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At least 685 records · Page 38Linked to original sources
USGS2002

SHRIMP U-Pb and 40Ar/39Ar age constraints for relating plutonism and mineralization in the Boulder batholith region, Montana

The composite Boulder batholith, Montana, hosts a variety of mineral deposit types, including important silver-rich polymetallic quartz vein districts in the northern part of the batholith and the giant Butte porphyry copper-molybdenum pre-Main Stage system and crosscutting copper-rich Main Stage vein system in the southern part of the batholith. Previous dating studies have identified ambiguous relationships among igneous and mineralizing events. Mineralizing hydrothermal fluids for these types of deposits and magma for quartz porphyry dikes at Butte have all been considered to be late-stage differentiates of the Boulder batholith. However, previous dating studies indicated that the Boulder batholith plutons cooled from about 78 to 72 Ma, whereas copper-rich Main Stage veins at Butte were dated at about 61 Ma. Recent efforts to date the porphyry copper-molybdenum pre-Main Stage deposits at Butte resulted in conflicting estimates of both 64 and 76 Ma for the mineralizing events. Silver-rich polymetallic quartz vein deposits elsewhere in the batholith have not been dated previously. To resolve this controversy, we used the U.S. Geological Survey, Stanford, SHRIMP RG ion microprobe to date single-age domains within zircons from plutonic rock samples and 40 Ar/ 39 Ar geochronology to date white mica, biotite, and K-feldspar from mineral deposits. U-Pb zircon ages are Rader Creek Granodiorite, 80.4 ± 1.2 Ma; Unionville Granodiorite, 78.2 ± 0.8 Ma; Pulpit Rock granite, 76.5 ± 0.8 Ma; Butte Granite, 74.5 ± 0.9 Ma; altered Steward-type quartz porphyry dike (I-15 roadcut), 66.5 ± 1.0 Ma; altered Steward-type quartz porphyry dike (Continental pit), 65.7 ± 0.9 Ma; and quartz monzodiorite of Boulder Baldy (Big Belt Mountains), 66.2 ± 0.9 Ma. Zircons from Rader Creek Granodiorite and quartz porphyry dike samples contain Archean inheritance. The 40 Ar/ 39 Ar ages are muscovite, silver-rich polymetallic quartz vein (Basin district), 74.4 ± 0.3 Ma; muscovite, silver-rich polymetallic quartz vein (Boulder district), 74.4 ± 1.2 Ma; muscovite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; biotite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; potassium feldspar, early dark micaceous vein (Continental pit), 63 to 59 Ma; and biotite, biotite breccia dike (Continental pit), 63.6 ± 0.2 Ma. Outlying silver-rich polymetallic quartz veins of the Basin and Boulder mining districts probably are directly related to the 74.5 Ma Butte Granite, whereas Steward-type east-west quartz porphyry dikes and Butte pre-Main Stage deposits are parts of a 66 to 64 Ma magmatic-mineralization system unrelated to emplacement of the Boulder batholith. The age of the crosscutting Main Stage veins may be about 61 Ma as originally reported but can only be bracketed as younger than the 64 Ma pre-Main Stage mineralization and older than the about 50 Ma Eocene Lowland Creek intrusions. The 66 Ma age for the quartz monzodiorite of Boulder Baldy and consideration of previous dating studies in the region indicate that small ca. 66 Ma plutonic systems may be common in the Boulder batholith region and especially to the east. The approximately 64 Ma porphyry copper systems at Butte and gold mineralization at Miller Mountain are indicative of regionally important mineralizing systems of this age in the Boulder batholith region. Resolution of the age and probable magmatic source of the Butte pre-Main Stage porphyry copper-molybdenum system and of the silver-rich polymetallic quartz vein systems in the northern part of the Boulder batholith documents that these deposits formed from two discrete periods of hydrothermal mineralization related to two discrete magmatic events.

Montana↗
USGS1953

Iron deposits of the congonhas district, minas Gerais, Brazil

Various origins have been proposed for the itabirite and associated hematite ores of Minas Gerais, Brazil. The U.S. Geological Survey, in cooperation with the Brazilian Departamento Nacional da Produqao Mineral, has undertaken a comprehensive program of mapping of these Precambrian deposits, which bear many similarities to other Precambrian iron formations. Itabirite is a finely laminated quartz-iron oxide rock with more or less dolomite, corresponding to James's oxide facies. It occurs principally in the middle group of the Minas series-a eugeosynclinal assemblage of quartzite, schist, chemical precipitates, graywacke, and volcanic rocks. Iron and silica were precipitated rhythmically in a shallow restricted basin under somewhat acid conditions that inhibited the precipitation of carbonates. Erosion of moderately deformed rocks of the Minas series furnished sediments for the overlying conglomeratic Itacolumi series. Severe post-Itacolumi deformation folded and thrust-faulted rocks of both series; the accompanying regional metamorphism recrystallized the chert and iron oxide to quartz, specular hematite, and minor amounts of magnetite. Ultramafic intrusions antedate this diastrophism; granodiorites and various basic dike rocks are younger. Hydrothermal replacement of breccia zones in itabirite and of dolomitic beds associated with the iron formation produced high-grade specular hematite ore nearly free of impurities. The areal distribution of the deposits indicates that the solutions followed fault zones. Heated meteoric water may have been responsible for the replacement, as minerals of obvious magmatic origin are absent. Since early Tertiary time the area has been uplifted several thousand feet. Leaching and cementation related to the present surface have modified both the iron formation and the hematite deposits, giving rise to various types of commercial ore. © 1953 Society of Economic Geologists, Inc.

