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At least 721 records · Page 40Linked to original sources
USGS1999

Induced infiltration from the Rockaway River and water chemistry in a stratified-drift aquifer at Dover, New Jersey, with a section on modeling ground-water flow in the Rockaway River Valley

The vertical hydraulic conductivity per unit thickness (streambed leakance) of unconsolidated sediment immediately beneath the channel of the Rockaway River near a municipal well field at Dover, N.J., is between 0.2 and 0.6 feet per day per foot and is probably near the low end of this range. This estimate is based on evaluation of three lines of evidence: (1) Streamflow measurements, which indicated that induced infiltration of river water near the well field averaged 0.67 cubic feet per second; (2) measurements of the rate of downward propagation of diurnal fluctuations in dissolved oxygen and water temperature at three piezometers, which indicated vertical Darcian flow velocities of 0.6 and 1.5 feet per day, respectively; and (3) chemical mixing models based on stable isotopes of oxygen and hydrogen, which indicated that 30 percent of the water reaching a well near the center of the well field was derived from the river. The estimated streambed-leakance values are compatible with other aquifer properties and with hydraulic stresses observed over a 2-year period, as demonstrated by a set of six alternative groundwater flow models of the Rockaway River valley. Simulated water levels rose 0.5 to 1.7 feet near the well field when simulated streambed leakance was changed from 0.2 to 0.6 feet per day per foot, or when a former reach of the Rockaway River valley that is now blocked by glacial drift was simulated as containing a continuous sand aquifer (rather than impermeable till). Model recalibration to observed water levels could accommodate either of these changes, however, by plausible adjustments in hydraulic conductivity of 35 percent or less. The ground-water flow models incorporate a new procedure for simulating areal recharge, in which water available for recharge in any time interval is accepted as recharge only where the water level in the uppermost model layer is below land surface. Water rejected as recharge on upland hillsides is allowed to recharge aquifers at the base of the hillsides. Inclusion of uplands in models of valley-fill aquifers and use of the new procedure increases model complexity and data requirements, but automates the simulation of recharge to those aquifers from the uplands, even in transient-state simulations with multiple periods of varied stresses, and facilitates delineation of upland areas that contribute water to well fields. The area from which ground water flowed toward the Dover well field decreased with an increase in simulated streambed leakance or an increase in simulated hydraulic conductivity of upland till. Concentrations of solutes in ground water near the Dover well field reflect the mixing of native ground water with water infiltrated from the Rockaway River. Chemical reactions in the aquifer, chiefly the weathering of carbonate minerals by dissolved carbon dioxide, affect the pH and the concentrations of both solutes and dissolved gases. Concentrations of sodium, chloride, and sulfate appear to be related to man's activities, such as road deicing, or to decay of organic matter in the aquifer.

New Jersey↗
USGS1998

Chemistry and isotopic composition of ground water along a section near the Newmark area, San Bernardino County, California

Chemical and isotopic analyses and flow-meter measurements in pumped wells were used to determine the source, movement, and age of ground water along a section of the valley-fill aquifer from the San Jacinto Fault to the base of the San Bernardino Mountains near the Newmark area in the Bunker Hill Basin of southern California. Water samples were collected from four multiple-depth well sites, from different depths within three production wells, and from two nearby streams; these samples were analyzed for major ions, selected trace elements, stable isotopes of oxygen and hydrogen (delta oxygen-18 and delta deuterium), tritium, and carbon-14. Within the production wells, variations in vertical flowrate with depth were recorded during pumped conditions using a standard spinner tool. Where saturated, the upper 200 feet of unconsolidated deposits contributed as much as 60 percent of the well discharge; deposits at depths greater than 700 feet contributed less than 10 percent. Chemical analyses indicate that three general zones of ground-water quality are present along a north-south section--an oxygenated zone near the base of the San Bernardino Mountains, an oxygen-depleted zone near the San Jacinto Fault, and a deeper zone characterized by concentrations of fluoride greater than 1 mg/L and by a general water-quality composition similar to that of base flow in East Twin Creek. The presence of tritium in water from wells along the section indicates that post-1952 recharge has moved rapidly through the valley-fill aquifer to depths as great as 800 feet. Carbon-14 data indicate that the maximum age of ground water, sampled at depths ranging from 600 to 1,000 feet, is less than 5,000 years before present. Ground water along the study section is much younger than ground water from similar depths in other nearby basins. Delta oxygen-18 and delta deuterium data indicate that as much as 25 percent of the discharge from some wells near the base of the San Bernardino Mountains is water that was imported from northern California. Improved knowledge of depth-dependent ground-water flow along this section can aid in the design of an effective strategy for basin management, including remediation of the Newmark area, which is designated by the U.S. Environmental Protection Agency as a Superfund cleanup site.

