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At least 685 records · Page 38Linked to original sources

USGS2007

Aufeis accumulations in stream bottoms in arctic and subarctic environments as a possible indicator of geologic structure: Chapter F in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

Thick accumulations of ice, called “aufeis,” form during winter along stream and river valleys in arctic and subarctic regions. In high-gradient alpine streams, aufeis forms mostly as a result of ground-water discharge into the stream channel. The ice occludes this discharge, perturbing the steady-state condition, and causing an incremental rise in the local water table until discharge occurs higher on the stream bank above the previously formed ice. Successive freezing of onlapping ice layers can lead to aufeis accumulations several meters thick. The location and extent of aufeis in high-gradient streams may be useful to relate local hydrology to geologic structure. In the Goodpaster River basin study area, mineral deposits are known to occur, the location of which may be structurally controlled. Therefore, a more thorough understanding of regional geologic structures may facilitate a more detailed understanding of the genesis of the mineral deposits. Extensive aufeis was observed during visits to the Goodpaster River basin in east-central Alaska during 1999, 2001, and 2002. Seeps from the sides of the valleys caused ice to build up, giving the ice surface a concave-upward shape perpendicular to the stream direction. This concavity is evidence for ground-water discharge along the length of the aufeis, as opposed to discharge from a single upstream point. During thaw, streamflow is commonly observed out of the normal channel, evidence that occlusion of the channel (and shallow sediments) by ice is a viable mechanism for causing the water table to rise. The thickest (>3 meters) and most extensive aufeis (100’s of meters to kilometers along valleys) coincided with locations of laterally extensive (>5 kilometers) mapped high-angle brittle fault zones, suggesting that the fault zones are hydraulically conductive. Additional evidence of water flow is provided by observed changes in stream-water chemistry in reaches in which aufeis forms, despite a lack of surface tributaries. Minor or no aufeis was observed in many other drainage valleys where no laterally extensive structures have been mapped, implying that aufeis formation results from more than a topographic effect or discharge from bank storage. Thus, the presence of thick, laterally extensive aufeis in highgradient streams may be a useful aid to geologic structural mapping in arctic and subarctic climates.

Alaska;Yukon↗

USGS2024

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska↗

USGS2021

Aeolian sediments in paleowetland deposits of the Las Vegas Formation

The Las Vegas Formation (LVF) is a well-characterized sequence of groundwater discharge (GWD) deposits exposed in and around the Las Vegas Valley in southern Nevada. Nearly monolithologic bedrock surrounds the valley, which provides an excellent opportunity to test the hypothesis that GWD deposits include an aeolian component. Mineralogical data indicate that the LVF sediments are dominated by carbonate minerals, similar to the local bedrock, but silicate minerals are also present. The median particle size is ~35 μm, consistent with modern dust in the region, and magnetic properties contrast strongly with local bedrock, implying an extralocal origin. By combining geochemical data from the LVF sediments and modern dust, we found that an average of ~25% of the LVF deposits were introduced by aeolian processes. The remainder consists primarily of authigenic groundwater carbonate as well as minor amounts of alluvial material and soil carbonate. Our data also show that the aeolian sediments accumulated in spring ecosystems in the Las Vegas Valley in a manner that was independent of both time and the specific hydrologic environment. These results have broad implications for investigations of GWD deposits located elsewhere in the southwestern U.S. and worldwide.

Nevada↗

USGS2005

Paleoenvironmental analyses of an organic deposit from an erosional landscape remnant, Arctic Coastal Plain of Alaska

