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At least 649 records · Page 36Linked to original sources

Use of ground-water reservoirs for storage of surface water in the San Joaquin Valley, California

The San Joaquin Valley includes roughly the southern two-thirds of the Central Valley of California, extending 250 miles from Stockton on the north to Grapevine at the foot of the Tehachapi Mountains. The valley floor ranges in width from 25 miles near Bakersfield to about 55 miles near Visalia; it has a surface area of about 10,000 square miles. More than one-quarter of all the ground water pumped for irrigation in the United States is used in this highly productive valley. Withdrawal of ground water from storage by heavy pumping not only provides a needed irrigation water supply, but it also lowers the ground-water level and makes storage space available in which to conserve excess water during periods of heavy runoff. A storage capacity estimated to be 93 million acre-feet to a depth of 200 feet is available in this ground-water reservoir. This is about nine times the combined capacity of the existing and proposed surface-water reservoirs in the San Joaquin Valley under the California Water Plan. The landforms of the San Joaquin Valley include dissected uplands, low plains and fans, river flood plains and channels, and overflow lands and lake bottoms. Below the land surface, unconsolidated sediments derived from the surrounding mountain highlands extend downward for hundreds of feet. These unconsolidated deposits, consisting chiefly of alluvial deposits, but including some widespread lacustrine sediments, are the principal source of ground water in the valley. Ground water occurs under confined and unconfined conditions in the San Joaquin Valley. In much of the western, central, and southeastern parts of the valley, three distinct ground-water reservoirs are present. In downward succession these are 1) a body of unconfined and semiconfined fresh water in alluvial deposits of Recent, Pleistocene, and possibly later Pliocene age, overlying the Corcoran clay member of the Tulare formation; 2) a body of fresh water confined beneath the Corcoran clay member, which occurs in alluvial and lacustrine deposits of late Pliocene age or older; and 3) a body of saline connate water contained in marine sediments of middle Pliocene or older age, which underlies the fresh-water body throughout the area. In much of the eastern part of the valley, especially in the areas of the major streams, the Corcoran clay member is not present and ground water occurs as one fresh-water body to considerable depth. The ground-water body is replenished by infiltration of rainfall, by infiltration from streams, canals, and ditches, by underflow entering the valley from tributary stream canyons, and by infiltration of excess irrigation water. In much of the valley, however, the annual rainfall is so low that little penetrates deeply, and soil-moisture deficiency is perennial. Infiltration from stream channels and canals and from irrigated fields are the principal sources of groundwater recharge. The ground-water storage capacity of the San Joaquin Valley has been estimated in an earlier report (Davis and others, 1959) as 93 million acre-feet. This is the quantity of water that would drain by gravity from the valley deposits if the regional water level were lowered from 10 to 200 feet below the land surface. Storage capacity was estimated for only the part of the valley considered to be potentially usable as a ground-water reservoir. In this study, a 200foot depth was selected as a practical valley-wide depth limit for unwatering under full utilization of the ground-water reservoir, even though in localized areas sections in excess of 350 feet in depth have already been dewatered. Some of the factors that locally limit the utilization of the ground-water reservoir are inferior water quality, relatively impermeable surface soils, and relatively impermeable subsurface deposits. On the basis of a detailed analysis of la peg model, the subsurface geology of the San Joaquin Valley was subdivided into predominantly permeable and impermeable zones in the 1

Water Supply Paper↗

Computer software for converting ground-water and water-quality data from the National Water Information System for use in a geographic information system

A geographic information system (GIS) is computer software that provides the capabilities to rapidly display and analyze spatially referenced data. To use a GIS efficiently, software is needed that provides a link between existing spatially referenced data-base systems and the GIS. The U.S. Geological Survey (USGS) stores large amounts of spatially referenced hydrologic data in computerized data-base systems. Currently, these data-base systems are physically located on computers that are installed in many USGS offices nationwide. This report describes software that can be used quickly and easily to convert site-description and water-quality data from these data-base systems to the GIS that is used by the USGS. The software described in this report is designed to be used with the same hardware and software that is available to most USGS personnel.

Water-Resources Investigations Report↗

Qualilty, isotopes, and radiochemistry of water sampled from the Upper Moenkopi Village water-supply wells, Coconino County, Arizona

The Hopi Tribe Water Resources Program has granted contracts for studies to evaluate water supply conditions for the Moenkopi villages in Coconino County, Arizona. The Moenkopi villages include Upper Moenkopi Village and the village of Lower Moencopi, both on the Hopi Indian Reservation south of the Navajo community of Tuba City. These investigations have determined that water supplies are limited and vulnerable to several potential sources of contamination, including the Tuba City Landfill and a former uranium processing facility known as the Rare Metals Mill. Studies are ongoing to determine if uranium and other metals in groundwater beneath the landfill are greater than regional groundwater concentrations. The source of water supply for the Upper Moenkopi Village is three public-supply wells. The wells are referred to as MSW-1, MSW-2, and MSW-3 and all three wells obtain water from the regionally extensive N aquifer. The N aquifer is the principal aquifer in this region of northern Arizona and consists of thick beds of sandstone between less permeable layers of siltstone and mudstone. The relatively fine-grained character of the N aquifer inhibits rapid movement of water and large yields to wells. In recent years, water levels have declined in the three public-supply wells, causing concern that the current water supply will not be able to accommodate peak demand and allow for residential and economic growth. Analyses of major ions, nutrients, selected trace metals, stable and radioactive isotopes, and radiochemistry were performed on the groundwater samples from the three public-supply wells to describe general water-quality conditions and groundwater ages in and immediately surrounding the Upper Moenkopi Village area. None of the water samples collected from the public-supply wells exceeded the U.S. Environmental Protection Agency primary drinking water standards. The ratios of the major dissolved ions from the samples collected from MSW-1 and MSW-2 indicate water with a major ion composition of calcium and sulfate. There is no significant vertical distribution of ion concentrations in the samples collected from the upper and lower portion of the water column within the two wells. The samples collected at MSW-3 are higher in sodium and lower in calcium than the samples collected from MSW-1 and MSW-2, and contain a similar sulfate-ion percentage. There is a vertical distribution of ion concentrations in the samples collected from the upper and lower portion of the water column in MSW-3. Groundwater samples from the three water-supply wells analyzed for oxygen-18 and deuterium stable isotopes plot on a local water line that is approximately parallel to the global meteoric water line. Tritium concentrations in samples from MSW-1 and MSW-3 were equal to or less than laboratory detection limits and were interpreted to contain no modern (post-1952) water. Tritium concentration in a sample from the top of the water column at MSW-2 was 0.41 tritium units, indicating that the composition is primarily pre-bomb (pre-1952) water, but may contain a small fraction of post-bomb modern water. The calculated carbon-14 ages of groundwater in MSW-1 and MSW-2, both completed about 140 feet into the Navajo Sandstone, are about 3,000 years before present. The calculated carbon-14 age of groundwater in MSW-3, completed about 240 feet into the Kayenta Formation-Navajo Sandstone transition zone is about 5,000 years before present in the upper portion of the water column and about 8,500 years before present in the lower portion of the water column. The gross alpha radioactivity of samples collected from the three water-supply wells ranged from 5.1 to 9.8 picocuries per liter-less than the U.S. Environmental Protection Agency primary drinking water standard of 15 picocuries per liter. The gross beta radioactivity of samples collected from the wells ranged from 0.9 to 2.8 picocuries per liter and are not considered elevated relative to the U.S. Environmental Protection Agency primary drinking water standard.

