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At least 667 records · Page 37Linked to original sources
USGS1984

Geohydrologic and drill-hole data for test well USW H-4, Yucca Mountain, Nye County, Nevada

Data are presented on drilling operations, lithology, geophysical well logs, sidewall-core samples, water-level monitoring, pumping tests, injection tests, radioactive-tracer borehole flow survey, and water chemistry for test well USW H-4. The well is one of a series of test wells drilled in the southwestern part of the Nevada Test Site, Nye County, Nevada, in cooperation with the U.S. Department of Energy. These test wells are part of the Nevada Nuclear Waste Storage Investigations to identify sites for storage of high-level radioactive wastes. Test well USW H-4 was drilled in ash-flow tuff to a total depth of 1,219 meters. Depth to water below land surface was 519 meters or at an altitude of 730 meters above sea level. After test pumping at a rate of 17.4 liters per second for approximately 9 days, the drawdown was 4.85 meters. A radioactive borehole-flow survey indicated that the Bullfrog Member was the most productive geologic unit, producing 36.5 percent of the water in the well. The second most productive geologic unit was the Tram Member, which produced 32 percent of the water. The water in test well USW H-4 is predominantly a soft, sodium bicarbonate type of water typical of water produced in tuffaceous rocks in southern Nevada. (USGS)

Open-File Report↗
USGS1979

Water resources of the Nisqually Lake area, Pierce County, Washington

This report presents data assembled during a July 1975 to August 1977 study of the water resources of an area within, and adjacent to, a part of the Fort Lewis Military Reservation that prior to 1917 was included in the Nisqually Indian Reservation. Because the area is within or near the artillery ranges of the U.S. Army, the existing water resources of the study area are almost undeveloped. The only surface-water bodies of significance in the study area are Muck Creek, Nisqually Lake, and springs. The flow of Muck Creek as measured at a gaging station at Roy, east of the study area, ranged from no flow to a maximum discharge of 692 cubic feet per second during the period 1956-77. No flow occurred there about 9 percent of the time during the period 19.56-71. A large spring discharged from 0.12 to 4.56 cubic feet per second during the study period. Development or diversion of Muck Creek near its mouth would provide sufficient water for a small- to medium-sized fish-rearing facility. The highest water temperature recorded at this site during the study was 14.0°C, in August 1977, with a stream discharge of 7.12 cubic feet per second. Nisqually Lake, with a surface area of about 89 acres, is shallow with a flat bottom. The existing lake water is relatively high with dissolved solids, organic nitrogen and phosphorus, and biologically productive. Species of warm-water fish are probably best suited for the lake. Ground water beneath the study area occurs in unconsolidated glacial drift or outwash of gravel, sand, silt, and clay. One of the permeable rock units is the Steilacoom Gravel of Pleistocene age. Yields to wells from this material in a nearby area are from 100 to 250 gallons per minute. Drilling of test wells in the study area would provide more reliable data on ground water.

Washington↗
USGS1966

Hydrology of the Upper Capibaribe Basin, Pernambuco, Brazil - A reconnaissance in an Area of Crystalline Rocks

The upper Capibaribe basin is the western three-fourths, approximately, of the valley of the river that empties into the Atlantic Ocean at Recife, the capital of the State of Pernambuco, Brazil. It is the part of the drainage basin that is within the Drought Polygon of northeast Brazil, and it totals about 5,400 square kilometers. It receives relatively abundant precipitation in terms of the annual average, yet is regarded as hot subhumid to semiarid because the precipitation is uneven from year to year and place to place. The dependable water supply, therefore, is small. The basin has water, which could be put to better use than at present, but the opportunities for augmenting the usable supply are not great. The streams are intermittent and therefore cannot be expected to fill surface reservoirs and to keep them filled. The ground-water reservoirs have small capacity--quickly filled and quickly drained. A rough estimate based on the records for 1964 suggests that, of 4,700 million cubic meters of precipitation in the upper Capibaribe basin, 2,700 million cubic meters (57 percent) left the basin as runoff and 2,000 million cubic meters {43 percent) went into underground storage or was evaporated or transpired. The bedrock of the upper Capibaribe basin is composed of granite, gneiss, schist, and other varieties of crystalline rocks, which have only insignificant primary permeability. They are permeable mainly where fractured. The principal fracture zones, fortunately, are in the valleys, where water accumulates and can feed into them, but the volume of fractured rock is small in relation to the basin as a whole. A well in a large water-filled fracture zone may yield up to 20,000 liters per hour, but the average well yields less than one-fourth this amount, and some wells yield none. The saprolite, or weathered rock, is many meters thick at some places especially in the eastern half of the upper Capibaribe basin. It contains water locally, but ordinarily will yield only small quantities to wells. The alluvium probably is the most productive aquifer in the basin, but is limited to narrow bands along the rivers that generally are no more than a few hundred meters wide and 5 meters thick. The alluvium contains variable amounts of silty sand capable of yielding small to moderate quantities of water to wells. Wells driven or dug into the alluvium could solve many small water problems. The chemical quality of the water in the upper Capibaribe basin ranges from good to bad and generally presents a major problem that cannot be solved solely by applying geological criteria. Mineralized water is widespread in the area, both in streams and underground, and .the choice of aquifers is small. All known aquifers contain, at one place or another, water that is mineralized, leaving no alternative for a natural supply of good-quality water. Although much of the available water is unsatisfactory for human consumption, it is generally acceptable for animals and therefore meets one of the principal water needs. Some of the ground water could be made potable by diluting it with rainwater, which could be collected during rainy seasons and temporarily stored in cisterns or reservoirs.

