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Use of Numerical Simulations in Surface-Water Studies by the U.S. Geological Survey in Missouri

Numerical simulations of surface-water systems can be a useful tool to predict and understand a variety of physical, chemical, and ecological processes. A number of applications have been conducted by the U.S. Geological Survey Missouri Water Science Center in conjunction with ecological and flood studies in Missouri. Numerical simulations can provide a physically based method to predict natural processes in situations where it is impractical to measure the results directly as a result of cost, time, or infrequent occurrence. Numerical simulations provide a means of analyzing 'What if?' scenarios. For example, a simulation can be used to estimate the effects of reservoirs in a basin on the timing and magnitude of downstream streamflows. Simulations also may provide a better understanding of a complex process, such as sediment transport and deposition during a large flood. Alternatively, numerical simulations can be used to quantify aquatic habitat that is defined by the hydraulic (depth and velocity) characteristics of streamflow. This report provides information on recent applications of numerical simulations of hydraulic, floodplain, and watershed processes.

Fact Sheet↗

Conceptual understanding and groundwater quality of selected basin-fill aquifers in the Southwestern United States

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey has been conducting a regional analysis of water quality in the principal aquifer systems in the southwestern United States (hereinafter, “Southwest”) since 2005. Part of the NAWQA Program, the objective of the Southwest Principal Aquifers (SWPA) study is to develop a better understanding of water quality in basin-fill aquifers in the region by synthesizing information from case studies of 15 basins into a common set of important natural and human-related factors found to affect groundwater quality. The synthesis consists of three major components: 1. Summary of current knowledge about the groundwater systems, and the status of, changes in, and influential factors affecting quality of groundwater in basin-fill aquifers in 15 basins previously studied by NAWQA (this report). 2. Development of a conceptual model of the primary natural and human-related factors commonly affecting groundwater quality, thereby building a regional understanding of the susceptibility and vulnerability of basin-fill aquifers to contaminants. 3. Development of statistical models that relate the concentration or occurrence of specific chemical constituents in groundwater to natural and human-related factors linked to the susceptibility and vulnerability of basin-fill aquifers to contamination. Basin-fill aquifers occur in about 200,000 mi 2 of the 410,000 mi 2 SWPA study area and are the primary source of groundwater supply for cities and agricultural communities. Four of the principal aquifers or aquifer systems of the United States are included in the basin-fill aquifers of the study area: (1) the Basin and Range basin-fill aquifers in California, Nevada, Utah, and Arizona; (2) the Rio Grande aquifer system in New Mexico and Colorado; (3) the California Coastal Basin aquifers; and (4) the Central Valley aquifer system in California. Because of the generally limited availability of surface-water supplies in the arid to semiarid climate, cultural and economic activities in the Southwest are particularly dependent on supplies of good-quality groundwater. Irrigation and public-supply withdrawals from basin-fill aquifers in the study area account for about one quarter of the total withdrawals from all aquifers in the United States. Many factors influence the quality of groundwater in the 15 case-study basins, but some common factors emerge from the basin summaries presented in this report. These factors include the chemical composition of the recharge water, consolidated rock geology and composition of aquifer materials derived from consolidated rock, and land and water use. The major water-quality issues in many of the developed case-study basins are increased concentrations of dissolved solids, nitrate, and VOCs in groundwater as a result of human activities. The information presented and the citations listed in this report serve as a resource for those interested in the groundwater-flow systems in the NAWQA case-study basins. The summaries of water-development history, hydrogeology, conceptual understanding of the groundwater system under both predevelopment and modern conditions, and effects of natural and human-related factors on groundwater quality presented in the sections on each basin also serve as a foundation for the synthesis and modeling phases of the SWPA regional study.

