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Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho

Reservoir evolution, downstream sediment transport, downstream channel change, and synthesis of geomorphic responses of Fall Creek and Middle Fork Willamette River to water years 2012–18 streambed drawdowns at Fall Creek Lake, Oregon

Executive Summary Chapter A. Introduction Fall Creek Dam impounds Fall Creek Lake, a 10-kilometer-long reservoir in western Oregon and is operated by the U.S. Army Corps of Engineers (USACE) primarily for flood-risk management (or flood control) in late autumn through early spring months, as well as for water quality, irrigation, recreation, and habitat in late spring through early autumn. Since 2011 (water year [WY] 2012), Fall Creek Lake has been temporarily drawn down each year to facilitate downstream passage of juvenile spring Chinook salmon ( Oncorhynchus tshawytscha ) through the 55-meter (m) high dam. This annual dam operation is temporary, typically lasting about 1–2 weeks from WY 2012 through 2020 (drawdown operations in WY 2022–24 have increased to more than 6 weeks). Drawdown of the reservoir results in lake levels being lowered to the elevation near the historical, pre-dam streambed. The annual streambed drawdowns of WY 2012–18 have improved fish passage and led the USACE to formally adopt streambed drawdowns as part of annual operations at Fall Creek Dam. However, temporarily lowering the lake to streambed creates free-flowing conditions in the reservoir that result in the erosion and episodic export of predominantly sand and finer-grained sediments (less than 2 millimeters [mm]) to the lower gravel-bed reaches of Fall Creek and the Middle Fork Willamette River. The introduction of large volumes of sand and finer-grain sediment into the dam-regulated reaches downstream from Fall Creek Dam prompted questions about the geomorphic responses to annual streambed drawdowns within Fall Creek Lake and downstream reaches along Fall Creek and the Middle Fork Willamette River. The U.S. Geological Survey (USGS) in partnership with USACE initiated a comprehensive geomorphic and sediment transport investigation to assess the coupled processes of reservoir erosion, sediment evacuation from Fall Creek Lake, and patterns of sediment transport and deposition in reaches downstream from the Fall Creek Dam that have resulted from annual streambed drawdowns. The purpose of this report is to systematically describe the processes of sediment erosion, transport, and deposition at Fall Creek Lake and geomorphic interactions between reaches upstream and downstream from Fall Creek Dam that relate to dam operations. Specifically, this report focuses on evaluating geomorphic responses to streambed drawdowns from WY 2012 through 2018 and placing drawdown-induced geomorphic responses within the broader context of physiographic and historical conditions and dam operations of Fall Creek and Middle Fork Willamette Rivers. Key objectives for this study were to characterize changes in reservoir morphology and substrate at Fall Creek Lake, describe the character and temporal pattern of sediment transport downstream from Fall Creek Dam, characterize geomorphic changes in channel reaches downstream from the Fall Creek Dam, and relate these data to the annual streambed drawdowns of WY 2012–18. This study uses multiple independent monitoring and measurement approaches to assess site, reach, and river-scale geomorphic responses to drawdowns to inform dam and reservoir management. Patterns and processes of reservoir evolution were assessed with geomorphic mapping and volumetric analyses of topography through comparison of multiple digital surface models (DSMs). Just downstream from Fall Creek Dam, analyses of sediment export from the reservoir focused on suspended sediment but also incorporated bedload analyses to assess sediment sizes. Geomorphic assessments downstream from the dam used reach-scale and site-scale approaches to document changes in channel morphology and substrate, including site measurements of sand and finer-grained sediment deposition and in-channel bed-material, volumetric change analyses from comparison of digital elevation models (DEMs), and repeat geomorphic mapping. Findings from this study inform river management and dam operations by providing an understanding of (1) coupled upstream-downstream geomorphic responses to the Fall Creek Lake streambed drawdowns, (2) geomorphic responses of Fall Creek Lake streambed drawdowns in comparison to drawdowns at other large dams, (3) controls on reservoir erosion and downstream geomorphic responses, and (4) implications for future hydrogeomorphic changes that may result from continued drawdowns and monitoring