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At least 685 records · Page 38Linked to original sources

Hydrology and quality of ground water in northern Thurston County, Washington

Northern Thurston County is underlain by as much as 1,800 feet of unconsolidated deposits of Pleistocene Age that are of glacial and nonglacial origin. Iterpretation of approximately 1,140 drillers' logs led to the delineation of seven major geohydrologic units, four of which are significant aquifers. Precipitation ranges from about 35 to 65 inches per year across the study area. Estimates of recharge indicate that the ground-water system of the Ground Water Management Area (GWMA), a subset of the study area, receives an average of about 28 inches per year. Ground water generally moves toward marine water bodies and to major surface drainage channels. At least 33,000 acre-feet per year of ground water discharges as springs from the GWMA. Approximately 21,000 acre-feet of water was withdrawn from the ground-water system of the GWMA through wells in 1988. Total ground-water use in the GWMA in 1988 was approximately 37,000 acre-feet. About 16,000 acre-feet of water that discharges naturally through springs was used together with water withdrawn by wells for domestic supply, agricultural, commercial, industrial, institutional, and aquaculture and livestock uses. Generally, the chemical quality of the ground water was good and 94 percent of the water samples were classified as soft or moderately hard. Of the few water-quality problems encountered, the most widespread anthropogenic problem appeared to be seawater intrusion. However, a comparison with data from 1978 indicated that the degree and extent of intrusion had not changed significantly since that time. Agricultural activities may be responsible for the presence of nitrate in ground waters at some individual wells, but septic tanks in areas of high housing density are likely responsible for elevated nitrate concentrations near the Cities of Lacey and Tumwater. The close correlation of nitrate concentrations with detergent concentrations supports the theory that the nitrate originates in septic systems, the only likely source of the detergents. Most water-quality problems in the study area, however, are due to natural causes. Iron concentrations are as large as 21,000 micrograms per liter, manganese concentrations are as large as 3,400 micrograms per liter, and connate seawater is present in ground water in the southern part of the study area.

Washington↗

Land-cover changes associated with oil and natural-gas production and concentrations of selected constituents in surface-water and streambed-sediment samples collected upstream from and within an area of oil and natural-gas production, south Texas, 2008–17

