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Surface-Water and Ground-Water Resources of Kendall County, Illinois

Water-supply needs in Kendall County, in northern Illinois, are met exclusively from ground water derived from glacial drift aquifers and bedrock aquifers open to Silurian, Ordovician, and Cambrian System units. As a result of population growth in Kendall County and the surrounding area, water use has increased from about 1.2 million gallons per day in 1957 to more than 5 million gallons per day in 2000. The purpose of this report is to characterize the surface-water and ground-water resources of Kendall County. The report presents a compilation of available information on geology, surface-water and ground-water hydrology, water quality, and water use. The Fox River is the primary surface-water body in Kendall County and is used for both wastewater disposal and as a drinking-water supply upstream of the county. Water from the Fox River requires pretreatment for use as drinking water, but the river is a potentially viable additional source of water for the county. Glacial drift aquifers capable of yielding sufficient water for municipal supply are expected to be present in northern Kendall County, along the Fox River, and in the Newark Valley and its tributaries. Glacial drift aquifers capable of yielding sufficient water for residential supply are present in most of the county, with the exception of the southeastern portion. Volatile organic compounds and select trace metals and pesticides have been detected at low concentrations in glacial drift aquifers near waste-disposal sites. Agricultural-related constituents have been detected infrequently in glacial drift aquifers near agricultural areas. However, on the basis of the available data, widespread, consistent problems with water quality are not apparent in these aquifers. These aquifers are a viable source for additional water supply, but would require further characterization prior to full development. The shallow bedrock aquifer is composed of the sandstone units of the Ancell Group, the Prairie du Chien Group, the Galena-Platteville dolomite, the Maquoketa Group, and the Silurian dolomite where these units are at the bedrock surface. The availability of water from the shallow bedrock aquifer depends primarily on the geologic unit utilized. The Silurian dolomite, Galena-Platteville dolomite, and Ancell Group can yield sufficient water for residential and municipal supply in at least some parts of the county. The Cambrian-Ordovician aquifer system is composed of the most widespread, productive aquifers in northern Illinois and is used for water supply by a number of municipalities and industrial facilities. Water levels in the aquifer system have declined by as much as 600 feet in Kendall County and the aquifer frequently contains concentrations of radium above established health guidelines.

Scientific Investigations Report↗

A system for calibrating seepage meters used to measure flow between ground water and surface water

A system has been developed for generating controlled rates of seepage across the sediment-water interface representing flow between ground water and surface water. The seepage- control system facilitates calibration and testing of seepage measurement devices commonly called seepage meters. Two slightly different seepage-control systems were evaluated. Both designs make use of a 1.5-m-diameter by 1.5-m-tall polyethylene flux tank partially filled with sand that overlies a pipe manifold and diffuser plate to provide a uniform flux of water through the sand. The flux tank is filled with water to maintain a water depth above the sand bed of about 0.6 m. Flow is generated by routing water through tubing that connects an adjustable-height reservoir to the base of the flux tank, through the diffuser plate and sand, and across the sediment-water interface. Seepage rate is controlled by maintaining a constant water depth in the reservoir while routing flow between the reservoir and the flux tank. The rate of flow is controlled by adjusting the height of the reservoir with a manually operated fork lift. Flow from ground water to surface water (inflow) occurs when the water surface of the reservoir is higher than the water surface of the flux tank. Flow from surface water to ground water (outflow) occurs when the water surface of the reservoir is lower than the water surface of the flux tank. Flow rates as large as ±55 centimeters per day were generated by adjusting the reservoir to the extremes of the operable range of the fork lift. The minimum seepage velocity that the flowmeter can reliably measure is about 7 centimeters per day. Water in the reservoir is maintained at a nearly constant depth by pumping return flow between the reservoir and flux tanks based on output from a submersible pressure transducer placed in the reservoir. A datalogger switches the pump on and off at appropriate intervals to maintain a nearly constant water depth inside the reservoir, which maintains a virtually constant hydraulic gradient between the reservoir and flux tanks. The datalogger also records flow, in units of volume per time, as measured by an in-line flowmeter positioned between the base of the flux tank and the reservoir. Seepage flux in units of distance per time is determined by dividing the flowmeter output by the surface area at the sediment-water interface in the flux tank. Spatial heterogeneity in seepage was evident in both flux tanks in spite of attempts to minimize heterogeneity during tank construction. Medium sand was used in both flux tanks and care was taken to homogenize the sand during and after filling of the tanks. Time was provided for release or dissolution of trapped air, and water was circulated to remove fine-grained sediments prior to system use. In spite of these precautions, seepage measured with five to six small 20.25-cm-diameter seepage meters varied by about a factor of two. Use of larger diameter seepage meters, which cover a larger percentage of the sediment surface of the flux tanks, greatly minimized measured seepage heterogeneity. The seepage-control system was used to demonstrate that seepage-meter efficiency is sensitive to the type of seepage-meter bag and that bag-measured seepage rate is sensitive to the duration of the seepage-meter measurement only during very short measurement times. The in-line flowmeter used with this system is incapable of measuring seepage rates below about 7 centimeters per day. Smaller seepage rates can be measured manually. The seepage- control system also can be modified for measuring slower seepage rates with the use of two flowmeters and a slightly different water-routing system, or a fluid-metering pump can be used to control flow through the flux tank instead of an adjustable-height reservoir.

Scientific Investigations Report↗

Review of Trace Element Blank and Replicate Data Collected in Ground and Surface Water for the National Water-Quality Assessment Program, 1991-2002

The trace elements Sb, Be, and Tl in ground water and Sb, Be, Co, Mo, and U in surface water are unaffected by contamination. Limited quality control data (blanks) for Li and V in ground water and surface water do not allow for a good assessment on the potential contamination associated with these trace elements. Potential contamination was identified for Al, As, Ba, B, Cd, Cr, Cu, Fe, Pb, Mn, Ni, Se, Ag, Sr, and Zn in ground water and surface water. Evidence of potential contamination was shown for Co, Mo, and U in ground water; potential contamination was shown for T1 in surface water. In comparing the potential contamination for these trace elements with the U.S. Environmental Protection Agency's (USEPA) drinking-water standards, the contamination for most of these trace elements is less than 10 percent of the drinking-water standard; therefore, contamination would have little or no effect when comparing trace element concentrations with the USEPA drinking-water standards. The exceptions are Al, Cd, and possibly Pb in ground water, and As and possibly Pb in surface water. Potential contamination identified for these trace elements is greater than 10 percent of the USEPA drinking-water standard, but affects only 5 percent or less of the As, Cd, and Pb samples. For most trace elements, the level of potential contamination is not large enough to significantly affect the measured concentration of the environmental sample. The exceptions may be Fe in ground water and Al in surface water, which have concentrations for at least 10 percent of the environmental samples that exceeded the USEPA drinking-water standards. Sample variability for some of the trace elements could not be determined because there were either no detected concentrations, or there were less than 10 replicate sets with detected concentrations. These trace elements are Be, Ag, and Tl for ground water and Sb, Be, Cr, Co, Pb, Ag, and Tl for surface water. For most trace elements, sample variability was less than 10 percent, which would have little or no affect on the reported concentrations. The exceptions are Al, Cd, Cu, Pb, Rn (at concentrations less than about 700 picocuries per liter), Se, and Zn in ground water and Cu, Se, and Zn in surface water, all of which have sample variability ranging from 10 to 20 percent. Sample variability should be considered when evaluating the potential error associated with a sample measurement. Collection of additional quality control samples for some of these trace elements to determine bias and variability is probably warranted particularly for those trace elements that the NAWQA Program did not begin sampling until 1998. Results obtained from the analysis of the quality control data can be applied to the interpretation of the environmental data collected from 1991 to 2002 and for water-quality data that are currently being collected as part of the NAWQA Program. More...