Arizona, California, Colorado, Nevada, New Mexico,↗

PFAS sampling activities in the U.S. Geological Survey national networks

Per- and polyfluoroalkyl substances (PFAS), frequently called “forever chemicals,” are used for a wide variety of industrial purposes and are often found in common household and industrial items such as firefighting foams, non-stick cookware, and water-resistant materials. The contamination of water, air, and soil by PFAS is a national and global issue due to their widespread occurrence in multiple applications and resistance to biodegradation and other traditional treatment processes. Research indicates that many PFAS can be emitted to the atmosphere and transported and deposited long distances from the source. The U.S. Geological Survey (USGS) Water Resources Mission Area received funding to implement a national-scale sampling effort to assess PFAS occurrence. To follow agency directives, the National Water Quality Network (NWQN) added PFAS sample monitoring for both surface water and groundwater, and also added PFAS monitoring to selected sites in the National Atmospheric Deposition Program (NADP).

General Information Product↗

Records of wells and chemical analyses of ground water in Charles Mix and Douglas counties, South Dakota

The U.S. Geological Survey, in cooperation with the South Dakota Department of Environmental and Natural Resources, maintains a data base of information on water resources in the State of South Dakota. The ground-water site data for Charles Mix and Douglas Counties are presented in two tables, with the data organized by county and location. The chemical data for ground-water sites also are located in a table organized by geologic unit and location.

Open-File Report↗

Effects of urbanization on stream ecosystems along an agriculture-to-urban land-use gradient, Milwaukee to Green Bay, Wisconsin, 2003-2004

In 2003 and 2004, 30 streams near Milwaukee and Green Bay, Wisconsin, were part of a national study by the U.S. Geological Survey to assess urbanization effects on physical, chemical, and biological characteristics along an agriculture-to-urban land-use gradient. A geographic information system was used to characterize natural landscape features that define the environmental setting and the degree of urbanization within each stream watershed. A combination of land cover, socioeconomic, and infrastructure variables were integrated into a multi-metric urban intensity index, scaled from 0 to 100, and assigned to each stream site to identify a gradient of urbanization within relatively homogeneous environmental settings. The 35 variables used to develop the final urban intensity index characterized the degree of urbanization and included road infrastructure (road area and road traffic index), 100-meter riparian land cover (percentage of impervious surface, shrubland, and agriculture), watershed land cover (percentage of impervious surface, developed/urban land, shrubland, and agriculture), and 26 socioeconomic variables (U.S. Census Bureau, 2001). Characteristics examined as part of this study included: habitat, hydrology, stream temperature, water chemistry (chloride, sulfate, nutrients, dissolved and particulate organic and inorganic carbon, pesticides, and suspended sediment), benthic algae, benthic invertebrates, and fish. Semipermeable membrane devices (SPMDs) were used to assess the potential for bioconcentration of hydrophobic organic contaminants (specifically polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine and pyrethroid insecticides) in biological membranes, such as the gills of fish. Physical habitat measurements reflective of channel enlargement, including bankfull channel size and bank erosion, increased with increasing urbanization within the watershed. In this study, percentage of riffles and streambed substrate size were more strongly related to local geologic setting, slope, watershed topography, and river-engineering practices than to urbanization. Historical local river-engineering features such as channelization, bank stabilization, and grade controls may have confounded relations among habitat characteristics and urbanization. A number of hydrologic-condition metrics (including flashiness and duration of high flow during pre- or post-ice periods) showed strong relations to the urban intensity index. Hydrologic-condition metrics cannot be used alone to predict habitat or geomorphic change. Chloride and SPMD measures of potential toxicity and polycyclic aromatic hydrocarbon concentrations showed the strongest positive correlations to urbanization including increases in road infrastructure, percentage of impervious surface in the watershed, urban land cover, and land-distribution related to urban land cover. This suggests that automobiles and the infrastructure required to support automobiles are a significant source of these compounds in this study area. Chloride in spring and summer showed a significant positive correlation with the urban intensity index; concentrations increased with increasing road infrastructure, urban land cover, and a number of landscape variables related to urbanization. Spring concentrations of sulfate, prometon, and diazinon correlated to fewer urban characteristics than chloride, including increases in road infrastructure, percentage of impervious surface, and urban land cover. Changes in biological communities correlated to the urban intensity index or individual urban-associated variables. Decreased percentages of pollution-sensitive diatoms and diatoms requiring high dissolved-oxygen saturation correlated to increases in the percentage of developed urban land, total impervious surface, stream flashiness, population density, road-area density, and decreases in the percentage of wetland in the watershed. Invertebrate taxa richness and Coleop

