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Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado

Geologic map of the Emmons Lake volcanic center, Alaska

Introduction The Emmons Lake volcanic center is a spatially clustered group of stratovolcanoes and calderas in the southwestern part of the Alaska Peninsula, Alaska. The volcanic center is characterized by several ice- and snow-clad stratovolcanoes located within and along the margins of a nested-caldera complex that includes Emmons Lake. A shieldlike ancestral edifice (ancestral Mount Emmons) is truncated by the caldera complex and forms a broad volcanic platform around the center. The main stratovolcanoes of the Emmons Lake volcanic center are Pavlof Sister, Pavlof Volcano, Little Pavlof, Double Crater, Mount Hague, and Mount Emmons. Several small unnamed cinder cones and vents also are located within Emmons Lake volcanic center and on the east flank of Pavlof Volcano. Many of these cones and vents have been the source of the young lava flows that mantle the floor of the caldera. Pavlof Volcano, in the northeastern part of the Emmons Lake volcanic center, is one of the most historically (that is, the past about 300 years) active volcanoes in Alaska, and eruptions from Pavlof Volcano pose the greatest hazards to the region. Volcanic rocks of the Emmons Lake volcanic center overlie continental and marine sedimentary rocks of chiefly Late Jurassic to early Tertiary age. The oldest rocks in the area are those of the Naknek Formation, consisting of volcaniclastic sandstone, siltstone, and conglomerate of Late Jurassic age. The southern part of the area includes rocks of the Belkofski Formation, a thick sequence of volcaniclastic sandstone, siltstone, and conglomerate of middle Tertiary age. Lava flows, volcanic breccia, and fluvial volcaniclastic rocks of late Miocene age, which unconformably overlie the Belkofski Formation south of the Emmons Lake volcanic center, are primarily exposed on the islands just south of the Alaska Peninsula. The Emmons Lake volcanic center was affected multiple times by glaciation associated with the glacier expansion that characterized the Quaternary. Glaciation has played a key role in shaping the present-day landscape, and much of the eruptive history of the Emmons Lake volcanic center has involved interactions with glacier ice. Thus, a brief review of the Quaternary glacial history of the area is provided to establish the physical context for Emmons Lake volcanic center eruptive activity.

Alaska

Geochemical monitoring of volcanic fluids in the twenty-first century

This chapter reviews the state-of-the-art of geochemical volcano monitoring techniques. We cover in-situ monitoring technologies that rely on sampling fluids (direct sampling) and on instrumental analysis of the composition of such fluids in real-time (remote sensing of volcanic fluids is covered elsewhere in this book). We first review key concepts and principles in the field, and then review the results of some selected case studies and applications. We cover the large variety of fluid categories emitted by volcanoes, in both the near-(crater fumaroles and lakes, and plumes) and far-(degassing soils, groundwaters) fields. Our aim is to demonstrate the utility of measuring the chemistry of fluids released by volcanoes, and how these can help characterize volcano unrest, and eventually the increased likelihood of eruption. We conclude with a brief discussion of current challenges and knowledge gaps, and on future directions in geochemical monitoring.

Book chapter

Hydrogeologic framework and conceptual model of the Red River alluvial aquifer east of Lake Texoma, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82-1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. At present (2025), the Oklahoma Water Resources Board has not established a maximum annual yield for the Red River alluvial aquifer east of Lake Texoma. To support the evaluation and determination of a maximum annual yield, a hydrogeologic framework and conceptual groundwater-flow model were developed to assess groundwater availability in the Red River alluvial aquifer east of Lake Texoma. The scope of this hydrologic investigation is the alluvium and terrace containing the Red River alluvial aquifer in Oklahoma between Lake Texoma, the Texas State line, and the Arkansas State line, an extent referred to in this report as “the eastern part of the Red River alluvial aquifer.” Parts of the alluvium and terrace extent in Arkansas and Texas are included in some analyses to address hydrologic influences from outside the aquifer’s boundaries in Oklahoma. The eastern part of the Red River alluvial aquifer in southeastern Oklahoma consists of approximately 401,280 acres of Quaternary alluvium and terrace deposits associated with the Red River and its major tributaries. Mean annual recharge to the aquifer for the 1980–2022 study period was estimated to be 8.62 inches per year, or 17.98 percent of the mean annual precipitation over the same period (47.94 inches). This mean annual recharge rate is equivalent to an inflow of approximately 288,250 acre-feet per year for the eastern part of the Red River alluvial aquifer. Recharge estimated using the Soil-Water-Balance code accounts for 98.7 percent of the conceptual-model inflows to the eastern part of the Red River alluvial aquifer. Saturated-zone evapotranspiration accounts for 11.9 percent and net streambed seepage accounts for 87.4 percent of the outflows in the conceptual model.

