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At least 667 records · Page 37Linked to original sources

Reassessment of mercury in surface water in the Adirondack region, New York

A study in 1970 established a natural background concentration of mercury in surface water in the Adirondack region of New York. In 1974, new methods of sample preservation and analysis were used in determining concentrations of mercury of samples of water from the same surface-water sites sampled in 1970-71. Concentrations of mercury for all sites in the 1974 study were virtually the same as those obtained in 1970-71, less than 0.5 microgram per litre, which is the detection limit of the methods.

New York↗

A framework for estimating economic impacts of ecological restoration

Ecological restoration projects are designed to improve natural and cultural resources. Spending on restoration also stimulates economic impacts to the restoration economy through the creation or support of jobs and business activity. This paper presents accessible methods for quantifying the economic impacts supported by restoration spending and is written to be a guide and toolbox for an interdisciplinary audience of restoration practitioners and economists. Measuring the economic impacts of restoration can be challenging due to lacking or limited data. The complex, collaborative, and heterogeneous nature of restoration projects can make it difficult to clearly track costs, contributing to limited availability and inconsistency in restoration cost data. And business classification systems, such as the North American Industrial Classification System (NAICS), do not include restoration-sectors that consistently describe the patterns of restoration spending. The aims of this paper are to (1) provide restoration practitioners and program managers with a clear understanding of the application of economic impact analyses to restoration, (2) provide a framework for collecting project cost data for economic impact analyses, and (3) provide modeling best practices and an example application of the framework.

Environmental Management↗

Quantification of aquifer properties with surface nuclear magnetic resonance in the Platte River valley, central Nebraska, using a novel inversion method

Surface nuclear magnetic resonance, a noninvasive geophysical method, measures a signal directly related to the amount of water in the subsurface. This allows for low-cost quantitative estimates of hydraulic parameters. In practice, however, additional factors influence the signal, complicating interpretation. The U.S. Geological Survey, in cooperation with the Central Platte Natural Resources District, evaluated whether hydraulic parameters derived from surface nuclear magnetic resonance data could provide valuable input into groundwater models used for evaluating water-management practices. Two calibration sites in Dawson County, Nebraska, were chosen based on previous detailed hydrogeologic and geophysical investigations. At both sites, surface nuclear magnetic resonance data were collected, and derived parameters were compared with results from four constant-discharge aquifer tests previously conducted at those same sites. Additionally, borehole electromagnetic-induction flowmeter data were analyzed as a less-expensive surrogate for traditional aquifer tests. Building on recent work, a novel surface nuclear magnetic resonance modeling and inversion method was developed that incorporates electrical conductivity and effects due to magnetic-field inhomogeneities, both of which can have a substantial impact on the data. After comparing surface nuclear magnetic resonance inversions at the two calibration sites, the nuclear magnetic-resonance-derived parameters were compared with previously performed aquifer tests in the Central Platte Natural Resources District. This comparison served as a blind test for the developed method. The nuclear magnetic-resonance-derived aquifer parameters were in agreement with results of aquifer tests where the environmental noise allowed data collection and the aquifer test zones overlapped with the surface nuclear magnetic resonance testing. In some cases, the previously performed aquifer tests were not designed fully to characterize the aquifer, and the surface nuclear magnetic resonance was able to provide missing data. In favorable locations, surface nuclear magnetic resonance is able to provide valuable noninvasive information about aquifer parameters and should be a useful tool for groundwater managers in Nebraska.

Nebraska↗

Sampling design for groundwater solute transport: Tests of methods and analysis of Cape Cod tracer test data

Tests of a one-dimensional sampling design methodology on measurements of bromide concentration collected during the natural gradient tracer test conducted by the U.S. Geological Survey on Cape Cod, Massachusetts, demonstrate its efficacy for field studies of solute transport in groundwater and the utility of one-dimensional analysis. The methodology was applied to design of sparse two-dimensional networks of fully screened wells typical of those often used in engineering practice. In one-dimensional analysis, designs consist of the downstream distances to rows of wells oriented perpendicular to the groundwater flow direction and the timing of sampling to be carried out on each row. The power of a sampling design is measured by its effectiveness in simultaneously meeting objectives of model discrimination, parameter estimation, and cost minimization. One-dimensional models of solute transport, differing in processes affecting the solute and assumptions about the structure of the flow field, were considered for description of tracer cloud migration. When fitting each model using nonlinear regression, additive and multiplicative error forms were allowed for the residuals which consist of both random and model errors. The one-dimensional single-layer model of a nonreactive solute with multiplicative error was judged to be the best of those tested. Results show the efficacy of the methodology in designing sparse but powerful sampling networks. Designs that sample five rows of wells at five or fewer times in any given row performed as well for model discrimination as the full set of samples taken up to eight times in a given row from as many as 89 rows. Also, designs for parameter estimation judged to be good by the methodology were as effective in reducing the variance of parameter estimates as arbitrary designs with many more samples. Results further showed that estimates of velocity and longitudinal dispersivity in one-dimensional models based on data from only five rows of fully screened wells each sampled five or fewer times were practically equivalent to values determined from moments analysis of the complete three-dimensional set of 29,285 samples taken during 16 sampling times.

