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The chemistry of eolian quartz dust and the origin of chert

Among the numerous models that have been suggested for the primary and predominant source of silica for chert, we suggest that eolian dust is worthy of further considerations. Such considerations are supported by the common association of Phanerozoic chert with evaporites, limestones, dolomites, or other strata that were deposited within or near arid paleoclimates. This association suggests a direct or indirect causal link between aridity and chert formation. In addition, eolian processes export large quantities of quartz-rich dust from arid climate ergs or loess lands. The chemistry of abraded quartz particles derived therefrom is consistent with chert formation. Abrasion of quartz particles produces an amorphous surface layer and underlying lattice disorder. An inverse relation between particle size distribution (< 64 μm) and the enthalpy of solution of abraded quartz is indicative of the degree of lattice disorder; as particle size decreases, the enthalpy of solution increases. The amorphous surface layer and underlying lattice disorder enhance both the rate and amount of dissolution of quartz dust particles; the solubilized silica can then be reprecipitated and diagenetically altered to the various silica polymorphs that occur in chert. An eolian supply and the chemistry of eolian abraded quartz particles may account for chert formation in disparate depositional environments that encompass deep-sea chert, chert in epicontinental seas including shallow shelves, and chert that formed in continental eolinites, lakes, and soils (arid climate silcretes).

Journal of Sedimentary Research

The tectonically controlled San Gabriel Channel–Lobe Transition Zone, Catalina Basin, Southern California Borderland

High-resolution geophysical data across the Catalina Basin, offshore southern California, USA, reveal a complex channel–lobe transition zone (CLTZ) and provide an opportunity to characterize an entire seafloor CLTZ in a tectonically active and confined-basin setting. The seafloor morphology, distribution of depositional and erosional features, and location of depocenters in the CLTZ are controlled by shifting confinement and seafloor gradient related to inherited basement structures, active faults, and basin margins. Below a Holocene hemipelagic drape, the Catalina Basin is dominated by CLTZ and lobe sedimentation from the San Gabriel Channel, with lesser accumulations from local sediment sources limited to basin margins. The San Gabriel Channel is structurally confined as it enters the Catalina Basin and appears unable to avulse; it continues into the basin as a channel that rapidly widens, decreases in relief, and becomes scoured at its margins. A CLTZ is imaged between the confined San Gabriel channel and its terminal lobes deposited > 50 km into the basin. Narrow, apparently disconnected channels with knickpoints occur throughout the proximal and mid-CLTZ and are concentrated near basement highs and basin-bounding Quaternary-active dextral strike-slip faults. A field of small-scale erosional crescent-shaped scours (∼ 100 m length, ∼ 200 m width, up to ∼ 10 m relief across ∼ 30 km 2 region) occurs above a partially buried basement high that creates perturbations in seafloor gradient. Likewise, above a buried basement structure that locally increases seafloor gradient (up to 0.4°), the distal CLTZ may contain sediment waves (∼ 2–4 m wave height and ∼ 200–300 m wavelength) that are smaller than many other CLTZ examples. This study of the San Gabriel CLTZ in Catalina Basin provides high-resolution geophysical data coverage of a complete CLTZ and illustrates a tectonically controlled end-member CLTZ from the modern seafloor.

Journal of Sedimentary Research

Evidence for variable precipitation and discharge from Upper Cretaceous–Paleogene fluvial deposits of the Raton Basin, Colorado–New Mexico, U.S.A.

The Raton Basin of Colorado–New Mexico, USA, is the southeasternmost basin of the Laramide intraforeland province of North America. It hosts a thick succession (4.5 km or 15,000 ft) of Upper Cretaceous to Paleogene marine and continental strata that were deposited in response to the final regression of the Western Interior Seaway and the onset of Laramide intraforeland deformation. The Upper Cretaceous–Paleogene Raton and Poison Canyon formations were previously described as meandering river and braided river deposits that represented distal and proximal members of rivers that drained the basin-bounding Sangre de Cristo–Culebra uplift. We present new observations of fluvial-channel architecture that show that both formations contain the deposits of sinuous fluvial channels. However, fluvial channels of the Raton Formation formed in ever-wet environments and were affected by steady discharge, whereas channels of the overlying Poison Canyon Formation formed in drier environments and were affected by variable discharge. The apparent transition in fluvial discharge characteristics was coeval with the progradation of fluvial fans across the Raton Basin during the Paleocene, emanating from the ancestral Sangre de Cristo–Culebra uplift. The construction of fluvial fans, coupled with the sedimentary features observed within, highlights the dual control of Laramide deformation and early Cenozoic climatic patterns on the sedimentary evolution of the Raton Basin.

