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Conceptual and numerical groundwater flow model of the Iowa River alluvial aquifer near Tama County, Iowa, 1980 through 2022

The Iowa River alluvial aquifer is an important source of water on the Meskwaki Settlement in Tama County, Iowa, which is land owned by the Sac & Fox Tribe of the Mississippi in Iowa (commonly known as the Meskwaki Nation). The U.S. Geological Survey constructed a groundwater flow model, including a conceptual and numerical model, of the Iowa River alluvial aquifer and underlying hydrogeologic units near the Meskwaki Settlement in Tama County, Iowa, for the period of January 1980–August 2022 to estimate the fraction of water pumped from the Iowa River alluvial aquifer by Meskwaki Settlement wells that is derived from streamflow depletion in the Iowa River and its tributaries. Streamflow depletion is a reduction in streamflow caused by groundwater pumping and includes the interception by groundwater production wells of water that otherwise would have been discharged to streams (called “captured groundwater discharge”) and induced infiltration of streamflow to the production wells. Calibrated model runs were performed with no simulated pumping and simulated pumping only at Meskwaki Settlement wells, and the change in simulated flow rates between the groundwater system and streams for the two model runs represents the amount of streamflow depletion in the Iowa River and tributary streams resulting from pumping at the Meskwaki Settlement wells. Streamflow depletion in the Iowa River and its tributaries as a percentage of simulated pumping at the Meskwaki Settlement wells was calculated by dividing this difference by the total simulated pumping rate for the Meskwaki Settlement wells. The model results demonstrate that the mean monthly streamflow depletion, including induced infiltration and captured discharge, in the Iowa River and its tributary streams as a percentage of mean monthly pumping at the Meskwaki Settlement wells was 97.4 percent and ranged from 65.4 to 112 percent. Of the total streamflow depletion, mean monthly induced recharge was 20.9 percent and ranged from 4.9 to 37.2 percent. Mean monthly captured discharge was 76.5 percent and ranged from 57.1 to 97.1 percent. These results indicate that most of the water pumped from the Meskwaki Settlement wells is the result of streamflow depletion, in the form of both induced infiltration and captured discharge.

Iowa

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2023

As part of a long-term cooperative program to monitor water quality within the Scituate Reservoir drainage area, the U.S. Geological Survey, in cooperation with Providence Water (formerly the Providence Water Supply Board), collected streamflow and water-quality data in tributaries to the Scituate Reservoir, Rhode Island. Streamflow and concentrations of chloride and sodium estimated from records of specific conductance for 16 tributaries were used to calculate loads of chloride and sodium during water year 2023 (October 1, 2022, through September 30, 2023). Water-quality samples were collected by Providence Water at 38 sampling stations on tributaries to the Scituate Reservoir during water year 2023. These water-quality data are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields of selected water-quality constituents for water year 2023. Annual mean streamflows for monitoring stations in this study ranged from 0.47 to 34.4 cubic feet per second during water year 2023. At the 16 continuous-record streamgages, tributaries transported about 3,000 metric tons of chloride and 1,900 metric tons of sodium to the Scituate Reservoir; annual chloride yields for the tributaries ranged from 19 to 200 metric tons per square mile, and annual sodium yields ranged from 13 to 120 metric tons per square mile. At the stations where water-quality samples were collected by Providence Water, the medians of the median daily loads were 65,000 million colony forming units per day for coliform bacteria, 870 million colony forming units per day for Escherichia coli , 200 kilograms per day for chloride, 8.2 grams per day as nitrogen for nitrite, 520 grams per day as nitrogen for nitrate, and 300 grams per day as orthophosphate for phosphate. The medians of the median yields were 25,000 million colony forming units per day per square mile for coliform bacteria, 600 million colony forming units per day per square mile for Escherichia coli , 65 kilograms per day per square mile for chloride, 4.6 grams per day per square mile as nitrogen for nitrite, 180 grams per day per square mile as nitrogen for nitrate, and 180 grams per day per square mile as orthophosphate for phosphate.

