Lithochronologic units and mineral deposits of the Appalachian Orogen from Maine to Alabama
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The three-part approach to quantitative mineral resource assessment requires information about the properties of undiscovered mineral deposits in an assessment area. These properties are unknown, so the properties of discovered mineral deposits of the same mineral deposit type are used instead. In the three-part approach, these discovered mineral deposits come from around the world, and their properties constitute the pooled data for that mineral deposit type. Alternatively, these discovered mineral deposits could come from the assessment area, and their properties constitute the tract data for that mineral deposit type. Tract data may be more representative of the undiscovered mineral deposits in the assessment area than the pooled data. The goal of this study was to determine whether resource predictions using pooled data are equivalent to resource predictions using tract data. To this end, 16 previous U.S Geological Survey assessments were studied. For each assessment, resources were predicted for one undiscovered mineral deposit in the assessment area. One set of predictions used pooled data, and another used tract data. The two sets of predictions were compared with an equivalence test, using the six assessment statistics that are commonly reported for mineral resource assessments. Practical equivalence is the condition that two corresponding assessment statistics are within a factor of 1.5 of one another. For each of 2 assessments, all 6 assessment statistics were practically equivalent. For both assessments, the assessment statistics from the pooled data, relative to the corresponding assessment statistics from the tract data, ranged from 1.30 times smaller to 1.03 times larger. For each of 14 assessments, 1 or more of the 6 assessment statistics were not practically equivalent. The assessment statistics from the pooled data, relative to the corresponding assessment statistics from the tract data, ranged from 26.6 times smaller to 5.53 times larger. The use of pooled data has been a standard procedure in the three-part approach since at least 1986. The 16 assessments in this study are not a representative sample of those prior assessments that used pooled data. So, it is inappropriate to use the study results to infer whether pooled data affected the resource predictions for those prior assessments.
The 40 Ar/ 39 Ar geochronology method is used to date potassium-bearing rocks and minerals, based on the decay of 40 K to 40 Ar, which provides important temporal constraints for geological events. The USGS Denver Argon Geochronology Laboratory dates samples from a variety of projects, mainly in the USGS Mineral Resource Program and the National Cooperative Geologic Mapping Program, facilitating in-depth research into the timing of geological events and processes. Recent applications of this method include geochronological studies in the Yellow Pine district, revealing mineralization ages that range from 51 to 70 Ma, and investigations into the Bear Lodge alkaline complex, providing insights into the timing of REE carbonatite formation. Additionally, studies at Alunite Ridge highlight the method's potential for understanding concealed mineral deposits. Ongoing projects continue to leverage 40 Ar/ 39 Ar data to enhance understanding of geologic frameworks and mineral resources, underpinning its importance in modern geochronology and mineral resource assessment.
The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.
The increasing global demand for critical minerals to support energy and technological advancement has accelerated exploration and research efforts for these essential resources. Since 2019, the United States Geological Survey (USGS) Earth Mapping Resources Initiative (EMRI) has worked to modernize geologic mapping of the Nation to better understand its critical mineral resources. To further this initiative, the USGS has flown a series of high-resolution airborne magnetic and radiometric surveys over large areas of the southern Midcontinent. The surveys cover known critical mineral deposits and areas with the potential to host additional critical minerals based on the presence of one or more overlapping mineral systems. One aspect of EMRI emphasizes close collaboration between the USGS and the Association of American State Geologists, as well as other government and industry partners to leverage geophysical, geological, and geochemical expertise on both regional and local scales. The EMRI high-resolution airborne survey data provide new insights into the geophysical framework of the southern Midcontinent and its critical mineral endowment. Additionally, discoveries made from the data have directed new studies for critical mineral exploration.
Recent geopolitical actions regarding the supply of critical minerals have highlighted both the threats posed by countries dominating a critical mineral supply chain, and the potential mitigations served by alternative supplier countries. However, no systematic quantification exists for the intranational factors that determine such threats or mitigations. This study outlines a methodological framework for quantifying the intranational risk profile of critical mineral sectors and compares them with the sector's international potential for leverage. The four intranational factors of concentration, synchronization, private sector involvement, and regulatory obstacles were analyzed across multiple scales in order to determine an intranational risk score that quantifies the resilience or fragility of the critical mineral sector in question. Network analysis was also separately conducted to identify the most important entities operating across all critical mineral sectors. Finally, this study assessed the critical mineral sector's global share of reserves and production to determine an international risk score that quantifies the country's critical mineral sector's leverage potential. A case study of India showed that two critical mineral sectors with high leverage potential, chromite and barite, were respectively intranationally resilient and fragile. Of the remaining sectors with minimal leverage, five sectors such as aluminum were intranationally resilient and may serve as viable mitigation options for future critical mineral supply. Three sectors such as titanium were intranationally fragile, but recent regulatory developments may both decrease intranational risk and increase international risk, potentially making them major critical mineral sectors in the future.
