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USGS1957

Progress report of hydrology and sedimentation in Bixler Run, Corey Creek, and Elk Run watersheds, Pennsylvania

This report describes the results of an investigation in progress and presents some tentative findings from a study of hydrology and sedimentation of three small watersheds where soil conservation practices are being applied. The study was begun in April 1954, to determine precipitation, runoff, probable sources and yields of sediment, and channel changes in two small watersheds in Pennsylvania. This report covers the period April 1954, to September 30, 1955 with the exception of the aggradation-degradation range data which covers the period October 1954 to November 1956. The internal or time control method of calibration is being used for the Bixler Run watershed study, and an external control is being used in the Corey Creek study. Precipitation on Bixler Run watershed was 47.33 inches for the 1955 water year. Total runoff was 14.08 inches and the suspended sediment yield was 1,143.3 tons or 76 tons per square mile of drainage area. Precipitation on Corey Creek watershed for the same period totaled 35.81 inches. The total runoff was 8.37 inches and the suspended-sediment yield was 713.0 tons or 58.2 tons per square mile of drainage area. The precipitation on Elk Run, external control watershed for the Corey Creek study was 34.54 inches. The runoff was 10.10 inches and the suspended sediment yield was 709.9 tons or 69.5 tons per square mile. Results from the study of channel changes by means of sediment aggradation-degradation ranges showed fill in all three watersheds. Bixler Run showed an average channel fill of 1.3 square feet per stream cross section. Corey Creek and Elk Run watersheds showed average fills of 2.9 and 4.1 square feet per cross section respectively. Most of the sediments comprising this fill were in the particle size range of gravel and coarser material. The water in all three watersheds was low in dissolved solids during the period of investigation, varying from 72 to 127 ppm in Bixler Run, from 58 to 130 ppm in Corey Creek, and from 58 to 117 ppm in Elk Run. These waters are essentially of the secondary alkaline type with calcium and magnesium bicarbonate being the main dissolved constituents.

Pennsylvania↗

USGS2011

Detection, emission estimation and risk prediction of forest fires in China using satellite sensors and simulation models in the past three decades-An overview

Forest fires have major impact on ecosystems and greatly impact the amount of greenhouse gases and aerosols in the atmosphere. This paper presents an overview in the forest fire detection, emission estimation, and fire risk prediction in China using satellite imagery, climate data, and various simulation models over the past three decades. Since the 1980s, remotely-sensed data acquired by many satellites, such as NOAA/AVHRR, FY-series, MODIS, CBERS, and ENVISAT, have been widely utilized for detecting forest fire hot spots and burned areas in China. Some developed algorithms have been utilized for detecting the forest fire hot spots at a sub-pixel level. With respect to modeling the forest burning emission, a remote sensing data-driven Net Primary productivity (NPP) estimation model was developed for estimating forest biomass and fuel. In order to improve the forest fire risk modeling in China, real-time meteorological data, such as surface temperature, relative humidity, wind speed and direction，have been used as the model input for improving prediction of forest fire occurrence and its behavior. Shortwave infrared (SWIR) and near infrared (NIR) channels of satellite sensors have been employed for detecting live fuel moisture content (FMC), and the Normalized Difference Water Index (NDWI) was used for evaluating the forest vegetation condition and its moisture status.

International Journal of Environmental Research an↗

USGS2007

Aquifer susceptibility to perchlorate contamination in a highly urbanized environment

Perchlorate contamination from anthropogenic sources has been released into the Rialto-Colton, California, USA, groundwater flow system since the 1940s during its production, distribution, storage, and use. Preliminary analysis of lithological, geophysical, and water-chemistry data provided new understanding of the pathways of perchlorate migration that aid in assessing the susceptibility of drinking-water supplies to contamination within the Rialto-Colton basin. Vertical migration of perchlorate into the main water-producing aquifers is restricted by an areally extensive old soil surface; however, perchlorate data indicate contamination below this soil surface. Possible pathways for the downward migration of the contaminated water include wellbore flow and discontinuities in the old soil surface. Horizontal migration of perchlorate is influenced by lithology and faults within the basin. The basin fill is a heterogeneous mixture of boulders, gravel, sand, silt, and clay, and internal faults may restrict perchlorate migration in some areas.