Arizona↗

Simulation of ground-water flow and the movement of saline water in the Hueco Bolson aquifer, El Paso, Texas, and adjacent areas

The Hueco bolson aquifer is being pumped at increasing rates to supply water for El Paso, Texas, and Ciudad Juarez, Mexico. Water-use projections for 1984-2000 indicate that the upward trend in pumping rates probably will continue, which will put an increasing burden on the limited freshwater resources of the aquifer. Near El Paso, saline water in the Rio Grande alluvium overlies freshwater in bolson deposits. Withdrawal of ground water has created a large cone of depression in the water table that is centered approximately under the El Paso-Ciudad Juarez urban area. The maximum depth of this cone in January 1984 was about 140 feet below the pre-development (before 1903) water table. The principal concern of the water-management agencies involved with the water supply for El Paso and Ciudad Juarez, and of the U.S. Department of Defense at Fort Bliss to the north of these cities is that the saline water underlying and surrounding the freshwater in the bolson deposits will begin to move into the intensively pumped freshwater zone. Intrusion of large volumes of saline water would contaminate the freshwater and make it unusable for municipal and industrial supply. Changes in ground-water quality, indicated by an increase in dissolved-solids concentrations in well water, have occurred near the El Paso airport and near the Rio Grande. This study focused primarily on simulation of historical and present (1984) ground-water flow and salinity of water in the Hueco bolson aquifer, to help understand and project the movement of saline water in the aquifer to January 2000. The objective of this study was to understand the movement of water resulting from historical and projected pumping, using numerical simulation of the transport of saline water. Results of the numerical simulations indicate that historical withdrawals of ground water have caused only slight movement of saline water, except near the Rio Grande. The saline water probably has moved laterally from the river alluvium into the bolson deposits and towards the wells located north and south of the river. Some downward movement of saline water has occurred; this movement was caused by withdrawals from wells screened only in the freshwater zone beneath the river alluvium. Simulation results further indicate that upconing of saline water into well screens probably is not, and will not become, a substantial problem. This conclusion is based on the assumption that the aquifer is anisotropic, specifically that horizontal intrinsic permeability is much greater than the vertical permeability. Results of the projected withdrawal simulations from 1984-2000 indicate that the general historical trend of saline-water movement probably will continue. The saline water in the Rio Grande alluvium is the major source of saline-water intrusion into the freshwater zone throughout the historical period and into the future on the basis of simulation results. Some saline water probably will continue to move downward from the Rio Grande alluvium to the freshwater below. Injection of treated sewage effluent into some wells will create a small zone of freshwater containing slightly increased amounts of dissolved solids in the northern area of the Texas part of the Hueco bolson aquifer. Many factors, such as well interference, pumping schedules, and other factors not specifically represented in the regional simulation, can substantially affect dissolved-solids concentrations at individual wells.

Chihuahua, Texas↗

Statistical summaries of ground-water level data collected in the Suwannee River Water Management District, 1948 to 1994

Since 1948, ground-water level data have beensystematically collected from selected wells in theSuwannee River Water Management District (SRWMD) by the U.S. Geological Survey (USGS),the SRWMD, and other agencies. Records of waterlevels in the SRWMD (fig. 1), collected by the USGS and SRWMD through 1990, and by the SRWMD from 1990 to 1994, have been published for many years in the USGS annual report series "Water Resources Data for Florida." However, no systematic statistical summaries of water levels in the SRWMD have been previously published. The need for such statistical summary data forevaluations of drought severity, ground-water supplyavailability, and minimum water levels for regulatory purposes increases daily as demands for ground-water usage increase. Also, much of the base flow of the Suwannee River is dependent upon ground water. As the population and demand for ground water for drinking water and irrigation purposes increase, the ability to quickly and easily predict trends in ground-water availability will become paramount. In response to this need, the USGS, in cooperation with the SRWMD, compiled this report. Ground-water sta tistics for 136 sites are presented as well as figures showing water levels that were measured in wells from 1948 through September 1994. In 1994, the SRWMD and the USGS began a long- term program of cooperative studies designed tobetter understand minimum and maximum streamflows and ground-water levels in the SRWMD. Minimum and maximum flows and levels are needed by the district to manage the surface- and ground-water resources of the SRWMD and to maintain or improve the various ecosystems. Data evaluation was a necessary first step in the long- term SRWMD ground-water investigations program, because basic statistics for ground-water levels are not included in the USGS annual data reports such as "Water Resources Data for Florida, Water Year 1994" (Fran klin and others, 1995). Statistics included in this report were generated using the USGS computer pro gram ADAPS (Automatic Data Processing System) to characterize normal ground-water levels and depar tures from normal. The report has been organized so that the statisti cal analyses of water levels in the wells are presentedfollowing this introductory material, a description ofthe hydrogeology in the study area, and a description of the statistics used to present the water-level data. Specifically, the report presents statistical analyses for each well, as appropriate, in the following manner: Description of the well.Hydrographs of ground-water levels for the period of record, for the last 10 years of record, and for the last 5 years of record. Graphs of maximum, minimum, and mean of monthly mean ground-water levels for wells with 5 or more years of record.Frequency hydrographs (25, 50, and 75 percent) of monthly mean ground-water levels for wells with 5 or more years of record. Water-level data and statistical plots are grouped by county and sorted within the county by ascendingsite identification number. Well locations are plottedon county maps preceding the well descriptions andhydrographs.

