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Organic geochemistry applied to environmental assessments of Prince William Sound, Alaska, after the Exxon Valdez oil spill—a review

Organic geochemistry played a major role in the environmental assessments conducted following the Exxon Valdez oil spill, which occurred on March 24, 1989, and released about 258,000 bbls (41 million liters) of Alaska North Slope crude oil into Prince William Sound. Geochemical analyses of more than 15,000 sediment, tar, and biological samples and about 5000 water samples provide the largest database yet collected on oil-spill chemistry, and we review the results here. The marine environment of the Sound has a complex background of petrogenic, pyrogenic, and biogenic hydrocarbons from natural and anthropogenic sources. Geochemical evaluation of the fate and effects of the spilled oil required that this oil and its residues be distinguished from the background. A variety of molecular and isotopic techniques were employed to identify various hydrocarbon sources and to distinguish quantitatively among mixed sources in the samples. Although the specific criteria used to distinguish multiple sources in the region affected by the Exxon Valdez spill are not necessarily applicable to all spill situations, the principles that governed their selection are. Distributions of polycyclic aromatic hydrocarbons (PAH) and dibenzothiophenes distinguish Exxon Valdez oil and its weathered residues from background hydrocarbons in benthic sediments. Ratios of C 2 -dibenzothiophene C 2 -phenanthrene "> C 2 -dibenzothiopheneC 2 -phenanthrene and C 3 -dibenzothiophene C 3 -phenanthrene "> C 3 -dibenzothiopheneC 3 -phenanthrene were particularly useful. Carbon isotopes and terpane distributions distinguished Exxon Valdez residues found on shorelines from tars from other sources. Diesel and diesel soot were identified by the absence of alkylated chrysenes and a narrow distribution of n -alkanes, whereas pyrogenic products were distinguished by the dominance of 4- to 6-ring PAH over 2- to 3-ring PAH and by the dominance of non-alkylated over alkylated homologues of each PAH series. The presence of 18α(H)-oleanane in benthic sediments, coupled with its absence in Exxon Valdez oil and its residues, confirm another petrogenic source. Results of geochemical studies suggest that the petrogenic component in the background of benthic sediments is derived from oil seeps in the eastern Gulf of Alaska. In 1990 and 1991, Exxon Valdez residues, generally forming a small increment to the pre-spill background, were found to be only sporadically distributed in some shallow, near shore sediments adjacent to shorelines that had been heavily oiled in 1989. In 1994, occurrences of Exxon Valdez tars on shoreline surfaces were rare, although residues could be found buried in shoreline sediments at some isolated locations along the spill path where they were protected from wave action. Spilled oil residues collected 16 months after the spill were degraded, on average, by nearly 50%. Shoreline residues from sources other than the spill were also identified and are widespread throughout the Sound. These residues include (1) geochemically distinct tars and oils imported from California oil fields to Alaska for fuel and construction purposes prior to the discovery of the Cook Inlet and North Slope oil fields, (2) diesel and diesel soot, and (3) more highly refined products. Of the more than 2700 chemical analyses of biological samples of higher life forms (fish, birds, and mammals) about 150 (6%) indicate recognizable residues of Exxon Valdez oil, which were identified by their distribution of polycyclic aromatic hydrocarbons (PAH). Most of these samples (138) were collected in 1989 and most were associated with external surfaces or the gastrointestinal tract. Rarely do internal tissues or fluids contain recognizable fingerprints of spilled oil. This observation includes samples from marine mammals that were visibly oiled externally. Other hydrocarbon sources, including diesel and a non-petroleum artifact that occurs when concentrations of individual PAH are at or near their method detection limit, are also identified in biological samples.