The extensive development of oil and natural-gas resources in south Texas during the past 10 years has led to questions regarding possible environmental effects of processes associated with oil and natural-gas production, in particular the process of hydraulic fracturing, on water and other natural resources. Part of the lower San Antonio River watershed intersects an area of oil and natural-gas production from the sedimentary rocks that compose the Eagle Ford Group. The rapid expansion of infrastructure associated with oil and natural-gas production increases potential pathways for inorganic and organic contaminants to enter surface-water systems. The U.S. Geological Survey, in cooperation with the San Antonio River Authority, analyzed geospatial data from different years (2008 and 2015) to evaluate changes in land cover associated with oil and natural-gas production activities in the lower San Antonio River watershed. Impervious surface in this study is defined as land cover consisting of well pads, oil- and gas-related features, or roads. The areal coverage associated with impervious surface increased from 201 acres to 5,390 acres (net increase of 5,189 acres) between 2008 and 2015. The total percentage of the study area accounted for by impervious surface resulting from oil and natural-gas production activities increased from 0.034 percent to 0.912 percent, which is an increase of approximately 27-fold. Collectively, 0.878 percent of the study area was converted to new impervious surface between 2008 and 2015. If the area associated with new storage ponds (0.066 percent) is added to the estimate of total land-cover changes as a result of oil and natural-gas production, then 0.944 percent of the study area was altered. During 2015–17, surface-water samples collected from 5 sites and streambed-sediment samples collected from 17 sites in the lower San Antonio River watershed were analyzed for a broad range of constituents that might be associated with oil and natural-gas production. All major elements, trace elements, semivolatile organic compounds (SVOCs), and volatile organic compounds (VOCs) measured in surface-water samples were detected at concentrations less than any of the U.S. Environmental Protection Agency’s water-quality standards. In general, the greatest SVOC and VOC concentrations were observed in samples collected from sites upstream from the area of active oil and natural-gas production and just downstream from urban areas. The lack of benzene, toluene, ethylbenzene, and all isomers of xylene (hereinafter referred to as BTEX) for most sites within the area of active oil and natural-gas production indicates that little, if any, local runoff associated with the area of active oil and natural-gas production has contaminated the surface water with BTEX compounds. Glycols, which are commonly used in hydraulic fracturing fluids as scale inhibitors, were detected in one surface-water sample from Ecleto Creek within the area of oil and natural-gas production; however, the presence of glycols does not necessarily indicate contamination from hydraulic fracturing fluid. The glycols detected also have other potential sources including the use of diethylene and ethylene glycols in antifreeze used in vehicles and the use of triethylene glycol in antibacterial air sanitizers. The concentrations of select constituents in the streambed-sediment samples were compared to sediment quality guidelines (SQGs). The SQGs evaluate the potential toxicity of bed sediments to sediment-dwelling organisms. Two SQG concentration levels are used: (1) a lower level, called the threshold effect concentration (TEC), below which harmful effects to benthic biota are not expected, and (2) a higher level, the probable effect concentration (PEC), above which harmful effects are expected to occur frequently. The PEC for arsenic was exceeded in a sample collected from one site on Ecleto Creek. The origin of the elevated arsenic concentration is unknown; the contamination likely is not related to oil and natural-gas production because the site of the sample collection is located upstream from the area of active oil and natural-gas production. Streambed-sediment samples were analyzed for selected polycyclic aromatic hydrocarbons (PAHs) because PAHs can be used as indicators of petroleum hydrocarbons associated with produced waters. Each streambed-sediment sample was analyzed for two size fractions of PAHs: less than (<) 63 micrometers (μm) and < 2 millimeters (mm). Total PAH concentrations in all samples, regardless of size fraction, were less than the TEC for total PAHs of 1,610 micrograms per kilogram. Total PAH concentrations generally were greater in the <63-μm size-fraction samples than in the <2-mm size-fraction samples, indicating that PAHs could potentially sorb more readily to the exclusively silt- and clay-sized particles that compose <63-μm size-fraction samples than to the mixture of silt and clay and larger sized particles that compose the <2-mm size-fraction samples. Total PAH concentrations typically were greater in the samples collected from the sites upstream from the area of active oil and natural-gas production compared to those collected from sites within the area in both the <2-mm and <63-μm size-fraction samples. The smaller PAH concentrations measured in samples collected from within the area of active oil and natural-gas production in comparison to the upstream urbanized areas indicate relatively minor additional local contributions of PAHs of uncertain origin to the watershed.

Texas↗

Global Cropland Area Database (GCAD) derived from Remote Sensing in Support of Food Security in the Twenty-first Century: Current Achievements and Future Possibilities

