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USGS2021

Hydrogeologic framework, water levels, and selected contaminant concentrations at Valmont TCE Superfund Site, Luzerne County, Pennsylvania, 2020

The Valmont TCE Superfund Site, Luzerne County, Pennsylvania is underlain by fractured and folded sandstones and shales of the Pottsville and Mauch Chunk Formations, which form a fractured-rock aquifer recharged locally by precipitation. Industrial activities at the former Chromatex Plant resulted in trichloroethene (TCE) contamination of groundwater at and near the facility, which was identified in 1987 and led to listing as a Superfund site by the U.S. Environmental Protection Agency (EPA) in 1989. To address the problem of TCE concentrations in nearby residential wells that exceed the maximum contaminant level (MCL) of 5 micrograms per liter (μg/L), alternate water supplies were provided. A 2015 review of initial characterization and subsequent remediation by the EPA identified the need for an updated understanding of the complex hydrogeology and the conceptual site model. Additional contaminants present in groundwater at the site include some other volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFAS), predominantly consisting of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) present in concentrations that exceeded the EPA Health Advisory (HA) level of 5 nanograms per liter (ng/L) for combined PFOA and PFOS. In response to a request from the EPA in 2019, the U.S. Geological Survey (USGS) prepared cross sections and maps to provide more information about the hydrogeologic framework at and near the site and assist in improving the conceptual site model using water level and contaminant data collected by the EPA in 2020. The cross sections present lithologic correlations from available geophysical logs collected in wells from 2002 to 2014; they show alternating intervals of relatively elevated and reduced natural gamma activity that correspond to changes in lithology, with water-bearing zones and well screens commonly located at lithologic contacts, sometimes near thin coal seams. Water-bearing zones commonly are associated with fractures at or near lithologic contacts but also may be associated with fractures at or near apparent faulting. Recent (March 2020) water-level data shown on cross sections and maps indicate large downward vertical gradients and apparent radial gradients laterally to the northeast, northwest, and southwest that generally following topography. Recent (February to March 2020) data for TCE groundwater concentration shown on cross sections and maps indicate the highest TCE concentrations (greater than 3,000 μg/L and as much as 75,000 μg/L) and combined PFOA and PFOS concentrations (greater than 1,000 ng/L and up to at least 2,350 ng/L) are from shallow (less than 60 feet [ft] below land surface [bls]) and intermediate depth (60 to 100 ft bls) wells near the center of the former Chromatex Plant. TCE and PFAS (as combined PFOA and PFOS) contamination is present at greater depths, as much as 304 ft bls, as evidenced by samples collected from one well (a reconstructed former production well) near the plant, that contained concentrations of about 240 μg/L and 508 ng/L, respectively. The 2020 data also indicate that TCE and PFAS concentrations which exceed drinking-water MCL or HA levels are present in groundwater depths of less than 200 ft in an area that extends predominantly in a northeast direction from the former Chromatex Plant, and is apparently influenced by hydraulic gradients, lithology, and geologic structure.

Pennsylvania↗

USGS2009

Water-quality monitoring in response to young-of-the-year smallmouth bass (Micropterus dolomieu) mortality in the Susquehanna River and major tributaries, Pennsylvania: 2008

Mortalities of young-of-the-year (YOY) smallmouth bass ( Micropterus dolomieu ) recently have occurred in the Susquehanna River due to Flavobacterium columnare , a bacterium that typically infects stressed fish. Stress factors include but are not limited to elevated water temperature and low dissolved oxygen during times critical for survival and development of smallmouth bass (May 1 through July 31). The infections were first discovered in the Susquehanna River and major tributaries in the summer months of 2005 but also were prevalent in 2007. The U.S. Geological Survey, Pennsylvania Fish and Boat Commission, Pennsylvania Department of Environmental Protection, and PPL Corporation worked together to monitor dissolved oxygen, water temperature, pH, and specific conductance on a continuous basis at seven locations from May through mid October 2008. In addition, nutrient concentrations, which may affect dissolved-oxygen concentrations, were measured once in water and streambed sediment at 25 locations. Data from water-quality meters (sondes) deployed as pairs showed daily minimum dissolved-oxygen concentration at YOY smallmouth-bass microhabitats in the Susquehanna River at Clemson Island and the Juniata River at Howe Township Park were significantly lower (p-value < 0.0001) than nearby main-channel habitats. The average daily minimum dissolved-oxygen concentration during the critical period (May 1–July 31) was 1.1 mg/L lower in the Susquehanna River microhabitat and 0.3 mg/L lower in the Juniata River. Daily minimum dissolved-oxygen concentrations were lower than the applicable national criterion (5.0 mg/L) in microhabitat in the Susquehanna River at Clemson Island on 31 days (of 92 days in the critical period) compared to no days in the corresponding main-channel habitat. In the Juniata River, daily minimum dissolved-oxygen concentration in the microhabitat was lower than 5.0 mg/L on 20 days compared to only 5 days in the main-channel habitat. The maximum time periods that dissolved oxygen was less than 5.0 mg/L in microhabitats of the Susquehanna and Juniata Rivers were 8.5 and 5.5 hours, respectively. Dissolved-oxygen concentrations lower than the national criterion generally occurred during nighttime and early-morning hours between midnight and 0800. The lowest instantaneous dissolved-oxygen concentrations measured in microhabitats during the critical period were 3.3 mg/L for the Susquehanna River at Clemson Island (June 11, 2008) and 4.1 mg/L for the Juniata River at Howe Township Park (July 22, 2008). Comparison of 2008 data to available continuous-monitoring data from 1974 to 1979 in the Susquehanna River at Harrisburg, Pa., indicates the critical period of 2008 had an average daily mean dissolved-oxygen concentration that was 1.1 mg/L lower (p-value < 0.0001) than in the 1970s and an average daily mean water temperature that was 0.8 °C warmer (p-value = 0.0056). Streamflow was not significantly different (p-value = 0.0952) between the two time periods indicating that it is not a likely explanation for the differences in water quality. During the critical period in 2008, dissolved-oxygen concentrations were lower in the Susquehanna River at Harrisburg, Pa., than in the Delaware River at Trenton, N.J., or Allegheny River at Acmetonia near Pittsburgh, Pa. Daily minimum dissolved-oxygen concentrations were below the national criterion of 5.0 mg/L on 6 days during the critical period in the Susquehanna River at Harrisburg compared to no days in the Delaware River at Trenton and the Allegheny River at Acmetonia. Average daily mean water temperature in the Susquehanna River at Harrisburg was 1.8 °C warmer than in the Delaware River at Trenton and 3.4 °C warmer than in the Allegheny River at Acmetonia. These results indicate that any stress induced by dissolved oxygen or other environmental conditions is likely to be magnified by elevated temperature in the Susquehanna River at Harrisburg compared to the Delaware River at Trenton or the Allegheny River at Acmetonia.

