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At least 73 records · Page 4Linked to original sources
USGS2010

Rocky Mountain snowpack physical and chemical data for selected sites, 2009

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region from New Mexico to Montana to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition. The U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, collected and analyzed snowpack samples annually for 48 or more sites in the Rocky Mountain region during 1993-2009. Sixty-three snowpack-sampling sites were sampled once each in 2009 and data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2009 also are included.

Data Series↗
USGS2011

Rocky Mountain snowpack physical and chemical data for selected sites, 2010

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region, from New Mexico to Montana, to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition on freshwater systems. Scientists with the U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, annually collected and analyzed snow-pack samples at 48 or more sites in the Rocky Mountain region during 1993-2010. Sixty-three snowpack-sampling sites were each sampled once in 2010, and those data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2010 also are included.

Rocky Mountains↗
USGS2010

Assessment of goods and valuation of ecosystem services (AGAVES) San Pedro River Basin, United States and Mexico

A consortium of federal, academic, and nongovernment organization (NGO) partners have established a collaborative research enterprise in the San Pedro River Basin to develop methods, standards, and tools to assess and value ecosystem goods and services. The central premise of ecosystem services research is that human condition is intrinsically linked to the environment. Human health and well-being (including economic prosperity) depend on important supporting, regulating, provisioning, and cultural services that we derive from our surrounding ecosystems. The AGAVES project is intended as a demonstration study for incorporating ecosystem services information into resource management policy and decisionmaking. Accordingly, a nested, multiscale project design has been adopted to address a range of stakeholder information requirements. This design will further facilitate an evaluation of how well methods developed in this project can be transferred to other areas.

Fact Sheet↗
USGS1996

Geohydrology of the shallow aquifers in the Denver metropolitan area, Colorado

The Denver metropolitan area is underlain by shallow layers of water-bearing sediments (aquifers) consisting of unconsolidated gravel, sand, silt, and clay. The depth to water in these aquifers is less than 20 feet in much of the area, and the aquifers provide a ready source of water to numerous shallow, small-capacity wells. The shallow depth to water also makes the aquifers susceptible to contamination from the land surface. Water percolating downward from residential, commercial, and industrial property, spills of hazardous materials, and leaks from underground storage tanks and pipelines can cause contaminants to enter the shallow aquifers. Wet basements, unstable foundation materials, and waterlogged soils also are common in areas of very shallow ground water. Knowledge of the extent, thickness, and water-table altitude of the shallow aquifers is incomplete. This, coupled with the complexity of development in this large metropolitan area, makes effective use, management, and protection of these aquifers extremely difficult. Mapping of the geologic and hydrologic characteristics of these aquifers would provide the general public and technical users with information needed to better use, manage, and protect this water resource. A study to map the geohydrology of shallow aquifers in the Denver metropolitan area was begun in 1994. The work was undertaken by the U.S. Geological Survey in cooperation with the U.S. Army-Rocky Mountain Arsenal, U.S. Department of Energy-Rocky Flats Field Office, Colorado Department of Public Health and Environment, Colorado Department of Natural Resources-State Engineers Office, Denver Water Department, Littleton-Englewood Wastewater Treatment Plant, East Cherry Creek Valley Water and Sanitation District, Metro Wastewater Reclamation District, Willows Water District, and the cities of Aurora, Lakewood, and Thornton. This report presents the results of a systematic mapping of the extent, thickness, and water-table altitude of the shallow aquifers in a 700-square-mile part of the greater Denver metropolitan area (fig. 1). The five sheets in this report (figs. 2-7) show (1) the thickness and extent of the unconsolidated sediments that overlie bedrock formations in the area, (2) the altitude and configuration of the buried bedrock surface, (3) the altitude of the water table and direction of ground-water movement, (4) the saturated thickness of the shallow aquifers, and (5) the depth to the water table in the shallow aquifers. The maps primarily are intended to indicate the general trends in altitude and thickness of the aquifers and are not intended to define conditions at specific sites.

Hydrologic Atlas↗
USGS2000

Interim report on the scientific investigations in the Animas River watershed, Colorado to facilitate remediation decisions by the U.S. Bureau of Land Management and the U.S. Forest Service, March 29, 2000 meeting, Denver, Colo.