California↗

USGS2007

Hydrology and Flood Profiles of Duck Creek and Jordan Creek Downstream from Egan Drive, Juneau, Alaska

Hydrologic and hydraulic updates for Duck Creek and the lower part of Jordan Creek in Juneau, Alaska, included computation of new estimates of peak streamflow magnitudes and new water-surface profiles for the 10-, 50-, 100-, and 500-year floods. Computations for the 2-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year recurrence interval flood magnitudes for both streams used data from U.S. Geological Survey stream-gaging stations weighted with regional regression equations for southeast Alaska. The study area for the hydraulic model consisted of three channels: Duck Creek from Taku Boulevard near the stream's headwaters to Radcliffe Road near the end of the Juneau International Airport runway, an unnamed tributary to Duck Creek from Valley Boulevard to its confluence with Duck Creek, and Jordan Creek from a pedestrian bridge upstream from Egan Drive to Crest Street at Juneau International Airport. Field surveys throughout the study area provided channel geometry for 206 cross sections, and geometric and hydraulic characteristics for 29 culverts and 15 roadway, driveway, or pedestrian bridges. Hydraulic modeling consisted of application of the U.S. Army Corps of Engineers' Hydrologic Engineering Center River Analysis System (HEC-RAS) for steady-state flow at the selected recurrence intervals using an assumed high tide of 20 feet and roughness coefficients refined by calibration to measured water-surface elevations from a 2- to 5-year flood that occurred on November 21, 2005. Model simulation results identify inter-basin flow from Jordan Creek to the southeast at Egan Drive and from Duck Creek to Jordan Creek downstream from Egan Drive at selected recurrence intervals.

Scientific Investigations Report↗

USGS2013

Implications of multi-scale sea level and climate variability for coastal resources

While secular changes in regional sea levels and their implications for coastal zone management have been studied extensively, less attention is being paid to natural fluctuations in sea levels, whose interaction with a higher mean level could have significant impacts on low-lying areas, such as wetlands. Here, the long record of sea level at Key West, FL is studied in terms of both the secular trend and the multi-scale sea level variations. This analysis is then used to explore implications for the Everglades National Park (ENP), which is recognized internationally for its ecological significance, and is the site of the largest wetland restoration project in the world. Very shallow topographic gradients (3–6 cm per km) make the region susceptible to small changes in sea level. Observations of surface water levels from a monitoring network within ENP exhibit both the long-term trends and the interannual-to-(multi)decadal variability that are observed in the Key West record. Water levels recorded at four long-term monitoring stations within ENP exhibit increasing trends approximately equal to or larger than the long-term trend at Key West. Time- and frequency-domain analyses highlight the potential influence of climate mechanisms, such as the El Niño/Southern Oscillation and the North Atlantic Oscillation (NAO), on Key West sea levels and marsh water levels, and the potential modulation of their influence by the background state of the North Atlantic Sea Surface Temperatures. In particular, the Key West sea levels are found to be positively correlated with the NAO index, while the two series exhibit high spectral power during the transition to a cold Atlantic Multidecadal Oscillation (AMO). The correlation between the Key West sea levels and the NINO3 Index reverses its sign in coincidence with a reversal of the AMO phase. Water levels in ENP are also influenced by precipitation and freshwater releases from the northern boundary of the Park. The analysis of both climate variability and climate change in such wetlands is needed to inform management practices in coastal wetland zones around the world.