Pennsylvania↗

USGS2018

Hydrologic characteristics and water quality of headwater streams and wetlands at the Allegheny Portage Railroad National Historic Site, Summit area, Blair and Cambria Counties, Pennsylvania, 2014–16

The Allegheny Portage Railroad National Historic Site (ALPO) in Blair and Cambria Counties, Pennsylvania, protects historic features of the first railroad portage over the Allegheny Front and the first railroad tunnel in the United States. This report, which was completed by the U.S. Geological Survey in cooperation with the National Park Service, summarizes water resources in the headwaters of the Blair Gap Run and Bradley Run watersheds at the ALPO Summit area during 2014–16. These new baseline data fill an existing gap in knowledge and may be helpful to evaluate potential changes in the hydrologic characteristics of streams and associated wetlands at the Summit area. Results of synoptic water-quality surveys and continuous stage records at two streamgages near the headwaters of Blair Gap Run and Bradley Run indicate that the headwater streams of the ALPO Summit area are perennial but have different water-quality characteristics. The water sampled in the headwaters of Blair Gap Run had pH that ranged from acidic to near neutral, combined with elevated concentrations of dissolved solids, mainly sulfate, chloride, and sodium. These characteristics can be attributed to drainage from legacy coal mines and runoff from nearby roads treated with deicing salt. More than once during the study, the chloride and associated contaminant concentrations in tributaries of Blair Gap Run exceeded chronic thresholds for protection of freshwater aquatic organisms. In contrast, the water quality at tributaries of Bradley Run in the Summit area was characterized by near-neutral pH and relatively low concentrations of dissolved constituents, which met criteria for protection of freshwater aquatic life. By comparison, the deep groundwater discharged as abandoned mine drainage to Sugar Run from the Argyle Stone Bridge Mine, which underlies the Summit area, had acidic pH and elevated concentrations of sulfate and metals, which exceeded chronic and acute thresholds for aquatic life. Data on shallow groundwater levels in piezometers at two wetlands in the Summit area, which were monitored during spring through fall of 2016, indicate downward hydraulic gradients (higher water level in shallow piezometer than in deeper piezometer) and potential for local groundwater recharge during rainfall events, particularly in the summer and fall seasons. The wetlands in the upland area (wetland 3, at altitude 2,370 feet NAVD 88) near the divide between Blair Gap Run and Bradley Run between the Lemon House and Picnic Area, exhibited a consistent downward gradient from spring through fall of 2016. The associated surface seepage at wetland 3 dried up in the summer of 2016. In contrast, the wetlands in the adjoining valley (wetland 6, at altitude 2,198 feet NAVD 88) in the northwestern Summit area exhibited upward hydraulic gradients in the spring and produced continuous seepage. Despite downward gradients during summer and fall, the seepage associated with wetland 6 sustained perennial conditions in the Bradley Run drainage through the summer of 2016. Differences in groundwater altitudes and associated water quality among the surface water, shallow groundwater, and deep groundwater in the Summit area imply that the surface water and shallow groundwater in the Summit area could recharge the groundwater of the underlying coal mines. Seasonally upward and downward vertical gradients in the near-surface soil and bedrock at wetland 6, and unimpaired water quality in the Bradley Run headwaters, are consistent with a perched water table and local hydrology that is influenced by local recharge. Persistent downward gradients and impaired water quality at wetland 3 and the adjacent headwaters seeps and tributaries of Blair Gap Run could be attributed to subsidence and drainage from shallow coalbeds (Upper Freeport, seam E) and associated mine workings in that area; however, the underlying deep coal mine pool (Lower Kittanning, seam B), which is hundreds of feet below the surface, does not appear to affect the hydrologic characteristics of the headwater streams and wetlands in the Summit area.

Pennsylvania↗

USGS2007

Reconnaissance of arsenic concentrations in ground water from bedrock and unconsolidated aquifers in eight northern-tier counties of Pennsylvania

Samples of ground water for analysis of total-arsenic concentrations were collected in eight counties--Potter, Tioga, Bradford, Susquehanna, Wayne, Pike, Sullivan, and Wyoming--and from eight bedrock formations (bedrock aquifers) and overlying glacial aquifers in the north-central and northeastern parts of Pennsylvania in July 2005 and from March through June 2006. The samples were collected from a total of 143 domestic wells, 2 stock wells, 4 non-community wells, 2 community water-system wells, and 3 domestic springs by well or spring owners using sampling kits provided by the U.S. Geological Survey (USGS). An additional 15 domestic wells were sampled by the USGS for analysis of total arsenic. These 15 samples were collected using the same methods and sampling kits provided to the homeowners. Samples were analyzed for total arsenic by the Pennsylvania Department of Environmental Protection Laboratory using a minimum reporting level of 4.0 µg/L (micrograms per liter). Arsenic was detected in water from 18 domestic wells in four counties--Bradford (3 wells), Sullivan (1 well), Tioga (13 wells), and Wayne (1 well). The median concentration of total arsenic was less than 4.0 µg/L, and the maximum concentration was 188 µg/L. Water from 10 wells had concentrations of total arsenic greater than the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 µg/L. Detectable concentrations of total arsenic were measured in water from wells that ranged in depth from 29 to 400 feet, and that were completed in three aquifers--Lock Haven Formation, Catskill Formation, and unconsolidated glacial sediments; no springs had detectable concentrations of total arsenic. Water samples representing the Lock Haven Formation were collected from 60 wells; water from 12 of these wells had detectable concentrations of total arsenic. Water samples representing the Catskill Formation were collected from 57 wells; water from 4 wells had detectable concentrations of total arsenic. Water samples representing the unconsolidated glacial sediments were collected from 17 wells; 2 wells had water with detectable concentrations of total arsenic. Contingency tables tested for significant differences in total arsenic between aquifers, topographic settings, and well depths. Concentrations of total arsenic were significantly greater (95-percent confidence level) in the Lock Haven Formation than in the other bedrock units. Concentrations of total arsenic also varied significantly by topographic setting. Wells completed in the Lock Haven Formation and located in valleys had significantly greater concentrations of total arsenic than similar wells located on hilltops or slopes. Concentrations of total arsenic did not vary significantly by topographic setting in the Catskill Formation. Concentrations of total arsenic did not vary significantly by well depth for any aquifer. Iron staining, hydrogen-sulfide odor, or both were common complaints of well owners. Iron staining was a complaint of 44 well owners. Hydrogen-sulfide odor was a complaint of 35 well owners. Fourteen well owners complained of both iron staining and hydrogen sulfide. No correlation to the presence of arsenic in the wells sampled was found with iron staining, hydrogen-sulfide odor, or both. Water from 8 of the 10 wells that contained concentrations of total arsenic greater than 10 µg/L were sampled by USGS personnel for the determination of concentrations of dissolved arsenic (minimum reporting level 0.3 µg/L) and arsenic species {arsenite [As (III)], arsenate [As (V)], monomethylarsonate (MMA), and dimethylarsinate (DMA)} at the USGS National Water Quality Laboratory. Analytical results from these samples showed a median concentration of 38.7 µg/L dissolved arsenic in water and a maximum of 178 µg/L. As (III) was the most common arsenic species present in the water for seven of the eight wells and was found in water characteristic of reducing environments [pH 8.2 to 9.1, dissolved oxygen 0.06 to 0.29 milligrams per liter (mg/L), and oxidation reduction potential -63 to -203 millivolts (mv)]. As (V) was the dominant arsenic species in water characteristic of an oxidizing environment (pH 4.8, dissolved oxygen 2.15 mg/L, oxidation reduction potential 265 mv). The arsenic species MMA and DMA were detected in the water from two wells. The arsenic species MMA was detected at an estimated concentration of 0.9 µg/L in water from one well; the concentration was less than 1.2 µg/L in water from seven wells. The arsenic species DMA was detected at concentrations of 1.0 and 1.5 µg/L in water from two wells; the concentration was less than 0.6 µg/L in water from six wells. Both wells that contained detectable concentrations of MMA and DMA produced water that was characteristic of reducing environments.

