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Advancing current understanding of Martian impact-generated hydrothermal systems through novel coupled modeling: Insights from Gale, Jezero, and other craters

Impact-generated hydrothermal systems are considered potentially habitable environments on Mars, Earth, and other planetary bodies for microbial life. However, there is an ongoing debate regarding what geological features on Mars provide definitive evidence for such systems. Although earlier studies have modeled hydrothermal processes in Martian craters, they often lacked integration with shock physics hydrocodes to constrain initial impact conditions. The importance of this two-code coupling was demonstrated by successfully replicating alteration signatures in the Earth's Haughton impact structure. In this study, we use a similar two-code approach, combining the iSALE hydrocode with the HYDROTHERM hydrothermal model to simulate the full evolution of impact-generated hydrothermal systems. We apply this method to craters the size of Jezero (∼50 km) and Gale (∼154 km) in diameter. Although Jezero's interior is largely buried, our results align with hypothesized hydrothermal vents and alteration minerals near central uplifts in similarly sized exposed craters, such as Toro and Auki. Furthermore, our models correspond to alteration patterns observed by the Curiosity in the lower layers of Mount Sharp, which may represent remnants of impact-driven hydrothermal activity. A key finding is that these systems may persist much longer than previously estimated. Our simulations suggest that a Jezero-sized system could remain habitable for thermophiles for approximately 720,000 years, whereas a Gale-sized system could persist for nearly 2 million years. Additionally, simulations under unsaturated crustal conditions reveal that air-dominated near-surface layers can suppress vertical fluid flow, enabling deep subsurface alteration without producing detectable mineral signatures at the surface.

Journal of Geophysical Research - Planets

Using the D-Claw software package to model lahars in the Middle Fork Nooksack River drainage and beyond, Mount Baker, Washington

Lahars, or volcanic mudflows, are the most hazardous eruption-related phenomena that will affect communities living along rivers that originate on Mount Baker. In the past 15,000 years, the largest lahars from Mount Baker have affected the Middle Fork Nooksack River drainage and beyond. Here we use the physics-based D-Claw software package to model nine lahar scenarios that are initiated as water-saturated landslides between Sherman Crater and the Roman Wall on the Mount Baker edifice and flow down the Middle Fork Nooksack River. The scenarios range in volume from 1 to 260 million cubic meters and have an initial hydraulic permeability from 10 −12 to 10 −10 meters squared. Model output includes data such as flow depth, velocity, runout distance, area inundated, arrival time, and sediment concentration as well as information that allows scientists to calculate other important hydrologic characteristics such as lahar discharge. These data are important to officials who have the responsibility to plan for, or take mitigation measures against, future Mount Baker lahars. To check the validity of the D-Claw results, we compare the scenarios to known geologic information. We also compare D-Claw results with empirical models that have been used in the past to determine potential inundation areas, runout distances, and arrival times. These comparisons highlight similarities and differences between empirical and physics-based models. We also present D-Claw scenario-based animations to help scientists, officials, and lay people alike to visualize how future lahars could affect communities.

Washington

ShakeAlert® and schools: Incorporating earthquake early warning in school districts in Alaska, California, Oregon, and Washington

The U.S. Geological Survey-managed ShakeAlert® earthquake early warning system is the first public alerting system in the United States to provide rapid mass notification when an earthquake is detected. Although public alert delivery via mobile phones began in California in 2019 followed by Oregon and Washington in 2021, little is known about what might drive widespread implementation in at-risk institutional settings such as schools. For example, there has been limited research on how to best integrate earthquake early warning into existing emergency plans, alert systems, and drills to keep school children and personnel safe in an earthquake. To address this gap, in the spring of 2022, every school district superintendent in Alaska, California, Oregon, and Washington was sent a 15-min online survey. The survey assessed superintendent knowledge of ShakeAlert, preferences for alert messaging, and perceived opportunities and barriers to incorporating the system in schools. The results showed that superintendents had low awareness of ShakeAlert but held positive perceptions of the system's potential to enable life-saving protective actions. A major barrier to adoption included the perceived financial cost of implementing and maintaining the system. There were some statistically significant differences in state responses, and future research could investigate the specific needs of each state based on school district size and composition, hazard exposure, and earthquake experience. Together these findings can help inform targeted strategies to increase ShakeAlert adoption in schools and ultimately improve the safety of school children and staff during earthquakes.