INTRODUCTION The joint U.S. Department of the Interior and U.S. Department of Agriculture Abandoned Mine Lands Initiative (AMLI) was developed as a collaborative effort between the Federal land management agencies (FLMA, that is the U.S. Bureau of Land Management and the U.S. Forest Service) and the U.S. Geological Survey (USGS) in 1996. The stated goal of the AML Initiative was to develop a strategy for gathering and communicating the scientific information needed to develop effective and cost-efficient remediation of abandoned mines within the framework of a watershed. Four primary objectives of the AMLI are to: 1. Provide the scientific information needed (in the short-term) by the FLMAs to make decisions related to the design and implementation of cleanup actions, 2. Develop a multi-disciplined, multi-division approach that integrates geologic, hydrologic, geochemical and ecological information into a knowledge base for sound decision making, 3. Transfer technologies developed within the scientific programs of the USGS to the field and demonstrate their suitability to solve real, practical problems, and 4. Establish working relationships among involved members of land management and regulatory agencies within the framework of a watershed approach to the cleanup of abandoned mines. Long-term process-based research, including development of analytical tools, is recognized as being critical to the long-term success in remediating watersheds impacted by historical mining activities (AML 5-year plan, http://amli.usgs.gov/amli). In a meeting of Federal agencies (U.S. Bureau of Land Management [BLM], U.S. Bureau of Reclamation [BOR], U.S. National Park Service [NPS], U.S. Forest Service [USFS], the U.S. Environmental Protection Agency [EPA], the U.S. Fish and Wildlife Service [F&WS]), and State agencies (Colorado Division of Public Health and Environment, Colorado Division of Mines and Geology), several watersheds were examined within the state whose water quality was presumed to be impacted by historical mining activities. The Animas River watershed (fig. 1) was selected by the State and Federal agencies as one of two watersheds in the U.S. to be studied in detail by the USGS in the AML Initiative. Beginning in October 1997, each of the four Divisions of the USGS (Water Resources, Geologic, Biological Resources, and National Mapping) initiated a collaborative integrated science study of the watershed. Funds were provided from USGS base funding to each of the four Divisions in response to the priorities set by Congressional action and within the flexibility provided by the budgetary framework funding individual research programs. The AML Initiative provides for a five-year focused scientific effort in the two watersheds with final synthesis of the scientific results from each to be published in 2001. Publications are released on the AML web site on a regular basis (http://amli.usgs.gov/amli). On March 29, 2000, the USGS hosted a meeting for the BLM and USFS to discuss remediation options that were under consideration for the summer of 2000. The purpose of this report is to provide an overview of the scientific rational provided by the USGS to meet objective one above, and to summarize our preliminary interpretations of our data. Additional information from sites on private lands have been collected by the State of Colorado, EPA, and the ARSG. Unfortunately, these data have not been fully supplied to the USGS so our conclusions are based only upon our data. These interpretations provide science-based constraints on possible remediation options to be considered by the FLMA, the State, and local property owners in the Animas River watershed. The report is presented in outline format to facilitate discussion of remediation options at the March 29, 2000 meeting. Not all historical mining sites within the watershed are on public lands. This should not be construed to be a final report of the USGS

Denver↗
USGS2021

Linear regression model documentation and updates for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River, Kansas, July 2012 through September 2019

The Kansas River provides drinking water to about 800,000 people in northeastern Kansas. Water-treatment facilities that use the Kansas River as a water-supply source use chemical and physical processes during water treatment to remove contaminants before public distribution. Advanced notification of changing water-quality conditions near water-supply intakes allows water-treatment facilities to proactively adjust treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, and Johnson County WaterOne, collected water-quality data at the Kansas River at Wamego (USGS site 06887500; hereafter referred to as the “Wamego site”) and De Soto (USGS site 06892350; hereafter referred to as the “De Soto site”) monitoring sites to update previously published regression models relating continuous water-quality sensor measurements, streamflow, and seasonal components to discretely sampled water-quality constituent concentrations or densities. Linear regression analysis was used to update and develop models for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and fecal indicator bacteria at the Wamego and De Soto monitoring sites using data collected during July 2012 through September 2019. The water-quality information documented in this report can be used as guidance for water-treatment processes and to characterize changes in water-quality conditions in the Kansas River over time that would not be otherwise possible.

Kansas↗
USGS1984

Relation of urban land-use and dry-weather, storm, and snowmelt flow characteristics to stream-water quality, Shunganunga Creek basin, Topeka, Kansas

Overland runoff from urban areas can cause concentrations of some water-quality constituents in local receiving streams to increase. The U.S. Geological Survey in cooperation with the Kansas Department of Health and Environment investigated the water-quality characteristics of streams draining Topeka, Kansas, and adjacent parts of the Shunganunga Creek basin from October 1979 through November 1981. The purpose of this investigation was to provide the data and interpretation necessary to determine the effects of runoff from urban areas on the water-quality characteristics of receiving streams. Water-quality characteristics for three streamflow conditions were determined: (1) dry-weather streamflow--a combination of base flow and point-source contributions, (2) storm streamflow--mainly provided by overland runoff from storms, and (3) snowmelt streamflow- mainly provided by overland runoff from snowmelt. Median concentrations of trace metals and nutrients were larger in storm streamflow than in dry-weather streamflow. Median concentrations of total lead and zinc were largest in storm streamflow from the more urban basins. Regression equations were developed to estimate median concentrations of total lead and zinc in storm streamflow from the percentage of drainage area in residential plus commercial land-use areas (correlation coefficients were 0.98 for total lead and 0.88 for total zinc); and from street density in lane miles per square mile (correlation coefficients were 0.89 for total lead and 0.84 for total zinc). Median concentrations of dissolved nitrite plus nitrate nitrogen and total phosphorus averaged, respectively, 76-percent and 70-percent larger during storm streamflow than during dry-weather streamflow and were largest in storm streamflow from the more agricultural basins. Median concentrations of dissolved sodium, chloride, and solids in snowmelt streamflow at all study sites averaged 218-percent larger for dissolved sodium, 296-percent larger for dissolved chloride, and 71-percent larger for dissolved solids relative to median concentrations in dry-weather streamflow. Regression equations also were developed to estimate median concentrations of dissolved sodium, chloride, and solids in snowmelt streamflow from the summation of percentages of the drainage area in residential, commercial, and industrial land-use areas (correlation coefficients were 0.97 for each of the three relationships) and from street density in lane miles per square mile (correlation coefficients were 0.93 for dissolved sodium and 0.94 for both dissolved chloride and dissolved solids). Multiple-correlation and regression analysis relating storm-runoff volumes and average constituent concentrations to land-use and storm characteristics produced significant relations (0.05 level of significance) for storm-runoff volume (0.81 coefficient of determination), total lead (0.71 coefficient of determination), total zinc (0.50 coefficient of determination), and suspended sediment (0.58 coefficient of determination).

