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Preserving and increasing water resources—Natural infrastructure in dryland streams in Baja California Sur, Mexico

The Los Planes watershed of Baja California Sur, Mexico, and its underlying aquifer are experiencing groundwater decline owing to low average annual rainfall (28.1 centimeters per year) and rising water demand from population growth and agricultural activities. This decline in water availability can lead to desertification—a process that changes arable land to desert by degrading soil and vegetation—and can pose serious challenges to livelihoods that depend on the land. To address these issues, a ranch in the Los Planes watershed has installed many natural infrastructures in dryland streams (NIDS) in channels for soil and water conservation. In 2022, the U.S. Geological Survey (USGS) began working with regional researchers and land managers to investigate the effects of NIDS on natural biological, geochemical, and physical processes and determine the efficacy of NIDS for water augmentation in the Los Planes watershed. The USGS also worked with local academic institutions and nonprofit organizations to create public educational opportunities focused on the area’s hydrogeology. These and other collaborative efforts with the U.S. Water Partnership and Innovaciones Alumbra aim at enhancing water resources in the Baja California Sur region and promoting water security and safeguarding community well-being. Resume La cuenca de Los Planes, ubicada en Baja California Sur, México, y su acuífero subyacente, están sufriendo una disminución de las aguas subterráneas debido a la baja precipitación media anual (28.1 centímetros por año) y la alta demanda de agua por parte de una población creciente y la actividad agrícola. Esta disminución de la disponibilidad de agua puede conducir a la desertificación—un proceso que por medio de la degradación del suelo y la vegetación convierte a la tierra cultivable en desierto—representando un serio desafío para los medios de vida de las personas. Para abordar estos problemas, un rancho en la cuenca de Los Planes ha instalado numerosas obras de Infraestructura Natural en Arroyos de Tierras Áridas (INATS) para conservación del suelo y del agua. En 2022, el Servicio Geológico de los Estados Unidos (USGS, por sus siglas en inglés) comenzó a trabajar con investigadores regionales y gestores de tierras para estudiar los efectos de INATS en los procesos biológicos, geoquímicos y físicos, y determinar su eficacia en el aumento de los recursos hídricos en la cuenca de Los Planes. El USGS se ha asociado con instituciones académicas y organizaciones locales sin fines de lucro para crear oportunidades educativas públicas centradas en la hidrogeología de la zona. Estos y otros esfuerzos colaborativos con la Asociación del Agua de Estados Unidos (U.S. Water Partnership) e Innovaciones Alumbra, tienen como objetivo mejorar el uso de los recursos hídricos en la región de Baja California Sur, promover la seguridad hídrica y proteger el bienestar de la comunidad.

Baja California Sur

Dating a medieval tsunami with uranium-series techniques on Caribbean corals

Uranium-series dates from coral boulders constrain the timing of a medieval tsunami from the Puerto Rico Trench. Previously reported evidence for this tsunami includes hundreds of coral boulders that came to rest hundreds of meters inland on Anegada, British Virgin Islands. New U-series dates on these coral boulders provide limiting dates for the tsunami. The narrowest limits were by dating interior bands of a coral that retains the hemispherical form of a living coral colony, and which include adjustments for the number of annual density band couplets between the dated samples and the boulder exteriors. By those limits, the tsunami dates between 1381 and 1391 CE, and likely occurred during summer or fall. The tsunami is important as the only reported sign that the eastern Puerto Rico Trench has produced a great earthquake. The dating may aid in defining the earthquake source and in communicating tsunami hazards.

British Virgin Islands, Puerto Rico

Eruptive history of northern Harrat Rahat—Volume, timing, and composition of volcanism over the past 1.2 million years

Harrat Rahat, one of several large, basalt-dominated volcanic fields in the western part of the Kingdom of Saudi Arabia, is a prime example of continental, intraplate volcanism. Excellent exposure makes this an outstanding site to investigate changing volcanic flux and composition through time. We present 93 40 Ar/ 39 Ar ages and 6 36 Cl surface-exposure ages for volcanic deposits throughout northern Harrat Rahat that, integrated with a new geologic map, define 12 eruptive stages. Exposed volcanic deposits in the study area erupted less than 1.2 million years ago (Ma), and 214 of 234 identified eruptions occurred less than 570 thousand years ago (ka). Two eruptions were in the Holocene, including a historically described basaltic eruption in 1256 C.E. and a trachyte eruption newly recognized as Holocene (4.2±5.2 ka). An estimated approximately 82 cubic kilometers (km 3 ; dense rock equivalent) of volcanic products can be documented as having erupted since 1.2 Ma, though this is a lower limit because of concealment of deposits older than 570 ka. Over the last 570 thousand years (k.y.), the average eruption rate was 0.14 cubic kilometers per thousand years (km 3 /k.y.), but volcanism was episodic with periods alternating between low (0.04–0.06 km 3 /k.y.) and high (0.1–0.3 km 3 /k.y.) effusion rates. Before 180 ka, eruptions vented from the volcanic field’s dominant eastern vent axis and from a subsidiary, diffuse, western vent axis. After 180 ka, volcanism focused along the eastern vent axis, and the composition of volcanism varied systematically along its length from basalt dominated in the north to trachyte dominated in the south. We hypothesize that these compositional variations younger than 180 k.y. reflect the growth of a mafic intrusive complex beneath the southern part of the vent axis, which led to the development of evolved magmas. Lastly, these new age data allow for a reassessment of the volcanic recurrence interval at northern Harrat Rahat. Based on available data, volcanism in northern Harrat Rahat over the last 180 k.y. is poorly described using a Poisson distribution with a single recurrence interval. Instead, data for northern Harrat Rahat are better described using a mixed exponential distribution that is applicable for volcanic systems characterized by two different eruptive states, where one state with a longer recurrence interval corresponding to periods of low eruption frequency and one state with a shorter recurrence interval corresponding to periods of high eruption frequency. The preferred model for northern Harrat Rahat over the last 180 k.y. uses a long recurrence interval of 4.0 k.y. and a short recurrence interval of 0.22 k.y.

