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Agricultural return flow dynamics on a reach of the East River, Colorado, as assessed by mass balance

The U.S. Geological Survey, in cooperation with the Upper Gunnison River Water Conservancy District, studied historical streamflow in a reach of the East River, Colorado, to gain a preliminary understanding of return flow dynamics. Return flow is agricultural irrigation water that is not consumed by evapotranspiration and instead reaches streams by surface and subsurface flow paths. The study reach had a contributing area of 50 square miles and contained 5.23 square miles of pastures irrigated with water diverted from the East River and its tributaries. By comparing upstream inflows to downstream outflows, the net water balance of the study reach from 1994 to 2023 was assessed. Two general hydrologic conditions for the study reach were identified. One hydrologic condition was characterized by a net loss or consumption of water, termed here as general deficit. This general deficit condition extended about 16 years, from 1997 to 2012. During general deficit years, there was usually a notable net loss of streamflow from April through July, and a small net gain, possibly related to return flows, occurred in August about 75 days after the minimums for losses. The second hydrologic condition was characterized by a net gain of water, termed here as general surplus. This second condition extended about 10 years, from 2014 to 2023. During general surplus years, two separate transitions from net loss to net gain commonly occurred during June through August. Losses during general surplus years were smaller than losses during general deficit years, the respective gains were larger, and times between losses and gains were about 18 and 22 days. Differences between the two hydrologic conditions could reflect interactions among irrigation water, available capacity to store additional shallow groundwater, and streamflow. However, deciphering the causes for the shifts between the two general hydrologic conditions was beyond the scope of this report.

Colorado

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

Estimation of magnitude and frequency of floods for streams in Puerto Rico: New empirical models

Flood-peak discharges and frequencies are presented for 57 gaged sites in Puerto Rico for recurrence intervals ranging from 2 to 500 years. The log-Pearson Type III distribution, the methodology recommended by the United States Interagency Committee on Water Data, was used to determine the magnitude and frequency of floods at the gaged sites having 10 to 43 years of record. A technique is presented for estimating flood-peak discharges at recurrence intervals ranging from 2 to 500 years for unregulated streams in Puerto Rico with contributing drainage areas ranging from 0.83 to 208 square miles. Loglinear multiple regression analyses, using climatic and basin characteristics and peak-discharge data from the 57 gaged sites, were used to construct regression equations to transfer the magnitude and frequency information from gaged to ungaged sites. The equations have contributing drainage area, depth-to-rock, and mean annual rainfall as the basin and climatic characteristics in estimating flood peak discharges. Examples are given to show a step-by-step procedure in calculating a 100-year flood at a gaged site, an ungaged site, a site near a gaged location, and a site between two gaged sites.

Puerto Rico

Technique for estimating magnitude and frequency of floods in Kentucky

This report presents flood magnitude and frequency relations applicable to unregulated streams in Kentucky. The relations are based on flood data at 117 gaging stations in Kentucky and 14 in adjacent states having 10 or more years of record not significantly affected by man-made changes. Equations that relate flood magnitude and frequency to contributing drainage area in 16 geographic areas may be used to estimate magnitude of future floods with recurrence intervals of as much as 100 years on gaged and ungaged streams having drainage areas of 10 to 4,300 square miles (25 .9 to 11,100 square kilometers) . Estimating equations are also presented in graphical form for the convenience of the user. Additional graphs are presented to estimate flood magnitude for selected recurrence intervals along the Cumberland, Kentucky, and Ohio Rivers.

Kentucky

Flood-inundation maps for 14.8 miles of Little and Big Papillion Creeks in Omaha, Nebraska, 2023

Digital flood-inundation map libraries for two reaches that constitute 14.8 miles of Little and Big Papillion Creeks in Omaha, Nebraska, were created by the U.S. Geological Survey (USGS) in cooperation with the Papio-Missouri River Natural Resource District. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Program website at https://www.usgs.gov/mission-areas/water-resources/science/flood-inundation-mapping-fim-program , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at Little Papillion Creek at Irvington, Nebr. (USGS station 06610750), Little Papillion Creek at Ak-Sar-Ben at Omaha, Nebr. (USGS station 06610765), and Big Papillion Creek at Q Street at Omaha, Nebr. (USGS station 06610770) streamgages. Near-real-time stages at these streamgages may be obtained from the USGS National Water Information System database at https://doi.org/10.5066/F7P55KJN or from the National Weather Service Advanced Hydrologic Prediction Service at https://water.weather.gov/ahps/ . Flood profiles were computed for two different reaches that constitute 14.8 miles of stream length in the study area by using hydraulic models. The models were calibrated by adjusting roughness coefficients to best represent the current (2022) stage-streamflow relation at the streamgages within the study reach. The hydraulic models were then used to compute water-surface profiles at 1-foot stage intervals for selected stage ranges to represent various flooding scenarios at the streamgages in each reach. The simulated water-surface profiles then were combined with a digital elevation model using a geographic information system, which had a 10-foot grid spacing to delineate the flooding extents and water depths for each stage. The availability of these flood-inundation maps, along with information regarding current stage from the USGS streamgages, can provide emergency management personnel and residents with information that is critical for flood response activities and post flood recovery efforts.

