USGS ScienceSearch

SEARCH · USGS Science

Results for “Near Surface Geophysics”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

735 records · Page 38Linked to original sources

Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment

Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.

ACS ES&T Water

Intense alteration on early Mars revealed by high-aluminum rocks at Jezero Crater

The NASA Perseverance rover discovered light-toned float rocks scattered across the surface of Jezero crater that are particularly rich in alumina ( ~ 35 wt% Al 2 O 3 ) and depleted in other major elements (except silica). These unique float rocks have heterogeneous mineralogy ranging from kaolinite/halloysite-bearing in hydrated samples, to spinel-bearing in dehydrated samples also containing a dehydrated Al-rich phase. Here we describe SuperCam and Mastcam-Z observations of the float rocks, including the first in situ identification of kaolinite or halloysite on another planet, and dehydrated phases including spinel and apparent partially dehydroxylated kaolinite. The presence of spinel in these samples is likely detrital in origin, surviving kaolinitization, pointing to an ultramafic origin. However, the association of low hydration with increased Al 2 O 3 abundances suggests heating-induced dehydration which could have occurred during the lithification or impact excavation of these rocks. Given the orbital context of kaolinite-bearing megabreccia in the Jezero crater rim, we propose an origin for these rocks involving intense aqueous alteration of the parent material, followed by dehydration/lithification potentially through impact processes, and dispersion into Jezero crater through flood or impact-related processes.

Communications Earth & Environment

A roadmap for identifying and interpreting physical processes and national water model prediction bias associated with baseflow index regimes across the contiguous United States

Understanding how groundwater–surface water interactions shape streamflow variability is critical for diagnosing low flow behavior and prediction bias in continental scale hydrologic models. We present a process informed framework that links observed baseflow (BF) dynamics, watershed attributes, and National Water Model (NWM) performance across the contiguous United States. Using daily observed streamflow from 797 reference quality streamgages, we developed monthly baseflow index (BFI) signatures using a streamgage specific, calibrated digital filter. Hierarchical clustering of these signatures identified seven distinct BFI regimes capturing regional and seasonal variability. We evaluated NWM v3.0 retrospective streamflow performance within each regime using multiple hydrograph and flow duration curve-based metrics. Model skill varied systematically across regimes: mixed flow systems were simulated most accurately, while predominantly BF dominated and quickflow dominated regimes exhibited substantially poorer performance. Across nearly all regimes, the NWM underestimated observed BFI magnitude and frequently failed to reproduce seasonal BF patterns, indicating systematic biases in simulated low flow contributions. To relate these regimes to potential process controls, we trained a Random Forest classifier using static watershed attributes and applied Shapley Additive Explanations to identify features most strongly associated with each regime. Results highlight regionally varying influences, including the dominant role of snow fraction and seasonal runoff timing in snow dominated basins and the importance of evapotranspiration and aridity in quickflow dominated systems. Collectively, these findings demonstrate how hydrologic signatures combined with interpretable machine learning can diagnose regime specific model biases and generate process-based hypotheses about limitations in large scale hydrologic prediction systems.

contiguous United States

A framework for understanding the effects of subsurface agricultural drainage on downstream flows

Understanding controls on streamflow volume and magnitude is important to water resource management applications, such as critical water and transportation structure design and floodplain mapping. Changes in land use and agricultural practices, such as subsurface agricultural drainage, may be contributing to changes in streamflow characteristics. Subsurface agricultural drainage, also known as tile drainage, is the practice of installing drains in the subsurface of agricultural fields to improve productivity. Because of the complex interactions between subsurface drainage systems, precipitation, local soil conditions, and land management practices, it is difficult to determine how subsurface agricultural drainage affects downstream flow. Previously developed subsurface agricultural drainage conceptual models under dry, saturated, and winter conditions are summarized, and current literature on the effects of subsurface agricultural drainage on downstream flows, focusing on peak flow, non-event flow, and total flow to develop frameworks for discussing these systems is compiled. The effects that subsurface drainage has on hydrologic systems are expected to vary by site and are seasonally based on system design, soil type, moisture conditions, precipitation characteristics, and land conditions. Subsurface drainage can affect the magnitude of peak flow by converting surface runoff from a storm event to subsurface runoff. By increasing hydrologic connectivity of a catchment, subsurface drainage can increase non-event flow or the flow between two storm events, typically dependent on lateral flow through the subsurface and groundwater. Theoretically, by diverting water from groundwater recharge or by reducing water available for evapotranspiration, subsurface drainage may increase the total volume of flow. Precipitation changes may increase infiltration, excess overland flow, and flood risk regardless of the presence or absence of subsurface drainage.