Alaska↗

Geochemical evidence for a Brooks Range mineral belt, Alaska

Geochemical studies in the central Brooks Range, Alaska, delineate a regional, structurally controlled mineral belt in east—west-trending metamorphic rocks and adjacent metasedimentary rocks. The mineral belt extends eastward from the Ambler River quadrangle to the Chandalar and Philip Smith quadrangles, Alaska, from 147° to 156°W. longitude, a distance of more than 375 km, and spans a width from 67° to 69°N. latitude, a distance of more than 222 km. Within this belt are several occurrences of copper and molybdenum mineralization associated with meta-igneous, metasedimentary, and metavolcanic rocks; the geochemical study delineates target areas for additional occurrences. A total of 4677 stream-sediment and 2286 panned-concentrate samples were collected in the central Brooks Range, Alaska, from 1975 to 1979. The −80 mesh (< 177 μm) stream sediment and the heavy (specific gravity > 2.86) nonmagnetic fraction of the panned concentrates from stream sediment were analyzed by semiquantitative spectrographic methods. Two geochemical suites were recognized in this investigation; a base-metal suite of copper-lead-zinc and a molybdenum suite of molybdenum-tin-tungsten. These suites suggest several types of mineralization within the metamorphic belt. Anomalies in molybdenum with associated Cu and W suggest a potential porphyry molybdenum system associated with meta-igneous rocks. This regional study indicates that areas of metaigneous rocks in the central metamorphic belt are target areas for potential mineralized porphyry systems and that areas of metavolcanic rocks are target areas for potential massive sulfide mineralization.

Alaska↗

Palynology, paleoclimatology and correlation of middle Miocene beds from Porcupine River (locality 90-1), Alaska

Beds in the Upper Ramparts Canyon of the Porcupine River, Alaska (67?? 20' N, 141?? 20' W), yielded a flora rich in pollen of hardwood genera now found in the temperate climates of North America and Asia. The beds are overlain or enclosed by two basalt flows which were dated to 15.2 ?? 0.1 Ma by the 40Ar 39Ar method, fixing the period of the greatest abundance of warm-loving genera to the early part of the middle Miocene. The assemblage is the most northern middle Miocene flora known in Alaska. Organic bed 1 underlies the basalt and is older than 15.2 Ma, but is of early to middle Miocene age. The pollen assemblage from organic bed 1 is dominated by conifer pollen from the pine and redwood-cypress-yew families with rare occurrences of temperate hardwoods. Organic bed 2 is a forest floor containing redwood trees in life position, engulfed by the lowest basalt flow. A pine log has growth rings up to 1 cm thick. Organic beds 3 and 4 comprise lacustrine sediment and peat between the two basalt flows. Their palynoflora contain conifers and hardwood genera, of which about 40% have modern temperate climatic affinities. Hickory, katsura, walnut, sweet gum, wingnut, basswood and elm pollen are consistently present, and beech and oak alone make up about 20% of the pollen assemblage. A warm high latitude climate is indicated for all of the organic beds, but organic bed 3 was deposited under a time of peak warmth. Climate data derived by comparison with modern east Asian vegetation suggest that, at the time of deposition of organic bed 3, the Mean Annual Temperature (MAT) was ca. 9??C, the Warm Month Mean Temperature (WMMT) was ??? 20??C and the Cold Month Mean Temperature (CMMT) was ca. -2??C. In contrast, the modern MAT for the region is -8.6??C, WMMT is 12.6??C and CMMT is -28??C. Organic beds 3 and 4 correlate to rocks of the middle Miocene-late Seldovian Stage of Cook Inlet and also probably correlate to, and more precisely date, the lower third of the Suntrana Formation in the Alaska Range, beds at Unalaklect, part of the upper Mackenzie Bay sequence in the Beaufort-Mackenzie basin, and the Mary Sachs gravel of Banks Island. This suggests that forests with significant percentages of temperate deciduous angiosperms existed between latitudes 60?? and 72??N during the early middle Miocene. ?? 1994.

Quaternary International↗

Post-breeding season distribution of black-footed and Laysan albatrosses satellite-tagged in Alaska: Inter-specific differences in spatial overlap with North Pacific fisheries