Open-File Report↗

Estimates of natural ground-water discharge and characterization of water quality in Dry Valley, Washoe County, West-Central Nevada, 2002-2003

The Dry Valley Hydrographic Area is being considered as a potential source area for additional water supplies for the Reno-Sparks area, which is about 25 miles south of Dry Valley. Current estimates of annual ground-water recharge to Dry Valley have a considerable range. In undeveloped valleys, such as Dry Valley, long-term ground-water discharge can be assumed the same as long-term ground-water recharge. Because estimating ground-water discharge has more certainty than estimating ground-water recharge from precipitation, the U.S. Geological Survey, in cooperation with Washoe County, began a three-year study to re-evaluate the ground-water resources by estimating natural ground-water discharge and characterize ground-water quality in Dry Valley. In Dry Valley, natural ground-water discharge occurs as subsurface outflow and by ground-water evapotranspiration. The amount of subsurface outflow from the upper part of Dry Valley to Winnemucca and Honey Lake Valleys likely is small. Subsurface outflow from Dry Valley westward to Long Valley, California was estimated using Darcy's Law. Analysis of two aquifer tests show the transmissivity of poorly sorted sediments near the western side of Dry Valley is 1,200 to 1,500 square feet per day. The width of unconsolidated sediments is about 4,000 feet between exposures of tuffaceous deposits along the State line, and decreases to about 1,500 feet (0.5 mile) west of the State line. The hydraulic gradient east and west of the State line ranges from 0.003 to 0.005 foot per foot. Using these values, subsurface outflow to Long Valley is estimated to be 50 to 250 acre-feet per year. Areas of ground-water evapotranspiration were field mapped and partitioned into zones of plant cover using relations derived from Landsat imagery acquired July 8, 2002. Evapotranspiration rates for each plant-cover zone were multiplied by the corresponding area and summed to estimate annual ground-water evapotranspiration. About 640 to 790 acre-feet per year of ground water is lost to evapotranspiration in Dry Valley. Combining subsurface-outflow estimates with ground-water evapotranspiration estimates, total natural ground-water discharge from Dry Valley ranges from a minimum of about 700 acre-feet to a maximum of about 1,000 acre-feet annually. Water quality in Dry Valley generally is good and primary drinking-water standards were not exceeded in any samples collected. The secondary standard for manganese was exceeded in three ground-water samples. One spring sample and two surface-water samples exceeded the secondary standard for pH. Dry Valley has two primary types of water chemistry that are distinguishable by cation ratios and related to the two volcanic-rock units that make up much of the surrounding mountains. In addition, two secondary types of water chemistry appear to have evolved by evaporation of the primary water types. Ground water near the State line appears to be an equal mixture of the two primary water chemistries and has as an isotopic characteristic similar to evaporated surface water.

Scientific Investigations Report↗

Surface- and ground-water relations on the Portneuf river, and temporal changes in ground-water levels in the Portneuf Valley, Caribou and Bannock Counties, Idaho, 2001-02

The State of Idaho and local water users are concerned that streamflow depletion in the Portneuf River in Caribou and Bannock Counties is linked to ground-water withdrawals for irrigated agriculture. A year-long field study during 2001 02 that focused on monitoring surface- and ground-water relations was conducted, in cooperation with the Idaho Department of Water Resources, to address some of the water-user concerns. The study area comprised a 10.2-mile reach of the Portneuf River downstream from the Chesterfield Reservoir in the broad Portneuf Valley (Portneuf River Valley reach) and a 20-mile reach of the Portneuf River in a narrow valley downstream from the Portneuf Valley (Pebble-Topaz reach). During the field study, the surface- and ground-water relations were dynamic. A losing river reach was delineated in the middle of the Portneuf River Valley reach, centered approximately 7.2 miles downstream from Chesterfield Reservoir. Two seepage studies conducted in the Portneuf Valley during regulated high flows showed that the length of the losing river reach increased from 2.6 to nearly 6 miles as the irrigation season progressed.Surface- and ground-water relations in the Portneuf Valley also were characterized from an analysis of specific conductance and temperature measurements. In a gaining reach, stratification of specific conductance and temperature across the channel of the Portneuf River was an indicator of ground water seeping into the river.An evolving method of using heat as a tracer to monitor surface- and ground-water relations was successfully conducted with thermistor arrays at four locations. Heat tracing monitored a gaining reach, where ground water was seeping into the river, and monitored a losing reach, where surface water was seeping down through the riverbed (also referred to as a conveyance loss), at two locations.Conveyance losses in the Portneuf River Valley reach were greatest, about 20 cubic feet per second, during the mid-summer regulated high flows. Conveyance losses in the Pebble-Topaz reach were greatest, about 283 cubic feet per second, during the spring regulated high flows and were attributed to a hydroelectric project.Comparison of water levels in 30 wells in the Portneuf Valley during September and October 1968 and 2001 indicated long-term declines since 1968; the median decline was 3.4 feet. September and October were selected for characterizing long-term ground-water-level fluctuations because declines associated with irrigation reach a maximum at the end of the irrigation season. The average annual snowpack in the study area has declined significantly; 1945 85 average annual snowpack was 16.1 inches, whereas 1986 through 2002 average annual snowpack was 11.6 inches. Water-level declines during 1998  2002 may be partially attributable to the extended dry climatic conditions. It is unclear whether the declines could be partially attributed to increases in ground-water withdrawals. Between 1968 and 1980, water rights for ground-water withdrawals nearly doubled from 23,500 to 46,000 acre-feet per year. During this period, ground-water levels were relatively constant and did not exhibit a declining trend that could be related to increased ground-water withdrawal rights. However, ground-water withdrawals are not measured in the valley; thus, the amount of water pumped is not known. Since the 1990s, there have been several years when the Chesterfield Reservoir has not completely refilled, and the water in storage behind the reservoir has been depleted by the middle of the irrigation season. In this situation, surface-water diversions for irrigation were terminated before the end of the irrigation season, and irrigators, who were relying in part on diversions from the Portneuf River, had to rely solely on ground water as an alternate supply. Smaller volumes of water in the Chesterfield Reservoir since the 1990s indicate a growing demand for ground-water supplies.

Scientific Investigations Report↗

Modeling hydrodynamics, water temperature, and water quality in Klamath Straits Drain, Oregon and California, 2012–15