Pennsylvania↗

USGS2015

Geohydrologic and water-quality characterization of a fractured-bedrock test hole in an area of Marcellus shale gas development, Tioga County, Pennsylvania

An integrated analysis of core, geophysical logs, gas isotopes, and specific-depth water-quality samples from the Cherry Flats test hole was used to characterize the stratigraphy, water-bearing zones, and groundwater quality at a site in southern Tioga County, Pennsylvania. The study was completed as a cooperative effort between the Pennsylvania Department of Natural Resources, Bureau of Topographic and Geologic Survey (BTGS) and the U.S. Geological Survey (USGS). The multi-disciplinary characterization of the test hole provided information to aid the bedrock mapping of the Cherry Flats 7.5-minute quadrangle by BTGS, and to help quantify the depth and character of fresh and saline groundwater in an area of shale-gas exploration. The Cherry Flats test hole was cored to a depth of 1,513 feet (ft) below land surface (bls) and cased to 189 ft through the collapsed mine workings of the former Arnot No. 2 underground coal mine. The test hole penetrated 128.0 ft of Allegheny Formation and 154.1 ft of Pottsville Formation of Pennsylvanian age, 564.8 ft of Huntley Mountain Formation of Mississippian and Devonian age, and 666.3 ft of Catskill Formation of Devonian age. Core recovery was nearly 100 percent, except where complete core loss occurred from a depth of 1,231.1 to 1,240.8 ft. Several coal beds and mined-out coal horizons were penetrated in the Allegheny and Pottsville Formations. The test hole penetrated the entire thickness of the Huntley Mountain Formation and was completed in the middle part of the Catskill Formation. Bedding features penetrated by the test hole were estimated to have a strike of 021 degrees and dip about 1.7 degrees to the southeast, consistent with the test-hole location on the north limb of the Blossburg syncline. Most fractures penetrated by the test hole were parallel to bedding, with steeply dipping fractures present but much less common. Fracture density, determined from optical televiewer, acoustic televiewer, and video logs, generally increased with depth from the base of casing to about 400 ft bls, then decreased with depth to the bottom of the hole except for an increase from 506 to 568 ft bls. Very few fractures were penetrated from 600 to 850 ft. The depths of fresh and saline water-bearing zones were identified in the test hole by geophysical-log analysis and, for inflow zones, verified by specific-depth groundwater sampling by the use of a wire-line point sampler. Under ambient conditions and during pumping of the test hole, fresh water entered the hole from fractures at 567 and 580.5 ft bls, within grayish-red siltstone and greenish-gray sandstone, respectively, and flowed upward and exited at fractures from 303 to 319.5 ft; a very minor amount exited into fractures within coal beds at 240.4 and 252 ft bls. Transmissivity, estimated from analysis of the specific-capacity data and flowmeter logs, was about 18 ft2/d for the fracture zones from 567 to 580.5 ft and 6.7 ft2/d for fracture zones from 240.4 to 252 ft bls. The analysis estimated the hydraulic head of the lower zone and that of the upper flow zone was 8 ft higher and 37 ft lower than the composite water level in the test hole, respectively. Water samples of the freshwater inflow from zones at 567 to 580.5 ft bls had a total dissolved solids concentration of 577 mg/L indicating that these zone are in the lower part of the active groundwater flow system. Below the freshwater-bearing zone at 580.5 ft, the flowmeter did not detect any vertical flow in the test hole, and the gradient of the temperature log approached the geothermal gradient, indicating little ambient fluid flow and minimal fracture transmissivity below this depth. However, small seeps of saline water having total dissolved solids concentrations of greater than about 6,200 mg/L at 945 and 946 ft bls, from dark-greenish-gray to greenish-gray silty beds, were delineated by a time series of specific conductancelogs and observed on the video log. A wat

Pennsylvania↗

USGS2016

Physical, chemical, and biological characteristics of selected headwater streams along the Allegheny Front, Blair County, Pennsylvania, July 2011–September 2013

The Altoona Water Authority (AWA) obtains all of its water supply from headwater streams that drain western Blair County, an area underlain in part by black shale of the Marcellus Formation. Development of the shale-gas reservoirs will require new access roads, stream crossing, drill-pad construction, and pipeline installation, activities that have the potential to alter existing stream channel morphology, increase runoff and sediment supply, alter streamwater chemistry, and affect aquatic habitat. The U.S. Geological Survey, in cooperation with Altoona Water Authority and Blair County Conservation District, investigated the water quality of 12 headwater streams and biotic health of 10 headwater streams. Channel morphology was characterized at 10 of 12 stream sites using 500-foot (minimum) longitudinal profiles, four cross-sections each, and pebble counts. Channel slopes ranged from 0.008 in Poplar Run near Newry to 0.045 in Mill Run. In general, streams draining watersheds of 5 square miles or less and at higher elevation had the steepest slopes. On the basis of the median particle size, determined during pebble counts, the streambed substrate can be characterized as cobble (Mill Run, Bells Gap Run, Tipton Run, and Sink Run), a mix of gravel and cobble (South Poplar Run, Dry Gap Run, Glenwhite Run, Sugar Run, Blair Gap Run), and gravel (Poplar Run, Newry). Daily mean values of gage height were determined, and continuous (30-minute interval) data consisting of specific conductance and water temperature were collected, at four sites; each site showed typical seasonal fluctuations and the effects of precipitation. Streamflow affected discrete water-quality. Dissolved oxygen always increased with increased streamflow. Most cations (including barium and strontium), along with pH, specific conductance, and total dissolved solids, decreased with greater streamflow, reflecting the dilution effect of moderately acidic surface runoff and precipitation on groundwater discharge (base flow) into the stream channels. Concentrations of trace elements varied by constituent and streamflow. On the basis of the results of water-quality analyses for the selected constituents, the water quality in 9 of the 12 streams can be considered fair or attaining with no measured constituent exceeding a U.S. Environmental Protection Agency maximum or secondary contaminant level. Abandoned mine drainage (AMD) affects Glenwhite Run, Blair Gap Run, and Sugar Run. For Sugar Run, the AMD is reflected in the elevated iron concentration (greater than 300 micrograms per liter). Manganese concentrations greater than 50 micrograms per liter were measured in Glenwhite Run, Sugar Run, and Blair Gap Run. A mixing curve based upon chloride/bromide ratios for two end points—precipitation and deicing salts—indicate that deicing salt is migrating to the streams. A similar curve representative of late-emerging flowback water from Marcellus gas wells indicated that the surface-water samples had not been influenced by such brines. On the basis of the concentration of major ions, the streams in the study area generally had mixed cation and anion compositions. Calcium is the dominant cation in one stream. Carbonate and bicarbonate are the dominant anions for two streams, and sulfate is dominant in three streams. The remaining six streams do not have a dominant ion. Biotic health was characterized at 10 of 12 stream sites; the two sites excluded were established late in the study period (May 2013) for refinement of water quality in the headwaters of Poplar Run and the location of Marcellus Formation gas wells. On the basis of the Maryland Index of Biotic Integrity (MdIBI) for fish assemblages, 8 of 10 streams can be considered in fair health. Tipton Run had the highest MdIBI score (3.75) and the greatest number of native species. South Poplar Run had the lowest MdIBI score (1.75); pollution tolerant blacknose dace was dominant. On the basis of the Pennsylvania Department of Environmental Protection macroinvertebrate index of biotic integrity, 9 of 10 streams were characterized as attaining, with scores as high as 88.9 at Tipton Run. Only Sugar Run was characterized as impaired, with a score of 40.4.

