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922 records · Page 36Linked to original sources
USGS2024

Evaluation of the lithium resource in the Smackover Formation brines of southern Arkansas using machine learning

Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithium concentration data to train a random forest machine-learning model using geologic, geochemical, and temperature explanatory variables and create a map of predicted lithium concentrations in Smackover Formation brines across southern Arkansas. Using these predicted lithium maps with reservoir parameters and geologic information, we calculated that there are 5.1 to 19 million tons of lithium in Smackover Formation brines in southern Arkansas, which represents 35 to 136% of the current US lithium resource estimate. Based on these calculations, in 2022, 5000 tons of dissolved lithium were brought to the surface within brines as waste streams of the oil, gas, and bromine industries.

Arkansas↗
USGS2026

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin↗
USGS2024

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗
USGS2025

Critical Minerals in Ores (CMiO) database

Critical minerals are commodities essential to modern industrial and strategic technologies and are highly vulnerable to supply chain disruption. The Critical Minerals Mapping Initiative (CMMI) is a collaboration among the U.S. Geological Survey (USGS), the Geological Survey of Canada, and Geoscience Australia that aims to deepen global understanding of where critical minerals are located. A key output of this initiative is the Critical Minerals in Ores (CMiO) database that is advancing our collective understanding of critical minerals distributions. For instance, publicly available data on the concentrations of many critical minerals are sparse because these commodities can only be produced in small, yet essential, quantities compared to the primary commodities like copper and zinc. The CMiO database helps bridge this gap by offering high-quality, multielement geochemical data from a wide variety of critical mineral-bearing deposits around the world. Importantly, it uses a novel consensus deposit environment, group, and type classification scheme developed by the agencies that allows comparisons among ore deposits from different regions. The CMiO database contains geochemical data for more than 20,000 samples from more than 100 deposit types comprising 10 deposit environments.

Fact Sheet↗
USGS2024

Geophysical modeling of a possible blind geothermal system near Battle Mountain, NV

The northeastern portion of the Reese River basin in north-central Nevada is the focus of detailed geophysical and geological studies as part of the INGENIOUS project, which aims to identify new, commercially viable hidden geothermal systems in the Great Basin region of the western U.S. This location, herein referred to as Argenta Rise, occupies a broad (~15km wide) left-step between major range-front fault systems along the northwestern edge of the Shoshone Range and Argenta Rim, with numerous ENE-striking intra-basin faults presumably accommodating sinistral-normal oblique slip across the step-over. Four discrete regions have been identified within the study area that have favorable structural settings for hosting a blind hydrothermal system. However, with no definitive or extensive surface manifestations of an active hydrothermal system (e.g., geysers, steam vents, sinter, etc.), detailed geophysical studies are necessary to resolve subsurface geology and structure, and identify zones of enhanced structural complexity that may promote hydrothermal fluid flow. Hence, we collected high-resolution gravity, MT, and rock property data (density, magnetic susceptibility), and analyzed the recently acquired GeoDAWN aeromagnetic data to characterize potential geothermal resources in this region. Using the new geophysical datasets, we jointly modeled gravity and magnetic data along a series of intersecting 2D profiles that integrated information from recent, local-scale fault mapping. Rock property measurements performed on outcrops and hand samples throughout the study area constrained the models. The MT data were used to construct a 3D resistivity model that highlights the location of inferred alteration and fluids in the subsurface. Combined MT and potential field results reveal which structures may be most important for controlling hydrothermal fluid migration, as well as which geologic units may host hydrothermal fluids. Our gravity derived depth to basement surface coincides well with the base of shallow conductive anomalies, suggesting hydrothermal fluids may be confined to basin fill sediments and volcanics. This work supports our development of 3D geophysical and geologic models that are focused along the western flank of the northern Shoshone Range and aids the process of selecting sites for temperature gradient drilling.

Nevada↗
USGS2026

Magmatic source of the opening phase of Kīlauea’s 2018 Lower East Rift Zone eruption