Water Supply Paper↗
USGS1999

Chlorine-bearing amphiboles from the Fraser mine, Sudbury, Ontario, Canada: Description and crystal chemistry

Three chemically distinct populations of Cl-bearing amphibole have been recognized in association with contact Ni-Cu ore deposits in Footwall Breccia at the Fraser mine, Sudbury, Ontario. The first population, defined as halogen-poor (<0.5 wt.% Cl) actinolite and magnesiohornblende, occurs predominantly as pale green grains and cores. These are generally overgrown by amphibole of the other two populations: a) Fe-rich, halogen-poor deep green rim of ferro-actinolite to ferrohornblende, and b) Fe-rich, Cl-rich (up to 4 wt.% Cl) ferrotschermakite to hastingsite to potassic-chlorohastingsite, which exhibits a characteristic deep blue-green pleochroism. Rare F-rich (up to 1.1 wt.% F) magnesiohornblende also is observed in the same environment. Major-element data for the Cl-rich amphiboles indicate linear, positive relationships for both Mg and K versus Cl, and a logarithmic, positive one for ([4])Al versus Cl. These data, along with selected X-ray maps, indicate that Cl is homogeneously distributed and likely structurally bound. Calculated Fe3+/Fe2+ values suggest crystallization under conditions of relatively low f(O2). At least two chemically distinct fluids seem to have been responsible for crystallization of the amphiboles. The first, which resulted in the crystallization of halogen-poor, pale green actinolite and magnesiohornblende, was likely relatively hot (???650??C) and contemporaneous with sulfide emplacement. This was followed by a lower-T (???350??C), Cl-rich fluid from which the Cl-rich amphiboles crystallized. This latter fluid may have been a modified product of the initial fluid or possibly a second discrete fluid. A subsequent F-rich fluid led to development of F-rich magnesiohornblende. The source of both Cl and F is not clear; whole-rock analyses of Footwall rocks of the Levack Gneiss Complex, however, reveal anomalous enrichments in both Cl (>700 ppm) and F (2500 ppm). These rocks thus may have been a significant contributor to the fluids.

Canadian Mineralogist↗
USGS1973

Microprobe analyses of sericite, chlorite, and epidote from Jerome, Arizona

Volcanic rocks in the vicinity of the massive sulfide deposits at the United Verde mine, Jerome, Ariz., have been modified in several periods of hydrothermal alteration and greenschist metamorphism. Chlorite, 2M, mica (sericite), and epidote are characteristic alteration products. Microprobe analyses for sericite, chlorite, and epidote are recalculated to structural formulas by the method employing oxygen anion equivalents. The sericite has the general composition of muscovite, but is moderately phengitic, and two samples have 6-12 percent paragonite in solid solution. Most of the chlorite is ripidolite with approximately one-third of the tetrahedral sites filled by aluminum; octahedral aluminum slightly exceeds tetrahedral. Fe:Fe+Mg+Mn ratios range from 0.34 to 0.66; low values are associated with sulfide minerals; higher values occur in a sample peripheral to the massive sulfide deposit. The epidote is a solid solution of 70 percent epidote, 30 percent clinozoisite.

Arizona↗
USGS1993

Thermal stability of hydrocarbons in nature: Limits, evidence, characteristics, and possible controls