Pennsylvania↗

USGS2014

Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013

Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled. Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories. The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6 wells; 5 of these 6 water samples had a pH greater than 7.7. Concentrations of dissolved methane ranged from less than 0.00006 to 3.3 mg/L. Methane was detectable in 22 of the 34 wells sampled (65 percent). Methane concentrations were greatest in the 5 samples with pH of 7.8 or higher, ranging from 0.040 to 3.3 mg/L. These samples also had among the lowest concentrations of dissolved oxygen. Three water samples, which had sufficient dissolved methane concentrations (greater than 0.9 mg/L), were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell within (two samples) or close to (one sample) the range for a thermogenic natural gas source. The total dissolved solids concentration ranged from 33 to 346 mg/L; the median concentration was 126 mg/L. Sodium concentrations ranged from 1.07 to 116 mg/L; the median concentration was 9.42 mg/L. The sodium concentration exceeded the USEPA health advisory for sodium of 20 mg/L in water samples from 7 of the 34 wells (21 percent). Concentrations of dissolved arsenic ranged from less than 0.06 to 21.8 micrograms per liter (µg/L); the median concentration was 0.59 µg/L. Water samples from 2 of the 34 wells (6 percent) exceeded the USEPA maximum contaminant level (MCL) of 10 µg/L for arsenic. Concentrations of dissolved manganese ranged from less than 0.15 to 61.5 µg/L; the median concentration was 0.42 µg/L. A water sample from 1 of the 34 wells (3 percent) exceeded the USEPA SMCL of 50 µg/L for manganese; the concentration was less than the USEPA lifetime health advisory of 300 µg/L for manganese. Activities of radon-222 in water from the 34 sampled wells ranged from 110 to 7,180 picocuries per liter (pCi/L); the median activity was 2,105 pCi/L. Water samples from 33 of the 34 wells (97 percent) exceeded the proposed USEPA MCL of 300 pCi/L, and 4 water samples (12 percent) exceeded the USEPA proposed alternative MCL of 4,000 pCi/L for radon-222. Differences in groundwater chemistry were related to pH. Water with a pH greater than 7.6 generally had low dissolved oxygen concentrations, indicating reducing conditions in the aquifer. These high pH waters also had relatively elevated concentrations of methane, arsenic, boron, bromide, fluoride, lithium, and sodium but low concentrations of copper, nickel, and zinc. Water samples with a pH greater than 7.8 had methane concentrations equal to or greater than 0.04 mg/L.

Pennsylvania↗

USGS2019

Baseline environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2016

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) facility in 2016. The ARMD Facility was designed to centralize rocket motor destruction and contain or capture all waste during the destruction process. Ideally, there would be no contaminant transport to air, soil, or water from the facility, but the Code of Federal Regulations requires that any hazardous waste disposal facility have an environmental monitoring program in place. In a study by the U.S. Geological Survey, in cooperation with the Letterkenny Army Depot, baseline characterization of constituents in groundwater, surface water, and soil was conducted from September to December 2016 to document site conditions prior to the beginning of operations at the facility in January 2017. Groundwater wells, surface water, and soils were sampled monthly during the baseline characterization period. No sediment transport from the site occurred on days when samples were collected from surface-water sites, so no sediment was collected from the retention basin at the facility during the baseline period. Data collected during the baseline period can be compared to data collected in future years to determine whether there is any contaminant transport from the ARMD Facility to the surrounding environment. During the baseline characterization period, monthly samples were collected from 4 groundwater wells and 9 soil sites near the ARMD Facility. The only surface-water site sampled monthly during the baseline period was upgradient from the facility. There was no streamflow at surface-water sites downgradient from the facility on days when surface-water samples were collected during the baseline characterization period. Groundwater results for the four wells sampled near the ARMD Facility during the baseline period did not show any major water-quality issues. Mean specific conductance (SC) and pH in groundwater ranged from 220 to 771 microsiemens per centimeter at 25 degrees Celsius (μS/cm) and 6.45 to 6.98, respectively. No constituents in groundwater samples exceeded any U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL). Dissolved iron (Fe) was the only groundwater constituent that exceeded a Secondary Maximum Contaminant Level (SMCL) established by the EPA. The SMCL for Fe is 300 micrograms per liter (μg/L); samples from three wells had mean dissolved Fe concentrations ranging from 1,100 to 2,600 μg/L. The only volatile organic compounds (VOCs) detected in groundwater samples were bromomethane, acetone, and chloromethane. All VOC detections in groundwater samples were less than the Reporting Detection Levels (RDLs). These three compounds also were detected in blank samples submitted for groundwater samples. Perchlorate was not detected in any groundwater sample collected during the baseline period. Surface-water data collected during the baseline period were strictly representative of a stream reach upgradient from the ARMD Facility. Stream discharge ranged from 0.03 to 0.08 cubic feet per second during sample collection. The mean SC and pH were 310 μS/cm and 7.6, respectively. No EPA established MCLs or SMCLs were exceeded for any constituents in samples collected from this upgradient stream. Some VOCs were detected in surface water at less than the RDLs. The VOCs detected in surface water were generally the same VOCs as those detected at less than the RDLs for groundwater. Perchlorate was detected in each sample collected from the stream; the mean concentration was 0.07 μg/L. All perchlorate results were less than the RDL of 0.2 μg/L. Soil samples collected during the baseline period did not have any constituent concentrations that exceeded any medium-specific concentrations (MSC) or soil screening levels (SSL) established by either the Commonwealth of Pennsylvania or the EPA. The Commonwealth of Pennsylvania calculates MSCs based on either a function of acceptable concentrations in groundwater or based on health concerns if the soil is directly contacted. The EPA derives acceptable concentrations of constituents (SSLs) in soil based on standardized equations combining exposure information assumptions with EPA toxicity data. The EPA calculates SSLs for residential and industrial sites. Soil sites at the ARMD Facility were considered “industrial” for comparative purposes. There was at least one order of magnitude difference between any inorganic constituent concentration detected in soil and the MSC and (or) SSL for that constituent. Four VOCs were detected in soil samples collected during the baseline period. None of the VOCs detected in the soils were within three orders of magnitude of any established MSCs or SSLs. The VOCs detected in soil were dichloromethane (also known as methylene chloride), methyl tert-butyl ether (MTBE), tetrachloroethene, and acetone (only detected once). Dichloromethane was the only VOC detected at greater than the RDLs; concentrations in all soil samples were greater than the RDLs. Dichloromethane concentrations ranged from 1.9 to 50.1 micrograms per kilogram (μg/kg). MTBE was detected in 50 percent of samples collected but all results were less than the RDLs of 1.7 to 2.6 μg/kg. Tetrachloroethene was detected in 20 percent of soil samples collected, with a maximum estimated value of 1.5 μg/kg. Inorganic constituents with the highest concentrations in soil were Fe and aluminum (Al); mean Fe and Al concentrations ranged from 28,700 to 52,400 and 10,300 to 19,800 milligrams per kilogram (mg/kg), respectively. Data collected during the baseline period in 2016 can be compared to future data to determine whether concentrations in water and soils surrounding the facility have shown any changes that could be caused by the facility operation.