The dominant landscape process on the Arctic Coastal Plain of northern Alaska is the formation and drainage of thaw lakes. Lakes and drained thaw-lake basins account for approximately 75% of the modern surface expression of the Barrow Peninsula. The thaw-lake cycle usually obliterates lacustrine or peat sediments from previous cycles, which could otherwise be used for paleoecological reconstruction of long-term landscape and vegetation changes. Several possible erosional remnants of a former topographic surface that predates the formation of the thaw lakes have been tentatively identified. These remnants are characterized by a higher elevation, a thick organic layer with very high ground ice content in the upper permafrost and a plant community somewhat atypical of the region. Ten soil cores were collected from one site, and one core was intensively sampled for soil organic carbon content, pollen analysis and 14 C dating. The lowest level of the organic sediments represents the earliest phase of plant growth and dates to ca. 9000 cal BP. Palynological evidence indicates the presence of mesic shrub tundra (including sedge, birch, willow and heath vegetation), and microfossil indicators point to wetter eutrophic conditions during this period. Carbon accumulation was rapid due to high net primary productivity in a relatively nutrient-rich environment. These results are interpreted as the local response to ameliorating climate during the early Holocene. The middle Holocene portion of the record contains an unconformity, indicating that between 8200 and 4200 cal BP sediments were eroded from the site, presumably in response to wind activity during a drier period centered around 4500 cal BP. The modern vegetation community of the erosional remnant was established after 4200 cal BP and peat growth resumed. During the late Holocene, carbon accumulation rates (CARs) were greatly reduced in response to the combined effects of declining productivity associated with climatic cooling, and increased nutrient stress as paludification and permafrost aggradation sequestered mineral nutrients.

Alaska↗

USGS2003

Physiological characteristics of wild Atlantic salmon post-smolts during estuarine and coastal migration

Changes were measured in some of the major physiological variables associated with seawater adaptability, growth and energetics in wild Atlantic salmon Salmo salar smolts and post-smolts migrating from the river and through the estuary, fjord and coastal areas in the River Orkla and the Trondheimsfjord, Norway during late May to early June. Gill Na+,K+-ATPase activity increased to levels of 12-16 ??mol ADP mg protein-1 h -1 in post-smolts caught in higher salinity zones, probably representing long-term levels of Atlantic salmon post-smolts in oceanic conditions. Muscle moisture was regulated within narrow limits (77.7-78.7%) in fish from all zones during both years, suggesting that post-smolts adapt to marine conditions without any long-term disturbance of hydro-mineral balance. Lipid and glycogen content showed a general trend towards depletion from the river, through the fjord and into the ocean. There was, however, no significant change in protein content. The present results confirm that smolts are naturally 'energy deficient' during downstream migration, and suggest that post-smolts also mobilize energy reserves during their early marine phase, while protein is allocated for somatic growth. Plasma growth hormone (GH) levels increased transiently during passage through the estuary and fjord, with lower levels observed in post-smolts caught off-shore, i.e. in fish which were feeding on marine prey and had adapted to the marine environment. These physiological changes may confer substantial selective advantages during the critical early marine phase of anadromous salmonids, and hence are adaptive for long-term survival in sea water. ?? 2003 The Fisheries Society of the British Isles.

Journal of Fish Biology↗

USGS1969

Geology and regional metamorphism of some high-grade cordierite gneisses, Front Range, Colorado