activities to assess those changes. Chapter B. Reservoir Morphology and Evolution Related to Dam Operations at Fall Creek Lake To understand the volume and distribution of sediment accumulation in Fall Creek Lake since dam closure in 1965, decadal-scale sedimentation patterns (spanning approximately 1965–2016) are evaluated using a combination of storage curve analyses and geomorphic mapping. Short-term (drawdown event-scale) patterns of erosion, sedimentation, and sediment export downstream are evaluated using a combination of geomorphic mapping and change detection analyses that quantify the distribution and total volume of sediment erosion and deposition within Fall Creek Lake. Geomorphic mapping of reservoir topography and analyses of historical datasets reveals four categories of landforms and sediment processes within Fall Creek Lake related to lake level operations: lacustrine sedimentation expressed in the reservoir floor, fluvial erosion and deposition within historical stream channels during streambed drawdowns, channel-like features created by erosion within the reservoir floor during streambed drawdowns, and erosion on reservoir hillslopes. Where the reservoir floor is mapped for this study as pelagic (deep water), deposition up to 3 meters (m) thick by lacustrine processes and burial of pre-dam topography with deposits thinning toward the edges of the valley floor and upstream areas of reservoir are observed. Despite over 50 years of sediment accumulation since dam construction, the main stream channels of Fall and Winberry Creeks (or reservoir thalwegs) through the reservoir are well defined, though their distinct morphology is likely influenced by a long history of recurring historical drawdowns to or near streambed since dam construction. Unregulated streamflow and sediment transport through the reservoir primarily are confined to these channels during the streambed drawdown periods. Erosional channel-like features created by drawdowns are carved through underlying, unconsolidated reservoir floor sediments and are most prominent in the lower reservoir below minimum conservation pool (the low pool elevation during winter flood season); sediment generated from the formation of these drawdown channels is more likely to be transported through and out of the reservoir than sediment deposits along the reservoir hillslopes at the valley margins that are separated from main channels by areas of low-gradient reservoir floor. Morphologic changes in the lower reservoir topography between January 2012 and November 2016 indicate overall net erosion of about 129,500 cubic meters (m 3 ). The most prominent geomorphic changes occurred along the main channels of Fall and Winberry Creeks near the Fall Creek Dam where incision, lateral migration, and slumping banks resulted in vertical and lateral adjustments to channel position, whereas most changes fell below the detectable limit on higher-elevation reservoir floor surfaces except where erosion occurred along features mapped as drawdown channels. Chapter C. Sediment Delivery from Fall Creek Lake and Transport through Downstream Reaches USGS implemented a sediment monitoring program in WY 2013–18 to evaluate the quantity and character of reservoir sediment exported from Fall Creek Lake during streambed drawdowns. Turbidity and suspended sediments were monitored annually autumn through spring to span the WY 2013–18 streambed drawdowns; however, unequal monitoring timeframes each year reduced the ability to compare results and factors affecting sediment export from the reservoir difficult between years. These data were originally measured to develop regressions and compute suspended-sediment loads (SSL). Bedload sediment monitoring from a cableway at the Fall Creek streamgage was completed in the autumn-winter of WY 2013 and 2017. The limited number of samples and presumed variability in sediment supply from the reservoir precluded construction of streamflow and bedload discharge relations to compute more than instantaneous bedload. Sand and finer-grained silts and clays were transported from the reservoir in suspension, though some coarser grains (up to 32 mm) were also mobilized and transported downstream from the dam as bedload. Observations of increased sediment transport downstream from Fall Creek Dam coincided with lake levels approaching about 3 m (10 feet [ft] or elevation 690 ft) above the streambed regulating outlets. Suspended-sediment loads computed for the full monitoring periods WY 2013–18 at the Fall Creek streamgage, located 1.4 kilometers (km) downstream from Fall Creek Dam, range from 54,700 metric tons (t) in WY 2013 to 13,900 t in WY 2018. Although the total annual SSL varied from year to year, the overall