Economic Geology↗
USGS1984

Textural and stable isotope studies of the Big Mike cupriferous volcanogenic massive sulfide deposit, Pershing County, Nevada

The massive ore contains two major generations of pyrite, a fine and a coarse grained, both of which show a striking variety of textures involving quartz. Framboidal pyrite in the argillite host rock has delta 34 S values of approximately -24 per mil indicating the presence of a euxinic environment. The delta 34 S values of fine-grained pyrite in the massive ore range from degrees 6.4 to + or -2.0 per mil; those of coarse-grained pyrite range from -3.5 to + or -5.5 per mil. A significant portion of the isotopically light sulfur for the early, fine-grained hydrothermal pyrite in the massive lens was probably derived from framboidal biogenic pyrite in interflow sediments of the underlying greenstone pillow lavas. Microcrystalline quartz in massive ore, hanging-wall jasper, footwall hydrothermal chert and coarse quartz from hanging-wall and footwall stringer zones have delta 18 O values between 15.6 and 19.6 per mil; one sample of vein hematite has a value of 4.4 per mil. The combined sulfur and oxygen isotope and textural data indicate that much of the material in the massive lens originally precipitated as fine-grained pyrite or as a precursor iron sulfide along with some silica from a hydrothermal plume similar to those recently observed at the East Pacific Rise spreading center at lat 21 degrees N. The primary material underwent recrystallization, mineralization, and late-stage quartz deposition in the presence of later fluids which had distinctly different sulfur isotope compositions.

Economic Geology↗
USGS1994

Fluid chemistry evolution and mineral deposition in the main-stage Creede epithermal system

This paper presents results of chemical speciation and reaction path calculations that model fluid chemistry evolution and ore deposition in the main-stage Creede, Colorado, epithermal system. An extensive geologic, mineralogic, and geochemical framework for mineralization has been developed by many researchers for the central and southern district vein systems (OH and P veins; central and southern Amethyst and Bulldog Mountain vein systems) and is used to constrain and guide the modeling presented in this paper. Previous studies have shown that the central base metal sulfide-rich and southern barite- and silver-rich Creede ores were deposited by hydrothermal brines with temperatures as high as 285 degrees C and salinities as high as 13 wt percent NaCl equiv. Fluid inclusion studies indicate that mixing with dilute steam-heated ground waters was the dominant ore deposition mechanism, although boiling did occur during some stages. Speciation calculations confirm that the hydrothermal fluids, due to their high salinities, were relatively acidic (pH near 5.5) and transported significant quantities of base metals (i.e., up to 10-2 m total concentrations of Zn) as chloride complexes. Reaction path calculations show that strong north-south mineralogical variations in main-stage mineralization are best accounted for by variable boiling of the hydrothermal brines, followed by lateral mixing of the brines with overlying dilute, steam-heated ground waters. The extent of boiling prior to mixing was a function of the temperature and gas contents of the hydrothermal fluids as they first entered the district ore zones from depth, and of the thickness of the steam-heated ground-water column overlying the hydrothermal fluids. The calculations indicate that limited amounts of boiling (during stages when the overlying ground-water column was relatively thick) produced a chlorite-pyrite-hematite-sphalerite-galena-chalcopyrite + or - adularia assemblage in the central district vein systems (OH and P veins; central Amethyst and Bulldog Mountain vein systems). More extensive boiling (during a stage in which the ground-water table apparently dropped considerably) deposited quartz, fluorite, adularia, and hematite with only minor sulfides in the central district veins. Boiling ceased when the saturation pressure of the hydrothermal fluids dropped below hydrostatic pressures generated by the overlying ground-water column. Following boiling, lateral mixing with overlying steam-heated ground waters initially produced sphalerite- and galena-rich assemblages in the central district vein systems. With continued mixing to the south, the hydrothermal fluids deposited abundant barite, subordinate sphalerite, galena, and quartz, and lesser native silver, acanthite, and sulfosalts in the district's southern vein systems (southern Amethyst, southern Bulldog Mountain vein systems).Modeling results for Creede and other epithermal fluid compositions show that epithermal ore grades, mineral assemblages, and mineral zoning patterns are strongly influenced by shallow hydrologic processes such as boiling and fluid mixing. As a result, epithermal mineral assemblages and zoning patterns can be used to reconstruct the paleohydrology of the hydrothermal systems from which they were deposited, and thus provide useful tools for epithermal ore exploration.

Economic Geology↗
USGS1989

Ground-water hydrology of the central Raton Basin, Colorado and New Mexico

The watersheds of the Purgatoire and Apishapa Rivers contain most of the public coal lands in the Raton Basin. The U.S. Geological Survey, in cooperation with the U.S. Bureau of Land Management, investigated the hydrogeology of this area from 1978 to 1982, inventorying 231 wells, 38 springs, and 6 mines, and collecting ground-water samples from 71 sites. The Raton Basin is an asymmetrical trough, containing 10,000 to 25,000 feet of sedimentary rocks that range in age from Pennsylvanian to Eocene. These rocks are intruded by Miocene igneous rocks, covered with Pleistocene and Holocene alluvium on pediments and in stream valleys, and underlain by Precambrian crystalline rocks. Bituminous coal occurs in the Vermejo and Raton Formations of Cretaceous and Paleocene age. Virtually all of the sedimentary rocks transmit water. Stream alluvium is the most productive aquifer. Bedrock aquifers have smaller yields but greater distribution. The principal bedrock aquifers are the Cuchara-Poison Canyon and the Raton-Vermejo-Trinidad. Other formations are nearly impermeable or too deep to be utilized economically. The Cuchara-Poison Canyon aquifer provides small, nonsustainable yields to wells. Sandstone and coal layers in the Raton-Vermejo-Trinidad aquifer provide small, sustainable yields, but many of these beds are lenticular and can be missed easily by wells. Water in alluvium typically is less mineralized than in bedrock but more susceptible to contamination. Sodium and calcium bicarbonate waters predominate in the area, but sodium chloride water commonly occurs in the Cuchara-Poison Canyon aquifer and may occur in the Pierre Shale. Plumes of sulfate-enriched water extend from coal mines into bedrock and alluvial aquifers. Dissolved-solids concentrations range from less than 500 milligrams per liter in calcium bicarbonate water to more than 1,500 milligrams per liter in sulfate and chloride waters. Much of the ground water is hard. Nitrogen is enriched in shallow ground water, and fluoride is enriched in deeper ground water. Levels of iron, manganese, zinc, and selenium locally exceed standards for domestic consumption. The Purgatoire River and its tributaries are predominantly gaining streams, but losing reaches occur. Water quality in streams is affected by tributary inflows, mine discharge, contact with and seepage from tailings, groundwater seepage, diversion ditches, and changes in stage. Ground water flows regionally from west to east and locally from stream divides to valleys. Depths to water vary from 500 feet beneath divides to less than 100 feet in valleys. Springs typically develop where valleys intersect the water table, at or below the contact between the Poison Canyon and Raton Formations, and in stream channels that are crossed by dikes or sills or underlain by shallow bedrock. Most of the water in regional circulation discharges into surface drainages before reaching the east side of the basin. Groundwater supplies probably are insufficient for expanded settlement and coal mining.

