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Hydrogeologic atlas of aquifers in Indiana

Aquifers in 12 water-management basins of Indiana are identified in a series of 104 hydrogeologic sections and 12 maps that show the thickness and configuration of aquifers. The vertical distribution of water-bearing units and a generalized potentiometric profile are shown along 3,500 miles of section lines that were constructed from drillers' logs of more than 4,200 wells. The horizontal scale of the sections is 1:125,000. Maps of aquifers showing the areal distribution of each aquifer type were drawn at a scale of 1:500,000. Unconsolidated aquifers are the most widely used aquifers in Indiana and include surficial, buried, and discontinuous layers of sand and gravel. Most of the surficial sand and gravel is in large outwash plains in northern Indiana and along the major rivers. Buried sand and gravel aquifers are interbedded with till deposits in much of the northern two-thirds of Indiana. Discontinuous sand and gravel deposits are present as isolated lenses, primarily in glaciated areas. The bedrock aquifers generally have lower yields than most of the sand and gravel aquifers; however, bedrock aquifers are areally widespread and are an important source of water. Bedrock aquifer types consist of carbonates; sandstones; complexly interbedded sandstones, siltstones, shales, limestones, and coals; and an upper weathered zone in low permeability rock. Carbonate aquifers underlie about one-half of Indiana and are the most productive of the bedrock aquifers. The other principal bedrock aquifer type, sandstone, underlies large areas in the southwestern one-fifth of Indiana. No aquifer is known to be present in the southeastern corner of Indiana.

Water-Resources Investigations Report

Beavers in the Tualatin River Basin, northwestern Oregon

Growing interest in beaver-assisted restoration in the Tualatin River Basin of northwestern Oregon motivated a series of studies by the U.S. Geological Survey to assess the capacity of the stream network to support beaver dams and to evaluate the effects of beaver dams and ponds on urban streams. This multichapter volume describes the data collection from 2016–17 and the findings of these studies, which were done in partnership with Clean Water Services. Chapter A documents the locations of beaver dams in the Tualatin River Basin and how many beaver dams the stream network could support with existing and improved riparian vegetation. Beaver dam capacity was estimated by modifying existing tools to account for the low gradient of many streams in the Tualatin River Basin. Chapter B describes the effects of beaver dams and ponds on hydrologic and hydraulic responses of storm flows. Hydrologic and hydraulic responses for two urban stream reaches were compared with and without beaver dams and ponds and for a range of streamflow conditions using two-dimensional hydraulic models. Chapter C characterizes the effects of beaver dams and ponds on the transport and deposition of suspended sediment. Continuous turbidity, discrete suspended-sediment samples, and streamflow measurements collected during storms and base-flow periods were used to assess: (1) suspended-sediment loads upstream and downstream from two beaver-affected reaches, and (2) seasonal and longitudinal turbidity patterns. Chapter D describes the effects of beaver dams and ponds on longitudinal, spatial, and seasonal water-quality patterns. Continuous and synoptic water-quality data were collected along urban stream reaches, and net ecosystem production was calculated for two beaver-affected reaches. The findings of these studies illustrate that the effects of beaver dams and ponds on hydrology, hydraulics, suspended-sediment transport and deposition, and water quality are dependent on the characteristics of a stream reach (for example, channel gradient, groundwater exchange, and riparian vegetation) and the characteristics of beaver dams and ponds along that reach. This information can be used to consider the implications of beaver-assisted restoration in the Tualatin River Basin and the effects of beaver dams and ponds in urban streams.

