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Critical minerals in orogenic (gold) and Coeur d’Alene-type mineral systems of the United States

Orogenic and Coeur d’Alene-type mineral systems are produced by metamorphic devolatilization of thick volcanic or siliciclastic sedimentary rock sequences and the focused flow of hydrothermal fluids upwards along crustal-scale faults. Most orogenic systems are found along the Cordilleran orogen, stretching from California northwards into Alaska, whereas most Coeur d’Alene-type systems occur in the Proterozoic Belt Basin in Idaho and Montana. Although the deposit types in these systems are exploited for precious and base metals, potential exists for the production of critical minerals necessary for current (2025) societal needs in the United States. Publicly available geochemical data compiled for these mineral systems, coupled with mineralogical characteristics, indicate that several critical minerals could potentially be recovered from unmined resources and processed mine waste: arsenic, antimony, tellurium, cobalt, and tungsten from orogenic gold deposits and zinc, antimony, arsenic, and manganese from Coeur d’Alene-type systems. These critical minerals reside primarily in arsenopyrite (arsenic), scheelite (tungsten), siderite (manganese), sphalerite (zinc), tetrahedrite (antimony and arsenic), stibnite (antimony), and telluride (tellurium) minerals.

continental United States

Utilization of stochastic ground motion simulations for scenario-based performance assessment of geo-structures

Probabilistic seismic performance assessments of engineered structures can be highly sensitive to the seismic input excitation and its variability. In the present study, the scenario-based performance assessment recommended by Federal Emergency Management Agency (FEMA) P-58 guidelines is adopted to estimate seismic fragility of concrete dams for various seismic hazard scenarios. Due to the scarcity of recorded ground motions and thereby their poor representation of uncertainties, stochastic ground motion simulation methods are utilized to obtain the required input excitations. Moreover, to understand the uncertainty in ground motion simulation models, two broadband stochastic simulation models are used to generate input excitations representing six seismic hazard scenarios defined by earthquake magnitude, source-to-site distance, and soil conditions. Optimal intensity measure parameters for each scenario are identified using a systematic procedure that considers criteria such as efficiency, practicality, proficiency, sufficiency, and hazard compatibility. Fragility curves and surfaces are derived using the cloud analysis technique, taking into account various damage measures and limit state functions. The study finds that the derived fragility curves are particularly sensitive to the selection of earthquake scenarios, the choice of records, and the methods used to calculate fragility curves, with less sensitivity observed to different engineering demand parameters. Given this sensitivity, particularly to ground motion selection, the study highlights the necessity of incorporating both model-to-model variability (epistemic uncertainty) and record-to-record variability (aleatory uncertainty), alongside the established material and modeling uncertainties, in the probabilistic seismic assessment.

Reliability Engineering and System Safety (RESS)

Light-dependent activity of deepwater sculpin (Myoxocephalus thompsonii) across substrates with and without predation risk

Light availability strongly influences predator–prey interactions in deepwater ecosystems, where visual constraints shape both foraging success and prey behavior. The behavioral response of deepwater sculpin ( Myoxocephalus thompsonii ) to siscowet lake trout ( Salvelinus namaycush siscowet ) was studied under ecologically relevant light intensities spanning several orders of magnitude typical of daytime downwelling light in the 20–100 m depth range of Lake Superior. Trials were conducted over varying substrates (gravel, sand, and black fabric). Deepwater sculpin showed a significant preference for gravel over sand and black fabric. In the absence of siscowet, sculpin movement frequency increased as light intensity decreased. Sculpin reaction distance to siscowet was influenced by both light and substrate. Reaction distance was shortest at low light intensities, peaked at intermediate light intensities (3.05 × 10⁹ to < 6.0 × 10⁹ photons m⁻2 s⁻1), and declined again at the highest light intensities tested. In the presence of siscowet, sculpin activity was suppressed at the upper end of the light range (≥ 6.0 × 10⁹ photons m⁻2 s⁻1). The greatest increase in movement occurred between 6.0 × 10⁹ and 3.05 × 10⁹ photons m⁻2 s⁻1, which corresponded to the range where siscowet prey capture declined, suggesting sculpin exploit this low-light window to move with reduced risk. Reduced activity in the presence of predators is common among cryptic species, and our findings suggest that sculpin restrict movement at higher light levels to avoid detection by siscowet.