Illinois, Iowa, Michigan, Minnesota, Missouri, Mon

Remote sensing evapotranspiration in ensemble-based framework to enhance cascade routing and re-infiltration concept in integrated hydrological model applied to support decision making

Integrated hydrological models (IHMs) help characterize the complexity of surface–groundwater interactions. The cascade routing and re-infiltration (CRR) concept, recently applied to a MODFLOW 6 IHM, improved conceptualization and simulation of overland flow processes. The CRR controls the transfer of rejected infiltration and groundwater exfiltration from upslope areas to adjacent downslope areas where that water can be evaporated, re-infiltrated back to subsurface, or discharged to streams as direct runoff. The partitioning between these three components is controlled by uncertain parameters that must be estimated. Thus, by quantifying and reducing those uncertainties, next to uncertainties of the other model parameters (e.g. hydraulic and storage parameters), the reliability of the CRR is improved and the IHM is better suited for decision support modelling, the two key objectives of this work. To this end, the remotely sensed MODIS-ET product was incorporated into the calibration process for complementing traditional hydraulic head and streamflow observations. A total of approximately 150,000 observations guided the calibration of a 13-year MODFLOW 6 IHM simulation of the Sardon catchment (Spain) with daily stress periods. The model input uncertainty was represented by grid-cell-scale parameterization, yielding approximately 500,000 unknown input parameters to be conditioned. The calibration was carried out through an iterative ensemble smoother. Incorporating the MODIS-ET data improved the CRR implementation, and reduced uncertainties associated with other model parameters. Additionally, it significantly reduced the uncertainty associated with net recharge, a critical flux for water management that cannot be directly measured and rather is commonly estimated by IHM simulations.

Sardon catchment

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

High frequency and region-scale simulations of large (Mw7+) earthquakes on the southern Whidbey Island fault, Washington, USA

We simulate ground shaking in western Washington State from hypothetical M w 7.0–7.5 earthquakes on the southern Whidbey Island fault (SWIF). Ground motions are modeled considering kinematic source distributions on a complex fault plane, a 3D seismic velocity model, and region‐specific soil velocity models. We run simulations with varying model resolutions, including regional‐scale simulations with a maximum‐modeled frequency of ∼1 Hz and local‐scale simulations with a maximum‐modeled frequency of ∼2.5 Hz. Additional local‐scale simulations are run considering high‐resolution surface topography. We explore how source parameters (i.e., magnitude, hypocenter location, and dip direction) and 3D velocity structure impact peak shaking intensity and its variability. In particular, we find that earthquakes on the SWIF would likely produce strong shaking throughout the populated Puget Lowland, including in the cities of Everett, Seattle, Bellevue, and Tacoma, Washington. Simulated short‐period ( T ≤ 2 s) spectral accelerations are strong throughout the Puget Lowland, and long‐period shaking ( T ≥ 5 s) is strong in the deep regional sedimentary basins, especially the Everett and Seattle basins. Source parameters strongly influence intra‐ and interevent variability in response, primarily through changes in source and site geometry, as well as rupture directivity. We also note a potential coupling between rupture directivity and basin effects, wherein directivity pulses are seemingly guided through the region’s deep, interconnected sedimentary basins. Overall, this work highlights the impacts of 3D source, path, and site effects on seismic hazard in the U.S. Pacific Northwest and substantially expands the catalog of simulated ground motions for Puget Sound area crustal faults.