The precise estimation of the global agricultural cropland- extents, areas, geographic locations, crop types, cropping intensities, and their watering methods (irrigated or rainfed; type of irrigation) provides a critical scientific basis for the development of water and food security policies (Thenkabail et al., 2012, 2011, 2010). By year 2100, the global human population is expected to grow to 10.4 billion under median fertility variants or higher under constant or higher fertility variants (Table 1) with over three quarters living in developing countries, in regions that already lack the capacity to produce enough food. With current agricultural practices, the increased demand for food and nutrition would require in about 2 billion hectares of additional cropland, about twice the equivalent to the land area of the United States, and lead to significant increases in greenhouse gas productions (Tillman et al., 2011). For example, during 1960-2010 world population more than doubled from 3 billion to 7 billion. The nutritional demand of the population also grew swiftly during this period from an average of about 2000 calories per day per person in 1960 to nearly 3000 calories per day per person in 2010. The food demand of increased population along with increased nutritional demand during this period (1960-2010) was met by the &ldquo;green revolution&rdquo; which more than tripled the food production; even though croplands decreased from about 0.43 ha/capita to 0.26 ha/capita (FAO, 2009). The increase in food production during the green revolution was the result of factors such as: (a) expansion in irrigated areas which increased from 130 Mha in 1960s to 278.4 Mha in year 2000 (Siebert et al., 2006) or 399 Mha when you do not consider cropping intensity (Thenkabail et al., 2009a, 2009b, 2009c) or 467 Mha when you consider cropping intensity (Thenkabail et al., 2009a; Thenkabail et al., 2009c); (b) increase in yield and per capita food production (e.g., cereal production from 280 kg/person to 380 kg/person and meat from 22 kg/person to 34 kg/person (McIntyre, 2008); (c) new cultivar types (e.g., hybrid varieties of wheat and rice, biotechnology); and (d) modern agronomic and crop management practices (e.g., fertilizers, herbicide, pesticide applications). However, some of the factors that lead to the green revolution have stressed the environment to limits leading to salinization and decreasing water quality. For example, from 1960 to 2000, the phosphorous use doubled from 10 million tons to 20 MT, pesticide use tripled from near zero to 3 MT, and nitrogen use as fertilizer increased to a staggering 80 MT from just 10 MT (Foley et al., 2007; Khan and Hanjra, 2008). Further, diversion of croplands to bio-fuels is already taking water away from food production; the economics, carbon sequestration, environmental, and food security impacts of biofuel production are net negative (Lal and Pimentel, 2009), leaving us with a carbon debt (Gibbs et al., 2008; Searchinger et al., 2008). Climate models predict that in most regions of the world the hottest seasons on record will become the norm by the end of the century-an outcome that bodes ill for feeding the world (Kumar and Singh, 2005). Also, crop yield increases of the green revolution era have now stagnated (Hossain et al., 2005). Thereby, further increase in food production through increase in cropland areas and\or increased allocations of water for croplands are widely considered unsustainable and\or infeasible. Indeed, cropland areas have even begun to decrease in many 3 parts of the World due to factors such as urbanization, industrialization, and salinization. Furthermore, ecological and environmental imperatives such as biodiversity conservation and atmospheric carbon sequestration have put a cap on the possible expansion of cropland areas to other lands such as forests and rangelands. Other important factors limit food security. These include factors such as diversion of croplands to biofuels (Bindraban et al., 2009), limited water resources for irrigation expansion (Turral et al., 2009), limits on agricultural intensifications, loss of croplands to urbanization (Khan and Hanjra, 2008), increasing meat consumption (and associated demands on land and water) (Vinnari and Tapio, 2009), environmental infeasibility for cropland expansion (Gordon et al., 2009), and changing climate have all put pressure on our continued ability to sustain global food security in the twenty-first century. So, how does the World continue to meet its food and nutrition needs?. Solutions may come from bio-technology and precision farming, however developments in these fields are not currently moving at rates that will ensure global food security over next few decades. Further, there is a need for careful consideration of possible harmful effects of bio-technology. We should not be looking back 30&ndash; 50 years from now, like we have been looking back now at many mistakes made during the green revolution. During the green revolution the focus was only on getting more yield per unit area. Little thought was put about serious damage done to our natural environments, water resources, and human health as a result of detrimental factors such as uncontrolled use of herbicides-pesticides-nutrients, drastic groundwater mining, and salinization of fertile soils due to over irrigation. Currently, there is talk of a &ldquo;second green revolution&rdquo; or even an &ldquo;ever green revolution&rdquo;, but clear ideas on what these terms actually mean are still debated and are evolving. One of the biggest issues that are not given adequate focus is the use of large quantities of water for food production. Indeed, an overwhelming proportion (60-90%) of all human water use in India goes for producing their food (Falkenmark, M., & Rockstr&ouml;m, 2006). But such intensive water use for food production is no longer tenable due to increasing pressure for water use alternatives such as increasing urbanization, industrialization, environmental flows, bio-fuels, and recreation. This has brought into sharp focus the need to grow more food per drop of water leading to a &ldquo;blue revolution&rdquo;

Book chapter↗

Predicting changes in hydrologic retention in an evolving semi-arid alluvial stream