Kansas↗
USGS1992

Hydrogeologic, water-quality, streamflow, bottom-sediment analyses, and biological data near the Wayne County landfill, Wayne County, Tennessee

This report summarizes the data collected as part of a hydrogeologic investigation to determine the effects of the Wayne County landfill on local water quality. The investigation was conducted from 1988 through 1989 by the U.S. Geological Survey in cooperation with the Tennessee Department of Health and Environment, Division of Superfund. The landfill was closed in November 1984 after allegations that contaminants from the landfill were affecting the quality of water from domestic wells in the Banjo Branch-Hardin Hollow valley. Test well construction data; water-quality data for selected wells, seeps, and surface-water sites: streamflow data from Banjo Branch; analyses of bottom-sediment samples: and biological data for the study area are documented in this report.

Tennessee↗
USGS2017

Titanium

Titanium is a mineral commodity that is essential to the smooth functioning of modern industrial economies. Most of the titanium produced is refined into titanium dioxide, which has a high refractive index and is thus able to impart a durable white color to paint, paper, plastic, rubber, and wallboard. Because of their high strength-to-weight ratio and corrosion resistance, titanium metal and titanium metal alloys are used in the aerospace industry as well as for welding rod coatings, biological implants, and consumer goods. Ilmenite and rutile are currently the principal titanium-bearing ore minerals, although other minerals, including anatase, perovskite, and titanomagnetite, could have economic importance in the future. Ilmenite is currently being mined from two large magmatic deposits hosted in rocks of Proterozoic-age anorthosite plutonic suites. Most rutile and nearly one-half of the ilmenite produced are from heavy-mineral alluvial, fluvial, and eolian deposits. Titanium-bearing minerals occur in diverse geologic settings, but many of the known deposits are currently subeconomic for titanium because of complications related to the mineralogy or because of the presence of trace contaminants that can compromise the pigment production process. Global production of titanium minerals is currently dominated by Australia, Canada, Norway, and South Africa; additional amounts are produced in Brazil, India, Madagascar, Mozambique, Sierra Leone, and Sri Lanka. The United States accounts for about 4 percent of the total world production of titanium minerals and is heavily dependent on imports of titanium mineral concentrates to meet its domestic needs. Titanium occurs only in silicate or oxide minerals and never in sulfide minerals. Environmental considerations for titanium mining are related to waste rock disposal and the impact of trace constituents on water quality. Because titanium is generally inert in the environment, human health risks from titanium and titanium mining are minimal; however, the processes required to extract titanium from titanium feedstock can produce industrial waste.

Professional Paper↗
USGS2005

Estimation of constituent concentrations, densities, loads, and yields in lower Kansas River, northeast Kansas, using regression models and continuous water-quality monitoring, January 2000 through December 2003

The lower Kansas River is an important source of drinking water for hundreds of thousands of people in northeast Kansas. Constituents of concern identified by the Kansas Department of Health and Environment (KDHE) for streams in the lower Kansas River Basin include sulfate, chloride, nutrients, atrazine, bacteria, and sediment. Real-time continuous water-quality monitors were operated at three locations along the lower Kansas River from July 1999 through September 2004 to provide in-stream measurements of specific conductance, pH, water temperature, turbidity, and dissolved oxygen and to estimate concentrations for constituents of concern. Estimates of concentration and densities were combined with streamflow to calculate constituent loads and yields from January 2000 through December 2003. The Wamego monitoring site is located 44 river miles upstream from the Topeka monitoring site, which is 65 river miles upstream from the DeSoto monitoring site, which is 18 river miles upstream from where the Kansas River flows into the Missouri River. Land use in the Kansas River Basin is dominated by grassland and cropland, and streamflow is affected substantially by reservoirs. Water quality at the three monitoring sites varied with hydrologic conditions, season, and proximity to constituent sources. Nutrient and sediment concentrations and bacteria densities were substantially larger during periods of increased streamflow, indicating important contributions from nonpoint sources in the drainage basin. During the study period, pH remained well above the KDHE lower criterion of 6.5 standard units at all sites in all years, but exceeded the upper criterion of 8.5 standard units annually between 2 percent of the time (Wamego in 2001) and 65 percent of the time (DeSoto in 2003). The dissolved oxygen concentration was less than the minimum aquatic-life-support criterion of 5.0 milligrams per liter less than 1 percent of the time at all sites. Dissolved solids, a measure of the dissolved material in water, exceeded 500 milligrams per liter about one-half of the time at the three Kansas River sites. Larger dissolved-solids concentrations upstream likely were a result of water inflow from the highly mineralized Smoky Hill River that is diluted by tributary flow as it moves downstream. Concentrations of total nitrogen and total phosphorus at the three monitoring sites exceeded the ecoregion water-quality criteria suggested by the U.S. Environmental Protection Agency during the entire study period. Median nitrogen and phosphorus concentrations were similar at all three sites, and nutrient load increased moving from the upstream to downstream sites. Total nitrogen and total phosphorus yields were nearly the same from site to site indicating that nutrient sources were evenly distributed throughout the lower Kansas River Basin. About 11 percent of the total nitrogen load and 12 percent of the total phosphorus load at DeSoto during 2000-03 originated from wastewater-treatment facilities. Escherichia coli bacteria densities were largest at the middle site, Topeka. On average, 83 percent of the annual bacteria load at DeSoto during 2000-03 occurred during 10 percent of the time, primarily in conjunction with runoff. The average annual sediment loads at the middle and downstream monitoring sites (Topeka and DeSoto) were nearly double those at the upstream site (Wamego). The average annual sediment yield was largest at Topeka. On average, 64 percent of the annual suspended-sediment load at DeSoto during 2000-03 occurred during 10 percent of the time. Trapping of sediment by reservoirs located on contributing tributaries decreases transport of sediment and sediment-related constituents. The average annual suspended-sediment load in the Kansas River at DeSoto during 2000-03 was estimated at 1.66 million tons. An estimated 13 percent of this load consisted of sand-size particles, so approximately 216,000 tons of sand were transported