Pennsylvania↗

USGS2012

Streamflow and water-quality monitoring in response to young-of-year smallmouth bass ( micropterus dolomieu ) mortality in the Susquehanna River and major tributaries, with comparisons to the Delaware and Allegheny Rivers, Pennsylvania, 2008-10

Since 2005, spring hatched young-of-year (YOY) smallmouth bass in Pennsylvania reaches of the Susquehanna River have experienced above-normal mortality when summertime streamflows are near or lower than normal. Stress factors include, but are not limited to, low dissolved oxygen and elevated water temperatures during times critical for survival and development (critical period is May 1 through July 31). At this time (2010), widespread disease and mortality are believed to be more prevalent for YOY smallmouth bass in the Susquehanna River Basin than in the Delaware or Allegheny River Basins. The U.S. Geological Survey began a study in 2008 to investigate water temperature and dissolved oxygen as possible stressors to the YOY smallmouth bass. Monitoring began in 2008 and continued in 2009 and 2010 in selected reaches. Continuous (30-minute intervals) measurements of dissolved oxygen, water temperature, pH, and specific conductance were made during all or parts of the study at stations including, but not limited to, the Delaware River at Trenton, N.J. (station C1), Susquehanna River at Clemson Island (station C4), Juniata River at Newport, Pa. (station C5), Juniata River at Howe Township Park (station C6), Susquehanna River at Harrisburg, Pa. (station C8), and Allegheny River at Acmetonia, Pa. (station C10). At stations C1, C5, and C8, streamflow data also were collected. Streamflow data were not collected at stations C4, C6, and C10; therefore, data from nearby streamgages on the Susquehanna River at Sunbury, Pa. (station N8), the Juniata River at Newport, Pa (station C5), and the Allegheny River at Natrona, Pa. (station C9), were used to represent flow conditions at these stations. Streamflow during the critical period of each year influenced dissolved-oxygen concentrations and water temperature, and was associated with the incidence of disease in YOY smallmouth bass. During the critical period of 2009, station C8 had a median daily streamflow of 26,300 cubic feet per second (ft 3 /s), approximately two times higher than for the critical periods in 2008 and 2010. Diseased YOY smallmouth bass were captured at only 3 sites in 2009 but 19 sites in 2008 and 28 sites in 2010. During relatively low streamflow in the critical periods of 2008 and 2010, dissolved-oxygen concentrations also were lower (more stressful to aquatic life) than in 2009. During the critical period, median daily minimum dissolved-oxygen concentrations in main-channel habitat of the Susquehanna River at station C8 were lower in 2008 and 2010 by 1.2 milligrams per liter (mg/L) and 1.5 mg/L, respectively, in comparison to the median daily minimum concentrations in 2009. Despite the year-to-year differences in dissolved oxygen, results of a comparison of data for station C8 from each year of the study period with historical data from 1974–79 indicate daily minimum dissolved-oxygen concentrations in all 3 years of the study were significantly lower than those from the historical dataset (p-values less than 0.05). Although lower streamflows for critical periods of 2008–10 may help explain statistical differences in dissolved oxygen between the two time periods, other factors such as long-term streamwater warming trends also may play a role. Median daily minimum dissolved-oxygen concentration in the microhabitat of the Susquehanna River at Clemson Island (station C4) was 1.6 mg/L lower in 2008 than 2009. No data were collected at station C4 in 2010. For the microhabitat of the Juniata River near Howe Township Park (station C6), median daily minimum dissolved-oxygen concentrations were about 0.6 mg/L lower in 2008 than in 2010. At station C6, no data were collected in 2009. Nighttime concentrations of dissolved oxygen in microhabitats at stations C4 and C6 were at times lower than the 5.0-mg/L criterion established by the U.S. Environmental Protection Agency for early life stages of warm-water fish. The most frequent occurrence of dissolved oxygen less than 5.0 mg/L was at station C4 (31 of 92 days in the critical period of 2008). The longest duration that dissolved oxygen was lower than 5.0 mg/L was 8.5 hours (station C4; 23:30 on June 10, 2008, to 08:00 on June 11, 2008). Median daily maximum water temperatures in the main channel of the Susquehanna River at station C8 were 4.0 degrees Celsius (°C) higher in 2008 and 4.3°C warmer in 2010 than in 2009 during the critical periods. At station C8, the water temperatures during the critical periods of all 3 years were significantly warmer (p-values <0.05) than during the critical periods of 1974–79. Year-to-year water-temperature differences in the main-channel habitat of the Juniata River at station C5 were slightly less than year-to-year differences in the Susquehanna River at station C8. During the critical periods, the water temperature at station C5 was 3.5°C warmer in 2008 and 3.3°C warmer in 2010 than in 2009. These results are consistent with warming trends documented in other streams of the northeastern United States with much more robust water-temperature datasets. For the critical period of each year, dissolved oxygen in the Susquehanna River at station C8 typically was 1.5 to 3.0 mg/L lower than in the Delaware River at station C1 and the Allegheny River at station C10. Median daily maximum water temperatures during the critical period of each year ranged from 1.6 to 2.7°C warmer at station C8 than at stations C1 and C10.

Pennsylvania↗

USGS2000

Hydrogeology and simulation of ground-water flow at the Gettysburg Elevator Plant Superfund Site, Adams County, Pennsylvania

Ground water in Triassic-age sedimentary fractured-rock aquifers in the area of Gettysburg, Pa., is used as drinking water and for industrial and commercial supply. In 1983, ground water at the Gettysburg Elevator Plant was found by the Pennsylvania Department of Environmental Resources to be contaminated with trichloroethene, 1,1,1-trichloroethane, and other synthetic organic compounds. As part of the U.S. Environmental Protection Agency?s Comprehensive Environmental Response, Compensation, and Liability Act, 1980 process, a Remedial Investigation was completed in July 1991, a method of site remediation was issued in the Record of Decision dated June 1992, and a Final Design Report was completed in May 1997. In cooperation with the U.S. Environmental Protection Agency in the hydrogeologic assessment of the site remediation, the U.S. Geological Survey began a study in 1997 to determine the effects of the onsite and offsite extraction wells on ground-water flow and contaminant migration from the Gettysburg Elevator Plant. This determination is based on hydrologic and geophysical data collected from 1991 to 1998 and on results of numerical model simulations of the local ground-water flow-system. The Gettysburg Elevator Site is underlain by red, green, gray, and black shales of the Heidlersburg Member of the Gettysburg Formation. Correlation of natural-gamma logs indicates the sedimentary rock strike about N. 23 degrees E. and dip about 23 degrees NW. Depth to bedrock onsite commonly is about 6 feet but offsite may be as deep as 40 feet. The ground-water system consists of two zones?a thin, shallow zone composed of soil, clay, and highly weathered bedrock and a thicker, nonweathered or fractured bedrock zone. The shallow zone overlies the bedrock zone and truncates the dipping beds parallel to land surface. Diabase dikes are barriers to ground-water flow in the bedrock zone. The ground-water system is generally confined or semi-confined, even at shallow depths. Depth to water can range from flowing at land surface to more than 71 feet below land surface. Potentiometric maps based on measured water levels at the Gettysburg Elevator Plant indicate ground water flows from west to east, towards Rock Creek. Multiple-well aquifer tests indicate the system is heterogeneous and flow is primarily in dipping beds that contain discrete secondary openings separated by less permeable beds. Water levels in wells open to the pumped bed, as projected along the dipping stratigraphy, are drawn down more than water levels in wells not open to the pumped bed. Ground-water flow was simulated for steady-state conditions prior to pumping and long-term average pumping conditions. The three-dimensional numerical flow model (MODFLOW) was calibrated by use of a parameter estimation program (MODFLOWP). Steady-state conditions were assumed for the calibration period of 1996. An effective areal recharge rate of 7 inches was used in model calibration. The calibrated flow model was used to evaluate the effectiveness of the current onsite and offsite extraction well system. The simulation results generally indicate that the extraction system effectively captures much of the ground-water recharge at the Gettysburg Elevator Plant and, hence, contaminated ground-water migrating from the site. Some of the extraction wells pump at low rates and have very small contributing areas. Results indicate some areal recharge onsite will move to offsite extraction wells.