The Intermountain West has a complex geologic history, resulting in the formation of a diverse array of mineral deposits. Effective mineral exploration requires understanding the spatial and temporal relationships among geologic processes and events, a key focus of the mineral systems approach to exploration. This paper presents the Intermountain West Seamless Geologic Map Database, a unified dataset designed to support mineral exploration. Integrating geologic provinces, structural settings, and hydrothermal alteration, the database leverages the Seamless Integrated Geologic Mapping (SIGMa) extension to the USGS Geologic Map Schema (GeMS) to standardize geologic data from varied sources. SIGMa's hierarchical stratigraphic organization and feature-level metadata enhance data interoperability and reusability, enabling seamless query, analysis, and visualization of lithology, structural features, mineral deposits, geochronology, hydrothermal alteration. volcanic activity, and By providing a regionally consistent and dynamically evolving geologic map, this database provides a foundational framework for mineral exploration and geologic research. It also allows for an efficient workflow that expedites the publication of integrated geologic map databases.
A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.
The Philipsburg mining district is a Mo-Cu porphyry system with associated Cordilleran polymetallic veins. Geochronology was employed to date the porphyry (~66 Ma, U/Pb in zircon) and molybdenite mineralization from the veins (~76 Ma, Re-Os). Age results suggest that the two-mineralization events model proposed by Lund et al. (2018) for the Butte district can be applied to the Philipsburg deposit. Furthermore, common fertility indicators from zircon trace elements were analyzed with variable success to characterize the existing Mo-Cu mineralization of the Philipsburg porphyry. This raises concerns about the benefits of this method and/or the importance of sampling, which could impact exploration for similar porphyry deposits.
The ca. 2.72 Ga Bradley Peak greenstone terrane in the Wyoming Province contains spinifex- and cumulate-textured komatiitic volcanic rocks that may host Ni-Cu-PGE sulfide mineralization. New whole rock geochemistry classifies these rocks as Al-undepleted komatiitic basalts derived from a parental melt with ~17 wt. % MgO. Isotopic data (Sm-Nd, Re-Os) and REE profiles suggest a plume source and possible assimilation of juvenile footwall volcanic rocks. Calculated sulfur concentrations at sulfide saturation and low-detection PGE geochemistry indicate these magmas did not saturate a sulfide liquid resulting in sulfide mineralization. Although the Bradley Peak komatiitic basalt flows are unlikely to host magmatic sulfide mineralization, they are likely the source of Au for regional orogenic gold deposits.
The Sheep Creek area in southwest Montana contains a number of small, tabular, carbonatite-related deposits that are rich in Nb- and REE-minerals. Two of the “vein-dikes” were mined at a small scale for Nb in the late 1950s. The most abundant Nb-bearing minerals are columbite-(Fe), nioboaeschynite-(Ce), baotite, and two varieties of Ti-Nb-Fe-oxide. An early oxide with Ti/Nb (atomic) near unity later broke down to a mixture of columbite + TiO2 with distinctly lower Nb content. Zircon intergrown with the Nb-REE minerals was dated by U-Pb methods to 116±2 Ma. This age is in agreement with previous dating (Th-Pb on monazite, Re-Os on molybdenite), and indicates that the Sheep Creek deposits are early Cretaceous in age.
Escanaba Trough off northern California is the southernmost and only sediment covered segment of the Gorda Ridge. Hydrothermal mineralization was first discovered in Escanaba Trough in 1985, and subsequent investigations included the delineation of the NESCA (northern Escanaba) and SESCA (southern Escanaba) sections of Escanaba Trough, as well as drilling by Ocean Drilling Program (ODP) Leg 169 in 1996. Preliminary research conducted in the 1980s distinguished two classes of sulfide mineral assemblages within the Escanaba Trough: one dominated by pyrrhotite (Fe 1-x S) and one containing ‘mixed sulfides’ including chalcopyrite (CuFeS 2 ) and sphalerite (ZnS). In 2022, we conducted a research expedition to the Escanaba Trough to more thoroughly characterize mineralization processes and consider preservation of precipitated minerals throughout hydrothermally active and inactive sections of Escanaba Trough, with the specific objective of characterizing the host minerals, and processes of enrichment for specific elements which are currently listed as critical elements and can also be toxic under certain conditions (Sb, As, Ba, Co, Ga, Ge, Te). The following will include initial results from that work.
Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.
Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.
Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.
Ferromanganese mineral precipitation in the global oceans is ubiquitous, occurring in the form of both crusts and nodules at a broad range of depths and seafloor terrains. Although ferromanganese crusts and nodules are both composed of ferromanganese minerals, mineralogy and mean element concentrations compiled for regional crust versus nodule occurrences differ. Notably, most published compilations compare nodules from abyssal plain sediments to crusts forming on seamounts, and do not address the question as to whether mineral morphology may affect the composition of crusts and nodules in addition to environmental factors. To address this, we have compiled a dataset of co-located hydrogenetic (seawater sourced) open-ocean ferromanganese crusts and seamount-hosted nodules. The preliminary data presented here support our hypothesis that co-located crusts and nodules exhibit similar compositions, both in terms of their mineralogy and mean element concentrations, as well as overall variance in concentrations for any given element. These data indicate that local processes influence sample-to-sample variation in both crusts and nodules, in contrast to broader ferromanganese variation reported between open-ocean seamounts- hosted crusts and abyssal plain-hosted nodules.