Scientific Investigations Report↗

Water resources data for Arizona, 1968: Part 2. Water quality records

Water-resources investigations of the U.S. Geological Survey include the collection of water-quality data on the chemical and physical characteristics of surface and groundwater supplies of the Nation. These data for the 1968 water year for the quality of surface waters in Arizona are presented in this report. The data were collected by the Water Resources Division of the U.S. Geological Survey under the direction of H. M. Babcock, district chief. Water-quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics, such as hardness, sodium-adsorption ratio, specific conductance, and pH. Fluvial-sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water-temperature data represent once-daily observations, except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained. The Geological Survey published the annual series of water supply papers, "Quality of Surface Waters of the United States," from 1941 through 1963, which contained the chemical-quality. temperature, and suspended-sediment data of the water. Each volume covered an area whose boundaries coincided with those of certain natural drainage areas. The records for Arizona are contained in part 9 of the water-supply paper series. (See table, p. 13.) These publications are available in most public libraries. Beginning with the 1964 water year, water-quality records for surface water obtained by the Geological Survey have been published in a new series of annual releases on a State boundary basis. These reports are primarily for local and immediate use, and their distribution is limited. The records also will be published in Geological Survey water-supply papers.

Arizona↗

Problems of underground storage of wastes

Problems of underground storage of waste involve geology in its broadest sense, including hydrology, geochemistry, and geophysics. Wastes may be solid, liquid, or gaseous, and they may be chemically toxic or noxious, esthetically offensive, or radioactive. Some wastes require only temporary containment, whereas others must be isolated for indefinitely long periods. The means and locale for emplacement underground depend upon many governing geological factors, including the physical, chemical, hydrological, and hydraulic properties of the host formation. These must be studied relative to the physical, chemical, and thermal properties of the waste and of potential interactions between the waste and the host formation. Thorough knowledge is essential because lack of it may lead to undesirable or disastrous environmental consequences. Escape of waste may contaminate the surface or near-surface environment; it may destroy the usefulness or accessibility of resources such as ground water, petroleum, and minerals. Effective management of underground waste requires adaptation of current technology and development of new technology.

Journal of Research of the U.S. Geological Survey↗

Water resources data for Arizona, 1967: Part 2. Water quality records

Water-resources investigations of the U.S. Geological Survey include the collection of water-quality data on the chemical and physical characteristics of surface and ground-water supplies of the Nation. These data for the 1967 water year for the quality of surface waters in Arizona are presented in this report. The data were collected by the Water Resources Division of the U.S. Geological Survey under the direction of H. M. Babcock, district chief. Water-quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics, such as hardness, sodium-adsorption ratio, specific conductance, and pH. Fluvial-sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water-temperature data represent once-daily observations, except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained. The Geological Survey published the annual series of water-supply papers, "Quality of Surface Waters of the United States," from 1941 through 1963, which contained the chemical-quality, temperature, and suspended-sediment data of the water. Each volume covered an area whose boundaries coincided with those of certain natural drainage areas. The records for Arizona are contained in part 9 of the water-supply paper series. (See table, p. 12.) These publications are available in most public libraries. Beginning with the 1964 water year, water-quality records for surface water obtained by the Geological Survey have been published in a new series of annual releases on a State boundary basis. These reports are primarily for local and immediate use, and their distribution is limited. The records also will be published in Geological Survey water-supply papers.