Pennsylvania↗

USGS2009

National assessment of historical shoreline change: a pilot study of historical coastal bluff retreat in the Great Lakes, Erie, Pennsylvania

Coastal bluff retreat is a chronic problem along many high-relief coastlines in the United States. As coastal populations continue to grow and community infrastructures are threatened by erosion, there is increased demand for accurate information regard-ing trends and rates of bluff retreat. There is also a need for a comprehensive analysis that is consistent from one coastal region to another. To address these national needs, the U.S. Geological Survey (USGS), as part of the National Assessment of Coastal Change Hazards Project, conducted a pilot study of bluff retreat along the Lake Erie, Pa., coastline to assess the feasibility of undertaking a larger, multi-state analysis in the Great Lakes region. This report provides an overview of the pilot-study location and bluff geomorphology, the data sources and methodology, results of the analysis, and a discussion of the feasibility of undertaking a similar analysis along eroding bluffs in other Great Lakes states. This pilot study is part of an ongoing effort by the USGS to provide a comprehensive analysis of historical shoreline change and cliff and bluff retreat along open-ocean coastlines of the conterminous United States and parts of Hawaii, Alaska, and the Great Lakes. One purpose of the work is to develop standard, repeatable methods for mapping and analyzing coastal change so that systematic and consistent periodic updates of coastal erosion can be made nationally. Bluff-retreat evaluations are conducted by comparing the location of a historical bluff edge digitized from aerial photographs with those of recent bluff edges interpreted from both aerial photographs and lidar topographic surveys. The historical bluff edge is from 1938, whereas the more recent bluff edges are from 1998 and 2006 lidar data. Long-term (68-year) rates of retreat are calculated using the available bluff-edge data. The rates of retreat presented in this report represent conditions from the 1930s to 1998/2006, and are not intended for predicting future bluff-edge positions or rates of retreat. The report presents bluff-retreat rates for 32 km of a 60-km stretch along the Lake Erie, Pa., coastline. Data are discontinuous due to gaps in source data and lack of continuous bluffs. The average rate of coastal bluff retreat for the Lake Erie, Pa., bluffs was -0.3 +- 0.1 m/yr (retreat rates are presented as negative numbers in this report), based on rates averaged from 1,595 individual transects. Retreat rates generally were lowest where bedrock outcrops are exposed as the basal unit in the bluff. The highest rates are associated with anthropogenic activities, including jetties that trap littoral sediment, depleting a source of material for the natural replenishment of protective beaches downcoast, and extensive irrigation of farmlands on the tops of the bluffs, which can destabilize bluffs by enhancing ground-water outflow.

Pennsylvania↗

USGS2018

Preliminary geologic framework developed for a proposed environmental monitoring study of a deep, unconventional Marcellus Shale drill site, Washington County, Pennsylvania

Background In the fall of 2011, the U.S. Geological Survey (USGS) was afforded an opportunity to participate in an environmental monitoring study of the potential impacts of a deep, unconventional Marcellus Shale hydraulic fracturing site. The drill site of the prospective case study is the “Range Resources MCC Partners L.P. Units 1-5H” location (also referred to as the “RR–MCC” drill site), located in Washington County, southwestern Pennsylvania. Specifically, the USGS was approached to provide a geologic framework that would (1) provide geologic parameters for the proposed area of a localized groundwater circulation model, and (2) provide potential information for the siting of both shallow and deep groundwater monitoring wells located near the drill pad and the deviated drill legs. The lead organization of the prospective case study of the RR–MCC drill site was the Groundwater and Ecosystems Restoration Division (GWERD) of the U.S. Environmental Protection Agency. Aside from the USGS, additional partners/participants were to include the Department of Energy, the Pennsylvania Geological Survey, the Pennsylvania Department of Environmental Protection, and the developer Range Resources LLC. During the initial cooperative phase, GWERD, with input from the participating agencies, drafted a Quality Assurance Project Plan (QAPP) that proposed much of the objectives, tasks, sampling and analytical procedures, and documentation of results. Later in 2012, the proposed cooperative agreement between the aforementioned partners and the associated land owners for a monitoring program at the drill site was not executed. Therefore, the prospective case study of the RR–MCC site was terminated and no installation of groundwater monitoring wells nor the collection of nearby soil, stream sediment, and surface-water samples were made. Prior to the completion of the QAPP and termination of the perspective case study the geologic framework was rapidly conducted and nearly completed. This was done for three principal reasons. First, there was an immediate need to know the distribution of the relatively undisturbed surface to near-surface bedrock geology and unconsolidated materials for the collection of baseline surface data prior to drill site development (drill pad access road, drill pad leveling) and later during monitoring associated with well drilling, well development, and well production. Second, it was necessary to know the bedrock geology to support the siting of: (1) multiple shallow groundwater monitoring wells (possibly as many as four) surrounding and located immediately adjacent to the drill pad, and (2) deep groundwater monitoring wells (possibly two) located at distance from the drill pad with one possibly being sited along one of the deviated production drill legs. Lastly, the framework geology would provide the lateral extent, thickness, lithology, and expected discontinuities of geologic units (to be parsed or grouped as hydrostratigraphic units) and regional structure trends as inputs into the groundwater model. This report provides the methodology of geologic data accumulation and aggregation, and its integration into a geographic information system (GIS) based program. The GIS program will allow multiple data to be exported in various formats (shapefiles [.shp], database files [.dbf], and Keyhole Markup Language files [.KML]) for use in surface and subsurface geologic site characterization, for sampling strategies, and for inputs for groundwater modeling.

Pennsylvania↗

USGS2019

Evaluating legacy effects of hyperabundant white-tailed deer (Odocoileus virginianus) in forested stands of Harriman and Bear Mountain State Parks, New York

Executive Summary White-tailed deer (Odocoileus virginianus) are among the most impactful herbivores in the eastern United States. Legacy forest effects, those accrued from intense herbivory over time, manifest as low seedling regeneration, high cover of plant species that are infrequently browsed by deer, presence or expansion of nonnative or invasive plant species, few herbaceous species, and diminished capacity for recovery. Interfering vegetation (that is, species that increase in cover and density due to avoidance by deer, such as American beech sprouts, Pennsylvania sedge, and hay-scented fern) increase competition for light and hinder recruitment of trees into the forest canopy. The lower Hudson Valley in New York has been heavily browsed by white-tailed deer since the early 20th century. The region has some of the lowest tree regeneration rates in New York State as a result of deer browsing and subsequent increases in interfering vegetation. The U.S. Geological Survey and the State University of New York College of Environmental Science and Forestry studied sites where deer hunting is permitted (case sites) and nearby sites where hunting is currently prohibited (control sites) to assess and identify forest structure and composition differences. Instead of using deer exclosures, which are time-consuming and expensive to install and maintain, we used a case-control study because such studies are well-suited to effects with long latency and rare outcomes. Case-control studies seek to describe the relation between an outcome of interest (in this study, forest understory recovery from chronic herbivory) and forest condition. We inferred recovery by comparing these characteristics on adjacent sites in the lower Hudson Valley with similar forest communities and land uses but different deer population management histories. Case plots were on lands where deer management has taken place annually for several decades. Control plots were on lands where deer populations have not been consistently managed to lowered abundance. We accounted for differences in forest recovery not attributable to deer by first matching case and control plots along several important environmental gradients (slope, aspect, elevation, moisture, canopy openness). By controlling for these gradients, we looked for associations between measured forest conditions and deer herbivory reduction through population management. We surveyed more than 200 plots in upland forest types across case and control sites where we assessed forest condition by estimating density (number per unit area) and composition and cover (percent) of important vegetation constituents in ground, shrub, subcanopy, and canopy layers of the forest. We recorded 37 tree species, 22 shrub species, 57 herbaceous species, and 19 species of grasses and sedges in our plot surveys, including a number of nonnative and invasive plants. We also estimated the ages of a number of common canopy trees by counting rings from cores extracted from individual stems. Effects of more than 100 years of chronic deer browsing manifested in low herbaceous ground cover and little to no tree recruitment (saplings) on lands without deer management. In contrast, sustained deer management resulted in forests with conditions that indicated substantial recovery from chronic herbivory in the ground, shrub, and subcanopy layers. Sites with ongoing deer management exhibited greater ground cover of tree seedlings and herbs and less ground cover of interfering vegetation and nonnative species. The well-developed sub-canopy layer of small trees, saplings, and tall shrubs on sites with deer management indicates a high potential for sapling recruitment to the canopy of the future forest. Of the 25 subcanopy trees sampled on control sites, most were more than 100 years old, indicating little to no regeneration in areas sampled for more than 100 years. The forest canopy, a relic of land uses of bygone days, requires a source of young trees to replace itself as older trees die. Without an abundant layer of young trees in the subcanopy, a forest cannot be sustained over time. Reduction in deer herbivory promotes forest recovery and could benefit Harriman and Bear Mountain State Parks (the control sites for the study), but removal of interfering vegetation may be necessary to mitigate legacy effects where they currently hinder ground layer recovery. To successfully promote a more desirable forest condition that includes elimination of nonnative plant species, promotion of tree recruitment into the forest canopy, and development of diverse and abundant herbaceous cover in ground layer vegetation, future management decisions could include information on herbivory reduction and management of interfering vegetation where necessary.