Hydrologic retention of solutes in hyporheic zones or other slowly moving waters of natural channels is thought to be a significant control on biogeochemical cycling and ecology of streams. To learn more about factors affecting hydrologic retention, we repeated stream-tracer injections for 5 years in a semi-arid alluvial stream (Pinal Creek, Ariz.) during a period when streamflow was decreasing, channel width increasing, and coverage of aquatic macrophytes expanding. Average stream velocity at Pinal Creek decreased from 0.8 to 0.2 m/s, average stream depth decreased from 0.09 to 0.04 m, and average channel width expanded from 3 to 13 m. Modeling of tracer experiments indicated that the hydrologic retention factor ( R h ), a measure of the average time that solute spends in storage per unit length of downstream transport, increased from 0.02 to 8 s/m. At the same time the ratio of cross-sectional area of storage zones to main channel cross-sectional area ( A s / A ) increased from 0.2 to 0.8 m 2 /m 2 , and average water residence time in storage zones ( t s ) increased from 5 to 24 min. Compared with published data from four other streams in the US, Pinal Creek experienced the greatest change in hydrologic retention for a given change in streamflow. The other streams differed from Pinal Creek in that they experienced a change in streamflow between tracer experiments without substantial geomorphic or vegetative adjustments. As a result, a regression of hydrologic retention on streamflow developed for the other streams underpredicted the measured increases in hydrologic retention at Pinal Creek. The increase in hydrologic retention at Pinal Creek was more accurately predicted when measurements of the Darcy–Weisbach friction factor were used (either alone or in addition to streamflow) as a predictor variable. We conclude that relatively simple measurements of channel friction are useful for predicting the response of hydrologic retention in streams to major adjustments in channel morphology as well as changes in streamflow.

Advances in Water Resources↗

Declining groundwater storage expected to amplify mountain streamflow reductions in a warmer world

Groundwater interactions with mountain streams are often simplified in model projections, potentially leading to inaccurate estimates of streamflow response to climate change. Here, using a high-resolution, integrated hydrological model extending 400 m into the subsurface, we find groundwater an important and stable source of historical streamflow in a mountainous watershed of the Colorado River. In a warmer climate, increased forest water use is predicted to reduce groundwater recharge resulting in groundwater storage loss. Losses are expected to be most severe during dry years and cannot recover to historical levels even during simulated wet periods. Groundwater depletion substantially reduces annual streamflow with intermittent conditions predicted when precipitation is low. Expanding results across the region suggests groundwater declines will be highest in the Colorado Headwater and Gunnison basins. Our research highlights the tight coupling of vegetation and groundwater dynamics and that excluding explicit groundwater response to warming may underestimate future reductions in mountain streamflow.

Nature Water↗

Simulation of steady-state ground water and spring flow in the upper Floridan aquifer of coastal Citrus and Hernando Counties, Florida

A digital groundwater flow model was developed to approximate steady-state predevelopment flow conditions in the Upper Floridan aquifer of coastal west-central Florida. The aquifer is the major source of water and natural spring flow in the area. The aquifer was simulated as a one-layer system with constant vertical recharge and discharge rates. Calibrated transmissivities ranged from 8,640 sq ft/day in the northern part of the area to nearly 13,000,000 sq ft/day near large springs. Calibrated inflows were about 2,708 cu ft/sec; of this, about 2,565 cu ft/sec discharged as natural spring flow and 137 cu ft/sec discharged as upward leakage along the coast. The model was used to show how the system might respond to large manmade stresses. Withdrawal of 116 cu ft/sec from a hypothetical regional well field resulted in potentiometric-surface drawdowns ranging from 0.1 to 1.7 ft and declines of generally less than 0.2 ft along the coast. Total spring flow decreased 5%, and the effect on individual springs varied from 0.1 to 8.0%. Withdrawal of 62 cu ft/sec from the 4-sq-mi node at each spring resulted in six of seven springs to the south of the Chassahowitzka River contributing 50% of their flow to pumpage. Springs located north of the Chassahowitzka River contributed as much as 18% of their flow to pumpage. (USGS)

Water-Resources Investigations Report↗

Advancing the science of headwater streamflow for global water protection

The protection of headwater streams faces increasing challenges, exemplified by limited global recognition of headwater contributions to watershed resiliency and a recent US Supreme Court decision limiting federal safeguards. Despite accounting for ~77% of global river networks, the lack of adequate headwaters protections is caused, in part, by limited information on their extent and functions—in particular, their flow regimes, which form the foundation for decision-making regarding their protection. Yet, headwater streamflow is challenging to comprehensively measure and model; it is highly variable and sensitive to changes in land use, management and climate. Modelling headwater streamflow to quantify its cumulative contributions to downstream river networks requires an integrative understanding across local hillslope and channel (that is, watershed) processes. Here we begin to address this challenge by proposing a consistent definition for headwater systems and streams, evaluating how headwater streamflow is characterized and advocating for closing gaps in headwater streamflow data collection, modelling and synthesis.