Regional Environmental Change↗

USGS2006

Effects of land cover on water table, soil moisture, evapotranspiration, and groundwater recharge: A Field observation and analysis

The effects of land cover on water table, soil moisture, evapotranspiration, and groundwater recharge were studied with water level measurements collected from two monitoring wells over a period of 122 days. The two wells were installed under similar conditions except that one was drilled on the east side of a creek which was covered with grass, and the other on the west side of the creek which was burned into a bare ground. Substantial differences in water level fluctuations were observed at these two wells. The water level in the east grass (EG) well was generally lower and had much less response to rainfall events than the west no-grass (WNG) well. Grass cover lowered the water table, reduced soil moisture through ET losses, and thus reduced groundwater recharge. The amount of ET by the grass estimated with a water table recession model decreased exponentially from 7.6 mm/day to zero as the water table declined from near the ground surface to 1.42 m below the ground surface in 33 days. More groundwater recharge was received on the WNG side than on the EG side following large rainfall events and by significant slow internal downward drainage which may last many days after rainfall. Because of the decreased ET and increased R, significantly more baseflow and chemical loads may be generated from a bare ground watershed compared to a vegetated watershed. ?? 2005 Elsevier Ltd All rights reserved.

Journal of Hydrology↗

USGS2024

Hydrodynamic model of the Colorado River, Glen Canyon Dam to Lees Ferry in Glen Canyon National Recreation Area, Arizona

The U.S. Geological Survey constructed a two-dimensional hydrodynamic model that was applied to a 15.8-mile tailwater reach of the Colorado River in Glen Canyon that begins 0.25 mile downstream from Glen Canyon Dam and extends to Lees Ferry in Glen Canyon National Recreation Area, Arizona. The model used the Flow and Sediment Transport with Morphological Evolution of Channels (FaSTMECH) solver in the International River Interface Cooperative (iRIC) modeling interface. The model grid was developed from a full channel digital elevation model derived by combining bathymetric and topographic data collected from March 2013 to February 2016. The model was used to predict water-surface elevations, depths, depth-averaged flow velocities, and bed shear stresses for discharges ranging from 1,000 to 70,000 cubic feet per second. Modeled water-surface elevations matched well with measured values at cross sections throughout the reach, with a mean absolute error of 0.14 meter over the range of typical discharge releases from Glen Canyon Dam. The mean error on discharge, a measure of how well the model solution converged, averaged 0.6 percent and did not exceed 2 percent over the range of discharges modeled. These results indicate that model predictions of hydraulic parameters are reasonably accurate and suitable for use for a variety of purposes, such as ecological and geomorphic modeling.

Arizona↗

USGS2005

Blind comparisons of shear-wave velocities at closely-spaced sites in San Jose, California: Proceedings of a Workshop held at the US Geological Survey, Menlo Park, May 3, 2004

Shear-wave velocities within several hundred meters of Earth's surface are important in specifying earthquake ground motions for engineering design. Not only are the shearwave velocities used in classifying sites for use of modern building codes, but they are also used in site-specific studies of particularly significant structures. Many are the methods for estimating sub-surface shear-wave velocities, but few are the blind comparisons of a number of the methods at a single site. The word "blind" is important here and means that the measurements and interpretations are done completely independent of one another. Stephen Hartzell of the USGS office on Golden, Colorado realized that such an experiment would be very useful for assessing the strengths and weaknesses of the various methods, and he and Jack Boatwright of the USGS office in Menlo Park, California, in cooperation with Carl Wentworth of the Menlo Park USGS office found a convenient site in the city of San Jose, California. The site had good access and space for conducting experiments, and a borehole drilled to several hundred meters by the Santa Clara Valley Water District was made available for downhole logging. Jack Boatwright asked David Boore to coordinate the experiment. In turn, David Boore persuaded several teams to make measurements, helped with the local logistics, collected the results, and organized and conducted an International Workshop in May, 2004. At this meeting the participants in the experiment gathered in Menlo Park to describe their measurements and interpretations, and to see the results of the comparisons of the various methods for the first time. This Open-File Report describes the results of that workshop. One of the participants, Michael Asten, offered to help the coordinator prepare this report. Because of his lead role in pulling the report together, Dr. Asten is the lead author of the paper to follow and is also the lead Compiler for the Open-File Report. It is important to recognize that most of the participants in the experiments contributed at their own expense. It is gratifying that many people recognized the importance of the experiment and were willing to volunteer their time and resources. We thank them for this effort. This Report is organized in three parts: the first part is a paper summarizing the results of the Workshop, and presenting some conclusions regarding the various methods; the second part is a compilation of those documents describing the experiments that were presented at the meeting (a few of the reports have had minor post-meeting revisions, but with only one exception noted later, none of the models were changed). The final part of this Report is a compilation of the presentations from the meeting -- these are largely in the form of Powerpoint files. No attempt has been made by the compilers to edit the material in parts 2 and 3. It is included here as is for the benefit of the reader.