Water Resources Research↗

Design and function of the Autonomous Benthic Imaging and Surveying System (ABISS) for remote sensing of lake and seabed environments

Lake and seabed environments are home to fisheries and other biota that are important to ecosystems and economies, yet these environments and the species that use them are difficult to accurately assess and monitor. Traditional benthic survey techniques, like bottom trawling used by the U.S. Geological Survey, are limited by substrate constraints, poor spatial resolution and precision, and operational depth limits, hindering accurate assessment of benthic species and habitats. In response to these limitations, the U.S. Geological Survey developed the Autonomous Benthic Imaging and Surveying System, a camera system integrated into underwater vehicles, to capture high-resolution images of the lakebed. The system uses color and stereo cameras to collect imagery, which can be analyzed using computational methods to detect organisms and (or) characterize habitat features, such as geologic substrate types. The system has been integrated into autonomous underwater vehicles and into an underwater housing used by self-contained underwater breathing apparatus (SCUBA) divers. Although the engineering of the system was motivated by the need for data collection in the Great Lakes, it has potential to collect high quality data in any aqueous setting with sufficient water clarity and safe operating conditions. The Autonomous Benthic Imaging and Surveying System can operate across diverse depths and light conditions to map and quantify ecological patterns that were difficult or impossible to assess using traditional methods. The Autonomous Benthic Imaging and Surveying System offers the potential for accurate and precise monitoring and assessment of native benthic biota, invasive species, and habitat, potentially providing natural resource managers with improved information to support decision making about benthic resource management.

Great Lakes↗

Organic-carbon sequestration in soil/sediment of the Mississippi River deltaic plain — Data; landscape distribution, storage, and inventory; accumulation rates; and recent loss, including a post-Katrina preliminary analysis