Alaska, California, Oregon, Washington

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah

Groundwater budget for the Mountain Home area, southern Idaho, 2022–23

The U.S. Geological Survey, with funding from the Idaho Department of Water Resources, developed a groundwater budget for the Mountain Home area in southern Idaho for irrigation year 2023 (November 1, 2022–October 31, 2023). This study focused on the water balance across the Cinder Cone Butte Critical Groundwater Area (CGWA), Mountain Home Groundwater Management Area (GWMA), and the rest of the study area (RoSA), compiling data from various sources, including precipitation records, groundwater level measurements, metered groundwater pumpage data, surface water diversions and evapotranspiration (ET) estimates derived from remote sensing satellite imagery, and ground-based reference data. Key inflow components included recharge from applied surface water irrigation (which incorporates incidental recharge from irrigation practices and conveyance losses), estimated tributary streamflow, and estimated mountain block recharge. The key outflow components were groundwater pumpage for irrigation, municipal, industrial, and domestic uses, and ET. Recharge from applied irrigation and mountain block recharge were the largest inflows, and groundwater pumpage for irrigation was the largest outflow. The CGWA had a positive groundwater budget residual of 2,170 acre-feet (acre-ft), which contrasts with observed long-term groundwater level declines and historical trends of storage depletion. This positive residual is likely associated with unquantified outflows, including lateral groundwater flow out of the subregion, or other complexities, such as overestimated tributary contributions relative to the actual recharge for the 2023 water budget. The GWMA exhibited a positive residual of 56,563 acre-ft, primarily owing to recharge from applied surface water irrigation and areal recharge during a wetter-than-average year, which allowed irrigation entities to deliver more water from in-basin and out-of-basin reservoirs. The RoSA showed a large positive residual of 124,933 acre-ft. The interpretation of these positive residuals must account for significant uncertainties, including estimations of areal recharge, tributary streamflow (particularly losses and diversions), ET, the volume of surface water loss to the Snake River, lateral groundwater flows between subregions and across study area boundaries, and the unquantified groundwater discharge to the Snake River. These uncertainties, in combination with the complex hydrogeologic controls on water movement and limitations of remotely sensed data, directly affect the accuracy of water availability assessments. Future data collection efforts would help reduce these uncertainties and support water resource management decisions in the Mountain Home area. Key efforts could include installing additional streamflow gaging stations (particularly to quantify tributary losses and gains and surface water losses to the Snake River), improving groundwater pumpage metering, and validating remotely sensed ET data with ground-based measurements. Furthermore, to better quantify unrepresented or highly uncertain fluxes, focused investigations on groundwater discharge to the Snake River, lateral groundwater flows between subregions and across study area boundaries, and a more robust determination of the actual influence and volume of mountain block recharge would help refine future water availability assessments for the Mountain Home area.

Idaho

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

“Leaky weirs” capture alluvial deposition and enhance seasonal mountain-front recharge in dryland streams

“Leaky weirs” are rock structures installed in dryland streams, which are anchored into exposed bedrock, loosely cemented, and designed to allow water to slowly pass through. They are being tested at a ranch in southeastern Arizona, USA, to restore and conserve the historic range and desert wetlands. Data are collected to assess how leaky weirs impact surface water, subsurface water, and groundwater recharge—including stream discharge, timing, and depth of infiltration, and groundwater elevations. Three adjacent watersheds, two with outlets just below leaky weirs and one with leaky weirs farther upstream, were instrumented with water-level loggers, wildlife cameras, and crest stage instruments with temperature sensors in the soil. As most groundwater recharge is assumed to be focused along the mountain fronts in this region, mountain-block recharge is also evaluated to differentiate between the two using isotope analyses. Finally, a single, late-season flood event is scrutinized to consider the leaky weir effect on all monitored components in the water budget. Results indicated groundwater flow is primarily from the mountains to the east via older, regional mountain-block recharge. However, the development of shallow alluvial aquifers is supported by the leaky weirs, that slow flows, capture permeable sediments, and allow infiltration, thus enhancing mountain-front recharge. In turn, these new pockets of water help support the restoration of historic wetlands. Sediment accumulates where leaky weirs are installed, reducing flashy peak flows, and resulting in a series of infiltration ponds along the channel that support vegetation during growing seasons and recharge the shallow aquifer during non-growing seasons.