We integrated satellite-tracking data from black-footed albatrosses (Phoebastria nigripes; n = 7) and Laysan albatrosses captured in Alaska (Phoebastria immutabilis; n = 18) with data on fishing effort and distribution from commercial fisheries in the North Pacific in order to assess potential risk from bycatch. Albatrosses were satellite-tagged at-sea in the Central Aleutian Islands, Alaska, and tracked during the post-breeding season, July-October 2005 and 2006. In Alaskan waters, fishing effort occurred almost exclusively within continental shelf and slope waters. Potential fishery interaction for black-footed albatrosses, which most often frequented shelf-slope waters, was greatest with sablefish (Anoplopoma fimbria) longline and pot fisheries and with the Pacific halibut (Hippoglossus stenolepsis) longline fishery. In contrast, Laysan albatrosses spent as much time over oceanic waters beyond the continental shelf and slope, thereby overlapping less with fisheries in Alaska than black-footed albatrosses. Regionally, Laysan albatrosses had the greatest potential fishery interaction with the Atka mackerel (Pleurogrammus monopterygius) trawl fishery in the Western Aleutian Islands and the sablefish pot fishery in the Central Aleutian Islands. Black-footed albatrosses ranged further beyond Alaskan waters than Laysan albatrosses, overlapping west coast Canada fisheries and pelagic longline fisheries in the subarctic transition domain; Laysan albatrosses remained north of these pelagic fisheries. Due to inter-specific differences in oceanic distribution and habitat use, the overlap of fisheries with the post-breeding distribution of black-footed albatrosses is greater than that for Laysan albatrosses, highlighting inter-specific differences in potential vulnerability to bycatch and risk of population-level impacts from fisheries. ?? 2008 Elsevier Ltd.

Biological Conservation↗

Mercury in mosses Hylocomium splendens (Hedw.) B.S.G. and Pleurozium schreberi (Brid.) Mitt. from Poland and Alaska: Understanding the origin of pollution sources

This report shows baseline concentrations of mercury in the moss species Hylocomium splendens and Pleurozium schreberi from the Kielce area and the remaining Holy Cross Mountains (HCM) region (south-central Poland), and Wrangell-Saint Elias National Park and Preserve (Alaska) and Denali National Park and Preserve (Alaska). Like mosses from many European countries, Polish mosses were distinctly elevated in Hg, bearing a signature of cross-border atmospheric transport combined with local point sources. In contrast, Alaskan mosses showed lower Hg levels, reflecting mostly the underlying geology. Compared to HCM, Alaskan and Kielce mosses exhibited more uneven spatial distribution patterns of Hg. This variation is linked to topography and location of local point sources (Kielce) and underlying geology (Alaska). Both H. splendens and P. schreberi showed similar bioaccumulative capabilities of Hg in all four study areas. ?? 2010 Elsevier Inc.

Ecotoxicology and Environmental Safety↗

Anomalously high relief on Denali, Alaska, caused by tectonic, lithologic, and climatic drivers

We assess the growth of anomalously high relief on Denali, located in the Alaska Range, Alaska, and the tallest mountain in North America (6190 masl). Denali is 3000 m taller than most surrounding peaks. It lies inside a 19° restraining bend in the active Denali fault system that is moving at about 7 mm/yr, and thus there is a tectonic and structural driver for ongoing rock uplift. High relief around Denali is also due, in part, to its granitic rock type and low fracture density relative to adjacent metasediments. Here we show that unique climatic conditions at high elevations also contribute to the growth of relief. We examine 10Be concentrations in 1) three new gravel samples between 3500 and 5200 m elevation from sites unaffected by recent glacial erosion, 2) previously published samples from a sidewall of the Kahiltna Glacier from 2400 to 2800 masl, 3) previously published samples from medial moraines along the length of the Kahiltna Glacier from 1400 to ~500 masl, and 4) previously published alluvial samples along the Kahiltna River at an elevation of ~200 masl. These samples constitute a transect extending more than 5000 vertical meters, and the data establish that erosion rates decrease with elevation and contribute to the growth of relief. Erosion rates for the three new high-elevation samples are calculated to 4.6±0.6 mm/ka at 5.2 km, 28.6±3.7 mm/ka at 4.0 km, and 38±5 mm/ka at 3.5 km. Erosion rates at intermediate elevations, on the sidewall of the Kahiltna Glacier, range between 160-327 mm/ka. Along the medial moraines inferred erosion rates range between 140-537 mm/ka, and basin-wide erosion rates calculated from sediments in the river below the glacier range between 450-896 mm/ka. These differences in erosion rates can create relief of 3 km within 1-10 Ma, well within the estimated period of increase in rock uplift and exhumation on Denali over the last ~6 Ma. Meteorological data from 2130 to 5550 masl at 5 sites show it rarely gets above freezing above 4 km elevation, indicating that frost weathering currently plays a diminished role in erosion at high elevations. The immediate implication of this temperature and erosional correlation is an increase in relief. This is the first study to directly measure a significant decrease in erosion rates at high elevations in the relative absence of frost weathering. The results highlight the combined influence of rock type, glacial erosion, and permanent sub-zero temperatures on erosion rates. In combination with active faulting, the data explain the resultant increase in relief along the southern side of the Alaska Range over the past 100 ka.