Numerous petroleum-geochemical analyses of deeply buried, high-rank, fine-grained rocks from ultra-deep wellbores by different investigators demonstrate that C 15 + hydrocarbons (HCs) persist in moderate to high concentrations at vitrinite reflectance ( R 0 ) values of 2.0–5.0% and persist in measurable concentrations up to R 0 = 7.0–8.0%, at which point the thermal deadline for C 15 + HC's is finally approached. Qualitative analyses have been carried out on 1. (1) high-rank gas condensates which have been exposed to the HC-thermal-destructive phase, 2. (2) bitumens from high-temperature aqueous-pyrolysis experiments in the HC-thermal-destructive phase, and 3. (3) bitumens from high-rank, fine-grained rocks near the HC-thermal-destructive phase. These analyses clearly demonstrate that well-defined compositional suites are established in the saturated, aromatic, and sulfur-bearing aromatic HCs in and near the HC-thermal-destructive phase. On the other hand, accepted petroleum-geochemical paradigms place rigid limits on HC thermal stability: C 15 + HCs begin thermal cracking at R 0 values of 0.9% and are completely thermally destroyed by R 0 = 1.35%; C 2 -C 4 HC gases are thermally destroyed by R 0 = 2.0% and methane is thermally destroyed by R 0 = 4.0%. Furthermore, published data and observations in many HC basins worldwide support these models; for example, 1. (1) sharp basinal zonations of gas and oil deposits vs. maturation rank in HC basins and 2. (2) decreasing C 15 + HC concentrations in some fine-grained rocks at ranks of R 0 ≥ 0.9%. The fact that observed data (C 15 + HCs thermally stable to R 0 = 7.0–8.0%) is so far removed from predicted behavior (C 15 + ) HCs expected to be thermally destroyed by R 0 = 1.35%) may be due to 1. (1) a lack of recognition of some important possible controlling parameters of organic matter (OM) metamorphism and too much importance given to other assumed controlling parameters; and 2. (2) assigning HC distribution patterns in petroleum basins to HC thermal cracking when such patterns may be due to other causes. In the first case, laboratory experiments strongly suggest that the presence of water, increasing fluid pressures, and closed systems (product retention) all suppress OM metamorphic reactions. Conversely, the absence of water, low fluid pressures, and open systems (product escape) all promote OM metamorphic reactions. These experiments also demonstrate that OM metamorphic reactions proceed by reaction kinetics greater than first order. Thus, the effect of geologic time appears to have been over-estimated in OM metamorphism. In the second case, the strong decreases in C 15 + HC concentrations in fine-grained rocks with Type III OM over R 0 = 0.9−1.35% are most probably due to intense primary migration and loss of HCs to drilling muds during the trip uphole in drilling operations. Data from coals demonstrate that these decreases in HC concentrations cannot be due to C 15 + HC thermal destruction. Oil deposits are generally found at shallow depths in basins, and “dry gas” (methane ≤ 98% of all HC gases) deposits are found at the greatest depths. This HC distribution pattern would be caused by methane, generated during the late stages of C 15 + HC generation, flushing oil (including C 2 –C 4 HC gases condensed into the liquid phase) out of deep basinal traps by Gussow's (1954) principle of differential entrapment. Hence, only “dry gas” deposits are left in the basin deeps. Oil emplacement processes in traps during expulsion and secondary migration could also contribute to the HC distribution pattern observed in petroleum basins.

Geochimica et Cosmochimica Acta↗
USGS1964

Ground water in folded Cretaceous sandstone of the Bhachau area, Kutch, India, with reference to the Kandla Port water supply

This report is based on an investigation of the availability of ground-water supplies in the Bhachau area for the nearby Kandla Port and township development undertaken by the Government of India. This seaport lies on an estuary of the Gulf of Kutch in western India and in the eastern part of the State of Kutch. The fieldwork on the investigation was carried on from November 1952 through April 1953 with continuing hydrologic observations through 1954-55. The fieldwork included: geologic mapping and delimitation of the principal aquifers of the region; preparation of water-table maps; a detailed inventory of existing wells and springs; observations of significant water table fluctuations; preparation of isobicarb, isochlor and isosulf maps to show the areal distribution of ground-water salinity. The Bhachau area includes about 116 square miles in eastern Kutch and lies in a belt of semiarid low-latitude steppes. The mean annual rainfall is about 15 inches, most of which falls from late June to late September during the southwest monsoon. The area includes a central sandy upland ranging from about 100 to 250 feet above sea level ; a northern lowland of between about 50 to 125 feet altitude that slopes north to the Great Rann of Kutch; a belt of low buttes and discontinuous ridges ranging from about 200 to 275 feet above sea level; and southern lowland which slopes in a southerly to southeasterly direction from an altitude of about 125 feet to 25 feet or less near the Gulf of Kutch. The principal streams are Kageshwar Vokra and Kara Vokra which drain north to the Great Rann and Kotwala Vokra and Dalwala Vokra which drain south toward the Gulf of Kutch. The rocks of the Bhachau area include nonmarine and marine sediments of Mesozoic, Tertiary, and Quaternary age and volcanic rocks of late Mesozoic to early Tertiary age. The oldest rocks in the area are medium- to coarse-grained white to buff current-bedded friable sandstone with occasional partings of white silty shale of the Upper Bhuj series that has been assigned to the Early Cretaceous. The soft friable sandstone of the Upper Bhuj series constitutes the most productive ground-water reservoir in the Bhachau area. At present (1955) there are nine irrigated tracts for which water is obtained from dug wells less than 90 feet deep in the Upper Bhuj. These wells are worked by bullocks and 'motes' (leather bags) at withdrawal rates ranging from about 6,000 to 24,000imperial gallons per day; however, many existing individual wells if equipped with mechanical pumps are capable of yielding 100,000 gallons per day. The Deccan trap of Late Cretaceous to Eocene age occurs in a sequence of basaltic lava flows in the Bhachau area, but trap dikes, sills and plugs that are common in other parts of Kutch have not been observed in the area. Laterite of probable Eocene age is extensive at the top of the Deccan trap, and in places where the lava flows are thin the parent rock has been almost completely lateritized. The Deccan lava flows or the laterite, where the trap is absent, rest disconformably on the Upper Bhuj. No wells have been observed in the Deccan trap of the Bhachau area, but it is possible that locally small supplies of good water may be obtained from these rocks. The Tertiary sediments, which are assigned to the Manchhar series of Pliocene age, generally rest on the laterite or the Deccan trap ; but where both are absent, the Manchhar rests directly on the Upper Bhuj. The Manchhar series includes massive reddish-brown gypseous clay shales, laminated gray siltstones, some limestone, mottled sandstone, and laterite trap gravel. Only meager supplies of brackish water are obtained from wells in these sediments. Along the channels of Kotwala, Dalwala, Kageshwar, and Kara Vokras are narrow bands of unconsolidated coarse sand with fine gravel of Quaternary age. No wells were observed in these deposits, but it is possible that locally they may contain small supplies of bracki