seasonal patterns of suspended sediment transport throughout each year were similar during monitoring in WY 2013-18. Suspended-sediment loads were low prior to the drawdown, then increased rapidly as lake levels lowered and approached the streambed. In the weeks following the drawdown period, as pool levels were increased, SSL remained slightly elevated above pre-drawdown levels but generally declined through the following winter and spring except during streamflow-driven pulses of suspended-sediment transport. WY 2013 had the greatest total computed SSL for each streambed drawdown and partial-year monitoring period. SSL computed for the partial-year period have generally decreased since WY 2013 and have varied by about 6,800 t with the exception of WY 2014. WY 2014 SSL reflects anomalously low sediment export due to low streamflows and freezing conditions that stabilized reservoir floor deposits. Bedload measurements in the short 1.4-km reach between Fall Creek Dam and the Fall Creek streamgage showed an inverse correlation between bedload transport rates and discharge, which probably reflects diminishing supply of coarse-sized sediment. Sand was more abundant (60–100 percent) than gravel in bedload samples confirming sand and finer-grained sediment dominated sediment evacuated from the reservoir during streambed drawdowns at Fall Creek Lake. Chapter D. Geomorphic Responses to Fall Creek Lake Streambed Drawdowns Downstream from Fall Creek Dam In the days, weeks, and months following streambed drawdown operations at Fall Creek Dam through WY 2018, sites downstream from the dam displayed a variety of geomorphic responses to reservoir sediment delivery within the main channel and overbank areas. Evaluation of streambed elevations at two streamgages located 1.4 km downstream from the dam on Fall Creek and 16.3 km downstream from the dam on the Middle Fork Willamette River indicated the effects of drawdown sediment on bed elevations were modest and transient. Repeat particle size measurements (October 2015 and September 2016) at five sites along Fall Creek and the Middle Fork Willamette River showed similar grain-sized distributions that do not reveal substantial deposition of fine-grained sediment related to the WY 2016 streambed drawdown. Altogether, these findings indicate that transport capacity in the main, low-flow channels of Fall Creek and Middle Fork Willamette River during WY 2012–18 was sufficient to mobilize and evacuate reservoir sediments from streambed drawdowns or other bank material and tributary sources. However, other monitoring for this study indicate low-velocity zones in off-channel areas are prime locations for sand and finer-grain sediment deposition. Patterns of overbank sediment accumulation indicate that the magnitude and timing of overbank deposition on bars and low-elevation floodplain varies with proximity to the dam, geomorphic setting, streamflows, and other factors. Sand and finer-grained reservoir sediments carried as suspended-sediment load in the reaches downstream from Fall Creek Dam were deposited in overbank areas as observed with clay-horizon markers during WY 2016–17. Overbank deposition quantified with Geomorphic Change Detection (GCD) software evaluated landform-scale patterns of erosion and deposition using repeat light detection and ranging (lidar) surveys at two sites in the Upper Fall Creek reach and one site in the Jasper reach for 3 years (2012–15) and one site in the Clearwater reach for 6 years (2009–15). Deposition thickness and spatial patterns from the GCD analysis were variable; some sites had dispersed but measurable deposition while at others, deposition was highly localized and exceeded 1 m in depth. Patterns of overbank deposition illustrate interactions among bar morphology, local hydraulics, and suspended-sediment transport dynamics that can create patches of highly localized deposition. The measured deposition at the two Fall Creek GCD sites likely resulted from reservoir sediments released from Fall Creek Lake during streambed drawdowns in WY 2016 and 2017 because the limited sediment inputs from bank material (geomorphically laterally stable reach) or tributaries (no significant tributaries) provided few other sediment sources. On the Middle Fork Willamette River, observed patterns of overbank deposition could reflect sediment sourced from upstream tributaries, bank erosion, or Fall Creek Lake streambed drawdown operations. Despite the introduction of several thousand tons of reservoir sediment delivered from the Fall Creek Lake streambed drawdowns to below-dam river corridors, reach-scale mapping of channel features downstream from Fall Creek Dam shows minimal evidence of changes in channel planform or landforms that