Scientific Investigations Report↗

Water levels and water quality in the Mississippi River Valley alluvial aquifer in eastern Arkansas, 2012

During the spring of 2012, the U.S. Geological Survey, in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey, measured water levels in 342 wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas. The Arkansas Natural Resources Commission measured water levels in 11 wells, and the U.S. Department of Agriculture-Natural Resources Conservation Service measured water levels in 239 wells completed in the alluvial aquifer and provided these data to the Arkansas Natural Resources Commission. In 2010, estimated water withdrawals from the alluvial aquifer in Arkansas totaled about 7,592 million gallons per day. Withdrawals more than doubled between 1985 and 2010, about a 115-percent increase. The regional direction of groundwater flow is generally to the south and east except where flow is affected by groundwater withdrawals. East of Crowleys Ridge, water flows from north to south along Crowleys Ridge and northeast to southwest along the Mississippi River. West of Crowleys Ridge, water flows from northeast to southwest along Crowleys Ridge from Clay County to Craighead County. From Craighead County to Monroe County, a depression redirects groundwater flow from all directions. A depression in Arkansas, Lonoke, and Prairie Counties alters groundwater flow from all directions. South of the Arkansas River, the flow is towards the southeast, except near depressions in Lincoln and Desha Counties and Desha and Chicot Counties where flow is towards the depression. In 2012, the lowest water-level altitude was 73 feet (ft) in Arkansas County. The highest water-level altitude was 288 ft in northeastern Clay County on the western side of Crowleys Ridge. The 2012 potentiomentric-surface map shows eight depressions, two large depressions and six small depressions. One large depression begins in southeastern Arkansas County, at the Arkansas and Desha County line, extends north into Prairie County, west into Lonoke County, and east into the westernmost part of Monroe County. The area in Lonoke, Prairie, and White Counties in the northwestern half of the depression has a water-level altitude measurement of 90 ft and has expanded into the northern third of Prairie County. The 2012 potentiometric-surface map shows a general north-south depression with the southern end in central Monroe County through western Lee, St. Francis, Cross, Poinsett, and Craighead Counties and eastern Woodruff and Jackson Counties. There are two deeper areas in this depression, one at the Monroe and Lee County line, with a low water-level altitude measurement of 123 ft, and the second in Poinsett County, with a low water-level altitude measurement of 113 ft. The six small depressions are located in northern Ashley County, in southern Desha and northern Chicot Counties, in eastern Lincoln and western Chicot Counties, at the Arkansas and Desha County line, in northern Phillips County, and in southeastern Greene County. A map showing the difference in water levels was constructed using 541 differences in water levels measured during 2008 and 2012. The difference in measured water levels from 2008 to 2012 ranged from -27.4 ft to 18.7 ft, with a mean of -1.0 ft. The largest decline of -27.4 ft occurred in Lonoke County, and the largest rise of 18.7 ft occurred in Prairie County. Four areas were predominated by declines—west of Crowleys Ridge from Greene County south to Lee County, including Lawrence and southern Woodruff Counties; east of Crowleys Ridge from Clay County south to Poinsett County and Mississippi County; Lonoke and Jefferson Counties; and Ashley, Chicot, Desha, and Drew Counties. Three areas are predominated by rises in measured water levels—east of Crowleys Ridge in Crittenden, Cross, Lee, and St. Francis Counties; Jackson and northern Woodruff Counties; and Arkansas, Monroe, Phillips, Prairie, and White Counties. Long-term water-level changes were evaluated using hydrographs from 319 wells in the alluvial aquifer for the period from 1988 to 2012. The annual rise or decline in water level for the entire study area was -0.45 feet per year (ft/yr) with a range from -2.08 to 0.84 ft/yr. Arkansas County had two different rates of annual decline for the two hydrographs shown, about 0.97 ft/yr and about 0.26 ft/yr. In Craighead, Cross, Lee, Poinsett, and St. Francis Counties, water levels are declining at a greater rate in areas west of Crowleys Ridge than in areas east of Crowleys Ridge. Two hydrographs are shown in each of Craighead, Cross, Lee, Poinsett, and St. Francis Counties, one on the west side of Crowleys Ridge and one on the east side of Crowleys Ridge. The hydrographs west of Crowleys Ridge have annual water-level declines from -0.91 to -1.24 ft/yr. The hydrographs east of Crowleys Ridge have annual water-level declines from -0.07 to -0.40 ft/yr. The mean county annual water-level declines for these counties range from -0.55 to -0.87 ft/yr. Water samples were collected in the summer of 2012 from142 wells completed in the alluvial aquifer and measured onsite for specific conductance, temperature, and pH. Samples were collected from 94 wells for dissolved chloride analysis. Specific conductance ranged from 91 microsiemens per centimeter at 25 degrees Celsius (μS/cm at 25 °C) in Drew County to 984 μS/cm at 25 °C in Monroe County. The mean specific conductance was 547 μS/cm at 25 °C. Temperature ranged from 18.1 degrees Celsius (°C) in Crittenden County to 22.4 °C in Prairie County. The mean temperature was 22.1 °C. The pH ranged from 8.3 in Randolph County to 6.2 in Drew County and had a median of 7.3. Dissolved chloride concentrations ranged from 3.34 milligrams per liter (mg/L) in Randolph County to 182 mg/L in Lincoln County. The mean chloride concentration was 27.6 mg/L.

Arkansas↗

Surface-water-quality data to support implementation of revised freshwater aluminum water-quality criteria in Massachusetts, 2018–19