Nebraska

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas

Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho

Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment

Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.

ACS ES&T Water

Wetland sedimentation and vegetation patterns near selected highway crossings in West Tennessee

Wetland sedimentation and vegetation patterns at 11 highway crossings in West Tennessee were studied from 1987 to 1989. The purpose of the study was to investigate potential adverse effects of highway crossings on wetlands. Sedimentation rates, determined from root-burial depths, were highly variable. Average rates offine-grained deposition ranged from 0.005 to 0.033 foot per year for stations in locally ponded areas and from -0.002 to 0.039 foot per year for stations in drained areas. Sedimentation rates upstream from highway crossings were not significantly different from downstream rates at 8 of the 11 study sites. Three study sites had significantly greater sedimentation rates downstream. Sand splays were observed downstream from bridges at most study sites. Vegetation patterns and tree growth appear most strongly related to hydropetiod, defined as the average length of time an area is covered by water each year. The influence of sedimentation on tree growth is difficult to separate from the influence of hydroperiod because areas with high sedimentation rates typically have long hydroperiods. Estimated hydroperiod increased no more than 1 percent because of backwater from the highway crossings at the 11 study sites, while the estimated average depth of flood-plain inundation increased by an average of 6 percent.

Tennessee

Multiple-well monitoring site adjacent to the Midway- Sunset and Buena Vista Oil Fields, Kern County, California

Groundwater quality in and around oil fields in the Southern San Joaquin Valley is of interest to many California residents that rely heavily on groundwater for domestic, commercial, and agricultural use. To help assess the effects of historical oil-field activities and natural geologic sources on groundwater near the southwest margins of the Kern County Groundwater Subbasin, a multiple-well monitoring site was installed near the administrative boundary between the Midway-Sunset and Buena Vista Oil Fields in Kern County, California. The installation of the Midway-Sunset Buena Vista multiple-well monitoring site (MSBV) supports regional analysis of the relations of oil and gas sources to groundwater quality by providing information about the geology, hydrology, geophysical properties, and water quality of the alluvial and upper Tulare aquifers in areas where groundwater data were limited. Data collected from the site included drill cuttings, whole core samples, sidewall core samples, mud-gas analysis, borehole geophysical logs, depth to water measurements, and water quality samples. Whole cores were scanned using dual energy computed tomography. Subsamples of selected cores were analyzed for density, porosity, specific retention, and bulk minerology. Thin sections of the subsamples were prepared, photographed, and examined. Two samples were analyzed using scanning electron microscope technology to examine the microporosity of diatomite laden sediment. Instrumentation installed in the wells collect hourly depth to water measurements. Analysis of the data show there is 355 feet of alluvium overlying the Tulare Formation at the well site. The contact between the two formations is an aquitard resulting in a perched aquifer in the alluvium and unconfined aquifer in the Tulare Formation. The alluvium is more heterogenous and finer grained than the Tulare Formation resulting in markedly higher porosity in the alluvium compared to the Tulare Formation. Higher specific retention observed in the alluvium is attributed to the finer grained sediment and greater abundance of reworked diatomite (as represented by opal-CT [cristobalite-tridymite]) compared to the Tulare Formation. Total dissolved solids (TDS) approached or exceeded 10,000 milligrams per liter (mg/L) in the alluvium from approximately 176 to 242 feet below land surface and at the top of the Amnicola clay at approximately 670 feet below land surface within the Tulare Formation. Elevated TDS, chloride, and boron concentrations in the alluvium and on top of the Amnicola clay likely reflect groundwater that is mixed with oil-field water. Water chemistry and modern-aged groundwater in the alluvial monitoring well (MSBV #3) are consistent with the oil-field water in the alluvium being derived from documented historical surface disposal of oil-field water upslope (northwest) of the site. Water chemistry and pre-modern groundwater age in the deeper Tulare monitoring well (MSBV #1) on top of the Amnicola clay are consistent with oil-field fluids derived from upslope natural geologic sources or old oil wells that leak in the subsurface. Shallow groundwater in the Tulare (MSBV #2) is not affected by mixing with oil-field sources.