Professional Paper

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii

Determining Volcanic Risk in Auckland (DEVORA) Research Programme—A transdisciplinary approach to address the challenge of distributed volcanism in an urban environment

The Determining Volcanic Risk in Auckland (DEVORA) Research Programme was launched in 2008 to address the challenges associated with monogenetic volcanism in an urban setting and to enhance volcanic risk management in Tāmaki Makaurau Auckland in Aotearoa New Zealand. It is a multi-agency, increasingly transdisciplinary (defined here as research that transcends traditional disciplinary boundaries by integrating diverse types of knowledge, perspectives, and methods from academic and non-academic participants to create novel solutions to complex problems), and collaborative research program jointly led by Waipapa Taumata Rau University of Auckland and Earth Sciences New Zealand (ESNZ; formerly GNS Science), with core funding from Natural Hazards Commission Toka Tū Ake (NHC; formerly the Earthquake Commission, EQC) and Te Kaunihera o Tāmaki Makaurau Auckland Council (AC). The primary research focus of DEVORA is to investigate the geologic history, volcanic hazards, and risk posed by the basaltic intraplate Auckland Volcanic Field. Disruption from ash fall and gas from other Aotearoa New Zealand volcanoes is also considered. DEVORA’s work to explore exposure and vulnerability in Tāmaki Makaurau Auckland is also useful for assessing risks from other non-volcanic natural hazards, such as seismic and tsunami hazards. The greater Tāmaki Makaurau Auckland region has an ethnically and socio-economically diverse population of approximately 1.7 million, representing about one-third of the Aotearoa New Zealand population, and hosts critical infrastructure of national significance. The size and nature of the populace, consequential economic base, and important infrastructure within Tāmaki Makaurau Auckland mean that the effects of a volcanic eruption would be felt nationally, including through the disruption of air travel to Aotearoa New Zealand. The hazards from such an eruption could potentially affect hundreds of thousands of people, businesses, and lifelines (critical infrastructure). A considerable challenge for emergency and risk managers is the monogenetic nature of the volcanic field. It is not known where or when the next eruption will occur, how much warning we may get before an eruption, nor how an eruption and its effects might unfold. In this contribution, we highlight the concept and collaborative intent of the DEVORA Programme and show how it has evolved over the 16 years since its inception. We describe how DEVORA has unified more than 100 researchers (including more than 50 graduate students) and numerous stakeholders to address key issues facing Tāmaki Makaurau Auckland and describe how research findings are being implemented into policy and communicated to stakeholder agencies and the public. We also illustrate the broader influence of the DEVORA Programme and provide some learnings that might benefit others embarking on similar integrated projects, especially those focused on distributed volcanism in and near populated areas.

Auckland

Assessment of channel morphology, hydraulics, and bedload transport along the Siletz River, western Oregon

Significant Findings Chinook salmon ( Oncorhynchus tshawytscha ) and Pacific lamprey ( Entosphenus tridentatus ) are native, anadromous fish species in the Siletz River Basin, western Oregon, that face many threats to their survival in freshwater and the ocean. The Confederated Tribes of Siletz Indians of Oregon seek to mitigate freshwater threats to Chinook salmon and Pacific lamprey, where possible, with habitat conservation and restoration efforts. This study was conducted to assist the Confederated Tribes of Siletz Indians of Oregon in documenting and understanding the hydrogeomorphic processes shaping present-day habitat conditions and assessing future habitat implications for Chinook salmon and Pacific lamprey along the main-stem Siletz River. As such, this study focused on understanding geomorphic processes and patterns of channel change, including lateral and vertical adjustments in channel position and changes in bed-material sediment (sands, gravels, and cobbles that mantle the channel bed), which collectively determine overall patterns of channel morphology and fluvial habitats. Objective One was to evaluate lateral changes in channel position, vertical changes in bed elevation, and longitudinal patterns in bed-material particle size along the Siletz River using detailed channel maps developed from aerial photographs collected from 1939 to 2016, long-term records of stage and discharge collected by the U.S. Geological Survey (USGS) near the City of Siletz, and sediment particle size data. Objective Two was to assess hydraulic conditions using one- and two-dimensional hydraulic models and transport capacity of bed-material sediment using bedload transport models and sediment particle size data for a range of discharge conditions. Objective Three was to identify potential burrowing habitat for lamprey larvae (PBH) along the Siletz River network and provide insights in local factors influencing PBH along the main-stem Siletz River. The overall findings are synthesized to describe habitat implications for Chinook salmon and Pacific lamprey under present-day and future conditions. Results of Objective One, an evaluation of changes in channel position and bed elevations and longitudinal patterns in bed-material particle size along the Siletz River, include the following From 1939 to 2016, channel planform and the mapped area of gravel bars did not change considerably along the 97.2-kilometers (km) of Siletz River between Elk Creek and Millport Slough, except for in short sections generally less than 1 km long. This inherent lateral channel stability results from the resistant bedrock and terraces that bound most of the channel and limit lateral changes in channel position. Intermittent sections along the study reach where the active channel widened at channel bends displayed noticeable planform changes and increases in mapped bar area. From water year (WY; a 12-month period from October 1 through September 30 and named for the year in which it ends) 1906 to 2021, changes in the stage-discharge relation interpreted as rising and lowering channel bed levels were observed at the USGS streamgage 14305500 (Siletz River at Siletz, OR) in response to floods (such as high flows in February 1996 and January 2002 that exceeded 0.1 and 0.667 annual exceedance probabilities [AEP] events, respectively). However, the rating curve representing the stage-discharge relation did not change in response to high-magnitude floods between 2007 and 2021. Along the approximately 54-km of the Siletz River between Moonshine Park and the Bulls Bag area, surficial particle distributions varied considerably between sampling sites in response to changes in channel width and gradient, sediment inputs from tributaries, and basin geology. Despite this variability, median particle sizes tended to decrease in size in the downstream direction over the 54 km. Results of Objective Two, an evaluation of hydraulic and bedload transport conditions along the Siletz River, include the following The most substantial increases in maximum and mean water velocity and bedload sediment transport capacity occurred at events between the 0.995 and 0.50 AEPs. Events of these magnitudes occur approximately every 1–2 years. Smaller events (0.995 AEP) are generally contained by the banks of the main channel, whereas larger events (0.50 AEP) generally spill over the banks and inundate high-elevation bar and low-elevation floodplain surfaces. Multiple smaller floods within a WY that exceed the 0.995 and 0.50 AEPs (such as in WY 1996) can transport as much or more bed-material sediment than a single, higher magnitude event (such as the maximum event recorded in WY 2000 with an estimated AEP of around 0.002). Bedload transport capacity generally exceeds sediment supply (greater than 2 millimeters [mm]) for most of the study area from Wildcat Creek to the City of Siletz as evidenced by substantial in-channel bedrock. Despite overall conditions of limited sediment supply, transport capacity still varies considerably within and between years with discharge magnitude and spatially in relation to local hydraulics imposed by bedrock, channel morphology, and human infrastructure (such as bridges). Results of Objective Three, an analysis of PBH for lamprey larvae, include the following About 28 percent of the Siletz River network meets the mean annual suspended sediment loads and channel slope criteria for PBH. Along the main-stem Siletz River, in-channel bedrock outcrops and high transport capacity are expected to further constrain PBH. Together, these results suggest that most of the Siletz River between Wildcat Creek and the City of Siletz has had only modest vertical and lateral change between the 1930s and 2010s because of the bedrock in and along the main channel and the river’s relatively high transport capacity relative to bed-material sediment supply. However, localized sections of the Siletz River where the active channel widens, particularly at channel bends, exhibited some change in channel planform and the locations and area of gravel bars. In the future, moderate increases in autumn-winter discharge may not result in substantial changes in coarse gravel bars along the Siletz River but may result in selective transport of finer bed-material sediment (gravel, sands, and silts) that provide spawning habitats for Chinook salmon and Pacific lamprey and burrowing habitats for lamprey larvae. Assuming no substantial changes in bed-material sediment supply, increased bedload transport capacity may cause frequent entrainment of lamprey larvae that are burrowed in coarse sand deposits, suspension and downstream transport of salmon eggs incubating in gravels, and reductions in the areas of spawning gravels for Chinook salmon and Pacific lamprey. Exact implications of current and future discharge conditions for these species along the Siletz River depends on many factors, including sediment supply, local hydraulics, and the timing of flood events relative to fish life stages.

