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Forecasting water levels using the ConvLSTM algorithm in the Everglades, USA

Forecasting water levels in complex ecosystems like wetlands can support effective water resource management, ecological conservation, and understanding surface and groundwater hydrology. Predictive models can be used to simulate the complex interactions among natural processes, hydrometeorological factors, and human activities. The Greater Everglades in the USA is a well-known example of an ecosystem where complexity has motivated adoption of machine learning algorithms in water level prediction studies. This paper aims to contribute to extending existing machine learning algorithms by integrating spatiotemporal data with deep-learning algorithms in the forecasting process. In this study, a deep-learning model is developed to predict water levels on a regional scale, covering a large area of approximately 9,138 square kilometers in the Everglades ecosystem. This model has the architecture of Convolutional Long Short-Term Memory which can deal with spatiotemporal data by capturing both spatial and temporal dependencies in the training data. The forecasting capabilities of this model (referred to as the global model) are assessed by comparing the global model to two Artificial Neural Networks developed at two different gaging stations, referred to here as local models. One local model is developed at a gaging station directly influenced by nearby water control structures, whereas the other is developed at a gaging station located farther away from these structures. By leveraging data from the Everglades Depth Estimation Network spanning from January 2002 to May 2023, the global and local models were trained to forecast water levels with a two-day lead time. Our findings suggest that both the global and local models perform with approximately the same level of accuracy, with Mean Absolute Relative Error values ranging from 0.38% to 1.4% at the selected stations. The developed global model has demonstrated strong potential as a standalone forecasting tool for the entire study area in the Everglades and could eliminate the need for developing multiple local models. This finding also highlights how machine learning can capture complex spatial and temporal relationships to generate accurate water level predictions on a regional scale.

Florida

3D viscoelastic models of slip-deficit rate along the Cascadia subduction zone

Interseismic deformation in the Pacific Northwest is constrained by the horizontal crustal velocity field derived from the Global Positioning System (GPS) in addition to vertical rates derived from GPS, leveling, and tide gauge measurements. Such measurements were folded in to deformation models of fault slip rates as part of the 2023 National Seismic Hazard Model (NSHM) update. Here I build upon one of the contributing models, the viscoelastic earthquake-cycle model of Pollitz [2022]. This model permits inclusion of effects of time-dependent viscoelastic relaxation within earthquake cycles (i.e., ‘ghost transients’) and laterally variable elastic and/or ductile material properties. I lever-age these capabilities to incorporate the Cascadia megathrust into Western U.S.-wide deformation models in which crustal fault slip rates are estimated simultaneously with slip deficit rates along the interplate boundary between the descending Juan de Fuca plate and North American plate. This effort includes construction of a margin-wide model of viscoelastic structure founded on the Slab 2.0 model and probes different models of the ductile properties of the surrounding oceanic asthenosphere, continental lower crust, and mantle asthenosphere. This results in new estimates of the distribution of slip deficit rate along the ∼ 1000 km long margin, highlights the importance of correcting for glacial-isostatic adjustment effects, and permits assessment of sensitivity of results to assumed ductile properties.