EarthArXiv

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota

Estimating the importance of floating surface material to the total phosphorus transport in Silver Creek, Wisconsin using Particle Image Velocimetry

Various techniques are used to estimate nutrient delivery in streams that combine flow and water-quality data. However, the transport of surface floating material is difficult to measure, and is therefore typically neglected when stream sampling and in the estimated nutrient delivery. Here, we describe an approach to estimate the amount of material (duckweed ( Lemna genus), filamentous algae, and other macrophyte fragments) and associated nutrients (in this case, phosphorus, P) transported on the surface of Silver Creek, Wisconsin, to determine if this material is an important transport mechanism and if historical P loads were underestimated. This approach includes estimating the transport of surface material using 10 s videos collected every 15 min from a downward-looking camera installed beneath a bridge. The average velocity of the surface material was first determined using Large-Scale Particle Image Velocimetry (LSPIV), which uses short videos to analyze surface particle movement. The amount of surface material in each video was then computed using computer-vision techniques. The P load associated with the transported surface material was then estimated by combining surface velocities, coverage of floating material, and laboratory-measured P content. Surface material transported ~9–11% of the total summer P load and ~4–7% of the annual load in Silver Creek.

Wisconsin

A process-based model for forecasting wave runup along the coast of Georgia

Wave runup is an important nearshore process that impacts total water level, sediment transport, and coastal design. Current methods for forecasting wave runup implement an empirical model that considers offshore wave height, wave period, and generalized beach slope. In this study, the authors generated wave runup forecasts from offshore wave conditions and a system of polynomial equations derived from numerical simulations at three different still water datums for each beach profile. They developed a process-based methodology that incorporated site-specific cross-shore topobathy into the phase-resolving numerical model. A comparison between the system of equations, deterministic hydrodynamic simulations, and observed high-water marks was made using Hurricanes Matthew (2016) and Irma (2017) for 12 cases, and it showed that the polynomials were capable of being consistent with the results from full simulation runs, while not requiring hours of runtime when a forecast was needed—the differences between the polynomial and the observed high water marks ranged from 3 to 32 cm for the Irma hindcast and 9–70 cm for Matthew. Then, using forcings from Hurricanes Ian and Nicole (2022), the model predicted the occurrence of dune collision, overwash, and inundation for the coast of Georgia and suggested that wave runup was impacted by the still water level and local topobathy.

Georgia

An optimized network for phosphorus load monitoring for Lake Okeechobee, Florida

Phosphorus load data were evaluated for Lake Okeechobee, Florida, for water years 1982 through 1991. Standard errors for load estimates were computed from available phosphorus concentration and daily discharge data. Components of error were associated with uncertainty in concentration and discharge data and were calculated for existing conditions and for 6 alternative load-monitoring scenarios for each of 48 distinct inflows. Benefit-cost ratios were computed for each alternative monitoring scenario at each site by dividing estimated reductions in load uncertainty by the 5-year average costs of each scenario in 1992 dollars. Absolute and marginal benefit-cost ratios were compared in an iterative optimization scheme to determine the most cost-effective combination of discharge and concentration monitoring scenarios for the lake. If the current (1992) discharge-monitoring network around the lake is maintained, the water-quality sampling at each inflow site twice each year is continued, and the nature of loading remains the same, the standard error of computed mean-annual load is estimated at about 98 metric tons per year compared to an absolute loading rate (inflows and outflows) of 530 metric tons per year. This produces a relative uncertainty of nearly 20 percent. The standard error in load can be reduced to about 20 metric tons per year (4 percent) by adopting an optimized set of monitoring alternatives at a cost of an additional $200,000 per year. The final optimized network prescribes changes to improve both concentration and discharge monitoring. These changes include the addition of intensive sampling with automatic samplers at 11 sites, the initiation of event-based sampling by observers at another 5 sites, the continuation of periodic sampling 12 times per year at 1 site, the installation of acoustic velocity meters to improve discharge gaging at 9 sites, and the improvement of a discharge rating at 1 site.

Florida

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Evaluation of submersible pressure transducers for streamflow monitoring in small streams

Compact streamgages requiring minimal infrastructure and equipped with submersible pressure transducers (PTs) are increasingly used to monitor small streams, yet disparate implementations obscure their accuracy under real-world conditions. This study isolated instrumentation-derived uncertainty in stage monitoring by co-locating various combinations of commercial vented and unvented PTs with seven U.S. Geological Survey (USGS) reference streamgages on small streams. Multi-year PT stage records from compact streamgages, collected and corrected following USGS protocols, were compared to concurrent reference observations. Vented PTs demonstrated an average measurement uncertainty of ±0.005 m and mean absolute percent error (MAPE) of ±0.2%. Unvented PTs exhibited higher uncertainty, averaging ±0.009 m and ±0.4% MAPE. Although both sensor types had stage errors up to ±0.3 m, 95% of vented PT and unvented PT observations were within 0.01 and 0.02 m of reference stage, respectively. Analysis of additional unvented PTs revealed stage errors of up to ±1.2% when using barometric sensors within 15 km of the in-water sensor. Propagation of stage error to discharge using reference rating models resulted in cumulative discharge MAPEs of ±4.5% for vented and ±5.5% for unvented PTs. These findings highlight PTs as practical alternatives to reference instrumentation when deployed with standardized procedures, potentially expanding access to reliable streamflow data.

conterminous United States