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A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan

Performance analysis of oil recovery and CO2 retention in a greenfield residual oil zone: CO2-EOR in Tall Cotton Field (Permian Basin, West Texas, USA)

Residual oil zones (ROZs) can offer significant oil resources via enhanced oil recovery (EOR) as well as subsurface carbon dioxide (CO 2 ) retention during injection. If injected CO 2 is anthropogenic, the ROZs can offer a substantial geologic storage potential. The ROZs below the oil/water contact (OWC) of main pay zones (MPZ) in conventional reservoirs or brownfields, are more commonly developed for CO 2 injection and oil production and reported in the literature. However, CO 2 -EOR in greenfield ROZs, reservoirs without a MPZ present, have rarely been developed for CO 2 -EOR operation. The Tall Cotton Field of West Texas, Permian Basin, which started production in 2015 (Phase 1) and expanded in 2017 (Phase 2) from the San Andres Limestone, is one of the first examples of greenfield ROZs developed for EOR by injecting CO 2 . This paper analyses EOR and CO 2 retention performance of Tall Cotton Field using allocated injection and production data from inverted 5-spot well patterns of Phase-1 and -2 developments. Production and injection data allocated to each of the 28 identified patterns (nine 20-acre patterns for Phase-1, three 20-acre and sixteen 10-acre patterns for Phase-2) were analyzed for historical and forecasted oil recovery using ratio-trend decline analysis, and for CO 2 retention performance of the patterns. The allocated data were further used to calculate injected reservoir pore volume and void replacement ratios (VRR) for the analysis period. Quantitative results indicated that oil recovery factors of the 5-spot patterns varied between 4–10 %, and 5–30 % between the end of injection and the forecast periods, respectively. Storage of CO 2 , on the other hand, increased to a mean value of ∼7130 MMscf per pattern in Phase-1 and to a mean storage of 3700 MMscf per pattern in Phase-2 until the end of injection, followed by a decline after the end of injection and into the forecast period. Resulting CO 2 utilization factors ∼6–50 Mscf/bbl were estimated at the end of injection. Overall, presented results suggested that developing greenfield ROZs for CO 2 -EOR can be as promising as brownfield ROZs and mature MPZs for EOR and underground storage of injected CO 2 . For Tall Cotton Field, results suggest that Phase-2 patterns generally outperformed Phase-1 for oil recovery factors, while Phase-1 performed better in CO 2 retention performance metrics. This is the first study in the literature that reports a detailed CO 2 -EOR performance analysis of a greenfield ROZ in the Permian Basin, which can potentially allow for comparison with MPZs and brownfield ROZs.

Texas

The influence of nodule versus crust morphology on the composition of seamount-hosted ferromanganese minerals

Ferromanganese mineral precipitation in the global oceans is ubiquitous, occurring in the form of both crusts and nodules at a broad range of depths and seafloor terrains. Although ferromanganese crusts and nodules are both composed of ferromanganese minerals, mineralogy and mean element concentrations compiled for regional crust versus nodule occurrences differ. Notably, most published compilations compare nodules from abyssal plain sediments to crusts forming on seamounts, and do not address the question as to whether mineral morphology may affect the composition of crusts and nodules in addition to environmental factors. To address this, we have compiled a dataset of co-located hydrogenetic (seawater sourced) open-ocean ferromanganese crusts and seamount-hosted nodules. The preliminary data presented here support our hypothesis that co-located crusts and nodules exhibit similar compositions, both in terms of their mineralogy and mean element concentrations, as well as overall variance in concentrations for any given element. These data indicate that local processes influence sample-to-sample variation in both crusts and nodules, in contrast to broader ferromanganese variation reported between open-ocean seamounts- hosted crusts and abyssal plain-hosted nodules.