Washington

Wavelet Inversion for SliP (WISP): Open-source earthquake slip modeling software

Models of the spatiotemporal evolution of earthquake slip, termed finite-fault models, are a critical component of rapid earthquake and tsunami response, earthquake forecasting, seismic ground-motion estimates, and studies of earthquake kinematics. Here, we detail a newly released finite-fault modeling software, Wavelet Inversion for SliP (WISP), in use at the U.S. Geological Survey’s National Earthquake Information Center (NEIC) and available to the public. WISP version 1.1.0 allows inversion of teleseismic body and surface waves, as well as local strong-motion, static and dynamic Global Navigation Satellite System, and satellite imagery (e.g., Interferometric Synthetic Aperture Radar) observations on single or multiple planar fault segments. The software is used in NEIC rapid response of earthquakes M w ≥ 7, generally resulting in a published model within the first few hours after the event origin time. The rupture location and dimensions are then used as inputs to downstream products to estimate earthquake shaking, predict loss, and model the likelihood of secondary hazards, namely landslides and liquefaction. WISP is also used in research studies to evaluate the characteristics of complex ruptures including multifault ruptures and earthquake doublets, among others. The WISP version 1.1.0 software release is composed of Python-wrapped FORTRAN code to accomplish the inversion procedure. A simple command line interface facilitates ease of use even for those with only a cursory knowledge of Python scripting. WISP version 1.1.0 includes a Jupyter Notebook tutorial demonstrating use of the software for modeling the 2015 M w 8.3 Illapel, Chile, earthquake. In parallel with the tutorial, we demonstrate the typical usage of the WISP software using the M w 8.3 Illapel earthquake example here.

Seismological Research Letters

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Land-based nutrient flux to a fringing reef: Insights from Ofu Island, American Samoa

Submarine groundwater discharge (SGD) is a critical driver of nutrient transport in coral reef ecosystems, shaping water quality, primary productivity, and overall reef health. This study quantifies SGD fluxes and associated nutrient dynamics in two reef flat pools within the Ofu Unit of the National Park of American Samoa: Papaloloa and Fatuana. A multi-method approach integrating unoccupied aerial system-based thermal infrared (UAS-TIR) surveys, radon-based SGD measurements, multichannel electrical resistivity tomography (ERT), and discrete water sampling was used to assess SGD rates and nutrient contributions. UAS-TIR imagery revealed cooler sea surface temperatures in both pools, indicative of SGD, with the higher fluxes observed in Papaloloa. Radon measurements revealed a strong inverse correlation between SGD rates and tidal stage, with a more immediate SGD response at Papaloloa due to its highly permeable calcareous sand and gravel substrate. In contrast, a 2–3-hour lag in SGD response at Fatuana suggests discharge from a more inland aquifer that has lower diffusivity. Nutrient concentrations correlated with temperature and salinity, confirming SGD as the dominant nutrient transport mechanism, whereas isotopic analyses indicated inputs from both groundwater and potential anthropogenic sources. Despite lower SGD flux at Fatuana, higher algal cover suggests additional factors influencing algal proliferation, including substrate availability and hydrodynamic conditions. Excess nutrient inputs from SGD may contribute to algal overgrowth, which threatens Ofu’s thermally tolerant corals by increasing competition for space and light. These findings underscore the complexity of SGD-mediated nutrient dynamics in reef environments and emphasize the need for integrated hydrological and ecological assessments to support effective reef conservation and management strategies.

American Samoa, Ofu Island, Olosega Island

Characterization of selected biological, chemical, and physical conditions at fixed sites in the Upper Colorado River Basin, Colorado, 1995-98