Water Supply Paper↗
USGS2003

Typing mineral deposits using their grades and tonnages in an artificial neural network

A test of the ability of a probabilistic neural network to classify deposits into types on the basis of deposit tonnage and average Cu, Mo, Ag, Au, Zn, and Pb grades is conducted. The purpose is to examine whether this type of system might serve as a basis for integrating geoscience information available in large mineral databases to classify sites by deposit type. Benefits of proper classification of many sites in large regions are relatively rapid identification of terranes permissive for deposit types and recognition of specific sites perhaps worthy of exploring further. Total tonnages and average grades of 1,137 well-explored deposits identified in published grade and tonnage models representing 13 deposit types were used to train and test the network. Tonnages were transformed by logarithms and grades by square roots to reduce effects of skewness. All values were scaled by subtracting the variable's mean and dividing by its standard deviation. Half of the deposits were selected randomly to be used in training the probabilistic neural network and the other half were used for independent testing. Tests were performed with a probabilistic neural network employing a Gaussian kernel and separate sigma weights for each class (type) and each variable (grade or tonnage). Deposit types were selected to challenge the neural network. For many types, tonnages or average grades are significantly different from other types, but individual deposits may plot in the grade and tonnage space of more than one type. Porphyry Cu, porphyry Cu-Au, and porphyry Cu-Mo types have similar tonnages and relatively small differences in grades. Redbed Cu deposits typically have tonnages that could be confused with porphyry Cu deposits, also contain Cu and, in some situations, Ag. Cyprus and kuroko massive sulfide types have about the same tonnages. Cu, Zn, Ag, and Au grades. Polymetallic vein, sedimentary exhalative Zn-Pb, and Zn-Pb skarn types contain many of the same metals. Sediment-hosted Au, Comstock Au-Ag, and low-sulfide Au-quartz vein types are principally Au deposits with differing amounts of Ag. Given the intent to test the neural network under the most difficult conditions, an overall 75% agreement between the experts and the neural network is considered excellent. Among the largestclassification errors are skarn Zn-Pb and Cyprus massive sulfide deposits classed by the neuralnetwork as kuroko massive sulfides—24 and 63% error respectively. Other large errors are the classification of 92% of porphyry Cu-Mo as porphyry Cu deposits. Most of the larger classification errors involve 25 or fewer training deposits, suggesting that some errors might be the result of small sample size. About 91% of the gold deposit types were classed properly and 98% of porphyry Cu deposits were classes as some type of porphyry Cu deposit. An experienced economic geologist would not make many of the classification errors that were made by the neural network because the geologic settings of deposits would be used to reduce errors. In a separate test, the probabilistic neural network correctly classed 93% of 336 deposits in eight deposit types when trained with presence or absence of 58 minerals and six generalized rock types. The overall success rate of the probabilistic neural network when trained on tonnage and average grades would probably be more than 90% with additional information on the presence of a few rock types.

Natural Resources Research↗
USGS2003

Geology and geochemistry of the Reocín zinc-lead deposit, Basque-Cantabrian Basin, Northern Spain

The Reocín Zn-Pb deposit , 30 km southwest of Santander, Spain , occurs within Lower Cretaceous dolomitized Urgonian limestones on the southern flank of the Santillana syncline. The Reocín deposit is one of the largest known strata-bound, carbonate-hosted, zinc - lead deposits in Europe. The total metal endowment of the deposit , including past production and remaining reserves, is 62 Mt of ore grading 8.7 percent Zn and 1.0 percent Pb. The epigenetic mineralization consists of sphalerite and galena, with lesser marcasite and trace pyrite with dolomite as gangue. Microprobe analyses of different generations of dolomite revealed nonstoichiometric compositions with various amounts of iron (up to 14 mol % of FeCO 3 ). Replacement of host dolomite, open-space filling of fractures, and cementation of breccias derived from dissolution collapse are the principal types of ore occurrence. Detailed cross-section mapping indicates a stratigraphic and structural control on the deposit . A stratiform morphology is present in the western part of the orebody (Capa Sur), whereas mineralization in the eastern part is highly discordant but strata bound (Barrendera). Stratigraphic studies demonstrate that synsedimentary tectonic activity, related to the rifting of the North Atlantic (Bay of Biscay), was responsible for variation in sedimentation, presence of unconformities (including paleokarsts), local platform emergence and dolomitization along the N60 fault trend. In the Reocín area, two stages of dolomitization are recognized. The first stage is a pervasive dolomitization of the limestone country rocks that was controlled by faulting and locally affected the upper part of the Aptian and the complete Albian sequence. The second dolomitization event occurred after erosion and was controlled by karstic cavities. This later dolomitization was accompanied by ore deposition and, locally, filling of dolomite sands and clastic sediments in karstic cavities. The circulation of hydrothermal fluids responsible for sulfide deposition and the infilling of karst cavities were broadly contemporaneous, indicating a post-Albian age. Vitrinite reflectance data are consistent with previously measured fluid inclusion temperatures and indicate temperatures of ore deposition that were less than 100°C. Carbon and oxygen isotopic data from samples of regional limestone, host-rock dolostone and ore-stage dolomite suggest an early hydrothermal alteration of limestone to dolostone. This initial dolomitization was followed by a second period of dolomite formation produced by the mixing of basinal metal-rich fluids with local modified seawater. Both dolomitization events occurred under similar conditions from fluids exhibiting characteristics of basinal brines. The δ 34 S values of sulfides are between -1.8 and +8.5 per mil, which is consistent with thermochemical sulfate reduction involving organic matter as the main source of reduced sulfur. Galena lead isotope compositions are among the most radiogenic values reported for Zn-Pb occurrences in Europe, and they are distinct from values reported for galena from other Basque - Cantabrian deposits. This suggests that a significant part of the lead was scavenged from the local underlying Asturian sediments. The stratigraphic and structural setting, timing of epigenetic mineralization, mineralogy, and isotopic geochemistry of sulfide and gangue minerals of the Reocín deposit are consistent with the features of most of Mississippi Valley-type ore deposits.