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed a study to inform the development of the department’s guidelines for the collection and use of water-chemistry data to support calculation of site-dependent aluminum criteria values. The U.S. Geological Survey collected and analyzed discrete water-quality samples at four wastewater-treatment facilities and seven water-treatment facilities in eastern and central Massachusetts from April 2018 through May 2019. For each of the 11 facilities considered, water-quality samples were collected from treatment-plant effluent and receiving-water bodies. Samples were collected for laboratory analysis of major ions (calcium and magnesium ions are used to calculate total hardness), dissolved organic carbon (DOC), total organic carbon (TOC), and total recoverable aluminum. Field parameters for pH, temperature, and specific conductance were measured in situ concurrently with sample collection. Water-quality conditions differed among monitoring stations. The highest pH values were observed for stations on the Assabet River that receive effluent discharges from wastewater-treatment facilities (the Westborough, Marlborough, Hudson, and Maynard wastewater-treatment facilities). High DOC concentrations (greater than 10 mg/L) were measured in water bodies associated with large areas of riparian wetlands—Lily Pond (Cohasset) and Third Herring Brook (Hanover), and low DOC concentrations (less than 2.5 mg/L) were measured at three water bodies in central Massachusetts—Hocomonco Pond (Westborough), Wyman Pond (Fitchburg), and Monoosnoc Brook (Leominster). Wyman Pond (Fitchburg), Monoosnoc Brook (Leominster), and Lily Pond (Cohasset) also had low pH values and low total hardness concentrations. The monthly discrete pH, DOC, and total hardness data for selected stations on receiving-water bodies were used in the U.S. Environmental Protection Agency Aluminum Criteria Calculator Version 2.0 to estimate site-dependent total recoverable aluminum concentrations that—if not exceeded—would be expected to protect fish, invertebrates, and other aquatic life from adverse effects associated with acute and chronic aluminum exposures. The U.S. Environmental Protection Agency Calculator output provides values for the acute criterion, defined as the criterion maximum concentration (CMC), an estimate of the highest aluminum concentration in surface water to which an aquatic community can be exposed briefly without resulting in an unacceptable effect. This output also provides values for the chronic criterion, defined as the criterion continuous concentration (CCC), an estimate of the highest concentration of aluminum in surface water to which an aquatic community can be exposed indefinitely without resulting in an unacceptable effect. To determine aluminum criteria values typically evaluated for use as protective water-quality criteria, the monthly instantaneous CMC and CCC values were used to calculate the minimum, 5th percentile, and 10th percentile CMC and CCC values for selected monitoring stations. The monthly instantaneous aluminum CMC and CCC values generated using the EPA Calculator varied among stations. Aluminum CMC and CCC values were highest for four ambient (upstream) stations on the Assabet River associated with wastewater-treatment facilities (Westborough, Marlboro, Hudson, and Maynard). Aluminum CMC and CCC values were lower for stations associated with water-treatment facilities, and lowest for selected ambient stations on Lily Pond, Monoosnoc Brook, and Wyman Pond associated with water-treatment facilities in Cohasset, Leominster, and Fitchburg, respectively. For many stations, the highest CMC and CCC instantaneous aluminum criteria values generated using the U.S. Environmental Protection Agency Calculator were for months during the growing season for algae and aquatic macrophytes (April or May through September or October) and the lowest values were for months during the nongrowing season (October or November through March or April), indicating the importance of collecting water-quality data during the nongrowing season. Aluminum CMC and CCC values generated by the U.S. Environmental Protection Agency Calculator are sensitive to variations in the input parameters (pH, DOC, and total hardness). Aluminum solubility is particularly affected by pH. To characterize diel and seasonal variations in pH, multiparameter water-quality monitors recording continuous (15-minute interval) water temperature and pH were installed in the receiving-water body for one station near each facility upstream from the effluent discharge (in rivers) or at a station outside the immediate effect of effluent discharge (in ponds). Continuous water temperature and pH data were collected from April or May 2018 through November or December 2018. Continuous pH data indicated that the pond stations and Assabet River stations had large diel variations in pH during the growing season. Continuous pH data were used together with discrete DOC and total hardness data to evaluate the potential effect of diel variations in pH on calculated site-dependent aluminum criteria values. For the 11 stations, diel variations in pH were determined to correspond to differences in the 10th percentile of CMC values by a median of 160 μg/L, ranging from 0 to 610 μg/L, and differences in the 10th percentile of CCC values by a median of 40 μg/L, ranging from 15 to 210 μg/L. The low monthly instantaneous CMC and CCC values that have the greatest effect on the minimum, 5th percentile, and 10th percentile aluminum values tend to result during the nongrowing season (October or November through March or April) when the range of diel variations in pH is small, thus minimizing the effect of diel variations in pH on the lowest CMC and CCC values. Historical water-quality data on organic carbon in Massachusetts streams were investigated using data retrieved from the USGS National Water Information System database. An assessment of the availability of historical pH, DOC, and hardness data indicated that more data were available for TOC than for DOC. A linear regression equation was developed for the relation between DOC and TOC concentrations to inform the potential use of available data to evaluate water-quality conditions at additional sites across Massachusetts where only pH, hardness, and TOC data are available. DOC and TOC concentrations were well correlated in the 223 samples in which both constituents were analyzed, and the equation had a coefficient of determination ( R 2 ) equal to 0.93.

Massachusetts↗

Water-withdrawal and groundwater-level fluctuations, physical and infiltration characteristics of Ohio River sediment, and isotope-based estimates of water sources relative to a riverbank filtration system in an alluvial aquifer, Louisville, Kentucky, 2000–20

The U.S. Geological Survey and the Louisville Water Company, from 2000 to 2020, cooperatively investigated physical and hydrologic conditions in the Ohio River alluvial aquifer and adjacent riverbed sediments in the northeast part of Louisville, Kentucky, to increase knowledge of processes affecting water sources to collector wells during operation of a riverbank filtration system (RBF). The RBF, in 2020, included an initial collector well (CW1) completed in 1999 and a tunnel and collector well system (TCWS) composed of four collector wells (CW2–CW5) completed in late 2010 that were connected by a tunnel that routed water to a pumping station and a treatment plant. Daily mean water-withdrawal rates typically ranged from about 10.4 to 20.7 million gallons per day (Mgal/d) from 2005 to 2007, then were cyclic from 2008 to 2010 and ranged from as low as about 9 to 13 Mgal/d in winter-spring months up to about 19 to 20 Mgal/d in summer-autumn months. From 2011 through 2017, peak daily mean water-withdrawal rates from CW2–CW5 fluctuated between winter-spring lows of about 20–30 Mgal/d to summer-autumn peak rates of about 41.6 Mgal/d in 2013 to about 48.2 Mgal/d in 2012. From 2017 to 2020, TCWS peak daily mean water-withdrawal rates decreased from about 45.7 Mgal/d in 2017 to about 37.5 Mgal/d in 2020 and peak daily mean rates from CW1 ranged from about 20.7 Mgal/d in 2020 to about 21.6 Mgal/d in 2018. Periods in 2019–20 with tunnel pumping station daily mean water-withdrawal rates smaller than about 30 Mgal/d had generally stable water levels in CW2 and indicated the sustainable yield of the TCWS collector wells under the prevailing hydrologic conditions. Drawdown during July–August of 2008 and 2009 was associated with CW1, the sole operating collector well. Groundwater-flow directions outside the CW1 cone of depression during July–August of 2008 and 2009 were from areas near the alluvial valley margin toward the Ohio River and in 2009 toward Harrods Creek. Collector wells CW2 through CW5 derived water during 2011–19 surveys from surface-water infiltration, as indicated by drawdown that extended beneath the Ohio River and Harrods Creek. Increases in drawdown toward the alluvial valley margins in July–August of 2013 and 2015, compared with July 2011, indicated less available recharge from those flow directions and decreased yield of groundwater from the aquifer after progressively longer TCWS water withdrawals. Drawdown at CW2–CW5 and at observation wells between them lessened in October 2019 and indicated that onshore groundwater levels can recover when collector well withdrawals decrease. Overlapping cones of depression in 2011–15 potentiometric surfaces centered around CW2, CW3, CW4, and CW5, and drawdown along divides between those wells indicated well interference between collector wells. Well-interference effects increased during 2013 and 2015 survey periods, despite decreased water-withdrawal rates compared with July 2011, and expanded to include CW1 when its use resumed. Groundwater-level fluctuations in observation wells near the Ohio River were consistent with gradual depletion of groundwater yield during tunnel pumping station operation at river elevations of about 420 feet above the National Geodetic Vertical Datum of 1929 (NGVD 29) and enhanced recharge of the aquifer when river elevations were above flood stage of about 430 feet above NGVD 29. Groundwater-level declines in observation wells near the Ohio River were most apparent in summer and some autumn months between 2012 and 2017 during periods when tunnel pumping station mean daily water-withdrawal rates were about 35 Mgal/d or more. Periods of relatively stable groundwater levels during 2019–20 in observation wells between CW2–CW5, when tunnel pumping station water-withdrawal rates were about 30–33 Mgal/d or less, also indicated that the prevailing sustainable yield was about 30 Mgal/d or less. Wells associated with CW3 and CW4 had the largest increases in slopes of best-fit lines relating water-level difference to water-withdrawal rate between 2012 and 2020, an indication of decreased efficiencies of those wells to supply water or of changes in groundwater yield around the well. Increased slopes of best-fit lines relating water-level difference to water-withdrawal rate from 2019 to 2020, when groundwater levels were otherwise relatively stable, also indicated that the specific capacity of one or more TCWS collector wells may have declined during that period. Riverbed surface elevation, roughness, and hardness changes between hydroacoustic surveys indicated active accretion and erosion of bed sediment offshore from the riverbank filtration system in 2002–4. Riverbed hydraulic conductivity computed from 2013 to 2015 in tests at 11 sites ranged from 0.2 to 230 feet per day. Ten temporary piezometer sites with adjacent operating collector wells had drawdowns that ranged from about 4 to 11.7 feet and hammer blows greater than or equal to 49 counts, which indicated a relatively great density of alluvial sediments and the potential for diminished riverbed infiltration rates. Contributions of Ohio River infiltration to collector wells estimated from deuterium and oxygen-18 isotopic ratios in representative Ohio River and groundwater samples were considerably larger in warmer months than cooler months and ranged from 80–90 percent in CW1–CW5 in May 2020 to 100 percent in May 2019 at CW2, CW4, and CW5. Groundwater contributions to water withdrawals by collector wells increased in cooler autumn months and ranged from 40 percent at CW3 and CW5 in November 2020 to 70 percent at CW2, CW4, and CW5 in November–December 2019. November 2019 and November 2020 isotopic compositions of water from the collector wells had enriched deuterium and oxygen-18 isotopic ratios consistent with mixtures of evaporation-modified water from the Ohio River and meteoric-origin groundwater.