Cordierite is common in regional metamorphic gneisses of Precambrian age in the central part of the Front Range. It occurs in discontinuous stratigraphic units that are structurally a minor component, except locally, of the thick succession of biotite gneisses that comprise the widespread Idaho Springs Formation. The rocks have mineral assemblages, that are characteristic of the sillimanite grade of metamorphism. The cordierite occurs in three principal rock types: (1) potassic feldspar-bearing cordierite-garnet-sillimanite-biotite gneiss, (2) cordierite-biotite gneiss, and (3) cordierite-gedrite-biotite gneiss; each type contains several characteristic mineral assemblages. The rock types are gradational and overlap in areal distribution, and mainly owe their diversity in mineralogy to differences in bulk chemical composition. The field relations are consistent with an interpretation that the diverse cordierite rocks were derived from original sedimentary rocks, largely pelitic sediments. The potassic feldspar-bearing cordierite-garnet gneisses were formed from shales that contained more MgO and FeO than the more abundant sedimentary facies that yielded sillimanitic biotite gneisses. Cordierite-gedrite-biotite gneisses contain much aluminum, iron, and magnesium and little sodium and potassium as compared to the other biotite gneisses; they have an extremely low content of minor elements. Although their chemical compositions are unlike those of known modern sediments, the cordierite-gedrite gneisses are considered also to have been derived from sedimentary rocks. The physical properties and chemical compositions of the mineral phases vary somewhat from one rock type to another. Biotite varies systematically in composition, and the changes are closely related to rock type and thus to bulk composition; the MgO/FeO ratios range from 1.7 in the more mafic cordierite-gedrite rocks to 0.49 in potassic feldspar-bearing cordierite-garnet gneisses. Cordierite is magnesium-rich and intermediate in the range of composition of all analyzed cordierites (Leake, 1960); its MgO/FeO ratio is higher in the gedrite-bearing gneisses than in the potassic feldspar-bearing gneisses. The garnets consist dominantly of the almandine and pyrope molecules, and range from 64 to 75 percent almandine and from 14 to 27 pyrope. These crystals are zoned; their rims are slightly more ferrous and less magnesian than their cores. Both monoclinic and triclinic alkali feldspars coexist in the potassic feldspar-bearing cordierite-garnet gneisses. The potassic feldspars contain from 18 to 27 weight percent NaAlSi 3 O 8 . Plagioclase (oligoclase-andesine) is uncommon in the rocks. Gedrite has an MgO/FeO ratio ranging from 1 to 1.2. Associated minor minerals include iron oxides, andalusite, spinel and its alteration product högbomite, and corundum. The mineral assemblages can be correlated imperfectly with episodes of deformation and metamorphism. Relict staurolite and associated garnet occur locally as remnants of an assemblage formed early in regional metamorphism, presumably early in the first period of deformation. The dominant assemblage biotite-cordierite-garnet-magnetite-plagioclase-potassic feldspar-quartz-sillimanite and associated assemblages having fewer phases, were formed during period one and period two deformations, the principal episodes of regional dynamothermal metamorphism in the central part of the Front Range. A minor assemblage andalusite-biotite-magnetite-plagioclase-quartz was formed later, possibly coincident with a third period of deformation, largely cataclastic in effects, which was more local than the earlier deformations and metamorphism. Phase equilibria studies of the assemblage biotite-cordierite-garnet-magnetite-plagioclase-potassic feldspar-quartz-sillimanite and associated assemblages are interpreted to indicate that the cordierite assemblages approach a state of chemical equilibrium. The scatter of points in a distribution diagram can be interpreted in terms of at least two sets of equilibrium conditions that prevailed during the major plastic deformations. Other discrepancies indicating departure from a homogeneous equilibrium can be explained as a result of mosaic equilibrium involving limited diffusion of iron and magnesium for short distances. The mineral assemblages and the compositions of the ferromagnesian minerals in the cordierite rocks of this region are dependent primarily on the bulk composition of the rocks and variations in the mineral species that comprise the rocks and, to a lesser degree, on the grade of metamorphism. Biotite and cordierite are markedly more magnesian in the more mafic cordierite-gedrite-biotite gneiss than in the potassic feldspar-bearing cordierite-garnet-sillimanite-biotite gneiss. Associated microcline gneiss and biotite-sillimanite gneiss that contains muscovite as a primary stable mineral provides a means to define the metamorphic grade in the area of study. It is concluded from analyses of the assemblages with respect to theoretical phase relations in the system SiO 2 -Al 2 O 3 -Na 2 O-K 2 O-H 2 O that at least some of the rocks in the Central City-Nederland area are above the sillimanite-potassic feldspar isograd as defined by Evans and Guidotti (1966). In rocks of appropriate composition, muscovite is a stable phase in assemblages containing potassic feldspar and sillimanite. The cordierite assemblages and associated rocks are inferred to have formed in an environment having a load pressure of 3–5 kilobars (fluid pressure equaled load pressure) and a temperature somewhat in excess of 620° C.