The 2018 eruption of Kīlauea volcano in its Lower East Rift Zone began with the discharge of evolved high-Ti basalt as weak lava fountains and short, slow-moving lava flows. The lavas were quickly geochemically recognized as being derived from magmas stored within the rift zone and remobilized by a new intrusion, a sequence that is common at Kīlauea. This initial phase of the 2018 eruption, referred to as phase 1a, lasted for 6 days and was followed by extrusion of mixed magma after a 3-day pause. Even though remobilization of older rift zone magmas is common within Kīlauea’s rift zones, it is difficult to determine which past intrusion(s) may have initially emplaced those stored magmas. This difficulty stems from the tendency for Kīlauea magmas to follow very similar differentiation paths without significant variations in major, minor, or even trace element chemistry. We investigate possible magma sources for the lavas erupted during phase 1a of the 2018 eruption using whole-rock, mineral, and glass major and trace element compositions from historical East Rift Zone eruptions with adjacent fissures. We consider two primary hypotheses for the phase 1a source: magmas associated with the 1955 Lower East Rift Zone eruption or the nine eruptions in the Middle and Upper East Rift Zone during the 1960s. Our results suggest that magma associated with the earliest phases of Kīlauea’s 1955 eruption was the most likely source of the 2018 phase 1a remobilized magma. We determine volatile saturation pressures from melt inclusion chemistry and find similar storage depths for the 2018 phase 1a and early 1955 magmas. The phase 1a and early 1955 lavas are nearly indistinguishable in all of the compositional criteria considered, implying that the leftover 1955 magma body barely cooled and differentiated in the 63 years between eruptions (cooling rates of ~0.1 °C/year). This study sheds light on the potential for protracted storage of eruptible magmas in rift zones at Kīlauea, and highlights some of the challenges and solutions to identifying genetic relationships between magmas at Kīlauea.

Hawaii↗
USGS2024

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research↗
USGS2026

Ground-motion characterization for the 2025 U.S. National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands

We develop the ground-motion characterization (GMC) for the 2025 U.S. National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands (NSHM-PRVI) for earthquakes in active crustal, subduction interface, and subduction intraslab regimes. Using ground-motion models (GMMs) from the Next-Generation Attenuation (NGA)-West2 and NGA-Subduction projects, the GMC is parameterized by scaled-backbone models for median ground motions and by independent logic trees of aleatory variability. We introduce several novel GMC features into the U.S. NSHM: (1) use of regional ground-motion data for modeling median ground motions; (2) development of scaled-backbone models for median ground motions; and (3) development of independent logic trees of aleatory variability from variance components of GMMs and computed from multiple ground-motion datasets, and incorporating regional ground-motion data effects on variability. We compute probabilistic seismic hazard curves and maps to evaluate the contributions from the GMC components and for comparison with the 2003 GMC. Contributions of the GMC to epistemic uncertainty in seismic hazard are evaluated through spatial variations in epistemic uncertainty in hazard maps, comparisons between mean hazard curves and fractiles, as well as investigations of the contributions of logic-tree branches to hazard maps and curves. Comparisons between seismic hazard from the 2025 and 2003 GMCs allow examination of the changes in hazard curves and mapped values with 2% and 10% probabilities of exceedance in 50 years. The 2025 GMC exhibits modest changes in median predictions, relative to the 2003 GMC; overall, values of aleatory variability are higher, except at long periods ( ), resulting in changes to probabilistic ground motions at low probabilities of exceedance (<10% probability of exceedance in 50 years). Changes in hazard at 2% and 10% probabilities of exceedance in 50 years are also relatively modest (within 20%) at most sites, with the impacts from the 2025 GMC exhibiting minor reductions and increases at 0.2 and 1.0 s periods, respectively, relative to the 2003 GMC.

Puerto Rico, U.S. Virgin Islands↗
USGS2023

Thickness of the Saudi Arabian crust

As part of a joint Saudi Geological Survey (SGS) and U.S. Geological Survey (USGS) project, we analyzed P-wave receiver functions from seismic stations covering most of the Kingdom of Saudi Arabia to map the thickness of the crust across the Arabia Plate. We present an update of crustal-thickness estimates and fill in gaps for the western Arabian Shield and the rifted margin at the Red Sea (the coastal plain), as well as the eastern Arabian Platform. We applied a conventional H-k stacking algorithm and included careful attention to stacking weights, two forms of sedimentary corrections for stations located on the Arabian Platform, and additional processing for noisy stations. We obtained useful results at 154 stations from 898 teleseismic events over a 2-year period from 1995–1997 (for non-SGS stations) and a 6-year period from 2008–2014 (for SGS stations). Average crustal thickness (that is, depth to the Mohorovičić discontinuity [Moho] below the surface) beneath the Red Sea coastal plain (the rift margin) is 29 kilometers (km), beneath the volcanic fields (known in Arabic as harra [plural] or harrat [singular]) is 35 km, beneath the Arabian Shield (excluding harrats) is 37 km, and beneath the Arabian Platform is 38 km. Crustal thinning appears not to extend east of the rift escarpment, suggesting uniform extension that is no broader at depth than at the surface. In contrast to some previous claims that the Arabian Platform crust is thicker than that of the Arabian Shield, we find no statistically significant difference between their whole crustal thicknesses. However, the average subsedimentary crustal thickness (that is, the crystalline crust) for stations on the Arabian Platform is 34 km, 3 km thinner than the crust of the Arabian Shield. Individual station P-wave (pressure) velocity and S-wave (shear) velocity ratios ( V P / V S ) are highly variable for the Arabia Plate, ranging from 1.60 to 1.97 and averaging 1.75, with a standard deviation of 0.07. There are no statistically significant differences between V P / V S ratios of the different geologic regions of Saudi Arabia. Similar V P / V S ratios, coupled with similar crustal thicknesses for harrats and the Arabian Shield, indicate that Cenozoic magmatism has contributed negligibly to crustal growth.