Indiana, Kentucky↗

Water quality and geochemical modeling of water at an abandoned coal mine reclaimed With coal combustion by-products

An abandoned coal mine in eastern Ohio was reclaimed with 125 tons per acre of pressurized fluidized bed combustion (PFBC) by-product. Water quality at the site (known as the Fleming site) was monitored for 7 years after reclamation; samples included water from soil-suction lysimeters (interstitial water), wells, and spring sites established downgradient of the application area. This report presents a summary of data collected at the Fleming site during the period September 1994 through June 2001. Additionally, results of geochemical modeling are included in this report to evaluate the potential fate of elements derived from the PFBC by-product. Chemical analyses of samples of interstitial waters within the PFBC by-product application area indicated elevated levels of pH and specific conductance and elevated concentrations of boron, calcium, chloride, fluoride, magnesium, potassium, strontium, and sulfate compared to water samples collected in a control area where traditional reclamation methods were used. Magnesium-to-calcium (Mg:Ca) mole ratios and sulfur-isotope ratios were used to trace the PFBC by-product leachate and showed that little, if any, leachate reached ground water. Concentrations of most constituents in interstitial waters in the application-area decreased during the seven sampling rounds and approached background concentrations observed in the control area; however, median pH in the application area remained above 6, indicating that some acid-neutralizing capacity was still present. Although notable changes in water quality were observed in interstitial waters during the study period, quality of ground water and spring water remained poor. Water from the Fleming site was not potable, given exceedances of primary and secondary Maximum Contaminant Levels (MCLs) for inorganic constituents in drinking water set by the U.S. Environmental Protection Agency. Only fluoride and sulfate, which were found in higher concentrations in application-area interstitial waters than in control-area interstitial waters, could be related to the PFBC by-product. Concentrations of arsenic, lead, and selenium typically were at or below the detection limits (generally 1 or 2 micrograms per liter). Elements detected at elevated concentrations in PFBC by-product application-area interstitial waters were not evident in downgradient ground water or spring water. Dilution of leachate by ground water was confirmed with a mixing model generated by the computer code NETPATH. Additionally, thermodynamic modeling of the chemical composition of water samples by use of the computer code PHREEQC indicated favorable conditions for precipitation of secondary minerals in the unsaturated zone and in aquifer materials. Because of low application rates of PFBC by-product and precipitation and sorption of elements in the unsaturated zone, it is improbable that concentrations of any toxic elements of concern (arsenic, lead, or selenium) will exceed drinking-water standards at this site or other sites where similar volumes of PFBC by-products are used.

Water-Resources Investigations Report↗

Environmental setting, water quality, and ecological indicators of surface-water quality in the Mermentau River Basin, southwestern Louisiana, 1998-2001

The U.S. Geological Survey collected data from 29 wells and 24 surface-water sites in the Mermentau River Basin, 1998-2001, to better understand ground-water and surface-water quality; aquatic invertebrate communities; and habitat conditions, in relation to land use. This study was apart of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Water-quality data were evaluated with criteria established for the protection of drinking water and aquatic life, and bed-sediment data were compared to aquatic life criteria. Water-quality and ecological data were analyzed statistically in relation to drainage area and agricultural land-use integrity. Concentrations of nutrients and major inorganic ions in ground water and surface water generally were highest in the southeastern part of the study area where soils contain thick loess deposits. Peak concentrations of nutrients in surface water occurred March-may at two sites with high agricultural intensity; the lowest concentrations occurred August-January. The greatest potential for eutrophic conditions in surface water, based on nutrient concentrations, existed March-May, at about the same time or shortly after ricefields were drained. Secondary Maximum Contaminant Levels established by the U.S. Environmental Protection Agency (USEPA) were exceeded for sulfate, chloride, iron, or manganese in samples from 20 wells, and for iron or manganese in samples from all surface-water sites. Fewer pesticides were detected in ground water than in surface water. In 11 of of the 29 wells sampled, at least one pesticide or pesticide degradation product was detected. The most frequently detected pesticides or pesticide degradation products in ground water were the herbicides benzaton and atrazine. Concentrations of 47 pesticides and degradation products were detected in surface water. At least 3 pesticides were detected in all surface-water samples. In 72 percent of the samples at least 5 hydrophilic pesticides were detected, and in more than 70 percent of the samples at least 3 hydrophobic pesticides were detected. Although atrazine concentrations in three samples collected in the spring exceeded 3 micrograms per liter, the USEPA Maximum Contaminant Level of 3 micrograms per liter was not exceeded because it is based on an annual average of quarterly samples. Concentrations larger than 3.0 micrograms per liter were not detected in samples collected during other times of the year. Tebuthiuron was detected at all surface-water sites; the largest concentration (6.33 micrograms per liter) was detected at a site on Bayou des Cannes, and was the only detection that exceeded the criterion (1.6 micrograms per liter) for the protection of aquatic life. Malathion was detected at 16 surface-water sites; the largest concentration (0.113 micrograms per liter) was detected at a site on Bayou Lacassine and was the only detection that exceeded the criterion (0.1 micrograms per liter) for the protection of aquatic life. Concentrations of fipronil exceeded numeric targets for acute total maximum daily loads (2.3 micrograms per liter) at 3 sites and chronic total maximum daily loads (4.6 micrograms per liter) at 14 sites. Maximum pesticide concentrations in surface water usually occurred in the spring at about the same time or shortly after ricefields were drained. Concentrations of DDE in bed sediment at two sites exceeded interim freshwater sediment quality guidelines for the protection of aquatic life. Fipronil sulfide and desulfinylpronil were detected at all 17 sites from which bed-sediment samples were collected, but there are no current (2002) guidelines with which to evaluate the environmental effects of fipronil and degradation products. Two methods were used to group the ecological data-collection sites: (1) Sites were grouped before data collection (according to the study design) using drainage area