New York↗

USGS2021

Geophysical and video logs of selected wells at and near the former Naval Air Warfare Center Warminster, Bucks County, Pennsylvania, 2017-19

The U.S. Geological Survey (USGS) collected borehole geophysical and video logs in 17 open-hole wells in Northampton, Warminster, and Warwick Townships, Bucks County, Pennsylvania during 2017–19 to support detailed groundwater investigations at and near the former Naval Air Warfare Center (NAWC) Warminster, where groundwater contamination with per- and polyfluoroalkyl substances (PFAS) had become a concern since 2014. The area is underlain by the Triassic Stockton Formation, which forms a fractured-sedimentary-rock aquifer used for private, industrial, and public drinking-water supply. The geophysical and video logs were used to characterize the boreholes and identify potential water-bearing fractures for subsequent detailed investigations. Of the 17 wells that were logged, subsequent investigations were conducted by USGS in 15 wells and included hydraulic tests of discrete water-bearing zones using a straddle-packer system in 13 wells and depth-discrete point sampling in 2 wells. These 15 wells ranged in depth from about 210 to 604 feet (ft) below land surface (bls) and included six new 6-inch diameter wells drilled to initial depths of 600 ft bls on the former NAWC Warminster base property in 2018 and nine 8- to 12-inch diameter existing former production or unused test wells. Partial geophysical or video logs also were collected by USGS during 2018 in two other wells that were not included in subsequent detailed investigations. Most wells had numerous water-bearing fractures or openings throughout the depth of the open boreholes. Most of these water-bearing features appeared to be openings parallel to bedding or high-angle fractures approximately orthogonal to bedding. Casing lengths ranged from about 19 to 93 ft bls. Depth to the ambient water level at the time of logging ranged from about 1.8 ft above land surface in a flowing well to about 55 ft bls. Measured borehole flow was predominantly downward in most of the deepest wells (greater than 400 ft), which were commonly located at the highest land-surface elevations, and contained inflow from fractures at relatively shallow depths and outflow through fractures near or below depths of 500 ft bls. Borehole flow was predominantly upward in most wells less than 400 ft in depth.

Pennsylvania↗

USGS2024

Results of 2018–19 water-quality and hydraulic characterization of aquifer intervals using packer tests and preliminary geophysical-log correlations for selected boreholes at and near the former Naval Air Warfare Center Warminster, Bucks County, Pennsylvania

The U.S. Geological Survey (USGS) collected data on the vertical distribution of hydraulic head, specific capacity, and water quality using aquifer-interval-isolation tests and other vertical profiling methods in 15 boreholes completed in fractured sedimentary bedrock in Northampton, Warminster, and Warwick Townships, Bucks County, Pennsylvania during 2018–19. This work was done, in cooperation with the U.S. Navy, to support detailed investigations at and near the former Naval Air Warfare Center (NAWC) Warminster, where groundwater contamination with per- and polyfluoroalkyl substances (PFAS) had become a concern since 2014. Two PFAS compounds, perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), have been measured in groundwater samples from supply and monitoring wells at or near NAWC Warminster in concentrations above U.S. Environmental Protection Agency health advisory levels for drinking water. The area is underlain by the Triassic Stockton Formation, which predominantly consists of sandstone interbedded with shale and siltstone beds and forms a layered fractured-rock aquifer used for private, industrial, and public drinking water supply. The vertical distribution of aquifer properties and water quality was assessed through hydraulic tests and sampling of aquifer intervals using a straddle-packer system (13 boreholes) or depth-discrete point sampling under known borehole-flow conditions (2 boreholes). Geophysical and video logs collected by USGS during 2017–19 were used to identify potential water-bearing fractures in 15 boreholes, which ranged in depth from 210 to 604 feet (ft) and included 6 boreholes drilled in 2018 and 9 existing wells on or near the former NAWC Warminster. Measured borehole flow was predominantly downward in most of the deepest boreholes (greater than 400 ft), which were commonly located at the highest land-surface elevations, with inflow from fractures at relatively shallow depths and outflow through fractures near or below depths of 500 ft below land surface. Hydraulic head differences measured during packer tests were up to about 60 ft between shallow and deep intervals. Borehole flow was predominantly upward in most boreholes less than 400 ft in depth and farther from, and at lower land-surface elevations than, the former NAWC Warminster. Total borehole specific capacity ranged from about 0.07 to 41 gallons per minute per foot [(gal/min)/ft]. Specific-capacity values for individual intervals ranged from 0.02 to 40.0 (gal/min)/ft, with a median of 1.14 (gal/min)/ft and a large range in values at most depths. Differences in water quality of samples as indicated by field properties (pH, dissolved oxygen, and specific conductance) and concentrations of dissolved major ions, PFOA, and PFOS were apparent among isolated intervals in the boreholes. Summed concentrations of PFOA and PFOS ranged from about 11 to 10,780 nanograms per liter (ng/L) and were greater than the 2016 U.S. Environmental Protection Agency health advisory of 70 ng/L for summed PFOA and PFOS concentrations in 62 of 104 intervals and discrete depths tested. The mass ratio of PFOS to PFOA was generally higher than 1.0 in samples with summed PFOA and PFOS concentrations greater than 70 ng/L, with ratio values as high as 8.7. In many boreholes, summed concentrations of PFOA and PFOS were positively related to chloride concentrations, which were elevated above natural-background values [less than 10 milligrams per liter] in most samples and as high as 717 milligrams per liter. Sources of the elevated chloride other than, or in addition to, common rock salt (sodium chloride) were indicated by chloride to sodium molar ratios greater than 1.0. Water-quality data indicated that sampled water from some intervals with lower hydraulic heads may be affected by water from intervals with higher hydraulic heads because of vertical flow in open boreholes; samples from these intervals with lower hydraulic heads may not be fully representative due to some component of cross contamination and should be interpreted with caution. Through a preliminary correlation of natural gamma and resistivity logs of boreholes drilled at and near the former NAWC Warminster, 11 lithologic units were identified and interpreted to strike northeast and dip to the northwest. Hydraulic heads were generally highest in isolated intervals that intercepted beds which, when projected up dip, crop out at the highest land-surface elevation on the former NAWC Warminster, indicating that the dipping-bed structure and topography are factors affecting the distribution of hydraulic head in the aquifer. The hydrogeologic framework in conjunction with the vertical distribution of hydraulic heads and water quality may assist in evaluating the locations of various PFAS sources and potential migration pathways of PFAS in groundwater at and near NAWC Warminster.