Professional Paper↗
USGS2026

Validating antler- and movement-based estimates of caribou reproduction using video camera collars

Wildlife agencies invest substantial resources in monitoring ungulate reproductive rates given ongoing concerns about population trends and their implications for management. For barren-ground caribou ( Rangifer tarandus ) in the North American Arctic, data on parturition and neonate survival have traditionally been collected using visual observations of antler retention and calf presence from small, fixed-wing aircraft. However, these surveys are weather-dependent, expensive, and dangerous, motivating the development of movement-based approaches that infer reproductive events from global positioning system (GPS) location data. We had the unique opportunity to use video camera collars to validate both antler- and movement-based methods for estimating reproduction in barren-ground caribou, using data from the Porcupine (2018–2023) and Western Arctic (2021, 2023) herds in Alaska, USA, and Yukon, Canada. For the movement-based approaches, we assessed individual-based and population-based methods, which both inferred parturition following a sharp decline in movement and inferred calf loss following a sharp increase in movement. We investigated these approaches using rarified 1-, 2-, 4-, and 8-hour fix intervals. Based on video collar observations, we found that antler retention at the onset of the calving period was highly accurate for predicting parturition (96% accuracy) but became unreliable as calving progressed, as approximately 80% of parturient females shed their antlers during the calving period. In contrast, both movement methods performed marginally for estimating caribou parturition (~70% accuracy), with estimates from the individual-based method exhibiting greater bias than those from the population-based method. The individual-based method also poorly predicted neonate survival (≤49% accuracy for detecting parturition and calf fate for the Porcupine Herd). Video data revealed that inaccuracies with the movement methods often occurred when caribou bedded during storms, rested after traversing mountainous terrain, lost a calf shortly after birth, or increased movement to evade insects. These results have important implications for management agencies using antler- and movement-based methods to estimate caribou reproduction, particularly when informing assessments of population decline or recovery. Our results demonstrate the utility of video collar data for validating reproductive monitoring approaches and provide insights into how these approaches can be improved.

Alaska, Yukon↗
USGS2025

The geology of Canadian potash: A critical mineral for feeding the world

Potash, potassium-bearing water-soluble salt, is the primary global economic source of potassium. Potash is recognized as a critical mineral in Canada as it is the largest source of potassium used in fertilizers. It is essential for global agricultural productivity and food security. Canada is the world’s largest potash exporter with vast deposits in the widely mined Prairie Evaporite of Saskatchewan, which formed in the epicontinental Elk Point Basin during the Middle Devonian. Potash is also found in the Windsor Group of Atlantic Canada where it formed in a series of tectonically active basins during the Mississippian that have undergone substantial post-depositional subsurface alteration and deformation. Potash deposits were mined in New Brunswick up until 2016. Both deposits are salt giants, recording times in the geologic record of extensive and long-lasting evaporite genesis under arid conditions in restricted seas. This paper reviews the geological and economic significance of Canadian potash, including (1) the genesis of each deposit, (2) diagenetic, erosional, and tectonic modification, and (3) exploration and mining in each basin. Underdeveloped regions, possible undiscovered resources, environmental considerations, and the importance of sustainable practices in light of climate change and socioeconomic risks are also addressed.

Facets↗
USGS2026

USGS 2025 critical minerals review

The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.