Nature Water↗

Water, frost, and frost resistance of natural and artificial building stones

The worst enemy of construction engineering and of construction material is uncontrollable water, whether it be ground-, seepage-, rainwater, water of condensation, or melting snow and ice, exerting objectionable pressure upon tracks and roads. this applies as well to structures above the ground as to bridge piers and foundations, road construction, earthwork, etc.

Open-File Report↗

Processes of multibathyal aragonite undersaturation in the Arctic Ocean

During 3 years of study (2010–2012), the western Arctic Ocean was found to have unique aragonite saturation profiles with up to three distinct aragonite undersaturation zones. This complexity is produced as inflow of Atlantic-derived and Pacific-derived water masses mix with Arctic-derived waters, which are further modified by physiochemical and biological processes. The shallowest aragonite undersaturation zone, from the surface to ∼30 m depth is characterized by relatively low alkalinity and other dissolved ions. Besides local influence of biological processes on aragonite undersaturation of shallow coastal waters, the nature of this zone is consistent with dilution by sea-ice melt and invasion of anthropogenic CO 2 from the atmosphere. A second undersaturated zone at ∼90–220 m depth (salinity ∼31.8–35.4) occurs within the Arctic Halocline and is characterized by elevated p CO 2 and nutrients. The nature of this horizon is consistent with remineralization of organic matter on shallow continental shelves bordering the Canada Basin and the input of the nutrients and CO 2 entrained by currents from the Pacific Inlet. Finally, the deepest aragonite undersaturation zone is at greater than 2000 m depth and is controlled by similar processes as deep aragonite saturation horizons in the Atlantic and Pacific Oceans. The comparatively shallow depth of this deepest aragonite saturation horizon in the Arctic is maintained by relatively low temperatures, and stable chemical composition. Understanding the mechanisms controlling the distribution of these aragonite undersaturation zones, and the time scales over which they operate will be crucial to refine predictive models.

Journal of Geophysical Research: Oceans↗

Geologic and hydrologic hazards in glacierized basins in North America resulting from 19th and 20th century global warming

Alpine glacier retreat resulting from global warming since the close of the Little Ice Age in the 19th and 20th centuries has increased the risk and incidence of some geologic and hydrologic hazards in mountainous alpine regions of North America. Abundant loose debris in recently deglaciated areas at the toe of alpine glaciers provides a ready source of sediment during rainstorms or outburst floods. This sediment can cause debris flows and sedimentation problems in downstream areas. Moraines built during the Little Ice Age can trap and store large volumes of water. These natural dams have no controlled outlets and can fail without warning. Many glacier-dammed lakes have grown in size, while ice dams have shrunk, resulting in greater risks of ice-dam failure. The retreat and thinning of glacier ice has left oversteepened, unstable valley walls and has led to increased incidence of rock and debris avalanches. ?? 1993 Kluwer Academic Publishers.

Natural Hazards↗

Chloride toxicity to native freshwater species in natural and reconstituted prairie pothole waters