California↗

USGS2007

Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group--Determination of dissolved isoxaflutole and its sequential degradation products, diketonitrile and benzoic acid, in water using solid-phase extraction and liquid chromatography/tandem mass spectrometry

An analytical method for the determination of isoxaflutole and its sequential degradation products, diketonitrile and a benzoic acid analogue, in filtered water with varying matrices was developed by the U.S. Geological Survey Organic Geochemistry Research Group in Lawrence, Kansas. Four different water-sample matrices fortified at 0.02 and 0.10 ug/L (micrograms per liter) are extracted by vacuum manifold solid-phase extraction and analyzed by liquid chromatography/tandem mass spectrometry using electrospray ionization in negative-ion mode with multiple-reaction monitoring (MRM). Analytical conditions for mass spectrometry detection are optimized, and quantitation is carried out using the following MRM molecular-hydrogen (precursor) ion and product (p) ion transition pairs: 357.9 (precursor), 78.9 (p), and 277.6 (p) for isoxaflutole and diketonitrile, and 267.0 (precursor), 159.0 (p), and 223.1 (p) for benzoic acid. 2,4-dichlorophenoxyacetic acid-d3 is used as the internal standard, and alachlor ethanesulfonic acid-d5 is used as the surrogate standard. Compound detection limits and reporting levels are calculated using U.S. Environmental Protection Agency procedures. The mean solid-phase extraction recovery values ranged from 104 to 108 percent with relative standard deviation percentages ranging from 4.0 to 10.6 percent. The combined mean percentage concentration normalized to the theoretical spiked concentration of four water matrices analyzed eight times at 0.02 and 0.10 ug/L (seven times for the reagent-water matrix at 0.02 ug/L) ranged from approximately 75 to 101 percent with relative standard deviation percentages ranging from approximately 3 to 26 percent for isoxaflutole, diketonitrile, and benzoic acid. The method detection limit (MDL) for isoxaflutole and diketonitrile is 0.003 ug/L and 0.004 ug/L for benzoic acid. Method reporting levels (MRLs) are 0.011, 0.010, and 0.012 ug/L for isoxaflutole, diketonitrile, and benzoic acid, respectively. On the basis of the calculated MRLs and MDLs and evaluation of the signal-to-noise ratios for each compound, the MRLs and MDLs are set at 0.010 and 0.003 ug/L, respectively, for all three compounds.

Techniques and Methods↗

USGS2014

National Oceanic and Atmospheric Administration hydrographic survey data used in a U.S. Geological Survey regional geologic framework study along the Delmarva Peninsula

The U.S. Geological Survey initiated a research effort in 2014 to define the geologic framework of the Delmarva Peninsula inner continental shelf, which included new data collection and assembly of relevant extant datasets. Between 2006 and 2011, Science Applications International Corporation, under contract to the National Oceanic and Atmospheric Administration National Ocean Service, carried out 23 hydrographic surveys covering more than 4,100 square kilometers of the continental shelf using Reson multibeam echosounders and Klein towed sidescan sonars to update nautical charts along the Delmarva Peninsula. Acoustic backscatter data from these instruments are valuable for characterizing aspects of shallow geologic framework, including seafloor geology, sediment transport pathways, and marine resources. The data cover an area that extends from the entrance of Delaware Bay, Delaware, south to Parramore Island, Virginia, in water depths of about 3 to 35 meters below mean lower low water. Data were collected along lines spaced 40 meters apart, resulting in 40 to 100 percent seafloor coverage for multibeam bathymetry. Processed bathymetric data within the Delmarva Peninsula study area are available through a National Ocean Service interactive map interface, but towed sidescan data products are limited, and multibeam backscatter data products have not been available in the past. The U.S. Geological Survey obtained raw Reson multibeam data files from Science Applications International Corporation and the National Oceanic and Atmospheric Administration for 20 hydrographic surveys and extracted backscatter data using the Fledermaus Geocoder Toolbox from Quality Positioning Service. The backscatter mosaics produced by the U.S. Geological Survey for the inner continental shelf of the Delmarva Peninsula using National Oceanic and Atmospheric Administration data increased regional geophysical surveying efficiency, collaboration among government agencies, and the area over which geologic data can be interpreted by the U.S. Geological Survey. This report describes the methods by which the backscatter data were extracted and processed and includes backscatter mosaics and interpolated bathymetric surfaces.