Rhode Island

Use of a ground-penetrating radar system to detect pre- and post-flood scour at selected bridge sites in New Hampshire, 1996-98

Ground-penetrating radar was used to measure the depth and extent of existing and infilled scour holes and previous scour surfaces at seven bridges in New Hampshire from April 1996 to November 1998. Ground-penetrating-radar survey techniques initially were used by the U.S. Geological Survey to study streambed scour at 30 bridges. Sixteen of the 30 bridges were re-surveyed where floods exceeded a 2-year recurrence interval. A 300-megahertz signal was used in the ground-penetrating radar system that penetrated through depths as great as 20 feet of water and as great as 32 feet of streambed materials. Existing scour-hole dimensions, infilled thickness, previous scour surfaces, and streambed materials were detected using ground-penetrating radar. Depths to riprap materials and pier footings were identified and verified with bridge plans. Post data-collection-processing techniques were applied to assist in the interpretation of the data, and the processed data were displayed and printed as line plots. Processing included distance normalization, migration, and filtering but processing was kept to a minimum and some interference from multiple reflections was left in the record. Of the 16 post-flood bridges, 22 ground-penetrating-radar cross sections at 7 bridges were compared and presented in this report. Existing scour holes were detected during 1996 (pre-flood) data collection in nine cross sections where scour depths ranged from 1 to 3 feet. New scour holes were detected during 1998 (post-flood) data collection in four cross sections where scour depths were as great as 4 feet deep. Infilled scour holes were detected in seven cross sections, where depths of infilling ranged from less than 1 to 4 feet. Depth of infilling by means of steel rod and hammer was difficult to verify in the field because of cobble and boulder streambeds or deep water. Previous scour surfaces in streambed materials were identified in 15 cross sections and the depths to these surfaces ranged from 1 to 10 feet below the streambed. Riprap materials or pier footings were identified in all cross sections. Calculated record depths generally agree with bridge plans. Pier footings were exposed at two bridges and steel pile was exposed at one bridge. Exposures were verified by field observations.

New Hampshire

Water-quality appraisal of NASQAN stations below impoundments, eastern Tennessee

The National Stream Quality Accounting Network (NASQAN) is a network of stations at which systematic and continuing water-quality data are collected. Major objectives of this U.S. Geological Survey program are (1) to depict areal variability of streamflow and water-quality conditions nationwide on a year-by-year basis and (2) to detect long-term changes in streamflow and stream quality. Several NASQAN stations in East Tennessee are downstream from impoundments which have a significant effect on water quality. NASQAN data obtained from the Tennessee River below Watts Bar Dam and the Clinch River below Melton Hill Dam were compared to water-quality data from the basins upstream. The comparison indicates that NASQAN data obtained below impoundment may not be adequate to describe a composite picture of water quality in the accounting unit. Detention time of storage in the impoundments is believed to moderate the range of constituent values observed at the NASQAN stations. Data obtained upstream and downstream from Watts Bar Dam indicate that the water sampled at the NASQAN station comes from stratified layers of the impoundment and is not representative of an integrated sample of water from the impoundment. Values of total recoverable iron suggest that, because of adsorption to sediments in impoundments, some constituents are not accurately described by sampling below impoundments. Relations between water-quality constituents and flow at stations on the Clinch River and Tennessee River are not well defined due to regulation. Direct load computations for many constituents were therefore not possible, which diminished the utility of data from these NASQAN stations to account for quantity versus quality of the water. Load computations were only possible for ionic constituents through use of a continuous specific-conductance record as an intermediary. Compensation for the effects of discharge prior to application of the Seasonal Kendall test for trends could not be done and identification of trends in water-quality constituents caused by some process (source) change was not possible. Some water-quality trends indicated by data from the Clinch and Tennessee Rivers might reflect the decreasing trend in discharge during the 1972-82 water years. Thus the stations below Watts Bar Dam and below Melton Hill Dam do not adequately meet the NASQAN objective to detect and assess long-term changes in stream quality.