Soil/sediment of the Mississippi River deltaic plain (MRDP) in southeastern Louisiana is rich in organic carbon (OC). The MRDP contains about 2 percent of all OC in the surface meter of soil/sediment in the Mississippi River Basin (MRB). Environments within the MRDP differ in soil/sediment organic carbon (SOC) accumulation rate, storage, and inventory. The focus of this study was twofold: (1) develop a database for OC and bulk density for MRDP soil/sediment; and (2) estimate SOC storage, inventory, and accumulation rates for the dominant environments (brackish, intermediate, and fresh marsh; natural levee; distributary; backswamp; and swamp) in the MRDP. Comparative studies were conducted to determine which field and laboratory methods result in the most accurate and reproducible bulk-density values for each marsh environment. Sampling methods included push-core, vibracore, peat borer, and Hargis1 sampler. Bulk-density data for cores taken by the "short push-core method" proved to be more internally consistent than data for samples collected by other methods. Laboratory methods to estimate OC concentration and inorganic-constituent concentration included mass spectrometry, coulometry, and loss-on-ignition. For the sampled MRDP environments, these methods were comparable. SOC storage was calculated for each core with adequate OC and bulk-density data. SOC inventory was calculated using core-specific data from this study and available published and unpublished pedon data linked to SSURGO2 map units. Sample age was estimated using isotopic cesium ( 37 Cs), lead ( 210 Pb), and carbon ( 14 C), elemental Pb, palynomorphs, other stratigraphic markers, and written history. SOC accumulation rates were estimated for each core with adequate age data. Cesium-137 profiles for marsh soil/sediment are the least ambiguous. Levee and distributary 137 Cs profiles show the effects of intermittent allochthonous input and/or sediment resuspension. Cesium-137 and 210 Pb data gave the most consistent and interpretable information for age estimations of soil/sediment deposited during the 1900s. For several cores, isotopic 14 C and 137 Cs data allowed the 1963-64 nuclear weapons testing (NWT) peak-activity datum to be placed within a few-centimeter depth interval. In some cores, a too old 14 C age (when compared to 137 Cs and microstratigraphic-marker data) is the probable result of old carbon bound to clay minerals incorporated into the organic soil/sediment. Elemental Pb coupled with Pb source-function data allowed age estimation for soil/sediment that accumulated during the late 1920s through the 1980s. Exotic pollen (for example, Vigna unguiculata and Alternanthera philoxeroides ) and other microstratigraphic indicators (for example, carbon spherules) allowed age estimations for marsh soil/sediment deposited during the settlement of New Orleans (1717-20) through the early 1900s. For this study, MRDP distributary and swamp environments were each represented by only one core, backswamp environment by two cores, all other environments by three or more cores. MRDP core data for the surface meter soil/sediment indicate that (1) coastal marshes, abandoned distributaries, and swamps have regional SOC-storage values >16 kg m -2 ; (2) swamps and abandoned distributaries have the highest SOC storage values (swamp, 44.8 kg m -2 ; abandoned distributary, 50.9 kg m -2 ); (3) fresh-to-brackish marsh environments have the second highest site-specific SOC-storage values; and (4) site-specific marsh SOC storage values decrease as the salinity of the environment increases (fresh-marsh, 36.2 kg m -2 ; intermediate marsh, 26.2 kg m -2 ; brackish marsh, 21.5 kg m -2 ). This inverse relation between salinity and SOC storage is opposite the regional systematic increase in SOC storage with increasing salinity that is evident when SOC storage is mapped by linking pedon data to SSURGO map units (fresh marsh, 47 kg m -2 ; intermediate marsh, 67 kg m -2 ; brackish marsh, 75 kg m -2 ; and salt marsh, 80 kg m -2 ). MRDP core data for this study also indicate that levees and backswamp have regional SOC-storage values <16 kg m -2 . Group-mean SOC storage for cores from these environments are natural levee (17.0 kg m -2 ) and backswamp (14.1 kg m -2 ). An estimate for the SOC inventory in the surface meter of soil/sediment in the MRDP can be made using the SSURGO mapped portion of the coastal-marsh vegetative-type map (13,236 km 2 , land-only area) published by the Louisiana Department of Wildlife and Fisheries and U.S. Geological Survey (1997). This area has a SOC inventory (surface meter) of 677 Tg (slightly more than 2 percent of the 30,289 Tg SOC inventory for the MRB). The MRDP (6,180 km2, land-only area) has an estimated SOC inventory of 397 Tg. Most of the MRDP is located within the SSURGO mapped coastal marshlands. The entire MRDP, including water, has an area of about 10,800 km 2 . Using the ratio of total MRDP area to SSURGO mapped MRDP area as an adjustment, the MRDP SOC inventory is estimated at 694 Tg. This larger estimate of 694 Tg for the SOC inventory is probably more realistic, because it is reasonable to assume that the marsh sediments overlain by shallow water have comparable SOC storage to that of the adjacent land areas. MRDP core data for this study indicate that there is some variability in long-term SOC mass-accumulation rates for centuries and millennia and that this variability may indicate important geologic changes or changes in land use. However, the consistency of the range in rates of SOC accumulation through time suggests a remarkable degree of marsh sustainability throughout the Holocene, including the recent period of significant marsh modification/channelization for human use. One example of marsh sustainability is its present ability to function as a SOC sink even with Louisiana's large-scale coastal land loss during the last several decades. With coastal-marsh restoration efforts, this sink potential will increase. Looking to the future, a total of 1,101 g m -2 yr -1 SOC is projected to be lost from all of coastal Louisiana (U.S. Army Corps of Engineers, Louisiana Coastal Area (LCA) subprovinces 1-4; not just the MRDP) through coastal erosion from year 2000 to 2050. This translates to a projected SOC-loss rate of about 0.20 percent per year. The recent Hurricanes Katrina and Rita, which devastated the Louisiana coast during late August and late September 2005, transformed about 259 km 2 (100 mi 2 ) of marsh to open water (U.S. Geological Survey, 2005). To the extent that some or all of this land loss is permanent, this result equates to a SOC loss of about 15 Tg. This estimate is based on the year-2000 15,153-km 2 land area for the LCA study area that includes LCA subprovince 4. Using the year-2000 land area, the LCA study area had an estimated SOC inventory of 858 Tg. The estimated 15 Tg SOC loss attributable to Hurricanes Katrina and Rita is 1.7 percent of the year-2000 LCA inventory and 2.3 percent of the year-2000 MRDP inventory. If this SOC loss is included in the projection for the year 2050, then the MRDP would either remain a source with a net SOC loss of 3 Tg or become a weak sink with a net SOC gain of 4 Tg. These estimates are lower bounds for potential SOC flux because they are only for the surface meter of landmass.