Colorado↗

USGS1964

Studies of pre-Selma Cretaceous core samples from the outcrop area in western Alabama

In 1954 four core holes were drilled in the pre-Selma Cretaceous strata of the Alabama Coastal Plain in order to get unweathered samples within a few miles of the outcrops. During the next few years several specialists studied the cores, and their reports are published as consecutive parts of this bulletin. Watson H. Monroe, who spent many years studying the Coastal Plain strata in Alabama and Mississippi, conceived and supervised the drilling and planned the later studies. His earlier published report (W. H. Monroe, 1955, Cores of pre-Selma Cretaceous rocks in the outcrop area in western Alabama: Gulf Coast Geol. Societies Trans., v. 5, p. 11-37) contains a brief description of the stratigraphy, together with logs and other information regarding the core holes, and he has provided the introductory chapter to this bulletin. Richard E. Bergenback studied the petrology of the cores, which included finding the distribution of grain sizes, determining the mineralogy of the grains and the matrix of the sediments, and having X-Ray identifications made of the clay minerals. Norman F. Sohl studied the mollusks and other large fossils obtained from the cores and compared them with other faunal suites collected in Alaban1a and Texas. Esther R. Applin studied the sparse microfauna, comparing it with faunas obtained from deep wells downdip in Georgia, Alabama, and Mississippi and with outcrop samples fron1 Texas, and has described a new species of Foraminifera. Estella B. Leopold and Helen M. Pakiser obtained a large pollen and spore assemblage by digesting carbonaceous layers of some of the cores in acid; this flora includes much new material, which is not described here. The Bergenback, Sohl, and Applin reports discuss the probable environment in which the sediments accumulated. Louis C. Conant, who spent several years studying and mapping these sediments, has written a summary chapter integrating some of the surface and subsurface information. Quarter-cuts of the cores belonging to the U.S. National Museum have been deposited on indefinite loan with the Alabama Geological Survey at University, Ala., and with the Shell Oil Co. at Jackson, Miss. They are available there for inspection and study.

Bulletin↗

USGS2002

Atlas of water resources in the Black Hills area, South Dakota

The Black Hills area is an important resource center that provides an economic base for western South Dakota through tourism, agriculture, the timber industry, and mineral resources. In addition, water originating from the area is used for municipal, industrial, agricultural, and recreational purposes throughout much of western South Dakota. The Black Hills area also is an important recharge area for aquifers in the northern Great Plains. Population growth, resource development, and periodic droughts have the potential to affect the quantity, quality, and availability of water within the Black Hills area. Growth has resulted in competing interests for available water supplies. The Black Hills Hydrology Study was initiated in 1990 to address these concerns. This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators.

Hydrologic Atlas↗

USGS2012

Linkages between denitrification and dissolved organicmatter quality, Boulder Creek watershed, Colorado

Dissolved organic matter (DOM) fuels the majority of in-stream microbial processes, including the removal of nitrate via denitrification. However, little is known about how the chemical composition of DOM influences denitrification rates. Water and sediment samples were collected across an ecosystem gradient, spanning the alpine to plains, in central Colorado to determine whether the chemical composition of DOM was related to denitrification rates. Laboratory bioassays measured denitrification potentials using the acetylene block technique and carbon mineralization via aerobic bioassays, while organic matter characteristics were evaluated using spectroscopic and fractionation methods. Denitrification potentials under ambient and elevated nitrate concentrations were strongly correlated with aerobic respiration rates and the percent mineralized carbon, suggesting that information about the aerobic metabolism of a system can provide valuable insight regarding the ability of the system to additionally reduce nitrate. Multiple linear regressions (MLR) revealed that under elevated nitrate concentrations denitrification potentials were positively related to the presence of protein-like fluorophores and negatively related to more aromatic and oxidized fractions of the DOM pool. Using MLR, the chemical composition of DOM, carbon, and nitrate concentrations explained 70% and 78% of the observed variability in denitrification potential under elevated and ambient nitrate conditions, respectively. Thus, it seems likely that DOM optical properties could help to improve predictions of nitrate removal in the environment. Finally, fluorescence measurements revealed that bacteria used both protein and humic-like organic molecules during denitrification providing further evidence that larger, more aromatic molecules are not necessarily recalcitrant in the environment.