can be attributed to a drawdowns in WY 2012–16. On Upper Fall Creek reach, widespread increases in gravel bars or other in-channel sediment did not result from the five streambed drawdowns. The main changes attributable to sediment releases from Fall Creek Lake were localized increases in vegetated bar area, particularly on channel margin areas where sand and finer-grain sediment was deposited and rapidly colonized by vegetation. The area of mapped secondary water features decreased between 2005 and 2016, but that may be due to lower discharges depicted in the 2016 aerial photographs and less mapped area of inundation. Primary changes along the Lower Fall Creek reach include a 6.4 percent decrease in area of secondary water features between 2011 and 2016, and a nearly twofold increase in the area of unvegetated bars. Immediately downstream from the Fall Creek confluence, there were negligible changes in the location and areas of vegetated bars and the main wetted channel between 2005 and 2016, and local increases in bar area cannot be attributed solely to deposition of reservoir sediments from Fall Creek Lake because (1) areas along the Middle Fork Willamette River just upstream from the Fall Creek confluence display similar type and magnitude of changes and (2) some of the increases at the confluence area pre-date the drawdowns. The cumulative effect of sediment releases from Fall Creek Lake streambed drawdowns from WY 2012 to 2016 on downstream channel planform and landforms are modest compared to the river-scale transformations and planform changes that occurred in the decades following dam construction. Chapter E. Discussion of Geomorphic Responses of Fall Creek and Middle Fork Willamette River to Streambed Drawdowns at Fall Creek Lake Multiple aspects of Fall Creek Dam infrastructure and operations exert first-order controls on the magnitudes of reservoir erosion that occur during the streambed drawdowns and ultimately determine the sediment delivery to downstream reaches. Key aspects of the dam and its operations that are most relevant to assessing geomorphic responses to streambed drawdowns include the (1) dam infrastructure, including configuration and size of regulating outlets and their proximity to the streambed which dictates the capacity and competence of the river to deliver sediment to downstream reaches and mode of sediment transport as suspended-sediment load or bedload; (2) frequency of historical drawdowns and long-term, year-round dam operations and lake level management, which partly dictate reservoir morphology and locations and magnitudes of readily erodible materials; (3) dam operations and hydroclimatic conditions during the streambed drawdown (including length of the drawdown and streamflows entering the reservoir), which directly control the timing, duration and magnitude of reservoir erosion and sediment evacuation; and (4) dam operations following the streambed drawdown operation that regulate streamflows (and thereby sediment transport conditions) downstream of Fall Creek Dam which primarily reflect interactions between hydroclimatic conditions and flood control operations. Patterns of sediment erosion and evacuation observed in this study at Fall Creek Lake from WY 2012–18 suggest that reservoir erosion during annual streambed drawdowns may remain similar or decrease in future years assuming (1) annual streambed drawdown operations are implemented in similar manner as the WY 2012–18 drawdowns (in terms of duration, late autumn or early winter implementation, rate of pool-level lowering to reach streambed, and other factors), (2) streambed drawdowns coincide with similar conditions as were observed WY 2012–18 (similar sediment yield into reservoir, low reservoir inflows, limited precipitation, moderate air temperature), and (3) no major geomorphic changes in the main reservoir channels of Fall and Winberry Creeks occur (for example, channel avulsion). Under such conditions, it is hypothesized that the stream channel within the reservoir would achieve a quasi-equilibrium state with respect to annual influx and export of sediment and aided by the substantial amount of in-channel bedrock, will remain laterally stable without erosion across reservoir deposits. Patterns of sediment transport measured at the Fall Creek streamgage downstream from Fall Creek Dam provide insight into the potential effects of future streambed drawdowns at Fall Creek Lake. Analyses of suspended sediment measured in WY 2013–18 show a major reduction in suspended-sediment loads between WY 2013 and later years, indicating streamflows transporting sediment through the reservoir to downstream reaches during streambed drawdowns have become supply limited. The 6-year suspended-sediment