California, Oregon, Washington

Technique for estimating magnitude and frequency of peak flows in Maryland

A convenient and reliable technique for estimating flood magnitudes is required for effective flood-plain management and for the efficient design of bridges, culverts, embankments, and flood-protection structures. Methods are presented for estimating peak-flow magnitudes of selected frequencies, ranging from 2 to 500 years, for all nontidal drainage basins in Maryland. The methods were developed by generalized least-squares regression techniques using data from 219 gaged basins in and near Maryland. The State is divided into five hydrologic regions: the Appalachian Plateaus and Allegheny Ridges region, the Blue Ridge and Great Valley region, the Piedmont region, the Western Coastal Plain region, and the Eastern Coastal Plain region. These regions correspond to the physiographic provinces of the State, with the exceptions that (1) the Coastal Plain Province is divided into two hydrologic regions, and (2) there is no distinct hydrologic region corresponding to the Valley and Ridge Province as it is divided into its constituent Allegheny Ridges and Great Valley subdivisions. Sets of equations for calculating peak discharges based on physical basin characteristics are provided for each of the regions. Based on the peak-flow equations, methods for estimating peak flows are presented for ungaged and gaged streams in Maryland. The methods and equations are supported by generalized least-squares analysis of basin and flood-frequency characteristics data from 219 drainage basins in and near Maryland. estimates for each of the five regions are calculated using combinations of the fol-lowing basin characteristics: drainage area, forest cover, basin relief, carbonate rock coverage, storage, and runoff-curve number. Drainage area contributes to the estimate in all five study regions. Carbonate rock coverage is used only in the Blue Ridge and Great Valley region. Storage and runoff-curve number are used solely in the Eastern Coastal Plain region. All other basin characteristics are used in two or more regions. Standard errors of estimate for the regression equations range from 19 to 31 percent in the Appalachian Plateaus and Allegheny Ridges region, 34 to 47 percent in the Blue Ridge and Great Valley region, 33 to 48 percent in the Piedmont region, 45 to 64 percent in the Western Coastal Plain region, and 36 to 42 percent in the Eastern Coastal Plain region.

Maryland

Waters divided: A history of alluvial fan research and a view of its future

Flows exiting confined valleys tend to deposit sediment in fan-shaped landforms. Where deposition is wholly or largely by the tractive forces of flowing water, these landforms are called alluvial fans. They are the product of the progressive division of water and sediment downfan, from slopes that may exceed 0.10 to distal slopes that may be below 0.01. Channel depths also tend to decline, from values that approach one to several meters at steep fanheads, to a few decimeters at distal fan margins. The result is a radiating, depositional ramp where confined or unconfined flows transport sediment from source basins to bounding streams, subsiding basins, or stable platforms. Where streams or subsiding basins consume the sediment supply from the source basin, the fan may approach a steady form whose extent and distal slope are set by stream location or subsidence rate. Where boundary conditions do not remove sediment, the fan may prograde out to long distances and low slopes (<0.01). Theoretical and experimental work over the past several decades support the notion that alluvial fan long-profiles become steeper as sediment supply increases or transport capacity decreases, and increasingly concave upward as the rate of bed material deposition decreases downfan. Grainsize distributions of alluvial fans seem to span the range observed in alluvial rivers, with no processes that uniquely identify them, apart from the distributary pattern of deposition. Bed sand cover tends to increase downfan in arid-region fans, with an absence of systematic downfan fining of coarser grain sizes. Surficial mapping and geochronology have demonstrated that fan deposition varies greatly through time, arguably from climate variations that alter hillslope sediment supply. The combination of surficial mapping and hydraulic modeling with high-resolution topography can now produce detailed flood susceptibility maps. The effective use of these maps to protect lives and property, however, depends on answering many of the enduring questions about the mechanics of how water and sediment divide down alluvial fans.

Book chapter

Flood-inundation maps for the Cuyahoga River at Jaite, Ohio, 2024

Digital flood-inundation maps for a nearly 6-mile reach of the Cuyahoga River at Jaite, Ohio, were created by the U.S. Geological Survey (USGS) in cooperation with the Northeast Ohio Regional Sewer District Board of Trustees. The maps depict estimates of the extent and depth of flooding corresponding to selected water levels (stages) at USGS streamgage 04206425 on the Cuyahoga River at Jaite, Ohio. Water-surface profiles were computed for the stream reach by using a one-dimensional steady-state step-backwater model. The hydraulic model was calibrated to the current USGS streamgage data and then used to compute 15 water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum and ranging from 6 to 20 feet, which correspond to below “action stage” to “major flood stage” as reported by the National Weather Service. The simulated water-surface profiles were then used with a geographic information system digital elevation model derived from light detection and ranging data to delineate the areas flooded at each stage. These maps, along with current stage data from the USGS streamgage and forecasted high-flow stages from the National Weather Service, can provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Ohio