Water-Resources Investigations Report↗

Aquifer-test results, direction of ground-water flow, and 1984-90 annual ground-water pumpage for irrigation, lower Big Lost River Valley, Idaho

The study area (see index map of Idaho), part of the Big Lost River drainage basin, is at the northern side of the eastern Snake River Plain. The lower Big Lost River Valley extends from the confluence of Antelope Creek and the Big Lost River to about 4 mi south of Arco and encompasses about 145 mi 2 (see map showing water-level contours). The study area is about 18 mi long and, at its narrowest, 4 mi wide. Arco, Butte City, and Moore, with populations of 1,016, 59, and 190, respectively, in 1990, are the only incorporated towns. The entire study area, except the extreme northwestern part, is in Butte City. The study area boundary is where alluvium and colluvium pinch out and abut against the White Knob Mountains (chiefly undifferentiated sedimentary rock with lesser amounts of volcanic rock) on the west and the Lost River Range (chiefly sedimentary rock) on the east. Gravel and sand in the valley fill compose the main aquifer. The southern boundary is approximately where Big Lost River valley fill intercalates with or abuts against basalt of the Snake River Group. Spring ground-water levels and flow in the Big Lost River depend primarily on temperature and the amount and timing of precipitation within the entire drainage basin. Periods of abundant water supply and water shortages are, therefore, related to the amount of annual precipitation. Surface reservoir capacity in the valley (Mackay Reservoir, about 20 mi northwest of Moore) is only 20 percent of the average annual flow of the Big Lost River (Crosthwaite and others, 1970, p. 3). Stored surface water is generally unavailable for carryover from years of abundant water supply to help relieve drought conditions in subsequent years. Many farmers have drilled irrigation wells to supplement surface-water supplies and to increase irrigated acreage. Average annual flow of the Big Lost River below Mackay Reservoir near Mackay (gaging station 13127000, not shown) in water years 1905, 1913-14, and 1920-90 was about 224,600 acre-ft; average annual flow of the Big Lost River near Arco (gaging station 13132500; see map showing water-level contours) in water years 1947-61, 1967-80, and 1983-90 was about 79,000 acre-ft (Harenberg and others, 1991, p. 254-255). Moore Canal and East Side Ditch divert water from the Big Lost River at the Moore Diversion, 3 mi north of Moore (see map showing water-level contours) and supply water for irrigation near the margins of the valley. When water supply is average or greater, water in the Big Lost River flows through the study area and onto the Snake River Plain, where it evaporates or infiltrates into the Snake River Plain aquifer. When water supply is below average, water in the Big Lost River commonly does not reach Arco; rather, it is diverted for irrigation in the interior of the valley, evaporates, or infiltrates to the valley-fill aquifer. This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, to collect hydrologic data needed to help address water-supply problems in the Big Lost River Valley. Work involved (1) field inventory of 81 wells, including 46 irrigation wells; (2) measurement of water levels in 154 wells in March 1991; (3) estimation of annual ground-water pumpage for irrigation from 1984 through 1990; and (4) analysis of results of an aquifer test conducted southwest of Moore. All data obtained during this study may be inspected at the U.S. Geological Survey, Idaho District office, Boise.

Idaho↗

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management: Water-quality study of the Conestoga River headwaters, Pennsylvania

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection1 , conducted a study as part of the U.S. Department of Agriculture's Rural Clean Water Program to determine the effects of agricultural best-management practices on surface-water and ground-water quality in the Conestoga River headwaters basin. This report describes Field-Site 1 and characterizes the surface-runoff and ground-water quantity and quality at the site from January 1983 through September 1984, before the implementation of terracing and nutrient-management best-management practices. The 22.1-acre site, part of two dairy farms, was cropland used primarily for the production of corn and alfalfa, and is underlain by carbonate rock. During the 21-month study period, 91.2 inches of precipitation fell, of which 66 percent occurred during the 1984 water year. Of the 169 storms of 0.10 inch or larger, 97 produced measurable runoff. The average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. About three times more nutrients were applied during 1984 water year than during the 1983 water year. The approximate soil-nitrate concentration as nitrogen for the study period was 8.2 milligrams per kilogram in the top 8 inches of soil. Runoff for the study period totalled 714,000 cubic feet, or 9.8 percent of total precipitation. Eighty-eight percent of the runoff occurred during the 1984 water year. Regression analyses indicate that total runoff was controlled primarily by total precipitation amounts during storms and by antecedent moisture conditions; mean event and maximum instantaneous discharges are controlled by precipitation intensity and by antecedent moisture conditions. Regression analyses also suggest that crop cover on the corn acreage affected runoff amounts and rates. Mean concentrations in runoff ranged from 24 to 73,000 milligrams per liter for suspended sediment, 0.45 to 24 milligrams per liter for total phosphorus, and 1.5 to 55 milligrams per liter for total nitrogen. Of the total nitrogen in instantaneous runoff samples, a median of 72 percent was total organic nitrogen. Results of multiple regression analyses suggest that mean nitrogen concentrations in runoff (1) increased with increased surface-nitrogen applications made prior to runoff, and (2) were diluted with increased precipitation duration. Runoff from storms on frozen ground produced the highest loads of nitrogen in runoff. Over the 21-month study period, an estimated 258 tons of suspended sediment, 314 pounds of nitrogen, and 176 pounds of phosphorus were transported with runoff from the site. Of this, 88 percent of the nitrogen and phosphorus loads and 94 percent of the suspended-sediment load were discharged during the wet 1984 water year. The loads for the study period represent 2.5 percent of the total nitrogen and 5.5 percent of the total phosphorus applied to the site as manure and commercial fertilizer. The ground-water basin at the site is slightly larger than the surface-water basin. Ground-water levels, except at one well, responded quickly to recharge; water levels peaked several hours to a day after precipitation. Surface-applied materials moved rapidly to the water table through macropores and slowly by transport through micropores in the unsaturated zone. Median concentrations of dissolved nitrate ranged from 9.2 to 13 milligrams per liter as nitrogen for ground-water samples collected monthly from five wells and a spring. Dissolved nitrate comprised 93 percent (median percentage) of the total nitrogen in ground-water samples. The effect of recharge on ground-water nitrate concentrations was affected by variations in nutrient availability at the land surface and in the unsaturated zone. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. Approximately 3,187,000 cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground-water discharge, and 3 percent to surface runoff.

