided 3D visualizations and geocellular models of the depositional sequences, hydrostratigraphy, and structural features. The geocellular data could be used to update the hydrogeologic structure inherent to groundwater flow simulations that are designed to address the sustainability of the water resources of the Floridan aquifer system. Two kinds of pathways that could enable upward cross-formational flow of injected treated wastewater from the Boulder Zone have been identified in the 80 miles of high-resolution seismic data collected for this study: a near-vertical reverse fault and karst collapse structures. The single reverse fault, inferred to be of tectonic origin, is in extreme northeastern Broward County and has an offset of about 19 feet at the level of the Arcadia Formation. Most of the 17 karst collapse structures identified manifest as columniform, vertically stacked sagging seismic reflections that span early Eocene to Miocene age rocks equivalent to much of the Floridan aquifer system and the lower part of the overlying intermediate confining unit. In some cases, the seismic-sag structures extend upward into strata of Pliocene age. The seismic-sag structures are interpreted to have a semicircular shape in plan view on the basis of comparison to (1) other seismic-sag structures in southeastern Florida mapped with two 2D seismic cross lines or 3D data, (2) comparison to these structures located in other carbonate provinces, and (3) plausible extensional ring faults detected with multi-attribute analysis. The seismic-sag structures in the study area have heights as great as 2,500 vertical feet, though importantly, one spans about 7,800 feet. Both multi-attribute analysis and visual detection of offset of seismic reflections within the seismic-sag structures indicate faults and fractures are associated with many of the structures. Multi-attribute analysis highlighting chimney fluid pathways also indicates that the seismic-sag structures have a high probability for potential vertical cross-formational fluid flow along the faulted and fractured structures. A collapse of the seismic-sag structures within a deep burial setting evokes an origin related to hypogenic karst processes by ascending flow of subsurface fluids. In addition, paleo-epigenic karst related to major regional subaerial unconformities within the Florida Platform generated collapse structures (paleo-sinkholes) that are much smaller in scale than the cross-formational seismic-sag structures.

Florida↗

Flood-frequency estimation for very low annual exceedance probabilities using historical, paleoflood, and regional information with consideration of nonstationarity

Streamflow estimates for floods with an annual exceedance probability of 0.001 or lower are needed to accurately portray risks to critical infrastructure, such as nuclear powerplants and large dams. However, extrapolating flood-frequency curves developed from at-site systematic streamflow records to very low annual exceedance probabilities (less than 0.001) results in large uncertainties in the streamflow estimates. Traditionally, methods for statistically estimating flood frequency have relied on the systematic streamflow record, which provides a time series of annual maximum flood peaks, often including some historical peaks. However, most peak-flow records are less than 100 years, and uncertainties are large when trying to extrapolate magnitudes of very low annual exceedance probability events. Other data may be available that extend the record beyond the systematic dataset. Historical data are defined as data from outside the period of systematic records but within the period of human records. Examples of historical information include flood estimates from other agencies and newspaper accounts that can be translated to flood magnitude point estimates, interval estimates, or perception thresholds (such as a statement that an 1880 flood was the largest since 1869). Paleoflood data, which may also extend the dataset, include a broad range of information about flood occurrence or magnitude from sources like sediment deposits or tree rings. Several assumptions are made in flood-frequency analysis, and an understanding of whether the data conform to these assumptions is desired. A particularly difficult assumption to evaluate for flood-frequency analysis is the underlying assumption that the flood series is stationary—the assumption that a time series of peak flow varies around a constant mean within a particular range of values (constant variance). As the hydrologic community’s understanding of natural systems and anthropogenic effects on streamflows has evolved, the community has come to understand that many surface-water systems exhibit one or more forms of nonstationarity, and thus the stationarity assumption is often violated to some degree. However, there is currently (2020) no consensus among hydrologists regarding the most appropriate flood-frequency-analysis methods for nonstationary systems, and this topic remains an active area of research. A literature review was completed to summarize the state of the science of flood frequency. The literature review highlights tools available to detect nonstationarities and identifies approaches that include external information to inform flood-frequency analysis. To demonstrate methods for initial data analysis and for incorporating historical and paleoflood information in flood-frequency analysis, five sites were selected: the Red River of the North at James Avenue Pumping Station, Winnipeg, Manitoba, Canada; lower reach, Rapid Creek, South Dakota; Spring Creek, South Dakota; Cherry Creek near Melvin, Colorado; and Escalante River near Escalante, Utah. The sites were chosen for the availability of published historical and paleoflood data and for their geographic diversity and unique characteristics, which highlighted issues such as autocorrelation, change points, trends, outlier peaks, or short periods of record. An initial data analysis that involved examining records for autocorrelation, change points, and trends was completed for all sites. The flood-frequency analysis completed for this study used version 7.2 of the U.S. Geological Survey PeakFQ program. Multiple analyses were done on each site documenting the change in the flood-frequency curve when additional historical or paleoflood data were added. When other flood-frequency studies were available, their results were compared to the results here. The comparisons in some cases simply show the effect of additional years of data, whereas other comparisons show results from probability distributions or fitting methods other than those used in PeakFQ. For the Red River of the North, flood-frequency analysis shows that paleoflood data appear necessary to reasonably estimate very low annual exceedance probabilities. For the analysis of the lower reach of Rapid Creek and Spring Creek, paleoflood information helped put a high outlier from the systematic period in context; however, very low annual exceedance probabilities at these sites still had extraordinarily large confidence bounds. These sites also showed that paleoflood information might be transferred from one site to another, with the caveat that this is a case where we had existing paleoflood data to test the transfer of paleoflood information—this is not the case at many sites, and transferring paleoflood information requires assumptions about the comparability of floods at the sites. The Cherry Creek analysis affirmed the result of an earlier study that showed that the generalized Pareto distribution was not a good distribution for estimating very low annual exceedance probabilities. The Escalante River analysis showed that adding paleoflood information might increase uncertainty for very low annual exceedance probabilities, compared to analysis with the systematic period of record information only, when the paleoflood peaks are of much larger magnitudes than the systematic record.