Oregon

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado

Moment magnitude for small earthquakes in the Delaware basin of west Texas and southeast New Mexico, USA

The Delaware Basin region of west Texas and southeast New Mexico has become one of the most prolific regions of seismic activity in the continental United States due to widespread hydraulic fracturing and wastewater disposal injection. In response to the increased number of earthquakes in this region, rapid and accurate characterization of earthquake sources is necessary to understand the evolution of seismic activity and level of seismic hazard associated with these earthquakes. This study re-evaluates earthquake magnitudes, estimating moment magnitude (MW) for small earthquakes in the Delaware Basin using 1) moment-rate spectra derived from S-wave coda envelopes, and 2) a relative magnitude method that relies exclusively on the ratio of waveform amplitudes between highly correlated waveform pairs. The coda-envelope method produces accurate M W estimates for small earthquakes ( M 1.5 – 3) that are consistent with independent, waveform modeled moment magnitudes for events with M W > 3 . Using the relative amplitudes method to extend these M W magnitudes to many other events, we successfully provide relative moment magnitude ( M W,rel ) values for 81% of the Texas Seismological Network catalog in the Delaware Basin region, and 45% of the USGS Induced Seismicity Project’s catalog of events in southeast New Mexico. The adoption and integration of the calibrated M W,rel method with current magnitude estimation methods offers valuable insights into the relationships between local and moment magnitude and will contribute to improved characterization of widespread induced seismicity.

New Mexico, Texas

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington

Oligocene–Miocene development and evolution of the south Dome Rock Mountains basin, lower Colorado River corridor, Arizona, USA

Sedimentary basins in the Colorado River extensional corridor record large-magnitude Basin and Range extension and younger dextral shear deformation in the evolving Pacific−North America plate boundary. The south Dome Rock Mountains basin is located in west-central Arizona (USA), where the history of basin evolution, style of deformation, and timing of the transition between extension and dextral shear are not well constrained. We integrate new geologic mapping of the south Dome Rock Mountains basin with zircon U-Pb geochronology of six marker beds to characterize the timing of basin evolution and the slip history of the south Dome Rock Mountains normal fault. Structural analysis defines structures consistent with regional extension and younger dextral shear deformation. We use sedimentological and petrological analysis to interpret the depositional environments of three basin sequences. A lower basin sequence consists of fluvial strata deposited in an internally drained intermontane basin from ca. 35 Ma to 24.4 Ma. A sequence of volcanic rocks was emplaced in the basin between 24.4 Ma and 23.3 Ma, before the onset of local extensional faulting. An upper basin sequence of coarse conglomerate and sedimentary breccia was deposited on the hanging wall of a half graben structure after 23.3 Ma and through ca. 12.8 Ma, synchronous with 3−7 km of dip slip on the west-dipping, listric south Dome Rock Mountains fault. The basin was subsequently deformed by dextral shear after 12.8 Ma and before 4.8 Ma. These results document how distributed deformation related to the evolving Pacific−North America plate boundary occurred >100 km from the primary plate boundary.

Arizona, California

Geologic map of MTM −15032 and −20032 quadrangles, western Ladon basin, Mars

Our mapping efforts focused on the geomorphic terrains and geologic units contained within Mars Transverse Mercator (MTM) −15032 and −20032 quadrangles. These two quadrangles are located along the west side of Ladon basin and span lat −12.5° N. to −22.5° N. and long 325° E. to 330° E. The western part of Ladon basin and its bounding basin ring structures to the west preserved features that help to understand the long history of drainage across the Margaritifer Terra region of Mars. Our geologic map provides new insight into the extent of aqueous activity across western Ladon basin and the adjoining highlands, which includes the northern part of Ladon Valles, Arda Valles, numerous small valleys in the western highlands, and light-toned layered deposits associated with these fluvial features. The Mars Odyssey Thermal Emission Imaging System (THEMIS) infrared (IR) daytime mosaic (100 meters per pixel) was used as the primary base map. We constructed the geologic map of western Ladon basin at 1:1,000,000 scale. We identified 20 geologic units in the map area, which we divided into the following groups: crater units; volcanic units; chaotic units; basin fill units; crater, valley, and channel units; and plateau and highlands units. We observed the following sequence of events: (1) formation of Ladon and Holden impact basins in the middle Noachian, producing a mountainous unit; (2) landscape degradation and infilling during the Late Noachian to Late Hesperian forming terra units; (3) formation of Ladon Valles in the Late Noachian to Early Hesperian by catastrophic flooding, producing channel units; (4) accumulation of sediments in the Late Noachian to Early Amazonian, forming basin fill units; (5) formation of a smooth crater fill unit during the Early to Late Hesperian; (6) deposition during the Late Hesperian to Early Amazonian, creating light-toned layered units within Ladon Valles, Ladon basin, and other smaller valley networks along the western uplands, as well as formation of a light-toned unit along some crater floors; (7) formation a of chaotic unit in the Early to Middle Amazonian, formation of alluvial fans in the Early Amazonian, and eruption of a volcanic unit in the Middle Amazonian; and (8) formation of craters throughout the geologic history of the map region.