Louisiana↗

Structural Equation Modeling: Applications in ecological and evolutionary biology

This book presents an introduction to the methodology of structural equation modeling, illustrates its use, and goes on to argue that it has revolutionary implications for the study of natural systems. A major theme of this book is that we have, up to this point, attempted to study systems primarily using methods (such as the univariate model) that were designed only for considering individual processes. Understanding systems requires the capacity to examine simultaneous influences and responses. Structural equation modeling (SEM) has such capabilities. It also possesses many other traits that add strength to its utility as a means of making scientific progress. In light of the capabilities of SEM, it can be argued that much of ecological theory is currently locked in an immature state that impairs its relevance. It is further argued that the principles of SEM are capable of leading to the development and evaluation of multivariate theories of the sort vitally needed for the conservation of natural systems. Supplementary information can be found at the authors website, http://www.jamesbgrace.com/ . • Details why multivariate analyses should be used to study ecological systems • Exposes unappreciated weakness in many current popular analyses • Emphasizes the future methodological developments needed to advance our understanding of ecological systems.

Book↗

Structural equation modeling and natural systems

This book, first published in 2006, presents an introduction to the methodology of structural equation modeling, illustrates its use, and goes on to argue that it has revolutionary implications for the study of natural systems. A major theme of this book is that we have, up to this point, attempted to study systems primarily using methods (such as the univariate model) that were designed only for considering individual processes. Understanding systems requires the capacity to examine simultaneous influences and responses. Structural equation modeling (SEM) has such capabilities. It also possesses many other traits that add strength to its utility as a means of making scientific progress. In light of the capabilities of SEM, it can be argued that much of ecological theory is currently locked in an immature state that impairs its relevance. It is further argued that the principles of SEM are capable of leading to the development and evaluation of multivariate theories of the sort vitally needed for the conservation of natural systems.

Book↗

Evaluation of the Malaga Bend salinity alleviation project, Eddy County, New Mexico

In an effort to reduce the flow of brine springs in the Malaga Bend reach of the Pecos River in southeastern New Mexico, brine was pumped from an aquifer underlying the Malaga Bend reach to a local depression known as Anderson Lake. The attempt to improve the quality of river water with this experiment was not successful because brine leakage from Anderson Lake to the nearby Pecos River through permeable subsurface rocks was greater than the previous natural spring inflow. Brine leakage from Anderson Lake from July 22, 1963, through September 30, 1968, was estimated by evaporation-pan, salt accumulation, and dissolved-constituent methods. The leakage values given by these three methods are in good agreement with each other and indicate that between the dates given, leakage from the lake was about 2 ,300 acre-feet, compared with a brine inflow to the lake of about 3,690 acre-feet. Other data indicate that pumping from the brine aquifer greatly reduced the natural inflow from brine springs to the Malaga Bend reach. The rate of brine leakage from Anderson Lake is probably greater than might be expected from other brine lakes in the area because the cavities in the bottom of the lake apparently are in hydrologic connection with the Pecos River. This connection is shown by a relation between the salinity of the Pecos River and the reservoir stage of Anderson Lake. (USGS)

New Mexico↗

Native American impacts on fire regimes of the California coastal ranges

Aim Native American burning impacts on California shrubland dominated landscapes are evaluated relative to the natural lightning fire potential for affecting landscape patterns. Location Focus was on the coastal ranges of central and southern California. Methods Potential patterns of Indian burning were evaluated based upon historical documents, ethnographic accounts, archaeological records and consideration of contemporary land management tactics. Patterns of vegetation distribution in this region were evaluated relative to environmental factors and the resilience of the dominant shrub vegetation to different fire frequencies. Results Lightning fire frequency in this region is one of the lowest in North America and the density of pre-Columbian populations was one of the highest. Shrublands dominate the landscape throughout most of the region. These woody communities have weak resilience to high fire frequency and are readily displaced by annual grasses and forbs under high fire frequency. Intact shrublands provided limited resources for native Americans and thus there was ample motivation for using fire to degrade this vegetation to an open mosaic of shrubland/grassland, not unlike the agropastoral modification of ecologically related shrublands by Holocene peoples in the Mediterranean Basin. Alien-dominated grasslands currently cover approximately one-quarter of the landscape and less than 1% of these grasslands have a significant native grass presence. Ecological studies in the Californian coastal ranges have failed to uncover any clear soil or climate factors explaining grassland and shrubland distribution patterns. Main conclusions Coastal ranges of California were regions of high Indian density and low frequency of lightning fires. The natural vegetation dominants on this landscape are shrubland vegetation that often form dense impenetrable stands with limited resources for Native Americans. Natural fire frequencies are not high enough to maintain these landscapes in habitable mixtures of shrublands and grasslands but such landscape mosaics are readily produced with additional human subsidy of ignitions. It is hypothesized that a substantial fraction of the landscape was type converted from shrubland to grassland and much of the landscape that underwent such type conversion has either been maintained by Euro-American land management practices or resisted recolonization of native shrublands. It appears that these patterns are disturbance dependent and result from anthropogenic alteration of landscapes initiated by Native Americans and sustained and expanded upon by Euro-American settlers.