Tennessee

Final project peport for “Mapping riparian vegetation response to climate change on the San Carlos Apache Reservation and Upper Gila River watershed to inform restoration priorities: 1935 to present – Phase 2: Focus on tamarisk vegetation”

Riparian ecosystems play a critical role in supporting wildlife habitats, maintaining water quality, and sustaining ecological resilience in arid landscapes. In the Upper Gila River level-4 Hydrologic Unit Code (HUC-4; Identification Number – 1504) watershed of Arizona and New Mexico, and across areas of the San Carlos Apache Tribe of the San Carlos Apache Reservation (hereafter, Tribe/Tribal – entity; or Reservation - place), riparian ecosystems have been substantially altered by the widespread expansion of tamarisk ( Tamarix spp.), an invasive and non-native riparian species. Tamarisk has high water use and increased flammability, making it a growing concern as droughts intensify across the southwestern United States (U.S.). Recent research indicates that tamarisk is increasingly stressed under prolonged drought conditions, which can elevate wildfire risk and further degrade riparian habitat. In response, the U.S. Geological Survey (USGS) Western Geographic Science Center, in collaboration with the Tribe, developed remote sensing–based tools to map riparian vegetation composition and monitor vegetation condition over time. These tools enable accurate identification of tamarisk extent, detection of vegetation stress, and comparison with native species such as cottonwood and willow. This information directly supports restoration and management actions, including targeted tamarisk removal, protection of endangered species habitat, and prioritization of areas for native vegetation recovery. The tools also provide insight into how riparian vegetation responds to changing climate and hydrologic conditions, strengthening long-term planning for riparian forest management. Findings from this work demonstrate that riparian vegetation responses vary across river systems, indicating differences in plant composition and hydro-climatic conditions. Tamarisk on both the Gila and San Carlos Rivers generally exhibit greater declines in greenness in response to higher temperature as well as lower precipitation and river flow, while cottonwood ( Populus fremontii ) and willow (Salix spp.) are particularly sensitive to changes in discharge along the San Carlos River and respond more directly to both high and low flows, with more moderate responses to precipitation and temperature. By providing actionable, science-based information, this research supports climate adaptation planning, wildfire risk reduction, and improved riparian ecosystem health, with benefits that extend beyond the Reservation to regional water and wildlife conservation efforts.

Arizona, New Mexico

Surficial geology and Quaternary tectonics of the Madison Valley and fault zone, Madison, Gallatin, and Beaverhead Counties, southwest Montana

The north-northwest-striking Madison fault is approximately 95 kilometers in length, lying at the confluence of the northeastern Basin and Range province and the Yellowstone tectonic parabola. The fault zone consists primarily of west-dipping normal faults that have east-dipping antithetic faults, which create the Madison Valley graben and several northeast-trending intrabasin faults. The Madison fault and associated sections discussed herein refer to the main west-dipping, range-bounding fault along the eastern side of the valley. Detailed geologic mapping (1:12,000 scale) of the entire fault zone and fault scarp profiling (total of 102 profiles) of the Madison fault reveal greater late Quaternary paleoseismic activity towards the south, including at least three paleoevents along the southern part of the fault that postdate Pinedale glaciation. Early to middle Holocene alluvial fans have vertical surface offsets that average between 2.0 and 3.0 meters and define the characteristic single-event surface offset. Pinedale lateral moraines have vertical surface offsets as great as 12.0 meters. Late Pleistocene to Holocene multiple-event fault scarps show little evidence of beveling, suggesting short seismic recurrence intervals and potential late Pleistocene and Holocene temporal clustering. Long-term average tectonic activity rates indicate slip rates ranging from 0.18–0.6 millimeters per year. Based on a comparison of fault-scarp height versus maximum slope angle of known regression lines developed from other paleoseismic investigations, the most recent event ranges from 5–1 ka. The northern section of the fault zone is defined by multiple normal faults, which detached the hanging walls of Laramide thrust faults within the Paleozoic and Mesozoic strata. This resulted in the partitioning of extension along multiple preexisting structures and less displacement along individual normal fault strands. Structural controls on lateral propagation of individual paleoevents involve the position of lateral ramps along preexisting Laramide contractional faults. This resulted in greater displacement within the larger basement-cored structures along the southern section of the fault zone, where extension is accommodated by one inferred principal basement-involved normal fault. Inferred east-northeast trending, intrabasin, normal faults within the southern half of the fault zone have no late Pleistocene displacement.