Wisconsin

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Characterization of selected biological, chemical, and physical conditions at fixed sites in the Upper Colorado River Basin, Colorado, 1995-98

Biological community samples were collected at 15 sites in the Upper Colorado River Basin (UCOL) in Colorado as part of the National Water-Quality Assessment (NAWQA) Program. Sites sampled in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, represented agriculture, mining, urban and recreation, and mixed land uses and background conditions. Nine measures of water quality, which include information on nutrients, specific conductance (a surrogate for salinity), trace elements in streambed sediment, pesticides in fish tissue, fish communities, and macroinvertebrate richness and composition and stream habitat were used for comparisons among sites within the two physiographic provinces. Sampling sites from three other NAWQA study units—the Rio Grande Valley, the South Platte River Basin, and the Upper Snake River Basin study units—were categorized on the basis of land use and stream size in order to develop a larger data set for comparison to sites in the UCOL. Three categories of land use—forested (includes mining, urban and recreation, and background), agriculture, and mixed—were used for comparison to the UCOL fixed sites. Results indicated that all sites other than the Colorado River below Baker Gulch (a background site) showed some water-quality characteristics to be significantly affected. Results indicated that the concentrations of cadmium and zinc in streambed sediment at mining land-use sites in the Southern Rocky Mountains physiographic province generally were orders of magnitude higher than streambed-sediment concentrations at the background site. Streambed-sediment concentrations at mining land-use sites in the UCOL were greater than the 75 th percentile of concentrations from sites in the three other NAWQA study units. Fish communities and habitat conditions were degraded at mining land-use sites compared to the background site. Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and the percentage of EPT were lower at mining land-use sites than at the background site and were less than the 50 th percentile of those for sites from the three other NAWQA study units. Nutrient concentrations at urban and recreation sites in the Southern Rocky Mountain physiographic province generally were greater than concentrations at the background site and generally were between the 25 th and 90 th percentile of concentrations for sites from the three other NAWQA study units. Habitat conditions and fish communities at urban and recreation sites were slightly degraded compared to the background site. EPT richness and the percentage of EPT were lower at urban and recreation sites than at the background site and were between the 25 th and 75 th percentile of those for sites from the three other NAWQA study units. The percentage of Chironomidae, which may be indicative of pollutant-tolerant organisms, was higher at urban and recreation sites than at the background site. Mixed land-use sites in the Southern Rocky Mountains physiographic province had similar nutrient concentrations and similar cadmium and zinc streambed-sediment concentrations. Fish-community degradation index values were very different among the three mixed land-use sites in the Southern Rocky Mountains physiographic province. Larger percentages of omnivores and anomalies such as lesions and deformities at two mixed land-use sites resulted in higher degradation values of the fish community. Agriculture land-use sites had higher concentrations of nutrients and selenium than the background site in the Colorado Plateau physiographic province. Concentrations of p,p '-DDE in fish tissue at agriculture sites were higher than the 75 th percentile of concentrations for sites from the three other NAWQA study units. Fish communities had degradation values near the 75 th percentile for agriculture sites. The percentage of EPT was low at agriculture sites when compared to the background site. Two mixed land-use sites in the Colorado Plateau physiographic province had similar concentrations of nutrients, selenium, and p,p '-DDE, and similar EPT richness and composition. These two sites were located downstream from agricultural and urban activities. Some water-quality measures at these two sites indicated degradation compared to a mixed land-use site upstream from most of the agriculture and urban activities in the Colorado Plateau physiographic province.