Conference Paper

U.S. Geological Survey Earthquake Hazards Program decadal science strategy, 2024–33

Executive Summary Earthquakes represent one of our Nation’s most significant and costly natural hazards, with estimated annual loses from earthquakes close to $15 billion in 2023. Over the past two centuries, 37 U.S. States have experienced an earthquake exceeding a magnitude of 5, and 50 percent of States have a significant potential for future damaging shaking; these statistics speak to the need for nationwide interest and investment in earthquake hazard characterization and risk reduction. Authorized under the Earthquake Hazards Reduction Authorization Act, the U.S. Geological Survey (USGS) Earthquake Hazards Program (EHP) provides the scientific information, situational awareness, and knowledge necessary to reduce deaths, injuries, and economic losses from earthquakes and earthquake-induced tsunamis, landslides, and soil liquefaction. The EHP supports activities in three focused topical areas: (1) earthquake monitoring, (2) hazard assessment, and (3) applied research, using the results of each—and the coordination among them—to further support risk translation and communication in regions at risk nationwide. For earthquake monitoring, the Advanced National Seismic System (ANSS), a cooperative effort of USGS networks, university partner regional seismic networks, and real-time geodetic networks, collects and analyzes data on earthquakes; issues timely, reliable notifications of their occurrence and impacts; and provides data for earthquake research, hazard, and risk assessment as a foundation for building an earthquake-resilient Nation. The USGS-operated ShakeAlert Earthquake Early Warning system is a recent addition to EHP’s ANSS infrastructure. In the realm of earthquake hazard assessment, the EHP contributes to earthquake risk mitigation strategies by developing the National Seismic Hazard Model and maps, and other related products, that describe the likelihood and potential effects of earthquakes nationwide, especially in the urban areas of highest risk. The EHP also conducts research on the causes, characteristics, and effects of earthquakes and prioritizes work that directly increases the accuracy and precision of earthquake hazards assessments, earthquake forecasts, and earthquake monitoring and situational-awareness products and that supports the Nation’s earthquake mitigation practices. Bridging the EHP’s efforts across research, hazard assessments, and earthquake monitoring is a broad and comprehensive collection of earthquake information products, including the National Seismic Hazard Model, ShakeAlert, and other products describing impact, such as ShakeMap and PAGER (Prompt Assessment of Global Earthquakes for Response), which have been developed and integrated into EHP’s real-time monitoring systems. EHP funds external partners to carry out many important collaborative activities through an active external grants program—one of the largest in the USGS—and through cooperative agreements with other partners such as the university-operated regional seismic networks, funded as part of the ANSS. To continue its support of earthquake hazard characterization and risk reduction, the EHP aims to strengthen its foundational products and practices while positioning itself to respond to the evolving needs of the Nation and follow best practices of the scientific community. This document describes a strategy for the program to ensure it can meet these demands. The foundational priorities outlined in this strategy represent those activities that remain critical to the core functionality of the program and those that can be supported under current fiscal year 2024-level appropriations. Priorities described as aspirational are important for future growth, and to maintain the program’s position as a leading global resource in earthquake science, but would require increases in appropriated funding to be fully realized. Across the program’s portfolio of activities, several major themes have been identified as the most critical activities to advance EHP science over the coming decade. Together, these activities provide the framework necessary to integrate critical hazard characterization and risk reduction activities across the program. They provide the structure for research to advance the understanding of where, when, and why earthquakes occur and how we can use improved knowledge to drive short-term and actionable forecasts of seismic activity. They expand the usefulness of critical earthquake products and advance the sophistication of those products to keep pace with the rapidly evolving needs of an ever-expanding user base while maintaining the position of the USGS as a global leader in earthquake science. Focus on system-level science. Establish an automated earthquake-processing pipeline. Enhance the accuracy and reliability of the ShakeAlert Earthquake Early Warning system and plan for extension to other regions. Implement time-dependent earthquake forecasting. Develop physically realistic models. Expand computational capacity. This science strategy is organized into three primary sections. The first section provides an overview of the EHP and its budget, governance, and program council. Readers familiar with the program may wish to focus on the second section, which describes the core of the science strategy, including priorities across each of the EHP’s major program activities in monitoring, hazard assessment, and targeted research. The third section outlines science priorities that cut across program activities, including those involving collaborations external to the EHP.

