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At least 703 records · Page 39Linked to original sources

Results of hydrologic tests and water-chemistry analyses, wells H-4A, H-4B, and H-4C, at the proposed waste isolation pilot plant site, southeastern New Mexico

Data were collected during hydrologic testing at wells H-4A, H-4B, and H-4C in the southern part of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico. The three water-bearing zones tested, the Magenta and Culebra Dolomite Members of the Rustler Formation and the Rustler Formation-Salado Formation contact, yield water to wells at rates less than 0.9 gallon per minute. Throughout the testing, water-pressure response in the tested zone was monitored by a pressure transducer system. Shut-in and slug tests were conducted to acquire the data from which the following values were derived. Calculated transmissivities for the Magenta, Culebra and the Rustler-Salado contact at wells H-4A, H-4B, and H-4C were 0.06, 0.9, and 0.0006 foot squared per day respectively. Water samples from the Magenta and Culebra had dissolved-solids concentrations of 22,300 and 18,100 milligrams per liter, respectively. The major chemical constituents of ground-water samples from these two zones were sodium, chloride, and sulfate. Water samples from the Rustler-Salado contact had a dissolved-solids concentration of 322,000 milligrams per liter and magnesium, sodium, and chloride were the major constituents. Radium-226, a naturally occurring radioactive element, was present in samples from all three zones. (USGS)

New Mexico↗

Results of hydrologic tests and water-chemistry analyses, wells H-5A, H-5B, and H-5C, at the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

Data were collected during hydrologic testing at wells H-5A, H-5B, and H-5C in the northeastern part of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico. The three water-bearing zones tested, the Magenta and Culebra Dolomite Members of the Rustler Formation and the Rustler Formation-Salado Formation contact, yield water to wells at rates less than 0.6 gallon per minute. Throughout the testing, water-pressure response in the tested zone was monitored by a pressure-transducer system. Shut-in and slug tests were conducted to acquire data from which the following values were derived. Dissolved-solids concentrations In water samples were: (1) Magenta Dolomite Member, 6,090 milligrams per liter; (2) Culebra Dolomite Member, 144,000 milligrams per liter; and (3) Rustler Formation-Salado Formation contact, 412,000 milligrams per liter. The major chemical constituents of water samples from the Magenta Dolomite Member were sodium and sulfate; from the Culebra Dolomite Member, sodium and chloride; and from the Rustler Formation-Salado Formation contact, magnesium and chloride. Radium-226, a naturally occurring radioactive element, was present in samples from all three zones.

New Mexico↗

Results of hydrologic tests and water-chemistry analyses, Wells H-6A, H-6B, and H-6C, at the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

Hydrologic testing was conducted at wells H-6A, H-6B, and H-6C in the northwestern part of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico to define hydraulic properties of three water-bearing zones. The zones tested were the Magenta and Culebra Dolomite Members of the Rustler Formation and the Rustler Formation-Salado Formation contact. The Magenta Dolomite and the Rustler-Salado contact yield water to wells at rates less than 0.5 gallon per minute as determined from shut-in and slug tests. A transmissivity value for the Culebra Dolomite Member was obtained by conducting conventional pumping and recovery tests in well H-6B; this well was pumped at a rate of approximately 11 gallons per minute. Water samples from the Magenta Dolomite Member of the Rustler Formation had a dissolved-solids concentration of 5,760 milligrams per liter. The major chemical constituents of water samples from this zone were sulfate, sodium, and chloride. Water samples from the Culebra Dolomite Member of the Rustler Formation had dissolved-solids concentration of 52,600 milligrams per liter, and samples from the Rustler Formation-Salado Formation contact had 316,000 milligrams per liter; chloride and sodium were the major constituents in the water samples. Radium-266, a naturally occurring radioactive element, was present in samples from all three zones.