northern Spain↗
USGS2017

Rare-earth elements

The rare-earth elements (REEs) are 15 elements that range in atomic number from 57 (lanthanum) to 71 (lutetium); they are commonly referred to as the “lanthanides.” Yttrium (atomic number 39) is also commonly regarded as an REE because it shares chemical and physical similarities and has affinities with the lanthanides. Although REEs are not rare in terms of average crustal abundance, the concentrated deposits of REEs are limited in number. Because of their unusual physical and chemical properties, the REEs have diverse defense, energy, industrial, and military technology applications. The glass industry is the leading consumer of REE raw materials, which are used for glass polishing and as additives that provide color and special optical properties to the glass. Lanthanum-based catalysts are used in petroleum refining, and cerium-based catalysts are used in automotive catalytic converters. The use of REEs in magnets is a rapidly increasing application. Neodymium-iron-boron magnets, which are the strongest known type of magnets, are used when space and weight are restrictions. Nickel-metal hydride batteries use anodes made of a lanthanum-based alloys. China, which has led the world production of REEs for decades, accounted for more than 90 percent of global production and supply, on average, during the past decade. Citing a need to retain its limited REE resources to meet domestic requirements as well as concerns about the environmental effects of mining, China began placing restrictions on the supply of REEs in 2010 through the imposition of quotas, licenses, and taxes. As a result, the global rare-earth industry has increased its stockpiling of REEs; explored for deposits outside of China; and promoted new efforts to conserve, recycle, and substitute for REEs. New mine production began at Mount Weld in Western Australia, and numerous other exploration and development projects noted in this chapter are ongoing throughout the world. The REE-bearing minerals are diverse and often complex in composition. At least 245 individual REE-bearing minerals are recognized; they are mainly carbonates, fluorocarbonates, and hydroxylcarbonates (n = 42); oxides (n = 59); silicates (n = 85); and phosphates (n = 26). Many of the world’s significant REE deposits occur in carbonatites, which are carbonate igneous rocks. The REEs also have a strong genetic association with alkaline magmatism. The systematic geologic and chemical processes that explain these observations are not well understood. Economic or potentially economic REE deposits have been found in (a) carbonatites, (b) peralkaline igneous systems, (c) magmatic magnetite-hematite bodies, (d) iron oxide-copper-gold (IOCG) deposits, (e) xenotime-monazite accumulations in mafic gneiss, (f) ion-absorption clay deposits, and (g) monazite-xenotime-bearing placer deposits. Carbonatites have been the world’s main source for the light REEs since the 1960s. Ion-adsorption clay deposits in southern China are the world’s primary source of the heavy REEs. Monazite-bearing placer deposits were important sources of REEs before the mid-1960s and may be again in the future. In recent years, REEs have been produced from large carbonatite bodies mined at the Mountain Pass deposit in California and, in China, at the Bayan Obo deposit in Nei Mongol Autonomous Region, the Maoniuping deposit in Sichuan Province, the Daluxiang deposit in Sichuan Province, and the Weishan deposit in Anhui Province. Alkaline igneous complexes have recently been targeted for exploration because of their enrichments in the heavy REEs. Information relevant to the environmental aspects of REE mining is limited. Little is known about the aquatic toxicity of REEs. The United States lacks drinking water standards for REEs. The concentrations of REEs in environmental media are influenced by their low abundances in crustal rocks and their limited solubility in most groundwaters and surface waters. The scarcity of sulfide minerals, including pyrite, minimizes or eliminates concerns about acid-mine drainage for carbonatite-hosted deposits and alkaline-intrusion-related REE deposits. For now, insights into environmental responses of REE mine wastes must rely on predictive models.

Professional Paper↗
USGS2020

Energy and minerals division tight oil and gas committee: Activities and commodity report for 2019-2020

In 2019, total daily tight oil and gas production increased in the United States month over month, with annualized growth of 14% for oil and 12% for gas. Those gains leveled off in the first quarter of 2020 due to aggressive price competition and increases in international production. Then came the pandemic with a substantially larger dose of economic turmoil, driving down demand due in part to shelter in place orders and safety concerns around travel. Between March and May, tight oil and gas production dropped by nearly 2 million bpd and almost 5 Bcf/day before beginning to recover. Production has continued to increase for the most part through the second half of 2020, but drilling remains subdued throughout most of the U.S. and uncertainty around long term demand along with the current price environment and general state of the economy has contributed to layoffs throughout the industry. Some shale-gas production has declined recently, but a few areas have seen expansion due to construction of LNG facilities along the East Coast of the U.S. (e.g., the Haynesville Formation). Current U.S. shale-gas production is still higher now than in 2019, with daily production of almost 71 Bcf as of October 2020 driven in large part by increased production from the Marcellus Shale in the Appalachian Basin and shales within the Permian Basin. Shale liquids production is down by around a million bpd to approximately 7.1 million (September 2020; U.S. EIA) from pre-pandemic production levels at the end of 2019 and beginning of 2020. Tight oil production remains dominated by plays in the Permian Basin as well as the Bakken and Eagle Ford Formations. On the development and production front, new enhanced oil recovery approaches for tight shale reservoirs are being more widely implemented. Natural gas or CO2 injection is currently being utilized in the Bakken Formation, Eagle Ford Formation, Anadarko Basin, and the Permian Basin to optimize injection sequences and boost recovery. Refracturing of existing wells to reduce drilling costs, improve production, and prolong well productive life has also begun to occur more widely in developed plays. International interest in exploiting hydrocarbons from unconventional reservoirs continues to develop, with active exploration projects on most continents. Europe remains relatively underexplored as compared to North America, although a total of 141 exploration and appraisal wells with a possible shale-gas exploration component have been spudded, including horizontal legs from vertical wells. Shale exploration has made a breakthrough in China with shale gas output in 2019 of 10 billion cubic meters (35.3 Bcf), 60% of which was produced from Sinopec’s Fuling Shale Gas field. Lacustrine shale oil exploration has also been successful in the Sichuan and Ordos Basins in central China, Junggar and Tarim Basins in northwest China, and Songliao Basin in north China, and Bohai Bay Basins in northeast China as of 2018. South America’s potential as an unconventional shale gas and oil province is mainly in Argentina and Brazil, where the production from Neuquen Basin’s tight shale of the Vaca Muerta Formation has been steadily increasing since 2016, but only 4% of the shale resource has been developed thus far. According to International Energy Agency’s report in 2013, Brazil holds the 9th largest unconventional gas reserves. Brazil has shale oil and gas potential in the Parana, Solimoes and Amazon Basins and is actively producing from the oil shale unit of the Irati Formation. In 2019, the Brazil energy ministry launched REATE 2020 to boost onshore investments that include the expectation of drilling an experimental unconventional well in the northeast region. For this inaugural report, the new AAPG EMD Tight Oil and Gas Committee (TO&G; formerly the Shale Gas & Liquids and Tight Gas Sands committees) has developed new commodity report requirements for contributors. This includes shorter annual reports focused on new developments, play concepts, along with the typical updates on production and new drilling in the play areas they cover. We are also asking contributors to collect background geologic and production related information into a document that summarizes important features of the plays they cover that will be stored on the TO&G webpage along with our commodity reports. TO&G is currently working to expand the number of contributors to cover more play areas and replace committee and advisory board members that have recently stepped down. Changes to committee leadership occurred in October as recent chairs transition to EMD elected positions.

