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Geochronology and mapping constraints on the time-space evolution of the igneous and hydrothermal systems in the Taurus Cu-Mo district, eastern Alaska

The Taurus porphyry Cu-Mo district contains four mineralized porphyry centers in the eastern interior of Alaska. All four centers were emplaced during a magmatic episode that spanned from ca. 72 to 67 Ma, with seven distinct igneous suites. Each igneous suite resulted in hydrothermal alteration and mineralization, with younger pulses overprinting older pulses. Each magmatic-hydrothermal system is not present at all four mineralized centers. Apart from the Dennison occurrence, each mineralized center records pulses of repeated intermediate-silicic magmatism and associated alteration and mineralization. Laser ablation-inductively coupled plasma-mass spectrometry U-Pb zircon crystallization ages indicate that an early quartz porphyry dike swarm ranges in age from ca. 71 to 70 Ma and is associated with potassic, sericitic, and propylitic alteration. Quartz latite intrusions were emplaced at ca. 69 Ma and exhibit early sodiccalcic alteration overprinted by potassic, sericitic, and propylitic alteration. The Taurus monzonite suite is cut by quartz latite but yielded an ca. 70 Ma emplacement age and exhibits the largest footprint of potassic and sericitic alteration. Feldspar porphyry dikes were emplaced ca. 69 Ma and have significant tourmaline-bearing potassic and sericitic alteration. This suite was followed by development of an igneous breccia with a monzonitic igneous matrix. Sodic-calcic alteration was associated with the igneous brecciation. A small stock of monzonite was emplaced at ca. 68 Ma causing locally pervasive sericite-tourmaline-pyrite alteration. The youngest suite of magmatism dated in the district is a series of granodiorite porphyry dikes with weak sodic-calcic and propylitic alteration that truncates earlier alteration assemblages. Mineralization in the district consists of chalcopyrite and molybdenite associated with sugary quartz veins with potassium feldspar and biotite alteration envelopes (A veins). Less common banded quartz-molybdenite veins (B veins) occur with potassium feldspar envelopes. Gold occurs throughout the district and is strongly correlated with copper grade. Sericitic alteration contains lower copper contents and is predominantly associated with quartz-pyrite veins with sericite envelopes (D veins). Pyrrhotite and local arsenopyrite are present in sericitic assemblages. Pyrrhotite also occurs as inclusions in pyrite within D veins. Magmas across the district exhibit oxidized characteristics, evidenced by the presence of abundant magnetite, rare titanite, and elevated Eu/Eu* and Ce/Ce* in zircon. Zircon Th/U and Yb/Gd compositions suggest a fractionation path controlled by apatite, titanite, and hornblende. Zircon rare earth element ratios and trace element data indicate two distinct batches of magma evolved from mafic parental compositions to monzonite and granodioritic compositions via fractional crystallization. In the early pulse of magma (ca. 72–69 Ma), fractional crystallization was key to ore formation. Earlier, better mineralized suites evolve to less negative Eu anomalies (Eu/Eu* > 0.7), indicating more oxidized and higher-water-pressure conditions evidenced by the suppression of plagioclase crystallization, compared to later, more poorly mineralized suites. The temporal and spatial evolution of the district was determined from mapping and U-Pb and Re-Os geochronology. Mapping of igneous and hydrothermal assemblages indicates that the locus of the intrusive suites and hydrothermal systems shifted spatially over time, based on the presence of high-temperature (K-silicate–dominant) alteration, which is coincident with the highest Cu and Au grades. The earliest hydrothermal system was centered at Bluff and East Taurus and transitioned to West Taurus during emplacement of the second magmatic suite. Emplacement of the third magmatic suite was centered back at East Taurus, and the fourth and fifth suites were centered at West Taurus. The latest suites were widespread without a core of high-temperature alteration marking a central locus. East Taurus contains the overlap of six of the seven magmatic and hydrothermal suites and has the highest intersected grades and tonnages in the district. The Bluff and Dennison occurrences exhibit fewer igneous suites and hydrothermal assemblages with weak mineralization. Sodic-calcic alteration, common on the deep and distal flanks of porphyry systems, is only present at West Taurus and is indicative of a localized source of high-salinity nonmagmatic fluids.