Colorado, New Mexico

Deepwater debrites and linked megaturbidites in confined basins: An example from the Onnuri Basin, East Sea of Korea

We analyzed data from seven piston cores, multi-channel seismic-reflection (MCS) and chirp profiles, and multibeam echosounder (MBES) data to study the distribution, emplacement time, sedimentary facies, and depositional processes of sediment-gravity-flow deposits in the Onnuri Basin, a confined basin in the East Sea. These data reveal that debris flows have traveled ca. 30 km downslope, forming a seismic facies consisting of stacked, wedge-shaped, transparent units separated by high-amplitude continuous reflectors. Analysis of piston cores shows three distinct sedimentary units, throughout the basin. The lowest unit, I, is a debrite containing numerous mud clasts of varying size and color distributed in a mud-rich matrix; it is absent over elevated basinal highs or ridges, such as the Onnuri Ridge, suggesting that local topography controls its distribution. The debrite forms a recognizable acoustically transparent layer on subbottom chirp profiles (av. 7 m thick), covers approximately 500 km 2 , and has an estimated volume of ∼ 3.5 km 3 . The overlying unit, II, contains normally graded beds composed of massive sand, laminated and cross-laminated sand and silt, and a thick cap of structureless mud. This unit is interpreted to be a megaturbidite deposited from turbidity currents that originated from the flow transformation of debris flows on the upper continental slope. The megaturbidite covers the entire basin (at least 650 km 2 ), and has an average thickness of 2.8 m (maximum thickness of 4.35 m), and comprises a volume of 1.8 km 3 . Variations in grain size and sedimentary structures suggest that the megaturbidite was deposited by progressively waning flows that reflected off basin flanks and ridges. The thick (up to 3.65 m) structureless mud cap further indicates deposition in a confined basin. The sharp basal contact, together with the lack of hemipelagic sediments between debrite and overlying megaturbidite, suggest that both were deposited during the same flow event, likely to have originated from a single catastrophic slope failure. Collapsing slide material evolved into a debris flow, from which a turbidite formed by dilution of the debris flow. Radiocarbon dates suggest that the slope failure occurred about 13–11 ka, a time when sea level was ca. 50 m lower than at the present day. Hemipelagic sediments in the topmost unit, III-2, above the megaturbidite indicate that the basin has been stable since ca. 11 ka. We provide robust evidence that submarine slope failures evolve downslope into slides, debris flows, and finally, thick megaturbidites. This contribution highlights the importance of seafloor morphology on the distribution and stratigraphy of submarine flows in confined basins.

Onnuri Basin

Selective sediment transport during Hurricane Sandy on Fire Island (New York, USA): Inferences from heavy-mineral assemblages

In October 2012, Hurricane Sandy caused severe erosion on beaches and dunes of Fire Island (New York, USA). Major shoreline changes occurred with erosional dominance in the upper shoreline and aggradation in the lowermost section of the beach due to the deposition of eroded upper beach and dune sediment. Sand laminations with a high concentration of heavy minerals (“black sand laminations”) were observed in three excavated trenches located on a washover terrace and fan on the east side of Fire Island. The mineralogical composition of these laminations reveals the presence of high quantities of magnetite, ilmenite (as opaque minerals), and garnet (as main translucent mineral). These heavy mineral enriched laminations were formed as waves eroded and transported sand from the primary dune and smaller relict dunes under specific hydrodynamic conditions that promoted grain sorting according to differences in size and specific gravity. Based on the concentrations of certain heavy minerals, the threshold for primarily density-driven sorting probably lies between the specific gravity of a less dense mineral (ilmenite, 4.7) and Garnet almandine (4.3), the most common transparent heavy mineral. The number of laminations and concentrations of heavy minerals vary between trenches on the overwash terrace and appear to be controlled by their distance from sediment sources. The trench with a greatest number of laminations and higher heavy mineral concentrations is located furthest from the main dune but is just 10 m inland of a relict dune that acts as the primary source of sediment of the washover deposit in this trench. A conceptual model for heavy mineral layer deposition is presented based on geomorphological and sedimentological evidences allowing the definition of a density threshold.