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California

Niobium-rich minerals from the Sheep Creek carbonatite-related deposits, Montana, USA

The Sheep Creek area in southwest Montana contains a number of small, tabular, carbonatite-related deposits that are rich in Nb- and REE-minerals. Two of the “vein-dikes” were mined at a small scale for Nb in the late 1950s. The most abundant Nb-bearing minerals are columbite-(Fe), nioboaeschynite-(Ce), baotite, and two varieties of Ti-Nb-Fe-oxide. An early oxide with Ti/Nb (atomic) near unity later broke down to a mixture of columbite + TiO2 with distinctly lower Nb content. Zircon intergrown with the Nb-REE minerals was dated by U-Pb methods to 116±2 Ma. This age is in agreement with previous dating (Th-Pb on monazite, Re-Os on molybdenite), and indicates that the Sheep Creek deposits are early Cretaceous in age.

Montana

Projections of multiple climate-related coastal hazards for the US Southeast Atlantic

Faced with accelerating sea level rise and changing ocean storm conditions, coastal communities require comprehensive assessments of climate-driven hazard impacts to inform adaptation measures. Previous studies have focused on flooding but rarely on other climate-related coastal hazards, such as subsidence, beach erosion and groundwater. Here, we project societal exposure to multiple hazards along the Southeast Atlantic coast of the United States. Assuming 1 m of sea level rise, more than 70% of the coastal residents and US \ $ 1 trillion in property are in areas projected to experience shallow and emerging groundwater, 15 times higher than daily flooding. Storms increase flooding exposure by an order of magnitude over daily flooding, which could impact up to ~50% of all coastal residents and US \ $ 770 billion in property value. The loss of up to ~80% of present-day beaches and high subsidence rates that currently affect over 1 million residents will exacerbate flooding and groundwater hazard risks.

Florida, Georgia, North Carolina, South Carolina,

Debris-flow entrainment modelling under climate change: Considering antecedent moisture conditions along the flow path

Debris-flow volumes can increase along their flow path by entraining sediment stored in the channel bed and banks, thus also increasing hazard potential. Theoretical considerations, laboratory experiments and field investigations all indicate that the saturation conditions of the sediment along the flow path can greatly influence the amount of sediment entrained. However, this process is usually not considered for practical applications. This study aims to close this gap by combining runout and hydrological models into a predictive framework that is calibrated and tested using unique observations of sediment erosion and debris-flow properties available at a Swiss debris-flow observation station (Illgraben). To this end, hourly water input to the erodible channel is predicted using a simple, process-based hydrological model, and the resulting water saturation level in the upper sediment layer of the channel is modelled based on a Hortonian infiltration concept. Debris-flow entrainment is then predicted using the RAMMS debris-flow runout model. We find a strong correlation between the modelled saturation level of the sediment on the flow path and the channel-bed erodibility for single-surge debris-flow events with distinct fronts, indicating that the modelled water content is a good predictor for erosion simulated in RAMMS. Debris-flow properties with more complex flow behaviour (e.g., multiple surges or roll waves) are not as well predicted using this procedure, indicating that more physically complete models are necessary. Finally, we demonstrate how this modelling framework can be used for climate change impact assessment and show that earlier snowmelt may shift the peak of the debris-flow season to earlier in the year. Our novel modelling framework provides a plausible approach to reproduce saturation-dependent entrainment and thus better constrain event volumes for current and future hazard assessment.