Idaho, Montana, Wyoming

Simulated hydrologic responses to proposed wastewater-returnflow scenarios in Falmouth, Massachusetts

The Cape Cod aquifer is the sole source of drinking water for communities on Cape Cod, Massachusetts, including the Town of Falmouth, where the aquifer is currently threatened by contamination from septic-system-derived nitrogen. To address this problem, the Town is proposing to sewer areas of Falmouth, treat the wastewater at the Town’s Main Wastewater Treatment Facility (a nitrogen removing/tertiary treatment facility), and discharge the treated wastewater to an ocean outfall pipe in Nantucket Sound. The U.S. Geological Survey, in cooperation with the Town of Falmouth, updated a three-dimensional steady-state groundwater flow model to represent current (defined as 2019–23) average hydrologic conditions and to simulate the long-term average freshwater hydrologic response to two wastewater-return-flow scenarios. Scenario 1 involves the sewering of all properties south of Route 28 in Falmouth, which approximates the Town’s possible sewer expansion over the next 20–30 years. Scenario 2 involves sewering of all properties in Falmouth to demonstrate the maximum potential effect of sewering on the aquifer. Overall, the simulated hydrologic response of water-table altitudes and streamflow in both scenarios was relatively small compared to fluctuations from natural recharge. In scenario 1, the water-table altitude decreased by about 0.1 feet south of Route 28, where the conversion to municipal sewers removed wastewater-return flow from onsite septic systems. The water-table altitude decreased by about 0.1–0.2 feet over a larger area in Falmouth under town-wide sewering in scenario 2. The greatest decrease in water-table altitude in both scenarios occurred near the Main Wastewater Treatment Facility, with a decrease of about 1.1 feet in scenario 1 and about 1.3 feet in scenario 2. Simulated decreases in streamflow also were estimated for six selected streams in Falmouth and Mashpee. In both scenarios, the largest simulated decreases in streamflow were at the Coonamessett River, which is the closest stream to the Main Wastewater Treatment Facility. In scenario 1, the average annual decrease in flow at the Coonamessett River was 0.1 cubic feet per second, a 1.1 percent decrease from current (2019–23) conditions. In scenario 2, streamflow at the Coonamessett River decreased by 0.6 cubic feet per second, a 5.4 percent decrease from current (2019–23) conditions.

Massachusetts

Thick- and thin-skinned contractional styles and the tectonic evolution of the northern Sangre de Cristo Mountains, Colorado, USA

The Sangre de Cristo Mountains of southern Colorado and northern New Mexico, USA, contain an unusual combination of thick- and thin-skinned contractional structures involving both basement and cover rocks in the Laramide Rocky Mountain foreland. These structures are truncated by down-faulted extensional basins to the east and west. Together with synorogenic sediments, these structures preserve a record of the rise of the Ancestral Rocky Mountains, the Laramide orogeny, and Rio Grande rifting. Laramide structures within the mountains provide clues to processes that link the three events and to necessary conditions for thin-skinned and thick-skinned contractional structures to form together in continental interiors. To examine the full variety of structural styles, a portion of the northern Sangre de Cristo fold- and-thrust belt in Colorado was described and interpreted using geologic maps and structural cross-sections. Stratigraphic relations of the Ancestral Rocky Mountain highlands and basin fill were reconstructed from existing maps. These relations allow identification of faults inherited from the Ancestral Rocky Mountains, differentiation of thrust sheets, and in some cases, estimation of the magnitude of displacement. To examine relations between Laramide thrusts and Rio Grande rifting, kinematic data were collected from a thrust fault adjacent to rift faults. Three thrust fault styles were recognized: thin-skinned basement, thin-skinned cover rocks, and thick-skinned basement. Thin-skinned thrusts arising from a hinterland beneath the present San Luis Valley carried sheets of Proterozoic basement rocks northeast over a Laramide foreland. These basement thrusts are interpreted to be faults of the Ancestral Rocky Mountains that reactivated during the Laramide orogeny. The Laramide foreland consists of thin-skinned thrusts and folds in sedimentary cover rocks as young as 49 Ma. Both thin-skinned thrusts in basement and cover rocks are bounded by thick-skinned basement thrusts that moved intermittently throughout the Laramide orogeny. We infer that thin-skinned thrusts form in continental interiors where deformation is focused in weak strata of thick basin fill and in fluid-reaction weakened preexisting faults in basement rocks. Both conditions are met in the Sangre de Cristo Mountains. Basement thrusts adjacent to the San Luis Valley contain evidence of plastic contractional microstructures overprinted by extensional microstructures that may record the transition from Laramide contraction to Rio Grande extension of the crust.