Arizona↗

Assessment of endocrine-disrupting chemicals attenuation in a coastal plain stream prior to wastewater treatment plant closure

The U.S. Geological Survey is conducting a combined pre/post-closure assessment at a long-term wastewater treatment plant (WWTP) site at Fort Gordon near Augusta, Georgia. Here, we assess select endocrine-active chemicals and benthic macroinvertebrate community structure prior to closure of the WWTP. Substantial downstream transport and limited instream attenuation of endocrine-disrupting chemicals (EDCs) was observed in Spirit Creek over a 2.2-km stream segment downstream of the WWTP outfall. A modest decline (less than 20% in all cases) in surface water detections was observed with increasing distance downstream of the WWTP and attributed to partitioning to the sediment. Estrogens detected in surface water in this study included estrone (E1), 17β-estradiol (E2), and estriol (E3). The 5 ng/l and higher mean estrogen concentrations observed in downstream locations indicated that the potential for endocrine disruption was substantial. Concentrations of alkylphenol ethoxylate (APE) metabolite EDCs also remained statistically elevated above levels observed at the upstream control site. Wastewater-derived pharmaceutical and APE metabolites were detected in the outflow of Spirit Lake, indicating the potential for EDC transport to aquatic ecosystems downstream of Fort Gordon. The results indicate substantial EDC occurrence, downstream transport, and persistence under continuous supply conditions and provide a baseline for a rare evaluation of ecosystem response to WWTP closure.

Georgia↗

Water resources data for Arizona, 1966: Part 2. Water quality records

Water-resources investigations of the U.S. Geological Survey include the collection of water-quality data on the chemical and physical characteristics of surface and ground-water supplies of the Nation. These data for the 1966 water year for the quality of surface waters in Arizona are presented in this report. The data were collected by the Water Resources Division of the U.S. Geological Survey under the di rection of H. M. Babcock, district chief. Water-quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics, such as hardness, sodium-adsorption ratio, specific conductance, and pH. Fluvial-sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water temperature data represent once-daily observations, except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained. The Geological Survey published the annual series of water-supply papers, "Quality of Surface Waters of the Unit ed States," from 1941 through 1963, which contained the chemical-quality, temperature, and suspended sediment data of the water. Each volume covered an area whose boundaries coincided with those of certain natural drainage areas. The records for Arizona are contained in part 9 of the water-supply paper series. (See table, p. 12.) These publications are available in most public libraries. Beginning with the 1964 water year, water quality records for surface water obtained by the Geological Survey have been published in a new series of annual releases on a State boundary basis. This report is primarily for local and immediate use, and its distribution is limited. The records will be published in Geological Survey water-supply papers at 5-year intervals. The first compilation will cover only the 1964 and 1965 water years.

Arizona↗

Water-quality conditions during low flow in the lower Youghiogheny River basin, Pennsylvania, October 5-7, 1998