New Mexico↗

Availability and chemistry of ground water on the Bruneau Plateau and adjacent eastern plain in Twin Falls County, south-central Idaho

The Bruneau plateau in south-central Idaho consists of about 889 ,600 acres of potentially irrigable land. About 112,200 of these acres have been developed for agriculture; 11,200 acres are irrigated with ground water, and the remaining acreage is irrigated with water from the Snake and Bruneau rivers and Salmon Falls Creek. On the basis of present usage, about 158,000 acre-feet of water per year are needed to develop an additional 63,000 acres. About 438,000 acre-feet per year are needed to irrigate existing and newly developed lands in dry years when streamflow in the Snake River at Milner Dam is inadequate to meet appropriated needs. Pumping lifts of about 400-600 feet and low well yields on the Bruneau plateau probably preclude large-scale irrigation development solely from local ground-water resources. However, supplemental sources of irrigation water are available from a perched-water aquifer, a thermal aquifer, and the regional aquifer adjacent to the plateau. About 100,000-115,000 acre-feet per year of water probably could be withdrawn from the perched and regional aquifers and conveyed to the plateau without serious impact on local ground-water resources. The amount of water that could be safely withdrawn from the thermal aquifer was not determined. (USGS)

Water-Resources Investigations Report↗

Controls on ground-water chemistry in the Horse Heaven Hills, south-central Washington

Miocene basaltic aquifers are the source of domestic and municipal water, and about 20,000 acre-feet of irrigation water annually, in the Horse Heaven Hills in south-central Washington State. Groundwater chemical variations derive from the hydraulic characteristics is of the geohydrologic system, from groundwater basalt reactions, and from irrigation. Some dissolved species concentrations increase with residence time; others decrease. Recharge area groundwaters are calcium magnesium sodium bicarbonate waters with sodium-adsorption ratios (SAR's) less than 1.0. They evolve to sodium potassium bicarbonate waters with SAR 's as high as 17. Glassy and cryptocrystalline phases of the basalt are the main sources of dissolved sodium. They dissolve by silicate hydrolysis in carbon dioxide charged waters that recharge the aquifer system. Dissolved silicon, iron, and aluminum concentrations are controlled by the solubilities of amorphous secondary alteration products, which order to silica phases, oxyhydroxides, and smectite. Carbonate mineral precipitation is induced by increasing pH from the hydrolysis reaction. Sodium and potassium concentrations increase until clinoptilolite saturation is reached and precipitation begins. Deviations from the general variation patterns are due to localized geologic structures which distort the groundwater flow system, and to the irrigation use of Columbia River water. (USGS)

Water-Resources Investigations Report↗

Numerical simulation of advective-dispersive multisolute transport with sorption, ion exchange and equilibrium chemistry

A model was developed that can simulate the effect of certain chemical and sorption reactions simultaneously among solutes involved in advective-dispersive transport through porous media. The model is based on a methodology that utilizes physical-chemical relationships in the development of the basic solute mass-balance equations; however, the form of these equations allows their solution to be obtained by methods that do not depend on the chemical processes. The chemical environment is governed by the condition of local chemical equilibrium, and may be defined either by the linear sorption of a single species and two soluble complexation reactions which also involve that species, or binary ion exchange and one complexation reaction involving a common ion. Partial differential equations that describe solute mass balance entirely in the liquid phase are developed for each tenad (a chemical entity whose total mass is independent of the reaction process) in terms of their total dissolved concentration. These equations are solved numerically in two dimensions through the modification of an existing groundwater flow/transport computer code. (Author 's abstract)

Water-Resources Investigations Report↗

Inorganic and organic ground-water chemistry in the Canal Creek area of Aberdeen Proving Ground, Maryland