Colorado

Quantitative risk of earthquake disruption to global copper and rhenium supply

Earthquakes have the potential to substantially affect mining operations, potentially leading to supply chain disruptions and adversely affecting the global economy. This study explores the quantification of earthquake risk to copper and rhenium commodity supply by examining the spatial concentration of high earthquake hazard areas and the commodity-specific mining, smelting, and refining operations across the globe. Because many of the largest facilities are concentrated geographically near the highly seismic regions of South America, East Asia, and the Pacific, there is a potential for cascading effects on the entire supply chain. The analysis indicates that the expected annual disruption of global production is 0.3–1.1 percent for copper mines, 1.8–4.0 percent for smelters, and 1.5–3.3 percent for refineries. Expected annual disruption of global rhenium production capacity is 0.32–1.32 percent. The research highlights that the potential lost revenue from earthquake disruptions is from $315 million to $1.29 billion for copper mining, $1.92 billion to $4.33 billion for copper smelting, $2.06 billion to $4.52 billion for copper refining, and $337,000 to $1.40 million for rhenium production capacity.

Open-File Report

Preliminary bedrock geologic map of the Port Henry quadrangle, Essex County, New York, and Addison County, Vermont

Introduction The bedrock geology of the 7.5-minute Port Henry quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 Ga (giga-annum). In the Port Henry quadrangle, the AMCG metaigneous rocks (Yhg, Ygb, Yanw) intruded older, mostly metasedimentary rocks of the Grenville Complex during the middle to late Shawinigan orogeny (~1,160–1,150 Ma [mega-annum]). All rocks were subsequently metamorphosed to upper amphibolite to granulite facies conditions during the 1,080–1,050 Ma Ottawan orogeny. New mapping reveals four periods of deformation: (1) D1 produced rarely preserved isoclinal folds in the paragneiss and marble and predates AMCG magmatism. (2) Subsequent D2 deformation produced the dominant gneissic fabric preserved in the rock, recumbent folding, and deformed all the Proterozoic units in the map area. Syn- to late-D2 felsic magmatism resulted in the regionally extensive Lyon Mountain Granite Gneiss, which hosts numerous magnetite ore bodies. (3) Mylonitic extensional shear zones and core complex formation marked the beginning of D3 deformation. Protracted D3 deformation resulted in F3 upright folding, dome and basin formation, pegmatite intrusion, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron-ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. (4) D4 created northeast- and northwest-trending local high-grade ductile shear zones and boudinage, northwest-trending regional kilometer (km)-wide ductile shear zones, and crosscutting granitic pegmatite dikes. The development of the late-stage regional shear zones (D4) was likely due to the continuation of extensional doming and uplift from upper amphibolite facies conditions at the end of the Ottawan orogeny. The majority of iron-ore deposits in the Port Henry and adjacent Witherbee quadrangles are in the hanging wall of these extensional shear zones. In the Port Henry quadrangle, the km-wide Cheney Mountain shear zone is the result of D4 deformation. Kilometer-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician carbonate bank on the ancient margin of Laurentia. The approximately 1-km-thick Cambrian to Ordovician stratigraphy records a transition from synrift clastics to passive-margin peritidal carbonate buildups to gradually deeper-water subtidal- to shelf-carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Open-File Report includes a bedrock geologic map; a description of map units; a correlation of map units; and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information.

New York, Vermont

Recent scientific contributions by the U.S. Geological Survey in the San Francisco Bay and Sacramento–San Joaquin Delta Estuary

Introduction The San Francisco Bay and Sacramento–San Joaquin Delta Estuary (hereafter, Bay-Delta) is the largest estuary on the West Coast of the United States. The Bay-Delta covers more than 1,600 square miles and drains a watershed of more than 75,000 square miles, which is greater than 40 percent of California. The region surrounding the Bay-Delta is home to about 10 million people, and its habitats (fig. 1) support more than 800 plant and animal species. The waterways of the Bay-Delta are the central hub of California’s extensive freshwater delivery system, supplying water to more than 27 million Californians and 4 million acres of farmland in the Central Valley. The U.S. Geological Survey (USGS) is the primary science agency of the U.S. Department of the Interior, providing a broad range of Earth, water, biological, and mapping data and expertise to inform natural resource management across the country. This fact sheet focuses on research conducted by the USGS in the Bay-Delta region, mostly within the past 5 years. The fact sheet is organized across five major themes: water flow and water quality, fish and wildlife, wetland restoration, invasive species, and hazards. In each of these areas, the USGS works closely with Federal, State, and local agencies; academia; and non-governmental organizations to provide objective, evidence-based science. The data and knowledge gained from USGS research and monitoring are publicly available and are routinely used by agencies, including the U.S. Bureau of Reclamation, U.S. Army Corps of Engineers, U.S. Fish and Wildlife Service, California Department of Water Resources, California Department of Fish and Wildlife, California State Water Resources Control Board, Delta Stewardship Council, and many additional organizations and stakeholders to inform management of the Bay-Delta region and its resources.