New York

Testing hypotheses on signatures of precipitation variability in the river and floodplain deposits of the Paleogene San Juan Basin, New Mexico, USA

Much progress has been made in recent years towards a set of recognition criteria for river discharge variability in river channel deposits, and thus sedimentary proxies for precipitation variability. Despite this progress, there is currently no consensus on how different styles of discharge variability are reflected in river sedimentary records, and whether variable-discharge river records from different climate types can be distinguished. Herein, river discharge and precipitation variability in the Paleogene is investigated using associations between river channel and floodplain deposits across the Paleocene-Eocene boundary from the Paleocene upper Nacimiento Formation and the early Eocene San Jose Formation in the San Juan Basin, New Mexico, USA. The succession is identified as deposits of variable-discharge river systems based on shared channel-deposit characteristics with modern and ancient variable-discharge river systems and the proposed facies models, in addition to alternations of poorly drained and well-drained floodplain deposits and/or slickensides indicating alternating wet-dry cycles. A long-term stratigraphic trend toward increasingly well-drained floodplain deposits is also observed and hypothesized to indicate successively more arid conditions from the Paleocene into the early Eocene. Comparisons with modern rivers from various climate zones suggest a long-term shift from a monsoonal climate in the Paleocene, to a fluctuating subhumid climate, ultimately leading to semiarid to arid conditions in the early Eocene. These observations suggest that floodplain deposits may be a better indicator of ambient climate, whereas channel deposits are records for frequency and magnitude of high-intensity precipitation events. Therefore, the existing facies models for variable-discharge rivers that consider only channel facies may not capture critical information needed to make accurate interpretations of paleoclimatic conditions. This study also adds to a growing body of evidence from geologic records of mid-latitude Paleogene river systems suggesting increases in the magnitude or variability of river discharge coinciding with established climate perturbations.

New Mexico

Stratigraphic architecture and fluvial interpretations of the Upper Cretaceous (Turonian?) Middendorf Formation, Chesterfield County, South Carolina, U.S.A.

The Upper Cretaceous (Turonian?) Middendorf Formation is a sand-rich stratigraphic unit of fluvial origin that forms a large aquifer in the U.S. Atlantic Coastal Plain. In Chesterfield County (South Carolina), which is the site of the type locality, the formation ranges in thickness from 66.5 to > 119.7 meters. The base of the formation is an unconformity above Paleozoic metasiltstone, and the upper contact is an unconformity above which lies sand of the Quaternary Pinehurst Formation. Outcrops display the following five facies assemblages: 1) sandstone to conglomeratic sandstone (fluvial bar and channel deposits), 2) beds of alternating laminae of sandstone and mudstone (fluvial overbank or floodplain deposits), 3) ≥ 1 m-thick beds of clay (swamp deposits, floodplain deposits, and/or sediment that accumulated in abandoned fluvial channels), 4) 0.2–0.5 m-thick planar to slightly undulatory beds of framework-supported sandstone with a mud matrix (traction-dominated current deposits at the top of fluvial bars, upper-flow-regime bedform deposits in subsidiary fluvial channels, or coarse-grained overbank deposits), and 5) sandstone to conglomeratic sandstone cemented by iron (interpreted as fluvial bar and channel deposits, with the iron cement being a diagenetic “groundwater ferricrete” that formed via the circulation of shallow groundwater and the oxidation of iron-bearing minerals). Kaolinite in various forms is pervasive throughout the formation and is interpreted as an early diagenetic phenomenon that formed by prolonged postdepositional weathering and flushing by meteoric water under a warm and humid paleoclimate. The fluvial system that formed the Middendorf Formation prograded into the area from the west or northwest from uplifted margins of Mesozoic rift basins and/or the Appalachian Mountains. This progradation was a response to a base-level fall and the sediment accumulated during base-level lowstand and subsequent early transgression. In Chesterfield County, the Middendorf Formation can be subdivided into three fining-upward sequences. Each sequence consists predominantly of medium to coarse sand with a greater abundance of gravel in the lower part of the sequence and a greater abundance of clay and silt beds in the upper part. Each sequence is interpreted as either a response to autogenic processes or a response to allogenic sea-level changes, specifically a higher-order (higher-frequency) progression from relative lowstand conditions to early transgression whereby coarse sand and gravel (e.g., fluvial bar and channel deposits) were preserved during initial lowstand conditions and a greater proportion of mud and finer-grained sand (floodplain deposits) were preserved during subsequent early transgression. The Middendorf Formation is correlative with several other kaolinite-rich fluvial sandstones in North America including the Raritan Formation in New Jersey, the Tuscaloosa Formation of the eastern Gulf of Mexico (Alabama, Mississippi, Louisiana), the Woodbine Formation of the central Gulf of Mexico (Texas), and the Frontier Formation of Wyoming. The accumulation and preservation of these formations occurred in response to a Turonian eustatic sea-level fall and subsequent transgression, and the early diagenetic kaolinite in these formations is attributed to similar warm and humid paleoclimate conditions.