Water-Resources Investigations Report↗
USGS1999

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming↗
USGS1999

Inorganic chemistry of water and bed sediment in selected tributaries of the south Umpqua River, Oregon, 1998

Ten sites on small South Umpqua River tributaries were sampled for inorganic constituents in water and streambed sediment. In aqueous samples, high concentrations (concentrations exceeding U.S. Environmental Protection Agency criterion continuous concentration for the protection of aquatic life) of zinc, copper, and cadmium were detected in Middle Creek at Silver Butte, and the concentration of zinc was high at Middle Creek near Riddle. Similar patterns of trace-element occurrence were observed in streambed-sediment samples.The dissolved aqueous load of zinc carried by Middle Creek along the stretch between the upper site (Middle Creek at Silver Butte) and the lower site (Middle Creek near Riddle) decreased by about 0.3 pounds per day. Removal of zinc from solution between the upper and lower sites on Middle Creek evidently was occurring at the time of sampling. However, zinc that leaves the aqueous phase is not necessarily permanently lost from solution. For example, zinc solubility is pH-dependent, and a shift between solid and aqueous phases towards release of zinc to solution in Middle Creek could occur with a perturbation in stream-water pH. Thus, at least two potentially significant sources of zinc may exist in Middle Creek: (1) the upstream source(s) producing the observed high aqueous zinc concentrations and (2) the streambed sediment itself (zinc-bearing solid phases and/or adsorbed zinc). Similar behavior may be exhibited by copper and cadmium because these trace elements also were present at high concentrations in streambed sediment in the Middle Creek Basin.

Oregon↗
USGS2000

Deposition and chemistry of bottom sediments in Cochiti Lake, north-central New Mexico

Bottom sediments were sampled at seven sites in Cochiti Lake in September 1996. Sediment cores penetrating the entire lacustrine sediment sequence were collected at one site near the dam. Surficial sediments were sampled at the near-dam site and six other sites located along the length of the reservoir. Analyses included grain size, major and trace elements, organochlorine compounds, polycyclic aromatic hydrocarbons (PAH's), and radionuclides. Concentrations of trace elements, organic compounds, and radionuclides are similar to those in other Rio Grande reservoirs and are low compared to published sediment-quality guidelines. Most elements and compounds that were detected did not show trends in the age estimated sediment cores with the exception of a decreasing trend in total DDT concentrations from about 1980 to 1992. The mixture of PAH's suggests that the increase is caused by inputs of fuel-related PAH and not combustion- related PAH.

New Mexico↗
USGS1972

Significance of ground-water chemistry in performance of North Sahara Tube wells in Algeria and Tunisia

Nine ground-water samples from the principal shallow and deep North Sahara aquifers of Algeria and Tunisia were examined to determine the relation of their chemical composition to corrosion and mineral encrustation thought to be contributing to observed decline in well capacities within a UNESCO/UNDP Special Fund Project area. Although the shallow and deep waters differ significantly in certain quality factors, all are sulfochloride types with corrosion potentials ranging from moderate to extreme. None appear to be sufficiently supersaturated with troublesome mineral species to cause rapid or severe encrustation of filter pipes or other well parts. However, calcium carbonate encrustation of deep-well cooling towers and related irrigation pipes can be expected because of loss of carbon dioxide and water during evaporative cooling. Corrosion products, particularly iron sulfide, can be expected to deposit in wells producing waters from the deep aquifers. This could reduce filterpipe openings and increase casing roughness sufficiently to cause significant reduction in well capacity. It seems likely, however, that normal pressure reduction due to exploitation of the artesian systems is a more important control of well performance. If troublesome corrosion and related encrustation are confirmed by downhole inspection, use of corrosion-resisting materials, such as fiber-glass casing and saw-slotted filter pipe (shallow wells only), or stainless-steel screen, will minimize the effects of the waters represented by these samples. A combination of corrosion-resisting stainless steel filter pipe electrically insulated from the casing with a nonconductive spacer and cathodic protection will minimize external corrosion of steel casing, if this is found to be a problem. However, such installations are difficult to make in very deep wells and difficult to control in remote areas. Both the shallow waters and the deep waters examined in this study will tend to cause soil salinization because their salt contents are relatively high, and both have sodium absorption ratios which are unfavorable to sodium-sensitive soils and vegetation. Proper drainage and soil treatment are the only means of overcoming these problems during irrigation.