American Samoa, Guam, Northern Marianas Islands, U

Evaluation of stream capture related to groundwater pumping, middle Humboldt River Basin, Nevada

Historical, future, and potential stream capture from groundwater pumping in the middle Humboldt River Basin (MHRB), Nevada, is estimated using a calibrated numerical groundwater flow model. The model was developed to estimate (1) stream capture, which is the change in flux between the groundwater system and the Humboldt River and tributaries, and (2) change in streamflow, which is the change in streamflow estimated for the Imlay gage on the Humboldt River (U.S. Geological Survey streamgage 10333000). Historical stream capture for water years (WYs) 1961–2015 is estimated using recorded and estimated groundwater pumping during that period. Future (predictive) stream capture was based on historical stresses (WYs 1961–2015) using a scenario that simulated non-mine pumping from WY 2015 at a uniform rate for 100 years into the future. Potential stream capture throughout the middle Humboldt River Basin from groundwater pumping during varying durations of time are presented in a series of capture maps. Maps also are presented that show the potential to capture from groundwater evapotranspiration, as well as the storage changes for pumping duration of 100 years. Estimates of historical stream capture from the mainstem Humboldt River during the early 1960s are less than 400 acre-feet per year (acre-ft/yr) when groundwater withdrawals and pumping rates were relatively small compared to more recent times. In the late 1980s and early 1990s, groundwater withdrawals increased and estimated historical stream capture also increased from about 4,000 acre-ft/yr in the late 1980s and early 1990s to as much as 18,800 acre-feet (acre-ft) in WY 1998. In WY 2015, estimated historical stream capture declined to about 13,000 acre-ft because of decreasing groundwater withdrawals and lower streamflow during the drought of WYs 2012–15, resulting in less stream water available for capture. Stream capture was estimated for 100 years into the future based on WY 2015 non-mine pumping rates and mine-dewatering activity through WY 2015. Stream capture is forecast to increase to about 23,000 acre-ft/yr, and streamflow in the Humboldt River could decrease by as much as 19,000 acre-ft/yr. Pumping for mine-dewatering and the associated discharge of that water affects streamflow in the Humboldt River at Imlay, Nevada (U.S. Geological Survey streamgage 10333000). Historically, from WYs 1991 to 2015, streamflow was greater at Imlay gage during active mine-dewatering from mine-water discharge operations and increased by as much as 105,000 acre-ft in WY 1998. The increase was attributed mostly to the discharge of groundwater from mine-related dewatering operations directly into the mainstem Humboldt River or its tributaries, with some of this increase associated with return flows from discharge to rapid infiltration basins. Results indicate that streamflow at Imlay gage is expected to decrease by as much as 1,600 acre-ft/yr 30 years after mine-related pumping and discharge are discontinued. The streamflow reductions at the Imlay gage are expected to then decrease to around 500 acre-ft/yr, 100 years after mine-related pumping and discharge are discontinued. Potential capture maps were produced for pumping durations of 10, 25, 50, and 100 years. Capture map results indicate that areas of greater potential stream capture occur adjacent to the Humboldt River and for upstream tributaries areas north of the Humboldt River.

Nevada

Digitizer Suite: The Albuquerque Seismological Laboratory Digitizer Testing Suite

Laboratory testing of digitizers and seismometers helps ensure that prior to deployment the instrumentation can produce high quality data and is operating within specifications. In this work we detail the software package called: the Albuquerque Seismological Laboratory (ASL) Digitizer Test Suite. This Java software package provides several algorithms to verify various performance parameters of digitizers commonly used for recording analog seismic instruments. The goal of these tests is not to be exhaustive, but to identify common failures that could compromise the integrity of seismic data being recorded on the digitizer. For example, Sandia National Laboratories (e.g., Slad and Merchant, 2018) routinely do comprehensive testing of digitizers for various monitoring missions. While these tests reports are valuable for comprehensively characterizing a recording system, it would be resource intensive to conduct such tests on every seismic recorder used in a network. We focus on tests that include ways to estimate the sensitivity, timing, self-noise, and clip-level of the digitizer, as well as the fidelity of the signal being recorded. The software is publicly available and provides a way for the community to verify the integrity of a digitizer using a minimum amount of outside equipment.

Seismological Research Letters

Statistical approaches for modeling correlated grade and tonnage distributions and applications for mineral resource assessments