Journal of Biogeography↗

Suitability of river delta sediment as proppant, Missouri and Niobrara Rivers, Nebraska and South Dakota, 2015

Sediment management is a challenge faced by reservoir managers who have several potential options, including dredging, for mitigation of storage capacity lost to sedimentation. As sediment is removed from reservoir storage, potential use of the sediment for socioeconomic or ecological benefit could potentially defray some costs of its removal. Rivers that transport a sandy sediment load will deposit the sand load along a reservoir-headwaters reach where the current of the river slackens progressively as its bed approaches and then descends below the reservoir water level. Given a rare combination of factors, a reservoir deposit of alluvial sand has potential to be suitable for use as proppant for hydraulic fracturing in unconventional oil and gas development. In 2015, the U.S. Geological Survey began a program of researching potential sources of proppant sand from reservoirs, with an initial focus on the Missouri River subbasins that receive sand loads from the Nebraska Sand Hills. This report documents the methods and results of assessments of the suitability of river delta sediment as proppant for a pilot study area in the delta headwaters of Lewis and Clark Lake, Nebraska and South Dakota. Results from surface-geophysical surveys of electrical resistivity guided borings to collect 3.7-meter long cores at 25 sites on delta sandbars using the direct-push method to recover duplicate, 3.8-centimeter-diameter cores in April 2015. In addition, the U.S. Geological Survey collected samples of upstream sand sources in the lower Niobrara River valley. At the laboratory, samples were dried, weighed, washed, dried, and weighed again. Exploratory analysis of natural sand for determining its suitability as a proppant involved application of a modified subset of the standard protocols known as American Petroleum Institute (API) Recommended Practice (RP) 19C. The RP19C methods were not intended for exploration-stage evaluation of raw materials. Results for the washed samples are not directly applicable to evaluations of suitability for use as fracture sand because, except for particle-size distribution, the API-recommended practices for assessing proppant properties (sphericity, roundness, bulk density, and crush resistance) require testing of specific proppant size classes. An optical imaging particle-size analyzer was used to make measurements of particle-size distribution and particle shape. Measured samples were sieved to separate the dominant-size fraction, and the separated subsample was further tested for roundness, sphericity, bulk density, and crush resistance. For the bulk washed samples collected from the Missouri River delta, the geometric mean size averaged 0.27 millimeters (mm), 80 percent of the samples were predominantly sand in the API 40/70 size class, and 17 percent were predominantly sand in the API 70/140 size class. Distributions of geometric mean size among the four sandbar complexes were similar, but samples collected from sandbar complex B were slightly coarser sand than those from the other three complexes. The average geometric mean sizes among the four sandbar complexes ranged only from 0.26 to 0.30 mm. For 22 main-stem sampling locations along the lower Niobrara River, geometric mean size averaged 0.26 mm, an average of 61 percent was sand in the API 40/70 size class, and 28 percent was sand in the API 70/140 size class. Average composition for lower Niobrara River samples was 48 percent medium sand, 37 percent fine sand, and about 7 percent each very fine sand and coarse sand fractions. On average, samples were moderately well sorted. Particle shape and strength were assessed for the dominant-size class of each sample. For proppant strength, crush resistance was tested at a predetermined level of stress (34.5 megapascals [MPa], or 5,000 pounds-force per square inch). To meet the API minimum requirement for proppant, after the crush test not more than 10 percent of the tested sample should be finer than the precrush dominant-size class. For particle shape, all samples surpassed the recommended minimum criteria for sphericity and roundness, with most samples being well-rounded. For proppant strength, of 57 crush-resistance tested Missouri River delta samples of 40/70-sized sand, 23 (40 percent) were interpreted as meeting the minimum criterion at 34.5 MPa, or 5,000 pounds-force per square inch. Of 12 tested samples of 70/140-sized sand, 9 (75 percent) of the Missouri River delta samples had less than 10 percent fines by volume following crush testing, achieving the minimum criterion at 34.5 MPa. Crush resistance for delta samples was strongest at sandbar complex A, where 67 percent of tested samples met the 10-percent fines criterion at the 34.5-MPa threshold. This frequency was higher than was indicated by samples from sandbar complexes B, C, and D that had rates of 50, 46, and 42 percent, respectively. The group of sandbar complex A samples also contained the largest percentages of samples dominated by the API 70/140 size class, which overall had a higher percentage of samples meeting the minimum criterion compared to samples dominated by coarser size classes; however, samples from sandbar complex A that had the API 40/70 size class tested also had a higher rate for meeting the minimum criterion (57 percent) than did samples from sandbar complexes B, C, and D (50, 43, and 40 percent, respectively). For samples collected along the lower Niobrara River, of the 25 tested samples of 40/70-sized sand, 9 samples passed the API minimum criterion at 34.5 MPa, but only 3 samples passed the more-stringent criterion of 8 percent postcrush fines. All four tested samples of 70/140 sand passed the minimum criterion at 34.5 MPa, with postcrush fines percentage of at most 4.1 percent. For two reaches of the lower Niobrara River, where hydraulic sorting was energized artificially by the hydraulic head drop at and immediately downstream from Spencer Dam, suitability of channel deposits for potential use as fracture sand was confirmed by test results. All reach A washed samples were well-rounded and had sphericity scores above 0.65, and samples for 80 percent of sampled locations met the crush-resistance criterion at the 34.5-MPa stress level. A conservative lower-bound estimate of sand volume in the reach A deposits was about 86,000 cubic meters. All reach B samples were well-rounded but sphericity averaged 0.63, a little less than the average for upstream reaches A and SP. All four samples tested passed the crush-resistance test at 34.5 MPa. Of three reach B sandbars, two had no more than 3 percent fines after the crush test, surpassing more stringent criteria for crush resistance that accept a maximum of 6 percent fines following the crush test for the API 70/140 size class. Relative to the crush-resistance test results for the API 40/70 size fraction of two samples of mine output from Loup River settling-basin dredge spoils near Genoa, Nebr., four of five reach A sample locations compared favorably. The four samples had increases in fines composition of 1.6–5.9 percentage points, whereas fines in the two mine-output samples increased by an average 6.8 percentage points.