Oregon

SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods

Monitoring recreation on federally managed lands and waters—Aspects of visitor use

Federally managed public lands and waters receive about 1 billion recreational visits each year. Data on these visitors can aid in guiding policy decisions, managing resources effectively, and communicating the economic contributions of lands and waters. This report explores the methods used by agencies to collect data on aspects of recreational visitor use to Federal lands and waters (apart from visitation numbers, which are the focus of a companion publication). Aspects of recreational visitor use include visitor demographics, recreational activity participation, visitor satisfaction, visitor attitudes and experiences, trip characteristics, and economic contributions. We review practices used to understand aspects of visitor use across seven Federal agencies, revealing similarities such as the use of visitor intercept surveys and coverage of similar topic area, and differences in how survey programs are operationalized and how specific questions on visitor surveys are worded. We also evaluate emerging technologies, such as geolocated social media and mobile device location data, for their potential to aid in understanding aspects of visitor use. This report concludes with potential opportunities to enhance data collection and coordination, ensuring cost-effective data collection and informed decision-making.

SocArXiv

Bedrock geologic map of the Eagle Lake quadrangle, Essex County, New York

The bedrock geology of the 7.5-minute Eagle Lake quadrangle, Essex County, New York, consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Granulite facies Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 giga-annum (Ga, billion years before present). The earliest of four phases of deformation (D1) predated AMCG magmatism and is characterized by gneissosity, rarely preserved F1 isoclinal folds, and migmatite in the paragneiss host rocks. A sample of hornblende quartz syenite from the AMCG suite, collected from an abandoned railroad cut on Old Furnace Road, yielded a U-Pb zircon age of 1,149±10 million years before present. D2 deformation produced a composite penetrative gneissosity, migmatite, and isoclinal F2 folds. Towards the end of D2, felsic magmatism (including the regionally extensive Lyon Mountain Granite Gneiss, abbreviated “LMG”) spread by penetrative migration as semiconcordant alkali feldspar granite sheets subparallel to S2 into the previously deformed lithologies. The LMG crystallized at approximately 1.15 to 1.14 Ga and displays synkinematic F2 folds thus constraining the time of D2 deformation. Exhumation of the Marcy anorthosite began during D3 along a mylonitic extensional detachment, as a type of core complex. Protracted D3 produced F3 folds exhibited in regional domes and basins, such as the Hammondville antiform, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. D4 created NE- and NW-trending boudinage, local high-grade ductile shear zones, and crosscutting granitic pegmatite dikes. Kilometer (km)-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. Lower Paleozoic rocks are part of the Early Cambrian to Late Ordovician great American carbonate bank on the ancient margin of Laurentia. The Potsdam Sandstone preserves the Cambrian stratigraphy in outliers above the Great Unconformity. The Paleozoic rocks are weakly folded and block faulted. Parts of the quadrangle are covered by undifferentiated glacial deposits, but much of the quadrangle contains only a variably thick, veneer of unmapped glacial till over significant areas of exposed bedrock. The map also shows waste rock piles and locations of historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondack Mountains, and provide a modern context for historical mines. This Scientific Investigations Map of the Eagle Lake 7.5-minute quadrangle consists of a map sheet, an explanatory pamphlet, and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information. The map sheet includes a bedrock geologic map, a correlation of map units, a description of map units, an explanation of map symbols, and two cross sections. The explanatory pamphlet includes a discussion of the geology.

New York

USGS—An Unparalleled Scientific Asset

The U.S. Geological Survey (USGS) delivers information critical to powering our economy, managing our natural resources, and keeping Americans safe and healthy. 1 Mapping the Nation $21B Geologic maps save users an estimated 15% in annual costs: a value of between $14B and $21B. $25.6B in annual value to users of imagery from Landsat satellites, which were codeveloped by NASA and the USGS and operated through their lifespans by the USGS. $13.5B in annual benefits is generated by the USGS's 3D Elevation Program. Securing America’s Energy Independence 44% USGS-identified undiscovered geothermal energy is equal to 44% of current U.S. electricity generation. 29.4B barrels of oil and 391.6 trillion cubic feet of gas in recoverable resources are available on U.S. public lands based on USGS assessments. Protecting Americans’ Health and Safety $424B in recent wildland fire damages highlight the need for USGS fire science, which supports efforts to protect communities and reduce risk. USGS earthquake, volcano, landslide, and coastal hazard monitoring and information save lives and minimize costs; for example, $2.8M can be saved because of USGS enhanced information about a Mauna Loa eruption. $4.5B is the estimated cost of annual flooding. Through a network of over 11,885 streamgages, the USGS supports public safety and enables forecasts, early warning systems, and management actions that protect lives and property. Supporting National Security $3.1B The USGS identified a $3.1B risk to the American economy if China restricts gallium imports. This is one example underscoring the importance of the USGS mapping critical minerals, investigating supply chains, and producing the Nation’s critical minerals list. Enhancing Our Lands and Waters $21B in estimated annual costs results from invasive species. The USGS’s invasive species research informs approaches used to reduce their effects on agriculture, water infrastructure, disease transmission, fisheries, and outdoor recreation. USGS innovations support early warnings for harmful algal blooms—over $2M in yearly benefits are provided to Kansas alone. $45B USGS science informs the management of big game (such as deer and elk). The big-game hunting industry contributes $45B to the U.S. economy. Fostering American Prosperity $4.1T Mineral commodities are necessary for the $4.1T in value added to the GDP by major industries that consume processed mineral materials and employ 1 million workers. Because of this, USGS data on mineral supply, demand, and trade are highly valued. 45,000 metric tons Rare earths power the growing technology economy, including cell phones, electric vehicles, and medical devices. For over 70 years, USGS work has supported the discovery of rare earth resources in California’s Mountain Pass area, which produced 45,000 metric tons of rare earth concentrates in 2024—over 11% of the global supply. Guarding American Food Security $70.2B USGS science informs early warning systems and management strategies to mitigate disease outbreaks in agriculture—critical research on highly pathogenic avian influenza, for example, helps safeguard the $70B value in poultry and egg production. $11.8B USGS groundwater tools are vital for agriculture; for example, in the Mississippi Alluvial Plain, 65% of farming relies on groundwater to support its $11.8B annual industry. 1 Values throughout are given in billions (B), millions (M), and trillions (T) of U.S. dollars. GDP is “Gross Domestic Product.” Percentages are shown as %.