California

Baseflow and snowmelt sustained streamflow in the Upper Colorado River Basin, 1986-2020

The Upper Colorado River Basin (UCRB) faces substantial water availability limitations. Although most streamflow originates as snowmelt, the partitioning of snowmelt between surface runoff and groundwater recharge and subsequent groundwater discharge to streams is highly uncertain. On average, over half of the streamflow in the UCRB is estimated to originate from groundwater discharge to streams, highlighting the importance of baseflow in sustaining surface water. However, the historical patterns of baseflow and streamflow, along with their variability over space and time and their specific sources, remain unknown at the basin scale. This study addresses those gaps by characterizing the sources and transport pathways of both baseflow and streamflow in the UCRB at a seasonal timestep from 1986 to 2020, including the lagged delivery of subsurface water to streams beyond the current season, using coupled models of baseflow and streamflow. Between 1986 and 2020, on average 63% of UCRB streamflow originated from baseflow. About half of this baseflow took longer than one season to reach streams, and outside the snowmelt season, baseflow was the dominant source of streamflow. Snowmelt was a key source of both baseflow and streamflow. Current season snowmelt contributed 33% of streamflow via runoff, and 22% of the 29% of streamflow that originated as current season baseflow via subsurface flow to streams. Over the study period, baseflow index (BFI) declined in headwaters and increased at mid-elevations. Springtime increases in BFI demonstrate the increasingly important role baseflow plays in water supply. Identifying the sources, locations, and timing of water that contributed to the UCRB outlet can inform management of water resources in the basin.

Arizona, Colorado, New Mexico, Utah, Wyoming

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

AAPG Wiki

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.

Connecticut, Massachusetts

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv

Polystyrene microplastics alter the accumulation and elimination dynamics of silver nanoparticles in Daphnia magna

Rationale Microplastics (MPs) can interact with engineered nanomaterials and alter their environmental fate and bioavailability. However, their influence on the bioaccumulation dynamics of silver nanoparticles (AgNPs) in aquatic filter feeders under environmentally relevant conditions remains poorly understood. We hypothesized that polystyrene microplastics (PS-MPs) alter the uptake, elimination and overall bioaccumulation dynamics of AgNPs in Daphnia magna . Methodology Adult D. magna were exposed to isotopically labeled citrate-coated 109 AgNPs in the presence and absence of PS-MPs. Waterborne uptake, dietary uptake, assimilation efficiency, food ingestion and elimination were quantified experimentally and incorporated into a biodynamic model to predict steady-state silver (Ag) concentrations under environmentally relevant exposure scenarios. Results PS-MPs increased waterborne Ag accumulation by approximately eightfold compared with AgNPs exposure alone. However, Ag elimination was substantially faster, with 98% of accumulated Ag eliminated after five days of depuration compared with 66% without PS-MPs. PS-MPs also reduced food ingestion rates (IRs), while assimilation efficiency remained largely unchanged. Biodynamic modeling predicted that steady-state Ag accumulation was approximately fivefold greater in the presence of PS-MPs, with waterborne exposure becoming the dominant accumulation pathway. Discussion These findings suggest that PS-MPs alter bioaccumulation dynamics of AgNPs in filter-feeding organisms by enhancing organism-associated Ag during waterborne exposure while accelerating Ag elimination, likely through particle-associated transport and gut egestion. Collectively, these results underscore the complexity of Ag bioaccumulation processes when MPs and AgNPs interact and highlight the importance of studies conducted under environmentally relevant conditions.