Alaska, Yukon Territory↗

Summary of references to mineral occurrences (other than mineral fuels and construction materials) in the Bering Glacier, Icy Bay, Middleton Island, and Yakutat quadrangles, Alaska

This summary of references is designed to aid in library research on metallic and nonmetallic (other than mineral fuels and construction materials) mineral occurrences in the Bering Glacier, Icy Bay, Middleton Island, and Yakutat quadrangles, Alaska. References to most reports of the Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys released before June 1, 1979, are included. Certain, mainly statistical, reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and the biennial and annual reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on geochemical anomalies and on many prospects and claims about which little more than their locations is known (for example, some of those in MacKevett and Holloway, 1977 (OF 77-169A)). These omissions should not be interpreted as a judgment on my part that the prospects and claims are not valid mineral occurrences, but only that there are insufficient data to describe any mineral deposits that might be present. This report is divided into three parts: a section made up of summaries of references arranged alphabetically by occurrence name; a section that lists synonyms for names in the first section and the names of operators and owners of mines and prospects; and a section that lists, by author, all references in the first section and in these introductory paragraphs.

Alaska↗

Summary of reconnaissance for radioactive deposits in Alaska, 1945-1954, and an appraisal of Alaskan uranium possibilities

In the period 1945-1954 over 100 investigations for radioactive source materials were made in Alaska. The nature of these investigations ranged from field examinations of individual prospects or the laboratory analysis of significantly radioactive samples submitted by prospectors to reconnaissance studies of large districts. In this period no deposits of uranium or thorium that would warrant commercial exploitation were discovered. The investigations, however, disclosed that radioactive materials occur in widely scattered areas of Alaska and in widely diverse environments. Many igneous rocks throughout Alaska are weakly radioactive because of uranium- and thorium-bearing accessory minerals, such as allanite, apatite, monazite, sphene, xenotime, and zircon; more rarely the radioactivity of these rocks is due to thorianite or thorite and their uranoan varieties. The felsic rocks, for example, granites and syenites, are generally more radioactive than the mafic igneous rocks. Pegmatites, locally, have also proved to be radioactive, but they have little commercial significance. No primary uranium oxide minerals have been found yet in Alaskan vein deposits, except, perhaps, for a mineral tentatively identified as pitchblende in the Hyder district of southeastern Alaska. However, certain occurrences of secondary uranium minerals, chiefly those of the uranite group, on the Seward Peninsula, in the Russian Mountains, and in the vicinity of Kodiak suggest that pitchblende-type ores may occur at depth beneath zones of alteration. Thorite-bearing veins have been discovered on Prince of Wales Island in southeastern Alaska. Although no deposits or carnotite-type minerals have been found in Alaska, several samples containing such minerals have been submitted by Alaskan prospectors. Efforts to locate the deposits from which these minerals were obtained have been unsuccessful, but review of available geologic data suggests that several Alaskan areas are potentially favorable for carnotite-type deposits. The chief of these areas is the Alaska Peninsula-Cook Inlet area which encompasses most of the reported occurrences of the prospectors' carnotite-type samples. Alaska is also potentially favorable for the occurrence of large bodies of the very low-grade uraniferous sedimentary rocks, such as phosphorites and black shales. This type of deposit, however, has not received much study because of the emphasis on the search for bonanza-type high-grade ores. Uraniferous phosphorites similar to those of Idaho, Montana, and Wyoming occur in northern Alaska on the north flank of the Brooks Range; black shales comparable to the uraniferous shales of the Chattanooga formation of southeastern United States have been noted along the Yukon River near the international boundary. Placer deposits in Alaska have some small potential for the production of the radioactive elements as byproducts of gold- and tin-placer mining. the placer area believed to have the relatively greatest potential in Alaska lies in the Kahiltna River valley where concentrates are known to contain such commercial minerals as ilmenite, cassiterite, platinum, and gold in addition to uranothorianite and monazite. The possibilities of the natural fluids--water and petroleum--have not yet been tested in Alaska to any great extent. Studies of fluids are in progress to determine whether they may be used to discover and define areas potentially favorable for the occurrence of uraniferous lodes.