Delaware, Maryland, Virginia↗

USGS2008

Chemical and stable isotopic composition of water and gas in the Fort Union Formation of the Powder River Basin, Wyoming and Montana: Evidence for water/rock interaction and the biogenic origin of coalbed natural gas

Significant amounts (> 36 million m3/day) of coalbed methane (CBM) are currently being extracted from coal beds in the Paleocene Fort Union Formation of the Powder River Basin of Wyoming and Montana. Information on processes that generate methane in these coalbed reservoirs is important for developing methods that will stimulate additional production. The chemical and isotopic compositions of gas and ground water from CBM wells throughout the basin reflect generation processes as well as those that affect water/rock interaction. Our study included analyses of water samples collected from 228 CBM wells. Major cations and anions were measured for all samples, δDH2O and δ18OH2O were measured for 199 of the samples, and δDCH4 of gas co-produced with water was measured for 100 of the samples. Results show that (1) water from Fort Union Formation coal beds is exclusively Na–HCO3-type water with low dissolved SO4 content (median < 1 mg/L) and little or no dissolved oxygen (< 0.15 mg/L), whereas shallow groundwater (depth generally < 120 m) is a mixed Ca–Mg–Na–SO4–HCO3 type; (2) water/rock interactions, such as cation exchange on clay minerals and precipitation/dissolution of CaCO3 and SO4 minerals, account for the accumulation of dissolved Na and depletion of Ca and Mg; (3) bacterially-mediated oxidation–reduction reactions account for high HCO3 (270–3310 mg/L) and low SO4 (median < 0.15 mg/L) values; (4) fractionation between δDCH4 (− 283 to − 328 per mil) and δDH2O (− 121 to − 167 per mil) indicates that the production of methane is primarily by biogenic CO2 reduction; and (5) values of δDH2O and δ18OH2O (− 16 to − 22 per mil) have a wide range of values and plot near or above the global meteoric water line, indicating that the original meteoric water has been influenced by methanogenesis and by being mixed with surface and shallow groundwater.

International Journal of Coal Geology↗

USGS2020

Liquid chromatographic method for determining the concentration of bisazir in water

Barrier dams, traps, and lampricides are the techniques currently used by the Great Lakes Fishery Commission to control sea lampreys {Petromyzon marinug) in the Great Lakes. To augment these control techniques, a sterile-male-release research program was initiated at the Lake Huron Biological Station. Male sea lampreys were sterilized by intraperitoneal injection of the chemical sterilant P,P-bis(1-aziridinyl)- N methylphosphinothioic amide (bisazir). An analytical method was needed to quantitate the concentration of bisazir in water and to routinely verify that bisazir (>25 μg/L) does not persist in the treated effluent discharged from the sterilization facility to Lake Huron. A rapid, accurate, and sensitive liquid chromatographic (LC) method was developed for determining bisazir in water. Bisazir was dissolved in Lake Huron water; extracted and concentrated on a C 18 solid-phase extraction column; eluted with methanol; and quantitated by reversed-phase LC using a Cis column, amobile phase of 70% water and 30% methanol (v/v), and UV detection (205 nm). Bisazir retention time was 7-8 min; total run time was about 20 min. Method detection limit for bisazir dissolved in Lake Huron water was about 15 μg/L. Recovery from Lake Huron water fortified with bisazir at 100 μg/L was 94% (95% confidence interval, 90.2-98.2%).