General Information Product

Evaluation of stream capture related to groundwater pumping, middle Humboldt River Basin, Nevada

Historical, future, and potential stream capture from groundwater pumping in the middle Humboldt River Basin (MHRB), Nevada, is estimated using a calibrated numerical groundwater flow model. The model was developed to estimate (1) stream capture, which is the change in flux between the groundwater system and the Humboldt River and tributaries, and (2) change in streamflow, which is the change in streamflow estimated for the Imlay gage on the Humboldt River (U.S. Geological Survey streamgage 10333000). Historical stream capture for water years (WYs) 1961–2015 is estimated using recorded and estimated groundwater pumping during that period. Future (predictive) stream capture was based on historical stresses (WYs 1961–2015) using a scenario that simulated non-mine pumping from WY 2015 at a uniform rate for 100 years into the future. Potential stream capture throughout the middle Humboldt River Basin from groundwater pumping during varying durations of time are presented in a series of capture maps. Maps also are presented that show the potential to capture from groundwater evapotranspiration, as well as the storage changes for pumping duration of 100 years. Estimates of historical stream capture from the mainstem Humboldt River during the early 1960s are less than 400 acre-feet per year (acre-ft/yr) when groundwater withdrawals and pumping rates were relatively small compared to more recent times. In the late 1980s and early 1990s, groundwater withdrawals increased and estimated historical stream capture also increased from about 4,000 acre-ft/yr in the late 1980s and early 1990s to as much as 18,800 acre-feet (acre-ft) in WY 1998. In WY 2015, estimated historical stream capture declined to about 13,000 acre-ft because of decreasing groundwater withdrawals and lower streamflow during the drought of WYs 2012–15, resulting in less stream water available for capture. Stream capture was estimated for 100 years into the future based on WY 2015 non-mine pumping rates and mine-dewatering activity through WY 2015. Stream capture is forecast to increase to about 23,000 acre-ft/yr, and streamflow in the Humboldt River could decrease by as much as 19,000 acre-ft/yr. Pumping for mine-dewatering and the associated discharge of that water affects streamflow in the Humboldt River at Imlay, Nevada (U.S. Geological Survey streamgage 10333000). Historically, from WYs 1991 to 2015, streamflow was greater at Imlay gage during active mine-dewatering from mine-water discharge operations and increased by as much as 105,000 acre-ft in WY 1998. The increase was attributed mostly to the discharge of groundwater from mine-related dewatering operations directly into the mainstem Humboldt River or its tributaries, with some of this increase associated with return flows from discharge to rapid infiltration basins. Results indicate that streamflow at Imlay gage is expected to decrease by as much as 1,600 acre-ft/yr 30 years after mine-related pumping and discharge are discontinued. The streamflow reductions at the Imlay gage are expected to then decrease to around 500 acre-ft/yr, 100 years after mine-related pumping and discharge are discontinued. Potential capture maps were produced for pumping durations of 10, 25, 50, and 100 years. Capture map results indicate that areas of greater potential stream capture occur adjacent to the Humboldt River and for upstream tributaries areas north of the Humboldt River.