monitoring and sampling program is insufficient to make predictions about future sediment transport conditions because of uneven monitoring periods and varying controls on reservoir sediment erosion. It is likely that future suspended-sediment loads will be variable but similar to those observed in WY 2015–18 if operational, climatic, and geomorphological factors remain similar to those monitored WY 2015–18. Suspended-sediment loads downstream from Fall Creek Lake will likely remain highest when regulating outlets are fully open and Fall Creek is free flowing with the reservoir fully drained with little to no residual pool. Over time, it is possible that the suspended-sediment loads would reflect mobilization of reservoir sediment deposited in the previous year rather than erosion of sediment deposited years or decades earlier. Bedload is likely to remain a small fraction of the total sediment load evacuated from the reservoir and is relatively modest compared with pre-dam bedload transport rates because most coarse sediment remains trapped by the dam. If sediment releases from Fall Creek Lake and ensuing streamflow conditions follow a similar pattern in the future as was assessed in this study spanning WY 2012–18, near-term geomorphic adjustments downstream of the dam are expected to be modest. Barring major operational, climatic, and geomorphological changes, local site-scale deposition on bars, overbank areas, or off-channel features that persists several months after the streambed drawdown will likely continue to be highly variable, ranging from negligible to several centimeters of deposition. At the landform-scale, low velocity areas nearest to Fall Creek Dam will likely continue to undergo rapid deposition immediately during and after a streambed drawdown event, similar to patterns observed for WY 2012–18. Some of the sediment entering these off-channel features and margin areas may be temporarily stored, then later remobilized and dispersed farther downstream. But if newly deposited sediment persists through the following spring, there is a greater likelihood that local vegetation will establish, reinforce deposited material, and trap sediment during later drawdowns. The reach-scale geomorphic changes may become more apparent if (1) streambed drawdowns continued for several decades, and geomorphic changes were measured at decadal scales or (2) the amount of sediment introduced to downstream reaches substantially increased and (or) sediment transport capacity decreased. The continued streamflow regulation of Fall Creek Dam after sediment releases provides an opportunity to strategically manage streamflows during and after the streambed drawdowns to minimize downstream sediment impacts and ensure other operational thresholds are satisfied. This study provides a comprehensive foundation of datasets and geomorphic analyses to inform dam operations at Fall Creek Lake, monitor sediment transport downstream, and consider operational schemes for future drawdowns. The datasets from this study also provide baselines of sediment transport and geomorphic conditions to assess future changes in reservoir and downstream environments. Future monitoring could be tailored to address specific questions regarding the long-term geomorphic effects of streambed drawdowns on fluvial habitats, flood hazards, cultural resources, or downstream water quality. Future monitoring activities could focus on the relevant geomorphic processes and spatial domains within the three categories used for this study: (1) reservoir erosion and net sediment evacuation, (2) sediment delivery to downstream reaches, including magnitude and temporal pattern of sediment transport, and (3) geomorphic responses of downstream reaches to sediment delivery. Specifically, high priority future monitoring activities could include: Repeat topographic or photographic surveys in the reservoir to characterize changes occurring within individual drawdowns, to quantify sediment export, to determine temporal changes in reservoir storage, and to identify locations of erosion and deposition. Continuous, year-round turbidity monitoring supplemented with suspended-sediment measurements at a streamflow-gaging station immediately downstream from the dam to quantify sediment export. Repeat geomorphic monitoring, mapping, or modeling in downstream reaches to track changes in channel and over bank features using a combination of site- and reach-scale monitoring approaches. This could support assessments of sediment deposition and ensuing vegetation encroachment on flood hazards and habitats and examine how sediment transport and depositional processes may be affected by different sediment supply, streamflow, or dam management scenarios.