Alaska↗

Paleoseismic potential of sublacustrine landslide records in a high-seismicity setting (south-central Alaska)

Sublacustrine landslide stratigraphy is considered useful for quantitative paleoseismology in low-seismicity settings. However, as the recharging of underwater slopes with sediments is one of the factors that governs the recurrence of slope failures, it is not clear if landslide deposits can provide continuous paleoseismic records in settings of frequent strong shaking. To test this, we selected three lakes in south-central Alaska that experienced a strong historical megathrust earthquake (the 1964 M w 9.2 Great Alaska Earthquake) and exhibit high sedimentation rates in their main basins (0.2 cm yr − 1 –1.0 cm yr − 1 ). We present high-resolution reflection seismic data (3.5 kHz) and radionuclide data from sediment cores in order to investigate factors that control the establishment of a reliable landslide record. Seismic stratigraphy analysis reveals the presence of several landslide deposits in the lacustrine sedimentary infill. Most of these landslide deposits can be attributed to specific landslide events, as multiple landslide deposits sourced from different lacustrine slopes occur on a single stratigraphic horizon. We identify numerous events in the lakes: Eklutna Lake proximal basin (14 events), Eklutna Lake distal basin (8 events), Skilak Lake (7 events) and Kenai Lake (7 events). The most recent event in each basin corresponds to the historic 1964 megathrust earthquake. All events are characterized by multiple landslide deposits, which hints at a regional trigger mechanism, such as an earthquake (the synchronicity criterion). This means that the landslide record in each basin represents a record of past seismic events. Based on extrapolation of sedimentation rates derived from radionuclide dating, we roughly estimate a mean recurrence interval in the Eklutna Lake proximal basin, Eklutna Lake distal basin, Skilak Lake and Kenai Lake, at ~ 250 yrs., ~ 450 yrs., ~ 900 yrs. and ~ 450 yrs., respectively. This distinct difference in recording can be explained by variations in preconditioning factors like slope angle, slope recharging (sedimentation rate) and the sediment source area: faster slope recharging and a predominance of delta and alluvial fan failures, increase the sensitivity and lower the intensity threshold for slope instability. Also, the seismotectonic setting of the lakes has to be taken into account. This study demonstrates that sublacustrine landslides in several Alaskan lakes can be used as reliable recorders of strong earthquake shaking, when a multi-lake approach is used, and can enhance the temporal and spatial resolution of the paleoseismic record of south-central Alaska.

Alaska↗

Stratigraphic and compositional complexities of the late Quaternary Lethe tephra in South-central Alaska

Recently discovered Lethe tephra has been proposed as a latest Pleistocene marker bed in Bristol Bay lowland NE to the Cook Inlet region, Alaska, on the basis of correlations involving a single "Lethe average" glass composition. Type deposits in the Valley of Ten Thousand Smokes, however, are chemically heterogeneous-individual lapilli as well as aggregate ash deposits have glass compositions that range from the average mode to much higher SiO2 and K2O. Moreover, a lake-sediment core from the Cook Inlet region contains one ash deposit similar to "Lethe average" and other, closely underlying deposits that resemble a mixture of the average mode and high-Si high-K mode of proximal deposits. Synthesis of previously published radiocarbon ages indicates a major eruption mainly of "Lethe average" mode about 13,000 14C yr BP. As many as six deposits in the Cook Inlet region-five chiefly "Lethe average" mode-range from about 13,000 to 15-16,000 14C yr BP, and an early Holocene deposit in the Bristol Bay lowland extends the minimum age range of Lethe tephra throughout this region to 8000 14C yr BP. Because of the appearance of "Lethe average" composition in multiple deposits spanning thousands of years, we urge caution when using a Lethe-like composition as a basis for inferring a latest Pleistocene age of a tephra deposit in south-central Alaska. Linear variation plots suggest that magma mixing caused the Lethe heterogeneity; multiple magmas were involved as well in other large pyroclastic eruptions such as Katmai (Alaska) and Rotorua (New Zealand). Lethe is an example of a heterogeneous tephra that may be better compared with other tephras by use of plots of individual analytical points rather than by calculating similarity coefficients based on edited data. ?? 2006 Elsevier Ltd and INQUA.