Nevada

Simulation of groundwater flow and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River affects agricultural, municipal, and industrial water users and is an important concern in the Western United States. In the Paradox Valley of southwestern Colorado, natural discharge of sodium-chloride brine to the Dolores River from the underlying core of a salt-valley anticline accounts for about 6 percent of the salinity load to the Colorado River. Formation of the Paradox Valley began during the Miocene, and subsequent erosion exposed the Pennsylvania Paradox Formation in the core of the anticline where a cap rock, collapse features, breccia, and sodium-chloride saturated brine developed at the top of the exposed salt diapir. The discharge of brine to the Dolores River is affected by these dissolution features, along with seasonal hydrologic conditions and density-dependent flow between older dense brine and the younger fresh groundwater in the overlying alluvial aquifer. To reduce TDS concentrations in the Dolores River through the Paradox Valley, the Bureau of Reclamation has pumped brine from a series of shallow wells adjacent to the river since July 1996. The pumped brine is collected and piped to a deep disposal well where it is injected into the Mississippian Leadville Limestone at a depth of about 4,570-meters below land surface. The pumping and injection operation is collectively known as the Paradox Valley Unit (PVU), and by 2015, the PVU had substantially reduced TDS concentrations in the Dolores River by about 70 percent. Since 2019, injection-pressure limits and related seismic activity have constrained deep-well injection and thus brine pumping at the PVU. In cooperation with the Bureau of Reclamation, the U.S. Geological Survey developed a MODFLOW-6 three-dimensional, variable-density groundwater flow and TDS transport model of the Paradox Valley to evaluate the effects of PVU pumping operations on brine discharge to the Dolores River and to guide additional research. The finite-difference model grid consists of 76 rows and 48 columns oriented from northwest to southeast in alignment with valley topography and groundwater-flow directions in the near-surface freshwater alluvial aquifer. A 7-layer hydrogeologic framework was developed from existing datasets to represent the alluvial aquifer, cap rock, collapse breccia, and groundwater flow and TDS transport from the underlying Paradox Formation salt to the Dolores River. The model represents a 33-year transient calibration period from 1987 through 2020 that includes pre-PVU conditions from 1987 through June 1996 and post-PVU conditions from July 1996 through 2020. A 1,000-year simulation of groundwater flow and coupled TDS transport computed the initial conditions for the subsequent 33-year transient simulation. Observations of precipitation, streamflow, evaporation, agricultural land use, and PVU brine pumping rates were used to specify appropriate boundary conditions to the model representing time-varying recharge, tributary streamflow, groundwater underflow, evapotranspiration (ET), and PVU pumping. Values for average monthly streamflow and TDS concentration at the upstream streamgage, the Dolores River at Bedrock (USGS streamgage 09169500), were specified as model input where the Dolores River enters Paradox Valley. Observed pumping from the PVU, water levels and TDS concentrations in groundwater, and streamflow and estimated TDS concentrations at the downstream streamgage, the Dolores River near Bedrock (USGS streamgage 09171100), were calibration targets that constrained the manual calibration of model parameters representing aquifer hydraulic conductivity, storage, streambed conductance, recharge, and (ET). Two primary model-calibration targets were the match between observed and simulated TDS mass flux from PVU pumping wells and the match between estimated and simulated TDS mass flux to the Dolores River. The simulated TDS mass withdrawn by pumping wells is calculated by the model as the product of the assigned pumping rate and simulated groundwater TDS concentrations. Because actual pumping rates were assigned as simulated values, the total simulated PVU pumping for the 33-year calibration is within 0.5 percent of the observed values. However, simulated concentrations and thus mass flux of TDS withdrawn by the PVU pumping wells were consistently about 26 percent less than observed values for all the simulated time periods (33-year simulation, pre-PVU, and post-PVU). The representation of brine inflow was explored through additional modeling to evaluate the effect of the simulated brine source on groundwater TDS concentrations. Results indicated that a saturated-salt constant-flux brine source best replicated the magnitude and transient pattern observed for TDS mass flux from PVU pumping wells. The simulated TDS mass flux to the Dolores River is compared to estimates based on observed streamflow and specific conductance (SC) data for the downstream streamgage. The calibrated model provided a close fit of simulated to measured streamflow at the downstream streamgage, and the calibrated model fit to estimated TDS concentrations at the downstream streamgage was reasonable. The greatest differences between simulated and estimated values occurred during drought periods from June 2000 to March 2003, May 2012 to June 2013, and October 2013 to October 2014, when simulated TDS concentrations in the river were greater than estimated concentrations. In general, simulated TDS mass flux to the river for the pre-PVU period is in good agreement with estimated values (2-percent difference), but the model overestimated TDS mass flux to the river by about 41 percent during the post-PVU period. The model uncertainty with respect to TDS mass flux to the river indicates other processes or model parameters not well represented by the model are affecting the system, especially during drought. During model calibration, the most sensitive parameters were identified as vertical hydraulic conductivity of the alluvial aquifer, conductance of the Dolores River streambed, ET extinction depth and rate, and recharge rate. Five 5-year scenarios of conditions for 2021–25 were simulated to assist evaluation of alternative strategies to manage the discharge of brine into the Dolores River. The first scenario simulates no PVU pumping and serves as a base case for comparison to the other scenarios. Two scenarios simulate the effects of varying withdrawal timing at an annual rate about one-third less than during 2010 through 2018. During high-flow spring snowmelt runoff periods when brine discharge is naturally minimized, PVU pumping does not substantially affect salinity in the Dolores River, and comparison of these two scenarios indicates that scheduling brine withdrawals during times of low river stage is nearly as effective at reducing TDS mass flux to the river as pumping brine year-round. Cessation of pumping during periods of high river stage may be advantageous for system maintenance, brine injection, and seismic-risk reduction. The fourth scenario tested the effect of reducing irrigation-return flow on brine discharge and predicted a slight reduction of TDS mass flux to the Dolores River, but not as great a reduction as that of using the PVU to remove brine. The fifth scenario simulated 5 years of drought conditions without PVU pumping and indicates brine discharge during drought about 15 percent greater than during average hydrologic conditions. Results from scenario 5 are consistent with the calibrated model results and indicate that aquifer properties and ET processes and parameters may be affecting simulation results during drought. The Paradox Valley groundwater model provides a reasonable overall match to observed conditions in the Dolores River. The model is useful for evaluating relative differences between brine management scenarios to inform PVU operational decisions and to identify gaps in data and process understanding. Representation of the brine source, hydraulic-conductivity parameters, and recharge and ET processes were identified as potential areas for additional field and modeling research. Additional research in the Paradox Valley might include field-data collection that provides additional information on the hydrogeologic framework, groundwater levels, groundwater TDS concentrations, stream characteristics, and aquifer properties. Additional modeling efforts could benefit from applying advanced tools for model development, calibration, and visualization including parameter-estimation and sensitivity analysis. Statistical evaluation of known model uncertainties such as hydraulic conductivity, streambed conductance, representations of the brine source, recharge, and ET could improve the match between simulated and estimated TDS mass flux from PVU pumping wells and to the Dolores River further informing model predictions and system understanding for the Paradox Valley.