Arizona

Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems

World-class Carlin-type Au deposits hosted in sedimentary rock were formed when profuse Eocene silicic magmatism swept across northern Nevada in response to arc migration. Carlin-type Au deposits formed along with porphyry/skarn Cu-Mo-W-Au deposits, epithermal Ag-Au deposits, and distal disseminated Ag-Au deposits. But unlike these other Au-bearing deposits that have clear associations with igneous intrusions, Carlin-type ore deposits appear to have formed distant from concealed plutons, and their origin remains controversial. Despite decades of abundant geophysical, geochronological, and geochemical studies suggesting the involvement of magmas, concrete evidence for magmatic involvement is still lacking. Consequently, the involvement of contemporaneous igneous systems remains inferred based on age, proximity, and variable isotopic, geochemical, and geophysical clues. A recent synthesis of deposit models postulates that Carlin-type Au deposits are intrusion-related, but that the causative magmas reside deeper (∼6–12 km) than in typical porphyry and peripheral systems (∼3–5 km), meaning that Carlin-type deposits are perhaps more distal expressions of igneous intrusions. We investigate a collection of “suspect” magmatic systems over a ∼7 m.y. timespan (∼41–34 Ma) that are contemporaneous with and near known Carlin-type ore deposits. We report results of a multifaceted array of in situ geochemical analyses (FTIR, EMP, SHRIMP-RG, LA-ICP-MS) of quartz-hosted melt inclusions, biotite, and quartz to better characterize the pre-eruptive characteristics of these magmas. We also report results of thermobarometry and thermodynamic phase equilibria modeling to help place constraints on magmatic reservoir depths and processes. Rather than a single “flavor” of silicic magma, we observe a surprisingly broad compositional spectrum of rhyolites, with one end of the spectrum exhibiting more arc-like (I-type) characteristics and the other end displaying more post-subduction, thick-crust extensional (A-type) characteristics. This broad compositional spectrum suggests a more complex picture of silicic crustal magmatism operating over a narrow span of time during slab rollback. Despite this spectrum, magmatic systems in this study are consistently ferroan and generally peraluminous, which we interpret as an expression of the relatively elevated geotherm at the time and incorporation of variable amounts of highly peraluminous metasedimentary crustal components. The silicic magma spectrum encompasses a range of mineralization associations, including subduction-related Cu-Mo-W-Au-Ag and post-subduction, thick-crust extensional rare-metal Mo-Sn-W-F-Be-Ag-Au, consistent with the prolific and diverse array of ore deposits that formed during this time. Carlin-type Au deposition appears to be associated with nearly the entire magmatic spectrum. This apparent indifference to silicic magma “flavor” would seem to imply that if magmas are involved in Carlin-type Au deposit genesis, they perhaps do not need to be compositionally specialized and/or possibly are only relevant as heat sources driving circulation to remobilize and redistribute metals.

Nevada

Lessons in business recovery following the 2023 Kahramanmaraş earthquake sequence, Türkiye informed by women entrepreneurs

On 6 February 2023, Southern Türkiye was hit by devastating earthquakes, directly affecting over 14 million people in 11 cities, causing more than 50,000 deaths and the destruction of more than 800,000 buildings. This article goes beyond the physical damage imposed by the catastrophe to discuss the effects of the earthquakes on the operations of women-owned businesses. The mixed-method study with entrepreneurs belonging to a women’s business association operating in a moderately disrupted part of the region explores their struggles and recovery expectations. Thirty-five questionnaires were analyzed to identify the reasons for business closure, challenges, and needs faced in the post-disaster period and their recovery strategies. In addition, 23 entrepreneurs participated in roundtable discussions to provide a broader context to their responses to survey topics as well as lessons learned. Across both the survey and roundtables, while many respondents reported minor physical damage to their building, they also experienced financial and personal challenges from disruption to equipment, infrastructure, services, supply chains, institutional decisions, employee well-being, and customer base. Many used their business resources and personal savings to assist employees and others in the community. The women entrepreneurs often felt their recovery needs were ignored by government and private relief organizations and encountered barriers to receiving assistance from public and private institutions. Organizing together as women in business, even informally, provided mutual support during the crisis and recovery periods and catalyzed their role in support of their communities. The results illuminate functional community recovery as a balance of recovery of built infrastructure functionality and recovery of the broader social and economic fabric of the community.

southern Turkey

Hydraulic conductivity and transmissivity estimates from slug tests in wells within the Mississippi Alluvial Plain, Arkansas and Mississippi, 2020