Colorado

Investigation of land cover within wetland complexes at Dixie Meadows, Churchill County, Nevada, from October 2015 to January 2022

The U.S. Geological Survey investigated land cover at subannual time steps within six wetland areas in Dixie Valley, Churchill County, Nevada, from October 2015 to January 2022. As requested by the U.S. Fish and Wildlife Service, we used aerial photography and satellite remote sensing data to map surface water and other land cover types within the wetland complexes. We identified five land cover classes using the green normalized difference vegetation index (gNDVI) and its inverse relationship to the normalized difference water index (NDWI) within three U.S. Department of Agriculture National Agriculture Imagery Program aerial images (acquired in 2015, 2017, and 2019) and 110 European Space Agency Sentinel-2 satellite images (acquired 2015–2022). The relative wetness of soil conditions within each land cover class is estimated by comparison to previously published observations of relative conductivity measured by 79 field-based sensors within the wetlands from 2019 to 2021. We mapped the areal coverage of the five land cover classes for approximately 385 acres (1,559,000 square meters [m²]) comprising six individual wetland complexes as well as a larger 1,298- acre (5,254,000-m 2 ) area of interest inclusive of the wetland complexes and adjacent landscape. Land cover of open water (Class 5) primarily within ponds at one of the wetland complexes comprised 8,333 m 2 , on average, of the wetland complexes. Land cover of mixed shallow surface water, saturated soil, and vegetation (Class 4) comprised 111,723 m 2 on average of the wetland complexes. Land cover of dense green vegetation canopy cover (Class 3) that often (46 percent of observations) had underlying surface water or saturated soil conditions comprised 592,522 m 2 on average of the wetland complexes. The remaining areas of the wetland complexes not mapped as these three land cover types (Classes 2 and 1) had sparse vegetation or bare soil cover and commonly (greater than or equal to 67 percent of observations) had dry soil conditions. The investigation of land cover detailed in this report could inform future efforts to map land cover more precisely via higher resolution remote sensing or ground-based surveying or could be incorporated with other environmental monitoring data to characterize habitat and hydrology of the wetland complexes at Dixie Meadows.

Nevada

A joint Gaussian process model of geochemistry, geophysics, and temperature for groundwater TDS in the San Ardo Oil Field, California, USA

Decline in availability of fresh groundwater has expanded interest in brackish groundwater resources; however, the distribution of brackish groundwater is poorly understood. Water resources in sedimentary basins across the United States often overlie oil and gas development. Mapping of groundwater total dissolved solids (TDS) using data from oil well geophysical logs has become an important technique for identifying fresh and brackish groundwater. Existing geophysical log analysis methods use porosity and temperature to relate formation resistivity to TDS. Typically, natural geothermal gradients are used to estimate temperature at the location of collected resistivity. However, in thermally enhanced oil fields, steam is injected into the subsurface to mobilize high viscosity oil, creating variable temperature distributions. Furthermore, TDS derived from resistivity also depends on the fractions of dominant ions. Typically, chloride and bicarbonate fractions must be determined. It is also necessary to model TDS across many geologic units with heterogenous porosity distributions. Collectively, each quantity used to estimate TDS (resistivity, porosity, temperature, bicarbonate fraction) varies in space and time, and available data points are rarely collocated. Here, we present a new method of mapping groundwater TDS that continuously models each quantity together with a joint Gaussian process. This method enables mapping fresh and brackish water with practically available data. We apply this method to the San Ardo Oil Field in Monterey County, California, where steam injection occurs. In some areas of the aquifer system overlying the oil zone, the temperature is ∼75 °C, roughly twice the natural background value. Groundwater TDS is typically <1,500 mg/L in the aquifer and increases with depth to ∼9,000 mg/L in the oil-producing zone. A low-permeability clay layer delineates the fresh and brackish water, likely by inhibiting surface recharge from penetrating the deeper zones, allowing higher-TDS connate water to remain in place. Weaker lateral TDS trends may be controlled by recharge patterns associated with the Salinas River. Our model reveals with high certainty that groundwater has freshened in one localized part of the oil-producing zone and suggests with less certainty that more widespread freshening has also occurred. The lowering of TDS was possibly from decades of low-TDS steam injection and the associated fluid production and disposal operations.