South Carolina

Insights into glendonite formation from the upper Oligocene Sagavanirktok Formation, North Slope, Alaska

The type locality for the upper Oligocene Nuwok Member of the Sagavanirktok Formation (Carter Creek, North Slope, Alaska, USA) contains abundant occurrence of glendonite, a pseudomorph after the calcium carbonate mineral ikaite, which typically forms in the shallow subsurface of cold marine sediments. The region during the time of Nuwok Member deposition was located at a high latitude, similar to today, and the study site is characterized by sands and silty muds interpreted here to have been deposited in coastal and shelfal marine environments. Isotopic (Sr) and biostratigraphic (foraminifera) evidence presented here refine the depositional age of the outcrop to approximately 24 Ma. Glendonites occur in two basic forms: radial clusters, commonly centered around a single larger primary crystal ( approx. 10 cm; Type A) and larger single blades generally without accessory crystals (approx. 15–25 cm; Type B). Microscopic examination revealed a sequence of multiple types of replacive calcite that formed as a direct result of ikaite transformation: Type 1 rhombohedral crystals characterized by microporous and inclusion-rich cores and concentric zones, Type 2A, composed of clear calcite that overgrew and augmented Type 1 crystals, and inclusion-rich, microcrystalline Type 2B, which formed a matrix surrounding the rhombs and commonly dominates the outer rims of glendonite specimens. Type 3 calcite precipitated as fibrous, botryoidal epitaxial cement atop previous phases and is not ikaite-derived. These phases are distributed in similar ways in all examined specimens and are consistent with several previously described glendonite occurrences around the world, despite differing diagenetic and geologic histories. Stable isotope evidence (δ13C and δ18O) suggests sourcing of glendonite carbon from both organic and methanogenic sources. Glendonites of the Nuwok Member can therefore assist in the determination of a more comprehensive ikaite transformation model, improving our understanding of glendonite formation and the sedimentological and environmental context of their occurrence. Oligocene glendonites are uncommon globally; the well-preserved occurrence described here can allow future studies to better reconstruct Arctic environmental conditions and paleoclimates during this time.

Alaska

Reevaluating the depositional model of the Cenomanian–Turonian Bridge Creek Limestone Member near Pueblo, Colorado, U.S.A.: Roles of changing sedimentation rate on the formation of limestone–marl bedding couplets