Scientific Investigations Map

Magnitude, depth and methodological variations of spectral stress drop within the SCEC/USGS Community Stress Drop Validation Study using the 2019 Ridgecrest Earthquake Sequence

We present the first ensemble analysis of the 56 different sets of results submitted to the ongoing Community Stress Drop Validation Study using the 2019 Ridgecrest, California, earthquake sequence. Different assumptions and methods result in different estimation of the source contribution to recorded seismograms, and hence to the source parameters (principally corner frequency, f c ⁠ , spectral stress drop, Δσ, and seismic moment, M 0 ⁠ ) obtained from modeling calculated source spectra. For earthquakes smaller than magnitude (M) 2.5 there is negligible correlation between the f c values obtained by different studies, implying that no present method is reliable using available data. For larger magnitude events, correlation between f c measurements of different studies, within even a small M range is always higher than spectral ⁠Δσ , because the f c measurements simply reflect the underlying physical decrease in f c with increasing M. We model the observed trends of submitted f c with both magnitude and depth. Most methods report an increase in spectral Δσ with M, although a magnitude‐invariant spectral Δσ is within the confidence limits. The depth dependence is smaller and depends on whether a study allows attenuation to vary with source depth; a combination of depth‐dependent attenuation correction, and depth‐dependent shear‐wave velocity can compensate for reported depth trends. We model the submitted values to remove differing M and depth variation to investigate the relative interevent variability. We find consistent relative variation between individual events, and also lower relative spectral Δσ in the northwest of the aftershock sequence, and higher on the cross fault and in the region of main fault intersection. This large‐scale comparison implies that absolute spectral Δσ estimates are dependent on the methods used; studies of different regions or using different methods should not be directly compared and improved constraints on path and site corrections are needed to resolve these absolute spectral Δσ differences.

California

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis

New occurrences of the rare, REE minerals daqingshanite, törnebohmite, biraite, sahamalite, and ferriperbøeite from the Sheep Creek area, Montana, USA

Over 30 small, discontinuous, tabular carbonatite bodies are located in the Sheep Creek area, Ravalli County, southwest Montana. The age and origin of these REE-Nb-rich deposits are currently being investigated. The purpose of this paper is to document the occurrence of several rare minerals, including daqingshanite, törnebohmite, biraite, sahamalite, and ferriperbøeite, in two of the carbonatite bodies. These minerals are found in association with monazite, hydroxylbastnäsite, ferriallanite, calcite, dolomite, baryte, quartz, actinolite, apatite, celsian, and Sr-rich aragonite. Automated SEM-EDS was used to target the areas of interest in polished specimens for more detailed spot SEM-EDS and electron probe microanalysis. Raman spectra were also acquired for each of the rare minerals. The complex mineralogy of the Sheep Creek carbonatites is most likely due to several overlapping thermal events, including primary magmatic, overprinting hydrothermal, and supergene weathering stages. The rare minerals described in this study are believed to be hydrothermal and/or carbothermal in origin, although no estimates of temperature are available at this time.