Biological community samples were collected at 15 sites in the Upper Colorado River Basin (UCOL) in Colorado as part of the National Water-Quality Assessment (NAWQA) Program. Sites sampled in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, represented agriculture, mining, urban and recreation, and mixed land uses and background conditions. Nine measures of water quality, which include information on nutrients, specific conductance (a surrogate for salinity), trace elements in streambed sediment, pesticides in fish tissue, fish communities, and macroinvertebrate richness and composition and stream habitat were used for comparisons among sites within the two physiographic provinces. Sampling sites from three other NAWQA study units—the Rio Grande Valley, the South Platte River Basin, and the Upper Snake River Basin study units—were categorized on the basis of land use and stream size in order to develop a larger data set for comparison to sites in the UCOL. Three categories of land use—forested (includes mining, urban and recreation, and background), agriculture, and mixed—were used for comparison to the UCOL fixed sites. Results indicated that all sites other than the Colorado River below Baker Gulch (a background site) showed some water-quality characteristics to be significantly affected. Results indicated that the concentrations of cadmium and zinc in streambed sediment at mining land-use sites in the Southern Rocky Mountains physiographic province generally were orders of magnitude higher than streambed-sediment concentrations at the background site. Streambed-sediment concentrations at mining land-use sites in the UCOL were greater than the 75 th percentile of concentrations from sites in the three other NAWQA study units. Fish communities and habitat conditions were degraded at mining land-use sites compared to the background site. Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and the percentage of EPT were lower at mining land-use sites than at the background site and were less than the 50 th percentile of those for sites from the three other NAWQA study units. Nutrient concentrations at urban and recreation sites in the Southern Rocky Mountain physiographic province generally were greater than concentrations at the background site and generally were between the 25 th and 90 th percentile of concentrations for sites from the three other NAWQA study units. Habitat conditions and fish communities at urban and recreation sites were slightly degraded compared to the background site. EPT richness and the percentage of EPT were lower at urban and recreation sites than at the background site and were between the 25 th and 75 th percentile of those for sites from the three other NAWQA study units. The percentage of Chironomidae, which may be indicative of pollutant-tolerant organisms, was higher at urban and recreation sites than at the background site. Mixed land-use sites in the Southern Rocky Mountains physiographic province had similar nutrient concentrations and similar cadmium and zinc streambed-sediment concentrations. Fish-community degradation index values were very different among the three mixed land-use sites in the Southern Rocky Mountains physiographic province. Larger percentages of omnivores and anomalies such as lesions and deformities at two mixed land-use sites resulted in higher degradation values of the fish community. Agriculture land-use sites had higher concentrations of nutrients and selenium than the background site in the Colorado Plateau physiographic province. Concentrations of p,p '-DDE in fish tissue at agriculture sites were higher than the 75 th percentile of concentrations for sites from the three other NAWQA study units. Fish communities had degradation values near the 75 th percentile for agriculture sites. The percentage of EPT was low at agriculture sites when compared to the background site. Two mixed land-use sites in the Colorado Plateau physiographic province had similar concentrations of nutrients, selenium, and p,p '-DDE, and similar EPT richness and composition. These two sites were located downstream from agricultural and urban activities. Some water-quality measures at these two sites indicated degradation compared to a mixed land-use site upstream from most of the agriculture and urban activities in the Colorado Plateau physiographic province.

Colorado

Field-trip guide to Mount Hood, Oregon, highlighting eruptive history and hazards

This guidebook describes stops of interest for a geological field trip around Mount Hood volcano. It was developed for the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon. The intent of this guidebook and accompanying contributions is to provide an overview of Mount Hood, including its chief geologic processes, magmatic system, eruptive history, local tectonics, and hazards, by visiting a variety of readily accessible localities. We also describe coeval, largely monogenetic, volcanoes in the region. Accompanying the field-trip guidebook are separately authored contributions that discuss in detail the Mount Hood magmatic system and its products and behavior (Kent and Koleszar, this volume); Mount Hood earthquakes and their relation to regional tectonics and the volcanic system (Thelen and Moran, this volume); and young surface faults cutting the broader Mount Hood area whose extent has come to light after acquisition of regional light detection and ranging coverage (Madin and others, this volume). The trip makes an approximately 175-mile (280-kilometer) clockwise loop around Mount Hood, starting and ending in Portland. The route heads east on Interstate 84 through the Columbia River Gorge National Scenic Area. The guidebook points out only a few conspicuous features of note in the gorge, but many other guides to the gorge are available. The route continues south on the Mount Hood National Scenic Byway on Oregon Route 35 following Hood River, and returns to Portland on U.S. Highway 26 following Sandy River. The route traverses rocks as old as the early Miocene Eagle Creek Formation and overlying Columbia River Basalt Group of middle Miocene age, but chiefly lava flows and clastic products of arc volcanism of late Miocene to Holocene age.