Scientific Investigations Report↗

Machine for preparing phosphors for the fluorimetric determination of uranium

The time saved by use of a machine for preparing many phosphors at one time increases the rate of productivity of the fluorimetric method for determining uranium. The machine prepares 18 phosphors at a time and eliminates the tedious and time-consuming step of preparing them by hand, while improving the precision of the method in some localities. The machine consists of a ring burner over which the platinum dishes, containing uranium and flux, are rotated. By placing the machine in an inclined position the molten flux comes into contact with all surfaces within th dish as the dishes rotate over the flame. Precision is improved because the heating and cooling conditions are the same for each of the 18 phosphors in one run as well as for successive runs.

Trace Elements Investigations↗

External quality-assurance results for the National Atmospheric Deposition Program/National Trends Network, 1997-99

Five external quality-assurance programs were operated by the U.S. Geological Survey for the National Atmospheric Deposition Program/ National Trends Network (NADP/NTN) during 1997 through 1999: the intersite-comparison program, the blind-audit program, the field- audit program, the interlaboratory-comparison program, and the collocated-sampler program. The intersite-comparison program assesses the accuracy of pH and specific-conductance determinations made by NADP/NTN site operators. In two 1997 intersite-comparison studies, 83.7 and 85.8 percent of the pH determinations met the NADP/NTN accuracy goals, whereas 97.3 and 92.4 percent of the specific-conductance determinations met the NADP/NTN accuracy goals. The percentage of pH and specific-conductance determinations that met the accuracy goals in 1998 were, for the most part, higher than in 1997. In two 1998 studies, 90.9 and 90.3 percent of the pH determinations met the accuracy goals compared to 94.7 and 96.0 percent of the specific- conductance measurements meeting the accuracy goals. In one 1999 intersite-comparison study, 89.5 percent and 99.4 percent of pH and specific- conductance determinations, respectively, met the NADP/NTN accuracy goals. The blind-audit program evaluates the effects of routine sample handling, processing, and shipping on the analytical bias and precision of weekly precipitation samples. A portion of the blind-audit sample subject to the normal onsite handling and processing of a weekly precipitation sample is referred to as the bucket portion, whereas the portion receiving only minimal handling is referred to as the bottle portion. Positive bias in regard to blind-audit results indicates that the bucket portion has a higher concentration than the bottle portion. The paired t-test for the 1997 through 1999 blind- audit data indicates that routine sample handling, processing, and shipping introduced a positive bias (a=0.05) for calcium and chloride and a negative bias (cz=0.05) for hydrogen ion. During 1997 through 1999, the median paired differences between the bucket and bottle portions ranged from 0.00 milligram per liter for nitrate and ammonium to +0.010 milligram per liter for both chloride and sulfate. The median paired difference between the bucket and bottle portions for hydrogen ion was -1.086 microequivalents per liter, whereas for specific conductance, the median paired difference between the bucket and bottle portions was -0.200 microsiemen per centimeter during 1997 through 1999. Surface-chemistry effects due to variable amounts of precipitation contacting prewashed sample-collection and shipping-container surfaces were studied in the blind-audit program by using three different sample volumes. The sample- collection and shipping containers used for the blind-audit study were obtained from the site operator's supply and could have been used for precipitation samples. Results of a Kruskal-Wallis analysis of variance test of the relation between paired blind-audit sample differences in units of concentration and sample volume were statistically significant for magnesium, chloride, sulfate, and hydrogen ion during 1997 through 1999. Before 1994, at least 5 of the 10 analytes displayed a statistically significant difference between paired blind-audit differences in units of concentration and sample volume, supporting the premise that chemical reactions between the 13-liter bucket shipping container (primarily the butadiene o-ring lid of the shipping container) and the sample, which resulted in an increasing loss of hydrogen ion with increasing volume, have been eliminated by the new l-liter bottle sample- shipping protocol. The field-audit program measures the effects of field exposure, handling, and processing on the chemistry of NADP/NTN precipitation samples. In the field-audit program, the site operator is instructed to process and submit a quality- control sample following a standard 7-day, Tuesday-to-Tuesday sampling period with no