In October 1998, a chemical synoptic survey was conducted by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, National Energy Technology Laboratory, in the Lower Youghiogheny River Basin in Pennsylvania to give a snapshot of present (1998) water quality during low-flow conditions. Water samples from 38 sites—12 mainstem sites, 22 tributaries, and 4 mine discharges that discharge directly to the Youghiogheny River—were used to identify sources of contaminants from mining operations. Specific conductance, water temperature, pH, and dissolved oxygen were measured in the field at each site and concentrations of major ions and trace elements were measured in the laboratory.z Unaccounted for gains and losses in streamflow were measured during the study. Unaccounted for losses in streamflow might be attributed to water loss through streambed fractures. Extensive mine tunnels are present in the basin and loss of water to these tunnels seems likely. Unaccounted for gains in streamflow may be from unmeasured tributaries or surface seeps, but most of the gains are suspected to come from artesian flow through fractures in the streambed from underground mine pools. Influent flows of rust-colored water were noted in some river sections. The pH values for all the samples collected during this survey were above 5.8, and most (33 of 38 samples) were above 7.0. Samples from the four mine-discharge sites also had pH values between 6.3 and 6.7. The lowest pH (5.8) was in a tributary, Galley Run. All 38 sampling sites had net alkalinity. The alkalinity load in the Youghiogheny River increased between Connellsville and McKeesport from 35 to 79 tons per day. Above Smithton, the measured alkalinity load in the Lower Youghiogheny River agreed well with the estimated alkalinity load. Below Smithton, measured alkalinity loads in the Lower Youghiogheny River are greater than calculated loads, resulting in unaccounted for gains in alkalinity. These gains are believed to be from seeps in the streambed. Approximately one-third of the load of total alkalinity in the Youghiogheny River at McKeesport is attributed to Sewickley Creek, which contributes 14 tons per day. Sulfate concentrations in the Youghiogheny River steadily increase from 33 milligrams per liter at Connellsville to 77 milligrams per liter near McKeesport. The measured concentrations of sulfate exceeded Pennsylvania water-quality standards at four tributary sites (Galley Run, Hickman Run, Sewickley Creek, and Gillespie Run) and all four mine-discharge sites but not at any main-stem sites. A large increase in sulfate load between West Newton and Sutersville can be attributed almost entirely to the contribution from Sewickley Creek (49 tons per day). Approximately 25 percent of the load measured between Connellsville and McKeesport is unaccounted for. These gains are believed to be from seeps in the streambed from underground mine pools. Similar patterns also were observed for loads of sodium, calcium, and magnesium. Unmeasured inputs from mine drainage are believed to be the source of these loads. Elevated concentrations (above background levels) of chemicals associated with drainage from coal-mining operations were measured in samples from tributaries, especially from Galley Run, Gillespie Run, and Sewickley Creek, and from the mine-discharge sites. The synoptic survey conducted for this study was successful in identifying generalized reaches of the Youghiogheny River where unaccounted for loads of constituents associated with mining activities are entering the river. However, the survey was not able to pinpoint the location of these loads. Remote-sensing techniques, such as thermal infrared imaging by the National Energy Technology Laboratory, could be useful for determining the precise locations of these inputs.

Water-Resources Investigations Report↗

Physical, chemical, and biological characteristics of Sturgeon Lake, Goodhue County, Minnesota, 2003-04

The U.S. Geological Survey, in cooperation with the Prairie Island Indian Community and the Minnesota Department of Natural Resources, conducted a study of Sturgeon Lake (a backwater lake in Navigation Pool 3 of the Mississippi River) during 2003-04 to describe the physical, chemical, and biological characteristics of the lake. Riparian and shoreline areas surrounding Sturgeon Lake consist primarily of deciduous tree and shrub cover with minimal amounts of commercial or residential land use. Woody debris and aquatic vegetation are the major types of physical habitat suitable for fish and invertebrates. Among 10 bottom-sediment sampling sites, 24 organic wastewater compounds, 1 organochlorine pesticide metabolite (p,p’DDE), and total polychlorinated biphenyls (PCBs) were detected in the bottom sediments of Sturgeon Lake. The most prevalent class of compounds detected were polyaromatic hydrocarbons. Other classes of compounds detected include sterols, disinfectants, plastic components, alkylphenols, and fragrances. Three compounds detected (bisphenol A, benzo[a]pyrene, and triclosan) are considered endocrine disrupting compounds. Twenty-one and 49 invertebrate taxa were identified from 10 bottom-sediment and 6 woody-debris/vegetation samples, respectively. Most of the taxa were Diptera in the family Chironomidae. The most common invertebrate in terms of density in bottom-sediment samples was the burrowing mayfly ( Hexagenia sp.). Trichoptera in the families Hydropsychidae or Polycentropodidae were common in most of the woody-debris samples. The presence of the Hexagenia larvae in samples indicates that the bottom sediments are stable and that dissolved oxygen concentrations in the lake do not drop to acute or sub-lethal anoxic conditions. Backwater lakes such as Sturgeon Lake are important areas of habitat for aquatic organisms along the Mississippi River, and this report provides baseline physical, chemical, and biological information that resource managers can compare with future investigations.