Water Supply Paper↗
USGS1968

Hydrology of Crater, East and Davis Lakes, Oregon; with section on Chemistry of the Lakes

Crater, East, and Davis Lakes are small bodies of fresh water that occupy topographically closed basins in Holocene volcanic terrane. Because the annual water supply exceeds annual evaporation, water must be lost by seepage from each lake. The seepage rates vary widely both in volume and in percentage of the total water supply. Crater Lake loses about 89 cfs (cubic feet per second), equivalent to about 72 percent of its average annual supply. East Lake loses about 2.3 cfs, or about 44 percent of its estimated supply. Davis Lake seepage varies greatly with lake level, but the average loss is about 150 cfs, more than 90 percent of its total supply. The destination of the seepage loss is not definitely known for any of the lakes. An approximate water budget was computed for stationary level for each lake, by using estimates 'by the writer to supplement the hydrologic data available. The three lake waters are dilute. Crater Lake contains about 80 ppm, (parts per million) of dissolved solids---mostly silica, sodium, and bicarbonate, and lesser amounts of calcium, sulfate, and chloride. Much of the dissolved-solids content of Crater Lake---especially the sulfate and chloride---may be related to fumarole and thermal-spring activity that presumably followed the collapse of Mount Mazama. Although Grater Lake loses an estimated 7,000 tons of its 1.5million-ton salt content each year by leakage, the chemical character of the lake did not change appreciably between 1912 and 1964. East Lake contains 200 ppm of dissolved solids, which includes major proportions of calcium, sodium, bicarbonate, and sulfate, but almost no chloride. The lake apparently receives much of its dissolved solids from subsurface thermal springs. Annual solute loss from East Lake by leakage is about 450 tons, or 3 percent of the lake's 15,000-ton estimated solute content. Davis Lake contains only 48 ppm of dissolved solids, much of which is silica and bicarbonate; chloride is almost completely absent. Approximate physical and hydrologic data for the lakes are summarized in the following table. [Table]

Water Supply Paper↗
USGS2019

Soil aggregates as a source of dissolved organic carbon to streams: An experimental study on the effect of solution chemistry on water extractable carbon

Over the past two decades, headwater streams of the northern hemisphere have shown increased amounts of dissolved organic carbon (DOC), coinciding with decreased acid deposition. The exact nature of the mechanistic link between precipitation composition and stream water DOC is still widely debated in the literature. We hypothesize that soil aggregates are the main source of stream water DOC and that DOC release is greater in organic rich, riparian soils vs. hillslope soils. To test these hypotheses, we collected soils from two main landscape positions (hillslope and riparian zones) from the acid-impacted Sleepers River Research Watershed in northeastern Vermont. We performed aqueous soil extracts with solutions of different ionic strength (IS) and composition to simulate changes in soil solution. We monitored dynamic changes in soil particle size, aggregate architecture and composition, leachate DOC concentrations, dissolved organic matter (DOM) characteristics by fluorescence spectroscopy and trends in bioavailability. In low IS solutions, extractable DOC concentrations were significantly higher, particle size (by laser diffraction) was significantly smaller and organic material was separated from mineral particles in scanning electron microscope observations. Furthermore, higher DOC concentrations were found in Na + compared to Ca 2+ solutions of the same IS. These effects are attributed to aggregate dispersion due to expanding diffuse double layers in decreased IS solutions and to decreased bridging by divalent cations. Landscape position impacted quality but not quantity of released DOC. Overall, these results indicate that soil aggregates might be one important link between Critical Zone inputs (i.e., precipitation) and exports in streams.