California

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Collaborative drought science planning in the Colorado River Basin

The U.S. Geological Survey (USGS) is using collaborative, interdisciplinary planning to develop data and tools needed to optimize the management of water resources and land use by resource management agencies during an ongoing, multidecadal drought in the Colorado River Basin. The USGS Actionable and Strategic Integrated Science and Technology team works to build relationships with resource management agencies and other stakeholders who can benefit from the use of USGS data and products. In 2023, the Actionable and Strategic Integrated Science and Technology team hosted a series of collaborative workshops to bring together representatives of resource management agencies and other stakeholders (any person or entity with interests in a resource or location) with USGS program managers, scientists, and multidisciplinary subject matter experts to codevelop concepts for interdisciplinary drought science and technology projects to address pressing needs related to drought in the Colorado River Basin. Workshop participants identified current and recent scientific data that could be shared through a centralized online data portal. Workshop participants also identified drought science and technology needs and developed project concepts to address those science needs. Participants categorized project concepts based on their potential to develop short-, mid-, and long-term drought science data and tools, provide for the spatial or temporal expansion of ongoing USGS science projects, and address high-priority science needs. Participants developed nine project concepts: (1) understanding shifting ecohydrologic baselines, (2) San Juan River Basin synthesis, (3) incorporating dynamic land cover into hydrologic models, (4) aridification compared to drought, (5) surface water-groundwater interactions, (6) cascading effects of drought on dust, (7) cascading effects of drought on water availability, (8) cascading effects of drought on socioeconomic factors, and (9) the value of water in the Colorado River Basin. This report provides an overview of the 2023 Codesign Workshop Series, synthesized outcomes from workshop materials and discussions, and science project concepts that emerged from the collaborative meetings that will continue to be refined into science project proposals through codevelopment processes. This report also highlights lessons learned and next steps needed to receive feedback and testing of the USGS Science Collaboration Portal, continue collaboration to develop detailed specifics and steps for short-term wins, develop interdisciplinary project proposals, and implement science planning and studies.

Arizona, California, Colorado, Nevada, New Mexico,

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ&rsquo;s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio

Generalized potentiometric maps of the Fort Union, Hell Creek, and Fox Hills aquifers within the Standing Rock Reservation

Generalized potentiometric surfaces of the Fort Union, Hell Creek, and Fox Hills aquifers were constructed to assess the groundwater resources of the Standing Rock Reservation. Additionally, this information can provide water managers with tools and data to effectively manage water resources in the future. Previous studies that mapped the geology and hydrogeology of the area at differing scales were used to confirm in which aquifer the study wells were completed. Water-level data from wells are provided by the U.S. Geological Survey Groundwater System Inventory database, the South Dakota Department of Agriculture and Natural Resources, and the North Dakota Department of Water Resources. Hydrographs were constructed for five selected observation wells to evaluate historical water-level fluctuations and trends. Hydrographs for the Hell Creek aquifer showed a flat trend with a rise in 2020. Hydrographs for the deeper Fox Hills aquifer showed that water levels fluctuated in response to climatic conditions and demonstrated an increasing trend in water-level elevations starting in 2010. Hydrographs were not constructed for any wells completed in the Fort Union Formation because none of the wells had continuous long-term measurements. Generalized potentiometric surfaces, constructed from interpolating water-level elevations, gave insight into groundwater flow directions. Groundwater in the Fort Union aquifer likely flows radially outward from the northwest part of the study area to the northeast and south-southeast parts. Groundwater in the Hell Creek aquifer generally flows from higher elevations in the northwest towards lower areas, where surface-water tributaries have incised into the aquifer. Groundwater in the Fox Hills aquifer likely flows from higher elevations in the west, southwest, and central parts of the study area towards the valleys of the Grand River and Missouri River. Most wells used for constructing potentiometric maps had only one recorded water-level measurement from drillers at the time of well construction. These measurements are often subject to error because the well is still recovering and because of spatial limitations of data availability. Also, because single water-level measurements were recorded at different points in time, additional uncertainty is introduced by fluctuating climatic conditions effect on water levels. Potentiometric map interpretation limitations are a result of areas with sparse data. Limitations also arise from potentiometric surfaces generalizing a complex and dynamic hydrogeologic system; however, the generalized potentiometric surface maps can be used to assist water managers and can help prioritize locations for future monitoring in areas with high uncertainty from sparse existing data.

North Dakota, South Dakota

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota

Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis

Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.

Michigan, Wisconsin