Pennsylvania↗

Water budgets, water quality, and analysis of nutrient loading of the Winter Park Chain of Lakes, central Florida, 1989-92, with a section on littoral vegetation

The Winter Park chain of lakes (Lakes Maitland, Virginia, Osceola, and Mizell) has a combined area of about 900 acres, an immediate drainage area of about 3,100 acres, and mean depths ranging from 11 to 15 feet. The lakes are an important recreational resource for the surrounding communities, but there is concern about the possible effects of stormwater runoff and seepage of nutrient-enriched ground water on the quality of water in the lakes. The lakes receive water from several sources: rainfall on lake surfaces, inflow from other surface-water bodies, stormflow that enters the lakes through storm drains or by direct runoff from land adjacent to the lakes, and ground-water seepage. Water leaves the lakes by evaporation, surface outflow, and ground-water outflow. Of the three, only surface outflow can be measured directly. Rainfall, surface inflow and outflow, and lake-stage data were collected from October 1, 1989, to September 30, 1992. Stormflow, evaporation and ground-water inflow and outflow were estimated for the 3 years of the study. Ground-water outflow was calculated by evaluating the rate of lake-stage decline during dry periods. Estimated ground-water outflow was compared to downward leakage rates estimated by ground-water flow models. Lateral ground-water inflow from surficial sediments was calculated as the residual of the flow budget. Flow budgets were calculated for the 3 years of the study. In water year 1992 (a year with about average rainfall), inflow consisted of rainfall, 48 inches; stormflow, 15 inches; surface inflow, 67 inches; and ground water, 40 inches. The calculated outflows were evaporation, 47 inches; surface outflow, 90 inches; and ground water, 33 inches. Water-quality data also were used to calculate nutrient budgets for the lakes. Bimonthly water samples were collected from the lakes and at surface inflow and outflow sites, and were analyzed for physical characteristics, dissolved oxygen, pH, specific conductance, major ions, the nutrients nitrogen and phosphorus, and chlorophyll (collected at lake sites only). Specific conductance ranged from about 190 to 230 microsiemens per centimeter at 25 degrees Celsius in Lakes Maitland, Virginia and Osceola and from about 226 to 260 microsiemens per centimeter at 25 degrees Celsius in Lake Mizell. The median concentrations of total ammonia-plus-organic nitrogen in all the lakes ranged from 0.79 to 0.99 milligrams per liter. Median total phosphorus concentrations ranged from less than 0.02 to 0.20 milligrams per liter. Stormwater samples were collected for 17 storms at one storm-drain site and 16 storms at another storm-drain site on Lake Osceola. Median total nitrogen concentrations at the sites were 2.23 and 3.06 milligrams per liter and median total phosphorus concentrations were 0.34 and 0.40 milligrams per liter. The water quality in the Winter Park lakes generally is fair to good, based on a trophic-state index used by the Florida Department of Environmental Protection for assessing the tropic state of Florida lakes. This index was determined from median total nitrogen, total phosphorus, and chlorophyll-a concentrations, and median Secchi-disk transparency for all lakes for the period September 1989 to June 1992. Based on a one-time sampling of 20 sites around the lakes, surficial ground-water quality is highly variable. Nutrient concentrations were highly variable and could not be correlated to the proximity of septic tanks. Fertilizer probably is the primary source of nutrients in the surficial ground water. Nutrient budgets were calculated for the lakes for the 3 years of the study. The most variable source of nutrient loading to the lakes is stormwater. Nutrient-loading modeling indicates that reduction of nutrients in stormflow probably would improve lake-water quality. However, even with complete removal of nitrogen and phosphorus from stormwater, the lakes might still be mesotrophic with respect to both nutrients during periods of below average rainfall because of the input from the other sources of inflow to the lakes. Littoral vegetation in the lakes was surveyed in March 1992. The length of shoreline containing vegetation was 44 percent in Lake Maitland, 62 percent in Lake Virginia, 46 percent in Lake Osceola, and 76 percent in Lake Mizell. The types of vegetation present generally were similar for all four lakes.

Florida↗

Ground-water levels and directions of flow in Geauga County, Ohio, September 1994, and changes in ground-water levels, 1986-94

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Geauga County Planning Commission and Board of County Commissioners, to determine directions of ground-water flow and to assess differences from 1986 to 1994 in groundwater levels in the glacial deposits and Pottsville Formation, Cuyahoga Group, and the Berea Sandstone. Water levels were measured in 219 wells in Geauga County, Ohio, in September 1994. Water levels measured in January and February 1986 in 88 of the 219 wells were used for comparison. Water-level maps constructed from measurements made in September 1994 show that ground-water levels in the Pottsville Formation and the glacial deposits generally correspond to the land-surface configuration and that ground water flows from the uplands to adjacent streams and buried valleys. Ground-water flow in the Cuyahoga Group is generally downward from the Pottsville Formation to the Berea Sandstone. Directions of ground-water flow in the Berea Sandstone are toward outcrop areas at the north and east edges of Geauga County and toward subcrops beneath buried glacial valley deposits in Chardon, Chester, Munson, and Russell Townships and along the west edge of the county. A comparison of water level measurements in 1986 and 1994 indicates that water levels declined in 70 percent of the measured wells and increased in 30 percent. The change in water levels from 1986 to 1994 ranged from an increase of 13.58 feet to a decrease of 29.25 feet. Thirty percent of all water-level changes were less than 1 foot in magnitude. In nearly 80 percent of the wells, water-level changes were within the range of plus or minus 5 feet. Among the wells for which two or more historical measurements were available, the 1994 water levels in 54 percent were outside the range of water-levels observed in previous studies (only 24 percent were greater than 1 foot outside of the previously-observed range). Water-level declines of greater than 10 feet were primarily in the Cuyahoga Group and Berea Sandstone. Some factors considered in the analysis of the differences in water levels in 1986 and 1994 were changes in water use, population, and the amount of available recharge. Water level differences could not be correlated to population changes between the 1980 and 1990 censuses. A decrease in the available recharge from 1986 to 1994 may be part of the cause for the decrease in water levels observed in two-thirds of the wells in and adjacent to Geauga County. Effects of withdrawal rates due to population increase on water levels, if present, are overshadowed by the effects of annual variations in precipitation.

Ohio↗

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin– Volatile organic compounds in surface and ground water, 1978-94