Oregon

Satellite time series analysis to quantify changing climax ciénegas using a state and transition model approach

Ciénegas are rare wetlands in arid landscapes of the North American Southwest, historically providing critical ecological and hydrological functions but increasingly threatened by changing climate and land use pressures. This study quantifies changes in ciénega condition and floodplain dynamics using a state-and-transition model (STM) informed by expert knowledge and remote sensing. Key factors include woody plant encroachment, water availability, and soil aggradation. We mapped 31 ciénegas with high-resolution imagery and analyzed Landsat data (1985–2023) to assess vegetation health and moisture using the Normalized Difference Vegetation Index (NDVI) and Normalized Difference Infrared Index (NDII). Results show substantial interannual variability in phenology, water stress, and soil moisture, with regional drying and elevation strongly influencing ciénega resilience. We classified ciénegas into three functional states—healthy, desiccated, and dormant—and mapped their 2023 condition. Trend analyses indicate most ciénegas exhibit greening despite drought, though localized variability underscores the need for site-specific management. None are in a stable climax (reference) state; rather, they transition among states in response to external drivers. Increasing woody plant cover and surface drying, likely linked to declining regional water tables, favor deep-rooted species over wetland grasses—a pattern mirrored in adjacent control plots. Spatially explicit analysis revealed intra-ciénega variability often masked by aggregated data, highlighting the importance of high-resolution monitoring. Seasonal and long-term trends provide context for understanding ciénega dynamics, including degradation and restoration pathways. This study emphasizes the importance of groundwater conservation and demonstrates how remote sensing supports long-term monitoring. The STM framework offers a practical tool for adaptive management to sustain freshwater resources in arid environments.

Arizona, New Mexico

Bioconcentration of per- and polyfluoroalkyl substances and precursors in fathead minnow tissues environmentally exposed to aqueous film-forming foam-contaminated waters

Exposure to per- and polyfluoroalkyl substances (PFAS) has been associated with toxicity in wildlife and negative health effects in humans. Decades of fire training activity at Joint Base Cape Cod (MA, USA) incorporated the use of aqueous film-forming foam (AFFF), which resulted in long-term PFAS contamination of sediments, groundwater, and hydrologically connected surface waters. To explore the bioconcentration potential of PFAS in complex environmental mixtures, a mobile laboratory was established to evaluate the bioconcentration of PFAS from AFFF-impacted groundwater by flow-through design. Fathead minnows ( n = 24) were exposed to PFAS in groundwater over a 21-day period and tissue-specific PFAS burdens in liver, kidney, and gonad were derived at three different time points. The ∑PFAS concentrations in groundwater increased from approximately 10,000 ng/L at day 1 to 36,000 ng/L at day 21. The relative abundance of PFAS in liver, kidney, and gonad shifted temporally from majority perfluoroalkyl sulfonamides (FASAs) to perfluoroalkyl sulfonates (PFSAs). By day 21, mean ∑PFAS concentrations in tissues displayed a predominance in the order of liver > kidney > gonad. Generally, bioconcentration factors (BCFs) for FASAs, perfluoroalkyl carboxylates (PFCAs), and fluorotelomer sulfonates (FTS) increased with degree of fluorinated carbon chain length, but this was not evident for PFSAs. Perfluorooctane sulfonamide (FOSA) displayed the highest mean BCF (8700 L/kg) in day 21 kidney. Suspect screening results revealed the presence of several perfluoroalkyl sulfinate and FASA compounds present in groundwater and in liver for which pseudo-bioconcentration factors are also reported. The bioconcentration observed for precursor compounds and PFSA derivatives detected suggests alternative pathways for terminal PFAS exposure in aquatic wildlife and humans.