During the spring and summer of 2020, the U.S. Geological Survey conducted single-well slug tests on selected observation wells within the Mississippi Alluvial Plain in Arkansas and Mississippi to estimate hydraulic conductivity and transmissivity values for the Mississippi River Valley alluvial and middle Claiborne aquifers. Well and aquifer data were collected from field measurements, well-construction reports, and published aquifer-thickness information. A total of 324 slug-in and slug-out tests were conducted on 48 wells by using mechanical slugs to displace the water column and submersible pressure transducers to record changes in water levels in the wells. Hydraulic conductivity of the aquifers in which the wells are screened was estimated by curve fitting the water-level-change data using aquifer test analysis software. Estimates of aquifer transmissivity were made by multiplying the estimated hydraulic conductivity value by the aquifer thickness at well locations. Mean hydraulic conductivity estimates for 44 observation wells screened in the Mississippi River Valley alluvial aquifer range from 3 to 401 feet per day, and mean transmissivity estimates range from 285 to 80,559 feet squared per day. Mean hydraulic conductivity estimates for four observation wells screened in units of the middle Claiborne aquifer range from 0.14 to 183 feet per day, and mean transmissivity estimates range from 55 to 67,913 feet squared per day. The results from these tests can be used to improve the understanding of water availability and groundwater migration, to refine groundwater models, and to ultimately provide stakeholders and decisionmakers better information for management of the groundwater resources within the Mississippi Alluvial Plain.

Arkansas, Mississippi

Exploring the uncertainty of machine learning models and geostatistical mapping of rare earth element potential in Indiana coals, USA

Rare earth elements and yttrium (REEs) have a wide range of applications in high- and low-carbon technologies. The strategic significance of REEs has grown due to their expanding applications in manufacturing industries and the constrained availability of these essential resources. This research explores the applicability of machine learning models and their uncertainty for assessing the REE potential in coal beds using various coal parameters as inputs. The work focuses on developing a predictive model based on geological variables, excluding considerations related to potential shifts in the commodities market. The Indiana Coal Quality Database was used as the data source. The promising and unpromising indicators derived from the outlook coefficient of samples from the database were used as the REE potential indicator for machine learning classification models. The filter-based approach with bootstrap was used to evaluate the importance of the coal parameters and their prediction uncertainties. Four machine learning methods (linear discriminant analysis (LDA), random forest (RF), support vector machine (SVM), and artificial neural networks (ANN), a data balancing and augmentation approach (Synthetic Minority Over-sampling Technique), and bootstrap resampling techniques were used for building the models and evaluating their prediction capabilities under uncertainty. It was determined that the SVM bootstrap model with ten-times balanced and augmented data provided superior results compared with other models. Finally, stochastic spatial maps of the REE potential within the coal basin were generated using sequential indicator simulation. The spatial maps of the REE potential showed that a 29% area of the Indiana section of the Illinois coal basin has economic potential of REEs, with 90% confidence.

Indiana

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California

Surface variable‐based machine learning for scalable arsenic prediction in undersampled areas

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed geologic logs, which limits their use in undersampled areas where improved guidance is most needed. We overcome these limitations by developing a machine learning model for Minnesota, USA, that predicts As exposure risk using only surficial variables from remote sensing and global data sets. Variables related to surface water hydrology and geomorphology are selected based on mechanistic links that control redox conditions and As mobilization. Local training was essential, and surficial geology variables that are more sensitive to local conditions were needed to maximize model accuracy. The resulting complete model was sufficiently sensitive to generate accurate and detailed risk maps and depth profiles of As concentrations above the 10 μg/L maximum contaminant level. Accuracy depended on local training data density. We identified a training data density of 0.07 wells/km 2 as a practical target for stable county-level performance. Maps of exceedance probabilities highlight priority areas for testing that are particularly important in rural communities that have received less sampling. These results support public health action by guiding where to install wells and where to test them, how much new sampling is needed, and where treatment outreach is most urgent.

Minnesota

Concentration-discharge relations and transient metal loads reveal spatiotemporal variability in solute-generation mechanisms in a mine-affected watershed

Concentration-discharge (CQ) relations are commonly used to understand geochemical and hydrologic controls on the generation of solutes in watersheds. Despite the widespread application of CQ relations, this technique has been infrequently applied to acid mine drainage (AMD) sites, but the CQ framework may allow mechanistic understanding of remedial outcomes such as impoundment of water within underground mines. Results of CQ analyses and changes in metal loads in an AMD affected watershed in Colorado, USA indicate that dissolved loads increased at many individual locations following water impoundment within mine workings. Although increased loads were observed at most individual locations, these increases were offset by a large decrease in loading from the largest mine. A loading analysis that included data from an instream monitoring location showed a statistically significant decrease in Fe and Zn after bulkhead emplacement, indicating a net positive effect of bulkheads. Streams generally displayed dilution CQ patterns whereas mines and springs showed either flushing or chemostatic patterns prior to bulkheading, which transitioned to chemostatic patterns following bulkheading, indicating a transition from dynamic to equilibrium geochemical processes. Saturation indices for sulfide and secondary minerals indicated that mines and springs were near equilibrium for phases including schwertmannite, fluorite, and gypsum. Saturation indices vary through time for mines suggesting progressive leaching of sulfide minerals as the mass of available minerals in the mine workings decreases. Together, these diverse analyses provide an integrated understanding of the variability in solute generating processes in this watershed and may inform remediation plans for similarly affected sites by indicating the nature of mineralogic controls on water quality.