Scientific Investigations Report↗
USGS2005

Effects of emission reductions at the Hayden powerplant on precipitation, snowpack, and surface-water chemistry in the Mount Zirkel Wilderness Area, Colorado, 1995-2003

Precipitation, snowpack, and surface-water samples collected during 1995-2003 were analyzed to evaluate the effects of emission reductions at the Hayden powerplant on water chemistry in the Mount Zirkel Wilderness Area. The Hayden powerplant, one of two large coal-fired powerplants in the Yampa Valley, was retrofitted with control systems during late 1998 and 1999 to reduce emissions of sulfur dioxide and nitrogen oxide--the primary precursors of haze and acidic precipitation. The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, evaluated three water-chemistry data sets: wet-only precipitation chemistry from the National Atmospheric Deposition Program, snowpack chemistry from the Rocky Mountain snowpack network, and surface-water chemistry from a U.S. Geological Survey long-term lakes monitoring program. Concentrations and deposition rates of selected constituents were compared for the periods before and after emission reductions at the Hayden powerplant. Data collected during 1995-98 were used to represent the pre-control period, and data collected during 2000-2003 were used to represent the post-control period. Ten stations in the National Atmospheric Deposition Program were evaluated including two that were directly downwind from the Hayden powerplant (Dry Lake and Buffalo Pass) and eight that were upwind or more distant (more than 100 kilometers) from the powerplant. Precipitation amount at all 10 precipitation stations was lower in the post-control period than the pre-control period as a result of a regional drought that persisted during the post-control period. In contrast to precipitation amount, there was no consistent pattern of change in sulfate concentrations between periods, indicating that the drought did not have a concentrating effect on sulfate or that trends in regional sulfur dioxide emissions masked its influence. Sulfate concentrations increased at three stations between periods, remained the same at three stations, and decreased at four stations. The largest change in average annual sulfate concentrations occurred at the two precipitation stations downwind from the Hayden powerplant, decreasing by 3.3 microequivalents per liter at Dry Lake and by 2.2 microequivalents per liter at Buffalo Pass. Declines in annual sulfate deposition also were greater at Dry Lake (3.4 kilograms per hectare) and Buffalo Pass (3.3 kilograms per hectare) than at the other stations, which ranged from 0.2 to 1.7 kilograms per hectare. These results indicate that emission reductions at the Hayden powerplant have been a factor in declines in atmospheric deposition of sulfate downwind from the powerplant. Nitrate, ammonium, and base-cation concentrations, in contrast to sulfate, were higher in the post-control period than the pre-control period at all 10 stations, most likely due to a concentrating effect of the drought. Twenty-two snowpack sites in the Rocky Mountain snowpack network were evaluated including 4 sites that were located directly downwind from the Hayden powerplant and 18 sites that were upwind or more distant (as much as 200 kilometers) from the powerplant. The water content of the snowpack at maximum accumulation was lower in the post-control period than the pre-control period, reflecting the regional drought. Although there were small declines in snowpack sulfate concentrations at the downwind stations between the pre- and post-control periods, the difference was not statistically significant, indicating emission reductions had a weaker effect on snowpack chemistry than precipitation chemistry. Sulfate deposition decreased at all four downwind sites in the post-control period, primarily reflecting both lower water content and concentrations in the snowpack. As observed at the precipitation stations, nitrate, ammonium, and base-cation concentrations at all 22 sites were significantly higher in the post-control period than the pre-control period, reflecting drier conditions caused by drought. The chemistry at six surface-water sites in and near the Mount Zirkel Wilderness Area and five control sites in the Flat Tops Wilderness Area was examined. No response to emission reductions was detectable in chemistry of the surface water in the Mount Zirkel Wilderness Area. Detection of a response to changes in emissions and deposition in the lake-chemistry data may have been confounded by drought conditions during the period after emission reductions occurred. The magnitude of reduced sulfate in atmospheric deposition indicates that at some time in the future, a reduction in lake sulfate attributable to Yampa Valley emission reduction should be detectable. The trend of decreasing sulfur dioxide emissions throughout western North America over the past 20 years is reflected in reduced concentrations of sulfate in lakes that were part of this study, as well as other lakes in the Rocky Mountains. However, detection of the surface-water response to changes in deposition requires a sufficiently long record to minimize effects of climate variability and to allow for lag time as sulfate moves through storage in soil, ground water, and lake reservoirs.