Arkansas, Oklahoma, Texas

Assimilation of reduced carbon triggers platinum alloy saturation in mafic and ultramafic magmas

It is generally observed that magmatic sulfide ores have higher ratios of Pd/Pt than the mantle-like values of their parental magmas. This discrepancy has defied simple explanation because the partitioning behavior of both elements between sulfide and silicate liquids is very similar. Assimilation of sulfur- and carbon-rich country rocks by mafic and ultramafic magmas is considered a critical, if not essential, step in the formation of magmatic base metal sulfide deposits. Although there is general consensus that the assimilation of external sulfur and carbon promotes sulfide saturation, the effect of carbon assimilation on the solubilities of platinum-group elements in natural S-bearing silicate melt has been overlooked. In this study, we investigate the variations of platinum and palladium solubilities during assimilation of graphite and methane through thermodynamic modeling, in comparison with data from an array of highly distinctive magmatic sulfide ore systems representing ages from Archean to Paleozoic, melt compositions from komatiite to basalt, and magmatic settings including lavas, hypabyssal intrusions, plutonic continental arc roots, and plutonic layered intrusions, namely: Raglan, Norilsk-Talnakh, Lac des Iles, and the J-M Reef of the Stillwater Complex. We model assimilation-fractional crystallization processes to estimate the reduction of oxygen fugacity ( ⁠fO2⁠ ) of the melt due to incorporation of graphite and methane. The simulations show that although Pd remains highly soluble during the progressive assimilation of reduced carbon, Pt solubility decreases significantly as the silicate melt becomes increasingly reduced. With less than 8 % of sediment assimilation, Pt alloy may saturate and then deviate from sulfide-undersaturated silicate melts, concomitantly increasing the Pd/Pt value of the remaining melts of the Raglan and Norilsk-Talnakh systems. For the Lac des Iles and Stillwater systems, a higher extent of assimilation is needed to reach Pt saturation because of the relatively carbon-poor nature of the lower crustal rocks. The assimilation of methane volatiles is shown to be more effective than graphite assimilation, and it provides a pathway to Pt alloy fractionation in the absence of detectable amounts of bulk host-rock assimilation. High Pd/Pt values have been documented in many world-class magmatic sulfide deposits whose parental magmas have demonstrably experienced crustal contamination. Our model suggests that although anomalous Pd/Pt values may be explained by other mechanisms such as incongruent melting of preexisting sulfide or differences in the diffusivities of the metals within achieving equilibration, the assimilation of graphite or methane may play an important role in the global occurrence of magmatic sulfide ores with elevated Pd/Pt values.

Economic Geology

Seismic response comparison of a historical masonry church subject to real and simulated ground motions

In recent years, advanced numerical models and high-performance computing have facilitated the utilization of ground motion time series in the assessment of the non-linear dynamic behavior of historic masonry structures. Since recorded accelerograms can be sparse for specific analysis conditions, stochastic ground motion simulations have become a viable alternative to overcome this limitation. This study simulates the recorded acceleration time series of the Central Italy 2016 earthquake event at the closest station to the town of Macerata using a site-based stochastic approach. The simulated motions are seismologically evaluated using a goodness-of-fit method in terms of various intensity measures. The simulated records, in conjunction with real records, are used to study the non-linear dynamic behavior of San Filippo Neri church located in Macerata. The church of San Filippo represents an important example of Baroque religious architecture in central Italy, which was damaged and closed off to the public after the 2016 earthquake events. The construction was investigated with a vast diagnostic campaign which included on-site testing and dynamic identification tests. The collected data is used to calibrate the dynamic response of a three-dimensional finite element model of the church. The model is finally used to compare the non-linear seismic responses under real and simulated ground motions with the site recorded damage. The results of structural responses demonstrate a strong agreement between the real and simulated records, providing evidence to support the validation of the site-based stochastic simulation.