Oil and gas extraction in the Prairie Pothole Region (PPR) of the northern USA has resulted in elevated chloride concentrations in ground and surface water due to widespread contamination with highly saline produced water, or brine. The toxicity of chloride is poorly understood in the high hardness waters characteristic of the region. We evaluated the toxicity of chloride to two endemic species, Daphnia magna (water flea) and Lemna gibba (duckweed), exposed in field-collected waters (hardness ~ 3000 mg/L as CaCO 3 ) and reconstituted waters (hardness 370 mg/L as CaCO 3 ) intended to mimic PPR background waters. We also investigated the role of chloride in the toxicity of water reconstituted to mimic legacy brine-contaminated wetlands, using two populations of native Pseudacris maculata (Boreal Chorus Frog). Chloride toxicity was similar in field-collected and reconstituted waters for both D. magna (LC50s 3070–3788 mg Cl −1 /L) and L. gibba (IC50s 2441–2887). Although hardness can ameliorate chloride toxicity at low to high hardness, we did not observe additional protection as hardness increased from 370 to ~ 3000 mg/L. In P. maculata exposures, chloride did not fully explain toxicity. Chloride sensitivity also differed between populations, with mortality at 2000 mg Cl − /L in one population but not the other, and population-specific growth responses. Overall, these results (1) document toxicity to native species at chloride concentrations occurring in the PPR, (2) indicate that very high hardness in the region’s waters may not provide additional protection against chloride and (3) highlight challenges of brine investigations, including whether surrogate study populations are representative of local populations.

Missouri, Montana, North Dakota, Wyoming↗

An aem-tem study of weathering and diagenesis, Abert Lake, Oregon: I. Weathering reactions in the volcanics

Abert Lake in south-central Oregon provides a site suitable for the study of sequential weathering and diagenetic events. In this first of two papers, transmission electron microscopy was used to characterize the igneous mineralogy, subsolidus alteration assemblage, and the structural and chemical aspects of silicate weathering reactions that occur in the volcanic rocks (basalts, basaltic andesites, and dacitic/ rhyolitic extrusive and pyroclastics) that outcrop around the lake. Olivine and pyroxene replacement occurred topotactically, whereas feldspar and glass alteration produced randomly oriented smectite in channels and cavities. The tetrahedral, octahedral, and interlayer compositions of the weathering products, largely dioctahedral smectites, varied with primary mineral composition, rock type, and as the result of addition of elements released from adjacent reaction sites. Weathering of the highly evolved, Fe-rich Jug Mountain complex at the north end of the lake produced a homogeneous smectite assemblage that contrasts with the heterogeneous smectite assemblage replacing the volcanics along the eastern margin of the lake. The variability within and between the smectite assemblages highlights the microenvironmental diversity, fluctuating redox conditions, and variable solution chemistry associated with mineral weathering reactions in the surficial environment. Late-stage exhalative and aqueous alteration of the volcanics redistributed many components and formed a variety of alkali and alkali-earth carbonate, chloride, sulfate, and fluoride minerals in vugs and cracks. Overall, substantial Mg, Si, Na, Ca, and K are released by weathering reactions that include the almost complete destruction of the Mg-smectite that initially replaced olivine. The leaching of these elements from the volcanics provides an important source of these constituents in the lake water. The nature of subsequent diagenetic reactions resulting from the interaction between the materials transported to the lake and the solution will be described in part II ( Banfield et al., 1991).

Geochimica et Cosmochimica Acta↗

Calibrated models as management tools for stream-aquifer systems: The case of central Kansas, USA

We address the problem of declining streamflows in interconnected stream-aquifer systems and explore possible management options to address the problem for two areas of central Kansas: the Arkansas River valley from Kinsley to Great Bend and the lower Rattlesnake Creek-Quivira National Wildlife Refuge area. The approach we followed implements, calibrates, and partially validates for the study areas a stream-aquifer numerical model combined with a parameter estimation package and sensitivity analysis. Hydrologic budgets for both predevelopment and developed conditions indicate significant differences in the hydrologic components of the study areas resulting from development. The predevelopment water budgets give an estimate of natural ground-water recharge, whereas the budgets for developed conditions give an estimate of induced recharge, indicating that major ground-water development changes the recharge-discharge regime of the model areas with time. Such stream-aquifer models serve to link proposed actions to hydrologic effects, as is clearly demonstrated by the effects of various management alternatives on the streamflows of the Arkansas River and Rattlesnake Creek. Thus we show that a possible means of restoring specified streamflows in the area is to implement protective stream corridors with restricted ground-water extraction.