Illgraben basin

Assessment of fresh groundwater discharge and saline surface-water intrusion at Operable Unit 2, North Chevalier Field Disposal Area (Site 11), Naval Air Station Pensacola, Florida, 2018–22

Site 11 is a former landfill at North Chevalier Field Disposal Area in Operable Unit 2 at Naval Air Station Pensacola, in northwest Florida. Site 11 is adjacent to Bayou Grande, a shallow, tidally influenced, saline estuary of the Pensacola Bay watershed. Federal and Florida regulators have expressed concern that contaminants detected in groundwater beneath the inland parts of Site 11 may discharge to Bayou Grande. In 2017, the Department of Defense, U.S. Navy, Naval Facilities Engineering Systems Command Southeast asked the U.S. Geological Survey to assess the occurrence of fresh groundwater discharge to Bayou Grande at Site 11 and to delineate to the extent practicable the location of groundwater discharge. Between 2018 and 2022, the U.S. Geological Survey used a multiple-lines-of-evidence approach that included a visual method and three physical methods based on the temperature difference between groundwater and surface water to assess groundwater discharge. One of the physically based methods also used the difference in specific conductance between fresh groundwater and brackish to saline surface water. Combined, the data indicate that fresh groundwater from across Site 11 discharges primarily along the shoreline of the northern and northeastern part of Site 11. The data also indicate that saline surface water from Bayou Grande intrudes tens of feet into the shallow aquifer beneath Site 11. The combined data indicate that the interface between fresh groundwater and saline surface water changes over space and time. Any new monitoring wells proposed for installation near the shoreline of Site 11 should include approaches to monitor the changes in the location of the freshwater/saltwater interface. Care would need to be taken to collect any groundwater samples at the correct season and tidal period to provide the highest probability of collecting a representative sample of Site 11 groundwater unaffected by saltwater.

Florida

Age and colony variation in Adélie penguin metapopulation vital rates: Insights from a 25-year mark–recapture study

Understanding how vital rates vary with age, life-history stage, and among populations is fundamental for predicting the demographic consequences of environmental change, especially in longer-lived species with complex life histories. These species often exhibit delayed maturity and iteroparity, making nuanced demographic insights critical for assessing their long-term viability. This study investigated age- and colony-related variation in Adélie penguin vital rates including survival, recruitment, and breeding propensity. We used mark–recapture data collected over 25 years (1996–2020) from three Adélie penguin breeding colonies that differed in population sizes and trends but comprised a metapopulation located at capes Royds, Bird, and Crozier on Ross Island, Antarctica. We used multi-state models to estimate survival and detection rates relative to reproductive state and breeding colony and estimated transition probabilities reflecting movements between reproductive states and colonies. Apparent survival varied by reproductive state, colony, and age and averaged 0.80 (SD = 0.02) at Bird, and 0.72 (SD = 0.03) and 0.73 (SD = 0.03) at Crozier and Royds, respectively, for pre-breeders age 2–7 years with strong declines in pre-breeder survival after age 8. We observed less age-related variation in survival of breeders and non-breeders, but we observed differences between colonies with lower survival for breeders (0.72 to 0.80) compared to non-breeders (0.75 to 0.82). The average probability of surviving the first 2 years after fledging ranged from 0.43 (SD = 0.14) at Royds and Crozier (0.43, SD = 0.10) to 0.55 (SD = 0.15) at Bird. Movement between colonies was highest for pre-breeders (0.00%–12.00% depending on age and colony) and lowest for breeders (<0.20%). We observed the lowest age-related recruitment rates at Royds, with recruitment at Crozier almost twice as high, and intermediate at Bird. Breeding propensity was highest at Crozier and lowest at Bird. Colony-specific variation in vital rates likely contributed differently to population trajectories, suggesting that care must be taken to extrapolate vital rate estimates across colonies even within a metapopulation. These findings also highlight the importance of considering age, life-history stage, and geographic variation when assessing population vital rates in species with complex life histories.

Frontiers in Ecology and Environment

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri River between Kansas City and St. Louis, Missouri, May 19–26, 2021