Colorado↗
USGS2005

Hydrologic and water-quality conditions in the Kansas River, northeast Kansas, November 2001–August 2002, and simulation of ammonia assimilative capacity and bacteria transport during low flow

Large concentrations of ammonia and densities of bacteria have been detected in reaches of the Kansas River in northeast Kansas during low streamflow conditions, prompting the Kansas Department of Health and Environment (KDHE) to list these reaches as water-quality limited with respect to ammonia and fecal coliform bacteria. Sources for ammonia and bacteria in the watershed consist of wastewater-treatment facilities (WWTFs) and agricultural and urban runoff. The U.S. Geological Survey (USGS), in cooperation with KDHE, conducted an investigation of the Kansas River to characterize hydrologic and water-quality conditions and to simulate ammonia assimilative capacity and bacteria transport during low streamflow. This report characterizes the water-quality conditions, documents the calibration of a two-dimensional water-quality model, and presents results of hypothetical simulations of existing and future WWTFs discharging to the Kansas River during low streamflow. Water samples were collected during low streamflow conditions at 50 sampling sites along and near the Kansas River between Wamego and Kansas City, Kansas, during three synoptic surveys conducted between November 2001 and August 2002. The analytical results from these samples indicated that ammonia and other nutrient concentrations and fecal coliform bacteria densities increased in the Kansas River from Wamego to Kansas City. Point sources were the primary contributors of ammonia and fecal coliform bacteria during low-flow conditions. Generally, ammonia concentrations in the Kansas River were largest at sampling sites just downstream from WWTFs. Overall, ammonia concentrations in the Kansas River, tributaries, and WWTF effluent were larger in the winter than during the summer. None of the main-stem sample concentrations exceeded the State of Kansas pH- and temperature-dependent chronic aquatic-life criteria for ammonia during the sampling periods. Other nutrients, such as total nitrogen and total phosphorus, indicated a similar, but less variable, spatial pattern along the main stem of the Kansas River, with concentrations increasing slightly downstream from major WWTFs. The temporal variance defined by the results of synoptic survey III (July 22–August 8, 2002) indicated that ammonia concentrations in the Kansas River sometimes varied daily by as much as 155 percent at a single site. Samples analyzed for densities of fecal coliform bacteria illustrated a seasonal, spatial, and temporal pattern slightly different from that of nutrients. Overall, the bacteria densities measured during the summer were larger than the densities measured in the winter. The only fecal coliform bacteria density to exceed the former State water-quality, single-sample criteria of 2,000 col/100 mL (colonies per 100 milliliters of water) was measured at 4,000 col/100 mL during synoptic III (summer 2002) on the main stem of the Kansas River at Kansas City. Temporal variability measured during synoptic survey III indicated up to a 263-percent difference in bacteria density over a 12-day period. Instantaneous loads of ammonia and bacteria were computed to determine primary inputs to the Kansas River and ammonia and bacteria decay rates in the river. The Oakland WWTF in Topeka was the largest contributor of both ammonia and bacteria on the basis of samples collected during the three synoptic surveys, except for fecal coliform bacteria collected during synoptic survey III when the DeSoto WWTF was discharging the largest concentration of bacteria. The ammonia assimilative process was about twice as effective during the summer synoptic survey than it was during the winter survey. Decay of fecal coliform bacteria density was less evident and appeared to have little seasonal effect on the basis of data collected for this report. The summer low-streamflow water-quality conditions were suitable for nitrification, algae that consume ammonia, and consequently, decaying organic matter that consume oxygen. The consumption of dissolved oxygen due to nitrification and decaying algae contributed to three measurements of dissolved oxygen that were less than the State of Kansas aquatic-life-support use criteria of 5.0 milligrams per liter. CE–QUAL–W2, a two-dimensional, hydrodynamic and water-quality model, was used to simulate ammonia and bacteria transport in the Kansas River from Topeka to Kansas City. The model was calibrated and verified using data from the three synoptic surveys. The calibrated model successfully simulated the hydrodynamics, water temperature, dissolved oxygen, ammonia, and fecal coliform bacteria in the Kansas River. Simulated in-stream ammonia concentrations were compared to measured concentrations upstream to downstream along the Kansas River. The simulated in-stream ammonia concentrations mostly overestimated the measured values for both winter and summer, with a few exceptions. Comparisons between measured and simulated in-stream ammonia concentrations indicated ammonia assimilation was simulated more accurately in the summer than during the winter. Four hypothetical simulations of varied effluent discharges from existing WWTFs and addition of a proposed WWTF near DeSoto were simulated to better understand future water-quality conditions in the Kansas River. Results indicated that ammonia and dissolved-oxygen concentrations in the Kansas River will decrease from the conditions observed during synoptic surveys II (February 25 through March 1, 2002) and III (July 22 through August 8, 2002) except near the proposed WWTF where concentrations of ammonia would be near or exceed criteria for waterborne species. Effects of the proposed WWTF on dissolved oxygen would result in concentrations less than the State of Kansas aquatic-life-support use criteria of 5.0 milligrams per liter for 1 to 2 miles downstream from either of the proposed sites.