Colorado↗

USGS2017

Emplacement of Holocene silicic lava flows and domes at Newberry, South Sister, and Medicine Lake volcanoes, California and Oregon

This field guide for the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly 2017 focuses on Holocene glassy silicic lava flows and domes on three volcanoes in the Cascade Range in Oregon and California: Newberry, South Sister, and Medicine Lake volcanoes. Although obsidian-rich lava flows have been of interest to geologists, archaeologists, pumice miners, and rock hounds for more than a century, many of their emplacement characteristics had not been scientifically observed until two very recent eruptions in Chile. Even with the new observations, several eruptive processes discussed in this field trip guide can only be inferred from their final products. This makes for lively debates at outcrops, just as there have been in the literature for the past 30 years. Of the three volcanoes discussed in this field guide, one (South Sister) lies along the main axis defined by major peaks of the Cascade Range, whereas the other two lie in extensional tectonic settings east of the axis. These two tectonic environments influence volcano morphology and the magmatic and volcanic processes that form silicic lava flows and domes. The geomorphic and textural features of glass-rich extrusions provide many clues about their emplacement and the magma bodies that fed them. The scope of this field guide does not include a full geologic history or comprehensive explanation of hazards associated with a particular volcano or volcanic field. The geochemistry, petrology, tectonics, and eruption history of Newberry, South Sister, and Medicine Lake volcanic centers have been extensively studied and are discussed on other field excursions. Instead, we seek to explore the structural, textural, and geochemical evolution of well-preserved individual lava flows—the goal is to understand the geologic processes, rather than the development, of a specific volcano.

California, Oregon↗

USGS2017

Preliminary assessment of porphyry copper deposits in the Sierra Maestra, Cuba

The U.S. Geological Survey’s “three-step” form of mineral-resource assessment was used to obtain a preliminary estimate of copper resources in undiscovered porphyry deposits of the Paleogene Sierra Maestra Arc. Results of this preliminary assessment suggest that a mean of 3.2 undiscovered deposits are likely present. This estimate is comparable to results from an independently-derived porphyry deposit density model, which points to 3.9 undiscovered deposits. Monte Carlo simulation results further show that the mean estimate of undiscovered copper resources in this porphyry copper tract is in the order of 12 million metric tons. Notwithstanding having been a relatively short-lived (20-25 Ma) magmatic event, the Sierra Maestra Arc was a particularly favorable environment for the formation of porphyry copper deposits.

Conference Paper↗

USGS2016

Organic petrology and geochemistry of Eocene Suzak bituminous marl, north-central Afghanistan: Depositional environment and source rock potential

Organic geochemistry and petrology of Eocene Suzak bituminous marl outcrop samples from Madr village in north-central Afghanistan were characterized via an integrated analytical approach to evaluate depositional environment and source rock potential. Multiple proxies suggest the organic-rich (TOC ∼6 wt.%) bituminous marls are ‘immature’ for oil generation (e.g., vitrinite R o < 0.4%, T max < 425 °C, PI ≤ 0.05, C 29 ααα S/S + R ≤ 0.12, C 29 ββS/ββS+ααR ≤ 0.10, others), yet oil seeps are present at outcrop and live oil and abundant solid bitumen were observed via optical microscopy. Whole rock sulfur content is ∼2.3 wt.% whereas sulfur content is ∼5.0–5.6 wt.% in whole rock extracts with high polar components, consistent with extraction from S-rich Type IIs organic matter which could generate hydrocarbons at low thermal maturity. Low Fe-sulfide mineral abundance and comparison of Pr/Ph ratios between saturate and whole extracts suggest limited Fe concentration resulted in sulfurization of organic matter during early diagenesis. From these observations, we infer that a Type IIs kerogen in ‘immature’ bituminous marl at Madr could be generating high sulfur viscous oil which is seeping from outcrop. However, oil-seep samples were not collected for correlation studies. Aluminum-normalized trace element concentrations indicate enrichment of redox sensitive trace elements Mo, U and V and suggest anoxic-euxinic conditions during sediment deposition. The bulk of organic matter observed via optical microscopy is strongly fluorescent amorphous bituminite grading to lamalginite, possibly representing microbial mat facies. Short chain n- alkanes peak at C 14 –C 16 ( n- C 17 / n- C 29 > 1) indicating organic input from marine algae and/or bacterial biomass, and sterane/hopane ratios are low (0.12–0.14). Monoaromatic steroids are dominated by C 28 clearly indicating a marine setting. High gammacerane index values (∼0.9) are consistent with anoxia stratification and may indicate intermittent saline-hypersaline conditions. Stable C isotope ratios also suggest a marine depositional scenario for the Suzak samples, consistent with the presence of marine foraminifera including abundant planktic globigerinida (?) and rare benthic discocyclina (?) and nummulites (?). Biomarker 2α-methylhopane for photosynthetic cyanobacteria implies shallow photic zone deposition of Madr marls and 3β-methylhopane indicates presence of methanotrophic archaea in the microbial consortium. The data presented herein are consistent with deposition of Suzak bituminous marls in shallow stratified waters of a restricted marine basin associated with the southeastern incipient or proto-Paratethys. Geochemical proxies from Suzak rock extracts (S content, high polar content, C isotopes, normal (αααR) C 27–29 steranes, and C 29 /C 30 and C 26 /C 25 hopane ratios) are similar to extant data from Paleogene oils produced to the north in the Afghan-Tajik Basin. This observation may indicate laterally equivalent strata are effective source rocks as suggested by previous workers; however, further work is needed to strengthen oil-source correlations.