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near nine bridges at eight highway crossings of the Missouri River between Kansas City and St. Louis, Missouri, from May 19 to 26, 2021. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 to 1,840 feet (ft) longitudinally and generally extending laterally across the active channel from bank to bank during low to moderate flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a low to moderate flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All the bridge sites in this study were previously surveyed and documented in previous studies. Comparisons between bathymetric surfaces from the previous surveys and those of the current (2021) study do not indicate any consistent correlation between channel-bed elevations and streamflow conditions. The average difference between the bathymetric surfaces varied from 1.59 ft higher to 0.95 ft lower in 2021 than 2017, which corresponds to a gain of 100,200 cubic yards and a loss of 55,800 cubic yards, respectively. The average difference between the bathymetric surfaces varied from 2.74 ft higher to 3.05 ft lower in 2021 than 2013, which corresponds to a gain of 111,500 cubic yards and a loss of 169,200 cubic yards, respectively. The average difference between the bathymetric surfaces varied from 4.52 ft higher to 1.38 ft lower in 2021 than 2011, which corresponds to a gain of 221,100 cubic yards and a loss of 90,300 cubic yards, respectively. The most substantial overall net gain was 221,100 cubic yards between 2011 and 2021 at structures L0550 and A4497 at Jefferson City (site 20). The large net gain likely results from a combination of the mitigation of the scour holes near pier 4 of both bridges and the substantially lower flow in 2021 than in 2011. Alternatively, the most substantial overall net loss was 169,200 cubic yards between 2013 and 2021 at structure A6288 at Hermann (site 21), despite comparable streamflows. Pier size, nose shape, and skew to approach flow had a substantial effect on the size of the scour hole observed at a given pier. Larger and deeper scour holes were present at piers with wide or blunt noses caused by exposed footings or caissons. When a pier was skewed to primary approach flow, the scour hole was generally deeper and larger than at a similar pier without skew; furthermore, the shape of the scour hole near skewed piers in this study generally was longer and deeper on the side with impinging flow. At structure A6288 at Hermann (site 21), the scour hole near pier 5 was difficult to discern from nearby dunes and ripples, whereas the upstream edge of the footing was visible at pier 4, which likely contributes to the larger scour hole near that pier; the top of the footing may blunt the horseshoe vortex at pier 5, but the exposed front of the footing may exacerbate the vortex at pier 4.

Missouri

A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States

Throughout the history of oil and gas production in the United States, millions of wells have been drilled for exploration and energy production. Hundreds of thousands of unplugged wells are no longer actively producing and are currently under orphan status, with no responsible party obligated for plugging. Orphan wells can pose threats to water resources by providing pathways for contaminants such as hydrocarbons and brines to migrate into water-supply aquifers. In this study, we investigate the potential threats to groundwater resources posed by orphan wells at the national scale. Water-quality data is extremely sparse in relation to orphan wells nationally and may not be suitable for identifying contamination from oil and gas development. We used geospatial and statistical methods to evaluate which principal and secondary aquifer systems may be most susceptible to contamination from orphan wells. Analysis involved three sets of susceptibility factors including: 1) factors related to the number and density of orphan wells; 2) factors that can threaten well integrity and contribute to transport of contaminants; and 3) factors related to groundwater withdrawal rates and the affected populations/communities in the event of water quality disturbances. From a dataset of 117,672 documented orphan wells, 64,203 fall within a principal aquifer system, while the remainder fall within a secondary aquifer system. By assessing the combination of well integrity and hydrogeologic factors within these aquifer systems, five groupings of principal aquifers were identified, where groups ranged from aquifer systems with high numbers of orphan wells, multiple well integrity threats and high withdrawals, to aquifers with a relatively low number of orphan wells, limited well integrity threats and minimal water use. Three regions of the country emerge containing aquifers with higher susceptibility to contamination from orphan oil and gas wells. These regions include 1) The Appalachian Basin (including the Pennsylvanian Aquifer System), 2) The Gulf Coast Aquifers (including the Coastal Lowlands Aquifer system) and 3) The California Aquifers (including the California Coastal Basin Aquifer system). This work is the first multivariate geospatial investigation of orphan wells and groundwater resources on a national scale, and sheds light on which aquifers are most susceptible to groundwater contamination from orphan wells.