Journal of AOAC International↗

USGS2007

Structure and composition of a watershed-scale sediment information network

A 'Watershed-Scale Sediment Information Network' (WaSSIN), designed to complement UNESCO's International Sedimentation Initiative, was endorsed as an initial project by the World Association for Sedimentation and Erosion Research. WaSSIN is to address global fluvial-sediment information needs through a network approach based on consistent protocols for the collection, analysis, and storage of fluvial-sediment and ancillary information at smaller spatial scales than those of the International Sedimentation Initiative. As a second step of implementation, it is proposed herein that the WaSSIN have a general structure of two components, (1) monitoring and data acquisition and (2) research. Monitoring is to be conducted in small watersheds, each of which has an established database for discharge of water and suspended sediment and possibly for bed load, bed material, and bed topography. Ideally, documented protocols have been used for collecting, analyzing, storing, and sharing the derivative data. The research component is to continue the collection and interpretation of data, to compare those data among candidate watersheds, and to determine gradients of fluxes and processes among the selected watersheds. To define gradients and evaluate processes, the initial watersheds will have several common attributes. Watersheds of the first group will be: (1) six to ten in number, (2) less than 1000 km2 in area, (3) generally in mid-latitudes of continents, and (4) of semiarid climate. Potential candidate watersheds presently include the Weany Creek Basin, northeastern Australia, the Zhi Fanggou catchment, northern China, the Eshtemoa Watershed, southern Israel, the Metsemotlhaba River Basin, Botswana, the Aiuaba Experimental Basin, Brazil, and the Walnut Gulch Experimental Watershed, southwestern United States.

International Journal of Sediment Research↗

USGS1997

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Water-Resources Investigations Report↗

USGS2023

Simulation of regional groundwater flow and advective transport of per- and polyfluoroalkyl substances, Joint Base McGuire-Dix-Lakehurst and vicinity, New Jersey, 2018

A three-dimensional numerical model of groundwater flow was developed and calibrated for the unconsolidated New Jersey Coastal Plain aquifers underlying Joint Base McGuire-Dix-Lakehurst (JBMDL) and vicinity, New Jersey, to evaluate groundwater flow pathways of per- and polyfluoroalkyl substances (PFAS) contamination associated with use of aqueous film forming foam (AFFF) at the base. The regional subsurface flow model spans an area of approximately 518 square miles around JBMDL and is based on a previously developed hydrogeologic framework of the area. Steady-state flow in the unconsolidated aquifers was simulated using the MODFLOW 6 groundwater flow model, which is able to account for hydrostratigraphic pinchouts and discontinuities in the Coastal Plain aquifers underlying JBMDL. To account for local patterns of fluid flow driving advective subsurface migration of PFAS, the grid was refined using quadtree meshes spanning 21 areas where historical AFFF use was identified, five off-site reconnaissance areas identified by AFCEC as areas in which the occurrence of PFAS is most likely to pose a potential danger to local drinking water supplies, and along streams that behave as drains in the base-flow-dominated Coastal Plain. Following grid refinement, four physical processes known to govern subsurface flow were introduced to the model. These included effective precipitation recharge, discharge to streams and stream-connected wetlands, regional inflows and outflows along the model bottom, and withdrawals from wells, each of which were incorporated into the model as either external or internal boundary conditions. To account for effective precipitation recharge, a specified-flow boundary was assigned along the top of the model. Similarly, regional flows predicted using the modified U.S Geological Survey’s New Jersey Coastal Plain Regional Aquifer System Analysis model were treated as specified-flow boundary conditions along the bottom of the model. Base-flow losses were treated as drains along streams delineated using a 10-foot LiDAR dataset. Drains were also assigned to cells falling within stream-connected National Hydrologic Database wetlands. Finally, well-pumpage data mined from the New Jersey Water Transfer database were added to the model to account for extraction of groundwater through pumping from industrial-supply and drinking-water-supply wells. Along model edges established at groundwater divides, where the net flux of water across the boundary is equal to zero, natural no-flow boundary conditions were imposed. The refined flow model was calibrated using the parameter-estimation (PEST) program, which adjusts model parameters by performing a gradient search over the sum-of-squared-error objective function until the parameter set that produces simulated water levels and base flows most closely matches 544 water levels and 20 estimated base flows and closely adheres to initial parameter estimates. Based on the analysis of calibration residuals, the model did not appear to be affected by significant model structural error. The MODPATH particle-tracking algorithm was used to estimate advective transport paths of PFAS in the vicinity of JBMDL. Forward tracking was used to determine paths of PFAS away from AFFF source areas to streams, wetlands, pumping wells, and geographic areas that PFAS may contaminate. Additionally, reverse tracking was used to determine particle pathlines away from off-site PFAS reconnaissance areas, or areas within which all sources of PFAS might be advectively transported into subsurface drinking-water supplies, to locations at land surface that may indicate a source of PFAS. The coupled and calibrated groundwater flow and particle-tracking transport model provide valuable tools for predicting the relative extent of PFAS contamination from onsite legacy source areas. The calibrated model also provides measures of water-level and base-flow observation influence that can help guide future data-collection efforts related to groundwater and surface water sampling for PFAS.