Executive Summary Located southwest of Klamath Falls, Oregon, Klamath Straits Drain is a 10.1-mile-long canal that conveys water uphill and northward through the use of pumps before discharging to the Klamath River. Klamath Straits Drain traverses an area that historically encompassed Lower Klamath Lake. Currently, the Drain receives water from farmland and from parts of the Lower Klamath Lake National Wildlife Refuge. To support water-quality improvement in Klamath Straits Drain, a hydrodynamic and water-temperature model was constructed and calibrated for calendar years 2012–15 with the two-dimensional model CE-QUAL-W2 (version 4.0). Water quality was calibrated for a subset of that time, from April 1, 2012 to March 31, 2015. Flows in calendar year 2012 were within the normal range, while calendar years 2013–15 were dry years. Significant findings from this study include: In the years studied, only limited flow entered Klamath Straits Drain at the upstream Headworks (KSDH) site. Most flow entered the Drain between KSDH and the E-EE pumps near Township Road through several irrigation channels and ditches. Few data were available to describe the quality of this water for the period of study. The E-EE and F-FF pumps along Klamath Straits Drain mainly operated automatically to keep water levels relatively steady. Ten-minute flow data at streamgage 11509340, downstream of the F-FF pumps, showed high-frequency on/off switching of the F-FF pumps. Combined with daily mean flow data from the F-FF pumps, the downstream 10-minute flow data allowed estimation of 10-minute pumping rates for the F-FF pumps. Paper pump charts showed the existence of short-term variability at the E-EE pumps; however, daily pump data were used at the E-EE pump location in the model. Water temperature in Klamath Straits Drain varied from less than 5 degrees Celsius (°C) (with occasional ice cover in December–January) to greater than 20 °C in May–September. In the years studied, specific conductance was typically 250–850 microsiemens per centimeter, higher than Klamath River specific conductance (typically 100–200 microsiemens per centimeter). Increased chlorophyll a in autumn and winter, along with supersaturated oxygen concentrations, indicated algal blooms in the Drain at that time of year. The blooms were most likely diatoms, based on the timing of blooms sampled elsewhere. Total nitrogen concentration was as much as 5.5 mg/L, with most in dissolved organic and particulate forms, and lower amounts in ammonia and nitrate+nitrite. Total phosphorus concentrations were distributed between orthophophorus (at a median concentration of 0.15 mg/L) and organic and particulate forms (at a median concentration of 0.13 mg/L). Most of the organic carbon in the Klamath Straits Drain was in dissolved rather than particulate form. Newly collected water-quality data for April 1, 2012–March 31, 2015 helped provide the impetus for this modeling study. However, a lack of some data still hindered the construction and calibration of this model. The model would benefit from additional data to describe water-quality boundary conditions, water-quality calibration data upstream of the F-FF pumps, short-term E-EE pump operations, and channel bathymetry in the reach between Highway 97 and the confluence with the Klamath River. Klamath River water mixed upstream into the Klamath Straits Drain, up to the Klamath Straits Drain F-FF pumps at Highway 97, when the F-FF pumps were not operating for periods of hours to days. The F-FF pumps were off for many days during this study, especially during dry years. The boundary between Klamath Straits Drain and the Klamath River was best modeled with an external head condition, which allows exchange of water between the river and the drain in both directions, upstream and downstream. Currently there is a flow gage, water-quality monitor, and a water-quality sampling site located downstream of the F-FF pumps, in the reach where Klamath Straits Drain water can mix with Klamath River water. To sample solely Klamath Straits Drain water, water samples would need to be collected only when the F-FF pumps are actively pumping. Alternately, the sampling location could be moved upstream of the pumps. Interpretation and use of historical water-quality data at the Klamath Straits Drain at Highway 97 site should be done in conjunction with information on pump activity to help inform whether mixing with Klamath River water may have occurred. Total 2014 (a dry year) phosphorus loads from the Drain to the Klamath River were lower and closer to total maximum daily load (TMDL) allocations, as compared to 2013, a year with greater flow and pumping. Modeled travel time through the Klamath Straits Drain, from Headworks to its confluence with the Klamath River, ranged from approximately 24 hours at high flow to 16 days or more, depending on how many days the pumps were turned off. The longer travel times are sufficient for important water-quality transformations, such as algal growth and organic-matter decomposition. This newly constructed model of the Klamath Straits Drain simulates flow, water levels, water temperature, and water quality with acceptable accuracy but with certain data limitations. This model should prove useful in evaluating potential strategies for flow and water-quality management and restoration.

California, Oregon↗

Ground-water quality and its relation to hydrogeology, land use, and surface-water quality in the Red Clay Creek basin, Piedmont Physiographic Province, Pennsylvania and Delaware

The Red Clay Creek Basin in the Piedmont Physiographic Province of Pennsylvania and Delaware is a 54-square-mile area underlain by a structurally complex assemblage of fractured metamorphosed sedimentary and igneous rocks that form a water-table aquifer. Ground-water-flow systems generally are local, and ground water discharges to streams. Both ground water and surface water in the basin are used for drinking-water supply. Ground-water quality and the relation between ground-water quality and hydrogeologic and land-use factors were assessed in 1993 in bedrock aquifers of the basin. A total of 82 wells were sampled from July to November 1993 using a stratified random sampling scheme that included 8 hydrogeologic and 4 land-use categories to distribute the samples evenly over the area of the basin. The eight hydrogeologic units were determined by formation or lithology. The land-use categories were (1) forested, open, and undeveloped; (2) agricultural; (3) residential; and (4) industrial and commercial. Well-water samples were analyzed for major and minor ions, nutrients, volatile organic compounds (VOC's), pesticides, polychlorinated biphenyl compounds (PCB's), and radon-222. Concentrations of some constituents exceeded maximum contaminant levels (MCL) or secondary maximum contaminant levels (SMCL) established by the U.S. Environmental Protection Agency for drinking water. Concentrations of nitrate were greater than the MCL of 10 mg/L (milligrams per liter) as nitrogen (N) in water from 11 (13 percent) of 82 wells sampled; the maximum concentration was 38 mg/L as N. Water from only 1 of 82 wells sampled contained VOC's or pesticides that exceeded a MCL; water from that well contained 3 mg/L chlordane and 1 mg/L of PCB's. Constituents or properties of well-water samples that exceeded SMCL's included iron, manganese, dissolved solids, pH, and corrosivity. Water from 70 (85 percent) of the 82 wells sampled contained radon-222 activities greater than the proposed MCL of 300 pCi/L (picoCuries per liter). Differences in selected major and minor ion concentrations and radon-222 activities were statistically significant between some lithologies and are related to differences in mineralogy. Ground water from felsic gneiss and schist generally contained higher radon-222 activities than the other lithologies; activities as high as 10,000 pCi/L were measured in a water sample from the felsic gneiss. Differences in the concentrations of nitrate, sodium, and chloride, and the frequency of pesticide detections in ground water were statistically significant between samples from wells in some land-use categories. Concentrations of nitrate generally were greatest in agricultural and in industrial and commercial areas and can be attributed to the use of fertilizers on the land surface and other agricultural activities. Much of the industrial and commercial land use is in areas previously used for or related to mushroom production. Concentrations of chloride and sodium also were greatest in water from wells in agricultural and industrial and commercial areas, probably because of the use of fertilizer and road salt. Concentrations of nitrate, chloride, and sodium in water samples from wells in forested and residential land use did not differ statistically significantly from each other. The herbicides metolachlor and atrazine were the most frequently detected pesticides and were detected more frequently in agricultural areas than in areas with other land uses; their presence is related to their use in crop production. VOC's were detected infrequently and only in residential and industrial and commercial areas. The relation between ground-water quality and surface-water quality is assessed by comparing nitrate and chloride concentrations in the 1993 ground-water samples and 1993-94 base-flow samples. Base-flow samples were collected at eight stream sites in the headwaters of the West Branch of Red Clay Creek in 1994 and at two long-term stream-monitoing sites on the East and West Branches of the Red Clay Creek in 1993-94. The average concentrations of chloride and nitrate in ground-water samples from wells in areas above the headwater stream sites and two long-term stream-monitoring sites were similar to the concentrations of chloride and nitrate in base flow at those sites. An observed increase in nitrate concentration in base flow at the long-term monitoring site on the West Branch of Red Clay Creek from 1970 to 1995 may be related to an increase in nitrate concentrations in ground water in that area of the basin.