Activities and Commodities Report↗
USGS2017

Genetic and grade and tonnage models for sandstone-hosted roll-type uranium deposits, Texas Coastal Plain, USA

The coincidence of a number of geologic and climatic factors combined to create conditions favorable for the development of mineable concentrations of uranium hosted by Eocene through Pliocene sandstones in the Texas Coastal Plain. Here 254 uranium occurrences, including 169 deposits, 73 prospects, 6 showings and 4 anomalies, have been identified. About 80 million pounds of U 3 O 8 have been produced and about 60 million pounds of identified producible U 3 O 8 remain in place. The development of economic roll-type uranium deposits requires a source, large-scale transport of uranium in groundwater, and deposition in reducing zones within a sedimentary sequence. The weight of the evidence supports a source from thick sequences of volcanic ash and volcaniclastic sediment derived mostly from the Trans-Pecos volcanic field and Sierra Madre Occidental that lie west of the region. The thickest accumulations of source material were deposited and preserved south and west of the San Marcos arch in the Catahoula Formation. By the early Oligocene, a formerly uniformly subtropical climate along the Gulf Coast transitioned to a zoned climate in which the southwestern portion of Texas Coastal Plain was dry, and the eastern portion humid. The more arid climate in the southwestern area supported weathering of volcanic ash source rocks during pedogenesis and early diagenesis, concentration of uranium in groundwater and movement through host sediments. During the middle Tertiary Era, abundant clastic sediments were deposited in thick sequences by bed-load dominated fluvial systems in long-lived channel complexes that provided transmissive conduits favoring transport of uranium-rich groundwater. Groundwater transported uranium through permeable sandstones that were hydrologically connected with source rocks, commonly across formation boundaries driven by isostatic loading and eustatic sea level changes. Uranium roll fronts formed as a result of the interaction of uranium-rich groundwater with either (1) organic-rich debris adjacent to large long-lived fluvial channels and barrier–bar sequences or (2) extrinsic reductants entrained in formation water or discrete gas that migrated into host units via faults and along the flanks of salt domes and shale diapirs. The southwestern portion of the region, the Rio Grande embayment, contains all the necessary factors required for roll-type uranium deposits. However, the eastern portion of the region, the Houston embayment, is challenged by a humid environment and a lack of source rock and transmissive units, which may combine to preclude the deposition of economic deposits. A grade and tonnage model for the Texas Coastal Plain shows that the Texas deposits represent a lower tonnage subset of roll-type deposits that occur around the world, and required aggregation of production centers into deposits based on geologic interpretation for the purpose of conducting a quantitative mineral resource assessment.

Texas↗
USGS1946

Quartz crystal in Brazil

The peak production of Brazilian quartz crystal was reached in 1943 when 2411 metric tons were exported. Minas Gerais, Goiaz, and Bahia are the principal producing states. Minor quantities are obtained from Espirito Santo and Northeastern Brazil. Primary veins and pegmatites yield secondary deposits of eluvial, colluvial, and alluvial origin. The veins range in form from tabular or lenticular bodies, pipes, and pockets to composite lodes and bedded masses. The mineralogy is simple; accessory minerals are few and rare. A small proportion of clear crystals, occurring in vein masses of milky quartz, furnishes the commercial product. Filling, rather than replacement, is believed to be the dominant emplacement process. Pegmatites yield a little commercial quartz. Both residual (eluvial) and water-laid (alluvial) quartz deposits are economically important. Crystals range up to 40 metric tons in weight; those of 1 to 5 tons occur in many deposits. Quartz from every locality studied is twinned on both the Brazil and Dauphiné laws. Phantoms are abundant. Field studies reveal little difference between the final quartz from some pegmatites and that from veins. It is inferred that the veins may grade into pegmatites at depth and that both are products of the same mineralogenic epoch. Present evidence does not justify a closer dating for the formation of the veins and pegmatites than the early Paleozoic. There are few large quartz mines in Brazil. The impressive quartz production during the war years came from many small, scattered workings. Mining methods are primitive, and mechanization was feasible in relatively few areas. The ratio of mine-clean crystal to the total quantity of excavated material varies between 1:1000 and 1:100,000, with an over-all average for the best mines of the order of 1:10,000. Cost of mining ranges from $2 to $10 a kilogram. The average export value during 1944 was $12.50 per kilogram. The potential reserves of quartz crystal in Brazil are large, but actual or visual reserves in known districts are small. Future production capacity will be determined by economic factors.