Kansas↗
USGS2005

Surface water-quality and water-quantity data from selected urban runoff-monitoring sites at the Rocky Mountain Arsenal, Commerce City, Colorado, water years 1988-2004

The U.S. Geological Survey has monitored the quality and quantity of streamflow at the Rocky Mountain Arsenal (RMA) northeast of Denver, Colorado, since the early 1990s in cooperation with the U.S. Army. This report, prepared in cooperation with the U.S. Fish and Wildlife Service, documents existing surface-water-quality conditions on the RMA. All RMA water-quality data for the Irondale Gulch and First Creek Basins adjacent to and on the RMA were reviewed. Where applicable, water-quality data were compared to State standards established by the Colorado Department of Public Health and Environment. At both the Havana Interceptor below 56th Avenue gaging station and the Uvalda Interceptor below 56th Avenue gaging station, all of the dissolved-oxygen concentrations met the State standard requiring at least 5.0 milligrams per liter (mg/L) of dissolved oxygen for the protection of aquatic life. In contrast, the dissolved-oxygen concentrations at the Peoria Interceptor below 56th Avenue gage commonly were less than 5.0 mg/L. Excluding one suspect concentration of 1.6 mg/L, the dissolved-oxygen concentrations for the First Creek Basin ranged from 4.2 to 12.6 mg/L. Excluding the one suspect value, three dissolved-oxygen concentrations failed to meet the State standard of 5.0 mg/L at the First Creek below Buckley Road site. At the Peoria Interceptor below 56th Avenue site, all pH values were within the range specified by the State standard (6.50-8.99). Results of seven sampling events at the Havana Interceptor below 56th Avenue gaging station indicated a pH greater than or equal to 9 (pH values of 9 or greater exceed the upper limit of the standard). No sampling events indicated a pH less than 6.50. Results from one sampling event at the Uvalda Interceptor below 56th Avenue indicated pH values outside the range specified by the State standard. The concentrations obtained for chloride, magnesium, and sodium generally were below 200 mg/L at all three Irondale Gulch monitoring stations for the entire period of record, but there were a few sampling events at each of these sites where much higher concentrations for these analytes were obtained. The median concentrations for calcium, magnesium, and sodium generally were higher at the First Creek below Buckley Road site than in the three Irondale Gulch sites, while the 90th percentile and maximum concentrations for magnesium and sodium generally were higher at the three Irondale Gulch sites than at the First Creek below Buckley Road site. The urban runoff flowing onto the RMA had low concentrations and few, if any, detections for most organic contaminants. Part of the reason for low detections of organic contaminants may be in how the samples are collected. The existing surface-water sampling program was not designed specifically to target storm runoff and therefore does not characterize water quality for all hydrologic regimes, most notably storm runoff. As a result, the existing data may not adequately represent potential contaminant transport onto the RMA. In addition, during stormwater-runoff events, the sites examined for this report frequently are subject to sharp increases in discharge, and just as quickly the discharge rapidly recedes. These types of transient flow events make water-quality sampling difficult, and none of the sites have a safe place to sample the higher flows that occur in any given year. As a result, most of the surface-water-quality samples were collected after the flow had decreased substantially from the peak flow, which may have transported much of the chemical contaminant load through the system. Thus, little is known about the water quality during the critical initial stormwater-runoff period when contaminants are most likely to be mobilized and transported through the stormwater conveyances past the locations where gaging stations are located.

Colorado↗
USGS2007

Effect of Drought on Streamflow and Stream-Water Quality in Colorado, July through September 2002

During 2002, Colorado experienced the State's worst drought since 1977. In 2003, the U.S. Geological Survey entered into cooperative agreement with the Colorado Department of Public Health and Environment to evaluate the general effects of drought on the water quality of streams in Colorado during summer 2002 by analyzing a water-quality data set obtained during summer 2002 in cooperation with a variety of State and local governments. Water samples were collected at 148 stream sites in Colorado and were measured or analyzed for field properties, major ions, nutrients, organic carbon, bacteria, and dissolved and total recoverable metals. Mean annual streamflow was analyzed at 134 sites in Colorado, and mean summer (July-September) streamflow for 2002 was determined for 146 sites for water years 1978-2002. Mean annual streamflow for 2002 had an average percentile of 29.4 and mean summer streamflow for 2002 had an average percentile of 7.6 relative to 1978-2002. These results indicate that streamflow in Colorado was substantially less than median streamflow for the period and that the effect of drought on streamflow was greater during summer 2002 than during water year 2002 (October 1, 2001, through September 30, 2002). Few measured constituent concentrations or values were elevated or depressed on a widespread basis during summer 2002. Specific conductance was elevated (in the upper quartile relative to historical data) in five of the seven basins that had sufficient data for characterization, indicating that specific conductance likely was affected by drought in those basins. Chloride concentrations were elevated in three of five basins with sufficient data and indicate that chloride concentration generally was affected by drought in those basins. Sulfate concentration was elevated in four of six basins with sufficient data. The widespread elevation of specific conductance and concentrations of chloride and sulfate indicates that salinity generally was affected by drought in Colorado streams during July-September 2002, likely because streamflow at most sites was dominated by base flow of ground water, which usually has substantially greater salinity compared to runoff from precipitation. Total-recoverable iron and manganese concentrations were depressed (in the lower quartile of historical data) in the Arkansas River Basin, which likely was due to reduced land-surface washoff of sediment containing oxyhydroxides of these metals. Of the 246 water samples collected at 148 sites during the summer of 2002, constituents in 115 exceeded Colorado water-quality standards. Constituents that exceeded water-quality standards were pH (all 9.0 standard unit exceedances; 9 samples), chloride (1 sample), sulfate (9 samples), dissolved ammonia (10 samples), dissolved nitrite nitrogen (3 samples), E. coli (Escherichia coli) bacteria (34 samples, 20 in Arkansas River Basin), fecal-coliform bacteria (18 samples, all in Arkansas River Basin), dissolved copper (1 sample), dissolved iron (3 samples), total-recoverable iron (3 samples), dissolved manganese (13 samples), dissolved selenium (10 samples), and dissolved zinc (1 sample). Of these 115 exceedances, historical data were sufficient to conclude that 21 probably were affected by drought, that 39 probably were not affected by drought, and that 55 were of indeterminate nature. Specific conductance indicates that the San Juan River Basin (average percentile 95.2) experienced the greatest effects of drought on water quality during summer 2002 compared to other basins in Colorado, followed by the Upper Colorado (90.0) and Dolores River (85.7) Basins. The South Platte River Basin (70.9) experienced the least effect of drought, and the Yampa and White River Basin group (73.7) had the second smallest effect. The Gunnison River (82.1) and Arkansas River (81.2) Basins had intermediate drought effects. The Rio Grande had insufficient data to rank the relative effect of drought on salinity.