Water-Resources Investigations Report↗

Geology and ground-water resources of the lower Lodgepole Creek drainage basin, Nebraska, with a section on chemical quality of the water

The area described is almost wholly in Nebraska and is the drainage basin of Lodgepole Creek from the Wyoming State line to the Colorado State line, a distance along the stream valley of about 95 miles. It covers about 1,950 square miles. The purposes of the study were to ascertain the characteristics, thickness, and extent of the water-bearing formations and to obtain and interpret data on the origin, quality, quantity, movement, availability, and use of ground water in the area. The rocks exposed in the drainage basin are the Brule formation of Oligocene (Tertiary) age, the Ogallala formation of Pliocene (Tertiary) age, and alluvium of Pleistocene and Recent (Quaternary) age. The Brule formation is mainly a siltstone, which yields an average of 950 gallons per minute (gpm) to irrigation wells tapping its fractured zones or reworked material; the maximum reported discharge is 2,200 gpm. The Ogallala formation underlies most of the area. It consists of lenticular beds of clayey, silty, sandy, and gravelly materials and supplies water to all wells on the upland, including a few large-discharge wells, and to many irrigation and public-supply wells in the valley of Lodgepole Creek. The yield of irrigation wells tapping the Ogallala formation ranges from 90 to 1,600 gpm and averages about 860 gpm. The alluvium is present in the valleys of Lodgepole Creek and its tributaries and consists mainly of heterogeneous . mixtures of silt, sand, and gravel, and lenticular bodies of these materials. Between the Colorado State line and Chappell, Nebr., irrigation wells derive most of their water from the alluvium. However, between Chappell and Sidney most of the irrigation wells tap both the alluvium and permeable zones in the underlying Brule formation, and in much of the valley west of Sidney, where the water table is beneath the bottom of the alluvium, irrigation wells derive water from the underlying Brule or Ogallala formations. Irrigation wells obtaining water chiefly from the alluvium have a yield ranging from 130 to 1,200 gpm, averaging about 770 gpm. In the Lodgepole Creek valley below Sidney the depth to water generally is less than 20 feet and, in many places, less than 10. In much of this part of the area the water table extends to the land surface or to the root zone of the vegetation, and discharge by evapotranspiration is high. In the valley of Lodgepole Creek between Sidney and the Wyoming State line, the depth to water generally ranges from less than 10 feet near the stream to more than 100 along the edge of the valley. In the upland the depth to water ranges from about 80 to about 300 feet. Recharge to the ground-water reservoir is derived chiefly from precipitation; other sources are seepage from irrigation systems and streams, and subsurface inflow of ground water. Water that infiltrates to the water table generally moves toward Lodgepole Creek in a downstream direction and is discharged into the stream through springs and seeps. However, within an area of at least 400 square miles in the northern part of the lower Lodgepole Creek drainage basin, ground water moves toward the valley of the North Platte River. Water is discharged from the ground-water reservoir into streams, by evapotranspiration, through wells, and by subsurface outflow. During the 1951-52 water year about 13,000 acre-feet of ground water left the area as streamflow. An estimated 20,000 acre-feet of water annually is discharged by the transpiration of grasses and trees growing along the creek bottom, and about 1,000 acre-feet of water leaves as subsurface outflow. During the period 1950-51 about 68,000 acre-feet of water was pumped from wells in the area for all uses. Of this amount; about 35,000 acre-feet in 1950 and 23,300 acre-feet in 1951 were used to irrigate about 15,560 and 15,790 acres. Nearly one-fourth of this water percolated back to the ground-water reservoir. These acreages, however, included about 2,100 acres irrigated in p

Water Supply Paper↗

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper↗

Strategic directions for U.S. Geological Survey water science, 2012-2022 - Observing, understanding, predicting, and delivering water science to the Nation

Executive Summary This report expands the Water Science Strategy that was begun in the USGS Science Strategy, “Facing Tomorrow’s Challenges—U.S. Geological Survey Science in the Decade 2007–2017” (U.S. Geological Survey, 2007). The report looks at the relevant issues facing society and develops a strategy built around observing, understanding, predicting, and delivering water science for the next 5 to 10 years by building new capabilities, tools, and delivery systems to meet the Nation’s water-resource needs. This report begins by presenting the vision of water science for the USGS and the societal issues that are influenced by, and in turn influence, the water resources of our Nation. The essence of the Water Strategic Science Plan is built on the concept of “water availability,” defined as spatial and temporal distribution of water quantity and quality, as related to human and ecosystem needs, as affected by human and natural influences . The report also describes the core capabilities of the USGS in water science—the strengths, partnerships, and science integrity that the USGS has built over its 130-year history. Nine priority actions are presented in the report, which combine and elevate the numerous specific strategic actions listed throughout the report. Priority actions were developed as a means of providing the audience of this report with a list for focused attention, even if resources and time limit the ability of managers to address all of the strategic actions in the report. Priority actions focus on the following: Improve integrated science planning for water. Expand and enhance water-resource monitoring networks. Characterize the water cycle through development of state-of-the-art 3-D/4-D hydrogeologic framework models at multiple scales. Clarify the linkage between human water use (engineered hydrology) and the water cycle (natural hydrology). Advance ecological flow science. Provide flood-inundation science and information. Develop rapid deployment teams for water-related emergencies. Conduct integrated watershed assessment, research, and modeling. Deliver water data and analyses to the Nation. The body of the report is presented as a hierarchal set of 5 goals, 14 objectives, and 27 strategic actions that the USGS should undertake to advance water science through year 2022. The goals deal with: Providing society the information it needs regarding the amount and quality of water in all components of the water cycle at high temporal and spatial resolution, nationwide; Advancing our understanding of processes that determine water availability; Predicting changes in the quantity and quality of water resources in response to changing climate, population, land use, and management scenarios; Anticipating and responding to water-related emergencies and conflicts; and Delivering timely hydrologic data, analyses, and decision-support tools seamlessly across the Nation to support water-resource decisions. Scientific information produced on water resources would be without value if it were not communicated to society in a fashion that can inform decisions and actions. Therefore, the chapter following the goals describes how the USGS should inform, involve, and educate society about the science it produces. This includes discussions on local outreach and the use of social media for effective communication. This report concludes with a chapter devoted to the crosscutting science issues of the Water Mission Area with the other USGS Mission Areas: Climate and Land Use Change, Core Science Systems, Ecosystems, Energy and Minerals, Environmental Health Science, and Natural Hazards. Not one of these Mission Areas stands alone—all must work together and integrate their actions to fulfill the USGS science mission for the future. This final chapter identifies the important linkages that must be realized and maintained for this integration to occur.

Open-File Report↗

Water-level altitudes 2016 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973–2015 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Most of the land-surface subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction of the aquifer sediments, mostly in the fine-grained silt and clay layers. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured cumulative compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. The report contains regional-scale maps depicting approximate 2016 water-level altitudes (represented by measurements made during December 2015–March 2016) for the Chicot, Evangeline, and Jasper aquifers; maps depicting 1-year (2015–16) water-level changes for each aquifer; maps depicting approximate contoured 5-year (2011–16) water-level changes for each aquifer; maps depicting approximate contoured long-term (1990–2016 and 1977–2016) water-level changes for the Chicot and Evangeline aquifers; a map depicting approximate contoured long-term (2000–16) water-level changes for the Jasper aquifer; a map depicting locations of borehole-extensometer sites; and graphs depicting measured long-term cumulative compaction of subsurface sediments at the extensometers during 1973–2015. Tables listing the water-level data used to construct each water-level map for each aquifer and the measured long-term cumulative compaction data for each extensometer site are included. Graphs depicting water-level measurement data also are included; these graphs can be used to approximate changes in effective stress caused by changes in groundwater withdrawal from the Chicot and Evangeline aquifers. In 2016, water-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below the vertical datum (North American Vertical Datum of 1988; hereinafter, datum) in a localized area in northwestern Harris County to 200 ft above datum in west-central Montgomery County. Water-level changes during 2015–16 in the Chicot aquifer ranged from a 39-ft decline to a 26-ft rise. Contoured 5-year and long-term changes in water-level altitudes of the Chicot aquifer ranged from a 30-ft decline to a 20-ft rise (2011–16), from a 140-ft decline to a 160-ft rise (1990–2016), and from a 120-ft decline to a 200-ft rise (1977–2016). In 2016, water-level-altitude contours for the Evangeline aquifer ranged from 250 ft below datum in three separate areas in south-central Montgomery County and extending into north-central Harris County, in west-central Harris County, and in southwestern Harris County to 200 ft above datum in southeastern Grimes and northwestern Montgomery Counties. Water-level changes during 2015–16 in the Evangeline aquifer ranged from a 65-ft decline to a 61-ft rise. Contoured 5-year and long-term changes in water-level altitudes of the Evangeline aquifer ranged from a 60-ft decline to a 40-ft rise (2011–16), from a 160-ft decline to a 160-ft rise (1990–2016), and from a 320-ft decline to a 240-ft rise (1977–2016). In 2016, water-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum in south-central Montgomery County extending into north-central Harris County to 250 ft above datum in northwestern Montgomery County and extending into eastern Grimes County and southwestern Walker County. Water-level changes during 2015–16 in the Jasper aquifer ranged from a 38-ft decline to a 51-ft rise. Contoured 5-year and long-term changes in water-level altitudes of the Jasper aquifer ranged from a 60-ft decline to a 40-ft rise (2011–16) and from a 220-ft decline to a 20-ft decline (2000–16). Compaction of subsurface sediments (mostly in the fine-grained silt and clay layers) in the Chicot and Evangeline aquifers was recorded continuously by using 13 extensometers at 11 sites that were either activated or installed between 1973 and 1980. During the period of record beginning in 1973 (or later depending on activation or installation date) and ending in December 2015, measured cumulative compaction at the 13 extensometers ranged from 0.095 ft at the Texas City-Moses Lake extensometer to 3.666 ft at the Addicks extensometer. From January through December 2015, the Northeast, Southwest, Addicks, Johnson Space Center, and Clear Lake (deep) extensometers recorded net decreases in land-surface elevation, but the Lake Houston, East End, Texas City-Moses Lake, Baytown C–1 (shallow), Baytown C–2 (deep), Seabrook, Clear Lake (shallow), and Pasadena extensometers recorded net increases in land-surface elevation. For the 11 extensometer sites during the selected years 1988, 1998, 2008, 2012, and 2015, the smallest effective stress (20.12 pounds per square inch [psi]) was estimated at the Texas City-Moses Lake extensometer site and was produced by a measured water level of 46.42 ft below land-surface datum (blsd) in January 2008. The corresponding net compaction during 2007 at this site was 0.001 ft. The largest effective stress (174.86 psi) was estimated at the Addicks extensometer site and was produced by a measured water level of 403.38 ft blsd in January 1998. The corresponding net compaction at the Addicks site was 0.067 ft in 1997. The 2011 drought caused water-level declines in the aquifers that were documented by the water-level-measurement data collected in January 2012. During the 2011 drought, the 13 extensometers recorded varying amounts of compaction that ranged from a net compaction value of 0.002 ft recorded by the Texas City-Moses Lake extensometer to a net compaction value of 0.192 ft recorded by the Pasadena extensometer. Water-level data for 1988, 1998, 2008, 2012, and 2015 and the corresponding net compaction values recorded by the extensometers for 1987, 1997, 2007, 2011, and 2014 were used to illustrate the cause and effect relations between changes in water level caused by groundwater withdrawals and resulting changes in effective stress. Changes in effective stress are related to changes in land-surface elevations caused by compaction of the fine-grained sediments composing the Chicot and Evangeline aquifers. The rate of compaction varies from site to site because of differences in rates of groundwater withdrawal in the areas adjacent to each extensometer site; differences among sites in the ratios of sand, silt, and clay and their corresponding compressibilities; and previously established preconsolidation heads. It is not appropriate, therefore, to extrapolate or infer a rate of compaction for an adjacent area on the basis of the rate of compaction recorded by proximal extensometers.

Texas↗

Ground-water flow direction, water quality, recharge sources, and age, Great Sand Dunes National Monument, south-central Colorado

Great Sand Dunes National Monument is located in south-central Colorado along the eastern edge of the San Luis Valley. The Great Sand Dunes National Monument contains the tallest sand dunes in North America; some rise up to750 feet. Important ecological features of the Great Sand Dunes National Monument are palustrine wetlands associated with interdunal ponds and depressions along the western edge of the dune field. The existence and natural maintenance of the dune field and the interdunal ponds are dependent on maintaining ground-water levels at historic elevations. To address these concerns, the U.S. Geological Survey conducted a study, in collaboration with the National Park Service, of ground-water flow direction, water quality, recharge sources, and age at the Great Sand Dunes National Monument. A shallow unconfined aquifer and a deeper confined aquifer are the two principal aquifers at the Great Sand Dunes National Monument. Ground water in the unconfined aquifer is recharged from Medano and Sand Creeks near the Sangre de Cristo Mountain front, flows underneath the main dune field, and discharges to Big and Little Spring Creeks. The percentage of calcium in ground water in the unconfined aquifer decreases and the percentage of sodium increases because of ionic exchange with clay minerals as the ground water flows underneath the dune field. It takes more than 60 years for the ground water to flow from Medano and Sand Creeks to Big and Little Spring Creeks. During this time, ground water in the upper part of the unconfined aquifer is recharged by numerous precipitation events. Evaporation of precipitation during recharge prior to reaching the water table causes enrichment in deuterium (2H) and oxygen-18 (18O) relative to waters that are not evaporated. This recharge from precipitation events causes the apparent ages determined using chlorofluorocarbons and tritium to become younger, because relatively young precipitation water is mixing with older waters derived from Medano and Sand Creeks. Major ion chemistry of water from sites completed in the confined aquifer is different than water from sites completed in the unconfined aquifer, but insufficient data exist to quantify if the two aquifers are hydrologically disconnected. Radiocarbon dating of ground water in the confined aquifer indicates it is about 30,000 years old (plus or minus 3,000 years). The peak of the last major ice advance (Wisconsin) during the ice age occurred about 20,000 years before present; ground water from the confined aquifer is much older than that. Water quality and water levels of the interdunal ponds are not affected by waters from the confined aquifer. Instead, the interdunal ponds are affected directly by fluctuations in the water table of the unconfined aquifer. Any lowering of the water table of the unconfined aquifer would result in an immediate decrease in water levels of the interdunal ponds. The water quality of the interdunal ponds probably results from several factors, including the water quality of the unconfined aquifer, evaporation of the pond water, and biologic activity within the ponds.

Colorado↗

Ground-Water Flow, 2004-07, and Water Quality, 1992-2007, in McBaine Bottoms, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data, surface-water quality data, and water-level data in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report describes the ground-water flow and water quality of McBaine Bottoms and provides information to better understand the interaction between treated effluent from the wetlands used on the Eagle Bluffs Conservation Area and the water in the alluvial aquifer that is pumped from the city of Columbia municipal-supply well field. Changes in major chemical constituent concentrations have been detected at several sampling sites between pre- and post-effluent application data. Analysis of post-effluent data indicates substantial changes in calcium, potassium, sodium, chloride, and sulfate concentrations in ground water. These changes became apparent shortly after the beginning of the operation of the wastewater-treatment wetland in 1994 and the formation of the Eagle Bluffs Conservation Area, which uses the treated effluent as a water source for the management of migratory water fowl. The changes have continued throughout the 15 years of sample collection. The concentrations of these major chemical constituents are on the mixing continuum between pre-effluent ground water as one end member and the treated wastewater effluent as the other end member. For monitoring wells that had changes in major chemical constituent concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 6 to 88 percent. Twenty-two monitoring wells throughout McBaine Bottoms have been affected by effluent based on chloride concentrations larger than 40 milligrams per liter. The chloride concentration of ground water in the alluvial aquifer reflects several sources, including precipitation, water from the Missouri River, water in the aquifer, and the treated effluent. Chloride concentrations from precipitation, the Missouri River, and water in the alluvial aquifer were less than 40 milligrams per liter. These monitoring wells affected by effluent are located in two general areas - adjacent to treatment wetland unit 1 and near the ground-water high on and north of the Eagle Bluffs Conservation Area. The probable source of the large chloride concentrations in well samples adjacent to treatment wetland unit 1 is leakage from the unit. The source for the large chloride concentrations in the other monitoring well samples is the effluent mixed with ground water and Missouri River water that is used to fill pools on the Eagle Bluffs Conservation Area. One monitoring well had a single sample with a chloride concentration larger than 40 milligrams per liter. That sample may have been affected by the use of road salt because of the presence of ice and snow immediately before the sample was collected. Lateral ground-water flow was dominated by the presence of a persistent ground-water high beneath the Eagle Bluffs Conservation Area and the presence of a cone of depression centered around the city of Columbia well field in the northern part of the study area. Ground-water flow was radially away from the apex of the ground-water high; west and south of the high, flow was toward the Missouri River, east of the high, flow was toward Perche Creek, and north of the high, flow was to the north toward the cone of depression around the city of Columbia well field. Another permanent feature on the water-level maps was a ground-water high beneath treatment wetland unit 1. Although the ground-water high was present throughout the study period, the subsurface expression of the high changed depending on hydrolo

Scientific Investigations Report↗

Hexavalent and total chromium at low reporting concentrations in source-water aquifers and surface waters used for public supply in Illinois, 2013

On the basis of their recent review of the human health effects of hexavalent chromium [Cr(VI)] in public drinking water, the U.S. Environmental Protection Agency is considering the need for Federal regulation of Cr(VI). Presently, only total chromium is regulated, at a Maximum Contaminant Level (MCL) of 100 micrograms per liter (µg/L). The occurrence of Cr(VI) in groundwater and surface waters generally is attributed to industrial sources, but can be of natural origin. California’s recently established MCL for Cr(VI) of 10 µg/L illustrates the drinking-water concerns associated with Cr(VI). To improve understanding of the possible impact of a Cr(VI)-specific standard that approximates the California level on the management of Illinois’ public drinking water, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, assessed the occurrence and distribution of Cr(VI) in the State’s public-water supplies. During 2013, untreated water samples were collected to be analyzed for Cr(VI) and total chromium [Cr(T)] at 119 water-supply wells and 32 surface-water intakes; also, 32 treated surface-water samples were collected near the point of treatment and 32 near the furthest point of distribution. Public-supply sample sites were selected by a stratified random method. Samples typically were analyzed within 24 hours of collection at reporting limits of 0.02 µg/L for Cr(VI) and 0.1 µg/L for Cr(T). The occurrence of Cr(VI) was compared with selected geophysical, physical, and sampling factors that might more fully explain its distribution and magnitude of concentrations. The maximum concentration of Cr(VI) in groundwater was 2.1 µg/L. Maximum concentrations in untreated and treated surface water were 0.29 µg/L and 2.4 µg/L, respectively. All sample concentrations were below the California MCL; only 35 percent were below that State’s non-enforceable public health goal of 0.02 of µg/L. Cr(VI) was undetected in 43 percent of untreated groundwater samples, with a median of 0.06 µg/L when detected. All but two (94 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.09 µg/L, whereas in treated (tap and distributed) water the median was 0.20 µg/L. Surface waters treated with lime for softening typically had the greatest Cr(VI) concentrations (maximum, 2.4 µg/L; median, 1.2 µg/L). The maximum concentration of Cr(T) in groundwater was 1.8 µg/L. Maximum concentrations in untreated and treated surface water were 1.8 µg/L and 2.5 µg/L, respectively. All sample concentrations were below the Federal MCL. Total chromium was detected in 65 percent of untreated groundwater samples, with a median of 0.40 µg/L, when detected. All but one (97 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.40 µg/L, whereas in treated (tap and distributed) water the median was 0.30 µg/L. As with Cr(VI), surface waters treated with lime typically had the greatest Cr(T) concentrations. Examination of factors that might account for or be associated with the occurrence of Cr(VI) in public-supply source waters found few clearly evident factors. Associations in frequencies of occurrence and range of concentrations indicate that surface waters and groundwaters of shallow, unconsolidated, unconfined aquifers, particularly alluvial aquifers, are possibly most commonly affected by anthropogenic sources of Cr(VI). Groundwaters of deep (greater than 500 feet) bedrock aquifers, particularly the Cambrian-Ordovician aquifer system, are possibly most commonly affected by geologic sources of Cr(VI). Additional study, with supporting geologic and geochemical data that were not collected in this study, would be necessary to verify these associations. There was a weak positive relation (ρ = 0.23) between concentrations of Cr(VI) and Cr(T) in untreated water samples, with a much stronger positive relation (ρ = 0.86 and ρ = 0.90, respectively) in samples collected soon after treatment and near the endpoint of distribution. The stronger relation and greater similarity between Cr(VI) and Cr(T) concentrations in treated water samples indicate that Cr(VI) represents a greater proportion of the measured concentrations of Cr(T) in treated waters than in untreated waters. The analysis of spikes and other quality-assurance samples indicate uncertainties associated with obtaining or confirming consistently accurate analytical results for Cr(VI) at near the applied reporting limit of 0.02 µg/L.

Illinois↗

Statistical analysis and mapping of water levels in the Biscayne aquifer, water conservation areas, and Everglades National Park, Miami-Dade County, Florida, 2000–2009

Statistical analyses and maps representing mean, high, and low water-level conditions in the surface water and groundwater of Miami-Dade County were made by the U.S. Geological Survey, in cooperation with the Miami-Dade County Department of Regulatory and Economic Resources, to help inform decisions necessary for urban planning and development. Sixteen maps were created that show contours of (1) the mean of daily water levels at each site during October and May for the 2000–2009 water years; (2) the 25th, 50th, and 75th percentiles of the daily water levels at each site during October and May and for all months during 2000–2009; and (3) the differences between mean October and May water levels, as well as the differences in the percentiles of water levels for all months, between 1990–1999 and 2000–2009. The 80th, 90th, and 96th percentiles of the annual maximums of daily groundwater levels during 1974–2009 (a 35-year period) were computed to provide an indication of unusually high groundwater-level conditions. These maps and statistics provide a generalized understanding of the variations of water levels in the aquifer, rather than a survey of concurrent water levels. Water-level measurements from 473 sites in Miami-Dade County and surrounding counties were analyzed to generate statistical analyses. The monitored water levels included surface-water levels in canals and wetland areas and groundwater levels in the Biscayne aquifer. Maps were created by importing site coordinates, summary water-level statistics, and completeness of record statistics into a geographic information system, and by interpolating between water levels at monitoring sites in the canals and water levels along the coastline. Raster surfaces were created from these data by using the triangular irregular network interpolation method. The raster surfaces were contoured by using geographic information system software. These contours were imprecise in some areas because the software could not fully evaluate the hydrology given available information; therefore, contours were manually modified where necessary. The ability to evaluate differences in water levels between 1990–1999 and 2000–2009 is limited in some areas because most of the monitoring sites did not have 80 percent complete records for one or both of these periods. The quality of the analyses was limited by (1) deficiencies in spatial coverage; (2) the combination of pre- and post-construction water levels in areas where canals, levees, retention basins, detention basins, or water-control structures were installed or removed; (3) an inability to address the potential effects of the vertical hydraulic head gradient on water levels in wells of different depths; and (4) an inability to correct for the differences between daily water-level statistics. Contours are dashed in areas where the locations of contours have been approximated because of the uncertainty caused by these limitations. Although the ability of the maps to depict differences in water levels between 1990–1999 and 2000–2009 was limited by missing data, results indicate that near the coast water levels were generally higher in May during 2000–2009 than during 1990–1999; and that inland water levels were generally lower during 2000–2009 than during 1990–1999. Generally, the 25th, 50th, and 75th percentiles of water levels from all months were also higher near the coast and lower inland during 2000–2009 than during 1990–1999. Mean October water levels during 2000–2009 were generally higher than during 1990–1999 in much of western Miami-Dade County, but were lower in a large part of eastern Miami-Dade County.

Florida↗

Instream water use in the United States: water laws and methods for determining flow requirements

Water use generally is divided into two primary classes - offstream use and instream use. In offstream use, sometimes called out-of-stream or diversionary use, water is withdrawn (diverted) from a stream or aquifer and transported to the place of use. Examples are irrigated agriculture, municipal water supply, and industrial use. Each of these offstream uses, which decreases the volume of water available downstream from the point of diversion, is discussed in previous articles in this volume. Instream use, which generally does not diminish the flow downstream from its point of use, and its importance are described in this article. One of the earliest instream uses of water in the United States was to turn the water wheels that powered much of the Nation's industry in the 18th and 19th centuries. Although a small volume of water might have been diverted to a mill near streamside, that water usually was returned to the stream near the point of diversion and, thus, the flow was not diminished downstream from the mill. Over time, the generation of hydroelectric power replaced mill wheels as a means of converting water flow into energy. Since the 1920's, the generation of hydroelectric power increasingly has become a major instream use of water. By 1985, more than 3 billion acre-feet of water (3,050,000 million gallons per day) was used annually for hydropower generation (Solley and others, 1988, p. 45)-enough water to cover the State of Colorado to a depth of 51 feet. Navigation is another instream use with a long history. The Lewis and Clark expedition journals and many of Mark Twain's novels illustrate the extent to which the Nation originally depended on adequate streamfiows for basic transportation. Navigation in the 1980's is still considered to be an instream use; however, it often is based upon a stream system that has been modified greatly through channelization, diking, and construction of dams and locks. The present (1987) inland water navigation system in the conterminous United States consists of about 12,000 miles of maintained waterways, over which about 500 million tons of cargo is carried each year (U.S. Army Corps of Engineers, 1988, p. 16). Although not so widely practiced in recent years, streams have been used to dispose of raw waste products from homes, communities, and factories. This use has been discouraged by law and public policy because of public health concerns and the damage it causes to the environment. Beginning in the mid-1960's, other instream uses gained new prominence in the water-resources arena-the assertion of a legal right to a free-flowing stream for biological, recreational, and esthetic purposes. These uses themselves, however, are not new. Riverine habitat always has produced fish, and the beauty of flowing water always has evoked a strong sense of esthetic appreciation. What is new is the emerging legitimacy and awareness of these noneconomic uses under State and Federal laws and regulations. In the past, environmental uses of flowing water were ignored, for the most part, under a long-standing legal tradition that favored offstream uses and certain instream uses that had a strong economic basis. The history of instream-flow policy debate really concerns those recently recognized types of interim uses. Although the more transitional water uses have been protected by law, the recognition of other in stream uses has resulted in substantial changes in State water laws. Although methods for determining the volume of water needed for most traditional water uses are relatively straight-forward and well-established, methods for determining water requirements for the in stream uses have been developed only recently and are continuing to evolve. Water laws that have favored the more traditional water uses, the inherent nature of conflict between instream and offstream water uses, and the special kinds of technological and philosophical problems posed by the "newer" types of instream uses are described below. Water laws that have been passed to accommodate the more recently recognized instream uses are summarized.

Report↗