Colorado

Integrity of production wells and confining unit at the Naval Weapons Industrial Reserve Plant, Dallas, Texas, 1995

Ground water in the shallow alluvial aquifer is contaminated at the Naval Weapons Industrial Reserve Plant, Dallas, Texas. Five production wells at the site are cased through the alluvial aquifer and underlying units and are screened in either the Paluxy or Twin Mountains aquifers. Three abandoned wells, originally completed in the Twin Mountains aquifer but filled with drilling mud in 1958, also penetrate the alluvial aquifer. The Paluxy and Twin Mountains aquifers are used for drinking-water supplies in and around the Dallas-Fort Worth metroplex. Trichloroethylene and its degradation products, dichloroethylene and vinyl chloride, and the metal chromium previously have been detected in the shallow alluvial aquifer. Current (1995) analyses of water-quality samples taken from the static water column of the five production wells and one of the abandoned wells indicate no trichloroethylene, dichloroethylene, or vinyl chloride in the water column of these wells. Chromium was detected in all samples, but concentrations were less than the practical quantitation limit, which is the regulatory action level for this site. The results of borehole geophysical log analysis indicate that two of the production wells could have vertically connected intervals where cement bonding in the well annulus is poor. The other production wells have overall good bonding. Temperature logs do not indicate flow behind casing except in the screened interval of one well. Geophysical logs show the Eagle Ford Shale ranges from 147 to 185 feet thick at the site. The Eagle Ford Shale has low permeability and a high plasticity index. These physical characteristics make the Eagle Ford Shale an excellent confining unit.

Texas

Determining Volcanic Risk in Auckland (DEVORA) Research Programme—A transdisciplinary approach to address the challenge of distributed volcanism in an urban environment

The Determining Volcanic Risk in Auckland (DEVORA) Research Programme was launched in 2008 to address the challenges associated with monogenetic volcanism in an urban setting and to enhance volcanic risk management in Tāmaki Makaurau Auckland in Aotearoa New Zealand. It is a multi-agency, increasingly transdisciplinary (defined here as research that transcends traditional disciplinary boundaries by integrating diverse types of knowledge, perspectives, and methods from academic and non-academic participants to create novel solutions to complex problems), and collaborative research program jointly led by Waipapa Taumata Rau University of Auckland and Earth Sciences New Zealand (ESNZ; formerly GNS Science), with core funding from Natural Hazards Commission Toka Tū Ake (NHC; formerly the Earthquake Commission, EQC) and Te Kaunihera o Tāmaki Makaurau Auckland Council (AC). The primary research focus of DEVORA is to investigate the geologic history, volcanic hazards, and risk posed by the basaltic intraplate Auckland Volcanic Field. Disruption from ash fall and gas from other Aotearoa New Zealand volcanoes is also considered. DEVORA’s work to explore exposure and vulnerability in Tāmaki Makaurau Auckland is also useful for assessing risks from other non-volcanic natural hazards, such as seismic and tsunami hazards. The greater Tāmaki Makaurau Auckland region has an ethnically and socio-economically diverse population of approximately 1.7 million, representing about one-third of the Aotearoa New Zealand population, and hosts critical infrastructure of national significance. The size and nature of the populace, consequential economic base, and important infrastructure within Tāmaki Makaurau Auckland mean that the effects of a volcanic eruption would be felt nationally, including through the disruption of air travel to Aotearoa New Zealand. The hazards from such an eruption could potentially affect hundreds of thousands of people, businesses, and lifelines (critical infrastructure). A considerable challenge for emergency and risk managers is the monogenetic nature of the volcanic field. It is not known where or when the next eruption will occur, how much warning we may get before an eruption, nor how an eruption and its effects might unfold. In this contribution, we highlight the concept and collaborative intent of the DEVORA Programme and show how it has evolved over the 16 years since its inception. We describe how DEVORA has unified more than 100 researchers (including more than 50 graduate students) and numerous stakeholders to address key issues facing Tāmaki Makaurau Auckland and describe how research findings are being implemented into policy and communicated to stakeholder agencies and the public. We also illustrate the broader influence of the DEVORA Programme and provide some learnings that might benefit others embarking on similar integrated projects, especially those focused on distributed volcanism in and near populated areas.

Auckland