Scientific Investigations Report↗
USGS2007

Assessment of biological conditions at selected stream sites in Johnson County, Kansas, and Cass and Jackson Counties, Missouri, 2003 and 2004

Macroinvertebrate samples were collected at 15 stream sites representing 11 different watersheds in Johnson County, Kansas, in 2003 and 2004 to assess biological conditions in streams and relations to environmental variables. Published data from an additional seven stream sites, one in Johnson County, Kansas, and six others in adjacent Cass and Jackson Counties in Missouri also were evaluated. Multimetric scores, which integrated a combination of measures that describe various aspects of biological community abundance and diversity, were used to evaluate and compare the biological health of streams. In addition, for 15 of 16 Johnson County stream sites, environmental data (streamflow, precipitation, and land use) and water- and sediment-quality data (primarily nutrients, indicator bacteria, and organic wastewater compounds) were used in statistical analyses to evaluate relations between macroinvertebrate metrics and variables that may affect them. The information is useful for defining current conditions, evaluating conditions relative to State aquatic-life support and total maximum daily load requirements, evaluating effects of urbanization, developing effective water-quality management plans, and documenting changes in biological condition and water quality. Biological conditions in selected Johnson County streams generally reflected a gradient in the degree of human disturbances upstream from the sites, including percentage of urban and agricultural land use as well as the presence, absence, and proximity of wastewater treatment discharges. In this report, the term gradient is used to describe a continuum in the conditions (biological, environmental, or land use) observed at the study sites. Upstream Blue River sites, downstream from primarily agricultural land use, consistently scored among the sites least impacted by human disturbance, and in some metrics these sites scored higher than the State reference site (Captain Creek). The term impact, as used in this report, refers to a negative biological response at a site associated with one or more human-induced sources of disturbance or stress. However, no sites, including the Captain Creek reference site, met Kansas Department of Health and Environment criteria for full support of aquatic life during the 2 years of sample collection. Upstream sites on Kill and Cedar Creeks also consistently scored among the least impacted. Sites less than 3 miles downstream from municipal wastewater treatment facility discharges (two Indian Creek sites) and sites with no wastewater discharge but with substantial impervious surface area within their respective watersheds (Tomahawk, Turkey, and Brush Creeks) consistently scored among the sites most impacted by human disturbance.

Scientific Investigations Report↗
USGS2007

Water quality on the Prairie Band Potawatomi Reservation, northeastern Kansas, June 1996 through August 2006