Marine and Petroleum Geology↗

USGS2015

Organic sedimentation in modern lacustrine systems: A case study from Lake Malawi, East Africa

This study examines the relationship between depositional environment and sedimentary organic geochemistry in Lake Malawi, East Africa, and evaluates the relative significance of the various processes that control sedimentary organic matter (OM) in lacustrine systems. Total organic carbon (TOC) concentrations in recent sediments from Lake Malawi range from 0.01 to 8.80 wt% and average 2.83 wt% for surface sediments and 2.35 wt% for shallow core sediments. Hydrogen index (HI) values as determined by Rock-Eval pyrolysis range from 0 to 756 mg HC g−1 TOC and average 205 mg HC g−1 TOC for surface sediments and 228 mg HC g−1 TOC for shallow core samples. On average, variations in primary productivity throughout the lake may account for ~33% of the TOC content in Lake Malawi sediments (as much as 1 wt% TOC), and have little or no impact on sedimentary HI values. Similarly, ~33% to 66% of the variation in TOC content in Lake Malawi sediments appears to be controlled by anoxic preservation of OM (~1–2 wt% TOC), although some component of the water depth–TOC relationship may be due to physical sediment transport processes. Furthermore, anoxic preservation has a minimal effect on HI values in Lake Malawi sediments. Dilution of OM by inorganic sediment may account for ~16% of variability in TOC content in Lake Malawi sediments (~0.5 wt% TOC). The effect of inputs of terrestrial sediment on the organic character of surface sediments in these lakes is highly variable, and appears to be more closely related to the local depositional environment than the regional flux of terrestrial OM. Total nitrogen and TOC content in surface sediments collected throughout the lake are found to be highly correlated (r2 = 0.95), indicating a well-homogenized source of OM to the lake bottom. The recurring suspension and deposition of terrestrial sediment may account for significant amounts of OM deposited in offshore regions of the lake. This process effectively separates denser inorganic sediment from less dense OM and allows terrestrial OM to preferentially be transported farther offshore. The conclusion is that for the organic carbon content in these regions to be elevated a mixed terrestrial-lacustrine origin is required. The hydrodynamic separation of mineral and organic constituents is most pronounced in regions with shallow bathymetric gradients, consistent with previous findings from Lake Tanganyika.