Water Supply Paper↗
USGS1975

A brief history of the U.S. Geological Survey

Established by an Act of Congress in 1879 and charged with responsibility for "classification of the public lands, and examination of the geological structure, mineral resources, and products of the national domain," the U. S. Department of the Interior's Geological Survey has been the Nation's principal source of information about its physical resources the configuration and character of the land surface, the composition and structure of the underlying rocks, and the quality, extent, and distribution of water and mineral resources. Although primarily a research and fact-finding agency, it has responsibility also for the classification of Federal mineral lands and waterpower sites, and since 1926 it has been responsible for the supervision of oil and mining operations authorized under leases on Federal land. From the outset, the Survey has been concerned with critical land and resource problems. Often referred to as the Mother of Bureaus, many of its activities led to the formation of new organizations where a management or developmental function evolved. These included the Reclamation Service (1902), the Bureau of Mines (1910), the Federal Power Commission (1920), and the Grazing Service (1934, since combined with other functions as the Bureau of Land Management). Mrs. Rabbitt's summary of the Survey's history in the following pages brings out well the development of these diverse activities and the Survey's past contributions to national needs related to land and resources.

General Information Product↗
USGS2007

Chapter 7 Magmatic-hydrothermal fluid interaction and mineralization in alkali-syenite nodules from the Breccia Museo pyroclastic deposit, Naples, Italy

The Breccia Museo, a pyroclastic flow that crops out in the Campi Flegrei volcanic complex (Naples, Italy), contains alkali-syenite (trachyte) nodules with enrichment in Cl and incompatible elements (e.g., U, Zr, Th, and rare-earth elements). Zircon was dated at ≈52 ka, by U-Th isotope systematics using a SHRIMP. Scanning electron microscope and electron microprobe analysis of the constituent phases have documented the mineralogical and textural evolution of the nodules of feldspar and mafic accumulations on the magma chamber margins. Detailed electron microprobe data are given for alkali and plagioclase feldspar, salite to ferrosalite clinopyroxene, pargasite, ferrogargasite, magnesio-hastingsite hornblende amphibole, biotite mica, Cl-rich scapolite, and a member (probable davyne-type) of the cancrinite group. Detailed whole rock, major and minor element data are also presented for selected nodules. A wide variety of common and uncommon accessory minerals were identified such as zircon, baddeleyite, zirconolite, pollucite, sodalite, titanite, monazite, cheralite, apatite, titanomagnetite and its alteration products, scheelite, ferberite, uraninite/thorianite, uranpyrochlore, thorite, pyrite, chalcopyrite, and galena. Scanning electron microscope analysis of opened fluid inclusions identified halite, sylvite, anhydrite, tungstates, carbonates, silicates, sulfides, and phosphates; most are probably daughter minerals. Microthermometric determinations on secondary fluid inclusions hosted by alkali feldspar define a temperature regime dominated by hypersaline aqueous fluids. Fluid-inclusion temperature data and mineral-pair geothermometers for coexisting feldspars and hornblende and plagioclase were used to construct a pressure-temperature scenario for the development and evolution of the nodules. We have compared the environment of porphyry copper formation and the petrogenetic environment constructed for the studied nodules. The suite of ore minerals observed in the nodules supports a potential for mineralization, which is similar to that observed in the alkaline volcanic systems of southern Italy (Pantelleria, Pontine Archipelago, Mt. Somma-Vesuvius).

Campi Flegrei↗
USGS1967

The porphyry copper deposit exposed in the Liberty open-pit mine near Ely, Nevada; Part 2, The formation of hydrothermal alteration zones