Nebraska, South Dakota↗

Declining American Goshawk (Accipiter atricapillus) nest site habitat suitability in a timber production landscape: Effects of abiotic, biotic, and forest management factors

Conservation of the American Goshawk ( Accipiter atricapillus ; hereafter goshawk) has been contentious in relation to forest management. Higher quality goshawk nesting habitat is generally considered to consist of contiguous tracts of mature forest, due to goshawks' large home ranges, territoriality, and food requirements. The large trees of mature forest have the greatest economic value to timber companies. We used long-term (1965–2019) data from 281 goshawk nest site locations in the Black Hills National Forest (BHNF), South Dakota, and Wyoming, USA, to evaluate (1) abiotic and biotic factors associated with goshawk nest site habitat suitability (hereafter habitat suitability); (2) changes in habitat suitability over time; and (3) the effect of anthropogenic activities and natural disturbances on habitat suitability. We evaluated forest attributes across five spatial scales relevant to goshawks, used information-theoretic methods to rank and select models, and assessed the predictive capability of the best-approximating models using the concordance statistic. The best-approximating model had excellent predictive capability (concordance = 0.821). Forest attributes at the 12-ha scale were a better predictor of goshawk habitat suitability than covariates evaluated at the point or >12-ha scales, indicating the importance of managing goshawk habitat beyond the nest tree, but within the nest stand. Goshawk habitat suitability was positively related to mean percent canopy cover and median canopy base height, and negatively related to variability in canopy base height within 12 ha of the location. As mean percent canopy cover within 12 ha of a location increased, goshawk habitat suitability increased more slowly in burned compared to unburned areas. Commercial thinning treatments were more likely to occur in closed canopy forest that already had a higher likelihood of goshawk nesting, and we documented a positive relationship between habitat suitability and the interaction of canopy cover with commercial thinning. Goshawk habitat suitability was negatively related to slope and distance to drainage bottoms, and positively related to distance to ridges, which may be related to microclimatic factors. Our results indicate goshawk habitat suitability decreased across the BHNF over the past three decades and much high-quality nesting habitat was lost during this period due to a combination of unsustainable timber harvest and natural disturbances. Minimizing forest management activities that decrease canopy cover and canopy base height, and increase variability in canopy base height in areas of high- and medium-quality goshawk habitat are likely to slow the loss of higher-quality habitat and allow development of future nesting habitat. In addition to informing management, this study demonstrates the value of using existing long-term legacy datasets in conjunction with time series of remotely sensed habitat attributes to evaluate changes in habitat suitability for raptors in heavily managed landscapes with extensive natural disturbances.

South Dakota, Wyoming↗

Borehole geophysical monitoring of amendment emplacement and geochemical changes during vegetable oil biostimulation, Anoka County Riverfront Park, Fridley, Minnesota