New Jersey↗

USGS2013

Evaluation of potential sources and transport mechanisms of fecal indicator bacteria to beach water, Murphy Park Beach, Door County, Wisconsin

Fecal Indicator Bacteria (FIB) concentrations in beach water have been used for many years as a criterion for closing beaches due to potential health concerns. Yet, current understanding of sources and transport mechanisms that drive FIB occurrence remains insufficient for accurate prediction of closures at many beaches. Murphy Park Beach, a relatively pristine beach on Green Bay in Door County, Wis., was selected for a study to evaluate FIB sources and transport mechanisms. Although the relatively pristine nature of the beach yielded no detection of pathogenic bacterial genes and relatively low FIB concentrations during the study period compared with other Great Lakes Beaches, its selection limited the number of confounding FIB sources and associated transport mechanisms. The primary sources of FIB appear to be internal to the beach rather than external sources such as rivers, storm sewer outfalls, and industrial discharges. Three potential FIB sources were identified: sand, swash-zone groundwater, and Cladophora mats. Modest correlations between FIB concentrations in these potential source reservoirs and FIB concentrations at the beach from the same day illustrate the importance of understanding transport mechanisms between FIB sources and the water column. One likely mechanism for transport and dispersion of FIB from sand and Cladophora sources appears to be agitation of Cladophora mats and erosion of beach sand due to storm activity, as inferred from storm indicators including turbidity, wave height, current speed, wind speed, sky visibility, 24-hour precipitation, and suspended particulate concentration. FIB concentrations in beach water had a statistically significant relation (p-value &lsaquo;0.05) with the magnitude of these storm indicators. In addition, transport of FIB in swash-zone groundwater into beach water appears to be driven by groundwater recharge associated with multiday precipitation and corresponding increased swash-zone groundwater discharge at the beach, as indicated by an increase in the specific conductance of beach water. Understanding the dynamics of FIB sources (sand, swash-zone groundwater, and Cladophora ) and transport mechanisms (dispersion and erosion from storm energy, and swash-zone groundwater discharge) is important for improving predictions of potential health risks from FIB in beach water.

Wisconsin↗

USGS2012

Contaminants in stream sediments from seven United States metropolitan areas: part II—sediment toxicity to the amphipod Hyalella azteca and the midge Chironomus dilutus