Groundwater chemical data were collected from November 1986 through April 1987 in the first phase of a 5-year study to assess the possibility of groundwater contamination in the Canal Creek area of Aberdeen Proving Ground, Maryland. Water samples were collected from 87 observation wells screened in Coastal Plain sediments; 59 samples were collected from the Canal Creek aquifer, 18 from the overlying surficial aquifer, and 10 from the lower confined aquifer. Dissolved solids, chloride, iron, manganese, fluoride, mercury, and chromium are present in concentrations that exceed the Federal maximum contaminant levels for drinking water. Elevated chloride and dissolved-solids concentrations appear to be related from contaminant plumes but also could result from brackish-water intrusion. Excessive concentrations of iron and manganese were the most extensive water quality problems found among the inorganic constituents and are derived from natural dissolution of minerals and oxide coatings in the aquifer sediments. Volatile organic compounds are present in the Canal Creek and surficial aquifers, but samples from the lower confined aquifer do not show any evidence of contamination by inorganic or organic chemicals. The volatile organic contaminants detected in the groundwater and their maximum concentrations (in micrograms/L) include 1,1,2,2- tetrachloroethane (9,000); carbon tetrachloride (480); chloroform (460); 1,1,2-trichloroethane (80); 1,2-dichloroethane (990); 1,1-dichloroethane (3.1); tetrachloroethylene (100); trichloroethylene (1,800); 1,2-trans- dichloroethylene (1,200); 1,1-dichloroethylene (4.4); vinyl chloride (140); benzene (70); and chlorobenzene (39). On the basis of information on past activities in the study area, some sources of the volatile organic compounds include: (1) decontaminants and degreasers; (2) clothing-impregnating operations; (3) the manufacture of impregnite material; (4) the manufacture of tear gas; and (5) fuels used in garages and at the air-field. The high density of most of the detected organic compounds in free-product form would have aided their movement into the aquifers by vertical sinking. The outcrop area of the upper confining unit and an area cut by a paleochannel are most susceptible to contamination because a near-surface impermeable layer is not present. (USGS)

Water-Resources Investigations Report↗

Characterization of bottom-sediment, water, and elutriate chemistry at selected stations at Reelfoot Lake, Tennessee

To better-understand and predict the potential effect of dredging on water quality at Reelfoot Lake, chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water. Chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water collected at five stations in the lake during November 1988. Lake water was of the calcium magnesium bicarbonate type with an average dissolved-solids concentration of 120 milligrams per liter. Trace constituents were present in bottom sediments at concentrations representative of their average relative abundance in the earth?s crust. Elutriate waters prepared by mixing bottom sediment and lake water had suspended-solids concentrations as high as 2,000 milligrams per liter which exerted significant oxygen demand Trace constituents in the unfiltered elutriate waters were elevated with respect to lake water; elevated concentrations were attributable to the increased suspended-solids concentrations. Concentrations of total-recoverable copper, lead., and zinc in many elutriate waters exceeded U.S. Environmental Protection Agency?s water-quality criteria for the protection of freshwater aquatic life. The toxicity of elutriate waters, as measured by a 48-hour bioassay with Ceriodaphnia dubia, was low.

Tennessee↗

Natural radioactivity in, and inorganic chemistry of, ground water in the Kirkwood-Cohansey aquifer system, southern New Jersey, 1983-89

The distribution of naturally occurring radionuclides in ground water of the Kirkwood- Cohansey aquifer system in southern New Jersey was assessed during 1988-89. The Kirkwood-Cohansey aquifer system consists of quartz-sand formations overlain by a feldspar-rich quartz-sand formation, the Bridgeton Formation, that is heavily developed agriculturally. The sum of the concentrations of radium-226 and radium-228 exceeded the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 5 pCi/L (picocuries per liter) in 26 of 81 wells from which water samples were analyzed, and gross alpha-particle activity exceeded the MCL of 15 pCi/L in 5 of the 81 samples. The median concentrations of radon-222 and uranium were 280 pCi/L and 0.03 micrograms per liter, respectively. Water in the Kirkwood-Cohansey aquifer system generally is dilute (median dissolved solids concentration, 55 milligrams per liter) and acidic (median pH, 4.90), but concentrations of major ions and acidity are higher in water from wells in areas where the Bridgeton Formation outcrop and agricultural land use are present than in areas where they are absent. Concentrations and activities of radionuclides also were greatest in these areas. Results of statistical analyses indicate that these relations are significant and nonrandom. The positive relation of radionuclide concentration or activity to the presence of geologic outcrop and agricultural land, and a similar relation of the concentration of inorganic constituents to the presence of geologic outcrop and agricultural land, indicate that geochemical processes enhance mobilization of radionuclides in these areas relative to areas where the Bridgeton Formation and agricultural land are absent. The sum of the ccncentrations of radium-226 and radium-228 most likely exceeds the MCL in ground-water samples with nitrate concentrations greater than 5 milligrams per liter.