In the southwest part of the Liberty pit a large porphyry body exhibits a zonal alteration pattern related to fissures and pyrite-bearing veins. The outermost zone contains unaltered K-feldspar, kaolinite after plagioclase, and black biotite after hornblende. An intermediate zone contains reconstituted K-feldspar, phlogopitic biotite, and muscovite or muscovite plus K-feldspar replacing only plagioclase. In the innermost zone the only silicates are quartz and muscovite. In some places an alteration band of K-feldspar after plagioclase separates kaolinite and muscovite.The widespread association of kaolinite and K-feldspar in hydrothermal alteration zones suggests that these two minerals were stable together at the time of formation. Experimental data show that, where quartz controls the activity of silica in solution, kaolinite and K-feldspar should react to form muscovite. However, calculations predict that, at 15,000 psi, solutions with silica activities compatible with amorphous or gelatinous silica could stabilize K-feldspar and kaolinite relative to muscovite at temperatures below about 250 degrees C. The rapid decomposition either of plagioclase feldspar or montmorillonite is considered a prime cause for the attainment of such high activities of silica in pore solutions of rock. The supersaturation of pore solutions with silica is a transient condition; quartz precipitates where kaolinite and K-feldspar react to give muscovite. Thus, the zonally distributed alteration at Ely is considered to have taken place after the rock had cooled to below 250 degrees C. In contrast, the diffusely distributed muscovite and montmorillonite found in another portion of the pit probably commenced at 600 degrees to 700 degrees C with only minor formation of alteration products below 250 degrees C.

Nevada↗
USGS2002

Petroleum geology and total petroleum systems of the Widyan Basin and Interior Platform of Saudi Arabia and Iraq

Two total petroleum systems are associated with the Widyan Basin - Interior Platform Province in northern Saudi Arabia and western Iraq. In the Paleozoic Qusaiba/Akkas/Abba/ Mudawwara Total Petroleum System, which consists of one assessment unit - the Horst/Graben-Related Oil and Gas Assessment Unit - high-gravity, low-sulfur crude oil, as well as natural gas, occurs in horst/graben-related traps that formed prior to, during, and after Hercynian deformation (Carboniferous). The source of oil and gas is from organic-rich marine shale at the base of the Silurian sedimentary sequence (Qusaiba, Akkas, Mudawwara, and Abba Formations) that was deposited under dysoxic to anoxic conditions in an intra-shelf basin located north of the Central Arabian Arch. Onset of oil generation in Iraq began about 250 million years ago (Ma) and in eastern Saudi Arabia about 160 Ma, reaching peak generation, expulsion, migration, and entrapment during the Jurassic Period. In Saudi Arabia, petroleum migrated into fluvial and eolian quartzose sandstones of the Carboniferous-Early Permian Unayzah Formation that overlies the Hercynian unconformity, filling in rifts and half-grabens to thicknesses ranging to more than 400 meters. Combined stratigraphic-structural traps exist where the Unayzah Formation is the reservoir, as is the case in central Saudi Arabia. Oil and gas are sealed in those reservoirs by overlying tight carbonate- evaporite strata, and by subunconformity pinchouts of Pre-Unayzah clastic reservoir units against impermeable facies. In Iraq, reservoirs are sandstones of the Ordovician Upper Khabour and Silurian Akkas Formations. Over most of the Southwestern Desert of Iraq, Lower Silurian shale is a seal for hydrocarbons in the underlying Ordovician Khabour Formation. The Jurassic Gotnia/Barsarin/Sargelu/Najmah Total Petroleum System has two assessment units: the Platform Horst/Graben- Related Oil Assessment Unit and the Basinal Oil and Gas Assessment Unit. All reservoirs are in the Upper Jurassic Najmah Limestone and Gotnia Formation in Iraq, and the correlative Arab Formation in Saudi Arabia, occurring as lenses of marine bar or shelf-margin calcarenites, calcarenitic limestone, and dolomite. These strata grade eastward into organic-rich source rocks that were deposited under anoxic and dysoxic conditions in three restricted intra-shelf basins - from north to south, the Gotnia, Arabian, and Southern Arabian Gulf Basins. Maturation of the Upper Jurassic source-rock formations (Sargelu and Naokelekan Formations in Iraq) began around 90 Ma; peak generation took place from 85 to 13 Ma. With time, the oil migrated updip and was trapped in calcarenite lenses. Later, oil remigrated and was trapped in anticlines that began to form in Early Cretaceous time. Younger Jurassic shale and anhydrite seal rocks are distributed throughout the total petroleum system. The Widyan Basin-Interior Platform Province (2023) ranks 17th in the world, exclusive of the United States, with 62.5 billion barrels of oil equivalent of total petroleum endowment (cumulative production plus remaining petroleum plus estimated mean undiscovered volumes). Mean estimates of undiscovered petroleum for the province, which includes both Paleozoic and Jurassic petroleum systems as well as portions of three additional total petroleum systems from adjacent provinces, are 21.22 billion barrels of oil, 94.75 trillion cubic feet of gas (15.8 billion barrels of oil equivalent), and 6.85 billion barrels of natural gas liquids. The Paleozoic total petroleum system is dominantly gas prone, whereas the volumetrically larger Jurassic total petroleum system is oil prone - resulting in the characterization of the province as an oil province. The discovery maturity for the province is a relatively low 31 percent, meaning that much of the province petroleum potential lies in the future.