Lake Malawi↗

USGS2006

Regional evaluation of the hydrogeologic framework, hydraulic properties, and chemical characteristics of the intermediate aquifer system underlying southern west-central Florida

Three major aquifer systems-the surficial aquifer system, the intermediate aquifer system, and the Floridan aquifer system-are recognized in the approximately 5,100-square-mile southern west-central Florida study area. The principal source of freshwater for all uses is ground water supplied from the three aquifer systems. Ground water from the intermediate aquifer system is considered only moderately abundant compared to the Upper Floridan aquifer, but it is an important source of water where the Upper Floridan aquifer contains water too mineralized for most uses. In the study area, the potential ground-water resources of the intermediate aquifer system were evaluated by regionally assessing the vertical and lateral distribution of hydrogeologic, hydraulic, and chemical characteristics. Although the intermediate aquifer system is considered a single entity, it is composed of multiple water-bearing zones separated by confining units. Deposition of a complex assemblage of carbonate and siliciclastic sediments during the late Oligocene to early Pliocene time resulted in discontinuities that are reflected in transitional and abrupt contacts between facies. Discontinuous facies produce water-bearing zones that may be locally well-connected or culminate abruptly. Changes in the depositional environment created the multilayered intermediate aquifer system that contains as many as three zones of enhanced water-bearing capacity. The water-bearing zones consist of indurated limestone and dolostone and in some places unindurated sand, gravel, and shell beds, and these zones are designated, in descending order, as Zone 1, Zone 2, and Zone 3. Zone 1 is thinnest (<80 feet thick) and is limited to <20 percent (southern part) of the study area. Zone 2, the only regionally extensive zone, is characterized by moderately low permeability. Zone 3 is found in about 50 percent of the study area, has the highest transmissivities, and generally is in good hydraulic connection with the underlying Upper Floridan aquifer. In parts of the study area, particularly in southwestern Hillsborough County and southeastern De Soto and Charlotte Counties, Zone 3 likely is contiguous with and part of the Upper Floridan aquifer. Transmissivity of the intermediate aquifer system ranges over five orders of magnitude from about 1 to more than 40,000 feet squared per day (ft2/d), but rarely exceeds 10,000 ft2/d. The overall transmissivity of the intermediate aquifer system is substantially lower (2 to 3 orders of magnitude) than the underlying Upper Floridan aquifer. Transmissivity varies vertically among the zones within the intermediate aquifer system; Zone 2 has the lowest median transmissivity (700 ft2/d), Zone 1 has a moderate median transmissivity (2,250 ft2/d), and Zone 3 has the highest median transmissivity (3,400 ft2/d). Additionally, the transmissivity varies geographically (from site to site) within a zone. Specifically, a region of relatively low transmissivity (<100 ft2/d) throughout the vertical extent of the intermediate aquifer system is present in the central part of the study area. This low transmissivity region is encompassed by a larger region of moderately low transmissivity (<1,000 ft2/d) that covers a large part of the study area. Clay beds and fine-grained carbonates form the confining units between the water-bearing zones and are characterized by low leakance. Leakance through the intermediate aquifer system confining units ranges over 4 orders of magnitude from 4.2x10-7 to 6.0x10-3 feet per day per foot [(ft/d)/ft]. Despite the large range, the geometric mean and median leakances of individual confining units are within the same order of magnitude, 10-5 (ft/d)/ft, which is 2 orders of magnitude less than the median leakance of the semiconfining unit within the Upper Floridan aquifer. Major ion concentrations in water from the intermediate aquifer system, and throughout the ground-water flow system, generally increase with depth. T

Scientific Investigations Report↗

USGS2017

User guide for luminescence sampling in archaeological and geological contexts

Luminescence dating provides a direct age estimate of the time of last exposure of quartz or feldspar minerals to light or heat and has been successfully applied to deposits, rock surfaces, and fired materials in a number of archaeological and geological settings. Sampling strategies are diverse and can be customized depending on local circumstances, although all sediment samples need to include a light-safe sample and material for dose-rate determination. The accuracy and precision of luminescence dating results are directly related to the type and quality of the material sampled and sample collection methods in the field. Selection of target material for dating should include considerations of adequacy of resetting of the luminescence signal (optical and thermal bleaching), the ability to characterize the radioactive environment surrounding the sample (dose rate), and the lack of evidence for post-depositional mixing (bioturbation in soils and sediment). Sample strategies for collection of samples from sedimentary settings and fired materials are discussed. This paper should be used as a guide for luminescence sampling and is meant to provide essential background information on how to properly collect samples and on the types of materials suitable for luminescence dating.