Mining Engineering↗
USGS2025

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming↗
USGS2025

Groundwater budget for the surficial aquifer surrounding Lake Nokomis, Minneapolis, Minnesota

During prolonged periods of above-average precipitation, rising groundwater levels have the potential to cause damage to and interfere with underground infrastructure and building foundations. To understand the relations between precipitation and groundwater in the vicinity of Lake Nokomis, the U.S. Geological Survey, in collaboration with the University of Minnesota, quantified five components of the groundwater budget: groundwater recharge, change in surficial aquifer storage, surficial aquifer groundwater discharge to Lake Nokomis, groundwater evapotranspiration, and groundwater discharge to underlying bedrock aquifers. Field data, geologic records, and empirical calculation methods were used to quantify groundwater budget components for April 2023 through April 2024. Lake water budget data indicate that Lake Nokomis is a flowthrough system during periods with no outflow through the weir, with groundwater inputs equal to outputs. Roughly 40 percent of precipitation that fell in the study area was added to the surficial aquifer as recharge. Uncertainty in the vertical hydraulic conductivity resulted in wide-ranging estimates (spanning three orders of magnitude) of water discharging from the surficial aquifer to the underlying bedrock aquifer. Drought conditions persisted for the duration of this study and were not representative of the conditions that motivated this study. This study is a start towards understanding relations between precipitation, Lake Nokomis levels, and groundwater levels that could affect local underground infrastructure.

Minnesota↗
USGS2025

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado↗
USGS2025

Fluid inclusion constraints on the geometry of the magmatic plumbing system beneath Mauna Loa – Part 2: Xenoliths

Mauna Loa volcano erupts crystal-poor material at its summit and more crystal-rich material on its rift zones. Some of the more olivine-rich lava flows contain xenoliths with diverse mineralogy, including cumulate harzburgites with high-Mg# orthopyroxenes and high-Fo olivines (both > 84). Previous experimental work and thermodynamic modelling has proposed that high-Mg# orthopyroxenes only crystallize from Mauna Loa melts at high pressures (> 6 kbar, > 20 km), leading to suggestions that there is a region of sub-Moho magma storage at Mauna Loa in addition to the geophysically imaged magma reservoir at 2–5 km depth below the summit. We use melt and fluid inclusion barometry combined with thermodynamic models to further investigate this suggestion. Fluid inclusion data from harzburgites and dunitic xenoliths yield storage depths remarkably similar to those found in non-xenolithic crystals from lavas and tephras, with a clear peak at ~ 2–3 km (below the summit). Depths from melt inclusions in these xenoliths overlap with fluid inclusion pressures, ruling out the possibility of fluid inclusion re-equilibration during a period of stalling in a shallower reservoir. We examine five different thermodynamic models and find that the minimum pressure of olivine-orthopyroxene co-saturation varies by ~ 4 kbar (~ 12 km). These models also fail to predict that orthopyroxene is stable in ~ 15–80% of compositionally relevant experimental charges which grew orthopyroxene. Overall, this shows that phase stability modelling is an unreliable method of determining magma storage depth at Mauna Loa. We suggest that model discrepancies reflect a lack of experimental constraints on orthopyroxene stability at > 1200 ℃ and 0.01–5 kbar. Based on the presence of large oikocrystic orthopyroxenes completely enclosing rounded olivine chadacrysts, we suggest that these harzburgitic xenoliths formed through the reaction of intruding melts with olivine mush piles within the Mauna Loa edifice at ~ 3 km depth below the summit, with no need for a deeper storage reservoir. The predominance of pre-eruptive shallow storage means that there is more chance of detecting reservoir destabilization with geophysical monitoring techniques compared to a scenario where melts are supplied from sub-Moho reservoirs.

Hawaii↗
USGS2026

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews↗
USGS2025

Quaternary-active faults and the role of inherited structures in the Sacramento-San Joaquin Delta, western Central Valley, northern California

Seismic sources and their associated hazards within the Sacramento-San Joaquin Delta region of north-central California are relatively poorly characterized as compared to other, more heavily studied regions of northern California, such as the San Francisco Bay Area. Here we present a synthesis of subsurface, bedrock geology, and geodetic datasets from the Delta and from the Coast Ranges and Diablo Range to the northwest and southwest, respectively. We integrate these data and our own surface geologic and geomorphic observations to present a comprehensive review of faults in the Delta that exhibit Quaternary activity. Structural geologic data from the surrounding region highlight the significant influence that Late Cretaceous-to-Paleogene forearc structures exert on the geometry and kinematics of major Quaternary-active structures within the Delta. These inherited structures — including the Pittsburg-Kirby Hills Fault, Midland Fault, and Great Valley Fault System — exhibit a range of geometries and kinematics. Analysis of geomorphology along these structures suggests that these structures combine to accommodate Quaternary strain across the Delta region. A clearer understanding of subsurface geometries and structural relationships, built upon the regional tectonic history, provides insight into modern deformation accommodated on older structures and helps inform interpretations of seismic hazard within the Delta.

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