Oregon

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California

Wind River subbasin restoration: Annual report of U.S. Geological Survey activities January 2024 through December 2024

We sampled juvenile wild Oncorhynchus mykiss (Steelhead Trout) in headwater streams of the Wind River, Washington, to characterize population attributes and investigate life-history metrics, particularly migratory patterns, and early life-stage survival. Additionally, this sampling provides an index of abundance of non-native Brook Trout Salvelinus confluentus . We used passive integrated transponder (PIT) tagging and a series of instream PIT-tag interrogation systems (PTISs) to track juveniles and adults. The Wind River subbasin is considered a wild Steelhead refuge by Washington Department of Fish and Wildlife (WDFW). No hatchery Steelhead Trout have been released in the Wind River subbasin since 1997, and hatchery adults are estimated at less than one percent of spawners in most years. Over 25 years of Steelhead Trout status and trend monitoring and research in the subbasin is contributing to understanding of population response to numerous restoration actions in the subbasin, including removal of Hemlock Dam from Trout Creek in 2009, which had an inadequate adult ladder and contributed to increased water temperatures, to near lethal levels for salmonids. Data from our study, and companion work by WDFW, are contributing to the Columbia Basin Fish and Wildlife Program (2009) Research, Monitoring, and Evaluation (RM&E) Strategy of Fish Population Status Monitoring. Specifically, this work addresses the sub-strategies of 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and Uncertainties Research regarding differing life histories of a wild Steelhead Trout population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer and fall 2024, we PIT-tagged 2,075 Steelhead Trout parr (age-0 and age-1), in the Trout Creek and upper Wind River watersheds. Age-0 and age-1 parr were at high abundance due to strong spawner numbers in 2023 and 2024 (Estimate of 932 in 2023; and a moderate number of spawners in 2024 though an estimate is not available at this time; 24-year median = 619; Charlie Cochran, WDFW Fish Biologist, personal commun., 2025). An additional 100 parr (age-0 and age-2 or older) were tagged to provide fish for estimating detection efficiencies at PTISs. Steelhead Trout parr were recaptured and detected through repeat headwater sampling, smolt trapping, instream PTISs and Columbia River mainstem PIT-tag detection. We maintained and upgraded six instream PTISs to detect PIT-tagged Steelhead Trout parr, smolts, and adults, providing data for population assessments, and life-cycle research. Detection data from PIT-tagged adult Steelhead Trout at our four primary PTISs allow assessment of adult escapement to tributary watersheds within the Wind River subbasin. Most adult Steelhead detected were tagged by WDFW at an adult trap in the lower Wind River and some as smolts at screw traps. Adult Steelhead Trout detection efficiency estimates at our primary PTIS in Trout Creek have been greater than 99 percent during eight of the past ten years and have exceeded 97% at our primary PTIS in the Wind River during nine of the past ten years. Adult escapement estimates to tributary watersheds are helping evaluate the efficacy of the 2009 removal of Hemlock Dam from rkm 2.0 of Trout Creek. Detections at the instream PTISs have shown trends of age-0 and age-1 Steelhead Trout parr emigration from natal areas during summer and fall, in addition to the expected movement of parr and smolts in spring. Our data suggest that most fish from a cohort that migrate downstream will do so at age-1 for additional rearing in the subbasin. We have estimated that from 15% to 56% of parr tagged as age-0 fish in headwater areas make downstream migrations at age-1 for additional rearing (median = 29%). We have estimated that from 1% to 27% of Steelhead Trout parr, tagged as age-1 fish, make downstream migrations during fall (median = 3.5%): this is especially pronounced in the upper Wind River portion of the watershed (median 10%). These findings raise questions about parr rearing habitat and whether migrations are density- or habitat-quality driven, and answers to such questions are long-term goals of this study as active and passive habitat restoration occurs. Repeat sampling at sites in the subbasin within and between years has enabled assessment of juvenile Steelhead Trout growth patterns. Growth rates (relative change in weight) of age-0 PIT-tagged parr during summer have been similar across the subbasin, though slightly lower in the Trout Creek watershed (Trout Creek sites, 0.57 - 1.25%/day, Wind River sites = 0.94 – 2.48%/day). Summer growth rates have been lower for age-1 parr in the Trout Creek watershed than the upper Wind River watershed (Trout Creek sites, = 0.03 - 0.14%/day, Wind River sites = 0.05 – 0.19%/day). Yearly relative growth was similar across the subbasin for both age-0 and age-1 tagged parr. During 2024 range of mean daily relative change in weight from the previous year for age-0 tagged fish was: Trout Creek sites = 0.96 – 1.41%/day, Wind River sites = 0.80 – 1.30 %/day; and for age1 tagged fish was: Trout Creek sites = 0.37 - 0.50 %/day, Wind River sites = no age-1 tagged recaptures. Non-native Brook Trout are present in the subbasin, chiefly the Trout Creek watershed. Mean percent-of-catch that is Brook Trout, at four sample sites in Trout Creek, has declined from the period 1998 – 2003 to the period 2011 – 2024 (range of decrease = 19 - 82%). Percent-of-catch (of 64 samples, 52 < 10%; 3 > 20%) and number of Brook Trout at the Trout Creek sites from 2011 through 2024, though variable, have generally declined. Habitat restoration evaluation efforts are critical to ensure efficient use of money and resources but require long-term monitoring of population metrics. Detailed viable salmonid population and life-history data, such as that provided by PIT-tagging and instream PTIS networks inform fisheries policy and management and enable assessment of long-term effects of habitat restoration actions such as the removal of Hemlock Dam on Trout Creek and proposed major instream habitat restoration in the upper Wind River.