Relationships between sediment toxicity and sediment chemistry were evaluated for 98 samples collected from seven metropolitan study areas across the United States. Sediment-toxicity tests were conducted with the amphipod Hyalella azteca (28 day exposures) and with the midge Chironomus dilutus (10 day exposures). Overall, 33 % of the samples were toxic to amphipods and 12 % of the samples were toxic to midge based on comparisons with reference conditions within each study area. Significant correlations were observed between toxicity end points and sediment concentrations of trace elements, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), or organochlorine (OC) pesticides; however, these correlations were typically weak, and contaminant concentrations were usually below sediment-toxicity thresholds. Concentrations of the pyrethroid bifenthrin exceeded an estimated threshold of 0.49 ng/g (at 1 % total organic carbon) in 14 % of the samples. Of the samples that exceeded this bifenthrin toxicity threshold, 79 % were toxic to amphipods compared with 25 % toxicity for the samples below this threshold. Application of mean probable effect concentration quotients (PECQs) based on measures of groups of contaminants (trace elements, total PAHs, total PCBs,OCpesticides, and pyrethroid pesticides [bifenthrin in particular]) improved the correct classification of samples as toxic or not toxic to amphipods compared with measures of individual groups of contaminants. Sediments are a repository for many contaminants released into surface waters. Because of this, organisms inhabiting sediments may be exposed to a wide range of contaminants (United States Environmental Protection Agency (USEPA) United States Environmental Protection Agency 2000; American Society for Testing and Materials [ASTM] American Society for Testing and Materials International 2012). Contaminants of potential concern in sediments typically include trace elements (metals), organochlorine (OC) pesticides, polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs; Ingersoll et al. 2001). In 2000, the USEPA began to restrict the use of organophosphate pesticides, such as diazinon and chlorpyrifos (Spurlock and Lee 2008). These restrictions have led to increased use of pyrethroid pesticides, which have widespread applications in both agricultural and urban environments (Kuivila et al. 2012). Pyrethroids are hydrophobic compounds that have been observed to accumulate in sediments (Laskowski 2002). Toxicity of pyrethroids in field-collected sediment from small urban streams (Weston et al. 2005; Holmes et al. 2008; Ding et al. 2010; Domagalski et al. 2010) or with pyrethroids spiked into sediment (Amweg et al. 2006; Hintzen et al. 2009) have been evaluated primarily in 10 day lethality tests conducted with the amphipod Hyalella azteca . However, the sublethal effects in long-term exposures to pyrethroids in sediment have not been evaluated, and the distribution of pyrethroids sediments has not typically been evaluated in wadeable streams (Gilliom et al. 2006). This article is the second in a series that describe the results of a study of the distribution and toxicity of pyrethroids and other co-occurring trace elements and organic contaminants (PCBs, PAHs, OC pesticides) in stream sediments from 7 metropolitan areas across the United States (Moran et al. 2012). The study evaluated 98 sediment samples collected from streams ranging from undeveloped to highly urban and differs from previous studies by sampling larger wadeable streams and avoiding point sources (such as storm drains) and other inflows (Gilliom et al. 2006). Part 1 of the series characterizes sediment contaminants in relation to urbanization and other factors in the 7 metropolitan study areas (Nowell et al. 2012). Part 2 (this article) evaluates relationships between sediment chemistry and sediment toxicity in 28 day whole-sediment exposures conducted with the amphipod H. azteca and in 10 day whole-sediment exposure conducted with the midge Chironomus dilutus (USEPA United States Environmental Protection Agency 2000; ASTM American Society for Testing and Materials International 2012). Toxicity end points evaluated in the amphipod and midge exposures included the effects of these field-collected sediments on survival, weight, or biomass of the test organisms.

Georgia;Massachusetts;Texas;Colorado;Wisconsin;Uta↗

USGS2021

Lessons learned from development of natural capital accounts in the United States and European Union

The United States and European Union (EU) face common challenges in managing natural capital and balancing conservation and resource use with consumption of other forms of capital. This paper synthesizes findings from 11 individual application papers from a special issue of Ecosystem Services on natural capital accounting (NCA) and their application to the public and private sectors in the EU and U.S. NCA is inherently a data-integration centered exercise, aiming to draw new insights by realigning environmental and economic data into a consistent framework. Drawing primarily on papers from the special issue and other key NCA literature, we identify lessons learned and gaps remaining for NCA’s development and application to decision making. In doing so, we identify eight key similarities and three major differences in NCA development, status, and application between the U.S. and EU. NCA can be highly policy relevant: special issue papers address critical issues including agriculture, water, conservation/land-use planning, climate, and corporate decision making. In both the U.S. and EU, further application is needed to drive demand for the accounts’ production. Based on these experiences, the U.S. and EU can be important leaders in cross-sector, international collaboration toward next-generation environmental economic accounts that advance global NCA practice.

Ecosystem Services↗