The U.S. Geological Survey compiled and summarized analyses of volatile organic compounds (VOC's) in surface and ground water from water-quality data bases maintained by-Federal, State, and local agencies as part of a retrospective analysis of water-quality data for the Upper Mississippi River Basin study unit of the National WaterQuality Assessment Program. The retrospective analysis focused on a study area that encompasses 19,500 mi 2 of the eastern portion of the study unit. Major river basins in the study area include the part of the Upper Mississippi River drainage from Lake Pepin upstream to sampling stations on the Mississippi and Minnesota Rivers where long-term water-quality data are available and the entire drainage basin of the St. Croix River. The Twin Cities metropolitan area, with a population of 2.4 million people, is located in the south-central part of the study area. Water-quality data collected in the study area from 1978 through 1994 by the U.S. Geological Survey, the Minnesota Department of Health, the Minnesota Pollution Control Agency, the Wisconsin Department of Natural Resources, the Metropolitan Council Environmental Services, and the city of Minneapolis were included in the retrospective analysis. In this report, assessment of the presence and distribution of VOC's in surface and ground water in the study area is restricted to two groups of VOC's: target VOC's, and trihalomethane compounds (THM's). Target VOC's, the most commonly detected non-trihalomethane VOC's in surface and ground water in the study area, include 1,1- dichloroethane, 1,2-dichloroethane, 1,1,1-trichloroethane, trichloroethene, tetrachloroethene, benzene, ethylbenzene, toluene, meta+para-xylene, and ortho-xylene. Trihalomethane compounds described in this report include chloroform, bromodichloromethane, chlorodibromomethane, bromoform, and fluorodichloromethane. Examination of water-quality data from widely distributed sampling networks of river sites and wells in the study area led to the following conclusions: 1) trace amounts of chlorinated VOC's were detected sporadically in waters of the Mississippi, Minnesota, St. Croix, and Vermillion Rivers; 2) benzene, ethylbenzene, toluene, and meta+paraxylene were detected sporadically in waters sampled from the chain of lakes used as the municipal supply for St. Paul, Minnesota; 3) the target VOC's were detected in less than five percent of ground-water samples at relatively low concentrations, generally near detection limits which ranged from 1 to 5 micrograms per liter; 4) VOC's were generally detected at similar frequencies, but at higher concentrations, in water samples from wells completed in sand and gravel aquifers than in water samples from wells completed in bedrock aquifers; 5) VOC's were most commonly detected in ground water in the vicinity of identifiable emission sites of VOC's, such as landfills, dumps, or major industries; 6) trichloroethene, a commonly used degreasing agent in dry cleaning, metal cleaning and cleaning septic lines, was the most frequently detected target VOC in ground water sampled from wells completed in both sand and gravel and bedrock aquifers; 7) wells producing water with detectable concentrations of the target VOC's tended to be shallower than wells producing water with no detectable concentrations of those compounds, but the differences in well depths were not statistically significant at a 95 percent confidence level; and 8) chlorination of water substantially increased the frequency of detection of trihalomethane compounds. The low frequencies of detection of the target VOC's and THM's in surface and ground water sampled from widely distributed sampling networks in the study area indicate that, although there are thousands of sites which can potentially emit these compounds to water, soil, and the atmosphere, these compounds have not had a widespread measurable effect on the quality of surface and ground water in the study area.

Minnesota, Wisconsin↗

The relation between hydrogeology and water quality of the Lower Floridan Aquifer in Duval County, Florida, and implications for monitoring movement of saline water

The hydrogeology of the Upper zone of the Lower Floridan aquifer and its relation to water quality were evaluated during a 3-year (1993-96) study. The Floridan aquifer system, a carbonate aquifer system composed of the Upper Floridan aquifer, a middle semi-confining unit, and the Lower Floridan aquifer, is the major source of water supply in northeastern Florida. The Lower Floridan aquifer is further subdivided into the Upper zone, a semi-confining unit, and the Fernandina permeable zone. As a result of increased withdrawals, heads in the aquifer system have declined and at the same time chloride concentrations have increased in the water from many wells in Duval County. A better understanding of the sources of and pathways for movement of brackish water is needed so that water managers can monitor the movement of brackish water and plan future water development. Most of the wells in Duval County deeper than 900 feet penetrate the Upper Floridan aquifer and the Upper zone of the Lower Floridan aquifer. Transmissivity estimates for these zones range from 2,000 to 194,000 feet squared per day. Permeability in the Upper zone of the Lower Floridan aquifer is primarily related to secondary porosity developed along bedding planes, joints, and fractures as a result of paleokarst processes. The Upper zone is about 300 to 500 feet thick in Duval County, based on the geophysical logs of about 40 wells ranging in depth from about 1,000 to 2,200 feet. In some areas the Upper zone has a single flow zone, but in other areas, two distinct flow zones are apparent. Water samples collected during this study confirm the continued increase in chloride concentrations in both the Upper Floridan aquifer and the Upper zone of the Lower Floridan aquifer. Most of the observed increases are in the eastern part of the county, but a pattern in the locations of wells yielding water with chloride increases is not discernible. In some areas, zones bearing brackish water are underlain by zones of fresher water, but in other areas, fresher water was not found beneath the brackish water. A single fracture or solution feature was the source of brackish water in several wells. The most likely source of brackish water to the Upper zone of the Lower Floridan aquifer is the underlying Fernandina permeable zone, which contains freshwater in the western part of the county but saline water in the eastern part. The pathways for movement of saline water are interconnecting vertical and horizontal fracture or solution zones probably developed along paleokarst features that are not mappable from the land surface; therefore, a conventional monitor-well network probably would not provide early warning of saline-water intrusion. Continued monitoring of water-quality trends in water-supply wells, combined with collection of additional surface and borehole geophysical data, can provide an increased understanding of the movement of brackish water in the Floridan aquifer system.

Florida↗

Water resources and related geology of Dera Ismail Khan district, West Pakistan, with reference to the availability of ground water for development

Dera Ismail (D.I.) Khan District contains an area of 3,450 square miles between the right bank of the Indus River and the Sulaiman Range in westcentral West Pakistan. Agriculture is the principal source of income in the District, but only a small part of the arable land is fully utilized. The region is semiarid and has an average annual rainfall of about 9 inches and a potential evapotranspirational rate of eight to nine times the annual rainfall. Thus, rainfall alone is not adequate for high-intensity cropping. Irrigation is practiced near the Indus River; the Paharpur Canal is used, as well as the traditional inundation method. Elsewhere in the District, adequate water is supplied to local areas by karezes, perennial streams from the mountains, and some recently installed tubewells (see 'Glossary'). Further development of ground-water supplies would permit a more effective utilization of most of the presently tilled land and would allow additional land to be farmed. D.I. Khan District is primarily an alluvial plain that slopes from the mountain ranges in the northern and western parts of the District toward the Indus River. Rocks in the bordering mountains are of Paleozoic to early or middle Pleistocene age. The unconsolidated rocks of the plain, of middle (?) Pleistocene to Holocene (Recent) age, consist of piedmont deposits derived from the hills to the north and west and of alluvium laid down by the Indus River. These deposits interfinger in a transitional zone about 8 to 12 miles west of the river. Lithologic and structural features indicate that the unconsolidated rocks possibly may be divided into broad units. The investigations in D.I. Khan District have revealed two main areas of potential ground-water development based on considerations of both permeability and chemical quality of the ground water: 1. A belt about 10 miles wide parallels the Indus River from the Khisor Range southward to the area immediately south of D.I. Khan town. In this belt, the material penetrated by test holes and tubewells consists predominantly of sand, which in tubewells can yield from 2 to 3 cfs (cubic feet per second) of water with only moderate drawdown. Also in this belt, ground water of good chemical quality extends to depths of 1,000 feet or more. 2. The area from the mouth of the Gumal River gorge to the vicinity of Kot Azam contains sand and gravel strata that may yield from 1 to 3 cfs of water, which contains 500 to 1,500 ppm (parts per million) of total dissolved solids. Other marginal parts of the District also contain water of good chemical quality, but developmental prospects are somewhat poorer because of greater depths to water, lower permeabilities, or greater depths to aquifers, all of which would require greater costs in the tubewell installations. The stratification or zoning of water of different chemical qualities to some extent governs the local availability of useful water. Generally, the ground water of poorest quality is found in the shallow zone, and quality improves with depth. The central part of the District, in a belt reaching from the vicinity of Tank southward to the Indus River near Dera Ghfizi Khan District, contains highly mineralized water and few aquifers. The mineralization of water in this belt is due primarily to large concentrations of sodium and sulfate and thus differs from the main part of the Punjab region where highly mineralized waters are generally chloride waters. Radical changes in water quality, both horizontally and vertically, are common in the District. Changes in chemical quality of water from large-capacity wells near areas of highly mineralized water are taking place, and further changes may be expected as withdrawals continue and increase in magnitude. Under present conditions, surface-water supplies are fully utilized, and ground water is the largest supply available for development-other than that from the Indus River.