GSA Bulletin↗
USGS1954

Copper cities copper deposit, Globe-Miami district, Arizona

The Copper Cities copper deposit in the Globe - Miami district , Arizona , is now in process of development. It is of the "porphyry" type and occurs in a body of quartz monzonite that has been intruded by smaller masses of granite porphyry. The hypogene sulfides are pyrite, chalcopyrite, and a very little molybdenite. Pyritic mineralization extends over a large area of which only a small portion contains an appreciable amount of chalcopyrite. The outcrop of the copper -bearing rock, roughly 1,800 feet square, is bounded on the west, north, and east sides by fault zones. The south boundary is gradational. The pyrite to chalcopyrite ratio of the protore increases rapidly with depth, whereas the copper content decreases but slightly. The ore body is a shallow chalcocite zone formed by supergene enrichment. Bodies of granite porphyry within the copper -bearing area were not as strongly mineralized by hypogene solutions as the quartz monzonite, and in them the chalcocite zone is thin, undoubtedly because the granite porphyry is less pervious to ground water than the quartz monzonite.

Arizona↗
USGS1982

Biogenic and nonbiogenic ore-forming processes in the south Texas uranium district; evidence from the Panna Maria deposit

Geochemical and petrographic studies of core samples from the Panna Maria uranium deposit, a roll-type orebody in the Eocene Jackson Group in Karnes County, Texas, yield important information on the origin of the deposit. Organic carbon content averages about 0.42 weight percent in reduced rock and correlates postively with sulfur content. Pyrite is the dominant iron disulfide (FeS 2 ) mineral in most of the ore zone and throughout a surrounding zone of reduced barren ground, and it is commonly associated with organic debris. Marcasite is sparse except in ore adjacent to the altered tongue in one core and locally in mineralized lignite. Sulfur isotopic compositions (delta 34 S) of FeS 2 minerals range broadly from -1 to -34 per mil; the lightest delta 34 S values (less than -20 per mil) were measured in samples from mineralized lignite and from the nose of the ore roll. Petrographic and geochemical characteristics of the Panna Maria deposit contrast greatly with those of three other south Texas roll-type uranium deposits (the Benavides, Felder, and Lamprecht deposits), which are devoid of organic carbon and which contain more sulfide than does the Panna Maria. These three deposits are characterized by abundant isotopically light ore-stage marcasite and by isotopically heavy preore (in the Benavides) or postore (in the Felder and Lamprecht) pyrite. We have concluded previously that sulfide-bearing fault-leaked solutions from underlying hydrocarbon accumulations were important in the formation of the Benavides, Felder, and Lamprecht deposits. Although the Panna Maria deposit shows an apparent alignment along a fault zone, and although underlying formations in the Karnes County area contain sour gas (delta 34 S [asymp] + 14 per mil) and produce oil, the deposit lacks characteristics indicating that its formation or preservation involved extrinsically derived reductants such as fault-leaked aqueous sulfide. Mineralization of the Panna Maria, rather, appears to have been controlled by intrinsically derived reductants related either directly or indirectly to the presence of organic matter.

Texas↗
USGS2008

Quantitative mineral resource assessment of copper, molybdenum, gold, and silver in undiscovered porphyry copper deposits in the Andes Mountains of South America

Quantitative information on the general locations and amounts of undiscovered porphyry copper resources of the world is important to exploration managers, land-use and environmental planners, economists, and policy makers. This publication contains the results of probabilistic estimates of the amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) in undiscovered porphyry copper deposits in the Andes Mountains of South America. The methodology used to make these estimates is called the 'Three-Part Form'. It was developed to explicitly express estimates of undiscovered resources and associated uncertainty in a form that allows economic analysis and is useful to decisionmakers. The three-part form of assessment includes: (1) delineation of tracts of land where the geology is permissive for porphyry copper deposits to form; (2) selection of grade and tonnage models appropriate for estimating grades and tonnages of the undiscovered porphyry copper deposits in each tract; and (3) estimation of the number of undiscovered porphyry copper deposits in each tract consistent with the grade and tonnage model. A Monte Carlo simulation computer program (EMINERS) was used to combine the probability distributions of the estimated number of undiscovered deposits, the grades, and the tonnages of the selected model to obtain the probability distributions for undiscovered metals in each tract. These distributions of grades and tonnages then can be used to conduct economic evaluations of undiscovered resources in a format usable by decisionmakers. Economic evaluations are not part of this report. The results of this assessment are presented in two principal parts. The first part identifies 26 regional tracts of land where the geology is permissive for the occurrence of undiscovered porphyry copper deposits of Phanerozoic age to a depth of 1 km below the Earth's surface. These tracts are believed to contain most of South America's undiscovered resources of copper. The second part presents probabilistic estimates of the amounts of copper, molybdenum, gold, and silver in undiscovered porphyry copper deposits in each tract. The study also provides tables showing the location, tract number, and age (if available) of discovered deposits and prospects. For each of the 26 permissive tracts delineated in this study, summary information is provided on: (1) the rationale for delineating the tract; (2) the rationale for choosing the mineral deposit model used to assess the tract; (3) discovered deposits and prospects; (4) exploration history; and (5) the distribution of undiscovered deposits in the tract. The scale used to evaluate geologic information and draw tracts is 1:1,000,000.

Open-File Report↗
USGS2010

Spatial Databases of Geological, Geophysical, and Mineral Resource Data Relevant to Sandstone-Hosted Copper Deposits in Central Kazakhstan

Central Kazakhstan is host to one of the world's giant sandstone-hosted copper deposits, the Dzhezkazgan deposit, and several similar, smaller deposits. The United Stated Geological Survey (USGS) is assessing the potential for other, undiscovered deposits of this type in the surrounding region of central Kazakhstan. As part of this effort, Syusyura compiled and partially translated an array of mostly unpublished geologic, geophysical, and mineral resource data for this region in digital format from the archives of the former Union of Soviet Socialists Republics (of which Kazakhstan was one of the member republics until its dissolution in 1991), as well as from later archives of the Republic of Kazakhstan or of the Kazakhstan consulting firm Mining Economic Consulting (MEC). These digital data are primarily map-based displays of information that were transmitted either in ESRI ArcGIS, georeferenced format, or non-georeferenced map image files. Box and Wallis reviewed all the data, translated Cyrillic text where necessary, inspected the maps for consistency, georeferenced the unprojected map images, and reorganized the data into the filename and folder structure of this publication.