Environmental Toxicology and Chemistry

Wet meadow regeneration through restoration of biophysical feedbacks

Wet meadows are globally significant ecosystems that provide critical hydrological, ecological, and biogeochemical functions, yet their extent has declined dramatically due to land use changes and hydrologic alteration. These sedge-dominated wetlands exist at the drier end of the wetland gradient, maintained by shallow groundwater and periodic inundation. This paper is a global synthesis of the ecological, geomorphic, and hydrological dynamics of wet meadows, with an emphasis on alluvial systems, to inform effective restoration strategies. We compare wet meadows to other wetlands, classify them into palustrine, lacustrine, and alluvial types, then focus on alluvial wet meadows and discuss how their formation and persistence depend on ground and surface water interactions, sediment deposition and flow obstructions, all mediated by biological processes. In particular, we highlight the role of hydric graminoids in resisting erosion and maintaining soil cohesion, how beaver promote meadow persistence, and the significance of wet meadows as carbon sinks. We also present stratigraphic evidence demonstrating that incision, often triggered by anthropogenic activity or changing climate, is the primary mechanism of alluvial wet meadow degradation, resulting in water table decline and shifts in vegetation composition. Restoration requires reversing these incisional processes through techniques that elevate water tables, disperse flow and retain sediment—methods traditionally associated with either soil conservation or stream restoration. These include nature-based solutions that create obstructions such as beaver dams and their analogues, rock and wood-based obstructions and incision trench or gully filling and grading. Given their multifunctional value—including but not limited to flood attenuation, biodiversity support, and carbon sequestration—wet meadows warrant a focused restoration framework. This review advocates for a valley-floor scale restoration paradigm that integrates hydrological reconnection, sediment retention, and biological reinforcement to ensure long-term resilience of these systems in the face of changing climate and land use pressures.

Frontiers in Environmental Science

From hydrated silica to quartz: Potential hydrothermal precipitates found in Jezero crater, Mars

On Earth, silica-rich phases from opal to quartz are important indicators and tracers of geological processes. Hydrated silica, such as opal, is a particularly good matrix for the preservation of molecular and macroscopic biosignatures. Cherts, a type of silica-dominated rocks, provide a unique archive of ancient terrestrial life while quartz is the emblematic mineral of the Earth's continental crust. On Mars, hydrated silica has been detected in several locations based on remote sensing and rover-based studies. In the present article we report on the detection of cobbles made of hydrated silica (opal or chalcedony), as well as well-crystallized quartz. These detections were made with the SuperCam instrument onboard Perseverance (Mars 2020 mission), using a combination of LIBS, infrared and Raman spectroscopy. Quartz-dominated stones are detected unambiguously for the first time on the Martian surface, and based on grain size and crystallinity are proposed to be of hydrothermal origin. Although these rocks were all found as float, we propose that these detections are part of a common hydrothermal system, and represent different depths / temperatures of precipitation. This attests that hydrothermal processes were active in and around Jezero crater, possibly triggered by the Jezero crater-forming impact. These silica-rich rocks, in particular opaline silica, are very promising targets for sampling and return to Earth given their high biosignature preservation potential.

Earth and Planetary Science Letters

High-resolution magnetic survey using an unoccupied aerial vehicle to constrain buried lava flow geometry, volume, and eruptive history of Little Cones, Crater Flat, Nevada

Magnetic surveys are an important tool used to augment geologic mapping in distributed volcanic fields. Using magnetic anomalies, it is possible to model the geometry of shallowly buried volcanic features, such as conduits, sills, and lava flows. This subsurface mapping is important for understanding eruption dynamics and emplacement of lava flows, and it sometimes reveals buried volcanoes no longer visible at the surface. These data are critical to better interpret the numbers, styles, and magnitudes of eruptions in distributed volcanic fields and their associated volcanic hazards. New advances in unoccupied aerial vehicles (UAVs) offer an attractive middle range of resolution and aerial coverage between ground-based magnetic surveys and aeromagnetic surveys. Here, we present the results of a UAV fluxgate magnetic survey of the Little Cones, Nevada, scoria cones, which have been the target of previous ground and aeromagnetic surveys. The magnetic anomalies at Little Cones are of interest because the surrounding alluvium conceals lava flows that erupted from Little Cones, making it very difficult to understand the volume and morphology of lava flows from geologic mapping alone. Nonlinear inversion of UAV-collected magnetic data were used to model the thickness and morphology of buried Little Cones’ lava flows with higher precision than achieved previously. The sequence of events and calculated flow characteristics are then interpreted. The total volume of Little Cones, including concealed lava flows, is approximately 0.016 cubic kilometer, and the initial sheet flow erupted in less than 24 hours. The findings presented herein demonstrate that UAV-based magnetic surveys are a reliable method of data collection and an efficient alternative to other survey methods, facilitating development of a three-dimensional perspective of distributed volcanic fields.

Nevada

Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24

The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.

Scientific Investigations Report