The U.S. Geological Survey ( USGS ) conducted a series of geophysical investigations to monitor a field-scale biostimulation pilot project at the Anoka County Riverfront Park ( ACP ), downgradient from the Naval Industrial Reserve Ordnance Plant, in Fridley, Minnesota. The pilot project was undertaken by the U.S. Naval Facilities Engineering Command, Southern Division, for the purpose of evaluating biostimulation using emulsified vegetable oil to treat ground water contaminated with chlorinated hydrocarbons. Vegetable oil was introduced to the subsurface to serve as substrate for naturally occurring microbes, which ultimately break down chlorinated hydrocarbons into chloride, carbon dioxide, and water through oxidation-reduction reactions. In support of this effort, the USGS collected cross-borehole radar data and conventional borehole geophysical data in five site visits over 1.5 years to evaluate the effectiveness of geophysical methods for monitoring emplacement of the vegetable oil emulsion and for tracking changes in water chemistry. Radar zero-offset profile ( ZOP ) data, radar traveltime tomograms, electromagnetic ( EM ) induction logs, natural gamma logs, neutron porosity logs, and magnetic susceptibility logs were collected and analyzed. In order to facilitate data interpretation and to test the effectiveness of radar for monitoring oil-emulsion placement and movement, three injection mixtures with different radar signatures were used: (1) vegetable oil emulsion, (2) vegetable oil emulsion with a colloidal iron tracer, and (3) vegetable oil emulsion with a magnetite tracer. Based on petrophysical modeling, mixture (1) was expected to increase radar velocity and decrease radar attenuation relative to background&mdash;a water-saturated porous medium; mixtures (2) and (3) were expected to increase radar velocity and increase radar attenuation because of their greater electrical conductivity compared to background ground water. Radar ZOP data and tomograms show increased EM velocity in the vicinity of injection wells. Comparison of pre- and post-injection datasets shows that velocity anomalies are observed only in planes connected to injection wells, indicating that the emulsified vegetable oil does not migrate far after injection. In contrast to the localization of velocity anomalies, radar attenuation anomalies are observed in all zero-offset profiles, particularly those downgradient from the injection wells. Despite the expected signatures of different tracers, increases in attenuation are observed downgradient from all three injection wells; thus, we infer that the attenuation changes do not result from the iron tracers alone. Over the period of data collection, the slowness (reciprocal velocity) anomalies are relatively stable, whereas the attenuation anomalies generally increase in magnitude and extent. One explanation for the attenuation changes is that products of vegetable oil-enhanced biodegradation (for example, chloride) increase the specific conductance of ground water and thus bulk electrical conductivity and radar attenuation. This interpretation is supported by the results of EM-induction and magnetic susceptibility logs, which indicate increases in electrical conductivity in the absence of magnetic anomalies that might result from the iron and magnetite. Based on the geophysical data, conceptual models of the distributions of emulsified vegetable oil and ground water with altered chemistry were developed. The field data indicate that, in several cases, the plume of ground water with altered chemistry would not be detected by direct chemical sampling given the construction of monitoring wells; hence the geophysical data provide valuable site-specific insights for the interpretation of water samples and monitoring of biostimulation projects. Application of geophysical methods to data from the ACP demonstrated the utility of radar for monitoring biostimulation injections.

Minnesota↗

Public participation GIS: a method for identifying ecosystems services

This study evaluated the use of an Internet-based public participation geographic information system (PPGIS) to identify ecosystem services in Grand County, Colorado. Specific research objectives were to examine the distribution of ecosystem services, identify the characteristics of participants in the study, explore potential relationships between ecosystem services and land use and land cover (LULC) classifications, and assess the methodological strengths and weakness of the PPGIS approach for identifying ecosystem services. Key findings include: (1) Cultural ecosystem service opportunities were easiest to identify while supporting and regulatory services most challenging, (2) participants were highly educated, knowledgeable about nature and science, and have a strong connection to the outdoors, (3) some LULC classifications were logically and spatially associated with ecosystem services, and (4) despite limitations, the PPGIS method demonstrates potential for identifying ecosystem services to augment expert judgment and to inform public or environmental policy decisions regarding land use trade-offs.

Society and Natural Resources↗

Application of binomial-edited CPMG to shale characterization

Unconventional shale resources may contain a significant amount of hydrogen in organic solids such as kerogen, but it is not possible to directly detect these solids with many NMR systems. Binomial-edited pulse sequences capitalize on magnetization transfer between solids, semi-solids, and liquids to provide an indirect method of detecting solid organic materials in shales. When the organic solids can be directly measured, binomial-editing helps distinguish between different phases. We applied a binomial-edited CPMG pulse sequence to a range of natural and experimentally-altered shale samples. The most substantial signal loss is seen in shales rich in organic solids while fluids associated with inorganic pores seem essentially unaffected. This suggests that binomial-editing is a potential method for determining fluid locations, solid organic content, and kerogen–bitumen discrimination.