Quaternary International↗

Testing the use of bulk organic δ 13 C, δ 15 N, and C org :N tot ratios to estimate subsidence during the 1964 great Alaska earthquake

During the M w 9.2 1964 great Alaska earthquake, Turnagain Arm near Girdwood, Alaska subsided 1.7 &plusmn; 0.1 m based on pre- and postearthquake leveling. The coseismic subsidence in 1964 caused equivalent sudden relative sea-level (RSL) rise that is stratigraphically preserved as mud-over-peat contacts where intertidal silt buried peaty marsh surfaces. Changes in intertidal microfossil assemblages across these contacts have been used to estimate subsidence in 1964 by applying quantitative microfossil transfer functions to reconstruct corresponding RSL rise. Here, we review the use of organic stable C and N isotope values and C org :N tot ratios as alternative proxies for reconstructing coseismic RSL changes, and report independent estimates of subsidence in 1964 by using &delta; 13 C values from intertidal sediment to assess RSL change caused by the earthquake. We observe that surface sediment &delta; 13 C values systematically decrease by &sim;4&permil; over the &sim;2.5 m increase in elevation along three 60- to 100-m-long transects extending from intertidal mud flat to upland environments. We use a straightforward linear regression to quantify the relationship between modern sediment &delta; 13 C values and elevation ( n = 84, R 2 = 0.56). The linear regression provides a slope&ndash;intercept equation used to reconstruct the paleoelevation of the site before and after the earthquake based on &delta; 13 C values in sandy silt above and herbaceous peat below the 1964 contact. The regression standard error (average = &plusmn;0.59&permil;) reflects the modern isotopic variability at sites of similar surface elevation, and is equivalent to an uncertainty of &plusmn;0.4 m elevation with respect to Mean Higher High Water. To reduce potential errors in paleoelevation and subsidence estimates, we analyzed multiple sediment &delta; 13 C values in nine cores on a shore-perpendicular transect at Bird Point. Our method estimates 1.3 &plusmn; 0.4 m of coseismic RSL rise across the 1964 contact by taking the arithmetic mean of the differences ( n = 9) between reconstructed elevations for sediment above and below the 1964 earthquake subsidence contact. This estimate compares well with independent subsidence estimates derived from post-earthquake leveling in Turnagain Arm, and from microfossil transfer functions at Girdwood (1.50 &plusmn; 0.32 m). While our results support the use of bulk organic &delta; 13 C for reconstructing RSL change in southern Alaska, the variability of stable isotope values in modern and buried intertidal sediment required the analysis of multiple samples to reduce error.

Alaska↗

Younger-Dryas cooling and sea-ice feedbacks were prominent features of the Pleistocene-Holocene transition in Arctic Alaska