Open-File Report↗
USGS2014

Evidence for large-magnitude, post-Eocene extension in the northern Shoshone Range, Nevada, and its implications for Carlin-type gold deposits in the lower plate of the Roberts Mountains allochthon

The northern Shoshone and Toiyabe Ranges in north-central Nevada expose numerous areas of mineralized Paleozoic rock, including major Carlin-type gold deposits at Pipeline and Cortez. Paleozoic rocks in these areas were previously interpreted to have undergone negligible postmineralization extension and tilting, but here we present new data that suggest major post-Eocene extension along west-dipping normal faults. Tertiary rocks in the northern Shoshone Range crop out in two W-NW–trending belts that locally overlie and intrude highly deformed Lower Paleozoic rocks of the Roberts Mountains allochthon. Tertiary exposures in the more extensive, northern belt were interpreted as subvertical breccia pipes (intrusions), but new field data indicate that these “pipes” consist of a 35.8 Ma densely welded dacitic ash flow tuff (informally named the tuff of Mount Lewis) interbedded with sandstones and coarse volcaniclastic deposits. Both tuff and sedimentary rocks strike N-S and dip 30° to 70° E; the steeply dipping compaction foliation in the tuffs was interpreted as subvertical flow foliation in breccia pipes. The southern belt along Mill Creek, previously mapped as undivided welded tuff, includes the tuff of Cove mine (34.4 Ma) and unit B of the Bates Mountain Tuff (30.6 Ma). These tuffs dip 30° to 50° east, suggesting that their west-dipping contacts with underlying Paleozoic rocks (previously mapped as depositional) are normal faults. Tertiary rocks in both belts were deposited on Paleozoic basement and none appear to be breccia pipes. We infer that their present east tilt is due to extension on west-dipping normal faults. Some of these faults may be the northern strands of middle Miocene (ca. 16 Ma) faults that cut and tilted the 34.0 Ma Caetano caldera ~40° east in the central Shoshone Range (<5 km south of Mill Creek), but further mapping is necessary to trace the faults through the highly deformed Paleozoic rocks that surround the isolated Tertiary outcrops. Significant post-Eocene extensional faulting in the northern Shoshone Range may have important implications for both the structure of the Roberts Mountains allochthon and the exposure of potentially mineralized rocks in its lower plate, both of which were likely east-tilted and repeated by west-dipping faults together with overlying Tertiary rocks.

Nevada↗
USGS1974

Alteration and fluid inclusion studies of the porphyry copper ore body at Bingham, Utah

Distribution patterns for biotitic alteration, sericitic alteration, and distinctive fluid-inclusion types in igneous host rocks of the porphyry copper ore body at Bingham, Utah, have been determined by petrographic examination of about 300 samples. These patterns are related to differences in original rock composition, variations in physical-chemical conditions during periods of intrusion and mineralization, and spatial position within the ore body. The distribution of biotitic (potassium-silicate) alteration assemblages and high-salinity fluid inclusions generally follows the crudely triangular form of the disseminated copper ore zone. Variations in abundance of hydrothermal biotite are attributed to differences in original mafic mineral content of the igneous host rocks. Biotitic alteration and initial copper mineralization were accomplished by high-salinity fluids concentrated during final crystallization of the monzonitic parent magma; genetic continuity between magmatic and hydrothermal stages is indicated . Pervasive sericitic alteration of plagioclase is confined to rocks in the northern one-third of the Bingham stock; a subzone of argillic alteration in the north-central part of the ore body occurs within the broader area of sericitic alteration. Fluids responsible for sericitic and argillic alteration were channeled by a broad zone of northeast-trending fractures. Hydrothermal minerals and high-salinity fluid inclusions occur within a large volume of shattered rock. Boiling of fluids during crystallization of the aplitic porphyry may account for the shattering. Sericitic (and argillic) alteration were apparently super-imposed on the earlier biotitic assemblage as the hydrothermal system cooled. Cooling and hydrolytic alteration were promoted by progressive introduction of meteoric waters. The many generations of inclusions trapped from boiling fluids in the temperature range 400 degrees to 600 degrees C suggest that the system was recharged repeatedly during the period of mineralization. Estimated fluid pressures of about 800 bars in the early stages of mineralization correspond to a lithostatic load of about 3 km; pressures were even lower (less than 200 bars) in the later stages and were probably controlled by hydrostatic conditions. Distribution patterns for biotitic alteration, sericitic alteration, and distinctive fluid-inclusion types in igneous host rocks of the porphyry copper ore body at Bingham, Utah, have been determined by petrographic examination of about 300 samples. These patterns are related to differences in original rock composition, variations in physical-chemical conditions during periods of intrusion and mineralization, and spatial position within the ore body.The distribution of biotitic (potassium-silicate) alteration assemblages and high-salinity fluid inclusions generally follows the crudely triangular form of the disseminated copper ore zone. Variations in abundance of hydrothermal biotite are attributed to differences in original mafic mineral content of the igneous host rocks. Biotitic alteration and initial copper mineralization were accomplished by high-salinity fluids concentrated during final crystallization of the monzonitic parent magma; genetic continuity between magmatic and hydrothermal stages is indicated.Pervasive sericitic alteration of plagioclase is confined to rocks in the northern one-third of the Bingham stock; a subzone of argillic alteration in the north-central part of the ore body occurs within the broader area of sericitic alteration. Fluids responsible for sericitic and argillic alteration were channeled by a broad zone of northeast-trending fractures.Hydrothermal minerals and high-salinity fluid inclusions occur within a large volume of shattered rock. Boiling of fluids during crystallization of the aplitic porphyry may account for the shattering. Sericitic (and argillic) alteration were apparently super-imposed on the earlier biotitic assemblage as the hydrothermal system cooled. Cooling and hydrolytic alteration were promoted by progressive introduction of meteoric waters. The many generations of inclusions trapped from boiling fluids in the temperature range 400 degrees to 600 degrees C suggest that the system was recharged repeatedly during the period of mineralization. Estimated fluid pressures of about 800 bars in the early stages of mineralization correspond to a lithostatic load of about 3 km; pressures were even lower (less than 200 bars) in the later stages and were probably controlled by hydrostatic conditions.