Journal of Hydrology↗

The solubility of noble gases in crude oil at 25-100°C

The solubility of the noble gases He, Ne, Ar, Kr and Xe was measured in two typical crude oils at temperatures of 25&ndash;100&deg;C. The oil samples were obtained from the Elk Hills oil field located in southern San Joaquin Valley, California. The experimental procedure consisted of placing a known amount of gas with a known volume of crude oil in a stainless steel hydrothermal pressure vessel. The vessel was housed inside an oven and the entire unit rotates providing continuous mixing. The amount of gas dissolved in oil at a measured temperature and partial pressure of gas was used to calculate the solubility constants for these gases. Results show that the solubility of He and Ne in both oils is approximately the same; solubility then increases with atomic mass, with the solubility of Xe at 25&deg;C being two orders of magnitude higher than that of He. The gas solubilities are somewhat higher in the lower density (higher API gravity) oil. The solubility of Ar is approximately constant in the range of temperatures of this study. The solubilities of He and Ne increase, but those of Kr and Xe decrease with increasing temperatures. Solubilities of noble gases in crude oil are significantly higher than their solubilities in water. For example, the solubilities of He and Xe at 25&deg;C in the light oil of this study are, respectively, 3 and 24 times higher than their solubilities in pure water, and they are 15 and 300 times higher than in a brine with a salinity of 350,000 mg/l dissolved solids. These large and variable differences in the solubilities of noble gases in oil and water indicate that, in sedimentary basins with oil, these gases must be partitioned between oil, water and natural gas before they are used to deduce the origin and residence time of these fluids.

Applied Geochemistry↗

Don’t move a mussel: The role of key environmental drivers and management scale in assessing spatial variation in dreissenid spread risk in the Missouri River Basin

The spread of non-native freshwater mussels in North America is a growing threat that has already resulted in substantial ecological and economic damage to infested areas. A primary vector by which invasive mussels spread is watercraft that are transported over land from an infested waterbody to an uninfested waterbody. Management efforts such as watercraft inspection and detection programs that attempt to intercept infected watercraft can help limit this type of spread, but optimizing the effectiveness of these programs under limited resources is complicated. Studies have looked at developing watercraft inspection and decontamination program strategies that focus on policy-specific objectives such as maximizing the number of infested watercraft interceptions. However, there is limited work that has considered the heterogeneous impact of protection efforts across different regions and waterbodies. Knowledge about this heterogeneity can highlight regions that would benefit the most from protection as well as regions that would require less effort to protect, e.g., areas with naturally unsuitable water quality for dreissenids. To this end, we construct a composite relative risk index (CRR) for watersheds within the Missouri River Basin, a region in the United States on the front line of dreissenid spread. The CRR uses a model that mirrors an expected value model but uses relative indexing as a proxy for the model components. The CRR incorporates a wide array of data sets to account for the direct and indirect damages from a potential infestation along with the risk of an infestation occurring. Our results suggest that the relative priority of a specific watershed—measured through CRR—can depend on whether we consider the entire Missouri River Basin or just the watersheds in the same state. This also indicates substantial state-level heterogeneity in the CRR. Another contribution is that the CRR index includes user-specified weights for certain parameters so that a user can adjust the relative importance of various factors to match their specific context. An accompanying web tool allows users to view the CRR results and adjust multiple parameters to see the resulting impacts on the CCR for watersheds in the Missouri River Basin.

Missouri River Basin↗

Comprehensive characterization of Mauna Loa basalt rheology based on the 2022 eruption

Rheological data are crucial for the understanding of storage, transport, eruption, and emplacement of magma and lava. While viscosity estimates for lavas from Mauna Loa, the largest active volcano on Earth, exist, no direct rheological measurements have been done to date. This is especially surprising given the role Mauna Loa lavas and resulting landforms play in the interpretation of volcanic processes across our solar system and beyond. We present the first complete rheological characterization of Mauna Loa lava, based on the 2022 eruption. We constrain the melt viscosity and map the lava's rheology during crystallization at isothermal subliquidus conditions and at cooling at rates between 0.25 and 3.00 °C/minute. These experiments were performed at oxygen fugacities relevant to storage and eruption conditions at Mauna Loa (log fO 2 = -8.7). We integrate textural and thermal characteristics obtained from the experiments with those from water quenched natural samples (i.e. sampled from actively flowing lava and quenched within seconds to preserve the textural state of the lava while flowing) to reconstruct the evolution of lava rheology during emplacement. This integration suggests that the Mauna Loa lavas were emplaced at viscosities between 10 1.5 to 10 4.5 Pa s over the temperature range of 1150 – 1090 °C before entering a region of rapid viscosity increase and effective solidification caused by groundmass crystallization. We provide a detailed comparison of our data to rheological reconstructions of the 1984 eruption. The resulting rheological map can help guide physical property-based magma ascent and lava emplacement models, as well as the interpretation of flow morphologies and the conditions of formation of basaltic landforms on other planets.