Advances in Archaeological Practice: A Journal of ↗

USGS2009

The Drenchwater deposit, Alaska: An example of a natural low pH environment resulting from weathering of an undisturbed shale-hosted Zn-Pb-Ag deposit

The Drenchwater shale-hosted Zn-Pb-Ag deposit and the immediate vicinity, on the northern flank of the Brooks Range in north-central Alaska, is an ideal example of a naturally low pH system. The two drainages, Drenchwater and False Wager Creeks, which bound the deposit, differ in their acidity and metal contents. Moderately acidic waters with elevated concentrations of metals (pH ??? 4.3, Zn ??? 1400 ??g/L) in the Drenchwater Creek drainage basin are attributed to weathering of an exposed base-metal-rich massive sulfide occurrence. Stream sediment and water chemistry data collected from False Wager Creek suggest that an unexposed base-metal sulfide occurrence may account for the lower pH (2.7-3.1) and very metal-rich waters (up to 2600 ??g/L Zn, ??? 260 ??g/L Cu and ???89 ??g/L Tl) collected at least 2 km upstream of known mineralized exposures. These more acidic conditions produce jarosite, schwertmannite and Fe-hydroxides commonly associated with acid-mine drainage. The high metal concentrations in some water samples from both streams naturally exceed Alaska state regulatory limits for freshwater aquatic life, affirming the importance of establishing base-line conditions in the event of human land development. The studies at the Drenchwater deposit demonstrate that poor water quality can be generated through entirely natural weathering of base-metal occurrences, and, possibly unmineralized black shale.

Applied Geochemistry↗

USGS1969

Massive sulfide deposits and volcanism

Massive sulfide deposits, consisting of pyrite and/or pyrrhotite and various ratios of chalcopyrite, sphalerite, and galena, are commonly associated with volcanic rocks that accumulated in eugeosynclines. Later deformation may leave an imprint of regional metamorphism. Two-thirds of the deposits mentioned in this review are about equally divided between silicic and mafic volcanic host rocks, and the remainder occur in tuffaceous sedimentary rocks interbedded with volcanics. Little compelling evidence is available to relate genetically most of these deposits to granitic rocks, whereas considerable evidence supports a complex genetic relationship to volcanic rocks that accumulated in a submarine environment. Some deposits apparently formed during or soon after emplacement of the volcanic rocks, and possibly involved early deposition of pyrite that was followed later by the addition of base metals. The transporting agents of the base metals and some of the sulfur are heated solutions probably of different origins containing alkali chlorides as well as alkali chloride brines. Pyrite and base metals may have been deposited during the accumulation of the volcanic and associated rocks, or later during diagenesis, regional metamorphism, or intrusion of granitic plutons. The source of the base metals may have been: (1) early metal concentrations distributed through the volcanic pile, (2) trace quantities in the silicate minerals in the volcanics, or (3) later crystallizing magma.

Economic Geology↗

USGS1989

Hydrothermal discharge zones beneath massive sulfide deposits mapped in the Oman ophiolite

The area in the Oman ophiolite containing the volcanic-hosted Bayda and Aarja massive sulfide deposits exposes a cross section of ocean crust and reveals to an unprecedented extent the fossil zones of hydrothermal upwelling that fed these sea-floor deposits. The fossil discharge zones are elongate areas of alteration and mineralization characterized by numerous small (metres to tens of metres in length), linear, discontinuous gossans. The gossans result from oxidation of hydrothermal pyrite replacing primary igneous phases and filling voids and fractures in the altered host rocks. The two deposits have separate discharge zones that appear to be sub-sea-floor extensions of their stockworks. The Bayda zone extends through the volcanic section into the upper sheeted dike complex and is interpreted as having formed on the ridge crest above an axial magma chamber; the Aarja zone terminates against a plagiogranite pluton that intrudes the lower volcanic section and is thought to have formed after Bayda in an off-axis environment. Structural, stratigraphic, and compositional characteristics of the Bayda and Aarja massive sulfide bodies are consistent with this interpretation. The geometry of the discharge zones suggests that in both cases upfiow occurred in broad zones (at least 400-600 m wide) that were elongated along strike (i.e., parallel to the spreading axis).

Oman ophiolite↗