Correlations between grade and tonnage exist in mineral resource data compiled from published reports, but they are not always addressed during quantitative assessment of undiscovered mineral resources. Failure to account for correlated grade and tonnage distributions can result in geologically unrealistic assessment results. Current software tools simulate univariate ore tonnage and multivariate resource grades of undiscovered deposits independently. As a result, analysts are forced to rely on ad-hoc solutions to minimize the correlation issues by: 1) creating subsets of data with restricted criteria; 2) truncating grade and tonnage distributions; and 3) testing model robustness using exploratory data analysis. While these methods represent pragmatic solutions, the statistical solutions presented here provide additional options to address real correlations in grade and tonnage data used for mineral resource assessments. We present a modified version of the MapMark4 package in R that introduces two alternatives for modeling grade and tonnage distributions, consisting of a multivariate solution that accounts for correlations between ore tonnage and metal grades and an empirical solution that utilizes simple random sampling with replacement to reproduce coupled grades and tonnages from the input data. We present simulations for contained ore and metal for three case studies representing tungsten skarn, komatiite-hosted nickel, and sediment-hosted carbonate amagmatic zinc-lead (Mississippi Valley-type) deposits. Employing the methods presented here yields quantitative mineral resource assessment results that more closely reflect the empirical distributions of grades and tonnages observed in nature and expands the applicability of these tools for ongoing critical mineral resource assessments.

Applied Computing and Geosciences

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research

Limited preservation of strike-slip surface displacement in the geomorphic record

Offset geomorphic markers are commonly used to interpret slip history of strike-slip faults and have played an important role in forming earthquake recurrence models. These data sets are typically analyzed using cumulative probability methods to interpret average amounts of slip in past earthquakes. However, interpretation of the geomorphic record to infer surface slip history is complicated by slip variability, measurement uncertainty, and modification of offset features in the landscape. To investigate how well geomorphic data record surface slip, we use offset measurements from recent strike-slip surface ruptures ( n = 39), faults with geomorphic evidence of multiple strike-slip earthquakes ( n = 29), and synthetic slip distributions with added noise ( n > 10,000) to examine the constraints of the geomorphic record and the underlying assumptions of the cumulative offset probability distribution analysis method. We find that the geomorphic record is unlikely to resolve more than two paleo-slip distributions, except in specific cases with low slip variability, high slip-per-event, and semiarid climate. In cases where site-specific conditions allow for interpretation of more than two earthquakes, lateral extrapolation along a fault is not straightforward because on-fault displacement and distributed deformation may be spatially variable in each earthquake. We also find that average slip in modern earthquakes is adequately recovered by probability methods, but the reported prevalence of strike-slip faults with characteristic slip history is not supported by geomorphic data. We also propose updated methods to interpret slip history and construct uncertainty bounds for paleo-slip distributions.

Journal of Geophysical Research: Solid Earth

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology

Geochemical evidence for the origin of late Quaternary loess, Seward Peninsula, Alaska

Loess is the most widespread surficial deposit in the state of Alaska. Although loess of last glacial age is common in mid-continental North America, records of last glacial loess in Alaska have been elusive. Here we report a record of last glacial loess on the Seward Peninsula, along with studies of a transect of loess localities also thought to date to the last glacial period. Highly diverse hypotheses on the origin of loess on the Seward Peninsula include local volcanic rocks and mountain ranges to the north and south, as well as offshore deposits. We present particle size and mineralogical and geochemical data that indicate that the most likely sources for loess in this part of eastern Beringia are glaciogenic silt particles of the Kobuk River and Noatak River, both of which drain the Brooks Range to the northeast. Northeasterly paleowinds were therefore responsible for loess on the Seward Peninsula. Such winds probably occurred during late summer or early autumn, when river discharge was at a minimum but temperatures were still above freezing. Northeasterly winds during the last glacial period are in good agreement with a recent paleoclimate model.

Alaska

Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters

Near-real-time earthquake-induced fatality estimation using crowdsourced data and few-shot large-language models

When a damaging earthquake occurs, immediate information about casualties (e.g., fatalities and injuries) is critical for time-sensitive decision-making by emergency response and aid agencies in the first hours and days. Systems such as the Prompt Assessment of Global Earthquakes for Response (PAGER) by the U.S. Geological Survey (USGS) were developed to provide a forecast of such impacts within about 30 min of any significant earthquake globally. However, existing disaster-induced human loss estimation systems often rely on early casualty reports manually retrieved from global traditional media, which are labor-intensive, time-consuming, and have significant time latencies. Recent approaches use keyword matching and topic modeling to identify human casualty-relevant information from social media but tend to be error-prone when dealing with complex semantics in multi-lingual text data and parsing dynamically changing and conflicting human death and injury numbers shared by various unvetted sources in social media platforms. In this work, we introduce an end-to-end framework to significantly improve the timeliness and accuracy of global earthquake-induced human loss forecasting using multi-lingual, crowdsourced social media. Our framework integrates (i) a hierarchical casualty extraction model built upon large language models, prompt design, and few-shot learning to retrieve quantitative human loss claims from social media, (ii) a physical constraint-aware, dynamic-truth discovery model that discovers the truthful human loss from massive noisy and potentially conflicting human loss claims, and (iii) a Bayesian updating loss projection model that dynamically updates the final loss estimation using discovered truths. We test the framework in real-time on a series of global earthquake events in 2021 and 2022 and show that our framework effectively automates the retrieval of casualty information faster but with comparable accuracy to those now retrieved manually by the USGS. The code associated with this work is made available at: https://github.com/SusuXu-s-Lab/Hierarchical-Earthquake-Casualty-Information-Retrieval