New Jersey↗

Hydrology and water chemistry of shallow aquifers along the upper Clark Fork, western Montana

Shallow ground-water resources in western Montana have been developed primarily in Quaternary alluvium and Tertiary deposits, although bedrock supplies water to wells locally. Well-yield and trans- missivity values were largest (medians of 40 gallons per minute and 970 feet squared per day, respec- tively) in alluvium and smallest (medians of 15 gallons per minute and 130 feet squared per day, respectively) in bedrock. Chemical composition of ground water was dominated by calcium, magnesium, and bicarbonate derived from dissolution of carbonate minerals. Other water types may be the result of ion exchange (increased sodium) and mixing of geothermal water or leachate from mine wastes (increased sulfate). Although concen- trations of arsenic were relatively small (maximum of 20 micrograms per liter), they were somewhat larger in alluvium within 300 feet of the Clark Fork. Elevated concentrations of cadmium (maximum of 6 micrograms per liter) were measured in water from one well downgradient from tailings ponds. Although mining and smelting activities have resulted in widespread distribution of contami- nants in the Clark Fork valley, this study indicates that ground water contains elevated concentrations of trace elements only locally. Streamflow data indicate significant ground-water inflow to the Clark Fork in two reaches. Between Racetrack and Garrison, irrigation-return flow probably augments naturally occurring ground-water discharge. Between Jens and Cramer Creek, geo- thermal water from bedrock flows through alluvium to the river. In the Clark Fork, the maximum arsenic concentration was 8.1 micrograms per liter; copper and manganese concentrations were largest at Warm Springs (maximums of 14 and 350 micrograms per liter, respectively) and decreased downstream.

Water-Resources Investigations Report↗

Geohydrology and water chemistry of abandoned uranium mines and radiochemistry of spoil-material leachate, Monument Valley and Cameron areas, Arizona and Utah

Uranium mines in the Monument Valley area were established predominately in channel-fill deposits within the Shinarump Member of the Chinle Formation. The Shinarump Member yields ground water to wells and may yield water to the Moonlight and Radium Hill mines. In the study area near Cameron, uranium was mined from channel-fill deposits within the Petrified Forest Member of the Chinle Formation. Units of the Petrified Forest Member do not yield ground water to wells in the area, but fractures in the lower part of the Petrified Forest Member are probable pathways for upward flow of water from the Shinarump Member. Most of the mines receive water from surface inflow of rainfall runoff, but ground water also may be transmitted to open pits and drill holes in the subsurface through fractures or along faults in the Petrified Forest Member. Uranium-238 activities in shallow ground water from mines ranged from 150 to 14,000 picocuries per liter. Radionuclide activities in well and spring water were less than in shallow ground water near mines; however, in some samples, radionuclide activities in wells and springs were greater than activities in pit water. Uranium concentrations in leachate samples ranged from 20 to 7,700 micrograms per liter. Batch tests were done with material that was 2.00 millimeters and smaller. The radiochemistry of leachate from coarser material was not determined, and the specific rate and magnitude of radionuclide leaching depends on site-specific conditions that include the amounts of oxygen and organic material present, temperature, spoil mineralogy, and local ground-water composition.

Arizona, Utah↗

Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1992-93

Physical and chemical data were collected from four surface-water sites, six ground-water sites, and two bottom-sediment sites during 1992-93. Specific conductance, hardness, alkalinity, and dissolved- solids concentrations generally were higher in ground water than in surface water. The median concentrations of dissolved major ions, with the exception of potassium, were higher in ground water than in surface water. In surface water and ground water, calcium was the dominant cation, and bicarbonate was the dominant anion. Concentrations of dissolved nitrite and nitrite plus nitrate in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels of 1 and 10 milligrams per liter for drinking water, respectively. Ammonium plus organic nitrogen in bottom sediment was detected at the highest concentration of any nitrogen species. Median values for most of the dissolved trace elements in surface water and ground water were below the detection levels. Dissolved trace elements in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels for drinking water. Trace-element concentrations in bottom sediment were similar to trace-element concentrations reported for soils of the western conterminous United States. Several organochlorine pesticides and priority pollutants were detected in surface-water and bottom-sediment samples; however, they did not exceed water-quality standards. Pesticides or priority pollutants were not detected in ground-water samples.

Water-Resources Investigations Report↗