Vermont↗
USGS2023

Land development and road salt usage drive long-term changes in major-ion chemistry of streamwater in six exurban and suburban watersheds, southeastern Pennsylvania, 1999-2019

In urbanized areas, the “freshwater salinization syndrome” (FSS), which pertains to long-term increases in concentrations of major ions and metals in fresh surface waters, has been attributed to road salt application. In addition to FSS, the water composition changes as an influx of sodium (Na + ) in recharge may displace calcium (Ca 2+ ), magnesium (Mg 2+ ), potassium (K + ), and trace metals by reverse cation exchange. These changing ion fluxes can result in adverse impacts on groundwater and surface waters used for municipal supplies. Few datasets exist to quantify the FSS on a watershed scale or link its manifestation to potential controlling factors such as changes in urban development, land use/land cover (LULC), or wastewater treatment plant (WWTP) discharges in upstream areas. Here, we use two decades (1999–2019) of monthly streamwater quality data combined with daily streamflow for six exurban and suburban watersheds in southeastern Pennsylvania to examine the relations among Ca 2+ , Mg 2+ , K + , Na + , chloride (Cl − ), sulfate (SO 4 2- ), and alkalinity (HCO 3 − ) concentrations and upstream controlling factors. Flow-normalized annual and baseflow (August ̶ November) concentrations for Ca 2+ , Mg 2+ , Na + , and Cl − increased in all six watersheds over the 20-year study, providing evidence of FSS’s impacts on groundwater that sustains streamflow. Additionally, a redundancy analysis using 2019 flow-normalized values identified the following positive associations between solute concentrations and controlling variables: 1) Cl − , Mg 2+ , and Ca 2+ with impervious surface cover (ISC), 2) Na + and SO 4 2- with ISC and total WWTP discharge volume, and 3) HCO 3 − with agriculture and total WWTP discharge volume. From a human health perspective, 2019 flow-normalized Na + concentrations exceeded the U.S. Environmental Protection Agency’s 20 mg L -1 threshold for individuals restricted to a low sodium diet. Furthermore, indices used to evaluate the corrosivity of source waters to drinking water infrastructure and inform municipal water treatment practices, such as the Chloride to Sulfate Mass Ratio and Larson Ratio, increased between two- and seven-fold over the 20-year time. Collectively, the results elucidate the causal factors of the FSS in suburban and exurban watersheds and its potential impacts on human health and drinking water infrastructure.

Pennsylvania↗
USGS2020

Cryptic lives of conspicuous animals: Otolith chemistry chronicles life histories of coastal lagoon fishes

Bar-built coastal lagoons are dynamic ecosystems at the land-sea interface that are important habitats for a variety of species. This study examined the habitat ecology of two lagoon species, the endangered Tidewater Goby ( Eucyclogobius newberryi ) and the Prickly Sculpin ( Cottus asper ) by reconstructing individual life histories from patterns in the concentration of the element Sr (as ratioed to Ca; Sr:Ca) in otoliths. Specific objectives were to (1) elucidate any movements of individual fishes among three primary habitat components of typical bar-built lagoon systems: coastal ocean, brackish lagoon, and freshwater watershed streams, and (2) determine if either species exhibited a consistent life history as defined by a stereotypical otolith Sr:Ca chronology, which could be indicative of a consistent range of salinity or temperature occupied through ontogeny. Results suggested that Tidewater Goby was a lagoon resident and that Prickly Sculpin exhibited migrations between lagoon and watershed stream habitats. There was no strong evidence in either species of ocean occupancy or of a stereotypical Sr:Ca chronology, the latter suggesting the full range of available lagoon habitat in terms of salinity and temperature was likely utilized at all life stages. These findings add to the body of evidence that bar-built lagoons are not isolated habitats, and holistic management of these habitats with adjoining watershed and marine environments could increase habitat connectivity across the landscape, with potential benefits to fishes.