Minnesota↗

Bed-Sediment Sampling and Analysis for Physical and Chemical Properties of the Lower Mississippi River near Memphis, Tennessee

In February 2010, the U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, Memphis District, investigated the presence of inorganic elements and organic compounds in bed sediments of the lower Mississippi River. Selected sites were located in the navigation channel near river miles 737, 773, and 790 near Memphis, Tennessee. Bed-sediment samples were collected using a Shipek grab sampler mounted to a boom crane with a motorized winch. Samples then were processed and shipped to the U.S. Geological Survey Sediment Laboratory in Rolla, Missouri, the USGS National Water Quality Laboratory in Denver, Colorado, and to TestAmerica Laboratory, Inc. in West Sacramento, California. Samples were analyzed for grain size, inorganic elements (including mercury), and organic compounds. Chemical results were tabulated and listed with sediment-quality guidelines and presented with the physical property results. All of the bed material samples collected during this investigation yielded concentrations that were less than the Consensus-Based Probable Effect Concentration guidelines. The physical properties were tabulated and listed using a standard U.S. Geological Survey scale of sizes by class for sediment analysis. All of the samples collected during this investigation indicated a percent composition mostly comprised of sand, ranging from less than 0.125 millimeters to less than 2 millimeters.

Open-File Report↗

Real-time, continuous water-quality monitoring in Indiana and Kentucky

Water-quality “super” gages (also known as “sentry” gages) provide real-time, continuous measurements of the physical and chemical characteristics of stream water at or near selected U.S. Geological Survey (USGS) streamgages in Indiana and Kentucky. A super gage includes streamflow and water-quality instrumentation and representative stream sample collection for laboratory analysis. USGS scientists can use statistical surrogate models to relate instrument values to analyzed chemical concentrations at a super gage. Real-time, continuous and laboratory-analyzed concentration and load data are publicly accessible on USGS Web pages.

Indiana, Kentucky↗

Desert wetlands in the geologic record

Desert wetlands support flora and fauna in a variety of hydrologic settings, including seeps, springs, marshes, wet meadows, ponds, and spring pools. Over time, eolian, alluvial, and fluvial sediments become trapped in these settings by a combination of wet ground conditions and dense plant cover. The result is a unique combination of clastic sediments, chemical precipitates, and organic matter that is preserved in the geologic record as ground-water discharge (GWD) deposits. GWD deposits contain information on the timing and magnitude of past changes in water-table levels and, therefore, are a potential source of paleohydrologic and paleoclimatic information. In addition, they can be important archeological and paleontological archives because desert wetlands provide reliable sources of fresh water, and thus act as focal points for human and faunal activities, in some of the world's harshest and driest lands. Here, we review some of the physical, sedimentological, and geochemical characteristics common to GWD deposits, and provide a contextual framework that researchers can use to identify and interpret geologic deposits associated with desert wetlands. We discuss several lines of evidence used to differentiate GWD deposits from lake deposits (they are commonly confused), and examine how various types of microbiota and depositional facies aid in reconstructing past environmental and hydrologic conditions. We also review how late Quaternary GWD deposits are dated, as well as methods used to investigate desert wetlands deeper in geologic time. We end by evaluating the strengths and limitations of hydrologic and climatic records derived from GWD deposits, and suggest several avenues of potential future research to further develop and utilize these unique and complex systems.

Earth-Science Reviews↗

Rare earth abundances and Rb-Sr systematics of basalts, gabbro, anorthosite and minor granitic rocks from the Indian Ocean Ridge System, Western Indian Ocean

Basalts dredged from the Mid-Indian Ocean Ridge System have rare earth, Rb, and Sr concentrations like those from other mid-ocean ridges, but have slightly higher Sr87/Sr86 ratios. Underlying gabbroic complexes are similar to the basalts in Sr87/Sr86, but are poorer K, Rb, and in rare earths. The chemical and isotopic data, as well as the geologic relations suggest a cumulate origin for the bulk of the gabbroic complexes. ?? 1979 Springer-Verlag.

Contributions to Mineralogy and Petrology↗