Science of the Total Environment

Water table rise sustains carbon release from soils in wetland-dominated landscapes: An intact soil core study

Wetland-dominated landscapes influence carbon cycling through their potential to act as both carbon sinks and sources. Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces that change seasonally with variable surface water and groundwater levels. However, few studies have directly quantified dissolved organic matter (DOM) release and greenhouse gas (CO 2 , CH 4 ) fluxes from wetland soils along terrestrial-aquatic interfaces as they are seasonally re-saturated by groundwater. To estimate groundwater-mediated soil DOM and gas fluxes, we performed laboratory simulations of vertical groundwater rise on intact soil cores collected from four Delmarva bay wetlands located in the Mid-Atlantic United States. At each wetland, one core was collected from within the wetland basin and the other from the transitional zone at the basin edge. Cores were re-saturated with groundwater over 15 days and then kept fully saturated for an additional 25 days. Source groundwater, soil porewater, and exfiltrated surface water samples were collected and analyzed for pH, ORP, DOM concentration, and DOM optical indices. In both the wetland and transition zone cores, porewater DOM concentrations increased over the wet up and were sustained during prolonged saturation. Optical indices shifted from recently produced, microbial-like signatures towards aromatic, terrestrial-like signatures. Fluxes of CO 2 decreased as the duration of soil saturation increased and soil cores switched from CH 4 sinks to sources upon full soil core saturation. Results indicate that groundwater rise sustains carbon mobilization from soils in wetland-dominated landscapes, emphasizing the need to understand how climate-driven changes to groundwater dynamics may affect carbon fluxes along terrestrial-aquatic interfaces.

Delaware, Maryland

Large springs in the Valley and Ridge Province in Tennessee

Approximately 2,700 miscellaneous discharge measurements for 171 large springs in 28 counties of East Tennessee, predominantly within the Valley and Ridge physiographic province, were analyzed statistically and results tabulated to summarize data useful to the Appalachian Valleys-Piedmont Regional Aquifer System Analysis study. The number of measurements at each spring ranged from 1 to 65. Information from each spring includes station numbers, latitude, longitude, spring name and where data are sufficient, an estimate of the mean discharge and the discharge exceeded by 75%, 50%, and 25% of the miscellaneous measurements. Data are referenced to locations on a 1:1,000 ,000-scale map. The highest mean spring discharge was 32.2 cu ft/sec (14,5000 gallons/min).

Tennessee

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California

Technique for simulating peak-flow hydrographs in Maryland

The efficient design and management of many bridges, culverts, embankments, and flood-protection structures may require the estimation of time-of-inundation and (or) storage of floodwater relating to such structures. These estimates can be made on the basis of information derived from the peak-flow hydrograph. Average peak-flow hydrographs corresponding to a peak discharge of specific recurrence interval can be simulated for drainage basins having drainage areas less than 500 square miles in Maryland, using a direct technique of known accuracy. The technique uses dimensionless hydrographs in conjunction with estimates of basin lagtime and instantaneous peak flow. Ordinary least-squares regression analysis was used to develop an equation for estimating basin lagtime in Maryland. Drainage area, main channel slope, forest cover, and impervious area were determined to be the significant explanatory variables necessary to estimate average basin lagtime at the 95-percent confidence interval. Qualitative variables included in the equation adequately correct for geographic bias across the State. The average standard error of prediction associated with the equation is approximated as plus or minus (+/-) 37.6 percent. Volume correction factors may be applied to the basin lagtime on the basis of a comparison between actual and estimated hydrograph volumes prior to hydrograph simulation. Three dimensionless hydrographs were developed and tested using data collected during 278 significant rainfall-runoff events at 81 stream-gaging stations distributed throughout Maryland and Delaware. The data represent a range of drainage area sizes and basin conditions. The technique was verified by applying it to the simulation of 20 peak-flow events and comparing actual and simulated hydrograph widths at 50 and 75 percent of the observed peak-flow levels. The events chosen are considered extreme in that the average recurrence interval of the selected peak flows is 130 years. The average standard errors of prediction were +/- 61 and +/- 56 percent at the 50 and 75 percent of peak-flow hydrograph widths, respectively.

Maryland