Water-Resources Investigations Report↗

Investigation of artificial recharge of aquifers in Nebraska

Large withdrawals of ground water for irrigation are causing progressive declines of ground-water levels in some areas of Nebraska. An investigation was conducted to determine the technical feasibility of artificially recharging aquifers through wells and through surface spreading by means of impoundments, pits, and canals. Information gained from a literature search and from preliminary tests was used to design several artificial-recharge experiments. The experiments showed that large quantities of water can be recharged through wells and by surface spreading if conditions are favorable. In the well experiments, about 0.5 billion gallons of water from an aquifer recharged by the Platte River was transported 3 miles by pipeline and recharged through a well into a Pleistocene sand and gravel aquifer near Aurora where ground-water levels are declining. The recharge rate was about 730 gallons per minute during two tests of 6 and 8 months duration. The rise in ground-water levels due to recharge extended more than a mile from the recharge well in both tests. The pattern of ground-water-level buildup during the 8-month test was similar to that during the 6-month test. Two-thirds of the way through the test the rate of water-level buildup in the recharge well increased greatly because casing failure allowed a large amount of sediment to enter the well. Although the chemical quality of the recharge water was markedly different from that of the native aquifer water, no evidence of clogging due to chemical reaction was detected; also, there was no evidence of clogging due to air entrainment or bacterial growth. Evaluation of water-level changes in the recharge well and in observation wells during the 6-month test indicated some clogging of the aquifer in the immediate vicinity of the recharge well due to a small amount (0.04 milligram per liter) of fine sediment in the recharge water. Analysis of water-level buildup in the recharge well during the 6-month test indicated that recharge could have continued at a rate of about 700 gallons per minute for several years before rehabilitation of the recharge well would have been necessary. In surface-spreading experiments, the maximum sustained infiltration rates from a 24-foot-diameter ring infiltrometer set in loess at the well-recharge site near Aurora were about 0.5 foot per day during a 140day test. The recharge water caused water levels in a perched zone of saturation at depths between 36 and 38 feet to rise 15 feet, to within 21 feet of the surface, indicating that if the test had continued or if the impoundment area had been larger, the water level in the perched zone of saturation might have risen to the surface thereby reducing the infiltration rate. The maximum sustained infiltration rate from a similar experiment in the Sand Hills near Tryon was 11 feet per day. Perching layers also retarded downward infiltration and caused lateral movement of water in the subsurface at this site. Infiltration rates from re-use pits near the Aurora site ranged from 0.01 to 1.60 feet per day, indicating that the permeability of the subsurface material is extremely variable and that perching layers probably are absent in some areas. Flow measurements in an irrigation canal excavated in loess near Farwell indicate an infiltration rate of 0.36 foot per day from a 2.7mile reach.

Nebraska↗

Restoration of freshwater in the Cano Tiburones area, Puerto Rico

Cano Tiburones on the north coast of Puerto Rico originally was a shallow, coastal lagoon, 9 square miles in area. It accumulated freshwater from adjacent rivers and springs and drained to the ocean through unobserved subterranean conduits. Forced drainage by pumping of Cano Tiburones for agriculture was begun in 1949, and resulted in lowering the water level to below sea level. The reversed hydraulic gradient permitted seawater to enter the Cano through the conduits forming seawater "springs". Seawater flooding caused widespread sodium chloride contamination in the canals and laterals and in the soils. Agricultural expectations of the area were not realized. The present investigation into the freshening potential of Cano Tiburones (1979-1982) determined that ground-water discharge does not contribute to salty conditions. On-site experiments were performed to segregate freshwater from seawater using differences in hydraulic head. Dams were constructed on canals and laterals, forcing accumulated saltwater to the ocean. Ring levees were placed around the discharging seawater conduits until sea level was reached and flow to the system stopped. These efforts have succeeded in reducing the amount of seawater in Cano Tiburones to one-third of its original concentration. Most of the water presently in Cano Tiburones is suitable for irrigation.

Cano Tiburones↗