This report describes surface- and ground-water-quality data collected on the Prairie Band Potawatomi Reservation in northeastern Kansas from November 2003 through August 2006 (hereinafter referred to as the "current study period"). Data from this study period are compared to results from June 1996 through August 2003, which are published in previous reports as part of a multiyear cooperative study with the Prairie Band Potawatomi Nation. Surface and ground water are valuable resources to the Prairie Band Potawatomi Nation as tribal members currently (2007) use area streams to fulfill subsistence hunting and fishing needs and because ground water potentially could support expanding commercial enterprise and development. Surface-water-quality samples collected from November 2003 through August 2006 were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, fecal-indicator bacteria, suspended-sediment concentration, and total suspended solids. Ground-water samples were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, and fecal-indicator bacteria. Chemical oxygen demand and volatile organic compounds were analyzed in all three samples from one monitoring well located near a construction and demolition landfill on the reservation, and in one sample from another well in the Soldier Creek drainage basin. Previous reports published as a part of this ongoing study identified total phosphorus, triazine herbicides, and fecal coliform bacteria as exceeding their respective water-quality criteria in surface water on the reservation. Previous ground-water assessments identified occasional sample concentrations of dissolved solids, sodium, sulfate, boron, iron, and manganese as exceeding their respective water-quality criteria. Fifty-six percent of the 55 surface-water samples collected during the current study period and analyzed for total phosphorus exceeded the goal of 0.1 mg/L (milligram per liter) established by the U.S. Environmental Protection Agency (USEPA) to limit cultural eutrophication in flowing water. Concentrations of dissolved solids frequently exceeded the USEPA Secondary Drinking-Water Regulation (SDWR) of 500 mg/L in samples from two sites. Concentrations of sodium exceeded the Drinking-Water Advisory of 20 mg/L set by USEPA in almost 50 percent of the surface-water samples. All four samples analyzed for atrazine concentrations showed some concentration of the pesticide, but none exceeded the Maximum Contaminant Level (MCL) established for drinking water by USEPA of 3.0 µg/L (micrograms per liter) as an annual average. A triazine herbicide screen was used on 55 surface-water samples, and triazine compounds were frequently detected. Triazine herbicides and their degradates are listed on the USEPA Contaminant Candidate List. In 41 percent of surface-water samples, densities of Escherichia coli ( E. coli ) bacteria exceeded the primary contact, single-sample maximum in public-access bodies of water (1,198 colonies per 100 milliliters of water for samples collected between April 1 and October 31) set by the Kansas Department of Health and Environment (KDHE). Nitrite plus nitrate concentrations in all three water samples from 1 of 10 monitoring wells exceeded the MCL of 10 mg/L established by USEPA for drinking water. Arsenic concentrations in all three samples from one well exceeded the proposed MCL of 10 µg/L established by USEPA for drinking water. Boron also exceeded the drinking-water advisory in three samples from one well, and iron concentrations were higher than the SDWR in water from four wells. There was some detection of pesticides in ground-water samples from three of the wells, and one detection of the volatile organic compound diethyl ether in one well. Concentrations of dissolved solids exceeded the SDWR in 20 percent of ground-water samples collected during the current study period, and concentrations of sulfate and chloride exceeded their respective SDWR in 10 percent of the ground-water samples. Concentrations exceeded the Drinking-Water Advisory Level set by USEPA for sodium in 50 percent of the ground-water samples. Results from the current study period remained similar to results from previous study periods. The median triazine herbicide concentration (triazine screen by ELISA) for the current study period decreased slightly compared to past study periods. In the event that ground water on the reservation is to be used as a drinking-water source, additional treatment may be necessary to remove excess dissolved solids, sulfate, sodium, and chloride.

Kansas↗
USGS2008

Summary and Evaluation of the Quality of Stormwater in Denver, Colorado, October 2001 to October 2005

Stormwater in the Denver area was sampled by the U.S. Geological Survey, in cooperation with the Urban Drainage and Flood Control District, in a network of five monitoring stations - three on the South Platte River and two on tributary streams, beginning in October 2001 and continuing through October 11, 2005. Composite samples of stormwater were analyzed at the U.S. Geological Survey National Water Quality Laboratory during water years 2003-2005 and the Metro Wastewater Reclamation District Laboratory during water year 2002 for water-quality properties such as pH, specific conductance, hardness, and residue on evaporation at 105 degrees Celsius; and for constituents such as major ions (calcium, chloride, fluoride, magnesium, potassium, sodium, and sulfate) in 2005, organic carbon and nutrients, including ammonia, nitrite plus nitrate, ammonia plus organic nitrogen, phosphorus, and orthophosphate; and for metals, including total and dissolved phases of copper, lead, manganese, and zinc. Samples analyzed for bacteriological indicators such as Escherichia coli and fecal coliform collected during selected storms also were analyzed at the Metro Wastewater Reclamation Laboratory. Discrete samples collected during selected storms were analyzed at the U.S. Geological Survey National Water Quality Laboratory for a suite of water-quality properties and constituents similar to those analyzed in the composite samples but that did not include determinations for total phases of metals. Streamflow characteristics associated with 176 composite stormwater samples indicate that most samples were collected from hydrographs classified as falling or event hydrographs and that only a few samples were collected from rising hydrographs. Results from laboratory analyses of the composite samples indicate spatial patterns in which concentrations for some constituents increase with contributing drainage area in the South Platte River and Sand Creek, but no well-defined relation with the amount of urban land cover was identified using data available from the U.S. Geological Survey National Land Cover data. Results from 22 discrete samples collected during two storms and used to obtain composited results with various weighting methods indicate that correlation coefficients between time-weighted and volume-weighted concentrations were generally at least 0.65, indicating a strong direct correlation between the two weighting methods for the stations involved in this study. In addition, the central tendency for relative percent differences between the time- and volume-weighting methods typically has an absolute value of about 10 or less, indicating good agreement for these weighting methods for data collected as part of this study. Comparison of stormwater results to numeric standards for streams developed by the Colorado Department of Public Health and Environment on the basis of use classifications indicates that, for water-quality properties and constituents other than bacteriological indicators, there were very few exceptions to numeric standards. Bacteriological indicators, however, such as Escherichia coli and fecal coliform consistently exceeded numeric standards in all bacteriological samples. An evaluation of laboratory results from composite samples on the basis of annual means indicates the presence of some simple upward and downward temporal trends in concentrations. In general, for annual means of results for all stations, hardness, ammonia plus organic nitrogen, total phosphorus, most dissolved metals (lead, manganese, and zinc), and all total metals (copper, lead, manganese, and zinc) all indicate annual means that decrease each year, or downward trends. Some trends were indicated only at individual stations in the network rather than at all stations. Ammonia as nitrogen at Union, Denver, and Henderson, orthophosphate at Sand Creek, and nitrite plus nitrate at Denver and Henderson all indicate decreasing annual means, or downward tr

Scientific Investigations Report↗