Declining sea-ice extent is currently amplifying climate warming in the Arctic. Instrumental records at high latitudes are too short-term to provide sufficient historical context for these trends, so paleoclimate archives are needed to better understand the functioning of the sea ice-albedo feedback. Here we use the oxygen isotope values of wood cellulose in living and sub-fossil willow shrubs (δ 18 O wc ) ( Salix spp.) that have been radiocarbon-dated ( 14 C) to produce a multi-millennial record of climatic change on Alaska's North Slope during the Pleistocene-Holocene transition (13,500–7500 calibrated 14 C years before present; 13.5–7.5 ka). We first analyzed the spatial and temporal patterns of δ 18 O wc in living willows growing at upland sites and found that over the last 30 years δ 18 O wc values in individual growth rings correlate with local summer temperature and inter-annual variations in summer sea-ice extent. Deglacial δ 18 O wc values from 145 samples of subfossil willows clearly record the Allerød warm period (∼13.2 ka), the Younger Dryas cold period (12.9–11.7 ka), and the Holocene Thermal Maximum (11.7–9.0 ka). The magnitudes of isotopic changes over these rapid climate oscillations were ∼4.5‰, which is about 60% of the differences in δ 18 O wc between those willows growing during the last glacial period and today. Modeling of isotope-precipitation relationships based on Rayleigh distillation processes suggests that during the Younger Dryas these large shifts in δ 18 O wc values were caused by interactions between local temperature and changes in evaporative moisture sources, the latter controlled by seaice extent in the Arctic Ocean and Bering Sea. Based on these results and on the effects that sea-ice have on climate today, we infer that ocean-derived feedbacks amplified temperature changes and enhanced precipitation in coastal regions of Arctic Alaska during warm times in the past. Today, isotope values in willows on the North Slope of Alaska are similar to those growing during the warmest times of the Pleistocene-Holocene transition, which were times of widespread permafrost thaw and striking ecological changes.

Alaska↗

Mercury in gray wolves (Canis lupus) in Alaska: Increased exposure through consumption of marine prey

Mercury (Hg) bioaccumulates in the tissues of organismsand biomagnifies within food-webs. Graywolves (Canis lupus) in Alaska primarily acquire Hg through diet; therefore, comparing the extent of Hg exposure inwolves, in conjunction with stable isotopes, from interior and coastal regions of Alaska offers important insight into their feeding ecology. Liver, kidney, and skeletal muscle samples from 162 graywolves were analyzed for total mercury (THg) concentrations and stable isotopic signatures (δ 13 C, δ 15 N, and δ 34 S).Median hepatic THg concentrations were significantly higher in wolves with coastal access compared to wolves from interior Alaska. Stable isotope ratios, in conjunction with THg concentrations, provide strong evidence that coastal wolves are utilizing marine prey representing several trophic levels. The utilization of cross-ecosystem food resources by coastal wolves is clearly contributing to increased THg exposure, and may ultimately have negative health implications for these animals.

Alaska↗

Late Quaternary vegetation and climate history of the central Bering land bridge from St. Michael Island, western Alaska

Pollen analysis of a sediment core from Zagoskin Lake on St. Michael Island, northeast Bering Sea, provides a history of vegetation and climate for the central Bering land bridge and adjacent western Alaska for the past ???30,000 14C yr B.P. During the late middle Wisconsin interstadial (???30,000-26,000 14C yr B.P.) vegetation was dominated by graminoid-herb tundra with willows (Salix) and minor dwarf birch (Betula nana) and Ericales. During the late Wisconsin glacial interval (26,000-15,000 14C yr B.P.) vegetation was graminoid-herb tundra with willows, but with fewer dwarf birch and Ericales, and more herb types associated with dry habitats and disturbed soils. Grasses (Poaceae) dominated during the peak of this glacial interval. Graminoid-herb tundra suggests that central Beringia had a cold, arid climate from ???30,000 to 15,000 14C yr B.P. Between 15,000 and 13,000 14C yr B.P., birch shrub-Ericales-sedge-moss tundra began to spread rapidly across the land bridge and Alaska. This major vegetation change suggests moister, warmer summer climates and deeper winter snows. A brief invasion of Populus (poplar, aspen) occurred ca. 11,000-9500 14C yr B.P., overlapping with the Younger Dryas interval of dry, cooler(?) climate. During the latest Wisconsin to middle Holocene the Bering land bridge was flooded by rising seas. Alder shrubs (Alnus crispa) colonized the St. Michael Island area ca. 8000 14C yr B.P. Boreal forests dominated by spruce (Picea) spread from interior Alaska into the eastern Norton Sound area in middle Holocene time, but have not spread as far west as St. Michael Island. ?? 2003 University of Washington. Published by Elsevier Inc. All rights reserved.