California↗
USGS2008

Mineral chemistry and shrimp U-Pb Geochronology of mesoproterozoic polycrase-titanite veins in the sullivan Pb-Zn-Ag Deposit, British Columbia

Small polycrase-titanite veins 0.1-2 mm thick cut the tourmalinite feeder zone in the deep footwall of the Sullivan Pb-Zn-Ag deposit, southeastern British Columbia. Unaltered, euhedral crystals of polycrase and titanite 50-100 ??m in diameter are variably replaced by a finer-grained alteration-induced assemblage composed of anhedral polycrase and titanite with local calcite, albite, epidote, allanite, and thorite or uranothorite (or both). Average compositions of the unaltered and altered polycrase, as determined by electron-microprobe analysis, are (Y0.38 REE0.49 Th0.10 Ca0.04 Pb0.03 Fe0.01U0.01) (Ti1.48 Nb0.54 W0.04 Ta0.02)O6 and (Y0.42 REE0.32 Th0.15 U0.06 Ca0.04 Pb0.01 Fe0.01) (Ti1.57 Nb0.44 W0.04 Ta0.02)O6, respectively. The unaltered titanite has, in some areas, appreciable F (to 0.15 apfu), Y (to 0.40 apfu), and Nb (to 0.13 apfu). SHRIMP U-Pb geochronology of eight grains of unaltered polycrase yields a weighted 207Pb/206Pb age of 1413 ?? 4 Ma (2??) that is interpreted to be the age of vein formation. This age is 50-60 m.y. younger than the ca. 1470 Ma age of synsedimentary Pb-Zn-Ag mineralization in the Sullivan deposit, which is based on combined geological and geochronological data. SHRIMP ages for altered polycrase and titanite suggest later growth of minerals during the ???1370-1320 Ma East Kootenay and ???1150-1050 Ma Grenvillian orogenies. The 1413 ?? 4 Ma age for the unaltered polycrase in the veins records a previously unrecognized post-ore (<1470 Ma) and premetamorphic (>1370 Ma) mineralizing event in the Sullivan deposit and vicinity. The SHRIMP U-Pb age of the polycrase and high concentrations of REE, Y, Ti, Nb, and Th in the veins, together with elevated F in titanite and the absence of associated sulfides, suggest transport of these high-field-strength elements (HFSE) by F-rich and S-poor hydrothermal fluids unrelated to the fluids that formed the older Fe-Pb-Zn-Ag sulfide ores of the Sullivan deposit. Fluids containing abundant REE, HFSE, and F may have been derived from a geochemically specialized magma such as those that form alkaline granites, pegmatites, or carbonatites. In an alternative model. preferred here, these fluids were associated with a rift-related, crustal metasomatic event in the region. Determination of a Mesoproterozoic age for the polycrase-titanite veins establishes the first known occurrence of pre-Grenvillian REE-rich mineralization in the Belt-Purcell basin.

Canadian Mineralogist↗
USGS2024

Seroprevalence, blood chemistry, and patterns of canine parvovirus, distemper virus, plague, and tularemia in free-ranging coyotes (Canis latrans) in northern New Mexico, USA.

Wildlife diseases have implications for ecology, conservation, human health, and health of domestic animals. They may impact wildlife health and population dynamics. Exposure rates of coyotes ( Canis latrans ) to pathogens such as Yersinia pestis , the cause of plague, may reflect prevalence rates in both rodent prey and human populations. We captured coyotes in north-central New Mexico during 2005–2008 and collected blood samples for serologic surveys. We tested for antibodies against canine distemper virus (CDV, Canine morbillivirus ), canine parvovirus (CPV, Carnivore protoparvovirus ), plague, tularemia ( Francisella tularensis ), and for canine heartworm ( Dirofilaria immitis ) antigen. Serum biochemistry variables that fell outside reference ranges were probably related to capture stress. We detected antibodies to parvovirus in 32/32 samples (100%), and to Y. pestis in 26/31 (84%). More than half 19/32 (59%) had antibodies against CDV, and 5/31 (39%) had antibodies against F. tularensis . We did not detect any heartworm antigens ( n = 9). Pathogen prevalence was similar between sexes and among the three coyote packs in the study area. Parvovirus exposure appeared to happen early in life, and prevalence of antibodies against CDV increased with increasing age class. Exposure to Y. pestis and F. tularensis occurred across all age classes. The high coyote seroprevalence rates observed for CPV, Y. pestis , and CDV may indicate high prevalence in sympatric vertebrate populations, with implications for regional wildlife conservation as well as risk to humans via zoonotic transmission.

New Mexico↗