Arabian Peninsula↗
USGS1968

Tertiary gold-bearing channel gravel in northern Nevada County, California

The remains of a huge Tertiary gravel-filled channel lie in the area between the South and Middle Yuba Rivers in northern Nevada County, Calif. The deposits in this channel were the site of some of the most productive hydraulic gold mines in California between the 1850's and 1884. The gravel occupies a major channel and parts of several tributaries that in Tertiary time cut into a surface of Paleozoic and Mesozoic igneous and metamorphic rocks. The gravel is partly covered by the remains of an extensive sheet of volcanic rocks, but it crops out along the broad crest of the ridge between the canyons of the South and Middle Yuba Rivers. The lower parts of the gravel deposits generally carry the highest values of placer gold. Traditionally, the richest deposits of all are found in the so-called blue gravel, which, when present, lies just above the bedrock and consists of a very coarse, poorly sorted mixture of cobbles, pebbles, sand, and clay. It is unoxidized, and, at least locally, contains appreciable quantities of secondary sulfide minerals, chiefly pyrite. Information in drill logs from private sources indicates that a 2-mile stretch of the channel near North Columbia contains over half a million ounces of gold dispersed through about 22 million cubic yards of gravel at a grade .averaging about 81 cents per cubic yard. The deposit is buried at depths ranging from 100 to 400 feet. Several geophysical methods have been tested for their feasibility in determining the configuration of the buried bedrock surface, in delineating channel gravel buried under volcanic rocks, and in identifying concentrations of heavy minerals within the gravel. Although the data have not yet been completely processed, preliminary conclusions indicate that some methods may be quite useful. A combination of seismic-refraction and gravity methods was used to determine the depth and configuration of the bottom of the channel to an accuracy within 10 percent as checked by the drill holes. Seismic-refraction methods have identified depressions which are in the bedrock surface, below volcanic rocks, and which may be occupied by gravels. Seismic methods, however, cannot actually recognize the presence of low-velocity gravels beneath the higher velocity volcanic rocks. Electromagnetic methods, supplemented in part by induced-polarization methods, show promise of being able to recognize and trace blue gravel buried less than 200 feet deep. A broad vague magnetic anomaly across the channel suggests that more precise magnetic studies might delineate concentrations of magnetic material. The usefulness of resistivity methods appears from this study to be quite restricted because of irregular topography and the variable conductivity of layers within the gravel.

Circular↗
USGS2015

Mineral potential tracts for orogenic, Carlin-like, and epithermal gold deposits in the Islamic Republic of Mauritania, (phase V, deliverable 69)

The gold resources of Mauritania presently include two important deposits and a series of poorly studied prospects. The Tasiast belt of deposits, which came into production in 2007, is located in the southwestern corner of the Rgue&iuml;bat Shield and defines a world-class Paleoproterozoic(?) orogenic gold ore system. The producing Guelb Moghrein deposit occurs along a shear zone in Middle Archean rocks at the bend in the Northern Mauritanides and is most commonly stated to be an iron oxide-copper-gold (IOCG) type of deposit, although it also has some important characteristics of orogenic gold and skarn deposits. Both major deposits are surrounded by numerous prospects that show similar mineralization styles. The Guelb Moghrein deposit, and IOCG deposit types in general are discussed in greater detail in a companion report by Fernette (2015). In addition, many small gold prospects, which are probably orogenic gold occurrences and are suggested to be early Paleozoic in age, occur along the length of Southern Mauritanides. Existing data indicate the gold deposits and prospects in Mauritania have a sulfide assemblage most commonly dominated by pyrrhotite and chalcopyrite, and have ore-related fluids with apparently high salinities. A preliminary evaluation of these gold data can be used to develop broad, firstorder tracts defining favorable and permissive areas for gold resources; detailed metamorphic and structural maps are required for more detailed future tract definition. Such a first-order assessment can, nonetheless, broadly identify four tracts of gold resource potential. Three of these are favorable for discovery of new orogenic gold deposits. One tract, although not favorable, is nevertheless permissive for discovery of epithermal gold deposits. Tract 1 is defined by favorable medium metamorphic grade greenstone belts within vast areas of unfavorable high metamorphic grade, Mesoarchean and Paleoproterozoic granite-gneiss basement of the Rgue&iuml;bat Shield. Faults >200 km in length following the general strike of the greenstone belts; lineament intersections with both exposed and buried parts of greenstone belts within 500 m of the surface, as defined by aeromagnetic data (Finn and Anderson, 2015); and areas of banded iron formation (BIF) in the belts are particularly favorable areas for hosting gold resources in orogenic gold deposits within and along the margins of the greenstone belts. Tracts 2 and 3, also for orogenic gold, reflect the favorable Proterozoic-Cambrian metamorphic rocks of the Northern and Southern Mauritanides, with >200-km-long faults following the general strike of the range, and areas underlain by ultramafic and BIF rocks being particularly favorable. Outcrops of Triassic-Jurassic igneous rocks along the margins of the Taoudeni Basin define tract 4, which is permissive for epithermal gold deposits. Although extensive data are lacking for the area, carbonate units along the northern side of the Taoudeni Basin could be considered permissive host rocks for Carlin-type mineralization, but the deep-water carbonate lithologies are typically not favorable for such.