Journal of Magnetic Resonance↗

Developing integrated methods to address complex resource and environmental issues

Introduction This circular provides an overview of selected activities that were conducted within the U.S. Geological Survey (USGS) Integrated Methods Development Project, an interdisciplinary project designed to develop new tools and conduct innovative research requiring integration of geologic, geophysical, geochemical, and remote-sensing expertise. The project was supported by the USGS Mineral Resources Program, and its products and acquired capabilities have broad applications to missions throughout the USGS and beyond. In addressing challenges associated with understanding the location, quantity, and quality of mineral resources, and in investigating the potential environmental consequences of resource development, a number of field and laboratory capabilities and interpretative methodologies evolved from the project that have applications to traditional resource studies as well as to studies related to ecosystem health, human health, disaster and hazard assessment, and planetary science. New or improved tools and research findings developed within the project have been applied to other projects and activities. Specifically, geophysical equipment and techniques have been applied to a variety of traditional and nontraditional mineral- and energy-resource studies, military applications, environmental investigations, and applied research activities that involve climate change, mapping techniques, and monitoring capabilities. Diverse applied geochemistry activities provide a process-level understanding of the mobility, chemical speciation, and bioavailability of elements, particularly metals and metalloids, in a variety of environmental settings. Imaging spectroscopy capabilities maintained and developed within the project have been applied to traditional resource studies as well as to studies related to ecosystem health, human health, disaster assessment, and planetary science. Brief descriptions of capabilities and laboratory facilities and summaries of some applications of project products and research findings are included in this circular. The work helped support the USGS mission to “provide reliable scientific information to describe and understand the Earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life.” Activities within the project include the following: Spanned scales from microscopic to planetary; Demonstrated broad applications across disciplines; Included life-cycle studies of mineral resources; Incorporated specialized areas of expertise in applied geochemistry including mineralogy, hydrogeology, analytical chemistry, aqueous geochemistry, biogeochemistry, microbiology, aquatic toxicology, and public health; and Incorporated specialized areas of expertise in geophysics including magnetics, gravity, radiometrics, electromagnetics, seismic, ground-penetrating radar, borehole radar, and imaging spectroscopy. This circular consists of eight sections that contain summaries of various activities under the project. The eight sections are listed below: Laboratory Facilities and Capabilities, which includes brief descriptions of the various types of laboratories and capabilities used for the project; Method and Software Development, which includes summaries of remote-sensing, geophysical, and mineralogical methods developed or enhanced by the project; Instrument Development, which includes descriptions of geophysical instruments developed under the project; Minerals, Energy, and Climate, which includes summaries of research that applies to mineral or energy resources, environmental processes and monitoring, and carbon sequestration by earth materials; Element Cycling, Toxicity, and Health, which includes summaries of several process-oriented geochemical and biogeochemical studies and health-related research activities; Hydrogeology and Water Quality, which includes descriptions of innovative geophysical, remote-sensing, and geochemical research pertaining to hydrogeology and water-quality applications; Hazards and Disaster Assessment, which includes summaries of research and method development that were applied to natural hazards, human-caused hazards, and disaster assessments; and Databases and Framework Studies, which includes descriptions of fundamental applications of geophysical studies and of the importance of archived data.

Circular↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of antimony by automated-hydride atomic absorption spectrophotometry

The analysis of natural-water samples for antimony by automated-hydride atomic absorption spectrophotometry is described. Samples are prepared for analysis by addition of potassium and hydrochloric acid followed by an autoclave digestion. After the digestion, potassium iodide and sodium borohydride are added automatically. Antimony hydride (stibine) gas is generated, then swept into a heated quartz cell for determination of antimony by atomic absorption spectrophotometry. Precision and accuracy data are presented. Results obtained on standard reference water samples agree with means established by interlaboratory studies. Spike recoveries for actual samples range from 90 to 114 percent. Replicate analyses of water samples of varying matrices give relative standard deviations from 3 to 10 percent.

Open-File Report↗

Early life history and survival of natural subyearling fall chinook salmon in the Snake and Clearwater rivers in 1995

Snake River fall chinook salmon Oncorhynchustshawytscha have declined in abundance the last three decades and now managers are seeking methods to restore the population, Estimates of adult fish returning to the Snake River prior to 1957 number in the tens of thousands (Irving and Bjornn 1981), compared to a range of about 300-750 for 1991-1995 (Lavoy 1995). As a result, Snake River fall chinook salmon were listed as threatened under the Endangered Species Act (USFWS 1988) in 1992 (NMFS 1992) and the Snake and Clearwater rivers were identified as critical habitat (NMFS 1995). Resource managers are attempting to recover the population of Snake River fall chinook salmon, but the fish are restricted to a small part of historical production areas. The objectives of this segment of our study were to (1) describe the early life history characteristics of naturally produced subyearling fall chinook salmon in the Snake and Clearwater rivers, and (2) estimate survival for juvenile fall chinook salmon emigrating from the Snake and Clearwater rivers to the tail race of Lower Granite Dam.

Idaho, Oregon, Washington↗