Washington

Preliminary geologic map of the Sparta East, Sparta West, and parts of the Glade Valley and Whitehead 7.5-minute quadrangles, North Carolina and Virginia, and the epicentral area of the August 9, 2020, Mw 5.1 earthquake near Sparta, North Carolina

Introduction New bedrock and surficial geologic mapping in the Sparta East, Sparta West, and parts of the Glade Valley and Whitehead 7.5-minute quadrangles, North Carolina and Virginia, investigates the geologic framework and causative mechanisms of the August 9, 2020, Mw 5.1 earthquake near Sparta, North Carolina. The mapping documents (1) the coseismic surface rupture from the 2020 earthquake and related brittle structures in the bedrock; (2) the fault contact between the western Blue Ridge and eastern Blue Ridge; (3) lithostratigraphy in the Lynchburg Group, Ashe Metamorphic Suite, and Alligator Back Metamorphic Suite; (4) the nature of the contact between the Lynchburg Group, Ashe Metamorphic Suite, and Alligator Back Metamorphic Suite; and (5) surficial deposits.

North Carolina, Virginia

2023 Earthquake Ground-Motion Workshop for the Central and Eastern United States, with a focus on the Gulf and Atlantic Coastal Plains—Agenda and abstracts

The U.S. Geological Survey held a virtual workshop December 7–8, 2023, to share research and ideas about earthquake ground motions in the Central and Eastern United States, with a focus on the Atlantic and Gulf Coastal Plains. The workshop was organized to learn about potential regionalization of ground-motion characteristics (source, path, and site), consider new explanatory variables for site response, and hear and discuss updates on ground-motion research on the Atlantic and Gulf Coastal Plains. The workshop was organized into a series of contributed presentations and three panel discussions held during 2 days. This report documents the agenda, contributed abstracts, and panel summaries.

Scientific Investigations Report

Hydrogeologic framework and considerations for drilling and grouting of closed-loop geothermal bores in the Erie-Ontario Lowlands and Allegheny Plateau of New York State

The hydrogeologic framework at closed-loop geothermal sites in the Erie-Ontario Lowlands and Allegheny Plateau of central and western New York is the result of the complex interaction of bedrock geology, glacial geology, and groundwater hydrology, and the occurrence of petroleum and gas. Considerations for closed-loop geothermal bore installation include the thickness and character of glacial deposits, bedrock solubility and depth to competent rock, karst development, the distribution of highly permeable zones and their hydraulic heads, and the presence of saline water, gas, and oil. The hydrogeology of the Erie-Ontario Lowlands and Allegheny Plateau poses challenges to closed-loop geothermal bore drilling and casing; managing drill cuttings, discharge water, and gas; and grouting. The potential to encounter severe challenges typically increases with bore depth. This report highlights hydrogeologic considerations for closed-loop geothermal bore installation in New York’s Erie-Ontario Lowlands and Allegheny Plateau to help guide the efficient and safe development of geothermal resources in the regions.