Montana

Estimation of reservoir storage capacity and geomorphic change detection analysis from a multibeam bathymetric survey of Randy Poynter Lake, Rockdale County, Georgia

Rockdale County Department of Water Resources has a directive to update estimates of the reservoir storage capacity of Randy Poynter Lake, located in northern Georgia, and to assess recent sedimentation and associated storage capacity loss. In 2022, the U.S. Geological Survey completed a multibeam bathymetric survey of Randy Poynter Lake to update storage capacity estimates and to quantify storage capacity change since the first multibeam bathymetric survey in 2012 in consideration of estimated errors inherent to bathymetric surveys. Data from the 2022 survey were used to generate contours of the reservoir as well as compute storage capacity at regular increments of water-surface elevation. Storage capacity comparisons between 2012 and 2022 at Randy Poynter Lake show minimal changes that are within the estimated uncertainties, with consistent or slightly increased storage capacities observed at most water-surface elevations and reductions observed at the remaining few elevations. Comparison of the multibeam bathymetric data collected in 2012 with data collected in 2022 further allowed for a formal geomorphic change detection analysis to map, quantify, and infer causation of morphological change over time with respect to a level of detectable change. The volume change in Randy Poynter Lake for the decade between 2012 and 2022 was slightly net-depositional and within the estimated uncertainty. The spatial distribution of sediment deposition was primarily concentrated in the northern portion of the lake, where the principal tributary flows into Randy Poynter Lake. The results of the geomorphic change analysis were used to further understand the future implications to storage capacity change. Despite the challenges of confirming systematic biases because of uncertainties exceeding the observed changes, insights from the study help predict long-term reservoir sediment accumulation, indicating a reservoir half-life extending about 650 years from 2022 on the basis of the current sediment yield estimates.

Georgia

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

Using geologic mapping to understand temporal and spatial relations of closely clustered to concurrent latest Holocene surface ruptures on two intersecting faults, south-central Mojave Desert, California

The Pinto Mountain Fault Zone (PMFZ) marks a major structural boundary between east-oriented sinistral faults of the eastern Transverse Ranges (to the south) and northwest-oriented dextral faults of the south-central Mojave Desert (to the north). These structural fault systems comprise sinistral and dextral deformational domains of the Eastern California Shear Zone (ECSZ) that intersect one another in the Copper Mountain and Twentynine Palms areas. The U.S. Geological Survey (USGS) is conducting detailed geologic mapping and geochronologic investigations designed to clarify geometric, kinematic, and temporal relations among the two domains, that are focused on the central portion of the left-lateral PMFZ near its intersection with the right-lateral Copper Mountain Fault (CMF) and Mesquite Lake Fault Zone (MLFZ).

California

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas

Wetlands, groundwater and seasonality influence the spatial distribution of stream chemistry in a low-relief catchment

Evaluating stream water chemistry patterns provides insight into catchment ecosystem and hydrologic processes. Spatially distributed patterns and controls of stream solutes are well-established for high-relief catchments where solute flow paths align with surface topography. However, the controls on solute patterns are poorly constrained for low-relief catchments where hydrogeologic heterogeneities and river corridor features, like wetlands, may influence water and solute transport. Here, we provide a data set of solute patterns from 58 synoptic surveys across 28 sites and over 32 months in a low-relief wetland-rich catchment to determine the major surface and subsurface controls along with wetland influence across the catchment. In this low-relief catchment, the expected wetland storage, processing, and transport of solutes is only apparent in solute patterns of the smallest subcatchments. Meanwhile, downstream seasonal and wetland influence on observed chemistry can be masked by large groundwater contributions to the main stream channel. These findings highlight the importance of incorporating variable groundwater contributions into catchment-scale studies for low-relief catchments, and that understanding the overall influence of wetlands on stream chemistry requires sampling across various spatial and temporal scales. Therefore, in low-relief wetland-rich catchments, given the mosaic of above and below ground controls on stream solutes, modeling efforts may need to include both surface and subsurface hydrological data and processes.