International Journal of Disaster Risk Reduction

On algorithmically determined versus traditional macroseismic intensity assignments

The utility of macroseismic data, defined as the effects of earthquakes on humans and the built environment, has been increasingly recognized following the advent of online systems that now produce unprecedented volumes of macroseismic intensity information. Contributed reports from the U.S. Geological Survey “Did You Feel It?” (DYFI) system ( Wald et al ., 1999 ) are used to generate intensity values with an algorithm based on seminal work by Dengler and Dewey (1998) . The algorithm was developed initially to reproduce intensity values assigned by expert opinion using questionnaire results collected by telephone survey. In this article, I discuss reasons why intensity values from (self‐selected) DYFI responses can differ from values that would be assigned by expert opinion given more complete data from randomly selected participants. For example, with the data used by Dengler and Dewey (1998) , intensities near 4 could be determined from the percentage of people who felt shaking in each town. With less spatially rich data from self‐selected participants, this percentage often cannot be determined reliably. Audible noises are key additional diagnostic criteria for modified Mercalli intensity (MMI) 4, but, although the DYFI system includes a question about noise, following Dengler and Dewey (1998) , the DYFI algorithm does not include a noise indicator. At the upper end of the scale, as defined the DYFI algorithm yields a maximum intensity value of 9.05, nominally corresponding to peak ground acceleration of 75% g . These and other factors can result in DYFI values that are low compared to traditional MMI values assigned using expert opinion, even absent factors that can bias traditional MMI assignments. Modern ground‐motion intensity conversion equations determined using DYFI intensities are expected to be appropriate for DYFI intensities, but the results of this study suggest that biases may be introduced if DYFI and traditional intensities are assumed to be interchangeable.

Seismological Research Letters

Remote sensing enables basin-scale inventories of coal mine methane

Underground coal mines are important global sources of methane, but emission estimates are uncertain. We show that emission estimates for individual mines from aircraft remote-sensing surveys in the United States agree within 40% with direct measurements used for national emission reporting (IPCC Tier 3 estimate). Such direct measurements are unavailable in most countries, which rely on estimated emission factors (EFs) applied to coal-production rates. We find that EFs from IPCC Tier 1 and the Model for Calculating Coal Mine Methane (MC2M) methods overestimate U.S. emissions 3-fold due to incorrect dependence on mine depth. An IPCC Tier 2 method using measured basin-specific mine gas content agrees with direct emission measurements but does not account for gob well emissions and requires gas content data that are generally unavailable. We show that aircraft remote sensing for a small sample of mines can successfully estimate basin-specific EFs for ventilation shafts and gob wells, enabling estimates of basin- and national-scale emissions. We discuss how the method can be applied with satellite remote sensing to quantify coal emissions worldwide.

Alabama, Colorado, Kentucky, New Mexico, Ohio, Pen

Evaluating machine learning approaches to identify and predict oil and gas produced water lithium concentrations