Hawaii↗

Retrospective analysis of associations between water quality and toxic blooms of golden alga ( Prymnesium parvum ) in Texas reservoirs: Implications for understanding dispersal mechanisms and impacts of climate change

Toxic blooms of golden alga (GA, Prymnesium parvum ) in Texas typically occur in winter or early spring. In North America, they were first reported in Texas in the 1980s, and a marked range expansion occurred in 2001. Although there is concern about the influence of climate change on the future distribution of GA, factors responsible for past dispersals remain uncertain. To better understand the factors that influence toxic bloom dispersal in reservoirs, this study characterized reservoir water quality associated with toxic GA blooms since 2001, and examined trends in water quality during a 20-year period bracketing the 2001 expansion. Archived data were analyzed for six impacted and six nonimpacted reservoirs from two major Texas basins: Brazos River and Colorado River. Data were simplified for analysis by pooling spatially (across sampling stations) and temporally (winter, December-February) within reservoirs and generating depth-corrected (1 m) monthly values. Classification tree analysis [period of record (POR), 2001-2010] using salinity-associated variables (specific conductance, chloride, sulfate), dissolved oxygen (DO), pH, temperature, total hardness, potassium, nitrate+nitrite, and total phosphorus indicated that salinity best predicts the toxic bloom occurrence. Minimum estimated salinities for toxic bloom formation were 0.59 and 1.02 psu in Brazos and Colorado River reservoirs, respectively. Principal component analysis (POR, 2001-2010) indicated that GA habitat is best defined by higher salinity relative to nonimpacted reservoirs, with winter DO and pH also being slightly higher and winter temperature slightly lower in impacted reservoirs. Trend analysis, however, did not reveal monotonic changes in winter water quality of GA-impacted reservoirs during the 20-year period (1991-2010) bracketing the 2001 dispersal. Therefore, whereas minimum levels of salinity are required for GA establishment and toxic blooms in Texas reservoirs, the lack of trends in water quality suggests that conditions favorable for toxic blooms pre-date the 2001 expansion. These observations are consistent with a climate change-independent scenario of past GA dispersals in Texas reservoirs driven by novel introductions into pre-existing favorable habitat. Reports of latent GA populations in certain nonimpacted reservoirs, however, provide a plausible scenario of future dispersals characterized by prolonged periods between colonization and toxic bloom development and driven by changes in water quality, natural, or anthropogenic.

Harmful Algae↗

Analysis of host genetic diversity and viral entry as sources of between-host variation in viral load

Little is known about the factors that drive the high levels of between-host variation in pathogen burden that are frequently observed in viral infections. Here, two factors thought to impact viral load variability, host genetic diversity and stochastic processes linked with viral entry into the host, were examined. This work was conducted with the aquatic vertebrate virus, Infectious hematopoietic necrosis virus (IHNV), in its natural host, rainbow trout. It was found that in controlled in vivo infections of IHNV, a suggestive trend of reduced between-fish viral load variation was observed in a clonal population of isogenic trout compared to a genetically diverse population of out-bred trout. However, this trend was not statistically significant for any of the four viral genotypes examined, and high levels of fish-to-fish variation persisted even in the isogenic trout population. A decrease in fish-to-fish viral load variation was also observed in virus injection challenges that bypassed the host entry step, compared to fish exposed to the virus through the natural water-borne immersion route of infection. This trend was significant for three of the four virus genotypes examined and suggests host entry may play a role in viral load variability. However, high levels of viral load variation also remained in the injection challenges. Together, these results indicate that although host genetic diversity and viral entry may play some role in between-fish viral load variation, they are not major factors. Other biological and non-biological parameters that may influence viral load variation are discussed.

Virus Research↗