Quaternary Research↗

Late Paleozoic orogeny in Alaska's Farewell terrane

Evidence is presented for a previously unrecognized late Paleozoic orogeny in two parts of Alaska's Farewell terrane, an event that has not entered into published scenarios for the assembly of Alaska. The Farewell terrane was long regarded as a piece of the early Paleozoic passive margin of western Canada, but is now thought, instead, to have lain between the Siberian and Laurentian (North American) cratons during the early Paleozoic. Evidence for a late Paleozoic orogeny comes from two belts located 100-200 km apart. In the northern belt, metamorphic rocks dated at 284-285 Ma (three 40Ar/39Ar white-mica plateau ages) provide the main evidence for orogeny. The metamorphic rocks are interpreted as part of the hinterland of a late Paleozoic mountain belt, which we name the Browns Fork orogen. In the southern belt, thick accumulations of Pennsylvanian-Permian conglomerate and sandstone provide the main evidence for orogeny. These strata are interpreted as the eroded and deformed remnants of a late Paleozoic foreland basin, which we name the Dall Basin. We suggest that the Browns Fork orogen and Dall Basin comprise a matched pair formed during collision between the Farewell terrane and rocks to the west. The colliding object is largely buried beneath Late Cretaceous flysch to the west of the Farewell terrane, but may have included parts of the so-called Innoko terrane. The late Paleozoic convergent plate boundary represented by the Browns Fork orogen likely connected with other zones of plate convergence now located in Russia, elsewhere in Alaska, and in western Canada. Published by Elsevier B.V.

Tectonophysics↗

Vegetation and paleoclimate of the last interglacial period, central Alaska

The last interglacial period is thought to be the last time global climate was significantly warmer than present. New stratigraphic studies at Eva Creek, near Fairbanks, Alaska indicate a complex last interglacial record wherein periods of loess deposition alternated with periods of soil formation. The Eva Forest Bed appears to have formed about the time of or after deposition of the Old Crow tephra (dated to ??? 160 to ??? 120 ka), and is therefore correlated with the last interglacial period. Pollen, macrofossils, and soils from the Eva Forest Bed indicate that boreal forest was the dominant vegetation and precipitation may have been greater than present around Fairbanks during the peak of the last interglacial period. A new compilation of last interglacial localities indicates that boreal forest was extensive over interior Alaska and Yukon Territory. Boreal forest also extended beyond its present range onto the Seward and Baldwin Peninsulas, and probably migrated to higher elevations, now occupied by tundra, in the interior. Comparison of last interglacial pollen and macrofossil data with atmospheric general circulation model results shows both agreement and disagreement. Model results of warmer-than-present summers are in agreement with fossil data. However, numerous localities with boreal forest records are in conflict with model reconstructions of an extensive cool steppe in interior Alaska and much of Yukon Territory during the last interglacial. ?? 2000 Elsevier Science Ltd.

Quaternary Science Reviews↗

Origin of last-glacial loess in the western Yukon-Tanana Upland, central Alaska, USA

Loess is widespread over Alaska, and its accumulation has traditionally been associated with glacial periods. Surprisingly, loess deposits securely dated to the last glacial period are rare in Alaska, and paleowind reconstructions for this time period are limited to inferences from dune orientations. We report a rare occurrence of loess deposits dating to the last glacial period, ~19 ka to ~12 ka, in the Yukon-Tanana Upland. Loess in this area is very coarse grained (abundant coarse silt), with decreases in particle size moving south of the Yukon River, implying that the drainage basin of this river was the main source. Geochemical data show, however, that the Tanana River valley to the south is also a likely distal source. The occurrence of last-glacial loess with sources to both the south and north is explained by both regional, synoptic-scale winds from the northeast and opposing katabatic winds that could have developed from expanded glaciers in both the Brooks Range to the north and the Alaska Range to the south. Based on a comparison with recent climate modeling for the last glacial period, seasonality of dust transport may also have played a role in bringing about contributions from both northern and southern sources.