Utah↗
USGS1992

The stable isotope geochemistry of acid sulfate alteration

Acid sulfate wall-rock alteration, characterized by the assemblage alunite + kaolinite + quartz + or - pyrite, results from base leaching by fluids concentrated in H 2 SO 4 . Requisite amounts of H 2 SO 4 can be generated by different mechanisms in three principal geologic environments: (1) by atmospheric oxidation of sulfides in the supergene environment, (2) by atmospheric oxidation at the water table in the steam-heated environment of H 2 S released by deeper, boiling fluids, and (3) by the disproportionation of magmatic SO 2 to H 2 S and H 2 SO 4 during condensation of a magmatic vapor plume at intermediate depths in magmatic hydrothermal environments in silicic and andesitic volcanic terranes. In addition, coarse vein alunite may form in a magmatic steam environment from rapid release of an SO 2 -rich magmatic vapor phase at high temperature and low pressure or from the oxidation of a more reduced magmatic vapor by entrained atmospheric oxygen in the carapace of a volcanic edifice.Alunite [KAl 3 (SO 4 ) 2 (OH) 6 ] contains four stable isotope sites and complete analyses (delta D, delta 18 O (sub SO 4 ) , delta 18 O OH , and delta 34 S) are now possible. Except for delta 18 O OH in magmatic hydrothermal alunites, primary values are usually retained. In cooperation with many colleagues, over 500 measurements have been made on nearly 200 samples of alunite and associated minerals from 23 localities, and 55 additional analyses have been taken from the literature. This survey confirms that kinetic factors play an important role in the stable isotope systematics of alunite and acid sulfate alteration. To a very large extent they form the isotopic basis for distinguishing between environments of acid sulfate alteration, and they provide important insights into attendant processes. Stable isotope analyses of alunite, often in combination with those on associated sulfides and kaolinite, permit recognition of environments of formation and provide information on origins of components, processes (including rates), physical-chemical environments, and temperatures of formation.Supergene acid sulfate alteration may form over any sulfide zone when it is raised above the water table by tectonics or exposed by erosion. It may overprint earlier acid sulfate assemblages, particularly the magmatic hydrothermal assemblages which are pyrite rich such as at El Salvador, Chile; Rodalquilar, Spain; and Goldfield, Nevada. Supergene alunite normally has delta 34 S values virtually identical to precursor sulfides unless bacteriogenic reduction of aqueous sulfate takes place in standing pools of water. delta D values are close to that of local meteoric water unless extensive evaporation occurs. delta D and delta 18 O OH values of supergene alunites from a range of latitudes fall in a broad zone parallel to the meteoric water line much the way delta D and delta 18 O values of associated halloysite-kaolinite fall near the kaolinite line of Savin and Epstein (1970). delta 18 O (sub SO 4 ) values are kinetically controlled and will reflect the hydro-geochemistry of the environment. delta 18 O (sub SO 4 -OH) alues are grossly out of equilibrium and large negative values are definitive of a supergene origin.In steam-heated environments, such as those at the Tolfa district, Italy, and Marysvale, Utah, and numerous modern geothermal systems, acid sulfate alteration zones are characterized by pronounced vertical zoning. Such acid sulfate alteration may occur over adularia-sericite-type base and precious metal ore deposits such as the one at Buckskin, Nevada. Initial delta 18 O (sub SO 4 ) and delta 34 S values are kinetically controlled, but delta 18 O (sub SO 4 ) values usually reach equilibrium with fluids, and even delta 34 S values may reflect partial exchange with H 2 S where the residence time of aqueous sulfate is sufficient. Most alunites of steam-heated origin have delta 34 S values the same as those of precursor H 2 S (and as related sulfides, if present) and delta D values similar to that of local meteoric water. In the samples analyzed, most delta 18 O (sub SO 4 -OH) values give reasonable temperatures of 90 degrees to 160 degrees C, indicating that delta 18 O (sub SO 4 ) and delta 18 O OH values reflect a close approach to equilibrium with the fluid. The delta 18 O (sub SO 4 ) and delta 18 O OH values also reflect the degree of exchange of the meteoric fluids with wall rock. Coeval kaolinites typically have delta 18 O and delta D values to the left of the kaolinitc line.Magmatic hydrothermal, acid sulfate alteration zones in near-surface epithermal deposits such as Summitville, Colorado. Julcani, Peru, and Red Mountain and Lake City, Colorado, are characterized by vertical orientation and horizontal zoning, the presence of coeval pyrite, PO 4 analogues of alunite, zunyite, and later gold, pyrite and enargite, and often other Cu-As-Sb-S minerals. Acid sulfate alteration assemblages also occur as late stages in the porphyry-copper deposit at E1 Salvador, Chile. In the examples studied, magmatic hydrothermal alunites have delta D values close to those for magmatic water. delta 34 S values are 16 to 28 per mil larger than those for associated pyrite, reflecting equilibrium between aqueous H 2 S and SO 4 formed by the disproportionation of magmatically derived SO 2 . delta 18 O (sub SO 4 ) values are usually 8 to 18 per mil and vary systematically with delta 34 S values, reflecting variations in temperature and/or H 2 S/SO 4 fluid ratios. Further variation in delta 18 O (sub SO 4 ) values may result if SO 2 condenses in mixed magmatic meteoric water fluids. delta 18 O (sub SO (sub 4-) OH) values of magmatic hydrothermal alunites are generally unsuitable for temperature determinations because of retrograde exchange in the OH site, but delta 34 S (sub alunite-pyrite) values provide reliable temperature estimates.Magmatic steam environments appear to occur over a range of depths and are characterized by monomineralic veins of coarse alunite in variably alunitized and kaolinized wall rocks containing minor pyrite. Alunite formed in the magmatic steam environment can usually be recognized by delta 34 S near delta 34 S (sub Sigma S) values and delta D and delta 18 O (sub SO 4 ) values near magmatic values. Magmatic steam alunite differs from magmatic hydrothermal alunite by having delta 34 S close to delta 34 S (sub Sigma S) values of the system. delta 18 O (sub SO (sub 4-) OH) values of most magmatic steam alunite give temperatures ranging from 90 degrees to 210 degrees C but, for reasons which are not understood, some temperatures as well as calculated delta 18 O (sub H 2 O) values are too low for presumed precipitation from a magmatic vapor phase. Magmatic steam environments may occur over porphyry-type mineralization as at Red Mountain, Colorado, and Alunite Ridge, Utah, and over or adjacent to adularia-sericite-type deposits in volcanic domes as at Cactus, California.

Economic Geology↗