New York

Coastal and Marine Hazards and Resources Program decadal science strategy 2020–2030

Overview The decadal science strategy of the Coastal and Marine Hazards and Resources Program (CMHRP) of the U.S. Geological Survey for 2020 to 2030 describes the CMHRP's vision and mission and the strategic framework needed to support key program goals: Conduct research and develop science-based tools that lead to safer, more productive coastal communities and improved stewardship of natural resources.

Circular

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

AAPG Wiki

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within parts of Bandera and Kendall Counties, Texas

The karstic Edwards and Trinity aquifers are classified as major sources of water in south-central Texas by the Texas Water Development Board. During 2019–23 the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, mapped and described the geology and hydrostratigraphy of the rocks composing the Edwards and Trinity aquifers within parts of Bandera and Kendall Counties from field observations of the surficial expressions of the rocks. The thicknesses of the mapped lithostratigraphic and hydrostratigraphic units were also estimated from field observations in the study area. The Cretaceous rocks in the study area are part of the Trinity Group and Edwards Group. The groups, formations, and members are composed primarily of layers of marls, shales, and limestones. The limestones are composed of mudstone through grainstone, framestone and boundstone, dolomite, and argillaceous and evaporitic rocks. The principal structural feature in the study area is the Balcones fault zone. The Balcones fault zone is the result of late Oligocene and early Miocene extensional faulting and fracturing that was a result of the eastern Edwards Plateau uplift. In the Balcones fault zone, most of the faults in the study area are high-angle to vertical, en echelon, normal faults that are predominantly downthrown to the southeast. Hydrostratigraphically, the rocks exposed in the study area are those that contain the Edwards aquifer, the upper zone of the Trinity aquifer, and the middle zone of the Trinity aquifer. Descriptions of the hydrostratigraphic units, thicknesses, hydrologic function, porosity types, and field identification and observations are provided, including those for the informal Bandera and Love Creek hydrostratigraphic units of the Edwards aquifer, which were identified through the mapping for this study.

Texas

The U.S. Geological Survey, the U.S. Department of Defense, and the U.S. Intelligence Community—100 years of mapping and remote sensing collaboration, 1879–1979

Introduction The U.S. Geological Survey (USGS)—a Federal civilian agency—and U.S. military and intelligence agencies collaborate on mapping and remote sensing and have since the establishment of the USGS. The organizations exchange data and information and share technology to further their respective missions in service to the American people. Often referred to as examples of “good government” or “whole of government,” the collaboration avoids costly duplication and maximizes time and effort for the government sectors. Collaboration between these sectors started with the original mapping of the United States and evolved to include remote sensing after the advent of aerial photography and satellite imagery.

Circular

Water-resources inventory and assessment at Katahdin Woods and Waters National Monument

The U.S. Geological Survey, in cooperation with the National Park Service, prepared a water-resources inventory and assessment for Katahdin Woods and Waters National Monument (KAWW). This compilation includes published and publicly accessible hydrologic data and resource assessments of streams, rivers, ponds, lakes, wetlands, vernal pools, and groundwater in and near KAWW. It also includes reports and datasets summarizing attributes of KAWW’s hydrologic infrastructure, such as stream crossings, dams, wastewater discharge plants, groundwater monitoring wells, and U.S. Geological Survey streamflow-gaging stations. Descriptions of data and details of current limitations in available datasets are included. Wetland, groundwater, streamflow, and water-quality information are all limited. Hydrography data are available; however, there are limited ground-truth data. Accurate streamlines within KAWW were developed from light detection and ranging (lidar) as a part of this work. Hydrologic infrastructure information is available from multiple sources; however, differences exist among the datasets. Datasets are summarized in appendix 1.

Maine