Alaska↗

A new set of basaltic tephras from southeastern Alaska represent key stratigraphic markers for the late Pleistocene

An 8-cm-thick black basaltic tephra with nine discrete normally graded beds is present in cores from a lake on Baker Island in southeastern Alaska. The estimated age of the tephra is 13,492 ± 237 cal yr BP. Although similar in age to the MEd tephra from the adjacent Mt. Edgecumbe Volcanic Field, this tephra is geochemically distinct. Black basaltic tephras recovered from two additional sites in southeastern Alaska, Heceta Island and the Gulf of Esquibel, are also geochemically distinct from the MEd tephra. The age of the tephra from Heceta Island is 14,609 ± 343 cal yr BP. Whereas the tephras recovered from Baker Island/Heceta Island/Gulf of Esquibel are geochemically distinct from each other, similarities in the ages of these tephras and the MEd tephra suggest a shared eruptive trigger, possibly crustal unloading caused by retreat of the Cordilleran Ice Sheet. The submerged Addington Volcanic Field on the continental shelf, which may have been subaerially exposed during the late Pleistocene, is a possible source for the southeastern Alaska tephras

Alaska↗

Scientific results of the Hydrate-01 Stratigraphic Test Well Program, Western Prudhoe Bay Unit, Alaska North Slope

The United States Department of Energy, the MH21-S Research Consortium of Japan, and the United States Geological Survey are collaborating to enable gas hydrate scientific drilling and extended-duration reservoir response testing on the Alaska North Slope. To feasibly execute such a test, a location is required that is accessible from existing roads and gravel pads and that can be occupied without disrupting ongoing industry operations. A review of potential locations meeting these criteria determined the likely occurrence of gas hydrate in two fine-grained marginal-marine sands of Tertiary age in the vicinity of the inactive “Kuparuk State 7-11-12” exploration pad in the western Prudhoe Bay Unit (PBU). Existing well and seismic data for that site were insufficient to preclude the potential for free gas occurrence within the deeper (and most prospective) target sand. Therefore, with support from the PBU Working Interest Owners, Alaska Department of Natural Resources, and Petrotechnical Resources Alaska, the Hydrate-01 Stratigraphic Test Well (STW) was drilled in December 2018 to confirm the suitability of the site for future gas hydrate scientific testing. The Hydrate-01 well was successfully drilled to −3290 ft (1003 m) subsea vertical depth at a bottom hole location of approximately 900 ft (∼275 m) east of the surface location. The drilling program featured acquisition of a full suite of logging while drilling data, the collection of side-wall pressure cores, and the installation of distributed temperature and distributed acoustic sensor fiber-optic cables. The log data acquired confirmed the occurrence of gas hydrate at high saturation in two target sands. Integrated evaluation of log and sidewall core data provide petrophysical and geomechanical property information that allow for potential reservoir response to depressurization to be simulated. The deeper “B1 sand” is deemed to be most favorable for reservoir response testing as a result of confirmed gas hydrate occurrence in sediments of high intrinsic permeability, location within 100 ft (30 m) of the base of gas hydrate stability, and minimal risk for direct communication with permeable water-bearing (hydrate-free) zones. The shallower “D1 sand” provides a secondary target that is differentiated by colder in situ temperatures and the interpreted direct hydraulic communication to a lower section of non-hydrate-bearing, water-saturated sand. The Hydrate-01 log data also confirm the occurrence of at least one sub-seismic fault in close proximity to the B1 sand reservoir. To better image the distribution of the gas-hydrate-bearing reservoir sections and associated faults, a three-dimensional (3D) vertical seismic profile was conducted in early 2019 using the distributed acoustic sensors installed as part of the Hydrate-01 STW completion. Detailed two-dimensional (2D) and 3D geologic models have been constructed to enable numerical simulations to inform the planning for potential future scientific tests of reservoir response to depressurization at the site.

Alaska↗

Volcanic ash plume identification using polarization lidar: Augustine eruption, Alaska

During mid January to early February 2006, a series of explosive eruptions occurred at the Augustine volcanic island off the southern coast of Alaska. By early February a plume of volcanic ash was transported northward into the interior of Alaska. Satellite imagery and Puff volcanic ash transport model predictions confirm that the aerosol plume passed over a polarization lidar (0.694 mm wavelength) site at the Arctic Facility for Atmospheric Remote Sensing at the University of Alaska Fairbanks. For the first time, lidar linear depolarization ratios of 0.10 &ndash; 0.15 were measured in a fresh tropospheric volcanic plume, demonstrating that the nonspherical glass and mineral particles typical of volcanic eruptions generate strong laser depolarization. Thus, polarization lidars can identify the volcanic ash plumes that pose a threat to jet air traffic from the ground, aircraft, or potentially from Earth orbit.

Alaska↗