Environmental Chemistry

Creation of aerial camera system boresight installations in Bangor, Maine; Monroe, Louisiana; and Bassville Park, Florida

Aerial camera systems rely on boresights for defining internal and external metrics. The U.S. Fish and Wildlife Service’s Migratory Bird Surveys Branch required boresights to calibrate their camera systems for creating georeferenced imagery that can then be used in geographic information systems. The U.S. Geological Survey created high-accuracy boresight installations in Bangor, Maine, in July 2024; Monroe, Louisiana, in September 2024; and Bassville Park, Florida, in January 2025 to provide this metric-defining capacity to the U.S. Fish and Wildlife Service. This U.S. Geological Survey Data Report details the methods and results of the boresight installation process and provides camera operators with the data needed to use each of the installations.

Florida, Louisiana, Maine

Paleoseismology and paleogeodesy using coral microatolls

Establishing the rupture extent and slip distribution of individual paleo-earthquakes is vital for assessing fault behavior including the persistence of rupture segmentation, recurrence patterns, and similarity of successive events, key issues in both fault mechanics and hazard assessment. Techniques with high temporal and geodetic precision as well as a wide distribution of study sites are necessary to investigate past earthquakes in such detail. Coral microatoll growth is one of the best types of geologic record for paleoseismology and paleogeodesy given these needs, as it provides long, continuous, widely distributed records of centimeter-scale vertical tectonic motion with potentially annual-level temporal precision. This chapter describes the process of interpreting microatoll growth records to obtain time series of relative sea level, tectonic vertical deformation fields, and finally slip and coupling parameters on an underlying fault interface.

Book chapter

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2022

Potentiometric-surface and depth-to-water maps for spring 2022 were created for the Mississippi River Valley alluvial aquifer (MRVA) using groundwater-altitude data from 1,136 wells completed in the MRVA and from the altitude of the top of the water surface in area rivers from 160 streamgages. The potentiometric-surface and depth-to-water maps for 2022 were created to support investigations to characterize the MRVA as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the MRVA for spring 2022 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 340 feet (ft) above the North American Vertical Datum of 1988. The regional direction of groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient was into the depression, and near rivers, where the groundwater gradient can be from aquifer to the river or from the river into the aquifer. There are large depressions in the potentiometric-surface map in the lower one-half of the Cache region and in much of the Grand Prairie and Delta regions. Depth to water in the MRVA, spring 2022, by well ranged from 5.00 ft above land surface to 145.66 ft below land surface.

Mississippi River Valley alluvial aquifer

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont

Comparison of water quality in shallow groundwater near agricultural areas in the Delaware Coastal Plain, 2014 and 2019

The State of Delaware has encouraged agricultural conservation practices to improve nutrient uptake by crops and mitigate nutrient transport to groundwater in the surficial aquifer. To study recent changes in groundwater quality, the U.S. Geological Survey and the Delaware Department of Agriculture (DDA) developed a network of shallow wells near agricultural areas throughout the Delaware Coastal Plain. This network was designed to characterize water quality related to agricultural practices and to detect any recent changes in shallow groundwater quality, in particular groundwater nitrate concentrations. The shallow well network was first sampled in 2014 and resampled in 2019. In 2019, field parameters (including dissolved oxygen, pH, specific conductance, and temperature), major ions, nutrients, stable isotopes of water, and isotopes of nitrate were measured in groundwater samples collected between October and December. Wells were organized into three groups based on their geochemical characteristics measured in 2014: the Agricultural, Urban, and Mixed Groups. Results from the 2019 sampling showed little change in water quality from the 2014 sampling. Land-use factors continued to be the driving influence between groups. Groundwater moves slowly and changes in groundwater quality are likely to respond slowly to changes in conservation practices. Continued sampling of both groundwater quality in this network and monitoring land management practices can help detect groundwater quality trends in the future.

Delaware