Pennsylvania↗

USGS2024

Hydrologic investigations and a preliminary conceptual model of the groundwater system at North Penn Area 1 Superfund Site, Souderton, Montgomery County, Pennsylvania

The U.S. Geological Survey (USGS) conducted hydrogeologic investigations, reviewed existing data, and developed a preliminary conceptual model of the groundwater system as part of technical support of the U.S. Environmental Protection Agency (EPA) at the North Penn Area 1 Superfund Site (hereafter, the NP1 Site) located within the Borough of Souderton in Montgomery County, Pennsylvania. Field work and monitoring took place during 2012–18. The area is underlain by sedimentary formations that form a fractured-rock aquifer used for drinking water and industrial supply. The EPA placed the Site on the National Priorities List in 1989, identifying tetrachloroethylene (PCE) and trichloroethylene (TCE) as contaminants of concern. During 2012–18, the USGS conducted field activities that included drilling an 82-foot (ft)-deep monitoring well (MG 2220) in 2016, reconstructing a 208-ft-deep former industrial production well (MG 668 [Granite Knitting Mill]), and collecting borehole geophysical and video logs and water levels from those and five additional wells, which ranged in depth from about 50 to 200 ft below land surface. Continuous water levels were collected during 2014–17, and a synoptic set of water levels were measured in April 2018 in the seven wells. The borehole geophysical logs (caliper, acoustic televiewer, natural gamma, single-point resistance, vertical flow, and fluid temperature and resistivity) and borehole video logs in the seven wells were evaluated to assess potential for lithologic correlation and to identify and describe water-bearing features, which included both low- and high-angle fractures and other openings oriented along dipping bedding planes, joints, or possible faults. Borehole geophysical logs collected by USGS in 1992 in a 300-ft-deep former production well near the Site were also evaluated. Few to no distinctive features were identified on geophysical logs (natural gamma and single-point resistance) that could be used for correlation, thus limiting this approach to determining local geologic structure. Extensive fracturing in the upper 62 ft of monitoring well MG 2220 indicates that the well was likely drilled through a zone of faulting, and other evidence of faulting is present in the area near the Site. Assessment of continuous water levels showed hydraulic connections among some wells as indicated by rising or falling water levels in response to changes in pumping rates at nearby wells. A map of water levels measured in April 2018 indicates potential for groundwater flow generally toward the stream to the south and southwest of the Site, but the limited water-level data are insufficient to describe vertical groundwater gradients or lateral gradients in any detail. Review of 1999–2022 volatile organic compound (VOC) monitoring data collected by the Pennsylvania Department of Environmental Protection for five monitoring wells indicates that the highest groundwater concentrations of PCE and TCE were found in samples from extraction well MG 2201 (S-1) downgradient from, and nearest to, the previously identified Site contaminant source area, and these concentrations fluctuated through time. PCE concentrations were higher than TCE concentrations in samples from all five monitoring wells and were much higher than TCE concentrations in samples from extraction well MG 2201 (S-1). Temporally variable recharge is a possible factor affecting observed fluctuations in PCE concentrations in groundwater samples from well extraction MG 2201 (S-1), as indicated by a general inverse relation between PCE concentrations and water levels in a nearby long-term observation well. The PCE concentration of 1,830 micrograms per liter (μg/L) in a May 2018 water sample from monitoring well MG 2220 was more than four times the PCE concentration of 444 μg/L in a December 2017 sample from the nearby extraction well MG 2201 (S-1), which is open to fewer fractures. Low concentrations of VOCs were measured in surface water at two stream sites downgradient from wells with the highest groundwater VOC concentrations at the Site, indicating that discharge of contaminated groundwater to the stream is likely. Development of a conceptual model of the groundwater system was constrained by limited data. In areas with no pumping, groundwater-flow directions generally are thought to be controlled by topography and geologic structure (bedding orientation) and likely to the south and southwest of the Site, with local flow directions affected by orientations of fractures, joints, and local faults. Additional investigations that could help improve the conceptual model of the groundwater system and help delineate the extent of groundwater contamination and its transport are discussed.

Pennsylvania↗

USGS1995

Surface-water-temperature statistics for streams in New Jersey and vicinity, 1955-93

Monthly Statistical summaries of surface-water temperatures collected at 277 U.S. Geological Survey surface-water sites in New Jersey and adjoining states are tabulated. The study was conducted by the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, to provide temperature data to characterize the condition of streams in and near New Jersey. Of the 277 sites, 259 are in New Jersey, 10 in Pennsylvania, 6 in New York, and 2 in Delaware. The Pennsylvania, New York, and Delaware sites are included because conditions there reflect conditions in New Jersey streams. Most of the temperatures were measured during 1955-93. Measurements were made prior to 1955, but were included only if available in the computer files. Temperature data from 265 periodic, 37 continuous, and 18 daily temperature records were used to compile monthly statistics for each site. The summaries for periodic and daily records include the number of observations; the maximum, minimum, and median temperatures; and the 25th and 75th percentile temperatures. Summaries of continuous records include the maximum, minimum, and median temperatures.

Open-File Report↗

USGS1998

Review of Aquifer Test Results for the Lansdale Area, Montgomery County, Pennsylvania, 1980–95

Aquifer and aquifer-isolation test results in and around North Penn Area 6 Superfund site, Lansdale, Montgomery County, Pennsylvania are reviewed to provide estimated aquifer properties for use in a numerical model of ground-water flow. This review was made to support of remedial action investigations by U.S. Environmental Protection Agency (USEPA), Region III, Philadelphia. The data reviewed are from ﬁles of the U.S. Geological Survey, USEPA, and water companies, and from unpublished consultant reports prepared for USEPA and corporations in the Lansdale area. Tested wells are in fractured sedimentary rocks of the Brunswick Formation, which are Triassic-aged, dipping shales and sandstones. Review procedures include, in some cases, new analyses of drawdown during pumping and recovery by use of analytical models of ﬂow to wells. Estimated aquifer transmissivities (T) range from zero to about 1,300 m 2 /d (meters squared per day); most tests indicate T between 10 and 100 m 2 /d. Aquifer-isolation testing results indicate that most ﬂow enters wells at a few discrete zones, probably fractures or bedding-plane openings. The vertical connection between the zones in a single borehole with multiple producing zones commonly is negligible. This suggests that the formation is vertically anisotropic; the hydraulic conductivity is much larger in the horizontal direction than in the vertical direction. Some evidence of well-ﬁeld-scale horizontal anisotropy exists, with maximum transmissivity aligned with the regional northeast strike of bedding, but this evidence is weak because of the small number of observation wells, particularly wells screened in isolated depth intervals. Analysis of recovery data after constant-pumping-rate aquifer tests and of drawdown during step tests suggests that a signiﬁcant fraction, perhaps as much as 85 percent, of the drawdown in some production wells is due to well loss or skin effects in or very near the pumped well and is not caused by resistance to ﬂow in the surrounding formations.

Pennsylvania↗