Macerata

Water quality of the Boca Raton canal system and effects of the Hillsboro Canal inflow, southeastern Florida, 1990-91

The City of Boca Raton in southeastern Palm Beach County, Florida, is an urban residential area that has sustained a constant population growth with subsequent increase in water use. The Boca Raton network of canals is controlled to provide for drainage of excess water, to maintain proper coastal ground-water levels to prevent saltwater intrusion, and to recharge the surficial aquifer system from which the city withdraws potable water. Most of the water supplied to the Boca Raton canal system and the surficial aquifer system, other than rainfall and runoff, is pumped from the Hillsboro Canal. The Biscayne aquifer, principal hydrogeologic unit of the surficial aquifer system, is highly permeable and there is a close relation between water levels in the canals and the aquifer. The amount of water supplied by seepage from the conservation areas is unknown. Because the Hillsboro Canal flows from Lake Okeechobee and Water Conservation Areas 1 and 2, which are places of more highly mineralized ground water and surface water, the canal is a possible source of contamination. Water samples were collected at 10 canal sites during wet and dry seasons and analyzed for major inorganic ions and related characteristics, nutrients, and trace elements. All concentrations were generally within or less than the drinking-water standards established by the Florida Department of Environmental Protection. The high concentrations of sodium and chloride that were detected in samples from the Boca Raton canal system are probably from the more mineralized water of the Hillsboro Canal. Other water-quality data, gathered from various sources from 1982 through 1991, did not indicate any significant changes nor trends. The data include pesticide and metal analyses of water samples and bottom sediments collected at four canal sites in the Boca Raton study area by the U.S. Geological Survey during 1982-84. The effects of the Hillsboro Canal on the water quality of the Boca Raton canal system are indicated by increased concentrations of sodium, chloride, dissolved solids, and total organic carbon. Concentrations of the constituents in the canal water generally decrease with distance from the Hillsboro Canal pumping station and are the result of dilution by receiving canal waters.

Florida

Earthquake effects surveyed during the nineteenth century as ecological features of Chinookan tidelands

Lasting effects of a Cascadia earthquake in 1700 were documented during surveys of Chinookan tidelands near the mouth of the Columbia River between 1805 and 1868. The effects resemble estuarine consequences, near Anchorage, of the 1964 Alaska earthquake: fatal drowning of subsided meadows and forests by post-earthquake tides, rebirth of marshes and forests through post-earthquake sedimentation, and uplift. Chinookan remains of killed forests were recorded by James Graham Cooper, John J. Lowell, and Cleveland Rockwell. Cooper, attached to a railroad survey and the Smithsonian Institution, wrote of redcedar stumps and trunks standing dead in tidal marshes of Shoalwater (now Willapa) Bay. Two such snags served as bearing trees for Lowell as he platted a Shoalwater Bay township under contract with the General Land Office. Rockwell, of the US Coast Survey, flecked landward edges of tidal flats west of Astoria with symbols that evoke remains of a bygone spruce forest. The Lewis and Clark Expedition, while in that area in 1805–1806, mapped and puzzled over tideland vegetation that post-1700 succession helps explain.