Colorado

Estimated average annualized tsunami losses for the United States

Tsunami hazards are substantial threats to coastal communities across the United States (U.S.) and its territories. U.S. states and territories collaborate through the National Tsunami Hazard Mitigation Program (NTHMP) to develop their own tsunami-hazard information for outreach and evacuation planning. An effort to curate this tsunami-hazard information to support comprehensive risk analysis at the national level has not yet been completed. In support of this effort, the Federal Emergency Management Agency (FEMA) collaborated with the NTHMP, the National Oceanic and Atmospheric Administration (NOAA) and the U.S. Geological Survey (USGS) starting in 2023. This collaboration included the collection and analysis of existing tsunami hazard data and methods in the U.S. Tsunami subject matter experts identified and selected scientifically defensible methods for estimating the risks to buildings and populations in coastal communities. These efforts may support decision making regarding resilience policies, priorities, strategies and funding levels. Tsunamis can be triggered by earthquakes, subaerial or submarine landslides, volcanic eruptions, glacial calving, near-earth objects, weather or other events. These events can cause severe destruction, injuries, and loss of life due to powerful currents and flooding. Tsunamis pose a substantial threat to the western United States and all U.S. territories, as described below. ■ Hawaii is threatened by distant tsunamis due to its central location in the Pacific Ocean basin and has a history of local events. ■ Alaska, particularly the Aleutian Islands, faces local tsunami threats due to proximity to the Alaska-Aleutian Subduction Zone, as well as distant tsunamis from around the Pacific Ocean basin. ■ The western coast of the U.S. is threatened by distant tsunamis from around the Pacific Ocean basin and local source tsunamis from earthquakes generated within the Cascadia Subduction Zone in the Pacific Northwest. ■ American Samoa faces local tsunami threats from earthquakes generated in the nearby Tonga Trench, as well as distant tsunami threats. ■ Guam and the Commonwealth of the Northern Mariana Islands are threatened by local tsunamis from the nearby Mariana Subduction Zone, as well as distant sources from around the Pacific Ocean Basin. ■ Puerto Rico and the United States Virgin Islands are threatened by multiple local and distant tsunami sources, such as the Puerto Rico Trench (PRT), given their location in the complex seismic region of the Caribbean Sea. Several historical events stand out because of their catastrophic impacts. ■ In the Pacific Northwest, the 1700 Cascadia earthquake caused a tsunami that affected coastal Native American communities, though the extent of the damage is not fully documented (Ludwin, et al., 2005). ■ In Puerto Rico, the 1918 earthquake triggered a tsunami that caused $77 million in damage in 2022 dollars and 116 fatalities, primarily along the western coast (Coffman et al., 1982). ■ The 1946 Aleutian Islands earthquake triggered a massive tsunami that devastated Hilo, Hawaii, killing 158 people and resulting in approximately $375 million in damage (adjusted to 2022 dollars) (Fisher et al., 2023). ■ The 1964 Alaska earthquake (M 9.2) generated tsunamis that caused severe destruction in some communities across Alaska, Oregon, and California. This disaster led to a total of 124 fatalities and approximately $2.9 billion in property damage (adjusted to 2022 dollars) (Brocher et al., 2014) (Alaska Science Center, 2024). ■ In American Samoa, a tsunami generated by the 2009 Samoa earthquake (Mw 8.1) caused widespread devastation, resulting in 34 confirmed fatalities (Apatu et al., 2013) and economic losses exceeding $160 million (adjusted to 2022 dollars) (DHS, 2011). More recent events, including the 2010 Chile earthquake, the 2011 Japan earthquake, and the 2022 Tonga volcanic eruption, resulted in millions of dollars in damage to numerous ports and harbors in the U.S. South Pacific territories, Hawaii, and along the west coast of the U.S. (Lynett, et al., 2022) (Wilson, et al., 2013). Since these events, the expansion of the built environment in lowlying areas along the coast has increased the exposure of buildings and people, thereby further escalating community risk from tsunamis. This report provides a comprehensive national assessment of earthquake-generated tsunami risk. It does not include impacts from tsunamis generated by landslides, volcanic eruptions, glacial calving, near-earth objects, weather, or other events. This study is based on the best available hazard data from the U.S. Pacific Coast (California, Oregon and Washington), Alaska, Hawaii, U.S. Pacific Territories (American Samoa, Guam and Commonwealth of the Northern Mariana Islands) and Caribbean Territories (Puerto Rico and United States Virgin Islands). Tsunami risks associated with states along the East Coast, Gulf Coast, and Great Lakes are not included in this study because Hazus 6.1 software (FEMA 2024a) does not currently include the ability to analyze tsunami risk in those states. Once modeling capabilities and tsunami hazard data become available for additional states, FEMA may incorporate these data into future editions of this study.

Alaska, California, Hawaii Oregon, Washington

Preliminary observations of the April 5th, 2024, Mw4.8 New Jersey earthquake

On 5 April 2024, 10:23 a.m. local time, a moment magnitude 4.8 earthquake struck Tewksbury Township, New Jersey, about 65 km west of New York City. Millions of people from Virginia to Maine and beyond felt the ground shaking, resulting in the largest number (>180,000) of U.S. Geological Survey (USGS) “Did You Feel It?” reports of any earthquake. A team deployed by the Geotechnical Extreme Events Reconnaissance Association and the National Institute of Standards and Technology documented structural and nonstructural damage, including substantial damage to a historic masonry building in Lebanon, New Jersey. The USGS National Earthquake Information Center reported a focal depth of about 5 km, consistent with a lack of signal in Interferometric Synthetic Aperture Radar data. The focal mechanism solution is strike slip with a substantial thrust component. Neither mechanism’s nodal plane is parallel to the primary northeast trend of geologic discontinuities and mapped faults in the region, including the Ramapo fault. However, many of the relocated aftershocks, for which locations were augmented by temporary seismic deployments, form a cluster that parallels the general northeast trend of the faults. The aftershocks lie near the Tewksbury fault, north of the Ramapo fault.

New Jersey

Black rails in Baja California

Summarizing records from 1905 to 2025, we document the presence and distribution of the California black rail ( Laterallus jamaicensis coturniculus ) in northwestern México, particularly Baja California and the Colorado River Delta. This subspecies has a restricted distribution in the western U.S. and northwestern México. We found few records over the past century: sparse detections in the early 1900s and an increase in reported records after 2000. Over 120 years, we compiled 35 documented records of California black rail occurrence in Baja California with a minimum reported count of 56 rails. Our call-broadcast survey methods reconfirmed previously occupied sites and documented the species at a previously unreported site. Surveys in the Baja California portion of the Colorado River Delta yielded 20 detections across nine survey events between 2000 and 2022. In April 2003, standardized surveys detected 12 California black rails: 7 in Bahía de San Quintín, 3 in Arroyo San Telmo, and 2 in Arroyo El Rosario. Our recent survey work (2022–2025) recorded maximum monthly counts of 31 detections at Bahía de San Quintín and 15 detections at Estero de Punta Banda, the latter representing a previously undocumented location for the subspecies. These surveys also yielded the first photographic and acoustic documentation of California black rail in México. The contribution of spatial and temporal data provided by citizen science platforms increased our understanding of the subspecies’ distribution. Enforceable protection of this subspecies’ habitat is needed to safeguard its persistence.