Recently, the demand for battery-grade lithium has substantially increased, largely due to electrification of the transportation sector. The search for new lithium sources has turned to produced waters (frequently brines), a large-volume wastewater by-product of oil and gas extraction. Geochemical analysis indicates the presence of varying concentrations of lithium from produced water samples collected across the United States and represented in the U.S. Geological Survey’s National Produced Water Geochemical Database, as well as mixtures of Marcellus Shale produced water included in the Pennsylvania Department of Environmental Protection’s Oil and Gas Well Waste Reports. We first examined whether the geochemical signature of the lithium-bearing produced waters is sufficiently distinct so that machine learning (ML) can be used to correctly classify samples to the formation of origin. The produced water sample data used to assess classification accuracy were from the Marcellus Shale, Utica Shale and Point Pleasant Formation (Utica), and Smackover Formation oil and gas wells. Further, we evaluated the potential for ML to accurately classify Marcellus Shale produced water spatially (i.e., northeast versus southwest Pennsylvania). We then investigated whether ML algorithms applied to a suite of geochemical concentration data (i.e. Ba, Br, Cl, K, Mg, Sr) may be used to predict the lithium concentration of an unknown sample. Finally, we applied an estimated economic lithium grade cutoff of 150 milligrams per liter (mg/l) and assessed the utility of ML to predict whether a produced water sample would fall above or below the grade cutoff based on the suite of geochemical parameters. Four machine learning algorithms—Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Networks (DNN) were assessed. This study successfully demonstrates that all four machine learning methods can precisely and accurately estimate lithium concentrations and geologic formation classification. The products of this study contribute to the growing body of knowledge aimed at expanding the lithium resource base within the United States.

Alabama, Arkansas, Florida, Georgia, Louisiana, Mi

A newly identified creeping strand of the Concord fault, San Francisco Bay Area

The Concord fault constitutes a major branch of the Pacific–North America transform plate boundary in Northern California, bridging the strike‐slip Bartlett Springs ‐ Green Valley Fault system to the north with the Greenville and Calaveras Faults to the south. Like many faults in the San Francisco Bay Area its long‐term slip is partially accommodated by aseismic slip (creep). Although creep has been recognized and monitored on the northern half of the fault for decades, the precise location of the southern half of the fault and its slip rate—whether accommodated seismically or aseismically—has remained enigmatic. How slip transfers between the Concord and Greenville or Calaveras faults to the south remains an outstanding question. New field observations presented here indicate that the active trace of the fault south of downtown Concord is not where previously interpreted and is indeed actively creeping. We report observations of shallow creep continuing >7 km farther south along the Concord fault than previously reported, along a fault strand not previously recognized for most of its length. This is evident as right‐laterally deflected concrete curbs and sidewalk slabs on both sides of every street that crosses the fault at a high angle in southeast Concord and northeast Walnut Creek. We document the magnitude and location of these deflections to estimate accumulated right‐lateral aseismic slip expressed in engineered structures. Offsets of these piercing lines range from 8 to 18 cm, over widths varying from narrow breaks along centimeter‐scale concrete joints to 10‐m‐wide zones of deflection. Significantly, this active trace is ∼400 m west of where the Quaternary active trace has previously been inferred, placing it within—rather than bounding—the built area of suburban Concord. Slip along the fault has already caused infrastructure damage. These results revise our understanding of the southern Concord fault and help constrain its seismic potential.

California

Magnitude conversion relations create substantial differences in seismic hazard models

Earthquake catalogs are essential data inputs for seismic hazard modeling. Because earthquake magnitudes are reported in a variety of types (e.g., local magnitudes and moment magnitudes), magnitude conversion relationships must be used to convert the different magnitude types present in a catalog to a uniform magnitude type to avoid biases in the hazard computation. However, these conversion relationships are often uncertain and have been shown to sometimes perform poorly. Here, we investigate the sensitivity of the gridded seismicity component of the National Seismic Hazard Model (NSHM) to the catalog conversion equations in the Eastern United States. In the 2023 NSHM, magnitudes of various types were converted to moment magnitudes using equations developed by the Central and Eastern United States Seismic Source Characterization for Nuclear Facilities (CEUS‐SSCn), based on least‐squares (LS) regressions made using data from a catalog containing events up through 2008. We recompute these equations using events in the Advanced National Seismic System Comprehensive Earthquake Catalog with multiple magnitudes from 2000 to 2023. Although we prefer the use of orthogonal regressions for our datasets, LS regressions produce broadly similar results, with both approaches exhibiting large deviations from the CEUS‐SSCn conversions, especially at smaller magnitudes. We compare the spatial distribution of annual rates using three different models: (1) the 2023 NSHM conversions, (2) our updated conversions, and (3) no conversions. We find that the choice of conversions leads to substantial differences in the rate forecasts, which can greatly impact the seismic hazard model, particularly in regions with low‐seismicity rates such as the Eastern United States, where the hazard is dominated by gridded seismicity rather than a fault model.

Seismological Research Letters