Alaska, British Columbia, California, Oregon, Wash

Reconnaissance of potential alternate water supply sources for the City of Gary, West Virginia

Seven potential sources of water, consisting of free-flowing discharge from abandoned coal mines at six locations and one abandoned flooded underground coal mine air shaft, were sampled for chemical analysis to assess the quality of the groundwater emanating from the seven mine sources. The six free-flowing mine discharge sources were also assessed for discharge by current-meter measurements on two separate occasions. The U.S. Geological Survey assessed these seven sources to provide information to the City of Gary, West Virginia (W. Va.), and the City of Gary’s consulting engineer with groundwater-quality and flow data to allow them to assess the seven sites as potential alternate sources of water for the City of Gary to augment its existing supply. For the six sites where discharge could be measured, discharge ranged from a minimum of 0.082 cubic feet per second (ft 3 /s) to a maximum of 3.685 ft 3 /s. Of the six sites measured, only two, Harmon Branch at Thorpe, W. Va. (USGS site 372201081303501) and the abandoned public-supply water wells near Havaco, W. Va. (USGS site 372358081344601), had discharge in excess of 1.00 ft 3 /s. Discharge from the abandoned public supply wells was 3.685 ft 3 /s on September 20, 2023, and 2.888 ft 3 /s on October 16, 2023, and discharge from Harmon Branch at Thorpe, W. Va., was 1.049 ft 3 /s on September 22, 2023, and 1.038 ft 3 /s on October 17, 2023. Discharge in the abandoned underground mine air shaft (USGS site 372224081340901) could not be assessed, but the air shaft drains an abandoned mine that likely contains water stored in approximately 1.7 square miles (mi 2 ) of abandoned underground coal mines in the Pocahontas No. 3 coal seam, and possibly an additional 0.9 mi 2 of leakage from the overlying Pocahontas No. 4 coal seam. Discharge for the six sites measured for the study was measured during a period between September 20 and October 18, 2023, and corresponded to the 12th to the 15th percentile of flow-duration statistics for the Tug Fork downstream of Elkhorn Creek at Welch, W. Va. streamgage (USGS site 03212750). Water-quality data for the seven sites sampled overall were acceptable with respect to drinking water standards. Of the 203 constituents analyzed, only a few failed to meet applicable U.S. Environmental Protection Agency (EPA) drinking water standards. Iron exceeded the 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) at only 1 of the 7 sites (14.3 percent) sampled. Iron concentrations ranged from a minimum of less than (<) 5.00 μg/L to a maximum of 724 μg/L with a median concentration of 7.62 μg/L. Manganese exceeded the 50.0 μg/L SMCL at 2 of the 7 sites (28.6 percent) sampled. Manganese concentrations ranged from a minimum of 1.93 μg/L to a maximum of 271 μg/L with a median concentration of 4.03 μg/L. No sites sampled exceeded the arsenic maximum contaminant level (MCL) of 10 μg/L. Arsenic concentrations ranged from a minimum of <0.100 μg/L to a maximum of 2.35 μg/L with a median arsenic concentration of 0.200 μg/L. None of the seven sites sampled for selenium for this study exceeded the EPA MCL of 50.0 μg/L. Selenium concentrations ranged from a minimum of <0.050 μg/L to a maximum of 5.26 μg/L with a median concentration of 3.21 μg/L. All seven sites were sampled for volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and polychlorinated biphenyls (PCBs), but most had concentrations below the detection limit. Of the 10 PCB compounds analyzed for the seven sites sampled, none contained detectable concentrations of PCBs or Aroclor compounds. Of the 44 SVOCs analyzed at each of the seven sites sampled, only 1 SVOC, acenaphthene, was detected, at a concentration of 0.02 μg/L. Of the 96 VOCs analyzed, from each of the seven sites sampled, only two were found at detectable concentrations. Trichloromethane was detected only at 1 of the 7 (14.3 percent) sites sampled at a concentration of 0.027 μg/L, and benzene was detected at the same site and 3 additional sites (4 of the 7 sites or 57.1 percent of the sites sampled) at concentrations of 0.028, 0.029, 0.021, and 0.035 μg/L, but none exceeded the EPA MCL for benzene of 5.00 μg/L. Total coliform bacteria are ubiquitous in the environment, and their presence only suggests the potential for contamination by near-surface processes. Escherichia coli ( E. coli ) bacteria are derived from either human or animal fecal material and can be an indicator of potential contamination by pathogenic bacteria or viruses. Total coliform bacteria were detected at all 7 sites sampled at concentrations ranging from 17.5 to greater than (>) 2,420 most probable number per 100 mL (MPN/100 mL) of sample, with a median total coliform concentration of 1,553 MPN/100 mL. Escherichia coli bacteria were detected at 4 of the 7 sites sampled at concentrations ranging from <1 to 11.9 MPN/100 mL, with a median E. coli concentration of 5.1 MPN/100 mL.