Baja California

New U-Pb geochronology and geochemistry of Paleozoic metaigneous rocks from western Yukon and eastern Alaska, cross-border synthesis, and implications for tectonic models

The tectonic evolution of and relation between the Yukon-Tanana terrane and the Lake George assemblage, as well as other associated tectonic assemblages in western Yukon and eastern Alaska, have been debated for decades. The Yukon-Tanana terrane is widely considered to be an allochthonous rifted fragment derived from the Laurentian continental margin, whereas the Lake George assemblage and associated assemblages are currently interpreted to be part of the parautochthonous continental margin of western North America (Laurentia). To address these topics, we present 40 new U-Pb zircon ages and 20 new whole-rock geochemical analyses. We incorporate these data into a new compilation of available geological mapping for a large area that straddles the Alaska-Yukon border, together with 34 previously published U-Pb age determinations and an extensive geochemical database of metaigneous rocks from Late Devonian to Early Mississippian and middle to late Permian assemblages in this area. Magmatism in the Lake George assemblage and related assemblages occurred in two pulses from about 371 to 360 and from about 358 to 347 million years ago (Ma); geochemical discrimination diagrams indicate a large crustal component, possibly indicative of arc magmatism, for felsic metaigneous rocks and a range of tectonic environments for mafic rocks. Magmatism in the Fortymile River and related assemblages, and parts of the Nasina assemblage—all parts of the Yukon-Tanana terrane—are mainly Early Mississippian and span a crystallization age range from about 361 to 343 Ma; geochemical discrimination diagrams for these rocks indicate primarily arc geochemical signatures for both mafic and felsic rocks. Middle to late Permian crystallization ages (about 261–253 Ma) are indicated for felsic metaigneous rocks in the Klondike assemblage and some of the felsic metaigneous rocks in the Nasina assemblage. Based on our mapping, we propose the existence of a possible unconformity between the Mississippian and Permian felsic metavolcanic rocks within the Nasina assemblage that is marked by sporadic occurrences of stretched-pebble conglomerate. Our combined database supports the well-established model of a magmatic arc comprising the Fortymile River and Finlayson assemblages of the rifted Yukon-Tanana terrane continental fragment on which a middle to late Permian arc (Klondike assemblage) was later built. The assemblages of the Yukon-Tanana terrane were subsequently intruded by Late Triassic to Early Jurassic granitoids, presumably during reaccretion of the Yukon-Tanana terrane to the continental margin. Permian and Late Triassic to Early Jurassic intrusions have not been mapped in the now structurally lower plate Lake George assemblage; their absence is one of the lines of evidence that have been used to support the parautochthonous, rather than allochthonous, origin of the Lake George assemblage and related assemblages. Our new data, together with previously published ranges of igneous crystallization ages and geochemical tectonic signatures of the Late Devonian to Early Mississippian magmatic rocks in the Lake George assemblage and associated assemblages and in the Fortymile River, Nasina, and correlated assemblages of the Yukon-Tanana terrane, indicate that the currently accepted interpretation of the Lake George assemblage and associated rocks being part of parauthochthonous North America is not the only possible interpretation of this tectonic entity. Approximately half of the dated intrusive rocks in the Lake George assemblage are contemporaneous with the metaigneous rocks of the Yukon-Tanana terrane arc (<361 Ma). We speculate that our approximately 361 Ma U-Pb age for quartz syenite in part of the North American continental margin in south-central Yukon defines the beginning of rifting of the Laurentian margin. Although the currently favored model of prolonged middle Paleozoic subduction and extension in both the Yukon-Tanana terrane and parautochthonous North America allows for simultaneous middle Paleozoic magmatism on both sides of the Slide Mountain Ocean, we now propose an alternative hypothesis in which the Lake George assemblage represents a deeper part of the rifted Yukon-Tanana terrane arc. If this is the case, the absence of Permian and Late Triassic to Early Jurassic arc rocks in the Lake George assemblage could be explained either by the arcs of these ages not being wide enough to have affected the Lake George assemblage or by tectonic displacement of these arc rocks away from the Lake George assemblage. Our approximately 259 Ma U-Pb zircon age and geochemical analyses of metarhyolite in the Seventymile terrane in Alaska, which comprises remnants of the back-arc basin that separated the Yukon-Tanana terrane from the Laurentian continental margin, confirm the presence of a late middle Permian volcanic arc component to the terrane. Our approximately 319 Ma U-Pb zircon age from the Chicken assemblage (as redefined in this study) in eastern Alaska, combined with previously reported fossil ages and a U-Pb zircon age from this assemblage, indicate that it is a Late Mississippian to Early Pennsylvanian arc assemblage. We propose several other relatively young, locally developed arc assemblages outboard of the ancient continental margin of Laurentia that may correlate with the Chicken assemblage, but we consider its origin to remain an enigma.

Alaska

Treatability study to evaluate bioremediation of trichloroethene at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, 2020–22