Water Supply Paper↗

Preliminary Water-Table Map and Water-Quality Data for Part of the Matanuska-Susitna Valley, Alaska, 2005

The Matanuska-Susitna Valley is in the northeastern part of the Cook Inlet Basin, Alaska, an area experiencing rapid population growth and development proximal to many lakes. Here water commonly flows between lakes and ground water, indicating interrelation between water quantity and quality. Thus concerns exist that poorer quality ground water may degrade local lake ecosystems. This concern has led to water-quality sampling in cooperation with the Alaska Department of Environmental Conservation and the Matanuska-Susitna Borough. A map showing the estimated altitude of the water table illustrates potential ground-water flow directions and areas where ground- and surface-water exchanges and interactions might occur. Water quality measured in selected wells and lakes indicates some differences between ground water and surface water. 'The temporal and spatial scarcity of ground-water-level and water-quality data limits the analysis of flow direction and water quality. Regionally, the water-table map indicates that ground water in the eastern and southern parts of the study area flows southerly. In the northcentral area, ground water flows predominately westerly then southerly. Although ground and surface water in most areas of the Matanuska-Susitna Valley are interconnected, they are chemically different. Analyses of the few water-quality samples collected in the area indicate that dissolved nitrite plus nitrate and orthophosphorus concentrations are higher in ground water than in surface water.'

Open-File Report↗

Review of water demand and water utilization studies for the Provo River drainage basin, and review of a study of the effects of the proposed Jordanelle Reservoir on seepage to underground mines, Bonneville unit of the central Utah project

Problem: Questions have been raised concerning the adequacy of available water to fulfill the needs of storage, exchanges, diversions, and instream flows, pursuant to existing water rights in the Provo River drainage basin part of the Bonneville Unit. Also, concern has been expressed about the potential for seepage of water from Jordanelle Reservoir to underground mines. The Utah Congressional Delegation requested that the U.S. Geological Survey (USGS) review the results of analyses performed by and for the USBR. Purpose and Scope: The purpose of this report is to present the results of the USGS review of (1) the hydrologic data, techniques, and model used by the USBR in their hydrologic analyses of the Provo River drainage basin and (2) the results of a study of the potential for seepage from the Jordanelle Reservoir to nearby underground mines. The USGS reviewed USBR-supplied water demands, water utilization studies, and models of seepage from Jordanelle Reservoir. The USBR estimated that about 90 percent of the water supply for Jordanelle Reservoir will be water from Strawberry Reservoir exchanged for water from the Provo River stored in Utah Lake. If the Utah State Engineer allows the USBR to claim an estimated 19,700 acre-feet of return flows from the CUP, only about 77 percent of the supply would be derived from exchange of existing water rights in Utah Lake. The USGS assumed that planned importations of water from the Uinta Basin will be available and deliverable to fulfill the proposed exchanges. Water rights and demands are important for determining water availability. The USGS did not conduct an independent review of water rights and demands. The USSR and Utah Division of Water Rights use different methods in some areas for determining stress on the system based on past records. The USSR used "historical observed diversions" and the Utah Division of Water Rights use "diversion entitlements", which may not be equal to the historical diversions. The USGS based its review upon water demands used by the USSR. The Utah Division of Water Rights has responsibility for granting and enforcing water rights, and the final decisions on how the rights will be adjudicated lies with the Utah Division of Water Rights and with the courts. The USGS review did not consider the draft water distribution plan for the Utah Lake drainage basin proposed by the Utah State Engineer (written commun., October 15,1991). This plan, when finalized, may have an effect on water availability to the CUP.

Utah↗

Suitability of ponds formed by strip mining in eastern Oklahoma for public water supply, aquatic life, waterfowl habitat, livestock watering, irrigation, and recreation

A study of coal ponds formed by strip mining in eastern Oklahoma included 25 ponds formed by strip mining from the Croweburg, McAlester, and Iron Post coal seams and 6 noncoal-mine ponds in the coal-mining area. Water-quality samples were collected in the spring and summer of 1985 to determine the suitability of the ponds for public water supply, aquatic life, waterfowl habitat, livestock watering, irrigation, and recreation. The rationale for water-quality criteria and the criteria used for each proposed use are discussed. The ponds were grouped by the coal seam mined or as noncoal-mine ponds, and the number of ponds from each group containing water that exceeded a given criterion is noted. Water in many of the ponds can be used for public water supplies if other sources are not available. Water in most of these ponds exceeds one or more secondary standards, but meets all primary standards. Water samples from the epilimnion (shallow strata as determined by temperature) of six ponds exceeded one or more primary standards, which are criteria protective of human health. Water samples from five of eight Iron Post ponds exceeded the selenium criterion. Water samples from all 31 ponds exceeded one or more secondary standards, which are for the protection of human welfare. The criteria most often exceeded were iron, manganese, dissolved solids, and sulfate, which are secondary standards. The criteria for iron and manganese were exceeded more frequently in the noncoal-mine ponds, whereas ponds formed by strip mining were more likely to exceed the criteria for dissolved solids and sulfate. The ponds are marginally suited for aquatic life. Water samples from the epilimnion of 18 ponds exceeded criteria protective of aquatic life. The criteria for mercury and iron were exceeded most often. Little difference was detected between mine ponds and noncoal-mine ponds. Dissolved oxygen concentrations in the hypolimnion (deepest strata) of all the ponds were less than the minimum criterion during the summer. This decreases available fish habitat and affects the type and number of benthic invertebrates. The ponds are generally well suited for use by wintering and migrating waterfowl. Thirteen of the ponds contained water that exceeded the pH, alkalinity, and selenium criteria. The noncoal-mine ponds had the largest percentage of ponds exceeding pH and alkalinity criteria. Water samples from five of eight Iron Post ponds exceeded the selenium criterion. All ponds are generally unsuitable as waterfowl habitat during the summer because of high temperatures and low dissolved oxygen. Most of the ponds are well suited for livestock watering. Water samples from the epilimnion of 29 ponds met all chemical and physical criteria. Water samples from five ponds exceeded the criteria in the hypolimnion. Mine ponds exceeded chemical and physical criteria more often than noncoal-mine ponds. All the ponds contained phytoplankton species potentially toxic to livestock. Water from most of the ponds is marginally suitable for irrigation of sensitive crops, but is more suitable for irrigation of semitolerant and tolerant crops. Most major cash crops grown in eastern Oklahoma are semitolerant and tolerant crops. Water from the epilimnion of 14 ponds was suitable for irrigation under almost all conditions. Water from the epilimnion of 20 ponds was suitable for irrigation of semitolerant crops, and water from the epilimnion of 25 ponds is suitable for irrigation of tolerant crops. The dissolved solids criterion was exceeded the most often. Most of the ponds would not be suitable for swimming. The pH criterion was exceeded in 17 ponds and turbidity restricts visibility needed for diving in 23 ponds. Little difference was detected between mine ponds and noncoal-mine ponds. Many of the ponds formed by strip mining have steep banks that may be dangerous to swimmers.

Open-File Report↗