Although interbedded limestone–marl couplets in many hemipelagic and pelagic deposits have been commonly attributed to orbital-driven climate cycles, the driving mechanisms of these couplets remain largely controversial. This situation arises from the fact that detailed sedimentologic and petrographic facies characteristics of these fine-grained deposits have rarely been examined closely. In this study we conduct an integrated sedimentologic and petrographic analysis to disentangle causes of the limestone–marl bedding couplets in the Cenomanian–Turonian Bridge Creek Limestone Member (BCL) of the Greenhorn Formation using cores and outcrop near Pueblo, Colorado. By integrating existing geochemical datasets, each of the three general lithologies in the BCL including limestone, marl, and calcareous mudstone can be divided into two facies, a more bioturbated vs. a more laminated facies, in addition to bentonite beds. The variability in sedimentary, bioturbation, and petrographic characteristics of different sedimentary facies types, as well as constraints from the existing orbital time scale, in the BCL indicate changes in sediment accumulation rate or the amount of time recorded by different facies—the limestone, marl, and calcareous facies are interpreted to reflect increasing sedimentation rate. The sedimentary and petrographic facies variations, including but not limited to lithological alternations, in the BCL are interpreted to result from the combined influence of various processes such as bottom currents, bioturbation, early diagenesis, and episodic volcanic input, with some of the above-mentioned processes likely modulated by short-term relative changes in sea level. Results of this study highlight the need for detailed sedimentologic and petrographic studies and consideration of short-term changes in sedimentation rate to fully resolve the causes of the apparent limestone–marl bedding couplets and reliably reconstruct short-term changes in depositional and environmental conditions from the BCL and other similar successions.

Colorado

An integrated mudstone facies classification scheme and revised interpretation of the sedimentologic processes driving carbon burial in the Cenomanian–Turonian Greenhorn Formation, Colorado, U.S.A.

Standardizing facies descriptions has proven key to integrating interpretations of depositional processes and environments from sedimentologic observations with geochemistry data for mudstone lithologies. Because of their fine-grained nature, high degree of compaction, and heterogeneous composition, standardizing methods for mudstone descriptions has proven difficult, but it is critical to formulating meaningful interpretations of the processes that govern the accumulation of organic-rich lithologies and their role in both petroleum systems and the global carbon cycle. In this study, we have developed a modified facies classification scheme for mudstone lithologies that incorporates sedimentologic and compositional observation at the hand-sample and thin-section scales with geochemical measurements, including bulk organic and inorganic geochemistry, to characterize these rocks and their variability more completely for improved interpretations of depositional environments during a low-order sea-level transgression. The facies described in this study are of the Cenomanian–Turonian Greenhorn Formation in the USGS #1 Portland Core drilled in Fremont County, Colorado. Strata of the Greenhorn Formation span Oceanic Anoxic Event 2 (OAE-2) and the preceding interval. Lithologies range from organic-rich argillaceous mudstones with varied sedimentary structures to organic-lean, highly bioturbated limestones. Six facies were identified, each differentiated by varied sedimentary structures and geochemical composition. These facies occur in a predictable stratigraphic stacking pattern that represents a low-order sea-level transgression with interpreted depositional environments ranging from terrigenous-dominated pro-delta and muddy continental shelf at the base of the interval to pelagic offshore marine at the top of the Greenhorn Formation. Though the facies are consistent with previous interpretations of depositional environments at this locale in the Cretaceous Western Interior Seaway during the Greenhorn cyclothem, the sedimentary processes governing the accumulation of organic-rich strata that have defined this interval are significantly revised. Variability in the proximity and intensity of bottom currents driven by storms and geostrophic flows were key to the accumulation of each facies, with significant sediment transport occurring even through deposition in the most oxygen-depleted bottom waters. The methodology and interpretations provided here are now being employed to basin-scale predictions of organic enrichment utilizing calibrated petrophysical methods. The approach and results from this study improve understanding of how organic and inorganic carbon was sequestered during perturbations to the global carbon cycle associated with events such as OAE-2.

Colorado

Quantitative controls on location and architecture of carbonate depositional sequences: upper miocene, cabo de gata region, se Spain

Sequence stratigraphy, pinning-point relative sea-level curves, and magnetostratigraphy provide the quantitative data necessary to understand how rates of sea-level change and different substrate paleoslopes are dominant controls on accumulation rate, carbonate depositional sequence location, and internal architecture. Five third-order (1-10 my) and fourth-order (0.1-1.0 my) upper Miocene carbonate depositional sequences (DS1A, DS1B, DS2, DS3, TCC) formed with superimposed higher-frequency sea-level cycles in an archipelago setting in SE Spain. Overall, our study indicates when areas of high substrate slope (>15 degrees ) are in shallow water, independent of climate, the location and internal architecture of carbonate deposits are not directly linked to sea-level position but, instead, are controlled by location of gently sloping substrates and processes of bypass. In contrast, if carbonate sediments are generated where substrates of low slope (<15 degrees in our area) are in shallow water, then architecture and location of deposits may be more directly controlled by the relative position of sea level. For these systems, the rates of relative sea-level change are important for determining which systems tracts develop. DS1A-DS1B, cooler-water ramps, result from sediment bypass across steep paleoslopes to toes of slopes. Accumulation rates decreased from >15.6 cm/ky to approximately 2 cm/ky and overall relative sea level rose at rates of 17-21.4 cm/ky. Higher frequency sea-level rates were about 111 to more than 260 cm/ky, producing onlapping, fining- (deepening-) upward cycles. Decreasing accumulation rates resulted from decreasing surface area for shallow-water sediment production, drowning of shallow-water substrates, and complex sediment dispersal related to the archipelago setting. Typical systems tract and parasequence development should not be expected in "bypass ramp" settings; facies of onlapping strata do not track base level and are likely to be significantly different compared to onlapping strata associated with coastal onlap. Basal and upper DS2 reef megabreccias (indicating the transition from cool to warmer climatic conditions) were eroded from steep upslope positions and redeposited downslope onto areas of gentle substrate during rapid sea-level falls (>22.7 cm/ky) of short duration. Such rapid sea-level falls and presence of steep slopes are not conducive to formation of forced regressive systems tracts composed of down-stepping reef clinoforms. The DS3 reefal platform formed where shallow water coincided with gently sloping substrates created by earlier deposition. Slow progradation (0.39-1.45 km/my) is best explained by the lack of an extensive bank top, progressively falling sea level, and low productivity resulting from siliciclastic debris and excess nutrients shed from nearby volcanic islands. Although DS3 strata were deposited during a third-order relative sea-level cycle, a typical transgressive systems tract is not recognizable, indicating that the initial relative rise in sea level was too rapid (>>19 cm/ky). Downstepping reefs, forming a forced regressive systems tract, were deposited during the relative sea-level fall at the end of DS3, indicating that relatively slow rates of fall (10 cm/ky or less) over favorable paleoslope conditions are conducive to generation of forced regressive systems tracts consisting of downstepping reef clinoforms. The TCC sequence consists of four shallow-water sedimentary cycles that were deposited during a 400 ky to 100 ky time span. Such shallow-water cycles, typical of many platforms, form only where shallow water intersects gently sloping substrates. The relative thicknesses of cycles (<2 m to 15 m thick), magnitudes of relative sea-level fluctuations associated with each cycle (25-30 m), high rates of relative sea-level fluctuations (minimum of 25-120 cm/ky), and the widespread distribution of similar TCC cycles in the Mediterranean and elsewhere are supportive of a glacio-eustatic influence. With rates of sea-level change so high, typical systems tracts do not form.

Journal of Sedimentary Research

Comparing sea-ice sediment load with Beaufort Sea shelf deposits: Is entrainment selective?

Modern dispersal of sea-ice-rafted debris (IRD) is important for the Arctic Ocean sediment budget from sources to sinks. Sediment entrainment occurs mainly through the action of small ice crystals (frazil) attaching to sedimentary particles in shallow water, a mechanism that could be selective. The principal source for entrainment of IRD by suspension freezing into the Beaufort Gyre, western Arctic Ocean, is the adjacent shallow (<30 m) shelf, here called the source surface. The texture, clay-mineral composition, coarse sand (<250 micrometers) lithology, and carbon and carbonate content of IRD in the Beaufort Gyre were compared to sediments from the probable source surface, in order to determine whether preferential entrainment occurs with any of these sediment parameters. IRD is generally much finer grained than the source surface, showing that silt- and clay-size particles are preferentially entrained by frazil ice, although anchor ice can locally incorporate very high percentages of sand and coarser clasts. The coarsest IRD is also the most poorly sorted. The clay mineralogy of the <2 micrometer IRD fraction is very similar to that of the source surface, indicating no selective entrainment within the clay fraction. The lithology of sand in IRD also matches that of the source surface, although the number of coarse grains is too small (<100) in most samples for a statistically meaningful count. The average organic-carbon content of IRD is three times higher than that of the source surface, but we attribute this to summer algal growth on ice floes rather than to selective entrainment. A relatively low carbonate content in IRD may be because much of the carbonate in the source is of silt size while about 50% of the IRD measured is clay size. The low carbonate content may also reflect solution under acidic summer conditions on sea ice. Selective export of silt- and clay-size particles by ice rafting from the shallow shelf with time should lead to the formation of a slightly coarser lag, even though some of the dirty ice drops its sediment load in the entrainment area. Further mineralogical and lithological analysis on IRD promises to become a useful tool for the study of sediment dispersal paths by drift ice in the Arctic today and in the past, and also for the study of sources of anthropogenic pollutants found in sea ice.

Beaufort Sea shelf

Sequential filling of a late paleozoic foreland basin

Through the use of an extensive data base of geophysical well logs, parasequence-scale subdivisions within a late Paleozoic synorogenic clastic wedge resolve cycles of sequential subsidence of a foreland basin, sediment progradation, subsidence of a carbonate shelf edge, diachronously subsiding discrete depositional centers, and basinwide transgression. Although temporal resolution of biostratigraphic markers is less precise in Paleozoic successions than in younger basins, parasequence-scale subdivisions provide more detailed resolution within marker-defined units in Paleozoic strata. As an example, the late Paleozoic Black Warrior basin in the foreland of the Ouachita thrust belt is filled with a synorogenic clastic wedge, the lower part of which intertongues with the fringe of a cratonic carbonate facies in the distal part of the basin. The stratal geometry of one tongue of the carbonate facies (lower tongue of Bangor Limestone) defines a ramp that grades basinward into a thin black shale. An overlying tongue of the synorogenic clastic wedge (lower tongue of Parkwood Formation) consists of cyclic delta and delta-front deposits, in which parasequences are defined by marine-flooding surfaces above coarsening- and shallowing-upward successions of mudstone and sandstone. Within the lower Parkwood tongue, two genetic stratigraphic sequences (A and B) are defined by parasequence offlap and downlap patterns and are bounded at the tops by basinwide maximum-flooding surfaces. The distribution of parasequences within sequences A and B indicates two cycles of sequential subsidence (deepening) and progradation, suggesting subsidence during thrust advance and progradation during thrust quiescence. Parasequence stacking in sequences A and B also indicates diachronous differential tectonic subsidence of two discrete depositional centers within the basin. The uppermost sequence (C) includes reworked sandstones and an overlying shallow-marine limestone, a vertical succession that reflects no tectonic subsidence, a very minor or null sediment supply, and basinwide transgression. The temporal resolution at parasequence scale significantly improves the resolution of the tectonic history of the thrust belt-foreland basin system.

Journal of Sedimentary Research

Detrital zircon geochronology of the Adams Argillite and Nation River Formation, east-central Alaska, U.S.A

The Cambrian Adams Argillite and the Devonian Nation River Formation are two sandstone-bearing units within a remarkably complete Paleozoic stratigraphic section in east-central Alaska. These strata, now foreshortened and fault-bounded, were originally contiguous with miogeoclinal strata to the east that formed as a passive-margin sequence along the northwestern margin of the North American continent. Seventy-five detrital zircon grains from the Adams Argillite and the Nation River Formation were analyzed in an effort to provide constraints on the original sources of the grains, and to generate a detrital zircon reference for miogeoclinal strata in the northern Cordillera. Thirty-five single zircon grains from a quartzite in the Adams Argillite yield dominant age clusters of 1047-1094 (n = 6), 1801-1868 (n = 10), and 2564-2687 (n = 5) Ma. Forty zircons extracted from a sandstone in the Nation River Formation yield clusters primarily of 424-434 (n = 6), 1815-1838 (n = 6), 1874-1921 (n = 7), and 2653-2771 (n = 4) Ma. The Early Proterozoic and Archean grains in both units probably originated in basement rocks in a broad region of the Canadian Shield. In contrast, the original igneous sources for mid-Proterozoic grains in the Adams Argillite and approximately 430 Ma grains in the Nation River Formation are more difficult to identify. Possible original sources for the mid-Proterozoic grains include: (1) the Grenville Province of eastern Laurentia, (2) the Pearya terrane along the Arctic margin, and (3) mid-Proterozoic igneous rocks that may have been widespread along or outboard of the Cordilleran margin. The approximately 430 Ma grains may have originated in: (1) arc-type sources along the Cordilleran margin, (2) the Caledonian orogen, or (3) a landmass, such as Pearya, Siberia, or crustal fragments now in northern Asia, that resided outboard of the Innuitian orogen during mid-Paleozoic time.