Executive Summary Chlorinated solvents, including trichloroethene (TCE) and other chlorinated volatile organic compounds (cVOCs), are widespread contaminants that can be treated by bioremediation approaches that enhance anaerobic reductive dechlorination. Reductive dechlorination can be enhanced either through the addition of an electron donor (biostimulation) or the addition of a known dechlorinating culture (bioaugmentation) along with an electron donor. Although bioremediation has been applied at many TCE-contaminated groundwater sites, application in source zones at sites where residual dense nonaqueous phase liquid (DNAPL) is present is more limited. In this study, laboratory and field treatability tests were completed to evaluate the potential application of anaerobic bioremediation for a shallow groundwater plume containing TCE in a perched alluvial aquifer at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, which was on the National Priorities List as the New Brighton/Arden Hills Superfund site until 2019. In addition to the presence of residual DNAPL at the site, temporal variability in groundwater flow directions and input of oxygenated recharge were possible complicating factors for the application of enhanced anaerobic biodegradation in the shallow plume. The Site K plume extends beneath the footprint of Building 103, which was demolished in 2006, and soil excavations to a maximum depth of 6 feet (ft) below ground surface in 2014 were known to leave some deeper contaminated soil in place in the TCE source area. Groundwater treatment at the site, formalized as part of the 1997 Record of Decision, has been in operation since 1986 and consists of an extraction trench at the downgradient edge of the plume to collect groundwater, which is then pumped to an on-site air stripper. Groundwater concentrations in the plume have been relatively stable since treatment began, indicating a continued source of TCE in the aquifer. The desire for a destructive remedy that would enhance the removal of cVOCs in the aquifer at Site K and shorten the remediation timeframe led the U.S. Army to request that the U.S. Geological Survey conduct a groundwater treatability study to assess bioremediation. This report describes the U.S. Geological Survey bioremediation treatability study conducted during 2020–22, including pre-design site characterization to assist in formulating the bioremediation approach, laboratory experiments to support the design of the field pilot test, and implementation and 1-year performance monitoring results for the pilot test. Pre-design site characterization included the collection of soil cores for cVOC analysis and lithologic descriptions and the re-installment of three wells to obtain hydrologic measurements and initial groundwater chemistry. Relatively flat head gradients were measured at the site, and substantial decreases in water-level elevations occurred from spring to summer (May–July 2021). Continuous water-level monitoring indicated a rapid response to precipitation. Groundwater flow velocities were consistently less than 0.5 foot per day, and the pilot bioremediation test was therefore designed with short lateral distances (about 5 ft) between injection and individual monitoring points. Soil analyses confirmed that high volatile organic compound contamination was left in place in the source area. The highest concentrations were near or in clay at the base of the perched aquifer. Concentrations of cVOCs measured in the replaced wells were consistent with historical data and had a maximum TCE concentration of 57,700 micrograms per liter (μg/L), indicative of nearby residual DNAPL based on the general rule of observed concentrations exceeding 1 percent of solubility. The primary TCE daughter product detected was 1,2-cis-dichloroethene (cisDCE), which indicated limited reductive dechlorination in the plume. Groundwater in both the source and downgradient areas was relatively reducing during the pre-design characterization, particularly in the source area where methane concentrations greater than 400 μg/L were measured. Initial laboratory tests conducted using native aquifer microorganisms from the three replacement wells showed that anaerobic TCE biodegradation rates were low when biostimulated with the addition of sodium lactate as an electron donor, also known as a carbon donor, and resulted in the production of only cisDCE. Addition of a known dechlorinating culture, WBC-2, however, resulted in rapid biodegradation and production of ethene, verifying complete reductive dechlorination of TCE. Microcosms constructed with aquifer soil collected from the site were used to evaluate other electron donors besides lactate to support reductive dechlorination by WBC-2, including corn syrup as an alternative fast-release compound and whey, soy-based vegetable oil, and 3-D Microemulsion (Regenesis, San Clemente, California) as slow-release compounds. First-order rate constants for total organic chlorine removal in these WBC-2 amended microcosms were greatest with either lactate or vegetable oil as the donor, ranging between 0.061 and 0.047 per day or corresponding half-lives of 11–15 days. Testing of commercial products in other WBC-2-bioaugmented microcosms led to selection for the field pilot test of an emulsified vegetable oil product that also contained some sodium lactate as a fast-release donor. Delaying the addition of WBC-2 relative to the donor in the microcosms resulted in the most rapid overall biodegradation rates. The selected design for the pilot test utilized three separate test plots, each about 30-ft wide and 60-ft long: plots GS1 and GS2 in the source area of the plume and plot GS3 in the downgradient area of the plume near the excavation trench. Each test plot had one injection well, one monitoring well upgradient from the injection point, and 12 surrounding monitoring wells in a grid to capture variable groundwater flow directions. Donor injections, which included a bromide tracer, were completed in October 2021, immediately following baseline sampling, and the WBC-2 culture was injected about 40 days later, between November 30 and December 2, 2021. Performance monitoring conducted until December 2022 included hydrologic measurements and analyses of cVOCs, redox-sensitive constituents, dissolved organic carbon, bromide, volatile fatty acids, compound-specific carbon isotopes, and microbial communities. The biogeochemical data collected during the pilot tests in the three treatment plots showed that enhanced, complete reductive dechlorination of cVOCs in the groundwater was achieved in the GS1 and GS3 plots. In contrast, evidence of distribution of the injected amendments and subsequent biodegradation was limited in GS2, which was in an area of more heterogeneous soil lithology and low water table elevations. The molar composition of volatile organic compounds in the GS1 and GS3 plots was dominated by ethene in wells that were reached by the injected amendments by the end of the monitoring period. In the GS1 and GS3 plots, similar patterns were observed of cVOC concentrations decreasing to near detection levels, or below, at some wells sampled in July and October 2022, whereas ethene became dominant and indicated sustained complete reductive dechlorination. Baseline cVOC concentrations were more than a factor of 10 higher in the groundwater in the GS1 plot than in GS3, but no apparent inhibition of complete dechlorination occurred. As expected from the initial pre-design site data and the laboratory experiments, enhanced dissolution of residual DNAPL coupled to biodegradation was evident in the GS1 plot, where a marked increase in dichloroethene (DCE) above the initial baseline and upgradient TCE and DCE concentrations occurred. DCE concentrations subsequently declined where DNAPL dissolution was evident, concurrent with production of vinyl chloride and then predominantly ethene. Thus, overall biodegradation rates outpaced the DNAPL dissolution and desorption and DCE production in the source area. This success in complete degradation to predominantly ethene was achieved even in areas where the DCE concentrations reached a maximum of about 30,000 μg/L. Compound specific isotope analysis of carbon in TCE, cisDCE, trans-1,2-dichloroethene, and vinyl chloride was conducted to provide another line of evidence of the occurrence and extent of anaerobic biodegradation. Along a flow path in each plot that was affected by the injected amendments, carbon isotopes in the TCE and daughter cVOCs in the groundwater became isotopically heavier, indicating biodegradation. Enhanced biodegradation rates calculated from the field tests in GS1 and GS3 showed half-lives of 36.9–75.3 days for DCE degradation and 9.48–38.5 days for ethene production. Notably, these ethene production rates calculated from the field tests are consistent with the results of WBC-2-bioaugmented microcosms amended with either lactate or vegetable oil, which had half-lives for total organic chlorine removal that ranged from 11 to 15 days. These rates indicated rapid enhanced biodegradation, which is promising for application of a full-scale bioremediation remedy. Ultimately, however, the mass of residual or sorbed TCE in the aquifer that remains accessible for dissolution and biodegradation would likely control the time required for a full-scale bioremediation effort to achieve performance goals for TCE and cisDCE specified in the Record of Decision for Site K. The field pilot tests showed that the relatively low hydraulic head gradients and temporal changes in groundwater flow directions in the shallow aquifer would add complexity to a full-scale bioremediation effort. The radius of influence (ROI) at GS1 and GS3 (16.3 ft and 12.7 ft, respectively) were close to the design ROI of 15 ft. The estimated ROI at GS2 was about four times the design ROI, but may be less reliable at this location owing to groundwater flow direction. In addition, the low temperatures following WBC-2 injection in late November to early December 2021, in combination with the low hydraulic head gradients, were probably major factors in the delay observed before the onset of enhanced biodegradation following injection of the culture. Additional test injections could be beneficial to optimize the timing of donor and culture injections with the variable temperatures and hydraulic head in the shallow aquifer.

Minnesota

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia