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Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Near-surface material and topography generate anomalous high-frequency ground motion amplification in Chugiak, Alaska

An ∼3 km long nodal array oriented approximately east–west was deployed in Chugiak, Alaska, by the U.S. Geological Survey during 2021. The array intersects with the permanent NetQuakes station NP.ARTY, where peak ground acceleration (PGA) value of 1.98 g was recorded during the 2018 M w 7.1 Anchorage, Alaska, earthquake, in sharp contrast to the PGA of ∼0.3 g at a site just 4 km to the west. Seismic data for M w 1.8–4.3 aftershocks from the M w 7.1 event recorded by the nodal array confirm the anomalously large ground motions obtained at NP.ARTY as well as similar amplifications at nodes within ∼1 km to the east. Here, we performed 0–10 Hz 3D finite‐difference simulations, including high‐resolution surface topography, to explore the cause of the unexpectedly large amplification. As expected, the simulations computed with a regional 3D tomography velocity model severely underpredict the 0–10 Hz acceleration records at almost all sites. Adding a near‐surface low‐velocity taper to 300 m depth amplifies the accelerations by up to a factor of 5 and enables a reasonable match between the nodal data and simulations at sites to the west of NP.ARTY. However, this model still underpredicts the spectral energy in the area covered by glacial sediments by up to an order of magnitude. The addition of a till layer using a depth‐dependent shear‐wave velocity ( ⁠⁠ V s ) profile along with a homogeneous, 8 m thick low‐velocity layer with V s = 250 m/s representing the kame terraces improves the fit to data to within a factor of 2 at nodes located on top of the glacial sediments. Our study shows that the anomalously large high‐frequency amplification recorded at and near NP.ARTY can be explained by a combination of topographic effects and near‐surface low‐velocity material with amplification effects on the high‐frequency ground motion by up to about 40% and an order of magnitude, respectively.

Alaska

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

Recent advances in characterizing the crustal stress field and future applications of stress data: Perspectives from North America

The stress field controls patterns of crustal deformation, including which faults are likeliest to cause earthquakes or transmit fluids. Since the 1950s, maps of maximum horizontal stress ( S Hmax ) orientations have advanced dramatically, and the style of faulting (relative principal stress magnitudes) has recently been mapped in some regions as well. This perspectives paper summarizes developments in characterizing stress orientations and (relative) magnitudes, including new seismic and borehole methods, as well as progress in identifying the causes of stress variations. Despite these advances, adding far more spatiotemporal detail would allow geoscientists to address many of today's key challenges regarding natural hazards, energy development, and geodynamics. In particular, it is critically important to characterize stress heterogeneity at multiple scales while also recognizing the coherent variability of the stress field. The second part of the paper considers how more detailed stress datasets could prove essential to addressing some of the grand questions in geoscience, including deciphering the poorly understood feedbacks between crustal dynamics and surface processes, improving earthquake and eruption forecasts, and determining the origins and shared properties of plate boundaries.

Geological Society, London, Special Publications

A spatial analysis of the groundwater emergence flood hazard in Long Island, New York and near coastal areas surrounding Long Island Sound in New York, Connecticut, and Rhode Island

Long Island, New York and near coastal areas surrounding Long Island Sound are densely populated and, like other coastal areas, are susceptible to flooding from several potential sources, including stormwater from precipitation events, tidal flooding and storm surge, and groundwater inundation or groundwater emergence flooding. The latter refers to the intersection of a rising water table with land surface or critical infrastructure. Many studies of flood drivers either neglect or only briefly discuss how shallow groundwater conditions may contribute to or exacerbate flood conditions. As part of a comprehensive study of compound flood hazards in the near coastal areas surrounding Long Island and Long Island Sound, a spatial analysis was completed, in cooperation with the Environmental Protection Agency’s Long Island Sound Study, using available regional datasets to characterize the potential hazard for groundwater emergence flooding. The approximately 3,100 square mile study area was subdivided into 11,407 900-meter by 900-meter (approximately 3,000-feet by 3,000-feet) grid cells, for the purposes of integrating the spatial datasets to calculate and map the groundwater emergence flood hazard. The depth to the water table, hydrologic soil groups, and National Land Cover Database were harmonized to the common grid. A groundwater emergence flood hazard rank was calculated for each grid cell for current average conditions following a set of rules accounting for the depth to the water table and the percent of area within each cell with slow infiltrating soils. A higher sea level position scenario was also calculated for the Long Island part of the study area. The calculated groundwater emergence flood hazard rank was reviewed in concert with the National Land Cover Data Base to identify developed areas and associated infrastructure that may be at risk to groundwater emergence flooding. Study results indicate that the groundwater emergence flood hazard is highest in coastal areas and near surface water where the water table is close to ground surface. Inland areas away from surface water bodies are not likely to be exposed to groundwater emergence flooding. For Long Island, under a scenario with higher sea level position, a greater groundwater emergence flood hazard is calculated in some locations closer to the coast and where land is submerged. Away from the coast and surface-water drainage, the groundwater emergence flood hazard is similar between the current average sea level condition and a higher sea level position scenario.

EarthArXiv

Pre-Acadian tectonics of the eastern Orange-Milford Belt, south-central Connecticut

This excursion presents a reinterpretation of mapping and new analytical data from the eastern Orange-Milford belt (OMB) in south-central Connecticut. The OMB is a fault-bound terrane of argillites and mafic rocks of anomalously low metamorphic grade—and of poorly constrained ages and tectonic affinity—wedged between kyanite/sillimanite-grade peri- Laurentian rocks to the west and anatectic peri-Gondwanan rocks to the east (Fig. 1A). Our data demonstrate that Ordovician(?) igneous and sedimentary rocks of the OMB were variably metamorphosed in the Ordovician and Silurian but escaped regionally pervasive, high-grade Devonian and later metamorphism. Previous interpretations (Fritts 1963a, 1965a, 1965b; Burger, 1967; Burger and others, 1968; Rodgers, 1985) described these rocks as a conformable sequence of low-grade, Ordovician to Devonian metasediments and metavolcanics. Our results reveal that the “metavolcanics” are not extrusive rocks but rather slivers of lower oceanic crust with complicated high- and low-grade metamorphic fabrics, intruded by a swarm of Silurian sheeted basalt dikes, and in fault contact with the surrounding metasediments. The purpose of this trip is to show evidence of early Paleozoic (Taconic) deformation and metamorphism preserved in rocks of the eastern OMB. These rocks remained shallow, cool, and sufficiently dry during the regionally dominant Acadian and Alleghanian orogenies to have avoided significant overprinting. As such, these rocks serve as windows into a geologic history otherwise unavailable between anatectic rocks of the peri-Gondwanan Bronson Hill, Avalon, and Gander terranes east of the Hartford basin and sillimanite-grade rocks of the peri-Laurentian Hartland and gneiss dome belts west of the OMB. We present major and trace element geochemistry including rare-earth element patterns for all mafic units in the eastern OMB as well as 40 Ar/ 39 Ar age spectra of amphibole, muscovite, and K-feldspar from rocks of the Maltby Lakes complex (of Deasy and others, 2017), Savin Schist, and Wepawaug Schist. Our evidence demonstrates that the units of the OMB have been assembled by faulting or intrusion, and that no stratigraphic relationships exist between the argillaceous schists and the metaigneous rocks.

Connecticut

Effect of deicing chemicals on the hydrologic environment in Massachusetts; evaluation of surface-water data collection

The objective of this study is to develop predictive relationships that can be used to describe the impact of highway deicing salts on the hydrologic environment. A method, presented in an earlier report, for estimating yearly mean chloride concentrations from estimated or actual runoff and salt-application data was applied to the period 1971 through1974 and the results compared with yearly mean chloride concentrations computed from records of specific conductance. Estimates were found to be from minus 63 percent to plus 56 percent in error when the error was expressed as the difference between estimated and computed values as a percentage of the computed values. Chloride concentrations used in this study are computed from specific conductance/chloride concentration relationships and records of specific conductance. Preliminary results from graphic analyses and least-squares regression analysis show that relationships between measured values of specific conductance and chloride concentration have correlation coefficients ranging from 0.30 to 0.97. Analysis of streamflow for all major dissolved constituents is recommended with the purpose of attempting to describe the variations in the specific conductance/chloride concentration relationships.

Massachusetts

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California

From critical minerals to food security, the benefits of data collaboration

The volume of data in the public geoscience sphere is rapidly and continually expanding. At Geoscience Australia (GA) we saw an over 500% increase in data points within our relational databases between 2018 and 2024, over the life of the Exploring for the Future (EFTF) program. With the Resourcing Australia’s Prosperity initiative, a continued increase in data quantity will be seen for the next 10 to 35 years. At the same time, a broadening audience for geoscience data is increasing the desire to enhance the diversity of delivery streams. This ranges from data-dense highly technical outputs for geoscience specialists to curated interpretive products for people who are non-geoscientists. Development of these curated outputs has contributed to our awareness of the need for data to be collected and compiled in a way that ensures its reuse, with a focus on quality metadata and data provenance.

Conference Paper

Relationship of atmospheric nitrogen deposition to soil nitrogen cycling along an elevation gradient in the Colorado Front Range

Microbial processing of atmospheric nitrogen (N) deposition regulates the retention and mobilization of N in soils, with important implications for water quality. Understanding the links between N deposition, microbial communities, N transformations, and water quality is critical as N deposition shifts toward reduced N and remains persistently high in many regions. Here, we investigated these connections along an elevation transect in the Colorado Front Range. Although rates of N deposition and pools of extractable N increased down the elevation transect, soil microbial communities and N transformation rates did not follow clear elevational patterns. The subalpine microbial community was distinct, corresponding to a high C:N ratio and low pH, while the microbial communities at the lower elevation sites were all very similar. Net nitrification, mineralization, and nitrification potential rates were highest at the Plains (1,700 m) and Montane (2,527 m) sites, suggesting that these ecosystems mobilize N. In contrast, the net immobilization of N observed at the Foothills (1,978 m) and Subalpine (3,015 m) sites suggests that these ecosystems retain N deposition. The contrast in N transformation rates between the plains and foothills, both of which receive elevated N deposition, may be due to spatial heterogeneity not captured in this study and warrants further investigation. Stream N concentrations from the subalpine to the foothills were consistently low, indicating that these soils are currently able to process and retain N deposition, but this may be disrupted if drought, wildfire, or land-use change alter the ability of the soils to retain N.

Colorado

Flood-inundation maps of the Blue River and major tributaries in and near Kansas City, Missouri, 2023–25

Digital flood-inundation maps for 35.5 miles of the Blue River, in and near Kansas City, Missouri, were created by the U.S. Geological Survey (USGS) in cooperation with the City of Kansas City. Maps were also developed for a combined 7.3 miles of Brush Creek (4.4 miles) and Indian Creek (2.9 miles), two primary tributaries to the Blue River in the study reach. The flood-inundation maps, available through the USGS Flood Inundation Mapping Program website at https://water.usgs.gov/osw/flood_inundation/ , depict estimates of the areal extent and depth of flooding, depth of water above first-floor elevations in selected buildings, water velocity, water-surface elevations, and time of travel corresponding to selected water levels or gage heights (hereafter referred to as “stages”) at nine reference USGS streamgages—five on the Blue River (USGS station numbers 06893590, 06893578, 06893500, 06893150, and 06893100), two on Brush Creek (USGS station numbers 06893562 and 06893557), one on Indian Creek (USGS station number 06893390), and one on the Missouri River (USGS station number 06893000). Near-real-time stages at these streamgages may be obtained from USGS Water Data for the Nation at https://doi.org/10.5066/F7P55KJN or the National Weather Service National Water Prediction Service at http://water.noaa.gov/ , which also forecasts flood hydrographs at seven of these sites (USGS station numbers 06893000, 06893590, 06893578, 06893500, 06893150, 06893557, and 06893390). Flood profiles were computed for eight map reaches by means of two-dimensional hydraulic models. The models were calibrated using the USGS-developed stage–streamflow relations at each reference streamgage. Two map reaches on the lower Blue River also include the effects of backwater from the Missouri River on flood inundation extent and hydraulic characteristics. The hydraulic models were used to compute water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datums. The profile stages ranged from the National Weather Service “Action Stage” or near bankfull to a stage exceeding the highest recorded water level at each streamgage. The simulated water-surface profiles were then combined with a digital elevation model (derived from light detection and ranging data having a nonvegetated vertical accuracy of a maximum 10-centimeter root-mean-square error) to delineate the area flooded at each water level and the associated hydraulic characteristics. The availability of these maps, along with information regarding current stage from the USGS streamgage and forecasted high-flow stages from the National Weather Service, will provide emergency management personnel, resource managers, and residents with information that could be critical for flood-response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Kansas, Missouri

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona

Groundwater response to managed aquifer recharge at the Southeast Houghton Artificial Recharge Project in Tucson, Arizona

Managed aquifer recharge is a widespread practice for storing water in the subsurface as groundwater. At a managed aquifer recharge facility in southern Arizona, groundwater-level and repeat microgravity data were collected to monitor aquifer response. These data were used to inform parameter identification for an unsaturated-zone flow model used to simulate the recharge process. The facility, the Southeast Houghton Artificial Recharge Project (SHARP), consists of 3 surface basins (about 27,600 square meters [6.8 acres] total surface area) where recycled water is distributed in recharge cycles lasting several months, with dry periods in between. During the study period, December 2020–December 2022, Tucson Water (the City of Tucson’s water utility) reported 6.56×10 6 cubic meters of water (5,320 acre-feet) recharged. Monitoring included groundwater-level observations at 3 monitoring wells and repeat microgravity measurements at as many as 22 locations (some stations were destroyed between surveys). Six gravity surveys were carried out using absolute- and relative-gravity meters. Large gravity increases, more than 250 microgals, were observed during the first repeat survey, 3.5 months after the start of recharge, but only in the immediate vicinity of the recharge basins. Data show that water moved downward to the water table, and storage changes in the unsaturated zone away from the facility were likely minimal. Gravity decreased at stations more than 1 kilometer from the facility, consistent with regional groundwater-level changes. Groundwater-level increases in wells adjacent to the recharge basins began 2 months after the second repeat gravity survey, and 5.5 months after recharge began. Unsaturated-zone flow modeling was carried out using software that simulates water movement and parameter estimation. Model calibration was carried out by minimizing an objective function calculated from the differences between simulated and observed groundwater levels, and between simulated and observed repeat microgravity data. Including repeat microgravity data in the objective function reduced the uncertainty in estimated parameter values for saturated hydraulic conductivity and saturated water content. Modeling indicated that the unsaturated zone between the recharge basins and the water table does not become saturated even after 685 days of simulated infiltration. This gradual wetting may account for increasing infiltration rates over time, as hydraulic conductivity increases with increasing water content. Unsaturated-zone water content decreased rapidly between recharge cycles. Model-simulated groundwater mounding extended about 1 kilometer from the center of SHARP after the 685-day period following the onset of recharge.

Arizona

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Scientific opportunities in the National Landscape Conservation System

The National Landscape Conservation System consists of unique and beautiful places across America’s landscapes where identified resources and values are protected and science is highlighted. The mission of the National Landscape Conservation System (NLCS), which is managed by the Bureau of Land Management and is often referred to as the agency’s National Conservation Lands, is to conserve, protect, and restore nationally significant landscapes for their cultural, ecological, and scientific values. This clear inclusion of science in the NLCS mission sets the stage for individual units to serve as places of learning, teaching, discovery, and innovation. Science is an integral part of managing the National Conservation Lands, and science conducted within and across the more than 900 units that make up the NLCS can inform and influence conservation and public land management well beyond its boundaries. Here, we highlight seven core aspects of National Conservation Lands that present valuable science opportunities: (1) the scientific values for which individual units are designated; (2) the many other resources, objects, and values within units; (3) the value of units as “control” sites for understanding the effects of activities such as mineral extraction that commonly occur elsewhere on multiple-use public lands but are often prohibited within National Conservation Lands; (4) the value of units for studying the effects of activities such as recreation that regularly occur and may be intensified on National Conservation Lands; (5) the high visibility of units, which draws strong interest and engagement from scientists, partners, and the public; (6) the functioning of the units as a network managed for a common purpose, which provides an opportunity to explore cross-cutting science questions across widely varying contexts and geographies; and (7) the opportunities units provide to promote and apply Indigenous Knowledge to scientific research to manage natural and cultural resources. Because of all of these characteristics, National Conservation Lands can serve as hubs for basic and applied science that can inform management of all public lands and resources into the future. We highlight these science opportunities through examples from existing units and suggest two actions that could help further science activities and impact on National Conservation Lands.

Parks Stewardship Forum

Timescales of cumulate mobilization and mixing for the 1868 A.D. eruption of Mauna Loa, Island of Hawai‘i

The deadly 1868 A.D. eruption of Mauna Loa’s lower Southwest Rift Zone (Island of Hawai‘i) included a M7.9 earthquake and associated tsunami and landslides, demonstrating the severe hazards posed by Earth’s largest active subaerial volcano. To better understand the relationship between intense seismic activity, dike emplacement, magma storage, transport histories, and mobilization of olivine cumulates at Mauna Loa, we examine compositional zoning of olivine in the 1868 lava flows. Samples range from basalt (< 10% olivine) to picrite (30–40% olivine). The olivine cargo is heterogeneous (Fo 78.2–89.2 ; forsterite = [Mg/(Mg + Fe) × 100]) but dominated by ~ Fo 89 cores that lie above the Fe-Mg equilibrium field of host glasses. Crystal rims < Fo 80 are due to post-eruptive modification in slow cooling lava flows. Minor element compositions fall within the range of other Mauna Loa olivine erupted in the past 200 years. Olivine crystals exhibit both normal and complex Fo zoning patterns that yield timescales of diffusive re-equilibration that range from 3 to 258 days, with 72% of crystals recording 71 days or less. These timescales correspond to magmatic priming of the summit reservoir system ~ 2 months prior to the eruption and the M7.9 earthquake likely facilitated the transport of the crystal-rich summit-derived magmas downrift shortly prior to eruption. If the recently proposed faster Fe-Mg diffusion coefficient is used, timescales instead range from < 1 day to 25 days, with most recording 1 week or less. In this scenario, most of the olivine zoning would have to have been generated after the M7.9 earthquake perturbed the system.

Hawaii