Michigan

Performance analysis of oil recovery and CO2 retention in a greenfield residual oil zone: CO2-EOR in Tall Cotton Field (Permian Basin, West Texas, USA)

Residual oil zones (ROZs) can offer significant oil resources via enhanced oil recovery (EOR) as well as subsurface carbon dioxide (CO 2 ) retention during injection. If injected CO 2 is anthropogenic, the ROZs can offer a substantial geologic storage potential. The ROZs below the oil/water contact (OWC) of main pay zones (MPZ) in conventional reservoirs or brownfields, are more commonly developed for CO 2 injection and oil production and reported in the literature. However, CO 2 -EOR in greenfield ROZs, reservoirs without a MPZ present, have rarely been developed for CO 2 -EOR operation. The Tall Cotton Field of West Texas, Permian Basin, which started production in 2015 (Phase 1) and expanded in 2017 (Phase 2) from the San Andres Limestone, is one of the first examples of greenfield ROZs developed for EOR by injecting CO 2 . This paper analyses EOR and CO 2 retention performance of Tall Cotton Field using allocated injection and production data from inverted 5-spot well patterns of Phase-1 and -2 developments. Production and injection data allocated to each of the 28 identified patterns (nine 20-acre patterns for Phase-1, three 20-acre and sixteen 10-acre patterns for Phase-2) were analyzed for historical and forecasted oil recovery using ratio-trend decline analysis, and for CO 2 retention performance of the patterns. The allocated data were further used to calculate injected reservoir pore volume and void replacement ratios (VRR) for the analysis period. Quantitative results indicated that oil recovery factors of the 5-spot patterns varied between 4–10 %, and 5–30 % between the end of injection and the forecast periods, respectively. Storage of CO 2 , on the other hand, increased to a mean value of ∼7130 MMscf per pattern in Phase-1 and to a mean storage of 3700 MMscf per pattern in Phase-2 until the end of injection, followed by a decline after the end of injection and into the forecast period. Resulting CO 2 utilization factors ∼6–50 Mscf/bbl were estimated at the end of injection. Overall, presented results suggested that developing greenfield ROZs for CO 2 -EOR can be as promising as brownfield ROZs and mature MPZs for EOR and underground storage of injected CO 2 . For Tall Cotton Field, results suggest that Phase-2 patterns generally outperformed Phase-1 for oil recovery factors, while Phase-1 performed better in CO 2 retention performance metrics. This is the first study in the literature that reports a detailed CO 2 -EOR performance analysis of a greenfield ROZ in the Permian Basin, which can potentially allow for comparison with MPZs and brownfield ROZs.

Texas

Integrated stratigraphic and geochemical analysis of organic-rich intervals of the Lewis Shale in the eastern Washakie Basin, Wyoming

Geological studies in the Cretaceous Western Interior Seaway (KWIS) in North America reveal highly variable sedimentological conditions on its western shore caused by rapidly changing sea level and detrital input during the seaway’s closure. Here we examine a 601-foot (183 meters) continuous core through the lower part of the Maastrichtian Lewis Shale in the eastern Washakie Basin, Wyoming, through integrating stratigraphic and geochemical analyses to better understand organic matter deposition and preservation during the final marine transgression within the seaway. The core penetrates eight organic-rich flooding intervals (F1-F8) and a regional condensed section, informally known as the Asquith marker. The lower portions of the core record sediment input from a southern source, likely the Sierra Madre/Park Ranges, while the upper part records sediment input from a northern source, likely the Granite Mountains. This provenance transition is supported by regional stratigraphic analysis and changes in bulk mineral and trace metal composition. The Asquith marker and early flooding surfaces are enriched in oil-prone, marine organic matter deposited under dysoxic to euxinic conditions, whereas younger flooding surfaces show increased terrigenous input and poorer preservation conditions. The Asquith marker is identified as a prime oil-prone source rock. Although younger flooding surfaces also exhibit favorable source-rock properties, their generative potential is reduced due to increased clastic and terrigenous organic matter deposition caused by regression. These results emphasize the importance of sediment source variability, organic matter preservation, and changing redox conditions to provide insight into the sediment provenance and petroleum potential of the Lewis Shale in the context of the final transgression within the KWIS.

Colorado, Wyoming