West Virginia

Storage timescales and the crystal growth history recorded in the layered reservoir of the Unit 3 Kulanaokuaiki Tephra Member of the Uēkahuna Ash from Kīlauea volcano

The Kulanaokuaiki Tephra Unit 3 (900 C.E.) was a subplinian basaltic scoria eruption, the largest known to have occurred at Kīlauea’s summit. The initiation mechanism and cause(s) of this highly hazardous eruption remain poorly understood, particularly as this style of activity has not been observed in the modern period. We use olivine diffusion timescales from Fe-Mg and lithium zoning to assess magma storage timescales and evaluate evidence for mixing prior to eruption. Of the 200 crystals assessed, 55% are normally zoned for forsterite and 45% are non-zoned. Zoned crystals (> 1 mm) ( n = 96) have average compositions of Fo 89 cores and Fo 81 rims, while small crystals 0.5–1 mm ( n = 14) have Fo 85 cores and Fo 82 rims. Modeled Fo diffusion timescales range from < 1 to 12.6 years (median of 3.0 years). Lithium maps in 32 of the forsterite-zoned crystals reveal a variety of lithium zoning types, most of which we attribute to crystal growth. Many lithium profiles are coupled to phosphorus within the outer ~ 100 μm of the crystal ( n = 17), reflecting growth processes and precluding their use for diffusion studies. Overall, our Unit 3 olivine dataset displays no evidence of magmatic priming shortly prior to eruption, unlike prior observations for the basaltic subplinian eruption of the Keanakāko‘i Tephra Unit E (1650 C.E.). Thus, explosive eruption magmas may be stored for considerably longer than previously thought, and magmatic priming is not a necessary precursor for Kīlauea’s explosive eruptions. We hypothesize that gas-driven filter pressing from crystallization of microlites and macrocrysts in the reservoir slurry contributed to the explosivity of the Unit 3 eruption.

Hawaii

The role of alkali bicarbonate-sulfate brines in the genesis of carbonatite REE resources at the Bear Lodge Alkaline Complex, Wyoming

Rare-earth element (REE) resources in the Bear Lodge Alkaline Complex, Wyoming, are hosted in a variably leached carbonatite dike swarm spatially related to bodies of diatreme breccia. This study examines fluid inclusions in carbonatite dikes, peripheral fluorite breccias, and smoky quartz veins to reconstruct the physiochemical conditions of REE mineralization. Results reveal a multi-stage evolution of carbonatitic fluids: 1) high-temperature (330–432°C), CO 2 -rich magmatic fluids, 2) REE-enriched alkali bicarbonate-sulfate brines, and 3) low-temperature meteoric (117–182°C) or diluted magmatic fluids. Multiphase inclusions (stage-2) contain burbankite, nahcolite, and alkali sulfate daughter crystals, linking the brines to early burbankite [(Na,Ca) 3 (Sr,Ba,REE) 3 (CO 3 ) 5 ] mineralization in carbonatite. REE mobility has been linked to the stability of aqueous complexes with ligands such as Cl-, SO 4 2- , and HCO 3 - . However, light REEs were not initially transported significant distances, rather they crystallized as burbankite from brines or brine-melts associated with the carbonatite magma. Crystallization of burbankite removed Na from the system, leaving residual fluids with high K/Na ratios and promoting potassic fenitization throughout the complex. Fractionation of light and heavy REEs and involvement of low temperature (<300°C), high K/Na bicarbonate brines may have facilitated transport and formation of peripheral occurrences that are more enriched in heavy REEs at Bear Lodge.

Wyoming

Surficial geology and Quaternary fault map of the Las Vegas Valley, Clark County, Nevada

The Surficial Geology and Quaternary Fault Map of the Las Vegas Valley, Clark County, Nevada is a 1:50,000-scale compilation of published 1:24,000-scale geologic maps integrated with new field and desktop mapping. This geologic map compilation and GIS database are part of a broader study on the Quaternary faults in the Las Vegas Valley, the results of which are summarized in this report. The map compilation utilized a variety of digital base maps to evaluate the characteristics of surficial deposits and Quaternary fault scarps including lidar data in undeveloped parts of the valley and orthorectified historical aerial photos in the urbanized center of the valley. The map distinguishes twenty surficial map units including alluvial-fan and ephemeral-wash deposits, groundwater discharge deposits of the Las Vegas Formation, and alluvium deposits of Las Vegas Wash. Quaternary faults include the Quaternary Las Vegas Valley fault system in the center of the valley and the Frenchman Mountain fault system along the eastern margin. All Quaternary fault traces in the valley were evaluated, and the previously published fault mapping was modified as needed. The new mapping and uniform correlation of surficial deposits displaced by Quaternary faults yields a consistent valley-wide characterization of the recency of fault activity. The map and GIS database include a Quaternary geochronology compilation of 119 previously published surficial deposit ages of various types, 35 new luminescence ages, and 3 new radiocarbon ages. The new age data further bracket the ages of the Las Vegas basin Quaternary stratigraphy and provide new constraints on the timing of Quaternary fault activity.

Nevada

Tungsten skarn quantitative mineral resource assessment and gold, rare earth elements, graphite, and uranium qualitative assessments of the Kuldjuktau and Auminzatau Ranges, in the central Kyzylkum region, Uzbekistan

A new quantitative mineral resource assessment for tungsten skarn was conducted for the Auminzatau and Kuldjuktau mountain ranges in Central Uzbekistan, along with qualitative assessments of orogenic gold, rare earth elements (REEs), amorphous graphite, and uranium. By integrating a variety of geological, geochemical, geophysical, and remote sensing data sets, estimates of undiscovered tungsten skarn deposits in permissive tracts are combined with grade and tonnage distributions of known deposits to generate probabilistic estimates of undiscovered resources. Undiscovered deposits in Auminzatau are estimated to contain median resources of 98 thousand metric tons (kt) of WO 3 with a 70 percent (%) probability of at least 28 kt and a 10% probability of at least 468 kt, of which 16 kt to 293 kt may be economic to extract. In Kuldjuktau, the undiscovered deposits are estimated to contain median resources of 27 kt of WO 3 with a 60% probability of at least 12 kt and a 10% probability of at least 208 kt, of which 5 kt to 132 kt may be economic to extract. Our results suggest that the Auminzatau–Kuldjuktau Mountains area is highly prospective for additional discovery of significant Au and U resources and has low prospectivity for discovery of significant REE and graphite resources.

Minerals

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment

Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean

Hydroacoustic observations reveal drivers of mixing and salinization of a karst subterranean estuary during intense precipitation

Karst subterranean estuaries within globally ubiquitous carbonate aquifers are coastal groundwater ecosystems that provide an essential water resource for human populations. To understand the drivers of salinization within a coastal aquifer in the Yucatan Peninsula (Mexico), we employed hydroacoustics in flooded caves to observe how oceanic and atmospheric events facilitate mixing between the meteoric lens (fresh-brackish groundwater) and the saline groundwater on tidal and episodic timescales. Precipitation during Tropical Storm Carlotta increased the flow and salinity of the meteoric lens without evidence for vertical mixing across the halocline. We postulate that vertical migration of haloclines in the conduit relative to those within the rock matrix during precipitation creates lateral density gradients that drive mixing, and ultimately creates a brackish layer within the meteoric lens. These results provide a mechanistic explanation for vertical and lateral exchange in a coastal carbonate aquifer, which has implications for groundwater response to future climatic change.

Ox Bel Ha cave system, Yucatan peninsula