Open-File Report↗
USGS1999

Age, double porosity, and simple reaction modifications for the MOC3D ground-water transport model

This report documents modifications for the MOC3D ground-water transport model to simulate (a) ground-water age transport; (b) double-porosity exchange; and (c) simple but flexible retardation, decay, and zero-order growth reactions. These modifications are incorporated in MOC3D version 3.0. MOC3D simulates the transport of a single solute using the method-of-characteristics numerical procedure. The age of ground water, that is the time since recharge to the saturated zone, can be simulated using the transport model with an additional source term of unit strength, corresponding to the rate of aging. The output concentrations of the model are in this case the ages at all locations in the model. Double porosity generally refers to a separate immobile-water phase within the aquifer that does not contribute to ground-water flow but can affect solute transport through diffusive exchange. The solute mass exchange rate between the flowing water in the aquifer and the immobile-water phase is the product of the concentration difference between the two phases and a linear exchange coefficient. Conceptually, double porosity can approximate the effects of dead-end pores in a granular porous media, or matrix diffusion in a fractured-rock aquifer. Options are provided for decay and zero-order growth reactions within the immobile-water phase. The simple reaction terms here extend the original model, which included decay and retardation. With these extensions, (a) the retardation factor can vary spatially within each model layer, (b) the decay rate coefficient can vary spatially within each model layer and can be different for the dissolved and sorbed phases, and (c) a zero-order growth reaction is added that can vary spatially and can be different in the dissolved and sorbed phases. The decay and growth reaction terms also can change in time to account for changing geochemical conditions during transport. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model tests illustrate use of these modifications and demonstrate that accurate solutions can be obtained for these simple cases. Two test cases have no dispersion, illustrating the suitability of this method-of-characteristics model for simulation of advection-dominated transport in ground water.

Water-Resources Investigations Report↗
USGS1982

Hydrogeology and results of injection tests at waste-injection test sites in Pinellas County, Florida

Potential benefits or hazards to freshwater resources could result from subsurface injection of treated wastewater. Recognizing this, the U.S. Geological Survey, in cooperation with Pinellas County and the city of St. Petersburg, undertook an evaluation of the hydrogeology and injection of wastewater at proposed test sites on the Pinellas peninsula. The injection sites are underlain by sedimentary rocks ranging in age from Cretaceous to Pleistocene. Lower Eocene carbonate rocks were penetrated to a maximum depth of 3,504 feet and were found to have relatively low water yields. The most permeable part of the investigated section was in rocks of middle Eocene age within the Floridan aquifer. At the injection sites, the Floridan aquifer was subdivided into four permeable zones and three semiconfining beds. The test injection zone is within the Avon Park Limestone, the most productive of the identified permeable zones, with a transmissivity of about 1,000,000 feet squared per day. Two semiconfining beds are above the injection zone in the Suwannee Limestone and Ocala Limestone and have vertical hydraulic conductivities estimated to range from about 0.1 to 1 foot per day where these beds do not contain clay. Limited fresh ground-water supplies exist in the Floridan aquifer within the Pinellas peninsula. At all test sites, chloride concentration in the injection zone ranged from 19,000 to 20,000 milligrams per liter. Injection tests ranging in duration from 3 to 91.1 days were run at three different sites. Pressure buildup occurred in permeable zones above and below the injection zone during these tests. Calculated pressure buildup in observation wells close to and at some distance from the test wells was typically less than 1 pound per square inch. Injection and formation water will probably move slowly through the semiconfining bed overlying the injection zone, and long-term injection tests will be needed to determine the effectiveness of these beds to retard flow. The injected water was well mixed with the native formation water, which, in part, is a direct consequence of the fractures in the injection zone.

Water Supply Paper↗
USGS2017

Selenium

Selenium (Se) was discovered in 1817 in pyrite from copper mines in Sweden. It is a trace element in Earth’s crust, with an abundance of three to seven orders of magnitude less than the major rock-forming elements. Commercial use of selenium began in the United States in 1910, when it was used as a pigment for paints, ceramic glazes, and red glass. Since that time, it has had many other economic uses—notably, in the 1930s and 1940s, when it was used in rectifiers (which change alternating current to direct current), and in the 1960s, when it began to be used in the liner of photocopier drums. In the 21st century, other compounds have replaced selenium in these older products; modern uses for selenium include energy-efficient windows that limit heat transfer and thin-film photovoltaic cells that convert solar energy into electricity. In Earth’s crust, selenium is found as selenide minerals, selenate and selenite salts, and as substitution for sulfur in sulfide minerals. It is the sulfide minerals, most commonly those in porphyry copper deposits, that provide the bulk of the selenium produced for the international commodity market. Selenium is obtained as a byproduct of copper refining and recovered from the anode slimes generated in electrolytic production of copper. Because of this, the countries that have the largest resources and (or) reserves of copper also have the largest resources and (or) reserves of selenium. Because selenium occurs naturally in Earth’s crust, its presence in air, water, and soil results from both geologic reactions and human activity. Selenium is found concentrated naturally in soils that overlie bedrock with high selenium concentrations. Selenium mining, processing, use in industrial and agricultural applications, and disposal may all contribute selenium to the environment. A well-known case of selenium contamination from agricultural practices was discovered in 1983 in the Kesterson National Wildlife Refuge in California. There, waters draining from agricultural fields created wetlands with high concentrations of dissolved selenium in the water. The selenium was taken up by aquatic wildlife and caused massive numbers of embryonic deformities and deaths. Regulatory agencies have since worked to safeguard ecological and human health by creating environmental exposure guidelines based upon selenium concentrations in water and in fish tissue. Any attempt to regulate selenium concentrations requires a delicate balance because selenium occurs naturally and is also a vital nutrient for the health of wildlife, domestic stock, and humans. Selenium is commonly added as a vitamin to animal feed, and in some regions of the United States and the world, it is added as an amendment to soils for uptake by agricultural crops. The important role of selenium in economic products, energy supply, agriculture, and health will continue for well into the future. The challenge to society is to balance the benefits of selenium use with the environmental consequences of its extraction. Increased understanding of the elemental cycle of selenium in the earth may lead to new (or unconventional) sources of selenium, the discovery of new methods of extraction, and new technologies for minimizing the transfer of selenium from rock to biota, so to protect environmental and human health.