Journal of Sedimentary Research

Climate and lake-level history of the northern altiplano, Bolivia, as recorded in holocene sediments of the Rio Desaguadero

Strata exposed in terraces and modern cutbanks along the Rio Desaguadero contain a variety of lithofacies that were deposited in four distinct facies associations. These facies associations document a history of aggradation and downcutting that is linked to Holocene climate change on the Altiplano. Braided-stream, meandering-stream, deltaic and shoreline, and lacustrine sediments preserved in multi-level terraces in the northern Rio Desaguadero Valley record two high-water intervals; one between 4500 and 3900 yr BP and another between 2000 and 2200 yr BP. These wet periods were interrupted by three periods of fluvial downcutting, centered at approximately 4000 yr BP, 3600 yr BP, and after 2000 yr BP. Braided-river sediments preserved in a single terrace level in the southern Rio Desaguadero Valley record a history of nearly continuous fluvial sedimentation from at least 7000 yr BP until approximately 3200 yr BP that was followed by a single episode (post-3210 yr BP) of down-cutting and lateral migration. The deposition and subsequent fluvial downcutting of the northern strata was controlled by changes in effective moisture that can be correlated to Holocene water-level fluctuations of Lake Titicaca. The deposition and dissection of braided-stream sediments to the south are more likely controlled by a combination of base-level change and sediment input from the Rio Mauri.

Journal of Sedimentary Research

Chronologic model and transgressive-regressive signatures in the late neocene siliciclastic foundation (long key formation) of the Florida keys

Recent drilling of continuous cores in southernmost Florida has documented a thick unit of upper Neogene siliciclastics subjacent to surficial shallow-water Quaternary carbonates exposed on islands of the Florida Keys. The siliciclastics comprise the Long Key Formation and were identified in two cores collected from the middle and upper Florida Keys. A chronologic model based on new planktic foraminiferal biochronology and strontium-isotope chronology suggests the timing of siliciclastic deposition and provides a basis for regional correlation. The chronologic model, supplemented by vertical trends in quartz grain size, pattern of planktic menardiiform coiling direction, and paleoenvironmental interpretations of benthic foraminiferal assemblages, shows that the Long Key Formation contains three intervals (I-III) of varying thickness, grain-size composition, and paleowater depth. Interval I is uppermost Miocene. The quartz grains in Interval I fine upward from basal very coarse sand to fine and very fine sand. Benthic foraminifera indicate an upward shift from an outer-shelf to inner-shelf depositional environment. Interval II, deposited during the late early to early late Pliocene, contains reworked upper Miocene siliciclastics and faunas. In the upper Keys, quartz grains in Interval II range from very coarse sand that fines upward to very fine sand and then coarsens to very coarse and medium sand. In situ benthic faunas indicate an upward shift from outer-shelf to inner-shelf deposition. In the middle Keys, Interval II is different, with the quartz grains ranging primarily from medium to very fine sand. In situ benthic taxa indicate deposition on an inner shelf. In both the middle and upper Keys, the upper Pliocene siliciclastics of Interval III contain quartz grains ranging from very coarse to very fine sands that were deposited on an inner shelf. A sequence boundary between Interval I and Interval II is suggested by; an abrupt shift in the strontium-isotope chemostratigraphy; coarsening in quartz grain size above the boundary; an abrupt landward shift in depositional facies in the upper Keys core; and a distinct variation in the predominant coiling direction of the menardiiform planktic foraminifera, from fluctuating dextral-sinistral to dextral in the upper Keys core. Successive siliciclastic infilling, likely associated with eustatic sea-level change and current redeposition, formed a foundation for subsequent carbonate deposition. Deep-sea biostratigraphic techniques, integrated with ages derived from strontium-isotope chemostratigraphy, can be successfully applied to coastal-margin sequences, even though a depauperate suite of faunal markers is common.

Journal of Sedimentary Research