Alaska↗

Selected Geological Survey, U.S. Bureau of Mines, and Alaska Division of Geological and Geophysical Surveys reports and maps on Alaska released during 1976, indexed by quadrangle

This open-file report lists all Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys reports and maps on the geology, geophysics, and mineral and water resources of Alaska published or released to open files in 1976. They are listed by the quadrangles (scale 1:250,000) into which Alaska has been subdivided for topographic mapping (p. 3). As these three agencies also issued reports and maps on other subjects, the following lists are selected in the sense that such documents are not included. Most of the listed reports and maps bear a 1976 imprint date; a few with a 1975 imprint date actually were not delivered until 1976. Also included are a few that I overlooked when I prepared a similar index of reports and maps issued in 1975. Reports that deal with regional tectonic hypotheses, regional syntheses, Alaska as a whole, or with areas that can not be identified with a specific quadrangle are listed under Alaska - General, as are statistical presentations, indexes, and the like. Reports and maps that deal with offshore areas not within quadrangle boundaries are listed under Offshore Areas. The Alaska - General and Offshore Areas lists appear before the alphabetically arranged quadrangle listings. This index is intended to bring up to date the other indexes of this series, which are listed on p. 2.

Alaska↗

Selected Geological Survey, U.S. Bureau of Mines, and Alaska Division of Geological and Geophysical Surveys reports and maps on Alaska released during 1977, indexed by quadrangle

This open-file report lists all Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys reports and maps on the geology, geophysics, and mineral and water resources of Alaska published or released to open files in 1977. They are listed by the quadrangles (scale 1:250,000) into which Alaska has been subdivided for topographic mapping (p. 3). As these three agencies also issued reports and maps on other subjects, the following lists are selected in the sense that such documents are not included. Most of the listed reports and maps bear a 1977 imprint date; a few with earlier imprint dates actually were not delivered until 1977. Reports that deal with regional tectonic hypotheses, regional syntheses, Alaska as a whole, or with areas that can not be identified with a specific quadrangle are listed under Alaska - General, as are statistical presentations, indexes, and the like. Reports and maps that deal with offshore areas not within quadrangle boundaries are listed under Offshore Areas. The Alaska - General and Offshore Areas lists appear before the alphabetically arranged quadrangle listings. This index is intended to bring up to date the other indexes of this series, which are listed on p. 2.

Alaska↗

Selected Geological Survey, U.S. Bureau of Mines, and Alaska Division of Geological and Geophysical surveys reports and maps on Alaska released during 1978, indexed by quadrangle

This open—file report lists all Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys reports and maps on the geology, geophysics, and mineral and water resources of Alaska published or released to open files in 1978. They are listed by the quadrangles (scale 1:250,000) into which Alaska has been subdivided for topographic mapping (p. 4). As these three agencies also issued reports and maps on other subjects, the following lists are selected in the sense that such documents are not included. Most of the listed reports and maps bear a 1978 imprint date; a few with earlier imprint dates actually were not delivered until 1978. Reports that deal with regional tectonic hypotheses, regional syntheses, Alaska as a whole, or with areas that can not be identified with a specific quadrangle are listed under Alaska — General, as are statistical presentations, indexes, and the like. Reports and maps that deal with offshore areas not within quadrangle boundaries are listed under Offshore Areas. The Alaska — General and Offshore Areas lists appear before the alphabetically arranged quadrangle listings.

Alaska↗

Targeting Cu–Au and Mo resources using multi-media exploration geochemistry: An example from Tyonek Quadrangle, Alaska Range, Alaska

Regional stream and pond sediment, panned concentrate, and water sampling at and around known mineral occurrences in the Tyonek quadrangle, Alaska Range, Alaska were undertaken to determine geochemical signatures in the different media. For sediment samples, two different size fractions (− 80 mesh and − 230 mesh) were analyzed. Elevated concentrations (mostly ~ 2 × median) of elements such as As, Au, Cd, Cu, Mo, Pb, and/or Zn were measured in both size fractions in streams draining known occurrences as well as from several other locations. Gold, molybdenite, arsenopyrite, and/or Cu minerals identified in panned concentrates explain some of these elevated values. Water samples from most stream, pond and seep sediment sample sites were analyzed by high-resolution ICP-MS methodology. Relative high concentrations of constituents (including Mo, Re, As, Tl, and/or Cu and/or SO 4 ) were commonly measured in waters where high metal concentrations were also measured in corresponding sediments and/or heavy mineral concentrates. However, water chemistry yielded higher contrast of upper quartile and anomalous groups relative to median values than observed in sediments. Elevated As, Mo and/or Re probably relate both to deposit mineralogy and the higher solubility of these metals (compared to that of Cu, Pb, Zn) under the predominantly oxidized and near-neutral pH conditions. Our pilot study indicates that, despite large input of snowmelt and very low absolute concentrations (μg/L), water chemistry can be useful for delineating sulfide-bearing mineral occurrences in this region.

Alaska↗