Professional Paper↗
USGS1998

Petrofacies Analysis - A Petrophysical Tool for Geologic/Engineering Reservoir Characterization

Petrofacies analysis is defined as the characterization and classification of pore types and fluid saturations as revealed by petrophysical measurements of a reservoir. The word "petrofacies" makes an explicit link between petroleum engineers' concerns with pore characteristics as arbiters of production performance and the facies paradigm of geologists as a methodology for genetic understanding and prediction. In petrofacies analysis, the porosity and resistivity axes of the classical Pickett plot are used to map water saturation, bulk volume water, and estimated permeability, as well as capillary pressure information where it is available. When data points are connected in order of depth within a reservoir, the characteristic patterns reflect reservoir rock character and its interplay with the hydrocarbon column. A third variable can be presented at each point on the crossplot by assigning a color scale that is based on other well logs, often gamma ray or photoelectric effect, or other derived variables. Contrasts between reservoir pore types and fluid saturations are reflected in changing patterns on the crossplot and can help discriminate and characterize reservoir heterogeneity. Many hundreds of analyses of well logs facilitated by spreadsheet and object-oriented programming have provided the means to distinguish patterns typical of certain complex pore types (size and connectedness) for sandstones and carbonate reservoirs, occurrences of irreducible water saturation, and presence of transition zones. The result has been an improved means to evaluate potential production, such as bypassed pay behind pipe and in old exploration wells, or to assess zonation and continuity of the reservoir. Petrofacies analysis in this study was applied to distinguishing flow units and including discriminating pore type as an assessment of reservoir conformance and continuity. The analysis is facilitated through the use of colorimage cross sections depicting depositional sequences, natural gamma ray, porosity, and permeability. Also, cluster analysis was applied to discriminate petrophysically similar reservoir rock.

AAPG Memoir↗
USGS2014

Compositional controls on early diagenetic pathways in fine-grained sedimentary rocks: Implications for predicting unconventional reservoir attributes of mudstones

Diagenesis significantly impacts mudstone lithofacies. Processes operating to control diagenetic pathways in mudstones are poorly known compared to analogous processes occurring in other sedimentary rocks. Selected organic-carbon-rich mudstones, from the Kimmeridge Clay and Monterey Formations, have been investigated to determine how varying starting compositions influence diagenesis. The sampled Kimmeridge Clay Formation mudstones are organized into thin homogenous beds, composed mainly of siliciclastic detritus, with some constituents derived from water-column production (e.g., coccoliths, S-depleted type-II kerogen, as much as 52.6% total organic carbon [TOC]) and others from diagenesis (e.g., pyrite, carbonate, and kaolinite). The sampled Monterey Formation mudstones are organized into thin beds that exhibit pelleted wavy lamination, and are predominantly composed of production-derived components including diatoms, coccoliths, and foraminifera, in addition to type-IIS kerogen (as much as 16.5% TOC), and apatite and silica cements. During early burial of the studied Kimmeridge Clay Formation mudstones, the availability of detrital Fe(III) and reactive clay minerals caused carbonate- and silicate-buffering reactions to operate effectively and the pore waters to be Fe(II) rich. These conditions led to pyrite, iron-poor carbonates, and kaolinite cements precipitating, preserved organic carbon being S-depleted, and sweet hydrocarbons being generated. In contrast, during the diagenesis of the sampled Monterey Formation mudstones, sulfide oxidation, coupled with opal dissolution and the reduced availability of both Fe(III) and reactive siliciclastic detritus, meant that the pore waters were poorly buffered and locally acidic. These conditions resulted in local carbonate dissolution, apatite and silica cements precipitation, natural kerogen sulfurization, and sour hydrocarbons generation. Differences in mud composition at deposition significantly influence subsequent diagenesis. These differences impact their source rock attributes and mechanical properties.

AAPG Bulletin↗